CN110328218A - 一种有机物污染盐渣的资源化利用方法 - Google Patents
一种有机物污染盐渣的资源化利用方法 Download PDFInfo
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- CN110328218A CN110328218A CN201910693761.2A CN201910693761A CN110328218A CN 110328218 A CN110328218 A CN 110328218A CN 201910693761 A CN201910693761 A CN 201910693761A CN 110328218 A CN110328218 A CN 110328218A
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- 150000003839 salts Chemical class 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000002893 slag Substances 0.000 title claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000005516 engineering process Methods 0.000 claims abstract description 26
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 20
- 239000002351 wastewater Substances 0.000 claims abstract description 18
- 238000002425 crystallisation Methods 0.000 claims abstract description 16
- 230000008025 crystallization Effects 0.000 claims abstract description 16
- 239000002699 waste material Substances 0.000 claims abstract description 13
- 230000000694 effects Effects 0.000 claims abstract description 12
- 239000012267 brine Substances 0.000 claims abstract description 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 6
- 239000007800 oxidant agent Substances 0.000 claims abstract description 3
- 230000001590 oxidative effect Effects 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 50
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 30
- 239000002101 nanobubble Substances 0.000 claims description 23
- 238000005189 flocculation Methods 0.000 claims description 20
- 230000016615 flocculation Effects 0.000 claims description 20
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 10
- -1 and treated Substances 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 238000004090 dissolution Methods 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000004062 sedimentation Methods 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000005188 flotation Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 239000005416 organic matter Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 239000010865 sewage Substances 0.000 claims description 5
- 238000007667 floating Methods 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 238000005265 energy consumption Methods 0.000 abstract description 6
- 238000006385 ozonation reaction Methods 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 239000003546 flue gas Substances 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 238000005979 thermal decomposition reaction Methods 0.000 description 5
- 239000002918 waste heat Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/14—Purification
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113828615A (zh) * | 2021-09-06 | 2021-12-24 | 浙江宜可欧环保科技有限公司 | 新型废盐处理*** |
CN114011852A (zh) * | 2021-09-18 | 2022-02-08 | 昆明市生态环境科学研究院 | 一种有机废弃物的无害盐化处理方法 |
CN114522443A (zh) * | 2022-04-22 | 2022-05-24 | 徐州宏武纳米科技有限公司 | 一种超声波震荡式纳米晶体萃取分离装置 |
CN114951237A (zh) * | 2022-05-09 | 2022-08-30 | 中南大学 | 一种微纳塑料的降解方法 |
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JP2010253457A (ja) * | 2009-04-21 | 2010-11-11 | Kansai Kako Kk | マイクロバブルやナノバブルなどの微細気泡を用いた膜ろ過装置の洗浄方法 |
CN103288236A (zh) * | 2013-05-27 | 2013-09-11 | 山东三维石化工程股份有限公司青岛分公司 | 含盐废水的处理方法 |
CN103922531A (zh) * | 2014-04-28 | 2014-07-16 | 江苏九九久科技股份有限公司 | 一种3,5,6-三氯吡啶-2-醇钠废水的处理方法 |
CN105668762A (zh) * | 2016-01-30 | 2016-06-15 | 清华大学 | 基于臭氧微纳米气泡的废水处理***及方法 |
CN105906149A (zh) * | 2016-06-02 | 2016-08-31 | 内蒙古君正氯碱化工技术研究院 | 一种氯碱厂浓盐水零排放的处理***及处理方法 |
CN107399871A (zh) * | 2017-09-13 | 2017-11-28 | 珠海市英翔建材有限公司 | 一种联合氧化的废水处理*** |
CN108275817A (zh) * | 2018-01-22 | 2018-07-13 | 浙江开创环保科技股份有限公司 | 一种高硬度高盐分废水资源化的处理方法 |
CN108640389A (zh) * | 2018-05-31 | 2018-10-12 | 同济大学 | 处理废水脱盐的方法及微纳米气泡-真空膜蒸馏耦合脱盐*** |
CN108751550A (zh) * | 2018-05-25 | 2018-11-06 | 中节能工程技术研究院有限公司 | 一种垃圾渗滤液尾水的处理方法及处理*** |
CN109231664A (zh) * | 2018-09-19 | 2019-01-18 | 河南慧锦药业有限公司 | 一种高含盐量和高cod制药废水的综合处理工艺 |
CN109550771A (zh) * | 2018-12-11 | 2019-04-02 | 中化环境控股有限公司 | 工业废盐中有机污染物的去除方法和去除装置 |
CN109970262A (zh) * | 2017-12-28 | 2019-07-05 | 江苏久吾高科技股份有限公司 | 一种中水零排放处理方法及装置 |
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JP2010253457A (ja) * | 2009-04-21 | 2010-11-11 | Kansai Kako Kk | マイクロバブルやナノバブルなどの微細気泡を用いた膜ろ過装置の洗浄方法 |
CN103288236A (zh) * | 2013-05-27 | 2013-09-11 | 山东三维石化工程股份有限公司青岛分公司 | 含盐废水的处理方法 |
CN103922531A (zh) * | 2014-04-28 | 2014-07-16 | 江苏九九久科技股份有限公司 | 一种3,5,6-三氯吡啶-2-醇钠废水的处理方法 |
CN105668762A (zh) * | 2016-01-30 | 2016-06-15 | 清华大学 | 基于臭氧微纳米气泡的废水处理***及方法 |
CN105906149A (zh) * | 2016-06-02 | 2016-08-31 | 内蒙古君正氯碱化工技术研究院 | 一种氯碱厂浓盐水零排放的处理***及处理方法 |
CN107399871A (zh) * | 2017-09-13 | 2017-11-28 | 珠海市英翔建材有限公司 | 一种联合氧化的废水处理*** |
CN109970262A (zh) * | 2017-12-28 | 2019-07-05 | 江苏久吾高科技股份有限公司 | 一种中水零排放处理方法及装置 |
CN108275817A (zh) * | 2018-01-22 | 2018-07-13 | 浙江开创环保科技股份有限公司 | 一种高硬度高盐分废水资源化的处理方法 |
CN108751550A (zh) * | 2018-05-25 | 2018-11-06 | 中节能工程技术研究院有限公司 | 一种垃圾渗滤液尾水的处理方法及处理*** |
CN108640389A (zh) * | 2018-05-31 | 2018-10-12 | 同济大学 | 处理废水脱盐的方法及微纳米气泡-真空膜蒸馏耦合脱盐*** |
CN109231664A (zh) * | 2018-09-19 | 2019-01-18 | 河南慧锦药业有限公司 | 一种高含盐量和高cod制药废水的综合处理工艺 |
CN109550771A (zh) * | 2018-12-11 | 2019-04-02 | 中化环境控股有限公司 | 工业废盐中有机污染物的去除方法和去除装置 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113828615A (zh) * | 2021-09-06 | 2021-12-24 | 浙江宜可欧环保科技有限公司 | 新型废盐处理*** |
CN114011852A (zh) * | 2021-09-18 | 2022-02-08 | 昆明市生态环境科学研究院 | 一种有机废弃物的无害盐化处理方法 |
CN114522443A (zh) * | 2022-04-22 | 2022-05-24 | 徐州宏武纳米科技有限公司 | 一种超声波震荡式纳米晶体萃取分离装置 |
CN114951237A (zh) * | 2022-05-09 | 2022-08-30 | 中南大学 | 一种微纳塑料的降解方法 |
CN114951237B (zh) * | 2022-05-09 | 2023-04-07 | 中南大学 | 一种微纳塑料的降解方法 |
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