CN110316968A - It is a kind of to burn polymorphic multicolour crystalline glaze and its preparation method and application fastly - Google Patents
It is a kind of to burn polymorphic multicolour crystalline glaze and its preparation method and application fastly Download PDFInfo
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- CN110316968A CN110316968A CN201910743849.0A CN201910743849A CN110316968A CN 110316968 A CN110316968 A CN 110316968A CN 201910743849 A CN201910743849 A CN 201910743849A CN 110316968 A CN110316968 A CN 110316968A
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- glaze
- polymorphic
- multicolour
- crystalline glaze
- crystalline
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- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 67
- 238000001354 calcination Methods 0.000 claims abstract description 39
- 239000000919 ceramic Substances 0.000 claims abstract description 32
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000005245 sintering Methods 0.000 claims abstract description 22
- 238000010792 warming Methods 0.000 claims abstract description 15
- 239000011787 zinc oxide Substances 0.000 claims abstract description 14
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims abstract description 12
- 239000010433 feldspar Substances 0.000 claims abstract description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010936 titanium Substances 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 7
- 238000002425 crystallisation Methods 0.000 claims abstract description 6
- 230000008025 crystallization Effects 0.000 claims abstract description 6
- 238000010411 cooking Methods 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000010453 quartz Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- 238000007873 sieving Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000013078 crystal Substances 0.000 abstract description 9
- 206010023126 Jaundice Diseases 0.000 abstract description 5
- 238000007665 sagging Methods 0.000 abstract description 4
- 229910052710 silicon Inorganic materials 0.000 abstract description 4
- 239000010703 silicon Substances 0.000 abstract description 4
- 230000000391 smoking effect Effects 0.000 abstract description 4
- 239000011575 calcium Substances 0.000 abstract description 3
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 238000003958 fumigation Methods 0.000 abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000011777 magnesium Substances 0.000 abstract description 2
- 229910052749 magnesium Inorganic materials 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- 229910052700 potassium Inorganic materials 0.000 abstract description 2
- 239000011734 sodium Substances 0.000 abstract description 2
- 229910052708 sodium Inorganic materials 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 239000007787 solid Substances 0.000 description 10
- 238000000498 ball milling Methods 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 7
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 239000004110 Zinc silicate Substances 0.000 description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 description 4
- ZOIVSVWBENBHNT-UHFFFAOYSA-N dizinc;silicate Chemical compound [Zn+2].[Zn+2].[O-][Si]([O-])([O-])[O-] ZOIVSVWBENBHNT-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 235000019352 zinc silicate Nutrition 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229910052611 pyroxene Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical class [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention belongs to ceramic glaze preparation technical fields, it is specially a kind of to burn polymorphic multicolour crystalline glaze and preparation method thereof fastly, a kind of preparation method for burning polymorphic multicolour crystalline glaze ceramic product fastly, burn polymorphic multicolour crystalline glaze ceramic product and its high temperature method for cooking fastly more particularly to a kind of fast burning polymorphic multicolour crystalline glaze and its preparation method and application.The crystalline glaze passes through calcining precipitated calcium carbonate (calcium), it calcines light magnesium carbonate (magnesium), calcining zinc oxide (zinc), calcined oxide titanium (titanium), kaolin (silicon), quartzy (silicon), feldspar (potassium, sodium) seven kinds of metal system cooperations, glaze slip is set to be in hypersaturated state, improve the crystallization rate of crystalline glaze, expand crystal region, avoid easy sagging, (the yin jaundice and fumigation occur) problem of smoking, make crystalline glaze that can normally be warming up to sintering temperature under the premise of not influencing its performance, room temperature is quickly down to after sintering, shorten manufacturing cycle, energy-saving and environment-friendly effect is reached.
Description
Technical field
The invention belongs to ceramic glaze preparation technical fields, and in particular to it is a kind of fast burn polymorphic multicolour crystalline glaze and its
Fast burning polymorphic multicolour crystalline glaze of preparation method and application, specially one kind and preparation method thereof, a kind of fast burning polymorphic are more
The preparation method of color crystalline glaze ceramic product, fast burning polymorphic multicolour crystalline glaze ceramic product and its high temperature method for cooking.
Background technique
Crystalline glaze be product after glaze melts at high temperature in sintering process its crystalline material it is in a saturated state, work as cooling
After generate crystallization, so that the crystalline solid of beautiful decorative pattern be precipitated.China has just burnt out " iron rust flower ", " tealeaves early in two Song's periods
The rare crystalline glaze such as end ", " oil droplet temmoku ", people also have developed " zinc silicate crystalline glaze ", " calcium silicates crystalline glaze " and " gold in recent years
Red stone crystalline glaze " etc., crystalline glaze are spent bright and colourful, beautiful grace with its crystalline form transformation nature, crystalline substance, are liked by people, so
And the production crystallization condition of these crystalline glazes is stringent, complex operation, enamel influence factor is more.
Chinese patent literature CN109279780A discloses a kind of ceramic glaze and preparation method thereof of resistance to alkali corrosion,
Including boron frit, silica flour, spodumene, calcining zinc oxide, calcinated talc powder, kaolin, zirconium silicate and toner, preparation method
Including carrying out ball milling, sieving to each component, then plus water and electrolyte adjust the concentration and thixotropy of glaze slip respectively, then by glaze
Base is immersed in glaze slip, and glazed body is entered roller kiln burning at ceramic glaze, the patent also needs that electricity is added when preparing glaze slip after drying
Xie Zhi, but electrolyte easily leads to ceramic and stomata occurs, is used cooperatively if being added without electrolyte, will affect the touching of glaze slip
Denaturation.In addition, in the prior art, the also generally existing glaze slip poor fluidity of the preparation process of crystalline glaze, to sintering atmosphere require compared with
To be stringent, during the sintering process glaze layer easily occur yin jaundice and sootiness, crystalline glaze thermal stability it is poor the problems such as.
Summary of the invention
Therefore, it the technical problem to be solved in the present invention is that overcoming glaze slip thixotropy and poor fluidity in the prior art, burns
Glaze layer after knot occur yin jaundice and fumigation, crystalline glaze thermal stability it is poor the defects of, a kind of fast burn polymorphic to provide
Multicolour crystalline glaze and its preparation method and application.
For this purpose, the present invention provides following technical schemes.
Burn polymorphic multicolour crystalline glaze the present invention provides a kind of fast, raw material proportioning based on parts by weight, including such as
Lower raw material: 0.5-1.5 parts of colorant, 5-10 parts of calcined oxide titanium, calcines precipitated calcium carbonate 10-20 at 15-20 parts of calcining zinc oxide
6-8 parts of part, light magnesium carbonate 10-20 parts of calcining, 20-30 parts of feldspar, 7-9 parts of kaolin and quartz.
The colorant is selected from least one of cobalt oxide, iron oxide, chromium oxide or manganese oxide.
The present invention also provides a kind of above-mentioned fast preparation methods for burning polymorphic multicolour crystalline glaze, comprising the following steps:
After raw material is mixed according to the weight ratio plus water is ground, and then obtains finished product glaze slip after sieving, water tune.
The moisture content of the finished product glaze slip is 40-50wt%.
In addition, the present invention provides a kind of fast preparation methods for burning polymorphic multicolour crystalline glaze ceramic product, in green body
On apply and burn polymorphic multicolour crystalline glaze, the thickness of glaze layer fastly made from above-mentioned fast burning polymorphic multicolour crystalline glaze or the above method
Degree is 3-5mm, obtains burning polymorphic multicolour crystalline glaze ceramic product fastly after high temperature sintering, cooling.
Further, by being stained with glaze, pouring glaze or glazing by sufflation method applies the fast burning polymorphic multicolour crystalline glaze on green body.
The rate of the cooling is 6.5-8 DEG C/min.
The present invention also provides one kind to burn polymorphic multicolour crystalline glaze ceramic product fastly as made from above-mentioned preparation method,
The crystalline glaze ceramic product can be applied to architectural pottery, domestic ceramics or the art pottery.
Further, the present invention provides a kind of above-mentioned fast high temperature firings for burning polymorphic multicolour crystalline glaze ceramic product
Temperature is risen to from room temperature 295-320 DEG C of a certain temperature, heating-up time 3-4h at 0.01-0.015MPa by method；So
It is warming up to 845-875 DEG C of a certain temperature, heating-up time 1-1.5h afterwards, the pressure of the process is 0.015-0.025MPa；So
It is warming up to 1135-1155 DEG C of a certain temperature, heating-up time 2-2.5h afterwards, the pressure of the process is 0.025MPa；Finally rise
The a certain temperature of temperature to 1250-1300 DEG C, heating-up time 1-1.5h, the pressure of the process are 0.025-0.030MPa；The burning
Knot method is the sintering atmosphere of oxygen abundance.
The present invention also provides a kind of above-mentioned fast high temperature method for cooking for burning polymorphic multicolour crystalline glaze ceramic product,
Under 0.01-0.015MPa, temperature is risen to from room temperature to 295-320 DEG C of a certain temperature, heating-up time 3-4h；It then heats to
845-875 DEG C of a certain temperature, heating-up time 1-1.5h, the pressure of the process are 0.015-0.025MPa；It then heats to
935-975 DEG C of a certain temperature, heating-up time 0.5-1.0h, the pressure of the process are 0.025MPa；Then heat to 1135-
The pressure of 1155 DEG C of a certain temperature, heating-up time 1.0-1.5h, the process is 0.045-0.05MPa, is finally warming up to
1250-1300 DEG C of a certain temperature, heating-up time 1-1.5h, the pressure of the process are 0.03-0.045MPa；The sintering method
For for the insufficient sintering atmosphere of oxygen.
Technical solution of the present invention has the advantages that
1. fast burning polymorphic multicolour crystalline glaze provided by the invention, the crystalline glaze by calcining precipitated calcium carbonate (calcium),
Calcine light magnesium carbonate (magnesium), calcining zinc oxide (zinc), calcined oxide titanium (titanium), kaolin (aluminium), quartzy (silicon), feldspar (potassium,
Sodium) seven kinds of metal system cooperations, so that glaze slip be in oversaturated state, improves the crystallization rate of crystalline glaze, expansion crystal region
Domain, makes crystalline glaze under the premise of not influencing its performance at the problem of avoiding easy sagging, smoking (yin jaundice and fumigation occur)
It is quickly down to room temperature after sintering temperature, sintering being normally warming up to, has reached energy-saving and environment-friendly effect；And the crystalline glaze
Better heat stability；
The present invention can adjust the thixotropic characteristic of glaze slip using calcining zinc oxide, the calcined magnesia of specific proportion, simultaneously
By adjusting each group distribution ratio, under the premise of not using electrolyte, the mobility of glaze slip is improved, glazed thickness is improved
Accuracy avoids Products of Crystalline Glaze from stomata occur.
The crystalline glaze can be such that crystalline glaze presents a variety of by introducing the toners such as iron oxide, cobalt oxide, chromium oxide or manganese oxide
Color.
2. the fast preparation method for burning polymorphic multicolour crystalline glaze ceramic product provided by the invention, this method includes will be former
It is ground after material mixing, then obtains finished product glaze slip after sieving, water tune；On green body, using being stained with glaze, pour glaze or the side of glazing by sufflation
Method glazing, green body after sintering, are quickly down to room temperature, obtain crystalline glaze, when the rate of 6.5-8 DEG C/min cools down, glaze melt exists
Oversaturated magnesium silicate crystalline solid, zinc silicate crystalline solid, perovskite crystalline body and pyroxene have been formd under high temperature fused state
Dotted, needle-shaped, stick can be quickly precipitated in the crystalline solid of the polymorphic types such as type crystalline solid, these crystal from glaze melt while cooling
The crystalline solid of the variforms such as shape, sheet；In addition, coloring oxide is added in glaze slip, coloury glaze can also be obtained
Face.
Crystalline glaze provided by the invention contain during the sintering process the calcium silicate crystals that can be quickly precipitated, perovskite crystal,
Polymorphous crystal such as cordierite crystal and zinc silicate can make glaze layer variation abundant, while dotted, needle-shaped, column, piece is presented
A variety of crystal forms such as shape crystallization.
In addition, the present invention, in high-temperature sintering process, calcining precipitated calcium carbonate, calcining light magnesium carbonate decompose and generate oxidation
Calcium and magnesia are formed by a plurality of types of crystalline solid with zinc oxide, titanium oxide, silicon substance etc., sufficient or not in oxygen
Magnesium silicate crystalline solid, zinc silicate crystalline solid, perovskite crystalline body and pyroxene type crystalline solid are formed under sufficient firing condition, are had
The advantages that brilliant Hua Shizhong, crystal form are naturally beautiful, rich in color, sparkling and crystal-clear beautiful, firing stability is good, without taking heat preservation method,
The production technology for porcelain carving either domestic ceramics tea set or tableware product is adapted to, technical economic benefit is good, and the present invention mentions
The crystalline glaze of confession adapts to a variety of high-temperature electric resistance furnaces.
Specific embodiment
There is provided following embodiments is to preferably further understand the present invention, it is not limited to the best embodiment party
Formula is not construed as limiting the contents of the present invention and protection scope, anyone under the inspiration of the present invention or by the present invention and its
The feature of his prior art is combined and any and identical or similar product of the present invention for obtaining, all falls within of the invention
Within protection scope.
Specific experiment step or condition person are not specified in embodiment, according to the literature in the art described routine experiment
The operation of step or condition can carry out.Reagents or instruments used without specified manufacturer, being can be by commercially available acquisition
Conventional reagent product.
Embodiment 1
A kind of fast burning polymorphic multicolour crystalline glaze is present embodiments provided, consisting of: 15 parts of calcining zinc oxide, calcining
10 parts of titanium oxide, calcining 15 parts of precipitated calcium carbonate, calcining 15 parts of light magnesium carbonate, 30 parts of feldspar, 8 parts of kaolin, quartz 7 parts and
1.5 parts of cobalt oxides；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 45%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of being stained with glaze, glazed thickness is controlled in 3-5mm, will at 0.01MPa
Temperature rises to 300 DEG C from room temperature, heating-up time 3.5h；850 DEG C, heating-up time 1h are then heated to, the pressure of the process
For 0.025MPa；1150 DEG C, heating-up time 2.3h are then heated to, the pressure of the process is 0.025MPa；Finally it is warming up to
1280 DEG C, heating-up time 1h, the pressure of the process is 0.030MPa；Then, it is down to often with the rate of temperature fall of 6.9 DEG C/min
Temperature obtains crystalline glaze ceramic product.
Embodiment 2
A kind of fast burning polymorphic multicolour crystalline glaze is present embodiments provided, consisting of: 15 parts of calcining zinc oxide, calcining
10 parts of titanium oxide, calcining 15 parts of precipitated calcium carbonate, calcining 20 parts of light magnesium carbonate, 20 parts of feldspar, 8 parts of kaolin, quartz 7 parts,
0.8 part of iron oxide；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 45%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of glazing by sufflation, glazed thickness is controlled in 3-5mm, then in 0.015MPa
Under, temperature is risen to 320 DEG C from room temperature, heating-up time 4h；845 DEG C, heating-up time 1.5h are then heated to, the process
Pressure is 0.015MPa；1135 DEG C, heating-up time 2h are then heated to, the pressure of the process is 0.025MPa；Finally heat up
To 1300 DEG C, heating-up time 1.5h, the pressure of the process is 0.025MPa；Then, it is down to the rate of temperature fall of 7.2 DEG C/min
Room temperature obtains crystalline glaze ceramic product.
Embodiment 3
A kind of fast burning polymorphic multicolour crystalline glaze is present embodiments provided, consisting of: 20 parts of calcining zinc oxide, calcining
5 parts of titanium oxide, calcining 20 parts of precipitated calcium carbonate, calcining 10 parts of light magnesium carbonate, 25 parts of feldspar, 8 parts of kaolin, quartz 7 parts and
0.8 part of cobalt oxide and 0.2 part of iron oxide；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 45%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of being stained with glaze, glazed thickness is controlled in 3-5mm, will at 0.01MPa
Temperature rises to 298 DEG C from room temperature, heating-up time 3h；875 DEG C, heating-up time 1.2h are then heated to, the pressure of the process
For 0.02MPa；1155 DEG C, heating-up time 2.5h are then heated to, the pressure of the process is 0.025MPa；Finally it is warming up to
1250 DEG C, heating-up time 1h, the pressure of the process is 0.030MPa；Then, it is down to often with the rate of temperature fall of 6.9 DEG C/min
Temperature obtains crystalline glaze ceramic product.
Embodiment 4
A kind of fast burning polymorphic multicolour crystalline glaze is present embodiments provided, consisting of: 20 parts of calcining zinc oxide, calcining
10 parts of titanium oxide, calcining 15 parts of precipitated calcium carbonate, calcining 15 parts of light magnesium carbonate, 25 parts of feldspar, 8 parts of kaolin, quartz 7 parts,
0.5 part of chromium oxide；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 40%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of being stained with glaze, glazed thickness is controlled in 3-5mm, then in 0.012MPa
Under, temperature is risen to 300 DEG C from room temperature, heating-up time 3h；850 DEG C, heating-up time 1h are then heated to, the pressure of the process
Power is 0.020MPa；950 DEG C, heating-up time 0.8h are then heated to, the pressure of the process is 0.025MPa；It then heats to
1150 DEG C, heating-up time 1.2h, the pressure of the process is 0.045MPa, is finally warming up to 1285 DEG C, heating-up time 1.5h,
The pressure of the process is then 0.040MPa is down to room temperature with the rate of temperature fall of 6.6 DEG C/min, obtains crystalline glaze ceramic product.
Embodiment 5
A kind of fast burning polymorphic multicolour crystalline glaze is present embodiments provided, consisting of: 15 parts of calcining zinc oxide, calcining
10 parts of titanium oxide, calcining 10 parts of precipitated calcium carbonate, calcining 20 parts of light magnesium carbonate, 20 parts of feldspar, 8 parts of kaolin, quartz 7 parts,
1 part of cobalt oxide；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 50%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of being stained with glaze, glazed thickness is controlled in 3-5mm, then in 0.01MPa
Under, temperature is risen to 295 DEG C from room temperature, heating-up time 3.5h；875 DEG C, heating-up time 1.5h are then heated to, the process
Pressure be 0.025MPa；935 DEG C, heating-up time 0.5h are then heated to, the pressure of the process is 0.025MPa；Then it rises
For temperature to 1135 DEG C, heating-up time 1.0h, the pressure of the process is 0.05MPa, is finally warming up to 1300 DEG C, and the heating-up time is
1h, the pressure of the process are then 0.03MPa is down to room temperature with the rate of temperature fall of 8 DEG C/min, obtains crystalline glaze ceramic product.
Embodiment 6
A kind of fast burning polymorphic multicolour crystalline glaze is present embodiments provided, consisting of: 18 parts of calcining zinc oxide, calcining
8 parts of titanium oxide, calcining 120 parts of precipitated calcium carbonate, calcining 10 parts of light magnesium carbonate, 30 parts of feldspar, 9 parts of kaolin, quartz 6 parts,
0.5 part of chromium oxide；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 45%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of being stained with glaze, glazed thickness is controlled in 3-5mm, then in 0.012MPa
Under, temperature is risen to 320 DEG C from room temperature, heating-up time 4h；848 DEG C, heating-up time 1.2h are then heated to, the process
Pressure is 0.020MPa；970 DEG C, heating-up time 0.8h are then heated to, the pressure of the process is 0.025MPa；Then it heats up
To 1152 DEG C, heating-up time 1.2h, the pressure of the process is 0.045MPa, is finally warming up to 1255 DEG C, and the heating-up time is
1.5h, the pressure of the process are then 0.040MPa is down to room temperature with the rate of temperature fall of 7 DEG C/min, obtain the production of crystalline glaze ceramics
Product.Comparative example 1
This comparative example provides a kind of crystalline glaze, consisting of: 10 parts of calcining zinc oxide, 10 parts of calcined oxide titanium, calcining
15 parts of precipitated calcium carbonate, 15 parts of light magnesium carbonate of calcining, 35 parts of feldspar, 10 parts of kaolin, quartzy 7 parts and 1.5 parts of cobalt oxides；
The preparation of above-mentioned crystalline glaze and sintering method be,
Above-mentioned raw materials are uniformly mixed, are added in ball mill, then plus water carries out ball milling processing, then crosses 180 meshes, adds
The water content that water adjusts glaze is 45%, obtains finished product glaze slip；
Green body is taken, glazing operation is carried out by the way of being stained with glaze, glazed thickness is controlled in 3-5mm, will at 0.01MPa
Temperature rises to 300 DEG C from room temperature, heating-up time 3.5h；850 DEG C, heating-up time 1h are then heated to, the pressure of the process
For 0.025MPa；1150 DEG C, heating-up time 2.3h are then heated to, the pressure of the process is 0.025MPa；Finally it is warming up to
1280 DEG C, heating-up time 1h, the pressure of the process is 0.030MPa；Then, it is down to often with the rate of temperature fall of 6.9 DEG C/min
Temperature obtains crystalline glaze ceramic product.
Test example
Performance test and as a result, the test side of the offer of this test example embodiment 1-6 and glaze slip and crystalline glaze in comparative example 1
Method is as follows, and test result is shown in Table 1；
Glaze slip fluidity testing method is shown in GB/T23460.1-2009；
The heat stability testing method of crystalline glaze: each example takes 10 qualified samples to be tested, puts it into sample basket
It is interior, it is placed in ceramic qualitative determination instrument, starts instrument, then when temperature reaches measurement temperature, after keeping the temperature 15min, stir hand
Handle makes sample basket hit the drink rapidly, after cooling 5min, takes out sample from water, after wiped clean, then checks whether out
It splits, if do not cracked, puts it into instrument, be heated to next measurement temperature (temperature interval measured twice is 20 DEG C),
Until repeating test to 10 samples all cracking, data are recorded, then calculate the cold temperature difference of heat being subjected to that is averaged of 10 samples
(the cold temperature difference of heat is to measure the difference of temperature and room temperature), as thermal stability, the temperature difference is bigger, and thermal stability is better, wherein every survey
Examination is primary, replaces a water, it is therefore an objective to remain unchanged water temperature.
The performance test results of crystalline glaze made from 1 embodiment 1-6 of table and comparative example 1
In table 1, the thermal stability of the good fluidity of the glaze slip in embodiment 1-6, crystalline glaze is good, and do not occur sagging,
The phenomenon that smoking；Not in the present invention, the mobility of the glaze slip in comparative example 1 is relatively poor for the composition of crystalline glaze in comparative example 1,
The thermal stability of crystalline glaze is also poor, and the problem of slight yin jaundice or sootiness occurs.
Preparation method provided by the invention does not have the problem of sagging, smoking, the thermal stability of the crystalline glaze of preparation and flowing
Preferable, the energy conservation and environmental protection of property.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And thus amplify out it is obvious variation or
It changes still within the protection scope of the invention.
Claims (10)
1. a kind of fast burn polymorphic multicolour crystalline glaze, which is characterized in that its raw material proportioning is based on parts by weight, including following former
Material: 0.5-1.5 part of colorant, 15-20 parts of calcining zinc oxide, 5-10 parts of calcined oxide titanium, calcine precipitated calcium carbonate 10-20 parts,
6-8 parts of light magnesium carbonate 10-20 parts of calcining, 20-30 parts of feldspar, 7-9 parts of kaolin and quartz.
2. fast burning polymorphic multicolour crystalline glaze according to claim 1, which is characterized in that the colorant is selected from oxidation
At least one of cobalt, iron oxide, chromium oxide or manganese oxide.
3. a kind of any one of claim 1-2 fast preparation method for burning polymorphic multicolour crystalline glaze, which is characterized in that packet
Include following steps: after raw material is mixed according to the weight ratio plus water is ground, and then obtains finished product glaze slip after sieving, water tune.
4. preparation method according to claim 3, which is characterized in that the moisture content of the finished product glaze slip is 40-50wt%.
5. a kind of fast preparation method for burning polymorphic multicolour crystalline glaze ceramic product, which is characterized in that the Shi Quanli on green body
It is required that burning polymorphic fastly made from any one of 1-2 fast burning polymorphic multicolour crystalline glaze or claim 3 or 4 the methods
Multicolour crystalline glaze, glaze layer with a thickness of 3-5mm, obtain burning polymorphic multicolour crystallization glazed pottery after high temperature sintering, cooling fastly
Porcelain products.
6. preparation method according to claim 5, which is characterized in that by being stained with glaze, pouring glaze or glazing by sufflation method is on green body
Apply the fast burning polymorphic multicolour crystalline glaze.
7. preparation method according to claim 5, which is characterized in that the rate of the cooling is 6.5-8 DEG C/min.
8. one kind burns the production of polymorphic multicolour crystalline glaze ceramics fastly as made from any one of the claim 5-7 preparation method
Product, which is characterized in that the crystalline glaze ceramic product can be applied to architectural pottery, domestic ceramics or the art pottery.
9. burning the high temperature method for cooking of polymorphic multicolour crystalline glaze ceramic product described in a kind of claim 8 fastly, feature exists
In at 0.01-0.015MPa, temperature to be risen to from room temperature to 295-320 DEG C of a certain temperature, heating-up time 3-4h；Then
It is warming up to 845-875 DEG C of a certain temperature, heating-up time 1-1.5h, the pressure of the process is 0.015-0.025MPa；Then
It is warming up to 1135-1155 DEG C of a certain temperature, heating-up time 2-2.5h, the pressure of the process is 0.025MPa；Finally heat up
To 1250-1300 DEG C of a certain temperature, heating-up time 1-1.5h, the pressure of the process is 0.025-0.030MPa.
10. burning the high temperature method for cooking of polymorphic multicolour crystalline glaze ceramic product described in a kind of claim 8 fastly, feature exists
In at 0.01-0.015MPa, temperature to be risen to from room temperature to 295-320 DEG C of a certain temperature, heating-up time 3-4h；Then
It is warming up to 845-875 DEG C of a certain temperature, heating-up time 1-1.5h, the pressure of the process is 0.015-0.025MPa；Then
It is warming up to 935-975 DEG C of a certain temperature, heating-up time 0.5-1.0h, the pressure of the process is 0.025MPa；Then it heats up
Pressure to 1135-1155 DEG C of a certain temperature, heating-up time 1.0-1.5h, the process is 0.045-0.05MPa, is finally risen
The a certain temperature of temperature to 1250-1300 DEG C, heating-up time 1-1.5h, the pressure of the process are 0.03-0.045MPa.
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