CN110573601A - 用于地板清洁或复原的组合物和方法 - Google Patents
用于地板清洁或复原的组合物和方法 Download PDFInfo
- Publication number
- CN110573601A CN110573601A CN201880028439.1A CN201880028439A CN110573601A CN 110573601 A CN110573601 A CN 110573601A CN 201880028439 A CN201880028439 A CN 201880028439A CN 110573601 A CN110573601 A CN 110573601A
- Authority
- CN
- China
- Prior art keywords
- composition
- floor
- weight percent
- fatty alcohol
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 172
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000004140 cleaning Methods 0.000 title claims description 11
- 238000000576 coating method Methods 0.000 claims abstract description 44
- 238000009408 flooring Methods 0.000 claims description 40
- -1 polyethylene Polymers 0.000 claims description 40
- 239000011248 coating agent Substances 0.000 claims description 30
- 239000004094 surface-active agent Substances 0.000 claims description 29
- 239000000839 emulsion Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000003085 diluting agent Substances 0.000 claims description 21
- 150000002191 fatty alcohols Chemical class 0.000 claims description 18
- 239000004014 plasticizer Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 11
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 229920006243 acrylic copolymer Polymers 0.000 claims description 7
- 239000003752 hydrotrope Substances 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 230000001680 brushing effect Effects 0.000 claims description 3
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims 1
- 125000000373 fatty alcohol group Chemical group 0.000 claims 1
- 230000008859 change Effects 0.000 abstract description 21
- 230000008439 repair process Effects 0.000 abstract description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 28
- 229920002554 vinyl polymer Polymers 0.000 description 28
- 238000009472 formulation Methods 0.000 description 27
- 239000010410 layer Substances 0.000 description 26
- 239000000463 material Substances 0.000 description 23
- 239000001993 wax Substances 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- 235000008504 concentrate Nutrition 0.000 description 10
- 239000012141 concentrate Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 229920001410 Microfiber Polymers 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 9
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 238000012423 maintenance Methods 0.000 description 7
- 230000007935 neutral effect Effects 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000003892 spreading Methods 0.000 description 6
- 230000007480 spreading Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 239000003658 microfiber Substances 0.000 description 5
- 239000004209 oxidized polyethylene wax Substances 0.000 description 5
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
- 239000012263 liquid product Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- HXHCOXPZCUFAJI-UHFFFAOYSA-N prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1 HXHCOXPZCUFAJI-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002888 zwitterionic surfactant Substances 0.000 description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 230000003716 rejuvenation Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- LTMQZVLXCLQPCT-UHFFFAOYSA-N 1,1,6-trimethyltetralin Chemical compound C1CCC(C)(C)C=2C1=CC(C)=CC=2 LTMQZVLXCLQPCT-UHFFFAOYSA-N 0.000 description 2
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 2
- NZFLWVDXYUGFAV-UHFFFAOYSA-N 1-methyl-2-acetylpyrrole Chemical compound CC(=O)C1=CC=CN1C NZFLWVDXYUGFAV-UHFFFAOYSA-N 0.000 description 2
- HGDVHRITTGWMJK-UHFFFAOYSA-N 2,6-dimethylheptan-2-ol Chemical compound CC(C)CCCC(C)(C)O HGDVHRITTGWMJK-UHFFFAOYSA-N 0.000 description 2
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 241001417527 Pempheridae Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 241001085205 Prenanthella exigua Species 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 150000001860 citric acid derivatives Chemical class 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 125000005456 glyceride group Chemical group 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000003165 hydrotropic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- CWXAYEQCHXOEIW-UHFFFAOYSA-N 1,1-diethoxyethanol Chemical compound CCOC(C)(O)OCC CWXAYEQCHXOEIW-UHFFFAOYSA-N 0.000 description 1
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-BGYRXZFFSA-N 1-o-[(2r)-2-ethylhexyl] 2-o-[(2s)-2-ethylhexyl] benzene-1,2-dicarboxylate Chemical compound CCCC[C@H](CC)COC(=O)C1=CC=CC=C1C(=O)OC[C@H](CC)CCCC BJQHLKABXJIVAM-BGYRXZFFSA-N 0.000 description 1
- RVBLXUAPXWEIPM-UHFFFAOYSA-N 1-o-benzyl 2-o-(2-ethylhexyl) benzene-1,2-dicarboxylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 RVBLXUAPXWEIPM-UHFFFAOYSA-N 0.000 description 1
- BHKLONWXRPJNAE-UHFFFAOYSA-N 1-o-butyl 2-o-cyclohexyl benzene-1,2-dicarboxylate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OC1CCCCC1 BHKLONWXRPJNAE-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- RECMXJOGNNTEBG-UHFFFAOYSA-N 1-phenylmethoxyethanol Chemical compound CC(O)OCC1=CC=CC=C1 RECMXJOGNNTEBG-UHFFFAOYSA-N 0.000 description 1
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- PACBIGNRUWABMA-UHFFFAOYSA-N 2-(2,3-dihydro-1,3-benzothiazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(C2SC3=CC=CC=C3N2)=C1O PACBIGNRUWABMA-UHFFFAOYSA-N 0.000 description 1
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- CETWDUZRCINIHU-UHFFFAOYSA-N 2-heptanol Chemical compound CCCCCC(C)O CETWDUZRCINIHU-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- ACBMYYVZWKYLIP-UHFFFAOYSA-N 2-methylheptan-2-ol Chemical compound CCCCCC(C)(C)O ACBMYYVZWKYLIP-UHFFFAOYSA-N 0.000 description 1
- IEBAJFDSHJYDCK-UHFFFAOYSA-N 2-methylundecan-4-one Chemical compound CCCCCCCC(=O)CC(C)C IEBAJFDSHJYDCK-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- BJEMXPVDXFSROA-UHFFFAOYSA-N 3-butylbenzene-1,2-diol Chemical compound CCCCC1=CC=CC(O)=C1O BJEMXPVDXFSROA-UHFFFAOYSA-N 0.000 description 1
- LDMRLRNXHLPZJN-UHFFFAOYSA-N 3-propoxypropan-1-ol Chemical compound CCCOCCCO LDMRLRNXHLPZJN-UHFFFAOYSA-N 0.000 description 1
- LURSBVMEKAXVBO-UHFFFAOYSA-N 5-butoxypentan-2-ol Chemical compound CCCCOCCCC(C)O LURSBVMEKAXVBO-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000005973 Carvone Substances 0.000 description 1
- 244000037364 Cinnamomum aromaticum Species 0.000 description 1
- 235000014489 Cinnamomum aromaticum Nutrition 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 description 1
- VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N Diethylhexyl phthalate Natural products CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000000899 Gutta-Percha Substances 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- YSSDALIKCHVBBZ-UHFFFAOYSA-N P.P.S.S Chemical compound P.P.S.S YSSDALIKCHVBBZ-UHFFFAOYSA-N 0.000 description 1
- 240000000342 Palaquium gutta Species 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920001744 Polyaldehyde Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229920002359 Tetronic® Polymers 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- 229920002310 Welan gum Polymers 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 229960001413 acetanilide Drugs 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000010441 alabaster Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000005910 alkyl carbonate group Chemical group 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- WXBLLCUINBKULX-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 WXBLLCUINBKULX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- LBKFHGHXATXEBY-UHFFFAOYSA-N bis(1-methylcyclohexyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OC2(C)CCCCC2)C=1C(=O)OC1(C)CCCCC1 LBKFHGHXATXEBY-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 229950003621 butoxylate Drugs 0.000 description 1
- MQWDTXAOPTYTLC-UHFFFAOYSA-N butyl 1-(3-cyano-3,3-diphenylpropyl)-4-phenylpiperidine-4-carboxylate Chemical compound C1CC(C(=O)OCCCC)(C=2C=CC=CC=2)CCN1CCC(C#N)(C=1C=CC=CC=1)C1=CC=CC=C1 MQWDTXAOPTYTLC-UHFFFAOYSA-N 0.000 description 1
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl ester butanoic acid Natural products CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 1
- BTMVHUNTONAYDX-UHFFFAOYSA-N butyl propionate Chemical compound CCCCOC(=O)CC BTMVHUNTONAYDX-UHFFFAOYSA-N 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229940082483 carnauba wax Drugs 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- QEFOHLDZJZYQEZ-UHFFFAOYSA-N dibutyl 2-(1,4-dibutoxy-1,4-dioxobutan-2-yl)sulfanylbutanedioate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)SC(C(=O)OCCCC)CC(=O)OCCCC QEFOHLDZJZYQEZ-UHFFFAOYSA-N 0.000 description 1
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 1
- ISXDVFNOXYQPIA-UHFFFAOYSA-N dibutyl pentanedioate Chemical compound CCCCOC(=O)CCCC(=O)OCCCC ISXDVFNOXYQPIA-UHFFFAOYSA-N 0.000 description 1
- 229960002097 dibutylsuccinate Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- OUWSNHWQZPEFEX-UHFFFAOYSA-N diethyl glutarate Chemical compound CCOC(=O)CCCC(=O)OCC OUWSNHWQZPEFEX-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- JMPVESVJOFYWTB-UHFFFAOYSA-N dipropan-2-yl carbonate Chemical compound CC(C)OC(=O)OC(C)C JMPVESVJOFYWTB-UHFFFAOYSA-N 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- IGOFAIGWJGFDDZ-UHFFFAOYSA-N ethanesulfonamide;toluene Chemical compound CCS(N)(=O)=O.CC1=CC=CC=C1 IGOFAIGWJGFDDZ-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- RHVPKFMWDXPWAF-UHFFFAOYSA-N ethoxycarbamic acid Chemical class CCONC(O)=O RHVPKFMWDXPWAF-UHFFFAOYSA-N 0.000 description 1
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 229920000588 gutta-percha Polymers 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FIDHJNPSYVPHFX-UHFFFAOYSA-N hexane-1,6-diol phthalic acid Chemical compound OCCCCCCO.OC(=O)C1=CC=CC=C1C(O)=O.OC(=O)C1=CC=CC=C1C(O)=O FIDHJNPSYVPHFX-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 239000010656 jasmine oil Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 1
- UQKAOOAFEFCDGT-UHFFFAOYSA-N n,n-dimethyloctan-1-amine Chemical compound CCCCCCCCN(C)C UQKAOOAFEFCDGT-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- WLGDAKIJYPIYLR-UHFFFAOYSA-N octane-1-sulfonic acid Chemical compound CCCCCCCCS(O)(=O)=O WLGDAKIJYPIYLR-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 229960005489 paracetamol Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- TWSRVQVEYJNFKQ-UHFFFAOYSA-N pentyl propanoate Chemical compound CCCCCOC(=O)CC TWSRVQVEYJNFKQ-UHFFFAOYSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- MCSINKKTEDDPNK-UHFFFAOYSA-N propyl propionate Chemical compound CCCOC(=O)CC MCSINKKTEDDPNK-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229930006978 terpinene Natural products 0.000 description 1
- 150000003507 terpinene derivatives Chemical class 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
- C09G1/12—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
本公开涉及组合物和使用该组合物处理地板表面的方法。公开的组合物清洁地板表面、修复其损坏或维持地板的原始外观。公开的组合物还不在地板上提供永久面层、为临时涂料或在施加后不明显改变地板的光泽。
Description
相关申请的交叉引用
本申请正在作为PCT国际申请于2018年5月2日提交,并要求2017年5月11日提交的美国临时申请系列号62/504,869的优先权和权益,所述文献的公开内容以全文引用的方式并入本文中。
技术领域
本公开涉及组合物和使用该组合物处理地板表面的方法。公开的组合物清洁地板表面、修复其损坏或维持地板的原始外观。公开的组合物还不在地板上提供永久面层、为临时的、在施加后不明显增加地板的光泽或者在施加后不显著改变地板的最终外观。
背景技术
随着时间的流逝,所有地板都遭受磨损。地板材料可以由制造商处理或在安装后处理,以防止或延缓磨损。改进的乙烯基树脂地板材料,有时也称为豪华乙烯基树脂地板材料,已经在住宅环境和商业环境中变得日益流行。以前归为住宅用途,更好防护涂料或“耐磨层”的演进已允许打入诸多市场,如急症医院、长期护理设施、酒店、办公建筑、学校、大学和零售场所。
在传统的乙烯基树脂复合面板(VCT)地板中,乙烯基树脂以随着使用而相对快速磨损并需要复原的涂料处理。相反,在某些高端豪华乙烯基树脂地板材料中,使用了极其坚硬和耐用的耐磨层,所述耐磨层抵抗磨损并且实际上免维护或需要很少的维护。这种层使豪华乙烯基树脂地板材料实际上在住宅区免维护。但是,当这种地板材料用于高度交通区域时,例如,用于商业建筑,如零售商店、饭店、旅馆、卫生保健设施、医院、长期护理设施等,随着时间流逝,极其坚硬的耐磨层可能磨损并需要维护。而另一方面,由于耐磨层因高度交联的***和其他新颖化学物质所致的耐受性质,发现常见的复原措施无效。该耐磨层能够抵抗常见的剥离材料和方法,并且传统的地板涂料常常无法粘附到地板上。
发明内容
在一些实施方案中,本公开涉及具有蜡、树脂、表面活性剂和稀释剂的地板护理组合物。具体的蜡、树脂、表面活性剂和稀释剂可各自独立地选自本文所述的那些材料的列表。
在一些实施方案中,本公开涉及具有蜡、树脂、表面活性剂和稀释剂的地板护理组合物。在一个优选的实施方案中,蜡是聚乙烯蜡乳液,树脂是丙烯酸共聚物乳液,表面活性剂是脂肪醇乙氧基化物,稀释剂是二醇醚。
在一些实施方案中,本公开涉及一种通过将组合物施加到地板上来复原地板的方法。该组合物具有蜡、树脂、表面活性剂和稀释剂。在一个优选的实施方案中,蜡是聚乙烯蜡乳液,树脂是丙烯酸共聚物乳液,表面活性剂是脂肪醇乙氧基化物,稀释剂是二醇醚。在该方法中,在60°测量时,将组合物施加到地板上不改变地板上的光泽超过3分。
在一些实施方案中,本公开涉及一种通过将组合物施加到地板上来复原地板的方法。该组合物具有蜡、树脂、表面活性剂和稀释剂。在一个优选的实施方案中,蜡是聚乙烯蜡乳液,树脂是丙烯酸共聚物乳液,表面活性剂是脂肪醇乙氧基化物,稀释剂是二醇醚。在该方法中,连续施加组合物在地板上产生厚度小于2μm的层堆积。
在一些实施方案中,本公开涉及一种通过将组合物施加到地板上来清洁地板的方法。该组合物具有约0.001至约0.1重量%的聚乙烯蜡乳液、约0.01至约0.5重量%的丙烯酸共聚物乳液、约0.005至约0.5重量%的脂肪醇乙氧基化物、约0.001至约0.15重量%的二醇醚溶剂和水。
附图简述
图1是敷设的地板材料的示意图。
具体实施方式
本公开涉及用于维护地板表面的方法和组合物。具体地,本公开涉及用于清洁或复原地板表面的方法和组合物。所公开的组合物可以用于多种地板上,但特别可用于特种地板表面,例如豪华乙烯基树脂板、油毡、橡胶和乙烯基树脂片材。
一般通过以下方式施加传统的地板涂料(有时称为地板上光剂、乳液、蜡、密封剂或密封剂涂料):首先从地板表面上剥下任何先前的地板涂料层,并且然后向地板表面施加一层或多层地板涂料组合物。可以通过使用剥离组合物或通过机械手段或两者进行剥离。可以通过倾倒、拖刷、喷洒或通过其他施加手段,例如地板清扫机,将涂料组合物施加并铺展到备妥(剥离)的地板表面上。地板涂料组合物可以例如通过化学固化或通过使用UV来固化。固化的面层可以进一步打磨或抛光,以获得有光泽、易维护的面层。
某些地板材料,例如高耐久性豪华乙烯基树脂地板,对传统的剥离组合物和方法以及传统的地板涂料具有抵抗力。如图1所示,豪华乙烯基树脂地板1通常作为多层产品制造,所述多层产品包括芯层10(例如,纤维板芯)和可以模仿各种其他材料如石材、木材、瓦等的装饰性着色和/或质地层20。装饰层通常被保护装饰层的透明耐磨层30覆盖。地板还可包括下表面40。
高耐久性的乙烯基树脂板可以具有耐磨层,所述耐磨层包含聚硅氧烷、聚氯乙烯(PVC)、聚氨酯强化的PVC、聚氨酯、紫外线涂层的聚氨酯、氧化铝或石英增强的聚氨酯。尽管此类材料抵抗化学磨损和物理磨损,但随着时间的流逝,需要维护高耐久性地板,尤其是暴露于高度交通、商业或工业使用的那些。
所公开的组合物向地板施加临时或并非永久的涂层。如本公开中所使用,短语“临时的”或“非永久的”是指涂层随着正常磨损或步行交通而磨损。另外,可以使用中性或碱性地板清洁剂、稀释的地板剥离剂或轻压移除该组合物、并不需要地板剥离过程中传统使用的强力机械作用或浓化学品移除涂层。
术语“重量百分比”、“wt-%”、“以重量计百分比”、“以重量计%”及其变体是指物质的浓度,即该物质的重量占组合物总重量的百分比。除非特别指出,否则术语“百分比”和“%”与“重量百分比”和“wt%”同义。
本文使用术语“基本上不含”来指示产品中不包含实质量(例如,不超过偶然量,例如约0.1%、约0.5%、约1%、约2%、约3%或约5%)的组分。
所公开的组合物通过同时从地板移动并移除污垢并且将保护膜薄层沉积到地板上由磨损引起的表面划痕中,提供了清洁和复原地板表面的双重益处。通过沉积这样的薄膜薄层,组合物不像传统地板涂料那样“包覆”地板。没有涂层意味着用公开的组合物处理后,不存在需要如传统地板涂料那样维护(例如,移除、再施加、抛光或打磨)的涂层。地板的“无维护”益处保持完好,因为组合物不增加维护工作量或不产生抛光或再涂布需求。无涂层还意味着地板的原始外观保持不变。地板会保持其居家般外观,并且不给表面带来塑料感外观。所公开的组合物不改变地板的光泽、地板上顶部涂层的不透明性或不导致地板上的图案遮挡或不显得浑浊。组合物意在是临时或非永久的。在一些实施方案中,一旦将组合物施加到地板上,则在连续5次施加后、连续10次施加后或连续20次施加后,在60°测量时,如使用行业标准的光泽度仪(如Byk的micro-TRI-gloss)测量,组合物使地板的光泽度增加超过5分。在一些实施方案中,连续5次施加,组合物施加到地板上导致厚度小于10μm、厚度小于5μm或厚度小于2μm的层堆积。为了比较,常见的地板涂料产生厚度约20-40μm的涂层。
组合物
组合物包含树脂、一种或多种表面活性剂和稀释剂。在一些实施方案中,组合物还包含增塑剂。在一些实施方案中,组合物不含或基本上不含增塑剂。在一些实施方案中,组合物不含或基本上不含氨基甲酸酯。在一些实施方案中,组合物不在地板表面上固化并且所公开的方法不包括使地板护理组合物固化。
组合物可以进一步包含额外的功能组分,包括一种或多种蜡、有机溶剂、稀释剂、增稠剂、润湿剂、pH调节剂或缓冲剂、水溶助长剂、增溶剂、消泡剂和增塑剂或聚结剂。组合物还可以包含改善组合物外观的额外组分,例如香料和染料。
合适的蜡的实例包括蜡、蜡乳剂和植物、动物源、合成源和/或矿物源蜡的蜡分散体或混合物。代表性蜡包括,例如巴西棕榈蜡、小烛树蜡、羊毛脂、硬脂精、蜂蜡、氧化聚乙烯蜡、聚乙烯乳液、聚丙烯、乙烯和丙烯酸酯的共聚物、氢化椰油或大豆油、以及矿物蜡,例如石蜡或纯地蜡。一种优选的蜡是聚乙烯蜡乳液。
合适的树脂的实例包括天然树脂或聚合物,例如松香树脂、合成树脂、加成聚合物,如丙烯酸聚合物或苯乙烯/丙烯酸聚合物、缩合聚合物,如聚酯聚合物、聚氨酯聚合物、聚醚聚合物、多醛聚合物、聚碳酸酯、聚酰胺和其组合。聚合物通常具有约500-2000的分子量。有机聚合物的实例包括苯乙烯或乙烯基甲苯与至少一种α-β-单烯键式不饱和酸或酸酐的共聚物,例如苯乙烯-马来酸酐树脂、与多元醇缩合的松香/马来酸酐加合物等。示例性的丙烯酸聚合物包括但不限于甲基丙烯酸甲酯/丙烯酸丁酯/甲基丙烯酸(MMA/BA/MAA)共聚物、甲基丙烯酸甲酯/丙烯酸丁酯/丙烯酸(MMA/BA/AA)聚合物等。苯乙烯-丙烯酸聚合物的实例包括但不限于苯乙烯/甲基丙烯酸甲酯/丙烯酸丁酯/甲基丙烯酸(S/MMA/BA/MMA)共聚物、苯乙烯/甲基丙烯酸甲酯/丙烯酸丁酯/丙烯酸(S/MMA/BA/AA)共聚物等。一种优选的丙烯酸聚合物是Mor-Glo 2,来自南卡罗莱纳州切斯特市Omnova Solutions的38%活性乳液。
合适的有机溶剂的实例包括短链或长链或环状醇(例如乙醇、异丙醇)、胺、酰胺、醚,例如羟基醚、酮、烷基碳酸酯、精油、酯(例如环状酯、双碱性和邻苯二甲酸酯)、氧合的溶剂(例如二醇醚)及其混合物。示例性溶剂包括乙酰氨基酚、乙酰苯胺、苯乙酮、2-乙酰基-1-甲基吡咯、乙酸苄酯、苯甲醇、苯甲酸苄酯、苄氧乙醇、乙二醇苯醚、丙二醇苯醚、2-(2-氨基乙氧基)乙醇、单乙醇胺、二乙醇胺、三乙醇胺、水溶性或水分散性聚合胺如聚(乙烯亚胺)、乙酸戊酯、戊基乙醇、丁醇、3-丁氧乙基-2-丙醇、乙酸丁酯、丙酸正丁酯、环己酮、双丙酮醇、二乙氧乙醇、二甘醇甲醚、二异丁基甲醇、二异丁酮、二甲基庚醇、双丙甘醇叔丁醚、乙醇、乙酸乙酯、2-乙基己醇、丙酸乙酯、乙二醇、乙酸乙二醇甲醚、丙三醇、己醇、异丁醇、乙酸异丁酯、异丁基庚基酮、异佛尔酮、异丙醇、乙酸异丙酯、甲醇、甲基戊基乙醇、甲基正戊基酮、2-甲基-1-丁醇、甲乙酮、甲基异丁酮、1-戊醇、丙酸正戊酯、1-丙醇、乙酸正丙酯、丙酸正丙酯、丙二醇、丙二醇***、二缩三丙醇甲醚、二缩三丙醇正丁醚、二甘醇正丁醚乙酸酯、二甘醇单丁基醚、乙二醇正丁基醚乙酸酯、乙二醇单丁基醚、双丙甘醇单丁基醚、丙二醇单丁基醚、3-乙氧基丙酸乙酯、2,2,4-三甲基-1,3-戊二醇单异丁酸酯、二甘醇单己基醚、乙二醇单己基醚、二甘醇单甲基醚、二甘醇单***、乙酸乙二醇甲醚、乙二醇单甲醚、双丙甘醇单甲基醚、丙二醇甲醚乙酸酯、丙二醇单甲基醚、二甘醇单丙基醚、乙二醇单丙基醚、双丙甘醇单丙基醚和丙二醇单丙基醚。代表性的二烷基碳酸酯包括碳酸二甲酯、碳酸二乙酯、碳酸二丙酯、碳酸二异丙酯和碳酸二丁酯。代表性的精油包括苯甲醛、蒎烯(α、β等)、松油醇、松油烯、香芹酮、肉桂醛、冰片及其酯、柠檬醛、紫罗烯、茉莉油、柠檬烯、双戊烯、芳樟醇及其酯。代表性的二价酸酯包括己二酸二甲酯、琥珀酸二甲酯、戊二酸二甲酯、丙二酸二甲酯、己二酸二乙酯、琥珀酸二乙酯、戊二酸二乙酯、琥珀酸二丁酯和戊二酸二丁酯。代表性的邻苯二甲酸酯包括邻苯二甲酸二丁酯、邻苯二甲酸二乙基己酯和邻苯二甲酸二乙酯。
合适的表面活性剂的实例包括水溶性或水分散性非离子、半极性非离子、阴离子、阳离子、两性或两性离子表面活性剂或其任意组合。表面活性剂可以是表面活性剂的组合。
非离子表面活性剂
合适的非离子表面活性剂的实例包括:嵌段聚氧丙烯-聚氧乙烯聚合化合物,包括由BASF Corp.制造的市售产品和烷基酚与环氧乙烷的缩合产物,包括Rhone-Poulenc制造的市售产品和Union Carbide制造的具有4至24个碳原子的直链或支链醇与环氧乙烷的缩合产物,包括由BASF制造的市售产品由Shell化学制造的和由Vista化学制造的直链或支链羧酸与环氧乙烷的缩合产物,包括由Henkel制造的市售产品和由Lipo化学有限制造的Lipopeg通过与甘油酯、甘油和多元醇的反应生成的链烷酸酯。
不发泡、低发泡或消泡非离子表面活性剂的具体实例包括:以商品名Genapol销售的脂肪醇聚氧丙烯-聚氧乙烯加合物;疏水性嵌段在分子外部(端基)的嵌段聚氧丙烯-聚氧乙烯聚合化合物,有时称为“反向”Pluronics或Tetronics,以商品名R和R销售;通过与疏水小分子反应或通过将端羟基转化为氯基,对端羟基“加帽”或“端基封闭”来改性的非离子表面活性剂。不发泡非离子表面活性剂的其他实例包括美国专利号2,903,486中提出的烷基苯氧基聚乙氧基链烷醇;美国专利号3,048,548的聚亚烷基二醇缩合物;美国专利号3,382,178的消泡非离子表面活性剂,其具有通式Z[(OR)nOH]z,其中Z是可烷氧基化的材料、R是原子团,n是10-2,000并且z由活泼可烷氧化基团的数目决定;美国专利号2,677,700中描述的共轭聚氧化烯化合物;美国专利号2,674,619中描述的共轭聚氧化烯化合物。
烷氧基化(例如乙氧基化或丙氧基化)的C6-C18脂肪醇是适用于本发明组合物的合适表面活性剂。合适的烷氧基化醇的实例是作为Lutensol从Florham Park,NJ的BASF Corp.可商业获得的乙氧基化C10醇。
阴离子表面活性剂
阴离子表面活性剂可用作洗净性表面活性剂,也可用作胶凝剂或用作胶凝体系或增稠体系的一部分,用作增溶剂、并用于水溶助长效果和浊点控制。组合物可以包含一种或多种阴离子表面活性剂。适用于本发明组合物的阴离子表面活性剂包括:羧酸及其盐,例如链烷酸和链烷酸酯、酯羧酸(例如琥珀酸烷基酯)、醚羧酸等;磷酸酯及其盐;磺酸及其盐,例如羟乙磺酸盐、烷基芳基磺酸盐、烷基磺酸盐、磺基琥珀酸盐;硫酸酯及其盐,例如烷基醚硫酸盐、烷基硫酸盐等。
阳离子表面活性剂
常用的一组阳离子表面活性剂是胺,例如烷基胺和酰胺基胺。胺类例如包括烷基胺及其盐、烷基咪唑啉、乙氧基化胺和季铵化合物及其盐。其他阳离子表面活性剂包括类似于胺化合物的基于硫(锍)和基于磷(鏻)的化合物。
两性和两性离子表面活性剂
两性和两性离子表面活性剂包括仲胺和叔胺的衍生物、杂环仲胺和叔胺的衍生物、或季铵、季鏻或叔锍合物的衍生物。铵、鏻或锍化合物可以被脂族取代基例如烷基、烯基或羟烷基;亚烷基或羟亚烷基;或羧酸酯、磺酸酯、硫酸酯、膦酸酯或磷酸酯基团取代。甜菜碱和磺基甜菜碱表面活性剂是用于组合物中的示例性两性离子表面活性剂。
在一些实施方案中,组合物包含还充当增塑剂以在配方中促进柔软性和可塑性的表面活性剂。也可以用作增塑剂的表面活性剂的实例包括脂肪醇乙氧基化物、两性羧酸酯、磺酸钠、氨基羧酸酯、氧化胺、烷氧基化物聚合物、EO/PO共聚物和辛基氨基丙酸酸酯。表面活性剂的选择不限于还具有增塑剂性能的表面活性剂,并且可以选择额外或不同的表面活性剂。
组合物还包含稀释剂,其通常是水,并且还可以包含一种或多种合适的有机溶剂。
组合物可以任选地包含一种或多种增稠剂。示例性的增稠剂包括树胶和其他多糖,例如角叉菜胶、决明胶、丢丁胶、吉兰糖胶、瓜尔胶、***树胶、黄蓍胶、刺槐豆胶、惠兰胶和黄原胶;藻酸盐,如琼脂;纤维素醚,例如乙基纤维素、羟乙基纤维素、乙基羟乙基纤维素、甲基纤维素、羟丙基纤维素、羟丙基甲基纤维素和其他烷基或羟烷基纤维素醚;丙烯酸共聚物;聚环氧乙烷(例如高分子量聚环氧乙烷),例如聚乙二醇和甲氧基聚乙二醇;聚乙烯醇;聚乙烯吡咯烷酮;淀粉;聚氨酯;甲基乙烯基醚/马来酸酐共聚物;及其混合物。水增稠剂还可包括疏水改性的乙氧基氨基甲酸酯(HEUR)增稠剂、疏水改性的碱溶性乳液(HASE)增稠剂、疏水改性的羟乙基纤维素(HM-HEC)增稠剂和HEUR-ASE组合增稠剂。作为固形物表述的增稠剂的量可以为总浓缩物重量的约0.1%至约30%、约2%至约20%或约3%至约10%。
组合物可以任选地包含一种或多种帮助组合物铺展到地板上的润湿剂。示例性的润湿剂包括阴离子氟表面活性剂、硅氧烷改性的聚丙烯酸酯、聚醚改性的硅氧烷、聚醚改性的聚硅氧烷、聚醚改性的聚二甲基硅氧烷、脂肪醇烷氧基化物和聚乙二醇聚丙二醇嵌段共聚物。作为固形物的润湿剂的量可以是总浓缩物重量的约0.05%至约0.20%、约0.05%至约0.50%或约0.01%至约1.0%。
组合物的pH优选在约5至约10或约6至约8的范围内。可以使用各种碱、酸或缓冲剂调节pH。示例性酸包括有机酸,例如柠檬酸、乙酸、乳酸和无机酸。示例性碱包括氢氧化钠和氢氧化钾。示例性缓冲剂包括磷酸盐、碳酸盐、胺、碳酸氢盐和柠檬酸盐。示例性磷酸盐包括无水磷酸一、二或三钠、三聚磷酸钠、焦磷酸四钠和焦磷酸四钾。示例性碳酸盐包括碳酸钠、碳酸钾和倍半碳酸盐。示例性柠檬酸盐包括柠檬酸钠或柠檬酸钾。示例性胺包括尿素、二乙醇胺、三乙醇胺和吗啉。
组合物可以任选地包含一种或多种水溶助长剂或增溶剂。可以在组合物中包含水溶助长剂,以辅助组成稳定性并通过与其他组分偶联来帮助溶解含水制剂中的其他组分。可以使用的水溶助长偶联剂或增溶剂的代表性类别包括阴离子表面活性剂,例如烷基硫酸盐和链烷磺酸盐、直链烷基苯或萘磺酸盐、仲链烷磺酸盐、烷基醚硫酸盐或磺酸盐、烷基磷酸盐或膦酸盐、二烷基磺基琥珀酸酯、糖酯(例如脱水山梨糖醇酯)、氧化胺(单、二或三烷基)和C8-C10烷基葡糖苷。优选的水溶助长剂包括从明尼苏达州圣保罗市Ecolab,Inc.以NAS8D的形式可获得的正辛烷磺酸盐;正辛基二甲基氧化胺;常用的芳族磺酸盐,例如烷基苯磺酸盐(例如二甲苯磺酸盐)或萘磺酸盐;具有1至约40个环氧乙烷、环氧丙烷或环氧丁烷单元的芳基或烷芳基磷酸酯或其烷氧基化类似物。其他优选的水溶助长剂包括C6-C24醇烷氧基化物(乙氧基化物、丙氧基化物或丁氧基化物)的非离子表面活性剂;C6-C24烷基酚烷氧基化物;C6-C24烷基多糖苷;C6-C24脂肪酸酯乙氧基化物、丙氧基化物或甘油酯;和C4-C12单或二烷醇酰胺。组合物可以含有约0至约15重量-%、约0.005至约7重量-%、约0.1至约12重量-%、约0.5至约10重量-%、约1.0至约8重量-%、或约2.0至约5.0重量%的水溶助长剂或增溶剂。
组合物可以任选地含有增塑剂或聚结剂。增塑剂通常是可以与聚合物缔合从而改变聚合物或组合物本身的物理性质的化合物或混合物。例如,增塑剂可以用于改***度、柔软性、玻璃化转变温度(Tg)以形成连续膜。示例性增塑剂包括邻苯二甲酸丁苄酯、邻苯二甲酸二丁酯、邻苯二甲酸二甲酯、磷酸三苯酯、邻苯二甲酸2-乙基己基苄基酯、邻苯二甲酸丁基环己基酯、季戊四醇的混合苯甲酸和脂肪酸酯、聚己二酸丙二酯、二甘醇二苯甲酸酯、四丁基硫代二琥珀酸酯、丁基邻苯二甲酚丁基丁酸酯、柠檬酸三乙酯、乙酰基柠檬酸三乙酯、乙酰基柠檬酸三丁酯、癸二酸二苄酯、磷酸三甲苯酯、磷酸三丁氧基乙基酯、甲苯乙基磺酰胺、六亚甲基二醇二邻苯二甲酸酯的二-2-乙基己酯、邻苯二甲酸二(甲基环己基)酯和磷酸三丁酯。示例性的聚结剂包括二甘醇或二丙二醇的单丁基、单乙基、单甲基或其他单烷基醚、异佛尔酮、苄醇、丁基溶纤剂和3-甲氧基丁醇-1。在一些实施方案中,增塑剂或聚结剂以约0至约10重量-%、约0至约5重量-%或约0至约2重量-%存在。在一些实施方案中,限制增塑剂的量小于1.0重量-%或小于0.5重量%。在一些实施方案中,组合物不含或基本上不含增塑剂或聚结剂。并且在一些实施方案中,组合物包含具有表面活性剂性质和增塑剂性质的表面活性剂。
组合物可以任选地含有消泡剂。示例性消泡剂是聚二甲基硅氧烷。在一些实施方案中,消泡剂以约0至约2重量-%、约0至约1重量-%或约0至约0.5重量-%存在。在一些实施方案中,限制消泡剂的量小于0.3重量-%或小于0.2重量%。
组合物可以进一步包含一种或多种香料或染料。
组合物可以作为浓缩物或作为即用溶液提供。浓缩物可以原样使用或可以进一步稀释以提供使用液。如果组合物作为浓缩物提供,则组合物可以处于固体形式(例如粉末、块、片、团粒、颗粒等),或处于液体形式(例如自由流动液体、增稠的液体、乳液、凝胶或糊膏)。即用型溶液可以配制成水稀薄液体、增稠的液体、乳液、凝胶或糊膏。
根据实施方案,组合物可以包含一种或多种稀释剂。在一个优选的实施方案中,稀释剂是水。组合物的液态浓缩物可以包含约10至约95重量-%、或约25至约75重量-%、或约30至约70重量%的稀释剂(例如水或其他水性液体)。浓缩物(液态或固态)可以由使用者用水或另一种合适的稀释剂稀释以制备使用液。例如,浓缩物组合物可以在使用前以水按照约1份浓缩物对约10-1,000份水的比率稀释。本领域技术人员将理解,稀释度将取决于浓缩物和所需使用液的浓度。
在一些实施方案中,使用液(作为使用液配制的组合物或从浓缩物制备的使用液)占约80至约99重量-%、或约90至约99重量-%、或约95至约99重量-%的水。在一个示例性的实施方案中,使用液包含约97至约99重量%的水。
组合物的示例性配方示于下表1中。
表1.示例性配方
可以使用行业标准的光泽度仪(如Byk的micro-micro-TRI-gloss)测试地板上的光泽度。
可以使用扫描电子显微镜(SEM)确定地板上涂层的厚度。
施加方法
所公开的组合物可以用于清洁、修复损坏或复原地板表面原始外观的方法中。在一些实施方案中,可选地首先清洁、扫除地板或对其抽真空,以移除任何松散的碎屑。可以使用多种方法和工具施加组合物,包括喷洒(例如,用扳机式喷雾器、泵式喷雾器、气雾剂或用位于拖把上的机载喷雾装置)、喷射、刷涂、平板或绳束拖刷、辊涂、用油漆辊施加、用T型杆涂施器施加、使用机器如地板清扫机,和溢流涂装。拖刷施加,尤其平板拖刷优选用于涂装大部分地板。合适的拖把包括在美国专利号5,315,734、5,390,390、5,680,667和5,887,311,所述文献的完整公开内容通过引用方式并入本文。可以使用垫(如擦洗垫、研磨垫、碎布)或任何其他合适方法,将组合物擦刷到地板上。铺展和擦洗可以作为单独的步骤进行,或者作为单一步骤同时进行。
示例性的拖把头包括绳束拖把,如,从Amsan可获得的那些;平板拖把,如,从Rubbermaid、Unger或Ecolab可获得的那些。拖把头材料可以由例如棉、人造丝、聚酯、尼龙或其组合制成。拖把头优选是由聚酯和尼龙超细纤维制成的平板拖把。典型的施加量为每加仑2000平方英尺,但也可以根据地板表面和所需的性能使用其他施加量。在一些实施方案中,将组合物每天多次、一天3次、一天2次、每天一次、隔天一次、一周一次、一周几次、隔周一次或一月一次地施加于地板上。
组合物可以施加到各种地板基材上。组合物特别适用于豪华乙烯基树脂地板、层压地板、橡胶地板、油毡地板和乙烯基树脂片材地板,但可以在任何地板上使用以保持地板的外观、延长剥离和翻新地板之间的时间、或减少磨损出现。代表性的地板基材包括例如弹性基材,例如片状商品(例如,乙烯基树脂地板、油毡或橡胶片)、乙烯基树脂复合面板、豪华乙烯基树脂板、乙烯基树脂石棉板、橡胶板、软木和合成运动地板、以及非弹性基材,例如混凝土、石材、大理石、木材、竹、瓷砖、水泥浆、水磨石和其他浇筑或“干摇”地板、环氧树脂、聚氯乙烯(PVC)和甲基丙烯酸甲酯(MMA)。组合物尤其可用于豪华乙烯基树脂板和其他地板材料类型上,其中希望减少因磨损所致损坏的可视性,同时不改变地板的原始外观或整饰的情况下(例如,通过将无光的地板涂料更改为有光泽的涂料或将有光泽的地板涂料更改为无光的涂料)。
实施例
实施例1
实施例1评估了连续施加组合物后豪华乙烯基树脂板材料的光泽度变化。表2中显示了测试的配方:
表2
将配方A和B通过以下方式施加于四种不同颜色的豪华乙烯基树脂板样品上:使用一次性移液器,将一系列液态产品施加到面板上并用超细纤维地板涂料涂施器铺展。面板样品是Tardus Centiva American Cherry(颜色为棕色)、Johnsonite Falcon(颜色为黑褐色)、Natural Creations Ronoak Charcoal(颜色为黑色)和Natural CreationsFruitwood Alabaster(颜色为白色)。使组合物干燥,并随后用行业标准的光泽度仪(如Byk的micro-TRI-gloss)测量面板的光泽度。在20度和60度取得光泽度量值。再次通过将组合物使用超细纤维涂施器垫铺展到地板上,将额外的组合物层施加到先前层的顶部上的面板。使新的组合物干燥并且随后取得额外的光泽度量值。重复此过程,总共20次施加。结果记录在表3和表4中。
表3
表4
经验法则是,受训的操作员可以目视检测到3分或更多的光泽度变化,而普通人可以目视检测到5分或或更多分的光泽度变化。表3和表4表明,对于受训或未受培的观察者,经历20次连续施加的面板的任何光泽度变化不显著并且在视觉上不可察觉。
实施例2
实施例2评估了连续施加表5中列出的两种配方后油毡面板材料的光泽度变化,并针对市售的竞争者产品进行了测试。
表5
材料 | 配方A(以wt%计) | 配方B(以wt%计) |
去离子水 | 99.208% | 99.869% |
二甘醇单*** | 0.062% | 0.010% |
二己二醇单*** | 0.008% | 0.001% |
支链C10 5EO脂肪醇乙氧基化物 | 0.234% | 0.039% |
聚二甲基硅氧烷(10%溶胶) | 0.019% | 0.003% |
阴离子氟表面活性剂(10%) | 0.014% | 0.002% |
苯乙烯丙烯酸聚合物 | 0.399% | 0.067% |
氧化聚乙烯蜡 | 0.056% | 0.009% |
将六种不同的Forbo油毡地板样品首先使用加重的绿色钢丝球刮擦,并且在Gardner直线磨蚀仪上通过20或40次,所述样品包括Modular T3233、MCT-621、Concrete3707、Real 3136、Piano 3629和Striato 5216地板。根据制造商的标签说明,将竞争者的产品按照2盎司/加仑和13盎司/加仑稀释。然后,通过以下方式处理刮划的油毡:使用一次性移液器,将一系列液态使用液产品施加到面板上并用超细纤维地板涂料涂施器铺展。使组合物干燥,并随后用行业标准的光泽度仪(如Byk的micro-TRI–gloss)测量面板的光泽度。在20度和60度取得光泽度量值。再次通过将组合物使用超细纤维涂施器垫铺展到地板上,将额外的组合物层施加到先前层的顶部上的面板。使新的组合物干燥并且随后取得额外的光泽度量值。重复此过程,总共了5次施加更浓的溶液或20次施加更稀的溶液。结果记录在表6至表9中。
表6
表7
表8
表9
经验法则是,受训的操作员可以目视检测到3分或更多的光泽度变化,而普通人可以目视检测到5分或或更多分的光泽度变化。表4和表5表明,对于受训受训的或未受培的观察者,经历所有连续施加的面板的任何光泽度变化不显著并且在视觉上不可察觉。表8和表9列出了竞争者产品的结果,与相应的发明配方相比,以较高的推荐浓度使用时,所述竞争者产品增加光泽度。此外,以较高的推荐浓度使用时,竞争者产品引起的光泽度增加轻易可见。
实施例3
实施例3评估了连续施加表10中列出的两种配方后,片状乙烯基材料的光泽度变化。
表10
材料 | 配方A(以wt%计) | 配方B(以wt%计) |
去离子水 | 99.208% | 99.869% |
二甘醇单*** | 0.062% | 0.010% |
二己二醇单*** | 0.008% | 0.001% |
支链C10 5EO脂肪醇乙氧基化物 | 0.234% | 0.039% |
聚二甲基硅氧烷(10%溶胶) | 0.019% | 0.003% |
阴离子氟表面活性剂(10%) | 0.014% | 0.002% |
苯乙烯丙烯酸聚合物 | 0.399% | 0.067% |
氧化聚乙烯蜡 | 0.056% | 0.009% |
将两种不同的片状乙烯基树脂地板材料样品,Johnsonite Melodia Quartz和Mannington Biospec Bright White,首先使用加重的绿色钢丝球刮擦,并且在Gardner直线磨蚀仪上通过30次。根据制造商的标签说明,将市售的竞争者产品按照2盎司/加仑和13盎司/加仑稀,并且在Johnsonite Melodia Quartz上测试以比较。然后,通过以下方式处理刮划的乙烯基树脂片材:使用一次性移液器,将一系列液态使用液产品施加到面板上并用超细纤维地板涂料涂施器铺展。使组合物干燥,并随后用行业标准的光泽度仪(如Byk的micro-TRI–gloss)测量面板的光泽度。在20度和60度取得光泽度量值。再次通过将组合物使用超细纤维涂施器垫铺展到地板上,将额外的组合物层施加到先前层的顶部上的面板。使新的组合物干燥并且随后取得额外的光泽度量值。重复此过程,总共了5次施加更浓的溶液或20次施加更稀的溶液。结果记录在表11和表12中。
表11
表12
经验法则是,受训的操作员可以目视检测到3分或更多的光泽度变化,而普通人可以目视检测到5分或或更多分的光泽度变化。表11表明,对于受训受训的或未受培的观察者,经历所有连续施加的面板的任何光泽度变化不显著并且在视觉上不可察觉。表12显示了竞争者产品的结果,与相应的发明配方相比,以较高的推荐浓度使用时,所述竞争者产品增加光泽度。此外,竞争者产品引起的光泽度增加轻易可见。
实施例4
实施例4评估了连续施加表13中列出的两种配方后橡胶地板材料的光泽度变化,并针对市售的竞争者产品进行了测试。
表13
材料 | 配方A(以wt%计) | 配方B(以wt%计) |
去离子水 | 99.208% | 99.869% |
二甘醇单*** | 0.062% | 0.010% |
二己二醇单*** | 0.008% | 0.001% |
支链C10 5EO脂肪醇乙氧基化物 | 0.234% | 0.039% |
聚二甲基硅氧烷(10%溶胶) | 0.019% | 0.003% |
阴离子氟表面活性剂(10%) | 0.014% | 0.002% |
苯乙烯丙烯酸聚合物 | 0.399% | 0.067% |
氧化聚乙烯蜡 | 0.056% | 0.009% |
将两种不同的Nora橡胶地板材料样品,Norament Hammered Dust Grey和Noraplan Valua Charboal,首先使用加重的绿色钢丝球刮擦,并且在Gardner直线磨蚀仪上通过10次或20次。根据制造商的标签说明,将竞争者的产品按照2盎司/加仑和13盎司/加仑稀释。然后,通过以下方式处理刮划的油毡:使用一次性移液器,将一系列液态使用液产品施加到面板上并用超细纤维地板涂料涂施器铺展。使组合物干燥,并随后用行业标准的光泽度仪(如Byk的micro-TRI–gloss)测量面板的光泽度。在20度和60度取得光泽度量值。再次通过将组合物使用超细纤维涂施器垫铺展到地板上,将额外的组合物层施加到先前层的顶部上的面板。使新的组合物干燥并且随后取得额外的光泽度量值。重复此过程,总共了5次施加更浓的溶液或20次施加更稀的溶液。结果记录在表14和表15中。
表14
表15
经验法则是,受训的操作员可以目视检测到3分或更多的光泽度变化,而普通人可以目视检测到5分或或更多分的光泽度变化。表14显示,在60°测量时,在NoramentHammered Dust Gray上重复使用产品会产生一些光泽。然而,表15显示,在60°测量时,按可比的较高稀释比重复使用竞争产品将产生甚至更多光泽。
实施例5
实施例5检查了组合物对地板砖的粘附性。下表16中阐述实施例5中所用的配方:
表16
对以下两种豪华乙烯基树脂板样品进行了黏附测试:Armstrong NaturalCreations Fruitwood Alabaster(颜色为白色)和Centiva Starnet(颜色为深灰色)。根据ASTM D3359,使用多层刻划工具,以交叉网状图案切割/刻划固化的涂层,将胶带施加到刻划的区域,并将胶带从面板快速拉下。根据胶带移除多少涂料,依据评分0-5目视评定组合物与地板的黏附,值5为因无涂层损耗而完全粘附,值4为涂层损耗小于5%,并且值3为涂层损耗5-15%。该测试在地板材料干燥的情况下进行,并允许水在刻划地板之前和之后静置在地板上。结果示于表17。
表17
表17表明,本发明将按照认为与施加地板涂料到地板上之时所需方式相当的方式粘附到豪华乙烯基树脂板上。本领域技术人员众所周知,在潮湿条件下测试时,施加至地板基材上的薄膜经常部分地(若非完全地)被移除,尤其视为并非半永久或永久的涂料。
实施例6
与市场上目前可获得的竞争产品比较,实施例6测定了表18中列出的配方在油毡、橡胶和乙烯基树脂片材上的黏附性能。
表18
材料 | 配方A(以wt%计) |
去离子水 | 91.54% |
二甘醇单*** | 0.66% |
二己二醇单*** | 0.09% |
支链C10 5EO脂肪醇乙氧基化物 | 2.50% |
聚二甲基硅氧烷(10%溶胶) | 0.20% |
阴离子氟表面活性剂(10%) | 0.15% |
苯乙烯丙烯酸聚合物 | 4.26% |
氧化聚乙烯蜡 | 0.60% |
用供试溶液处理每种地板基材的6”×6”样品,所述供试溶液以每1平方英尺地板材料以2g产品的比率施加。施加供试溶液5次,以确保足够材料留在地板上以实现该测试。第5次施加后,测试前,允许地板材料固化1周。对以下3种NORA橡胶样品进行了测试:Noraplan Valua、Norament Hammered和Norament Grano。还对两种乙烯基树脂片材样品进行了测试:Johnsonite Melodia Quartz和Mannington Biospec Bright White。此外,对6种Forbo油毡样品进行了测试:Modular T3233、MCT-621、Concrete 3707、Real 3136、Piano3629和Striato 5216。
根据ASTM D3359,使用多层刻划工具,以交叉网状图案切割/刻话固化的涂层,将胶带施加到刻划的区域,并将胶带从面板快速拉下。根据胶带移除多少涂料,依据评分0-5目视评定组合物与地板的黏附,值5为因无涂层损耗而完全粘附,值4为涂层损耗小于5%,并且值3为涂层损耗5-15%。该测试在地板材料干燥的情况下进行,并允许水在刻划地板之前和之后静置在地板上。结果示于表19。
表19
表19表明,本发明将按照认为与施加地板涂料到地板上之时所需方式相当的方式粘附到乙烯基树脂片材、油毡和一些橡胶地板材料上,而市场上可获得的现有产品则不会。本领域技术人员众所周知,在潮湿条件下测试时,施加至地板基材上的薄膜经常部分地(若非完全地)被移除,尤其视为并非半永久或永久的涂料。
实施例7
实施例7测定了实施例5中配方的接触角。使用具有液滴形状分析软件的FTA200接触角测角仪,通过测量清洁溶液的液滴与面板表面相交处的角度,测定接触角。比照从Ecolab Inc.(明尼苏达州圣保罗)可商业获得的高性能中性地板清洁剂HP Neutral测试实验性配方。结果示于表20。
表20
接触角 | ||||||
初次 | 1秒 | 6秒 | 11秒 | 16秒 | 21秒 | |
HP Neutral | 38.98 | 38.66 | 38.5 | 38.34 | 38.38 | 37.27 |
配方E | 37.62 | 36.49 | 37.35 | 35.67 | 36.49 | 35.72 |
配方A | 39.52 | 39.32 | 38.19 | 38.88 | 38.67 | 38.25 |
配方D | 38.07 | 38.07 | 36.26 | 36.07 | 36.03 | 36.25 |
配方C | 42.97 | 43.15 | 43.75 | 43.55 | 43.15 | 42.97 |
表20表明,本发明将有效地润湿表面,可比于(如果不优于)既有的地板清洁剂。经验法则是,小于90o的实测接触角表示溶液有效地润湿了表面,并且实测接触角超过5度的差异视为表明真实和可观察润湿差异的显著差异。
实施例8
实施例8测定了反射比变化百分比。反射率变化百分比是移除多少污垢的指标;值越高,污垢移除和清洁性能越好。通过比较如借助Hunter MiniScan仪器测量的清洁之前和之后面板的L*的复合色号,确定反射比变化百分比。将测试的配方与作为空白的普通水以及与市售高性能中性地板清洁剂HP Neutral比较。下表21中列出了测试的配方:
表21
结果示于表22和表23。
表22
表23
表22和表23的结果表明,本发明比普通水明显更好地移除工业标准黑色污垢,并且与确立的中性地板清洁剂相当。
实施例9
实施例9显示了用标准地板清洁剂清洁地板时本发明的可移除性。将清洁剂施加在面板上,接触时间不定,并用纸巾轻轻擦拭面板,以确定是否发生任何移除。结果列于表24。
表24
来自表24的结果显示了使用标准清洁剂化学物质从地板上移除本发明的能力。
尽管已经描述了所公开的组成和方法的某些实施方案,但是可以存在其他实施方案。尽管说明书包括发明详述,但本发明的范围由后续权利要求指示。此外,尽管已经以专用于结构特征和/或方法学措施的语言描述了本说明书,但是权利要求不限于上述特征或措施。相反,上述专用特征和措施作为组合物和方法的说明性方面和实施方案公开。阅读本文中的描述之后,各种其他方面、实施方案、修改及其等同物可以本身启发本领域技术人员,而不背离本发明的精神或者要求保护的主题的范围。
Claims (30)
1.一种用于具有不可移除涂层的地板的地板护理组合物,组合物包含:
约1至约8重量%的树脂;
约0.02至约40重量%的表面活性剂;和
稀释剂。
2.根据权利要求1所述的组合物,还包含约0.1至约2重量%的蜡。
3.根据权利要求2所述的组合物,其中蜡是聚乙烯蜡乳液。
4.根据权利要求1-3中任一项所述的组合物,其中树脂是丙烯酸共聚物乳液。
5.根据权利要求1-4中任一项所述的组合物,其中表面活性剂是脂肪醇乙氧基化物。
6.根据权利要求1-5中任一项所述的组合物,其中稀释剂包括有机溶剂和水中的至少一种。
7.根据权利要求6所述的组合物,其中有机溶剂包括二醇醚。
8.根据权利要求1-7中任一项所述的组合物,其中表面活性剂充当增塑剂并且组合物不含其他增塑剂。
9.根据权利要求5所述的组合物,其中脂肪醇乙氧基化物以有效浓度存在,以在不存在其他增塑剂的情况下充当增塑剂。
10.根据权利要求5或9所述的组合物,其中脂肪醇乙氧基化物以组合物的约0.02至约25重量%存在。
11.根据权利要求5所述的组合物,其中脂肪醇乙氧基化物是Guerbet醇。
12.根据权利要求5所述的组合物,其中脂肪醇乙氧基化物是支链脂肪醇乙氧基化物。
13.根据权利要求1-12中任一项所述的组合物,其中组合物还包含约0.005至约0.5重量%的硅氧烷乳液。
14.根据权利要求1所述的组合物,其中表面活性剂是含氟表面活性剂。
15.根据权利要求1-14中任一项所述的组合物,其中组合物不含氨基甲酸酯类。
16.根据权利要求1-15中任一项所述的组合物,还包含水溶助长剂。
17.根据权利要求16所述的组合物,其中水溶助长剂占组合物的约0.005至约7%。
18.复原具有不可移除涂层的地板的方法,该方法包括:
将地板护理组合物施加到地板上,地板护理组合物包含:
蜡;
树脂;
一种或多种表面活性剂;和
稀释剂,
其中将地板护理组合物施加至地板不增加在60°测得的地板光泽度超过3分。
19.根据权利要求18所述的方法,其中10次连续施加后,将地板护理组合物施加至地板不增加在60°测得的地板光泽度超过5分。
20.根据权利要求19所述的方法,其中连续施加地板护理组合物是每天施加。
21.根据权利要求18-20中任一项所述的方法,其中方法不包括地板护理组合物的固化。
22.根据权利要求18-21中任一项所述的方法,其中地板护理组合物通过拖刷、刷涂、擦拭、喷洒、倾倒或用机器施加。
23.根据权利要求18-22中任一项所述的方法,其中所述地板包含聚氯乙烯、聚氨酯或UV涂布的聚氨酯的顶层。
24.根据权利要求18-23中任一项所述的方法,其中组合物提供临时涂层。
25.根据权利要求18-24中任一项所述的方法,其中地板护理组合物还包含蜡。
26.根据权利要求18-25中任一项所述的方法,其中稀释剂包含水。
27.根据权利要求26所述的方法,其中稀释剂进一步包含有机溶剂。
28.根据权利要求18-27中任一项所述的方法,其中组合物包含:
约0.001至约0.1重量%的聚乙烯蜡乳液;
约0.01至约0.5重量%的丙烯酸共聚物乳液;
约0.005至约0.5重量%的脂肪醇乙氧基化物;和
约0.001至约0.1重量%的二醇醚溶剂。
29.复原层压地板的方法,该方法包括:
将地板护理组合物施加到层压地板上,地板护理组合物包含:
蜡;
树脂;
一种或多种表面活性剂;
溶剂;和
水,
其中将地板护理组合物连续5次施加到层压地板上产生厚度小于2μm的层堆积。
30.清洁地板的方法,包括将组合物施加到地板上,组合物包含:
约0.001至约0.1重量%的聚乙烯蜡乳液;
约0.01至约0.5重量%的丙烯酸共聚物乳液;
约0.005至约0.5重量%的脂肪醇乙氧基化物;
约0.001至约0.1重量%的二醇醚溶剂;和
水。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762504869P | 2017-05-11 | 2017-05-11 | |
US62/504,869 | 2017-05-11 | ||
PCT/US2018/030658 WO2018208558A1 (en) | 2017-05-11 | 2018-05-02 | Compositions and method for floor cleaning or restoration |
Publications (1)
Publication Number | Publication Date |
---|---|
CN110573601A true CN110573601A (zh) | 2019-12-13 |
Family
ID=62223267
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201880028439.1A Pending CN110573601A (zh) | 2017-05-11 | 2018-05-02 | 用于地板清洁或复原的组合物和方法 |
Country Status (9)
Country | Link |
---|---|
US (3) | US10774292B2 (zh) |
EP (1) | EP3635084A1 (zh) |
JP (1) | JP7144447B2 (zh) |
CN (1) | CN110573601A (zh) |
AU (1) | AU2018266305B2 (zh) |
BR (1) | BR112019022571B1 (zh) |
MA (1) | MA49244A (zh) |
MX (1) | MX2019013420A (zh) |
WO (1) | WO2018208558A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115489184A (zh) * | 2022-03-15 | 2022-12-20 | 中国辐射防护研究院 | 一种防氚耐磨增强高分子复合材料及其制备方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2018266305B2 (en) * | 2017-05-11 | 2024-03-21 | Ecolab Usa Inc. | Compositions and method for floor cleaning or restoration |
US20220290007A1 (en) * | 2021-03-12 | 2022-09-15 | Parasol Medical, Llc | Floor coating composition with organosilane quaternary ammonium ion or salt thereof and method of imparting floor base with antimicrobial properties with the floor coating composition |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1528592A (en) * | 1974-12-10 | 1978-10-11 | Procter & Gamble | Floor care and cleaning composition |
US4376175A (en) * | 1980-06-04 | 1983-03-08 | Airwick Industries, Inc. | Floor care compositions |
EP0122788A2 (en) * | 1983-04-19 | 1984-10-24 | Rohm And Haas Company | Self-leveling polish compositions and polymer compositions useful therein |
US4725319A (en) * | 1985-09-20 | 1988-02-16 | Henkel Kommanditgesellschaft Auf Aktien | Cleaning preparations for hard surfaces |
WO1994020595A1 (de) * | 1993-03-05 | 1994-09-15 | Henkel Kommanditgesellschaft Auf Aktien | Fussbodenreinigungsmittel |
US5753604A (en) * | 1993-10-14 | 1998-05-19 | Henkel Kommanditgesellschaft Auf Aktien | Water-containing floor cleaning composition |
JP2001131495A (ja) * | 1999-08-26 | 2001-05-15 | Kao Corp | 床用処理剤 |
CN1491265A (zh) * | 2001-02-05 | 2004-04-21 | 3M | 抛光组合物中有机硅表面活性剂的使用 |
CN103509654A (zh) * | 2012-06-27 | 2014-01-15 | 罗门哈斯公司 | 用于清洁和涂覆硬表面的无条纹制剂 |
US20160185997A1 (en) * | 2009-07-16 | 2016-06-30 | James H. Gaston | Protective coating compositions |
Family Cites Families (196)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2903486A (en) | 1959-09-08 | Karl h | ||
NL272723A (zh) | 1951-05-31 | |||
US2674619A (en) | 1953-10-19 | 1954-04-06 | Wyandotte Chemicals Corp | Polyoxyalkylene compounds |
US3048548A (en) | 1959-05-26 | 1962-08-07 | Economics Lab | Defoaming detergent composition |
US3356612A (en) | 1965-02-01 | 1967-12-05 | Petrolite Corp | Stable detergent compositions |
US3979487A (en) | 1972-10-02 | 1976-09-07 | M. Lowenstein & Sons, Inc. | Process for manufacturing a foamed resin article having a flocked three dimensional surface design |
US3956779A (en) | 1974-12-16 | 1976-05-18 | Jewett Harold A | Tippable sunken baffles for diver protection in pools |
GB1489635A (en) | 1975-03-03 | 1977-10-26 | Toyo Seikan Kaisha Ltd | Packaging materials |
US4449764A (en) | 1975-08-07 | 1984-05-22 | Transaction Security, Inc. | Data processing equipment enclosures |
US4589712A (en) | 1977-08-25 | 1986-05-20 | Hastings Otis | Data processing equipment enclosures |
US4172064A (en) | 1977-08-30 | 1979-10-23 | Claremont Polychemical Corporation | Printing ink copolymers |
JPS5559955A (en) | 1978-10-30 | 1980-05-06 | Dainippon Ink & Chemicals | Interior finish material with uneven pattern that is excellent in tobacco fire resisting property |
DE2920525A1 (de) | 1979-05-21 | 1980-12-04 | Bayer Ag | Verfahren zur herstellung von polyadditionsprodukten aus isocyanaten und denaturierten biomassen sowie deren verwendung als reaktiver fuellstoff und als pflanzennaehrstoffe und verfahren zur herstellung von platten oder formteilen unter verwendung der polyadditionsprodukte |
US5111627A (en) | 1984-01-03 | 1992-05-12 | Brown John G | Modular-accessible-units |
US4692364A (en) | 1985-11-12 | 1987-09-08 | The 2500 Corporation | Retainer for automotive floor mat |
US4674745A (en) | 1986-01-21 | 1987-06-23 | Amf Bowling Companies Inc. | Bowling lane surface |
US4784908A (en) | 1986-03-25 | 1988-11-15 | Nevamar Corporation | Static dissipative laminate for work surfaces |
US4835030A (en) | 1987-10-14 | 1989-05-30 | C. H. Masland & Sons | In situ pattern molding and adhesion of PVC heel pad blanks to automotive carpeting without dielectric means |
US5314554A (en) | 1988-04-05 | 1994-05-24 | Owens Charles R | Method for producing a laminated tile product |
US5062913A (en) | 1988-04-05 | 1991-11-05 | Charles R. Owens | Laminated tile product and method for producing the same |
US5208086A (en) | 1988-04-05 | 1993-05-04 | Owens Charles R | Laminated tile product, method for producing the same and method for installing the same |
DE3813435A1 (de) | 1988-04-21 | 1989-11-02 | Siemens Ag | Bauelement in chip-bauweise zum befestigen auf einer schaltplatte, mit einem elektrischen oder elektronischen funktionskoerper |
US5030488A (en) | 1988-11-23 | 1991-07-09 | Chemical And Polymer Technology, Inc. | Laminates, panels and means for joining them |
US5257159A (en) | 1989-05-26 | 1993-10-26 | Loral Vought Systems Corporation | Electronically monitored and controlled electrostatic discharge flooring system |
US5317476A (en) | 1989-05-26 | 1994-05-31 | Loral Vought Systems Corporation | Electronically monitored and controlled electrostatic discharge flooring system |
DE3937718A1 (de) | 1989-11-13 | 1991-05-16 | Henkel Kgaa | Mopbezug mit einer tasche und einer lasche |
US5093958A (en) | 1990-05-30 | 1992-03-10 | Lloyd Levine | Automobile floor mat anchoring system |
DE4025646A1 (de) | 1990-08-14 | 1992-02-20 | Henkel Kgaa | Wischbezug mit haltereinfuehrhilfe |
US5271200A (en) | 1990-11-05 | 1993-12-21 | Permagrain Products, Inc. | Title display system |
US5244721A (en) | 1990-12-10 | 1993-09-14 | Nevamar Corporation | Static dissipative laminate containing stainless steel fibers |
US7481453B2 (en) | 1991-07-09 | 2009-01-27 | Automotive Technologies International, Inc. | Inflator system |
US5830937A (en) | 1992-02-04 | 1998-11-03 | Congoleum Corporation | Coating and wearlayer compositions for surface coverings |
US5254798A (en) | 1992-07-13 | 1993-10-19 | Warminster Fiberglass Company | Secondary containment structures for hazardous materials |
US5596912A (en) | 1993-08-12 | 1997-01-28 | Formica Technology, Inc. | Press plate having textured surface formed by simultaneous shot peening |
DE4330493C2 (de) | 1993-09-09 | 1996-07-25 | Henkel Ecolab Gmbh & Co Ohg | Wischbezug für die Reinigung von Fußböden |
US5573088A (en) | 1994-05-10 | 1996-11-12 | Daniels; John J. | Controllable resistance device and force dampener, and vehicle utilizing the same |
US5653494A (en) | 1994-06-29 | 1997-08-05 | Transmaster Technologies Inc. | Modular sport, work, and travel trailer system |
JPH0834089A (ja) | 1994-07-25 | 1996-02-06 | Lintec Corp | 制振シート |
DK0788328T3 (da) | 1994-10-26 | 1999-08-23 | Henkel Ecolab Gmbh & Co Ohg | Fladt rengøringsbetræk til rengøring af gulve |
US5509715A (en) | 1995-04-17 | 1996-04-23 | Scharpf; Mike A. | Protected flooring |
US6126132A (en) | 1995-04-28 | 2000-10-03 | Lear Automotive Dearborn, Inc. | Multi-function single motor seat track actuator assembly |
US5891564A (en) | 1995-06-07 | 1999-04-06 | Mannington Mills, Inc. | Decorative surface coverings |
US5749993A (en) | 1996-02-01 | 1998-05-12 | Foamex L.P. | Method of making an automotive carpeting with precut conforming foam underlayment |
US5645279A (en) | 1996-05-20 | 1997-07-08 | Reutlinger; Alicia L. | Vehicle history and trivia race game |
JP2001521840A (ja) | 1997-11-03 | 2001-11-13 | ラファエル ヘイフェツ | 構造物表面用密閉シートアセンブリおよびその製造並びに適用方法 |
US6079182A (en) | 1997-11-05 | 2000-06-27 | Ellenberger; Jack Richard | Floor panel compressing apparatus and method |
US6345481B1 (en) | 1997-11-25 | 2002-02-12 | Premark Rwp Holdings, Inc. | Article with interlocking edges and covering product prepared therefrom |
US6324809B1 (en) | 1997-11-25 | 2001-12-04 | Premark Rwp Holdings, Inc. | Article with interlocking edges and covering product prepared therefrom |
JPH11217541A (ja) * | 1998-02-05 | 1999-08-10 | Lion Corp | つや出し剤組成物 |
JPH11217545A (ja) * | 1998-02-05 | 1999-08-10 | Lion Corp | 床用つや出し剤組成物 |
US6182128B1 (en) | 1998-03-05 | 2001-01-30 | Touchmusic Entertainment Llc | Real-time music distribution systems |
SE513189C2 (sv) | 1998-10-06 | 2000-07-24 | Perstorp Flooring Ab | Vertikalmonterbart golvbeläggningsmaterial innefattande skivformiga golvelement vilka sammanfogas med hjälp av separata sammanfogningsprofiler |
US6090437A (en) | 1998-11-20 | 2000-07-18 | Rafter; Thomas | Floor repair method |
US6413618B1 (en) | 1999-05-11 | 2002-07-02 | Congoleum Corporation | Laminated glass floor tile and flooring made therefrom and method for making same |
AU5871500A (en) | 1999-06-11 | 2001-01-02 | Sydney Hyman | Image making medium |
US6804923B1 (en) | 1999-07-02 | 2004-10-19 | John Potter | Prefabricated modular deck system |
US6287681B1 (en) | 1999-07-20 | 2001-09-11 | The Mead Corporation | Preparation of wear-resistant laminates using mineral pigment composites |
DE60008383T2 (de) | 1999-07-23 | 2004-12-23 | Cryovac, Inc. | Schutzmehrschichtwerkstoff für kraftfahrzeugteppiche |
US6131983A (en) | 1999-08-18 | 2000-10-17 | Jackson; William T. | Truck bed utility tarpaulin |
JP3913418B2 (ja) | 1999-09-27 | 2007-05-09 | 花王株式会社 | 床用処理剤 |
US7614197B2 (en) | 1999-11-08 | 2009-11-10 | Premark Rwp Holdings, Inc. | Laminate flooring |
US6460306B1 (en) | 1999-11-08 | 2002-10-08 | Premark Rwp Holdings, Inc. | Interconnecting disengageable flooring system |
US6863768B2 (en) | 1999-11-08 | 2005-03-08 | Premark Rwp Holdings Inc. | Water resistant edge of laminate flooring |
US6449918B1 (en) | 1999-11-08 | 2002-09-17 | Premark Rwp Holdings, Inc. | Multipanel floor system panel connector with seal |
US6627704B2 (en) | 1999-12-01 | 2003-09-30 | General Electric Company | Poly(arylene ether)-containing thermoset composition, method for the preparation thereof, and articles derived therefrom |
US6812276B2 (en) | 1999-12-01 | 2004-11-02 | General Electric Company | Poly(arylene ether)-containing thermoset composition, method for the preparation thereof, and articles derived therefrom |
SE522860C2 (sv) | 2000-03-10 | 2004-03-09 | Pergo Europ Ab | Vertikalt förenade golvelement innefattande en kombination av olika golvelement |
DE10012949A1 (de) | 2000-03-16 | 2001-09-27 | Henkel Kgaa | Kieselsäureester-Mischungen |
JP2001295454A (ja) | 2000-04-07 | 2001-10-26 | Three M Innovative Properties Co | 接着シートおよび床面被覆構造体 |
US6230418B1 (en) | 2000-04-26 | 2001-05-15 | Dennis R. Gomulinski | Low profile dryer exhaust vent system |
DE10029694A1 (de) | 2000-06-16 | 2001-12-20 | Basf Ag | Verwendung eines polymeren Umsetzungsprodukts |
JP2002065825A (ja) | 2000-08-30 | 2002-03-05 | Kao Corp | 床処理剤組成物 |
US7144625B2 (en) | 2000-09-06 | 2006-12-05 | George Tunis | Wire reinforced thermoplastic coating |
AU2002239731A1 (en) | 2000-11-13 | 2002-06-03 | Imaging Alternatives, Inc. | Wood surface inkjet receptor medium and method of making and using same |
US6485094B2 (en) | 2000-12-06 | 2002-11-26 | Asc Incorporated | Automotive vehicle open air system |
US6625937B1 (en) | 2000-12-27 | 2003-09-30 | Sunrise Holding, Ltd. | Modular building and method of construction |
US6673097B1 (en) | 2001-02-23 | 2004-01-06 | Hollywood Tanning Systems, Inc. | Tanning booth having reduced tanning time |
US8382004B2 (en) | 2001-04-04 | 2013-02-26 | Graftech International Holdings Inc. | Flexible graphite flooring heat spreader |
US7785098B1 (en) | 2001-06-05 | 2010-08-31 | Mikro Systems, Inc. | Systems for large area micro mechanical systems |
US8071491B2 (en) | 2001-11-07 | 2011-12-06 | FledForm Technologies, LLC | Process, composition and coating of laminate material |
US8012889B2 (en) | 2001-11-07 | 2011-09-06 | Flexform Technologies, Llc | Fire retardant panel composition and methods of making the same |
US8158539B2 (en) | 2001-11-07 | 2012-04-17 | Flexform Technologies, Llc | Heat deflection/high strength panel compositions |
US20030108718A1 (en) | 2001-12-07 | 2003-06-12 | Jean-Yves Simon | Polyurethane coated resilient surface covering having improved fidelity of texture and process of manufacture |
US7013609B2 (en) | 2002-03-01 | 2006-03-21 | Hydock Gary J | Modular radiant heat panel system |
DE20220655U1 (de) | 2002-04-04 | 2004-01-08 | Akzenta Paneele + Profile Gmbh | Paneel sowie Verriegelungssystem für Paneele |
CA2486862C (en) | 2002-05-30 | 2011-08-09 | Nexicor Llc | Induction seaming tapes, systems and methods |
US7108914B2 (en) | 2002-07-15 | 2006-09-19 | Motorola, Inc. | Self-healing polymer compositions |
DE10233731A1 (de) | 2002-07-24 | 2004-04-08 | M. Kaindl | Anordnung von Bauteilen mit Verbindungselementen |
US6949274B2 (en) | 2002-07-31 | 2005-09-27 | Premark Rwp Holdings, Inc. | Packaging systems and methods for applying sealant to panels |
US6685388B2 (en) | 2002-08-05 | 2004-02-03 | The United States Of America As Represented By The Secretary Of The Army | Multi-purpose mat |
CA2508918A1 (en) | 2002-12-18 | 2004-07-08 | Johnsondiversey, Inc. | Ultra-thin surface modification system |
US7320739B2 (en) | 2003-01-02 | 2008-01-22 | 3M Innovative Properties Company | Sound absorptive multilayer composite |
US7243513B2 (en) | 2003-01-14 | 2007-07-17 | Milliken & Company | Patterned textile product |
WO2005021634A2 (en) | 2003-02-20 | 2005-03-10 | Texas Research International, Inc. | Ultraviolet light curing compositions for composite repair |
US7240951B2 (en) | 2003-03-05 | 2007-07-10 | Intier Automotive Inc. | Visor assembly with integrated storage receptacles |
JP4291051B2 (ja) | 2003-06-17 | 2009-07-08 | ジョンソンディバーシー株式会社 | 床面用洗浄剤組成物およびそれを用いた床面洗浄方法 |
US6762162B1 (en) * | 2003-06-18 | 2004-07-13 | S. C. Johnson & Son, Inc. | Disinfecting cationic polymer cleaner comprising an acrylate cationic polymer |
US8932632B2 (en) | 2003-10-21 | 2015-01-13 | Ppg Industries Ohio, Inc. | Adhesives and sealants nanotechnology |
US8734263B2 (en) | 2004-04-01 | 2014-05-27 | Qubicaamf Worldwide Llc | Flooring system for bowling alley |
CA2505357C (en) | 2004-05-05 | 2008-07-29 | Blair Farrend | Floor bracket |
US7702113B1 (en) | 2004-09-01 | 2010-04-20 | Richard Rives Bird | Parametric adaptive room compensation device and method of use |
US7282264B2 (en) | 2004-10-08 | 2007-10-16 | W.F. Taylor Co., Inc. | Composition and method for controlling moisture |
US20080090477A1 (en) | 2004-12-17 | 2008-04-17 | Balthes Garry E | Fire Retardant Panel Composition and Methods of Making the Same |
US7906176B2 (en) | 2004-12-17 | 2011-03-15 | Flexform Technologies, Llc | Methods of manufacturing a fire retardant structural board |
US7597373B2 (en) | 2005-01-28 | 2009-10-06 | Mcauliffe Jr John Joseph | Flexible adjustable cargo area liner for station wagons, minivans and sport utility vehicles |
US7045706B1 (en) | 2005-02-23 | 2006-05-16 | Tyco Electronics Corporation | Flush floor service hideaway universal box assembly |
JP4667127B2 (ja) | 2005-06-09 | 2011-04-06 | 花王株式会社 | つや出し清掃物品 |
US7246839B1 (en) | 2005-06-17 | 2007-07-24 | Nyberg Donald E | Hard tonneau cover with carrying rack |
US7799943B2 (en) | 2005-06-24 | 2010-09-21 | Rohm And Haas Company | Method for promoting Michael addition reactions |
US7908810B2 (en) | 2005-06-30 | 2011-03-22 | United States Gypsum Company | Corrugated steel deck system including acoustic features |
EP1907202B1 (en) | 2005-07-01 | 2016-01-20 | Carolyn M. Dry | Multiple function, self-repairing composites with special adhesives |
US8716220B2 (en) | 2005-09-07 | 2014-05-06 | Nikolaos Tezapsidis | Leptin compositions and methods for treating progressive cognitive function disorders resulting from accumulation of neurofibrillary tangles and amyloid beta |
BE1016846A3 (nl) | 2005-11-09 | 2007-08-07 | Flooring Ind Ltd | Vloerbekleding, vloerpanelen en werkwijze voor het vervaardigen van vloerpanelen. |
US8021014B2 (en) | 2006-01-10 | 2011-09-20 | Valinge Innovation Ab | Floor light |
US8360362B2 (en) | 2006-02-21 | 2013-01-29 | The Boeing Company | Aircraft floor and method of assembly |
US8529646B2 (en) | 2006-05-01 | 2013-09-10 | Lpp Combustion Llc | Integrated system and method for production and vaporization of liquid hydrocarbon fuels for combustion |
EP2029680A4 (en) * | 2006-05-02 | 2010-10-20 | Whiteley Corp Pty Ltd | SAFETY COVERS |
US7886488B2 (en) | 2006-06-19 | 2011-02-15 | United States Gypsum Company | Acoustical isolation floor underlayment system |
DE102006035647A1 (de) | 2006-07-31 | 2008-02-07 | Kaindl Flooring Gmbh | Vorrichtung zum Herstellen oder/und Bearbeiten von Paneelen |
US7793483B2 (en) | 2006-09-18 | 2010-09-14 | Pergo AG | Ventilated floor moldings |
US8210126B2 (en) | 2006-12-01 | 2012-07-03 | Yik Hei Sia | Swiftlets farming for production of edible bird's nests |
JP5308039B2 (ja) | 2007-02-20 | 2013-10-09 | 富士フイルム株式会社 | 紫外線吸収剤を含む高分子材料 |
US9278478B2 (en) | 2007-04-05 | 2016-03-08 | Curtis Goad | Methods and apparatus for lining process tanks |
US8382033B2 (en) | 2007-05-21 | 2013-02-26 | Gary Thomas Reece | Ballistic resistant and explosive containment systems for aircraft |
US7665272B2 (en) | 2007-06-20 | 2010-02-23 | Reen Michael J | Floor hole repair method |
US7810453B2 (en) | 2007-07-26 | 2010-10-12 | Raymond Craft | Poultry flooring system |
WO2009022736A1 (ja) | 2007-08-16 | 2009-02-19 | Fujifilm Corporation | ヘテロ環化合物、紫外線吸収剤及びこれを含む組成物 |
PL2602077T3 (pl) | 2007-11-19 | 2017-12-29 | Välinge Innovation AB | Odzyskiwanie laminowanych podłóg |
US7712199B1 (en) | 2007-11-29 | 2010-05-11 | George Wilson | Portable apparatus for installing floor boards and associated method |
WO2009085684A1 (en) | 2007-12-20 | 2009-07-09 | Mannington Mills, Inc. | Dual-edge irregular bevel-cut system and method |
WO2009129265A1 (en) | 2008-04-14 | 2009-10-22 | Huntington Medical Research Institutes | Methods and apparatus for pasadena hyperpolarization |
US8286919B2 (en) | 2008-05-13 | 2012-10-16 | The Boeing Company | Impact resistant composite structures |
US9072292B2 (en) | 2008-06-06 | 2015-07-07 | T. Brian Cavitt | Biofilm resistant polymer materials |
JP5422161B2 (ja) | 2008-09-24 | 2014-02-19 | 花王株式会社 | ワックス処理された床の処理方法 |
JP5260210B2 (ja) | 2008-09-24 | 2013-08-14 | 花王株式会社 | 床用つや出し洗浄剤組成物 |
EP2559535A3 (en) | 2008-09-26 | 2016-09-07 | Mikro Systems Inc. | Systems, devices, and/or methods for manufacturing castings |
US8342283B2 (en) | 2008-09-29 | 2013-01-01 | Deakin University | Pneumatic powertrain for an automotive vehicle |
US8317257B2 (en) | 2008-09-29 | 2012-11-27 | Deakin University | Body for pneumatic vehicle |
US8313121B2 (en) | 2008-09-29 | 2012-11-20 | Deakin University | Chassis for pneumatic vehicle |
PT2411423E (pt) | 2009-03-27 | 2015-09-10 | Henkel Ag & Co Kgaa | Adesivos fabricados a partir de sistemas de polímeros |
WO2010124003A1 (en) | 2009-04-22 | 2010-10-28 | W.F. Taylor Co., Inc. | Carrier-free adhesive film |
MX2011011330A (es) | 2009-04-27 | 2011-11-18 | Mohawk Carpet Corp | Sistemas de entarimado y metodos para elaborar y utilizar los mismos. |
US8613166B2 (en) | 2009-05-13 | 2013-12-24 | The David S. Smith Irrevocable Trust | Collapsible temporary housing system stackable upon others for transport |
GB0908375D0 (en) | 2009-05-15 | 2009-06-24 | Element Six Ltd | A super-hard cutter element |
US9303403B2 (en) | 2009-06-26 | 2016-04-05 | Joel W. Bolin | Composite panels and methods and apparatus for manufacture and installtion thereof |
US8298650B2 (en) | 2009-09-26 | 2012-10-30 | Gip International Limited | Hollow base decorative surface covering |
US8206511B2 (en) | 2009-10-06 | 2012-06-26 | Ecolab Usa Inc. | Daily cleaner with slip-resistant and gloss-enhancing properties |
US8429870B2 (en) | 2009-12-04 | 2013-04-30 | Mannington Mills, Inc. | Connecting system for surface coverings |
CN101881076B (zh) | 2010-06-09 | 2014-07-09 | 黄焕文 | 一种方便铺的组合式地板 |
US8833028B2 (en) | 2010-01-11 | 2014-09-16 | Valinge Innovation Ab | Floor covering with interlocking design |
US9248468B2 (en) | 2010-01-15 | 2016-02-02 | Texas Research International, Inc. | Ultraviolet light curing compositions for composite repair |
US8375668B2 (en) | 2010-01-20 | 2013-02-19 | Robert Paul Kuepfer | Seal guard lip and tape systems |
US8394217B2 (en) | 2010-04-29 | 2013-03-12 | Advance Vinyl Floor Manufacturing Corp. | Method and apparatus for floor planks |
US8156710B1 (en) | 2010-11-19 | 2012-04-17 | Advance Vinyl Floor Manufacturing Corp. | Method and apparatus for floor tiles and planks |
US8791185B2 (en) | 2010-06-21 | 2014-07-29 | Basf Se | 2-ethylhexyl methyl terephthalate as plasticizer in adhesives and sealants |
US8347575B2 (en) | 2010-09-02 | 2013-01-08 | United States Gypsum Company | Lightweight acoustical flooring underlayment |
US8434738B1 (en) | 2010-09-13 | 2013-05-07 | Powernail Company | Flooring installation tool |
US8703275B2 (en) | 2011-06-21 | 2014-04-22 | Gip International Limited | Adhesiveless decorative floor tile |
US8512848B2 (en) | 2010-09-16 | 2013-08-20 | Gip International Limited | Adhesiveless decorative floor tile |
US9023591B2 (en) | 2010-09-30 | 2015-05-05 | Chemence, Inc. | Inkjet printable flexography substrate and method of using |
BR112013014595B1 (pt) | 2010-12-13 | 2021-01-26 | Ecolab Usa Inc. | composição de limpeza, método para limpar uma superfície dura de piso e kit |
US8475928B2 (en) | 2011-01-31 | 2013-07-02 | Neocantera Board S.A. De C.V. | Rock sheet and plate mix based on volcanic rock particles useful for building and decoration |
US8806832B2 (en) | 2011-03-18 | 2014-08-19 | Inotec Global Limited | Vertical joint system and associated surface covering system |
CN103459144B (zh) | 2011-04-19 | 2015-06-17 | F顾问株式会社 | 层叠体 |
US8881476B2 (en) | 2011-04-25 | 2014-11-11 | BTU Comfort Systems, LLC. | Panels having multiple channel structures |
ES2745641T3 (es) | 2011-05-16 | 2020-03-03 | Diversified Foam Products Inc | Sistema de entarimado con losetas de vinilo de lujo |
US9155310B2 (en) | 2011-05-24 | 2015-10-13 | Agienic, Inc. | Antimicrobial compositions for use in products for petroleum extraction, personal care, wound care and other applications |
EA025752B1 (ru) | 2011-06-10 | 2017-01-30 | Акцо Нобель Кемикалз Интернэшнл Б.В. | Способ и добавка для повышения адгезии композиций к основам |
TWI415572B (zh) | 2011-06-17 | 2013-11-21 | Univ Chang Gung | 利用1,2,3,4,6-五-o-沒食子醯基-d-葡哌喃糖來抑制生物膜形成 |
US9399865B2 (en) | 2011-06-29 | 2016-07-26 | Worksafe Technologies | Seismic isolation systems |
EP3552784B1 (en) | 2011-08-29 | 2024-04-10 | Ceraloc Innovation AB | Mechanical locking system for floor panels |
US9358754B2 (en) | 2011-09-06 | 2016-06-07 | Afi Licensing Llc | Dimensionally stable product and process of fabricating a dimensionally stable product |
US8729213B2 (en) | 2011-09-23 | 2014-05-20 | Air Products And Chemicals, Inc. | Benzylated polyamine curing agents |
US8650824B2 (en) | 2011-12-06 | 2014-02-18 | Johnsonite Inc. | Interlocking floor tile |
EP2820202B1 (en) | 2012-02-23 | 2018-10-31 | Armstrong World Industries, Inc. | Floating floor system, floor panel, and installation method for the same |
US8609884B2 (en) | 2012-03-19 | 2013-12-17 | Awi Licensing Company | Biobased plasticizer and surface covering employing same |
US8974003B2 (en) | 2012-03-30 | 2015-03-10 | Toyota Motor Engineering & Manufacturing North America, Inc. | Rear seat cushion sound reduction mat |
AU2013245653B2 (en) | 2012-04-13 | 2016-02-11 | Armstrong World Industries, Inc. | Floating floor system, floor panel, and installation method for the same |
US8985820B2 (en) | 2012-08-10 | 2015-03-24 | GM Global Technology Operations LLC | Lighted vehicle interior accessory assembly and method |
US8776698B2 (en) | 2012-10-08 | 2014-07-15 | Advanced Composite Structures, Llc | Composite air cargo pallet |
US9409382B2 (en) | 2012-11-28 | 2016-08-09 | Valinge Innovation Ab | Method of producing a building panel |
US9375750B2 (en) | 2012-12-21 | 2016-06-28 | Valinge Photocatalytic Ab | Method for coating a building panel and a building panel |
RU2640615C2 (ru) | 2013-01-11 | 2018-01-10 | Флоринг Индастриз Лимитед, Сарл | Панель пола для образования покрытия пола, покрытие пола, образованное такими панелями пола, и способ изготовления таких панелей пола |
US20140199495A1 (en) | 2013-01-11 | 2014-07-17 | Floor Iptech Ab | Digital printing and embossing |
US8800245B1 (en) | 2013-03-27 | 2014-08-12 | Advancecd Vinyl Floor Manufacturing Corp. | Method and apparatus for floor tiles and planks |
US9151066B1 (en) | 2013-04-10 | 2015-10-06 | Fix-A-Floor Worldwide, Inc. | Apparatus and method to fix a floor |
MX2015014620A (es) | 2013-04-22 | 2016-03-01 | Ethox Chemicals Llc | Aditivos para composiciones de resina para mejorar la resistencia al impacto y la flexibilidad. |
US9415565B2 (en) | 2013-08-13 | 2016-08-16 | Pak-Lite, Inc. | Underlayment with of non-woven polyethylene mesh |
US9109108B1 (en) | 2013-08-13 | 2015-08-18 | Pak-Lite, Inc. | LVT flooring and underlayment including extruded sheet material with expanded microspheres |
US9169659B1 (en) | 2013-08-13 | 2015-10-27 | Pak-Lite, Inc. | Underlayment including extruded sheet material with expanded microspheres and metalized PET film |
US9290936B2 (en) | 2014-02-10 | 2016-03-22 | Sico Incorporated | Portable floor |
US9309183B2 (en) | 2014-02-20 | 2016-04-12 | Basf Corporation | Plasticizer composition comprising di(2-ethylhexyl) terephthalate |
US9260870B2 (en) | 2014-03-24 | 2016-02-16 | Ivc N.V. | Set of mutually lockable panels |
US9249582B1 (en) | 2014-11-14 | 2016-02-02 | Awi Licensing Company | Interlocking floor panels with high performance locking profiles |
US10676621B2 (en) * | 2016-03-04 | 2020-06-09 | S. C. Johnson & Son, Inc. | Multi-purpose floor finish composition |
AU2018266305B2 (en) * | 2017-05-11 | 2024-03-21 | Ecolab Usa Inc. | Compositions and method for floor cleaning or restoration |
-
2018
- 2018-05-02 AU AU2018266305A patent/AU2018266305B2/en active Active
- 2018-05-02 WO PCT/US2018/030658 patent/WO2018208558A1/en unknown
- 2018-05-02 MX MX2019013420A patent/MX2019013420A/es unknown
- 2018-05-02 CN CN201880028439.1A patent/CN110573601A/zh active Pending
- 2018-05-02 US US15/969,015 patent/US10774292B2/en active Active
- 2018-05-02 EP EP18726636.6A patent/EP3635084A1/en active Pending
- 2018-05-02 JP JP2019561795A patent/JP7144447B2/ja active Active
- 2018-05-02 MA MA049244A patent/MA49244A/fr unknown
- 2018-05-02 BR BR112019022571-4A patent/BR112019022571B1/pt active IP Right Grant
-
2020
- 2020-08-12 US US16/991,433 patent/US11453844B2/en active Active
-
2022
- 2022-09-09 US US17/931,038 patent/US20230080941A1/en active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1528592A (en) * | 1974-12-10 | 1978-10-11 | Procter & Gamble | Floor care and cleaning composition |
US4376175A (en) * | 1980-06-04 | 1983-03-08 | Airwick Industries, Inc. | Floor care compositions |
EP0122788A2 (en) * | 1983-04-19 | 1984-10-24 | Rohm And Haas Company | Self-leveling polish compositions and polymer compositions useful therein |
US4725319A (en) * | 1985-09-20 | 1988-02-16 | Henkel Kommanditgesellschaft Auf Aktien | Cleaning preparations for hard surfaces |
WO1994020595A1 (de) * | 1993-03-05 | 1994-09-15 | Henkel Kommanditgesellschaft Auf Aktien | Fussbodenreinigungsmittel |
US5753604A (en) * | 1993-10-14 | 1998-05-19 | Henkel Kommanditgesellschaft Auf Aktien | Water-containing floor cleaning composition |
JP2001131495A (ja) * | 1999-08-26 | 2001-05-15 | Kao Corp | 床用処理剤 |
CN1491265A (zh) * | 2001-02-05 | 2004-04-21 | 3M | 抛光组合物中有机硅表面活性剂的使用 |
US20160185997A1 (en) * | 2009-07-16 | 2016-06-30 | James H. Gaston | Protective coating compositions |
CN103509654A (zh) * | 2012-06-27 | 2014-01-15 | 罗门哈斯公司 | 用于清洁和涂覆硬表面的无条纹制剂 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115489184A (zh) * | 2022-03-15 | 2022-12-20 | 中国辐射防护研究院 | 一种防氚耐磨增强高分子复合材料及其制备方法 |
CN115489184B (zh) * | 2022-03-15 | 2023-12-15 | 中国辐射防护研究院 | 一种防氚耐磨增强高分子复合材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
US10774292B2 (en) | 2020-09-15 |
BR112019022571A2 (pt) | 2020-05-19 |
US11453844B2 (en) | 2022-09-27 |
EP3635084A1 (en) | 2020-04-15 |
AU2018266305B2 (en) | 2024-03-21 |
MA49244A (fr) | 2020-04-15 |
US20230080941A1 (en) | 2023-03-16 |
WO2018208558A1 (en) | 2018-11-15 |
BR112019022571B1 (pt) | 2024-02-06 |
AU2018266305A1 (en) | 2019-11-14 |
MX2019013420A (es) | 2020-02-07 |
JP7144447B2 (ja) | 2022-09-29 |
JP2020519720A (ja) | 2020-07-02 |
US20210024854A1 (en) | 2021-01-28 |
US20180327694A1 (en) | 2018-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20230080941A1 (en) | Compositions and method for floor cleaning or restoration | |
JP4606585B2 (ja) | 濃縮剥離剤および方法 | |
EP1276839B1 (en) | Phase-separating solvent composition | |
US20040191484A1 (en) | Strippable laminate finish | |
JP5290762B2 (ja) | 有機酸系の一組を含む床剥離剤/清浄剤 | |
CN103069343A (zh) | 羧基酯缩酮除去组合物、其制造方法及应用 | |
TW201402807A (zh) | 用於清潔及塗覆硬表面之無痕製劑 | |
AU2001253778B2 (en) | Strippable laminate finish | |
JP2013531090A (ja) | 剥離用組成物、ならびにそれらの製造方法および使用方法 | |
CN101855306A (zh) | 化学耐***联地板面层的地板清除剂 | |
JP4318983B2 (ja) | 床用洗浄つや出し剤組成物 | |
JPH0710996B2 (ja) | 洗浄剤組成物 | |
US20120077045A1 (en) | Soil resistant cleaner and surface treatment | |
EP3802710B1 (en) | Strip free floor system | |
JPH08507319A (ja) | 床保護剤 | |
JP2002309127A (ja) | 光硬化型樹脂塗膜用剥離剤及び該光硬化型樹脂塗膜の剥離方法 | |
MXPA01003342A (es) | Metodo y composicion concentrada para despojar |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |