CN111196893A - Functional composite wire based on carbon fiber reinforced nylon and electric heating driving element made of functional composite wire - Google Patents

Functional composite wire based on carbon fiber reinforced nylon and electric heating driving element made of functional composite wire Download PDF

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Publication number
CN111196893A
CN111196893A CN201811372924.9A CN201811372924A CN111196893A CN 111196893 A CN111196893 A CN 111196893A CN 201811372924 A CN201811372924 A CN 201811372924A CN 111196893 A CN111196893 A CN 111196893A
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China
Prior art keywords
carbon fiber
composite wire
functional composite
nylon
fiber reinforced
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CN201811372924.9A
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Chinese (zh)
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CN111196893B (en
Inventor
赵岳
祝颖丹
颜春
张洪生
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Ningbo Institute of Material Technology and Engineering of CAS
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Ningbo Institute of Material Technology and Engineering of CAS
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements

Abstract

The invention discloses a functional composite wire based on carbon fiber reinforced nylon, wherein a wire core of the composite wire is a carbon fiber bundle, and a wire skin is nylon; the composite wire can be used as a material of a driving element, and the carbon fiber exposed out of two ends of the manufactured electrothermal driving element is connected with a power supply, and voltage is applied to the carbon fiber to heat the carbon fiber. When the spring is stretched, a recovered pulling force can be generated under the environment of electric heating driving to drive the mechanical arm or other components/objects to move; when the wire skin needs to be maintained or repaired, the stress applied on the electric heating driving element is unloaded, the voltage applied to the two ends of the carbon fiber bundle is changed, the heating temperature of the carbon fiber bundle is higher than the working temperature, the carbon fiber bundle is maintained for a period of time, and the wire skin can be fused and repaired under the action of electric heating, so that the self-repairing function is realized.

Description

Functional composite wire based on carbon fiber reinforced nylon and electric heating driving element made of functional composite wire
Technical Field
The invention relates to the technical field of composite materials, in particular to a functional composite wire based on carbon fiber reinforced nylon and an electrothermal driving element made of the functional composite wire.
Background
The high functionality of functional materials often comes with high costs. The existing functional materials can not be prepared from an industrial perspective, the preparation cost is high in a laboratory stage, the preparation process is complex, and a series of problems that a plurality of materials are difficult to repair after being damaged severely restrict the application development of the materials. Nylon (polyamide) is a low-cost, easily processable polymer material that has been widely used for its good mechanical properties, and nylon, as a thermoplastic, has good superplasticity. However, nylon is mainly used in the traditional field as a plastic at present, and the functionality of nylon is not widely developed and applied.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art: the functional composite wire based on the carbon fiber reinforced nylon and the electric heating driving element made of the functional composite wire have the advantages of low cost, simple process, excellent performance and suitability for industrial large-scale use.
The technical solution of the invention is as follows: a functional composite wire based on carbon fiber reinforced nylon is characterized in that a wire core of the composite wire is a carbon fiber bundle, and a wire skin is nylon.
Preferably, the diameter of the carbon fiber bundle is as follows: 0.007-0.1 mm.
As an optimization, the thickness of the sheath nylon is as follows: 0.01-1 mm.
Preferably, the preparation method of the functional composite wire based on the carbon fiber reinforced nylon comprises the following step of coating the nylon on the carbon fiber bundle by an extruder at the temperature of 220-300 ℃ for extrusion molding.
The invention also provides an electrothermal driving element made of the functional composite wire based on the carbon fiber reinforced nylon, wherein a single functional composite wire based on the carbon fiber reinforced nylon is wound and molded, then is heated and cooled at 60-200 ℃ for shaping, and the end parts of carbon fiber bundles at two ends of the functional composite wire are used as electrodes.
Preferably, after a single functional composite wire based on carbon fiber reinforced nylon is wound into a spring shape, the functional composite wire is heated and cooled at 60-200 ℃ for shaping, and the ends of the carbon fiber bundles at two ends of the functional composite wire are exposed to be used as input electrodes.
The invention has the beneficial effects that: the composite wire can be used as a material of a driving element, and the carbon fiber exposed out of two ends of the manufactured electrothermal driving element is connected with a power supply, and voltage is applied to the carbon fiber to heat the carbon fiber. When the "spring" is stretched, a restoring pulling force is generated under the environment of electrothermal driving, and the mechanical arm or other components/objects are driven to move. The wire sheath is subject to cumulative mechanical damage, such as microcracks, over time, which can lead to eventual failure of the material. When the wire skin needs to be maintained or repaired, the stress applied on the electric heating driving element is unloaded, the voltage applied to the two ends of the carbon fiber bundle is changed, the heating temperature of the carbon fiber bundle is higher than the working temperature, the carbon fiber bundle is maintained for a period of time, and the wire skin can be fused and repaired under the action of electric heating, so that the self-repairing function is realized. The electric heating driving element can realize self-driving through electric heating and can also be driven through external heating, and the controllability is strong. The carbon fiber not only has the heating function, but also has the reinforcing function;
the electric heating driving element prepared by the invention can be used on the driving of a mechanical arm and other devices needing external force driving, the movement of the connected members is driven by the extension and retraction of the material driven by electric heating, the element can realize self-repair by utilizing the electric heating, is easy to maintain, can provide a driving material with low cost and easy maintenance for industrial mechanical equipment and the like, namely, can generate power under the condition of the electric heating, and can be healed by electric heating when microcracks appear on the wire skin in the material.
Drawings
Fig. 1 is a schematic structural diagram of a functional composite wire based on carbon fiber reinforced nylon according to the present invention.
FIG. 2 is a schematic structural diagram of an electrothermal driving element according to an embodiment of the present invention.
Detailed Description
The present invention will be described in further detail with reference to the following examples, but the present invention is not limited to the following examples.
Examples
Extruding and molding by an extruder at 230-280 ℃, coating nylon with the thickness of 0.5mm on carbon fiber bundles with the diameter of 0.1mm, and exposing carbon fibers at two ends. The extruded material is rapidly cooled in water or other medium to prevent crystallization. And rolling the material for later use.
One or more ends of the material are hung on the free end of the motor rotor, a balance weight of 0.1-3kg is added at the other end of the material, the free end of the motor rotor faces the ground, the balance weight only moves up and down and cannot rotate or translate, the motor is driven to twist the material when running, and the material is twisted into a spring shape along with gradual accumulation of stress.
The material is then heated at 60-200 ℃ to set the shape.
An electric heating driving process: the carbon fiber with two exposed ends of the material is connected with a power supply, and a direct current voltage of 0.1-30V is applied to heat the carbon fiber serving as a heating wire to 60-180 ℃. When the "spring" is stretched, a restoring pulling force is generated under the condition of electric heat, and the mechanical arm or other components/objects are driven to move.
Self-repairing process: when the material needs to be maintained or repaired, the stress applied on the material is unloaded, the voltage applied at two ends of the carbon fiber is changed, the temperature of the carbon fiber is increased to 180-300 ℃ under the direct current voltage of 0.5-50V, and the carbon fiber is maintained for a period of time, and the material is fused and repaired under the action of electric heat, so that the self-repairing function is realized.
The above are merely characteristic embodiments of the present invention, and do not limit the scope of the present invention in any way. All technical solutions formed by equivalent exchanges or equivalent substitutions fall within the protection scope of the present invention.

Claims (6)

1. The utility model provides a function composite wire based on carbon fiber reinforcement nylon which characterized in that: the core of the composite wire is carbon fiber bundle, and the sheath is nylon.
2. The carbon fiber reinforced nylon-based functional composite wire according to claim 1, characterized in that: the diameter of the carbon fiber bundle is as follows: 0.007-0.1 mm.
3. The carbon fiber reinforced nylon-based functional composite wire according to claim 1, characterized in that: the thickness of the sheath nylon is as follows: 0.01-1 mm.
4. The carbon fiber reinforced nylon-based functional composite wire according to claim 1, characterized in that: the preparation method comprises the following steps of coating nylon on the carbon fiber bundle by an extruder at the temperature of 220-300 ℃ and carrying out extrusion molding.
5. An electrothermal actuator element made of the functional composite wire based on carbon fiber reinforced nylon of any one of claims 1 to 4, characterized in that: after being wound and formed, a single functional composite wire based on carbon fiber reinforced nylon is heated, cooled and shaped at the temperature of 60-200 ℃, and the end parts of carbon fiber bundles at two ends of the functional composite wire are used as electrodes.
6. An electrothermal actuator according to claim 5, wherein: after a single functional composite wire based on carbon fiber reinforced nylon is wound into a spring shape, the functional composite wire is heated and cooled at the temperature of 60-200 ℃ for shaping, and the end parts of the carbon fiber bundles at two ends of the functional composite wire are exposed to be used as input electrodes.
CN201811372924.9A 2018-11-19 2018-11-19 Functional composite wire based on carbon fiber reinforced nylon and electric heating driving element made of functional composite wire Active CN111196893B (en)

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CN201811372924.9A CN111196893B (en) 2018-11-19 2018-11-19 Functional composite wire based on carbon fiber reinforced nylon and electric heating driving element made of functional composite wire

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114960217A (en) * 2022-06-27 2022-08-30 浙江理工大学 Preparation method of low-voltage heating film

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CN1544238A (en) * 2003-11-17 2004-11-10 中国航空工业第一集团公司北京航空材 Self-resistance heating forming method for carbon fiber reinforced composite material
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CN103413629A (en) * 2013-08-23 2013-11-27 苏州苏月新材料有限公司 Electric transmission line carbon fiber composite core manufacturing method
CN103438090A (en) * 2013-08-19 2013-12-11 北京航空航天大学 Hinge made of composite material and provided with shape memory function, and preparation method of hinge
CN103770341A (en) * 2014-01-16 2014-05-07 北京航空航天大学 Processing system for carbon fiber reinforced composite material and controllable carbon fiber self-heating method adopting liquid molding technology
CN104358767A (en) * 2014-10-23 2015-02-18 江阴市恒达车辆配件有限公司 Brake cable
CN104428351A (en) * 2012-07-05 2015-03-18 帝人株式会社 Material for molding, molded article produced from said material, and method for producing said molded article
CN105542205A (en) * 2015-12-29 2016-05-04 哈尔滨工业大学 Preparation method of electrically-driven shape memory polyimide
JP2016139496A (en) * 2015-01-27 2016-08-04 有限会社 高城電気製作所 Carbon fiber heating wire
US20170266910A1 (en) * 2016-03-19 2017-09-21 International Business Machines Corporation Shape memory materials with reversible transitions

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4385957A (en) * 1979-07-13 1983-05-31 Messerschmitt-Boelkow-Blohm Gmbh Method for heating a webbing reinforced by carbon fibers
CN1544238A (en) * 2003-11-17 2004-11-10 中国航空工业第一集团公司北京航空材 Self-resistance heating forming method for carbon fiber reinforced composite material
JP2005239806A (en) * 2004-02-25 2005-09-08 Toray Ind Inc Carbon fiber-reinforced thermoplastic resin molding
CN102024518A (en) * 2010-11-01 2011-04-20 山东大学 Composite wire core bar with thermoplastic resin substrate and preparation die and process thereof
US20150191583A1 (en) * 2012-07-05 2015-07-09 Teijin Limited Material for Molding, Shaped Product Therefrom, and Method for Manufacturing Shaped Product
CN104428351A (en) * 2012-07-05 2015-03-18 帝人株式会社 Material for molding, molded article produced from said material, and method for producing said molded article
CN103438090A (en) * 2013-08-19 2013-12-11 北京航空航天大学 Hinge made of composite material and provided with shape memory function, and preparation method of hinge
CN103413629A (en) * 2013-08-23 2013-11-27 苏州苏月新材料有限公司 Electric transmission line carbon fiber composite core manufacturing method
CN103770341A (en) * 2014-01-16 2014-05-07 北京航空航天大学 Processing system for carbon fiber reinforced composite material and controllable carbon fiber self-heating method adopting liquid molding technology
CN104358767A (en) * 2014-10-23 2015-02-18 江阴市恒达车辆配件有限公司 Brake cable
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114960217A (en) * 2022-06-27 2022-08-30 浙江理工大学 Preparation method of low-voltage heating film
CN114960217B (en) * 2022-06-27 2023-09-22 浙江理工大学 Preparation method of low-voltage heating film

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