CN110644704B - 一种石塑pvc马赛克板及其制备方法 - Google Patents

一种石塑pvc马赛克板及其制备方法 Download PDF

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CN110644704B
CN110644704B CN201911178909.5A CN201911178909A CN110644704B CN 110644704 B CN110644704 B CN 110644704B CN 201911178909 A CN201911178909 A CN 201911178909A CN 110644704 B CN110644704 B CN 110644704B
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layer
parts
stone
mosaic
mixture
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CN110644704A (zh
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胡元军
李龙建
胡先权
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Zhejiang Ruiteng new building materials Co., Ltd
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Abstract

本发明公开了一种石塑PVC马赛克板及其制备方法，包括底料层、石塑层、玻璃荧光层、仿石层、印刷层和耐磨层，底料层的顶端设有石塑层，石塑层的顶端交替设有若干个玻璃荧光层和仿石层，玻璃荧光层和仿石层的顶端均设有底漆保护层，底漆保护层的顶端上热压有印刷层，印刷层的顶端上热压有耐磨层，该马赛克板采用石塑PVC材料制成，并在石塑PVC材料上设有玻璃荧光层和仿石层，玻璃荧光层和仿石层交叉设置，仿石层为马赛克形状，玻璃荧光层可以在白天吸光晚上发光，增加美观，而石塑PVC材料采用的是天然石粉，是绿色环保材料，弹性好，具有很强的抗冲击性，还具有防火阻燃、防水防潮、吸音防噪和抗菌杀菌的性能。

Description

一种石塑PVC马赛克板及其制备方法
技术领域
本发明涉及马赛克板领域，具体为一种石塑PVC马赛克板及其制备方法。
背景技术
马赛克是在建筑上用于拼成各种装饰图案用的片状小瓷砖。坯料经半干压成形，窑内焙烧成锦砖。泥料中有时用氧化钙、Fe2O3等作为着色剂。主要用于铺地或内墙装饰，也可用于外墙饰面。马赛克的种类多，应用也十分广泛，也常常把小小的马赛克粘接在基层板上，形成马赛克板，马赛克板的应用也十分广泛，很多地面或墙面铺设马赛克，由于马赛克的体积较小，铺设难度大，效率低，采用马赛克板可以提高效率，节约时间，而且增加马赛克之间连接的美观性。
传统的马赛克板都是把小的马赛克粘接在板材上，从而形成马赛克板，但是这种的马赛克板，稳定性能差，马赛克容易脱落，而且马赛克粘接难度大，粘接形状不美观，市场上大多的马赛克板都是采用玻璃马赛克或陶瓷马赛克，不能把陶瓷和玻璃有机的结合到马赛克板上，从而提高马赛克板的整体性能，而现有的玻璃马赛克板只能通过玻璃的作用，对照射的光进行处理后反射出去，而不能白天对光进行吸收，晚上即使不用光照也能发光，从而增加美观，陶瓷马赛克板质量比较大，重力比较重，美观性差。
发明内容
本发明的目的是针对现有技术的缺陷，提供一种石塑PVC马赛克板及其制备方法，以解决上述背景技术提出的问题。
为实现上述目的，本发明提供如下技术方案：一种石塑PVC马赛克板，包括底料层、石塑层、玻璃荧光层、仿石层、印刷层和耐磨层，所述底料层的顶端设有所述石塑层，所述石塑层的顶端交替设有若干个所述玻璃荧光层和所述仿石层，所述玻璃荧光层和所述仿石层的顶端均设有底漆保护层，所述底漆保护层的顶端上热压有印刷层，所述印刷层的顶端上热压有所述耐磨层。
作为本发明的一种优选技术方案，所述底料层与所述石塑层为叠加结构，所述石塑层和所述底漆保护层均与所述玻璃荧光层和所述仿石层为叠加结构，所述底漆保护层、所述印刷层和所述耐磨层为叠加结构。
作为本发明的一种优选技术方案，所述石塑层包括如下重量份数的组分：PVC65-70份，石粉60-120份，助剂15-25份，其中助剂包括钙锌稳定剂4-10份，聚乙二醇二硬脂酸酯1-3份，PE蜡1-3份，氯化聚乙烯5-10份，ACR抗冲改性剂3-6份。
作为本发明的一种优选技术方案，所述底料层包括如下重量份数的组分：硅酸盐40-55份、粘土20-35份、石英15-20份、氟化物5-10份、抗菌剂10-15份、菱镁矿3-5份、滑石1-5份、无水硼砂1-5份、叶蜡石1-5份、锂辉石1-5份和绿柱石1-5份，其中抗菌剂为纳米银抗菌剂。
作为本发明的一种优选技术方案，所述玻璃荧光层包括如下重量份数的组分：荧光粉60-70份、石英砂50-55份、硼砂20-25份、硼酸10-20份、重晶石1-10份、碳酸钡1-10份、石灰石1-10份、长石1-10份和纯碱1-10份。
作为本发明的一种优选技术方案，所述仿石层包括如下重量份数的组分：云母片1-5份、二氧化锆3-5份、氧化钙2-5份、三氧化二铬3-5份、氧化钠1-4份、氧化镁1-4份、三氧化二铝4-7份、二氧化硅40-45份和三氧化二铁4-7份。
作为本发明的一种优选技术方案，所述底漆保护层为马赛克印刷粘接剂，所述耐磨层为釉层，所述耐磨层包括如下重量份数的组分：长石20-25份、石英20-25份、滑石20-25份和高岭土20-25份。
一种石塑PVC马赛克板的制备方法，具体步骤如下；
步骤一：底料层的制作，将硅酸盐、粘土、石英、氟化物、抗菌剂、菱镁矿、滑石、无水硼砂、叶蜡石、锂辉石和绿柱石按照比例称取，然后通过混合、粉碎、球磨和干燥得到底料层的混合物粉料，然后把混合物粉料放入自动压机进行底料胚模的制作，底料胚模的厚度、长和宽均可以根据需要定制，得到的底料胚模待用；
步骤二：石塑层的制作，将PVC，石粉，钙锌稳定剂，聚乙二醇二硬脂酸酯，PE蜡，氯化聚乙烯和ACR抗冲改性剂按照比例称取，然后通过混合、粉碎、球磨和干燥得到石塑层的混合物，然后通过模具把混合物浇注在步骤一所得到的底料胚模顶部上，然后通过烘干得到石塑层和底料层的叠加物；
步骤三：玻璃荧光层的制作，将荧光粉、石英砂、硼砂、硼酸、重晶石、碳酸钡、石灰石、长石和纯碱原料进行干燥，并将含铁原料进行除铁处理得到玻璃荧光层混合物，然后将混合物放入到坩埚窑内，进行高温加热，温度为550-1600度，使之形成均匀、无气泡，得到具有荧光粉的液态玻璃；
步骤四：仿石层的制作，将云母片、二氧化锆、氧化钙、三氧化二铬、氧化钠、氧化镁、三氧化二铝、二氧化硅和三氧化二铁按照比例称取，然后通过混合、粉碎、球磨和干燥得到仿石层的混合物粉料；
步骤五：将步骤三中的液态玻璃和步骤四中的仿石层混合物粉料分别浇注到步骤二中的叠加物顶部的模具上，通过压制冷却，让液态玻璃和仿石层混合物粉料均与步骤二中的叠加物连接；
步骤六：冷却后，在仿石层和玻璃荧光层的顶部上喷涂马赛克印刷粘接剂，然后利用马赛克印刷机进行印刷，再进行上釉处理，然后进行烧结，表面处理，得到石塑PVC马赛克板。
本发明的有益效果是：该马赛克板采用石塑PVC材料制成，并在石塑PVC材料上设有玻璃荧光层和仿石层，玻璃荧光层和仿石层交叉设置，仿石层为马赛克形状，玻璃荧光层可以在白天吸光晚上发光，增加美观，而石塑PVC材料采用的是天然石粉，是绿色环保材料，弹性好，具有很强的抗冲击性，还具有防火阻燃、防水防潮、吸音防噪和抗菌杀菌的性能，石塑PVC材料与底料结合，提高整体的稳定性能，提高马赛克板的硬度，而且玻璃荧光层和仿石层均与石塑层融为一体，不会出现玻璃荧光层和仿石层脱落的现象，该马赛克板上的马赛克产品纹路逼真美观、超强耐磨，表面光亮而不滑，而且环保无毒、耐刮擦，防水、防火，遇水不变形，止滑性强，可消除老人、儿童的忧虑，而且坚韧有弹性，安全性高，阻燃，耐腐蚀，耐酸碱，使用寿命高。
附图说明
图1为本发明马赛克板的剖视图；
图2为本发明马赛克板的立体结构示意图；
图3为本发明马赛克板的局部结构示意图之一；
图4为本发明马赛克板的局部结构示意图之二；
图中：1、底料层，2、石塑层，3、玻璃荧光层，4、仿石层，5、印刷层，6、耐磨层，7、底漆保护层。
具体实施方式
下面结合附图对本发明的较佳实施例进行详细阐述，以使本发明的优点和特征能更易被本领域人员理解，从而对本发明的保护范围做出更为清楚明确的界定。
请参阅图1-4，本发明提供一种技术方案：一种石塑PVC马赛克板，包括底料层1、石塑层2、玻璃荧光层3、仿石层4、印刷层5和耐磨层6，底料层1的顶端设有石塑层2，石塑层2的顶端交替设有若干个玻璃荧光层3和仿石层4，玻璃荧光层3和仿石层4的顶端均设有底漆保护层7，底漆保护层7的顶端上热压有印刷层5，印刷层5的顶端上热压有耐磨层6。
底料层1与石塑层2为叠加结构，石塑层2和底漆保护层7均与玻璃荧光层3和仿石层4为叠加结构，底漆保护层7、印刷层5和耐磨层6为叠加结构。
石塑层2包括如下重量份数的组分：PVC65-70份，石粉60-120份，助剂15-25份，其中助剂包括钙锌稳定剂4-10份，聚乙二醇二硬脂酸酯1-3份，PE蜡1-3份，氯化聚乙烯5-10份，ACR抗冲改性剂3-6份；底料层1包括如下重量份数的组分：硅酸盐40-55份、粘土20-35份、石英15-20份、氟化物5-10份、抗菌剂10-15份、菱镁矿3-5份、滑石1-5份、无水硼砂1-5份、叶蜡石1-5份、锂辉石1-5份和绿柱石1-5份，其中抗菌剂为纳米银抗菌剂；玻璃荧光层3包括如下重量份数的组分：荧光粉60-70份、石英砂50-55份、硼砂20-25份、硼酸10-20份、重晶石1-10份、碳酸钡1-10份、石灰石1-10份、长石1-10份和纯碱1-10份；仿石层4包括如下重量份数的组分：云母片1-5份、二氧化锆3-5份、氧化钙2-5份、三氧化二铬3-5份、氧化钠1-4份、氧化镁1-4份、三氧化二铝4-7份、二氧化硅40-45份和三氧化二铁4-7份；底漆保护层7为马赛克印刷粘接剂，耐磨层6为釉层，耐磨层6包括如下重量份数的组分：长石20-25份、石英20-25份、滑石20-25份和高岭土20-25份。
一种石塑PVC马赛克板的制备方法，具体步骤如下；
步骤一：底料层的制作，将硅酸盐、粘土、石英、氟化物、抗菌剂、菱镁矿、滑石、无水硼砂、叶蜡石、锂辉石和绿柱石按照比例称取，然后通过混合、粉碎、球磨和干燥得到底料层的混合物粉料，然后把混合物粉料放入自动压机进行底料胚模的制作，底料胚模的厚度、长和宽均可以根据需要定制，得到的底料胚模待用；
步骤二：石塑层的制作，将PVC，石粉，钙锌稳定剂，聚乙二醇二硬脂酸酯，PE蜡，氯化聚乙烯和ACR抗冲改性剂按照比例称取，然后通过混合、粉碎、球磨和干燥得到石塑层的混合物，然后通过模具把混合物浇注在步骤一所得到的底料胚模顶部上，然后通过烘干得到石塑层和底料层的叠加物；
步骤三：玻璃荧光层的制作，将荧光粉、石英砂、硼砂、硼酸、重晶石、碳酸钡、石灰石、长石和纯碱原料进行干燥，并将含铁原料进行除铁处理得到玻璃荧光层混合物，然后将混合物放入到坩埚窑内，进行高温加热，温度为550-1600度，使之形成均匀、无气泡，得到具有荧光粉的液态玻璃；
步骤四：仿石层的制作，将云母片、二氧化锆、氧化钙、三氧化二铬、氧化钠、氧化镁、三氧化二铝、二氧化硅和三氧化二铁按照比例称取，然后通过混合、粉碎、球磨和干燥得到仿石层的混合物粉料；
步骤五：将步骤三中的液态玻璃和步骤四中的仿石层混合物粉料分别浇注到步骤二中的叠加物顶部的模具上，通过压制冷却，让液态玻璃和仿石层混合物粉料均与步骤二中的叠加物连接；
步骤六：冷却后，在仿石层和玻璃荧光层的顶部上喷涂马赛克印刷粘接剂，然后利用马赛克印刷机进行印刷，再进行上釉处理，然后进行烧结，表面处理，得到石塑PVC马赛克板。
实施例1
原料配方：
石塑层：PVC65份，石粉60份，钙锌稳定剂4份，聚乙二醇二硬脂酸酯1份，PE蜡1份，氯化聚乙烯5份，ACR抗冲改性剂3份；
底料层：硅酸盐40份、粘土20份、石英15份、氟化物5份、抗菌剂10份、菱镁矿3份、滑石1份、无水硼砂1份、叶蜡石1份、锂辉石1份和绿柱石1份，
玻璃荧光层：荧光粉60份、石英砂50份、硼砂20份、硼酸10份、重晶石1份、碳酸钡1份、石灰石1份、长石1份和纯碱1份；
仿石层：云母片1份、二氧化锆3份、氧化钙2份、三氧化二铬3份、氧化钠1份、氧化镁1份、三氧化二铝4份、二氧化硅40份和三氧化二铁4份；
耐磨层：长石20份、石英20份、滑石20份和高岭土20份；
具体步骤如下：
步骤一：底料层的制作，将硅酸盐、粘土、石英、氟化物、抗菌剂、菱镁矿、滑石、无水硼砂、叶蜡石、锂辉石和绿柱石按照比例称取，然后通过混合、粉碎、球磨和干燥得到底料层的混合物粉料，然后把混合物粉料放入自动压机进行底料胚模的制作，底料胚模的厚度、长和宽均可以根据需要定制，得到的底料胚模待用；
步骤二：石塑层的制作，将PVC，石粉，钙锌稳定剂，聚乙二醇二硬脂酸酯，PE蜡，氯化聚乙烯和ACR抗冲改性剂按照比例称取，然后通过混合、粉碎、球磨和干燥得到石塑层的混合物，然后通过模具把混合物浇注在步骤一所得到的底料胚模顶部上，然后通过烘干得到石塑层和底料层的叠加物；
步骤三：玻璃荧光层的制作，将荧光粉、石英砂、硼砂、硼酸、重晶石、碳酸钡、石灰石、长石和纯碱原料进行干燥，并将含铁原料进行除铁处理得到玻璃荧光层混合物，然后将混合物放入到坩埚窑内，进行高温加热，温度为550-1600度，使之形成均匀、无气泡，得到具有荧光粉的液态玻璃；
步骤四：仿石层的制作，将云母片、二氧化锆、氧化钙、三氧化二铬、氧化钠、氧化镁、三氧化二铝、二氧化硅和三氧化二铁按照比例称取，然后通过混合、粉碎、球磨和干燥得到仿石层的混合物粉料；
步骤五：将步骤三中的液态玻璃和步骤四中的仿石层混合物粉料分别浇注到步骤二中的叠加物顶部的模具上，通过压制冷却，让液态玻璃和仿石层混合物粉料均与步骤二中的叠加物连接；
步骤六：冷却后，在仿石层和玻璃荧光层的顶部上喷涂马赛克印刷粘接剂，然后利用马赛克印刷机进行印刷，再进行上釉处理，然后进行烧结，表面处理，得到石塑PVC马赛克板。
实施例2
原料配方：
石塑层：PVC68份，石粉100份，钙锌稳定剂6份，聚乙二醇二硬脂酸酯2份，PE蜡2份，氯化聚乙烯7份，ACR抗冲改性剂4份；
底料层：硅酸盐50份、粘土30份、石英18份、氟化物8份、抗菌剂12份、菱镁矿4份、滑石3份、无水硼砂3份、叶蜡石3份、锂辉石3份和绿柱石3份，
玻璃荧光层：荧光粉65份、石英砂52份、硼砂22份、硼酸15份、重晶石5份、碳酸钡5份、石灰石5份、长石5份和纯碱5份；
仿石层：云母片3份、二氧化锆4份、氧化钙3份、三氧化二铬4份、氧化钠3份、氧化镁3份、三氧化二铝5份、二氧化硅43份和三氧化二铁5份；
耐磨层：长石22份、石英22份、滑石22份和高岭土22份；
具体步骤如下：
步骤一：底料层的制作，将硅酸盐、粘土、石英、氟化物、抗菌剂、菱镁矿、滑石、无水硼砂、叶蜡石、锂辉石和绿柱石按照比例称取，然后通过混合、粉碎、球磨和干燥得到底料层的混合物粉料，然后把混合物粉料放入自动压机进行底料胚模的制作，底料胚模的厚度、长和宽均可以根据需要定制，得到的底料胚模待用；
步骤二：石塑层的制作，将PVC，石粉，钙锌稳定剂，聚乙二醇二硬脂酸酯，PE蜡，氯化聚乙烯和ACR抗冲改性剂按照比例称取，然后通过混合、粉碎、球磨和干燥得到石塑层的混合物，然后通过模具把混合物浇注在步骤一所得到的底料胚模顶部上，然后通过烘干得到石塑层和底料层的叠加物；
步骤三：玻璃荧光层的制作，将荧光粉、石英砂、硼砂、硼酸、重晶石、碳酸钡、石灰石、长石和纯碱原料进行干燥，并将含铁原料进行除铁处理得到玻璃荧光层混合物，然后将混合物放入到坩埚窑内，进行高温加热，温度为550-1600度，使之形成均匀、无气泡，得到具有荧光粉的液态玻璃；
步骤四：仿石层的制作，将云母片、二氧化锆、氧化钙、三氧化二铬、氧化钠、氧化镁、三氧化二铝、二氧化硅和三氧化二铁按照比例称取，然后通过混合、粉碎、球磨和干燥得到仿石层的混合物粉料；
步骤五：将步骤三中的液态玻璃和步骤四中的仿石层混合物粉料分别浇注到步骤二中的叠加物顶部的模具上，通过压制冷却，让液态玻璃和仿石层混合物粉料均与步骤二中的叠加物连接；
步骤六：冷却后，在仿石层和玻璃荧光层的顶部上喷涂马赛克印刷粘接剂，然后利用马赛克印刷机进行印刷，再进行上釉处理，然后进行烧结，表面处理，得到石塑PVC马赛克板。
实施例3
原料配方：
石塑层：PVC70份，石粉120份，钙锌稳定剂10份，聚乙二醇二硬脂酸酯3份，PE蜡3份，氯化聚乙烯10份，ACR抗冲改性剂6份；
底料层：硅酸盐55份、粘土35份、石英20份、氟化物10份、抗菌剂15份、菱镁矿5份、滑石5份、无水硼砂5份、叶蜡石5份、锂辉石5份和绿柱石5份，
玻璃荧光层：荧光粉70份、石英砂55份、硼砂25份、硼酸20份、重晶石10份、碳酸钡10份、石灰石10份、长石10份和纯碱10份；
仿石层：云母片5份、二氧化锆5份、氧化钙5份、三氧化二铬5份、氧化钠4份、氧化镁4份、三氧化二铝7份、二氧化硅45份和三氧化二铁7份；
耐磨层：长石25份、石英25份、滑石25份和高岭土25份；
具体步骤如下：
步骤一：底料层的制作，将硅酸盐、粘土、石英、氟化物、抗菌剂、菱镁矿、滑石、无水硼砂、叶蜡石、锂辉石和绿柱石按照比例称取，然后通过混合、粉碎、球磨和干燥得到底料层的混合物粉料，然后把混合物粉料放入自动压机进行底料胚模的制作，底料胚模的厚度、长和宽均可以根据需要定制，得到的底料胚模待用；
步骤二：石塑层的制作，将PVC，石粉，钙锌稳定剂，聚乙二醇二硬脂酸酯，PE蜡，氯化聚乙烯和ACR抗冲改性剂按照比例称取，然后通过混合、粉碎、球磨和干燥得到石塑层的混合物，然后通过模具把混合物浇注在步骤一所得到的底料胚模顶部上，然后通过烘干得到石塑层和底料层的叠加物；
步骤三：玻璃荧光层的制作，将荧光粉、石英砂、硼砂、硼酸、重晶石、碳酸钡、石灰石、长石和纯碱原料进行干燥，并将含铁原料进行除铁处理得到玻璃荧光层混合物，然后将混合物放入到坩埚窑内，进行高温加热，温度为550-1600度，使之形成均匀、无气泡，得到具有荧光粉的液态玻璃；
步骤四：仿石层的制作，将云母片、二氧化锆、氧化钙、三氧化二铬、氧化钠、氧化镁、三氧化二铝、二氧化硅和三氧化二铁按照比例称取，然后通过混合、粉碎、球磨和干燥得到仿石层的混合物粉料；
步骤五：将步骤三中的液态玻璃和步骤四中的仿石层混合物粉料分别浇注到步骤二中的叠加物顶部的模具上，通过压制冷却，让液态玻璃和仿石层混合物粉料均与步骤二中的叠加物连接；
步骤六：冷却后，在仿石层和玻璃荧光层的顶部上喷涂马赛克印刷粘接剂，然后利用马赛克印刷机进行印刷，再进行上釉处理，然后进行烧结，表面处理，得到石塑PVC马赛克板。
实验：根据国家 GB 7697-1987《玻璃马赛克》和JCT 456-2015 《陶瓷马赛克》及相关标准，对本发明的石塑PVC马赛克板进行产品质量检测，抽样方案按照 GB 7697-1987和JCT 456-2015 的规定，在实施例1-3制成的每100块马赛克板中采用随机取抽样的方法进行抽取10块马赛克板，检测结果如下 ：
实施例1-3的与对照组实验检测表格；对照组为普通马赛克板10块；
试验组 光泽度 裂纹及变形 吸水率% 断裂模数MPa 抗热性 耐酸碱性 抗冻性 抗弯曲性能N 耐磨性
实施例1 优 无裂纹和变形 6 66 优 优 优 1690 优
实施例2 优 无裂纹和变形 4.5 68 优 优 优 1650 优
实施例3 优 无裂纹和变形 5.4 68 优 优 优 1680 优
对照组 合格 有裂纹，有变形 8.6 50 合格 合格 合格 1360 合格
该马赛克板采用石塑PVC材料制成，并在石塑PVC材料上设有玻璃荧光层和仿石层，玻璃荧光层和仿石层交叉设置，仿石层为马赛克形状，玻璃荧光层可以在白天吸光晚上发光，增加美观，而石塑PVC材料采用的是天然石粉，是绿色环保材料，弹性好，具有很强的抗冲击性，还具有防火阻燃、防水防潮、吸音防噪和抗菌杀菌的性能，石塑PVC材料与底料结合，提高整体的稳定性能，提高马赛克板的硬度，而且玻璃荧光层和仿石层均与石塑层融为一体，不会出现玻璃荧光层和仿石层脱落的现象，该马赛克板上的马赛克产品纹路逼真美观、超强耐磨，表面光亮而不滑，而且环保无毒、耐刮擦，防水、防火，遇水不变形，止滑性强，可消除老人、儿童的忧虑，而且坚韧有弹性，安全性高，阻燃，耐腐蚀，耐酸碱，使用寿命高。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护。

Claims (1)

1.一种石塑PVC马赛克板，包括底料层(1)、石塑层(2)、玻璃荧光层(3)、仿石层(4)、印刷层(5)和耐磨层(6)，其特征在于，所述底料层(1)的顶端设有所述石塑层(2)，所述石塑层(2)的顶端交替设有若干个所述玻璃荧光层(3)和所述仿石层(4)，所述玻璃荧光层(3)和所述仿石层(4)的顶端均设有底漆保护层(7)，所述底漆保护层(7)的顶端上热压有印刷层(5)，所述印刷层(5)的顶端上热压有所述耐磨层(6)，所述底料层(1)与所述石塑层(2)为叠加结构，所述石塑层(2)和所述底漆保护层(7)均与所述玻璃荧光层(3)和所述仿石层(4)为叠加结构，所述底漆保护层(7)、所述印刷层(5)和所述耐磨层(6)为叠加结构，所述石塑层(2)包括如下重量份数的组分：PVC65-70份，石粉60-120份，助剂15-25份，其中助剂包括钙锌稳定剂4-10份，聚乙二醇二硬脂酸酯1-3份，PE蜡1-3份，氯化聚乙烯5-10份，ACR抗冲改性剂3-6份，所述底料层(1)包括如下重量份数的组分：硅酸盐40-55份、粘土20-35份、石英15-20份、氟化物5-10份、抗菌剂10-15份、菱镁矿3-5份、滑石1-5份、无水硼砂1-5份、叶蜡石1-5份、锂辉石1-5份和绿柱石1-5份，其中抗菌剂为纳米银抗菌剂，所述玻璃荧光层(3)包括如下重量份数的组分：荧光粉60-70份、石英砂50-55份、硼砂20-25份、硼酸10-20份、重晶石1-10份、碳酸钡1-10份、石灰石1-10份、长石1-10份和纯碱1-10份，所述仿石层(4)包括如下重量份数的组分：云母片1-5份、二氧化锆3-5份、氧化钙2-5份、三氧化二铬3-5份、氧化钠1-4份、氧化镁1-4份、三氧化二铝4-7份、二氧化硅40-45份和三氧化二铁4-7份，所述底漆保护层(7)为马赛克印刷粘接剂，所述耐磨层(6)为釉层，所述耐磨层(6)包括如下重量份数的组分：长石20-25份、石英20-25份、滑石20-25份和高岭土20-25份；
具体步骤如下：
步骤一：底料层的制作，将硅酸盐、粘土、石英、氟化物、抗菌剂、菱镁矿、滑石、无水硼砂、叶蜡石、锂辉石和绿柱石按照比例称取，然后通过混合、粉碎、球磨和干燥得到底料层的混合物粉料，然后把混合物粉料放入自动压机进行底料胚模的制作，底料胚模的厚度、长和宽均可以根据需要定制，得到的底料胚模待用；
步骤二：石塑层的制作，将PVC，石粉，钙锌稳定剂，聚乙二醇二硬脂酸酯，PE蜡，氯化聚乙烯和ACR抗冲改性剂按照比例称取，然后通过混合、粉碎、球磨和干燥得到石塑层的混合物，然后通过模具把混合物浇注在步骤一所得到的底料胚模顶部上，然后通过烘干得到石塑层和底料层的叠加物；
步骤三：玻璃荧光层的制作，将荧光粉、石英砂、硼砂、硼酸、重晶石、碳酸钡、石灰石、长石和纯碱原料进行干燥，并将含铁原料进行除铁处理得到玻璃荧光层混合物，然后将混合物放入到坩埚窑内，进行高温加热，温度为550-1600度，使之形成均匀、无气泡，得到具有荧光粉的液态玻璃；
步骤四：仿石层的制作，将云母片、二氧化锆、氧化钙、三氧化二铬、氧化钠、氧化镁、三氧化二铝、二氧化硅和三氧化二铁按照比例称取，然后通过混合、粉碎、球磨和干燥得到仿石层的混合物粉料；
步骤五：将步骤三中的液态玻璃和步骤四中的仿石层混合物粉料分别浇注到步骤二中的叠加物顶部的模具上，通过压制冷却，让液态玻璃和仿石层混合物粉料均与步骤二中的叠加物连接；
步骤六：冷却后，在仿石层和玻璃荧光层的顶部上喷涂马赛克印刷粘接剂，然后利用马赛克印刷机进行印刷，再进行上釉处理，然后进行烧结，表面处理，得到石塑PVC马赛克板。
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