CN110846147B - Cleaning agent for removing polishing powder on glass surface and preparation method and application thereof - Google Patents
Cleaning agent for removing polishing powder on glass surface and preparation method and application thereof Download PDFInfo
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- CN110846147B CN110846147B CN201911190089.1A CN201911190089A CN110846147B CN 110846147 B CN110846147 B CN 110846147B CN 201911190089 A CN201911190089 A CN 201911190089A CN 110846147 B CN110846147 B CN 110846147B
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- cleaning agent
- polishing powder
- sodium
- glass surface
- sodium dodecyl
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- 239000011521 glass Substances 0.000 title claims abstract description 82
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 68
- 238000005498 polishing Methods 0.000 title claims abstract description 60
- 239000000843 powder Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 239000002562 thickening agent Substances 0.000 claims abstract description 25
- 150000007524 organic acids Chemical class 0.000 claims abstract description 23
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 22
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000004140 cleaning Methods 0.000 claims abstract description 19
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 51
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 41
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 41
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 36
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 23
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 23
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 23
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 18
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 18
- 239000011780 sodium chloride Substances 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 11
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 11
- 235000011152 sodium sulphate Nutrition 0.000 claims description 11
- -1 sodium fatty alcohol Chemical class 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- 230000002411 adverse Effects 0.000 abstract description 5
- 239000003513 alkali Substances 0.000 abstract description 5
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a cleaning agent for removing polishing powder on the surface of glass, a preparation method and application thereof. The cleaning agent comprises 1 to 20 mass percent of organic acid, 0.5 to 5 mass percent of inorganic acid, 0.05 to 0.1 mass percent of anionic surfactant, 0.01 to 0.1 mass percent of nonionic surfactant, 0.01 to 0.1 mass percent of thickening agent and 74.7 to 98.43 mass percent of water. The raw materials are mutually matched to form the cleaning agent, and the cleaning agent can effectively remove polishing powder on the surface of glass, such as cerium dioxide, silicon dioxide, aluminum oxide and other particles. Meanwhile, the cleaning agent is an acidic cleaning agent, when the cleaning agent is used for cleaning the surface of the glass which is not alkali-resistant, the adverse effect on the surface of the glass can not be caused, and the performance of the glass can be ensured in the cleaning process. The preparation method of the cleaning agent is simple and feasible, and is suitable for industrial production.
Description
Technical Field
The invention relates to the technical field of glass cleaning, in particular to a cleaning agent for removing polishing powder on the surface of glass, and a preparation method and application thereof.
Background
In the production process of glass, in order to reduce the roughness of the surface of the glass, it is necessary to perform polishing treatment on the surface of the glass. In the polishing process, the surface of the glass is usually modified by using polishing powder, so that a part of the polishing powder remains on the surface of the glass after polishing. At this time, the polishing powder on the surface of the glass needs to be removed, otherwise, after the glass is assembled on the electronic product, the polishing powder remaining on the surface of the glass can seriously affect the stability and reliability of the electronic product, and even cause the electronic product to fail. The traditional method for cleaning the glass surface polishing powder is to clean the glass surface by using an alkaline cleaning agent, but the removal effect of the glass surface polishing powder by using the alkaline cleaning agent is not good enough. Moreover, when such a cleaning agent is used to clean some glass surfaces that are not alkali resistant, some adverse effects may even be caused on the glass surface.
Disclosure of Invention
Based on the above, it is necessary to provide a cleaning agent for removing glass surface polishing powder, which has a good removal effect on the glass surface polishing powder and is suitable for cleaning a glass surface which is not alkali-resistant.
A cleaning agent for removing glass surface polishing powder comprises the following raw materials in percentage by mass:
in one embodiment, the anionic surfactant is one or more of carboxylate, sulfate, sulfonate and phosphate.
In one embodiment, the anionic surfactant is prepared by mixing sodium dodecyl benzene sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate and sodium dodecyl sulfate.
In one embodiment, the mass ratio of the sodium dodecyl benzene sulfonate, the sodium fatty alcohol polyoxyethylene ether sulfate and the sodium dodecyl sulfate is (50-60): (30-35): (5-20).
In one embodiment, the mass percentage of the organic acid is 5-15%; and/or the presence of a gas in the gas,
the mass percent of the inorganic acid is 1-3%.
In one embodiment, the organic acid is a carboxylic acid.
In one embodiment, the nonionic surfactant is a polyoxyethylene type nonionic surfactant.
In one embodiment, the thickener is an inorganic salt thickener.
A preparation method of a cleaning agent for removing polishing powder on the surface of glass comprises the following steps:
preparing organic acid, inorganic acid, anionic surfactant, nonionic surfactant, thickening agent and water according to the mass percentage in the cleaning agent for removing the glass surface polishing powder in any embodiment;
mixing the organic acid, the inorganic acid, the anionic surfactant, the nonionic surfactant, the thickener, and the water.
The cleaning agent for removing the glass surface polishing powder in any embodiment is applied to cleaning the glass surface polishing powder.
The cleaning agent for removing the glass surface polishing powder comprises, by mass, 1-20% of organic acid, 0.5-5% of inorganic acid, 0.05-0.1% of anionic surfactant, 0.01-0.1% of nonionic surfactant, 0.01-0.1% of thickening agent and 74.7-98.43% of water. The raw materials are mutually matched to form the cleaning agent, the organic acid has good wettability to the polishing powder, the anionic surfactant can reduce the surface tension of the polishing powder in an aqueous solution, and the cleaning agent can effectively remove the polishing powder (such as cerium dioxide, silicon dioxide, aluminum oxide and other particles) on the surface of glass under the combined action of the raw materials. Meanwhile, the cleaning agent is an acidic cleaning agent, when the cleaning agent is used for cleaning the surface of the glass which is not alkali-resistant, the adverse effect on the surface of the glass can not be caused, and the performance of the glass can be ensured in the cleaning process.
The preparation method of the cleaning agent is simple and feasible, and is suitable for industrial production.
Detailed Description
In order that the invention may be more fully understood, reference will now be made to the accompanying examples. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The embodiment of the invention provides a cleaning agent for removing polishing powder on the surface of glass, which comprises the following raw materials in percentage by mass:
in a specific example, the anionic surfactant is one or more of carboxylate, sulfate ester salt, sulfonate and phosphate ester salt.
As a preferable scheme, the anionic surfactant is formed by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate.
Furthermore, the mass ratio of the sodium dodecyl benzene sulfonate, the sodium fatty alcohol polyoxyethylene ether sulfate and the sodium dodecyl sulfate is (50-60): (30-35): 5-20).
In a specific example, the mass percentage of the organic acid is 5% to 15%. The mass percent of the inorganic acid is 1-3%.
Preferably, the organic acid is a carboxylic acid. Specifically, the organic acid is one or more of citric acid, oxalic acid and acetic acid. The inorganic acid is one or more of nitric acid, sulfuric acid, hydrochloric acid and phosphoric acid.
As a preferable mode, the nonionic surfactant is a polyoxyethylene type nonionic surfactant. Further, the nonionic surfactant is nonylphenol polyoxyethylene ether.
In one particular example, the thickener is an inorganic salt thickener. The thickening agent is a cleaning agent which keeps a uniform and stable state. The cleaning agent is an aqueous solution system, and compared with other organic matter thickeners, the inorganic salt thickener can exert a better thickening effect in the aqueous solution system, so that the cleaning agent is more uniform and stable. Preferably, the thickener is sodium chloride.
In a specific example, in order to obtain a cleaning agent with better dispersion effect and better cleaning effect, organic acid, inorganic acid, anionic surfactant, nonionic surfactant and thickening agent are dispersed in deionized water to prepare the cleaning agent for removing polishing powder on the surface of glass.
In the formula of the cleaning agent, the raw materials are mutually matched, so that the cleaning agent can effectively remove polishing powder on the surface of glass, such as cerium dioxide, silicon dioxide, aluminum oxide and other particles. Meanwhile, the cleaning agent is an acidic cleaning agent, when the cleaning agent is used for cleaning the surface of the glass which is not alkali-resistant, the adverse effect on the surface of the glass can not be caused, and the performance of the glass can be ensured in the cleaning process.
The embodiment of the invention also provides a preparation method of the cleaning agent for removing the polishing powder on the surface of the glass, which comprises the following steps:
preparing organic acid, inorganic acid, anionic surfactant, nonionic surfactant, thickener and water according to the mass percentage in the cleaning agent; mixing organic acid, inorganic acid, anionic surfactant, nonionic surfactant, thickener and water.
The embodiment of the invention also provides application of the cleaning agent for removing the glass surface polishing powder in cleaning the glass surface polishing powder. After the glass surface is polished, the glass surface is cleaned by using the cleaning agent, so that residual polishing powder on the glass surface can be effectively removed, the glass surface cannot be adversely affected, and the performance of the glass can be ensured in the cleaning process.
The following are specific examples.
Example 1
In this example, the organic acid is citric acid; the inorganic acid is concentrated sulfuric acid; the anionic surfactant is prepared from sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate according to the mass ratio of 50:30: 20; the nonionic surfactant is nonylphenol polyoxyethylene ether; the thickener is sodium chloride.
The preparation method of the cleaning agent for removing the polishing powder on the glass surface in the embodiment comprises the following steps:
(1) and (5) preparing materials. Taking the following raw materials in percentage by mass: 5% of citric acid, 1% of concentrated sulfuric acid, 0.05% of sodium dodecyl benzene sulfonate, 0.03% of fatty alcohol-polyoxyethylene ether sodium sulfate, 0.02% of sodium dodecyl sulfate, 0.02% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Example 2
In this example, the organic acid is citric acid; the inorganic acid is concentrated sulfuric acid; the anionic surfactant is composed of sodium dodecyl benzene sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate and sodium dodecyl sulfate according to the mass ratio of 55:30: 15; the nonionic surfactant is nonylphenol polyoxyethylene ether; the thickener is sodium chloride.
The preparation method of the cleaning agent for removing the polishing powder on the glass surface in the embodiment comprises the following steps:
(1) and (5) preparing materials. Taking the following raw materials in percentage by mass: 10% of citric acid, 1% of concentrated sulfuric acid, 0.055% of sodium dodecyl benzene sulfonate, 0.03% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.015% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Example 3
In this example, the organic acid is citric acid; the inorganic acid is concentrated sulfuric acid; the anionic surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate according to a mass ratio of 60:35: 5; the nonionic surfactant is nonylphenol polyoxyethylene ether; the thickener is sodium chloride.
The preparation method of the cleaning agent for removing the polishing powder on the glass surface in the embodiment comprises the following steps:
(1) and (5) preparing materials. Taking the following raw materials in percentage by mass: 10% of citric acid, 3% of concentrated sulfuric acid, 0.06% of sodium dodecyl benzene sulfonate, 0.035% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.005% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Example 4
In this example, the organic acid is citric acid; the inorganic acid is concentrated sulfuric acid; the anionic surfactant is prepared from sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate according to the mass ratio of 50:35: 15; the nonionic surfactant is nonylphenol polyoxyethylene ether; the thickener is sodium chloride.
The preparation method of the cleaning agent for removing the polishing powder on the glass surface in the embodiment comprises the following steps:
(1) and (5) preparing materials. Taking the following raw materials in percentage by mass: 10% of citric acid, 3% of concentrated sulfuric acid, 0.05% of sodium dodecyl benzene sulfonate, 0.035% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.015% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Example 5
In this example, the organic acid is citric acid; the inorganic acid is concentrated sulfuric acid; the anionic surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate in a mass ratio of 30:30: 40; the nonionic surfactant is nonylphenol polyoxyethylene ether; the thickener is sodium chloride.
The preparation method of the cleaning agent for removing the polishing powder on the glass surface in the embodiment comprises the following steps:
(1) and (5) preparing materials. Taking the following raw materials in percentage by mass: 10% of citric acid, 3% of concentrated sulfuric acid, 0.03% of sodium dodecyl benzene sulfonate, 0.03% of fatty alcohol-polyoxyethylene ether sodium sulfate, 0.04% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Example 6
In this example, the organic acid is citric acid; the inorganic acid is concentrated sulfuric acid; the anionic surfactant is prepared by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate according to a mass ratio of 20:40: 40; the nonionic surfactant is nonylphenol polyoxyethylene ether; the thickener is sodium chloride.
The preparation method of the cleaning agent for removing the polishing powder on the glass surface in the embodiment comprises the following steps:
(1) and (5) preparing materials. Taking the following raw materials in percentage by mass: 10% of citric acid, 3% of concentrated sulfuric acid, 0.02% of sodium dodecyl benzene sulfonate, 0.04% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.04% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Comparative example 1
(1) And (5) preparing materials. Taking the following raw materials in percentage by mass: 10% of sodium hydroxide, 5% of sodium carbonate, 5% of sodium phosphate, 0.05% of sodium dodecyl benzene sulfonate, 0.03% of fatty alcohol-polyoxyethylene ether sodium sulfate, 0.02% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
(2) And (4) mixing. And (3) uniformly mixing the raw materials in the step (1) to obtain the cleaning agent for removing the glass surface polishing powder in the embodiment.
Test example 1
The cleaning agents of examples 1 to 6 and comparative example 1 were subjected to cleaning effect test.
The test method comprises the following steps: 7 groups of glass which is polished by the polishing powder and produced in the same batch are taken as test objects, each group comprises 200 pieces of glass, and the 7 groups of glass respectively correspond to the cleaning agents in the examples 1-6 and the comparative example 1. The cleaning agents in the examples 1 to 6 and the comparative example 1 were used to clean the corresponding groups of glasses by the same cleaning method, and the residual polishing powder on the glass surface was manually checked after cleaning. And (4) inspecting the glass below the desk lamp after cleaning, marking that no polishing powder residue exists on the surface of the glass as qualified, and marking that polishing powder residue exists on the surface of the glass after cleaning as unqualified. The specific test results are shown in the following table.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. The cleaning agent for removing the glass surface polishing powder is characterized in that: the material is prepared from the following raw materials in percentage by mass:
the anionic surfactant is formed by mixing sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate and sodium dodecyl sulfate;
the mass ratio of the sodium dodecyl benzene sulfonate to the sodium fatty alcohol polyoxyethylene ether sulfate to the sodium dodecyl sulfate is (50-60): 30-35): 5-20);
the nonionic surfactant is a polyoxyethylene nonionic surfactant.
2. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the mass percentage of the organic acid is 5-15%; and/or the presence of a gas in the gas,
the mass percent of the inorganic acid is 1-3%.
3. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the organic acid is a carboxylic acid.
4. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the thickening agent is an inorganic salt thickening agent.
5. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the material is prepared from the following raw materials in percentage by mass: 5% of citric acid, 1% of concentrated sulfuric acid, 0.05% of sodium dodecyl benzene sulfonate, 0.03% of fatty alcohol-polyoxyethylene ether sodium sulfate, 0.02% of sodium dodecyl sulfate, 0.02% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
6. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the material is prepared from the following raw materials in percentage by mass: 10% of citric acid, 1% of concentrated sulfuric acid, 0.055% of sodium dodecyl benzene sulfonate, 0.03% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.015% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
7. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the material is prepared from the following raw materials in percentage by mass: 10% of citric acid, 3% of concentrated sulfuric acid, 0.06% of sodium dodecyl benzene sulfonate, 0.035% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.005% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
8. The cleaning agent for removing polishing powder from a glass surface according to claim 1, wherein: the material is prepared from the following raw materials in percentage by mass: 10% of citric acid, 3% of concentrated sulfuric acid, 0.05% of sodium dodecyl benzene sulfonate, 0.035% of sodium fatty alcohol-polyoxyethylene ether sulfate, 0.015% of sodium dodecyl sulfate, 0.05% of nonylphenol polyoxyethylene ether, 0.01% of sodium chloride and the balance of deionized water.
9. A preparation method of a cleaning agent for removing polishing powder on the surface of glass is characterized by comprising the following steps: the method comprises the following steps:
preparing organic acid, inorganic acid, anionic surfactant, nonionic surfactant, thickener and water according to the mass percentage in the cleaning agent for removing glass surface polishing powder of any one of claims 1 to 8;
mixing the organic acid, the inorganic acid, the anionic surfactant, the nonionic surfactant, the thickener, and the water.
10. Use of the cleaning agent for removing glass surface polishing powder according to any one of claims 1 to 8 for cleaning glass surface polishing powder.
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| CN112625808B (en) * | 2020-12-29 | 2022-08-16 | 万津实业(赤壁)有限公司 | Acidic cleaning agent and preparation method and application thereof |
| CN112812900B (en) * | 2020-12-29 | 2022-05-27 | 万津实业(赤壁)有限公司 | Foamless acidic cleaning agent and preparation method and application thereof |
| CN114181788A (en) * | 2021-11-25 | 2022-03-15 | 万津实业(赤壁)有限公司 | Glass cleaning agent and preparation method and application thereof |
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