CN111454079A - Method for forming black substrate golden wafer ceramic product in glaze firing process - Google Patents
Method for forming black substrate golden wafer ceramic product in glaze firing process Download PDFInfo
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- CN111454079A CN111454079A CN202010276351.0A CN202010276351A CN111454079A CN 111454079 A CN111454079 A CN 111454079A CN 202010276351 A CN202010276351 A CN 202010276351A CN 111454079 A CN111454079 A CN 111454079A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 38
- 238000010304 firing Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000000758 substrate Substances 0.000 title claims abstract description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000015895 biscuits Nutrition 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- 239000010453 quartz Substances 0.000 claims abstract description 9
- 239000000454 talc Substances 0.000 claims abstract description 9
- 229910052623 talc Inorganic materials 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 8
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052656 albite Inorganic materials 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 229910021538 borax Inorganic materials 0.000 claims abstract description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 7
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 7
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 7
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 5
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000005507 spraying Methods 0.000 claims abstract description 5
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 4
- 239000011812 mixed powder Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 4
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000007873 sieving Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 235000012222 talc Nutrition 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229910011255 B2O3 Inorganic materials 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 238000004886 process control Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- ZDYUUBIMAGBMPY-UHFFFAOYSA-N oxalic acid;hydrate Chemical compound O.OC(=O)C(O)=O ZDYUUBIMAGBMPY-UHFFFAOYSA-N 0.000 description 2
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229940036811 bone meal Drugs 0.000 description 1
- 239000002374 bone meal Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- PGWFQHBXMJMAPN-UHFFFAOYSA-N ctk4b5078 Chemical compound [Cd].OS(=O)(=O)[Se]S(O)(=O)=O PGWFQHBXMJMAPN-UHFFFAOYSA-N 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Adornments (AREA)
- Cosmetics (AREA)
Abstract
A process for preparing the golden crystal plate with black substrate in the enamel firing procedure includes such steps as preparing ceramic biscuit, mixing potassium feldspar or albite, quartz, magnetite, ilmenite, titanium white powder, talc, zinc oxide, cobalt oxide, 5-11 wt% of borax and barium carbonate, ball grinding, adding aqueous solution of oxalic acid or citric acid to form emulsion, spraying it on the biscuit, enamel firing to obtain ceramic product with black fat shape, golden yellow spots or blocks, circular or elliptical shape, clear outline and area of 1-2 mm2。
Description
Technical Field
The invention relates to a method for manufacturing ceramic products, in particular to a method for forming a black substrate golden wafer ceramic product in a glaze firing process.
Background
The black substrate golden wafer ceramic product formed through the glaze firing process is generally known as high-grade ceramic due to elegant color and difficult process control. Few manufacturing methods are disclosed for such ceramics.
CN1724477A discloses a ceramic glaze for forming red glowing and skyhook effect, which mainly contains K2O and/or Na2O、Al2O3、SiO2、MgO、Fe2O3、P2O5CaO and B2O3In the glaze firing process, under an oxidizing atmosphere, the temperature is raised to 120-180 ℃ per hour, the temperature is raised to 30-70 ℃ per hour after 1050-1150 ℃, the temperature is kept at 1200-1300 ℃ for 10-120 minutes, fire is stopped, and the ceramic product with red glowing and changing skyhook meshes is obtained after natural cooling.
CN102070357A discloses a golden red temmoku transmutation fancy glazeThe preparation method of western-style food tableware adopts SiO as ground coat2、Al2O3，CaO，K2O，Fe2O3，Na2O，MnO2，B2O3，MgO，Li2O; the overglaze is SiO2，ZnO，Al2O3，CaO，B2O3，K2O，Na2O，TiO2BaO, MgO; the technological process includes the first preparation of tableware blank, the subsequent ball milling of ground glaze and surface glaze slurry, adding red pigment including cadmium sulfoselenide coated with zirconium silicate in 5-10 weight portions into the surface glaze slurry, glazing the blank and final sintering.
CN102515864A discloses a daily ceramic glaze with a gold crystal glaze, which consists of potash feldspar, kaolin, limestone, quartz, talc, glass powder, sericite, cobalt oxide, iron oxide and zinc oxide. The ceramic fired by the glaze formula has glittering and translucent fine patterns similar to gold.
CN103992140A discloses a cuprammonium enamel, which is composed of quartz, clay, calcined talc, calcite, bone meal, feldspar, iron oxide, calcined titanium oxide, and iron silicate.
Disclosure of Invention
The invention aims to provide a novel method for forming a black substrate golden wafer ceramic product in a glaze firing process, which has the advantages of easily available raw materials, simple process control and high yield.
The invention comprises the following steps:
A. making a ceramic blank, and firing the ceramic blank into a ceramic biscuit at 1200-1300 ℃;
B. mixing materials of 30-40 wt% of potassium feldspar or albite, 5-15 wt% of quartz, 10-20 wt% of magnetite, 5-10 wt% of ilmenite, 1-3 wt% of titanium dioxide, 5-10 wt% of talc, 3-5 wt% of zinc oxide, 5-11 wt% of cobalt oxide, 5-11 wt% of borax and 1-2 wt% of barium carbonate, wherein the total is 100%, performing ball milling, and sieving by a 500-mesh sieve to obtain mixed powder;
C. adding the mixed powder into 3-10 wt% of oxalic acid or citric acid aqueous solution according to the weight ratio of the mixed powder to the oxalic acid or citric acid aqueous solution of 1: 0.5-1.2, stirring uniformly to form emulsion, and aging for 2-7 days;
D. spraying the emulsion on a ceramic biscuit, wherein the coating weight is 200-400 g per square meter after drying;
E. glaze firing, heating at the speed of 60-120 ℃/h below 900 ℃, heating at the speed of 40-60 ℃/h at the temperature of 900-1150 ℃, keeping the temperature for 1-2 h at the temperature of 1150-1180 ℃, stopping firing, naturally cooling, and cooling to obtain the ceramic product.
Preferably, the materials in step B are: 30-40 wt% of potassium feldspar or albite, 5-15 wt% of quartz, 10-15 wt% of magnetite, 5-8 wt% of ilmenite, 1-3 wt% of titanium dioxide, 5-10 wt% of talc, 3-5 wt% of zinc oxide, 6-9 wt% of cobalt oxide, 7-10 wt% of borax and 1-2 wt% of barium carbonate.
In step C, the concentration of oxalic acid or citric acid aqueous solution is 5-10 wt%.
The ceramic product of the present invention has black grease appearance, countless golden flash spots or color blocks, circular or elliptical shape, clear outline and area of 1-2 mm2. The invention has the advantages of easily available raw materials, simple process control and high finished product rate of products up to over 80 percent.
Detailed Description
Example 1:
A. making a ceramic blank, and firing the ceramic blank into a ceramic biscuit at 1200-1300 ℃;
B. mixing 38 wt% of albite, 10 wt% of quartz, 12 wt% of magnetite, 6 wt% of ilmenite, 2 wt% of titanium dioxide, 8 wt% of talc, 4 wt% of zinc oxide, 8 wt% of cobalt oxide, 10 wt% of borax and 2 wt% of barium carbonate, performing ball milling, and sieving by using a 500-mesh sieve to obtain mixed powder;
C. adding the mixed powder into 8 wt% oxalic acid water solution at a weight ratio of the mixed powder to the oxalic acid water solution of 1: 1, stirring to form emulsion, standing and aging for 5 days;
D. spraying the emulsion on a ceramic biscuit, wherein the coating weight is 320 g per square meter after drying;
E. glaze firing, heating at a speed of 100 ℃/h below 900 ℃, heating at a speed of 50 ℃/h between 900 ℃ and 1150 ℃, keeping the temperature for 2 h at 1160 ℃, and then cooling at a speed of 50 ℃/h to obtain the ceramic product.
The ceramic product has dark black grease appearance, numerous golden flash spots or color blocks, circular or elliptical shape, clear outline, high brightness, and area of 1-2 mm2。
Example 2:
A. making a ceramic blank, and firing the ceramic blank into a ceramic biscuit at 1200-1300 ℃;
B. mixing 35 wt% of albite, 14 wt% of quartz, 15 wt% of magnetite, 6 wt% of ilmenite, 2 wt% of titanium dioxide, 8 wt% of talc, 5 wt% of zinc oxide, 6 wt% of cobalt oxide, 7 wt% of borax and 2 wt% of barium carbonate, performing ball milling, and sieving by using a 500-mesh sieve to obtain mixed powder;
C. adding the mixed powder into 8 wt% citric acid water solution at a weight ratio of 1: 1, stirring to form emulsion, standing and aging for 5 days;
D. spraying the emulsion on a ceramic biscuit, wherein the coating weight is 250 g per square meter after drying;
E. glaze firing, heating at a speed of 100 ℃/h below 900 ℃, heating at a speed of 50 ℃/h between 900 ℃ and 1150 ℃, keeping the temperature for 2 h at 1160 ℃, and then cooling at a speed of 50 ℃/h to obtain the ceramic product.
The ceramic article produced had a slightly lighter dark-black grease appearance than example 1, had numerous golden yellow sparkling spots or color patches, was round or oval, had a clear outline, was highly luminous, and had an area of about 1 to 2mm2。
Claims (3)
1. A method for forming a black substrate golden wafer ceramic product in an enamel firing process is characterized by comprising the following steps:
A. making a ceramic blank, and firing the ceramic blank into a ceramic biscuit at 1200-1300 ℃;
B. mixing 30-40 wt% of potassium feldspar or albite, 5-15 wt% of quartz, 10-20 wt% of magnetite, 5-10 wt% of ilmenite, 1-3 wt% of titanium dioxide, 5-10 wt% of talc, 3-5 wt% of zinc oxide, 5-11 wt% of cobalt oxide, 5-11 wt% of borax and 1-2 wt% of barium carbonate, wherein the total weight is 100 wt%, performing ball milling, and sieving by a 500-mesh sieve to obtain mixed powder;
C. adding the mixed powder into 3-20 wt% of oxalic acid or citric acid aqueous solution according to the weight ratio of the mixed powder to the oxalic acid or citric acid aqueous solution of 1: 0.5-1.2, stirring uniformly to form emulsion, and aging for 2-7 days;
D. spraying the emulsion on a ceramic biscuit, wherein the coating weight is 200-400 g per square meter after drying;
E. glaze firing, heating at the speed of 60-120 ℃/h below 900 ℃, heating at the speed of 40-60 ℃/h at the temperature of 900-1150 ℃, preserving heat for 1-2 h at the temperature of 1150-1180 ℃, and then cooling at the speed of 40-60 ℃/h to obtain the ceramic product.
2. The method of claim 1, wherein the material in step B is: 30-40 wt% of potassium feldspar or albite, 5-15 wt% of quartz, 10-15 wt% of magnetite, 5-8 wt% of ilmenite, 1-3 wt% of titanium dioxide, 5-10 wt% of talc, 3-5 wt% of zinc oxide, 6-9 wt% of cobalt oxide, 7-10 wt% of borax and 1-2 wt% of barium carbonate.
3. The method according to claim 1, wherein in the step C, the concentration of the aqueous solution of oxalic acid or citric acid is 5 to 10% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010276351.0A CN111454079A (en) | 2020-04-09 | 2020-04-09 | Method for forming black substrate golden wafer ceramic product in glaze firing process |
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| CN202010276351.0A CN111454079A (en) | 2020-04-09 | 2020-04-09 | Method for forming black substrate golden wafer ceramic product in glaze firing process |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113233766A (en) * | 2021-06-22 | 2021-08-10 | 景德镇陶瓷大学 | Three-dimensional fancy glaze for feldspar porcelain decoration and application method thereof |
| CN115259834A (en) * | 2022-06-08 | 2022-11-01 | 景德镇陶瓷大学 | Preparation method of building ceramic using high-calcium iron tailings as main raw material and ceramic product thereof |
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Application publication date: 20200728 |