CN1112418C - 用于由环氧化－羟基二烯聚合物制造可紫外固化粘合剂和密封剂的无溶剂方法 - Google Patents

用于由环氧化－羟基二烯聚合物制造可紫外固化粘合剂和密封剂的无溶剂方法 Download PDF

Info

Publication number: CN1112418C
Authority: CN; China
Prior art keywords: monohydroxy; block; polymkeric substance; light trigger; epoxidation
Prior art date: 1995-06-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CN96196032A

Other languages

English (en)

Chinese (zh)

Other versions

CN1192227A (zh

Inventor

K·S·凯伯勒

J·G·索思维克

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Internationale Research Maatschappij BV

Original Assignee

Shell Internationale Research Maatschappij BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-06-16

Filing date

1996-06-12

Publication date

2003-06-25

1996-06-12 Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV

1998-09-02 Publication of CN1192227A publication Critical patent/CN1192227A/zh

2003-06-25 Application granted granted Critical

2003-06-25 Publication of CN1112418C publication Critical patent/CN1112418C/zh

2016-06-12 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 42
238000000034 method Methods 0.000 title claims abstract description 33
150000001993 dienes Chemical class 0.000 title claims abstract description 19
239000002904 solvent Substances 0.000 title claims abstract description 19
230000008569 process Effects 0.000 title claims abstract description 10
239000013466 adhesive and sealant Substances 0.000 title abstract 2
229920005989 resin Polymers 0.000 claims abstract description 38
239000011347 resin Substances 0.000 claims abstract description 38
239000000203 mixture Substances 0.000 claims abstract description 34
238000006735 epoxidation reaction Methods 0.000 claims abstract description 22
239000000178 monomer Substances 0.000 claims abstract description 16
239000004593 Epoxy Substances 0.000 claims abstract description 9
239000000126 substance Substances 0.000 claims description 50
239000003795 chemical substances by application Substances 0.000 claims description 32
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 18
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
-1 alkenyl aromatic hydrocarbon Chemical class 0.000 claims description 9
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
229920001577 copolymer Polymers 0.000 claims description 6
239000008393 encapsulating agent Substances 0.000 claims description 4
239000004215 Carbon black (E152) Substances 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
229930195733 hydrocarbon Natural products 0.000 claims description 2
150000002430 hydrocarbons Chemical class 0.000 claims description 2
ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims 1
229920003051 synthetic elastomer Polymers 0.000 claims 1
239000005061 synthetic rubber Substances 0.000 claims 1
238000009472 formulation Methods 0.000 abstract description 6
229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 14
238000001723 curing Methods 0.000 description 12
238000002360 preparation method Methods 0.000 description 12
239000000853 adhesive Substances 0.000 description 11
230000001070 adhesive effect Effects 0.000 description 11
238000005984 hydrogenation reaction Methods 0.000 description 10
238000007789 sealing Methods 0.000 description 10
238000009826 distribution Methods 0.000 description 9
239000003999 initiator Substances 0.000 description 8
239000006185 dispersion Substances 0.000 description 7
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 7
BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 6
239000000463 material Substances 0.000 description 6
238000006116 polymerization reaction Methods 0.000 description 6
238000012360 testing method Methods 0.000 description 6
239000011230 binding agent Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
230000005855 radiation Effects 0.000 description 5
238000012546 transfer Methods 0.000 description 5
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 4
238000007334 copolymerization reaction Methods 0.000 description 4
238000005227 gel permeation chromatography Methods 0.000 description 4
239000011159 matrix material Substances 0.000 description 4
239000003504 photosensitizing agent Substances 0.000 description 4
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000000499 gel Substances 0.000 description 3
229910052740 iodine Inorganic materials 0.000 description 3
239000011630 iodine Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
239000004902 Softening Agent Substances 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
238000005266 casting Methods 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
VPUGDVKSAQVFFS-UHFFFAOYSA-N coronene Chemical compound C1=C(C2=C34)C=CC3=CC=C(C=C3)C4=C4C3=CC=C(C=C3)C4=C2C3=C1 VPUGDVKSAQVFFS-UHFFFAOYSA-N 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
230000006378 damage Effects 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000000945 filler Substances 0.000 description 2
MBAKFIZHTUAVJN-UHFFFAOYSA-I hexafluoroantimony(1-);hydron Chemical compound F.F[Sb](F)(F)(F)F MBAKFIZHTUAVJN-UHFFFAOYSA-I 0.000 description 2
239000012943 hotmelt Substances 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
150000004967 organic peroxy acids Chemical class 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000000049 pigment Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
229920005604 random copolymer Polymers 0.000 description 2
239000010959 steel Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
DXBHBZVCASKNBY-UHFFFAOYSA-N 1,2-Benz(a)anthracene Chemical compound C1=CC=C2C3=CC4=CC=CC=C4C=C3C=CC2=C1 DXBHBZVCASKNBY-UHFFFAOYSA-N 0.000 description 1
KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
PAWXNABRTCGGRV-UHFFFAOYSA-N 1-dodecyl-2-iodobenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1I PAWXNABRTCGGRV-UHFFFAOYSA-N 0.000 description 1
DIYFBIOUBFTQJU-UHFFFAOYSA-N 1-phenyl-2-sulfanylethanone Chemical compound SCC(=O)C1=CC=CC=C1 DIYFBIOUBFTQJU-UHFFFAOYSA-N 0.000 description 1
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
QTTAWIGVQMSWMV-UHFFFAOYSA-N 3,4-dimethylhexa-1,3-diene Chemical compound CCC(C)=C(C)C=C QTTAWIGVQMSWMV-UHFFFAOYSA-N 0.000 description 1
OCTVDLUSQOJZEK-UHFFFAOYSA-N 4,5-diethylocta-1,3-diene Chemical compound CCCC(CC)C(CC)=CC=C OCTVDLUSQOJZEK-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 1
229910017008 AsF 6 Inorganic materials 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
239000004821 Contact adhesive Substances 0.000 description 1
229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
229910018286 SbF 6 Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
XBDYBAVJXHJMNQ-UHFFFAOYSA-N Tetrahydroanthracene Natural products C1=CC=C2C=C(CCCC3)C3=CC2=C1 XBDYBAVJXHJMNQ-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
229910052768 actinide Inorganic materials 0.000 description 1
150000001255 actinides Chemical class 0.000 description 1
239000002390 adhesive tape Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
PCWZHTGDXLRULT-UHFFFAOYSA-N buta-1,3-dienylbenzene styrene Chemical compound C(=C)C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 PCWZHTGDXLRULT-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
238000010538 cationic polymerization reaction Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000012937 correction Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
230000001934 delay Effects 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
150000002118 epoxides Chemical class 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000004845 hydriding Methods 0.000 description 1
230000001976 improved effect Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000012939 laminating adhesive Substances 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
150000002632 lipids Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
150000002642 lithium compounds Chemical class 0.000 description 1
239000002075 main ingredient Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000000269 nucleophilic effect Effects 0.000 description 1
238000005457 optimization Methods 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920005990 polystyrene resin Polymers 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
238000003847 radiation curing Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
229920013730 reactive polymer Polymers 0.000 description 1
230000004044 response Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
229920002725 thermoplastic elastomer Polymers 0.000 description 1
YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
230000007704 transition Effects 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
125000005409 triarylsulfonium group Chemical group 0.000 description 1
229920000428 triblock copolymer Polymers 0.000 description 1
238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
239000011345 viscous material Substances 0.000 description 1
239000011800 void material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J115/00—Adhesives based on rubber derivatives
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/08—Epoxidised polymerised polyenes
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/005—Modified block copolymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/08—Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Adhesives Or Adhesive Processes (AREA)
Epoxy Resins (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Sealing Material Composition (AREA)
Compositions Of Macromolecular Compounds (AREA)

CN96196032A 1995-06-16 1996-06-12 用于由环氧化－羟基二烯聚合物制造可紫外固化粘合剂和密封剂的无溶剂方法 Expired - Fee Related CN1112418C (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US26895P	1995-06-16	1995-06-16
US000,268		1995-06-16

Publications (2)

Publication Number	Publication Date
CN1192227A CN1192227A (zh)	1998-09-02
CN1112418C true CN1112418C (zh)	2003-06-25

Family

ID=21690722

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN96196032A Expired - Fee Related CN1112418C (zh)	1995-06-16	1996-06-12	用于由环氧化－羟基二烯聚合物制造可紫外固化粘合剂和密封剂的无溶剂方法

Country Status (11)

Country	Link
US (1)	US5691414A (ja)
EP (1)	EP0832163B1 (ja)
JP (1)	JPH11507968A (ja)
CN (1)	CN1112418C (ja)
BR (1)	BR9608932A (ja)
CA (1)	CA2224636A1 (ja)
DE (1)	DE69601718T2 (ja)
ES (1)	ES2128866T3 (ja)
TW (1)	TW407163B (ja)
WO (1)	WO1997000299A1 (ja)
ZA (1)	ZA965077B (ja)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP4662598B2 (ja) *	1999-09-06	2011-03-30	積水化学工業株式会社	反応性ホットメルト接着剤組成物
WO2001081494A2 (en) *	2000-04-27	2001-11-01	Kraton Polymers Research B.V.	Non-aqueous solvent-free process for making uv curable adhesives and sealants from epoxidized monohydroxylated diene polymers
US20040162371A1 (en) *	2001-05-03	2004-08-19	Erickson James R	Formulation for strippable adhesive and coating films
US6803081B2 (en) *	2001-06-26	2004-10-12	National Starch And Chemical Investment Holding Corporation	Radiation curable adhesive
US7723441B2 (en) *	2005-12-29	2010-05-25	Corning Incorporated	Low out-gassing room temperature curable rubbery polymer, preparation thereof and device comprising same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1066275A (zh) *	1991-04-29	1992-11-18	国际壳牌研究有限公司	交联环氧官能聚二烯嵌段聚合物，其制备方法，粘合剂组合物及起始嵌段共聚物
US5393818A (en) *	1993-04-06	1995-02-28	Shell Oil Company	Solvent-free laminating adhesive composition from epoxidized block polymer

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5500481A (en) *	1995-05-17	1996-03-19	Shell Oil Company	Compositions containing epoxidized monohydroxylated diene polymers, amino resins, and reactive reinforcement agents

1996
- 1996-06-11 US US08/665,071 patent/US5691414A/en not_active Expired - Lifetime
- 1996-06-12 BR BR9608932A patent/BR9608932A/pt not_active Application Discontinuation
- 1996-06-12 CN CN96196032A patent/CN1112418C/zh not_active Expired - Fee Related
- 1996-06-12 DE DE69601718T patent/DE69601718T2/de not_active Expired - Fee Related
- 1996-06-12 ES ES96921990T patent/ES2128866T3/es not_active Expired - Lifetime
- 1996-06-12 CA CA002224636A patent/CA2224636A1/en not_active Abandoned
- 1996-06-12 EP EP96921990A patent/EP0832163B1/en not_active Expired - Lifetime
- 1996-06-12 WO PCT/EP1996/002576 patent/WO1997000299A1/en active IP Right Grant
- 1996-06-12 JP JP9502646A patent/JPH11507968A/ja active Pending
- 1996-06-14 ZA ZA965077A patent/ZA965077B/xx unknown
- 1996-08-07 TW TW085109592A patent/TW407163B/zh not_active IP Right Cessation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1066275A (zh) *	1991-04-29	1992-11-18	国际壳牌研究有限公司	交联环氧官能聚二烯嵌段聚合物，其制备方法，粘合剂组合物及起始嵌段共聚物
EP0516203A2 (en) *	1991-04-29	1992-12-02	Shell Internationale Researchmaatschappij B.V.	Cross-linked epoxy functionalized polydiene block polymers, process to prepare them, adhesive compositions and starting block copolymer
US5393818A (en) *	1993-04-06	1995-02-28	Shell Oil Company	Solvent-free laminating adhesive composition from epoxidized block polymer

Also Published As

Publication number	Publication date
EP0832163A1 (en)	1998-04-01
JPH11507968A (ja)	1999-07-13
ZA965077B (en)	1997-01-23
EP0832163B1 (en)	1999-03-10
TW407163B (en)	2000-10-01
CA2224636A1 (en)	1997-01-03
WO1997000299A1 (en)	1997-01-03
US5691414A (en)	1997-11-25
BR9608932A (pt)	1999-06-15
DE69601718T2 (de)	1999-08-19
CN1192227A (zh)	1998-09-02
ES2128866T3 (es)	1999-05-16
DE69601718D1 (de)	1999-04-15
MX9710193A (es)	1998-03-31

Legal Events

Date	Code	Title
1998-09-02	C06	Publication
1998-09-02	PB01	Publication
1998-09-16	C10	Entry into substantive examination
1998-09-16	SE01	Entry into force of request for substantive examination
2003-06-25	C14	Grant of patent or utility model
2003-06-25	GR01	Patent grant
2006-08-23	C19	Lapse of patent right due to non-payment of the annual fee
2006-08-23	CF01	Termination of patent right due to non-payment of annual fee

Publication	Publication Date	Title
JP3499932B2 (ja)	2004-02-23	接着剤及びシーラント用異種アームを有する非対称ラジアル又は星形ブロック共重合体
CN1080740C (zh)	2002-03-13	可紫外光固化的组合物
US6541553B1 (en)	2003-04-01	Formulation for strippable adhesive and coating films and high performance adhesive
EP0785971B1 (en)	1999-02-10	Epoxidized monohydroxylated rubber toughening modifiers for epoxy resins
CN1076379C (zh)	2001-12-19	用于压敏胶和密封胶的可固化粘合剂及含该粘合剂的胶粘剂和密封胶
CN1112418C (zh)	2003-06-25	用于由环氧化－羟基二烯聚合物制造可紫外固化粘合剂和密封剂的无溶剂方法
EP0832164B1 (en)	2002-12-11	Non-aqueous solvent free process for making uv curable adhesives and sealants from epoxidized monohydroxylated diene polymers
CN1150245C (zh)	2004-05-19	用芳香酸酐固化剂的改进环氧化二烯聚合物的化学固化
US7163968B2 (en)	2007-01-16	UV curable pressure sensitive adhesives
KR100417344B1 (ko)	2005-02-24	에폭시화모노하이드록실화디엔중합체로부터자외선경화성접착제및봉입제의무-용매제조법
MXPA97010193A (en)	1998-10-15	Solvent-free process for manufacturing adhesives and sealants curable with ultraviolet light apparatus of diohe polymers monohidroxiladosepixida
MXPA97010226A (en)	1998-10-15	Non-aqueous solvent-free process for manufacturing current hesives with ultraviolet light and sealers of monohydroxyled diameter polymers, epoxide