CN110241617A - A kind of environment-friendly type wash and wear finisher and its application method - Google Patents
A kind of environment-friendly type wash and wear finisher and its application method Download PDFInfo
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- CN110241617A CN110241617A CN201910182441.0A CN201910182441A CN110241617A CN 110241617 A CN110241617 A CN 110241617A CN 201910182441 A CN201910182441 A CN 201910182441A CN 110241617 A CN110241617 A CN 110241617A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of environment-friendly type wash and wear finisher and its application methods.Contain in the wash and wear finisher: easy-care finish resin-modification hydroxymethyl-2 dihydroxy-ethylene urea 40-120g/L, catalyst 10-30g/L, softening agent 20-120g/L, bleeding agent 0.5-1.5g/L.Its application method: being transferred to neutrality for the cloth cover PH of fabric, be put into padding finishing in wash and wear finisher, adjusts working solution PH 4-5.5 with glacial acetic acid, controls pick-up rate 70-90%, pad 25-35 DEG C of temperature, pad time 5-20 second；Prebake is to remaining moisture percentage 5-8%；It bakes: 145-150 DEG C, 3-10 minutes；Or 170-175 DEG C, 45-60 seconds.The wash and wear finisher has different arrangement agent prescriptions and different application methods for cotton and polyester-cotton blend viscose fabric, is suitably padded by control, bakes condition, can guarantee good Influencing Non-Ironing Finish.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, be related to a kind of textile auxiliary and its application method, in particular to it is a kind of
Environment-friendly type wash and wear finisher and its application method.
Background technique
Noniron finish is the Treatment technique for processing for a kind of fabric that pure cotton fabric is also easy to produce wrinkle and uses, use
Auxiliary agent is exactly wash and wear finisher.There are two types of the process routes of no-ironing finishing of pure cotton textile: method is baked before first is that, i.e. fabric open width is soaked
Resin is rolled, the whole process such as flat curing is completed by printing and dyeing mill, this is traditional process route, and shortcoming is to clothes
Processing brings certain difficulty, is difficult to assign its a little goffering and apparel modeling to clothes, therefore the arrangement that it is only applicable to cloth adds
Work；Second is that method is baked after use is now popular, it is different according to the mode for padding resin, and fabric can be divided into and pad kimonos
Two kinds of dress dipping.After the former pads resin in printing and dyeing mill and dries for pure cotton fabric, but resin cross-linking reaction stays in garment sewing
It is just completed after being put into baking oven；The latter is then to impregnate finishing fluid with clothes or dry and bake again after being sprayed with spray gun.Clothes
For dress after baking, crosslinked resin makes the goffering of clothes and smooth appearance be fixed up, and for clothes after dress washing, fiber is total
It is state when trying hard to be returned to crosslinking, here it is so-called " formative memory " functions.Clothes have after durable press finish
It is soft, the features such as goffering is lasting.Noniron finish is carried out using wash and wear finisher, output can be controlled flexibly and effectively,
Certain Special Finishing (such as Placer tin deposit) can be also neatly carried out before grooming, to reach processing multiplicity and vdiverse in function
Property, it is greatly improved the class and snugness of fit of clothes.
During the noniron finish of cotton fabric, optimal wrinkle resistant non-ironing effect how is obtained, there are many factor of influence, main
There are following link and influence factor:
(1) structural parameters of fibre length, yarn twist, yarn formation structure and fabric；
(2) there is certain requirement to the fabric before arrangement.Before arrangement, fabric should be by desizing, kiering and bleaching
Reason, the preferably slurry and impurity on removing fabric, make fabric hygroscopicity with higher；Fabric should generally be processed through mercerising,
It is conditional that liquid nitrogen processing also can be used；Stained clot-h can first carry out the test of durable pressing in dyeing with resin, be with determination
No colored light variation, to adjust formula in time；Cloth cover after dyeing, which should keep clean, does not have impurity, and moisture absorption with higher
Property.PH value should control between 5.5~7.0, should be below 0.05% with the NaoH content that titration detects；Printing and dyeing mill is arranging
Before should to fabric carry out preshrunk processing, with reduce ready-made clothes washing shrinkage and guarantee cut out the correct of size.
(3) suitable wash and wear finisher, the quality of strict control easy-care finish resin are selected.Stringent selection wash and wear finisher
The key that fabric strength and content of formaldehyde meet the requirements is to ensure that with easy-care finish resin.It first has to exempt from using low formaldehyde content
It scalds and arranges resin；Its secondary formula that finishing agent is formulated according to crosslinking degree can make the intensity of fabric if crosslinking is excessively
It is reduced much with wear resistance, eventually affects the service life of clothes；Conversely, if crosslinking not enough, can make washing shrinkage, cloth cover
The indexs such as planarization and goffering retentivity do not reach requirement.
(4) equipment and technology is baked.Front and rear, left and right, upper and lower temperature in baking oven are to ensure that the requirement for baking equipment
Should be consistent, using the automatic control instrument of temperature and time, and using the continuous baking oven of driven type, not only can be improved whole
The quality of reason, but also yield can be improved.
(5) the correct selection of the sewing quality of clothes and auxiliary material.In order to ensure the quality and wrinkle resistant non-ironing effect of clothes,
It is required that the washing shrinkage very little of sewing thread, generally preferably uses polyester cotton sewing thread, and sutured with single needle, needle gage and tension are appropriate, to protect
Clothes after card sewing are indeformable.The various linings of clothes and the washing shrinkage of lining cloth should be consistent with fabric.
Only notice above-mentioned links and influence factor, the effect of DP finish of cotton fabric could be guaranteed.Cotton is knitted
The kind of object has all-cotton fabric, viscose glue (synthetic cotton) fabric there are many kind, and there are also the polyester-cotton fabrics etc. of various different blend proportions
Deng.For a variety of different cotton fabrics, suitable wash and wear finisher, strict control wash and wear finisher and easy-care finish resin are selected
Quality be vital.
Main component in wash and wear finisher is easy-care finish resin, non-ironing whole in the wash and wear finisher generallyd use at present
Reason resin mostly also contains formaldehyde, if improper use will formaldehyde influence environment and health.In addition, existing non-ironing whole
It manages in agent, due to the collocation improper use of easy-care finish resin and other auxiliary agents, alternatively, being selected for different types of cotton fabric
Wash and wear finisher be not it is very suitable, it is not good enough to cause Influencing Non-Ironing Finish.
Summary of the invention
It is an object of the present invention to overcome the deficiencies of the prior art and provide a kind of environmental protection that Influencing Non-Ironing Finish can be improved
Type wash and wear finisher and its application method.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of environment-friendly type wash and wear finisher of the present invention contains the component of following mass-volume concentration in the wash and wear finisher:
The easy-care finish resin are as follows: modified hydroxymethyl-2 dihydroxy-ethylene urea；
The catalyst is SFA, i.e. SO4^2-Fe2O3- γ-Al2O3 solid super acid catalyst；
The bleeding agent is JFC-S, i.e. polyoxyethylene ether compound；
The softening agent is softening agent PEN (i.e. polyethylene emulsion), (the i.e. double amino modified poly- silicon oxygen of softening agent 608
Alkane), one or more of softening agent HC (i.e. the emulsification mixture of polymer fatty acid and tertiary amine salt etc.).
Further, dosage of the softening agent PEN in wash and wear finisher is 20-80g/L；Softening agent 608 is in noniron finish
Dosage in agent is 10-30g/L；Dosage of the softening agent HC in wash and wear finisher is 20-40g/L.
Further, the component of following mass-volume concentration is contained in the wash and wear finisher: the wash and wear finisher is suitable
For noniron finish all-cotton fabric；
Further, the component of following mass-volume concentration is contained in the wash and wear finisher: the wash and wear finisher is suitable
For noniron finish polyester-cotton blend or viscose glue (synthetic cotton) fabric；
Further, the polyurethane-modified organosilicon of 300-600g/L is also added in the wash and wear finisher,
It is possible thereby to which the feel for adjusting fabric reaches more preferably.
A kind of application method of environment-friendly type wash and wear finisher of the present invention is as follows:
Cloth cover PH to the fabric of noniron finish is adjusted in neutral range, the fabric to noniron finish is put into above-mentioned
Padding finishing is carried out in wash and wear finisher, the PH for adjusting working solution with glacial acetic acid (acetic acid) controls pick-up rate 70- in 4-5.5
90%, guarantee suitably to pad temperature and pads the time and (pad 25-35 DEG C of temperature, pad time 5-20 second), it is abundant to obtain
Cross-linking reaction, guarantee good finishing effect；Prebake is to remaining moisture percentage 5-8%；It bakes: 145-150 DEG C, 3-10 points
Clock；Or 170-175 DEG C, 45-60 seconds.
Further, the fabric to noniron finish is all-cotton fabric；By the cloth cover PH tune to the fabric of noniron finish
It is whole in neutral range, the fabric to noniron finish is put into above-mentioned wash and wear finisher and carries out padding finishing, with glacial acetic acid (second
Acid) adjust working solution PH in 4-5, control pick-up rate 70-80%, pad 25-30 DEG C of temperature, pad time 5-10 second；Preliminary drying
It does to remaining moisture percentage 5-7%；It bakes: 145-150 DEG C, 3-10 minutes.
Further, the fabric to noniron finish is polyester-cotton blend or viscose glue (synthetic cotton) fabric；It will be to noniron finish
The cloth cover PH of fabric is adjusted in neutral range, the fabric to noniron finish is put into above-mentioned wash and wear finisher pad it is whole
Reason, the PH for adjusting working solution with glacial acetic acid (acetic acid) control pick-up rate 80-90%, pad 30-35 DEG C of temperature, pad in 4-5.5
Time 10-20 second；Prebake is to remaining moisture percentage 6-8%；It bakes: 170-175 DEG C, 45-60 seconds.
Beneficial effects of the present invention:
Compared with the prior art, the invention has the following advantages:
The easy-care finish resin used in wash and wear finisher of the invention is modified hydroxymethyl-2 dihydroxy-ethylene urea, trip
It is very low from content of formaldehyde.Without washing, " ecological textile attestation -- Oeko-Tex (R) can be reached
Requirement of the Standard 100 " to formaldehyde content of textiles.Wash and wear finisher of the invention is a kind of noniron finish of environment-friendly type
Agent.
Wash and wear finisher of the invention has different arrangements for all-cotton fabric and polyester-cotton blend or viscose glue (synthetic cotton) fabric
Agent prescription and different application methods control suitable leaching by controlling suitable PH, pick-up rate, prebake residue moisture percentage
Temperature is rolled, the time is padded, baking temperature, bakes the time, sufficient cross-linking reaction can be obtained, can guarantee good noniron finish
Effect.
Specific embodiment
The present invention is further illustrated with reference to embodiments.
Embodiment 1
A kind of environment-friendly type wash and wear finisher of the present invention contains the component of following mass-volume concentration in the wash and wear finisher:
The easy-care finish resin are as follows: modified hydroxymethyl-2 dihydroxy-ethylene urea；
The catalyst SFA are as follows: SO4^2-Fe2O3- γ-Al2O3 solid super acid catalyst；
The softening agent PEN are as follows: polyethylene emulsion；
The softening agent 608 are as follows: double amino modified polysiloxanes.
Penetrating agent JFC-the S are as follows: polyoxyethylene ether compound；
The wash and wear finisher is suitable for noniron finish all-cotton fabric.
The application method of above-mentioned environment-friendly type wash and wear finisher, it includes:
The fabric to noniron finish is all-cotton fabric；Cloth cover PH to the fabric of noniron finish is adjusted to neutral model
In enclosing, the fabric to noniron finish is put into above-mentioned wash and wear finisher and carries out padding finishing, adjusts work with glacial acetic acid (acetic acid)
Make the PH of liquid in 4-5, controls pick-up rate 70-80%, pad 25-30 DEG C of temperature, pad time 5-10 second, adequately handed over obtaining
Connection reaction, guarantees good finishing effect；Prebake is to remaining moisture percentage 5-7%；It bakes: 145-150 DEG C, 3-10 minutes.
Embodiment 2
A kind of environment-friendly type wash and wear finisher of the present invention contains the component of following mass-volume concentration in the wash and wear finisher:
The easy-care finish resin are as follows: modified hydroxymethyl-2 dihydroxy-ethylene urea；
The catalyst SFA are as follows: SO4^2-Fe2O3- γ-Al2O3 solid super acid catalyst；
The softening agent 608 are as follows: double amino modified polysiloxanes.
The softening agent HC are as follows: the emulsification mixture of polymer fatty acid and tertiary amine salt etc..
Penetrating agent JFC-the S are as follows: polyoxyethylene ether compound；
The wash and wear finisher is suitable for noniron finish polyester-cotton blend or viscose glue (synthetic cotton) fabric.
The application method of above-mentioned environment-friendly type wash and wear finisher, it includes:
The fabric to noniron finish is polyester-cotton blend or viscose glue (synthetic cotton) fabric；By the cloth cover to the fabric of noniron finish
PH is adjusted in neutral range, and the fabric to noniron finish is put into above-mentioned wash and wear finisher and carries out padding finishing, with ice vinegar
Sour (acetic acid) adjusts the PH of working solution in 4-5.5, controls pick-up rate 80-90%, pads 30-35 DEG C of temperature, pad time 10-20
Second, to obtain sufficient cross-linking reaction, guarantee good finishing effect；Prebake is to remaining moisture percentage 6-8%；It bakes: 170-
175 DEG C, 45-60 seconds.
Embodiment 3
A kind of environment-friendly type wash and wear finisher of the present invention contains the component of following mass-volume concentration in the wash and wear finisher:
The easy-care finish resin are as follows: modified hydroxymethyl-2 dihydroxy-ethylene urea；
The catalyst SFA are as follows: SO4^2-Fe2O3- γ-Al2O3 solid super acid catalyst；
The softening agent PEN are as follows: polyethylene emulsion；
The softening agent HC are as follows: the emulsification mixture of polymer fatty acid and tertiary amine salt etc..
Penetrating agent JFC-the S are as follows: polyoxyethylene ether compound；
The wash and wear finisher is suitable for noniron finish polyester-cotton blend or viscose glue (synthetic cotton) fabric.
The polyurethane-modified organosilicon of 300-600g/L is added in the wash and wear finisher, it is possible thereby to adjust the hand of fabric
Sense reaches more preferably.
The application method of above-mentioned environment-friendly type wash and wear finisher, it includes:
The fabric to noniron finish is polyester-cotton blend or viscose glue (synthetic cotton) fabric；By the cloth cover to the fabric of noniron finish
PH is adjusted in neutral range, and the fabric to noniron finish is put into above-mentioned wash and wear finisher and carries out padding finishing, with ice vinegar
Sour (acetic acid) adjusts the PH of working solution in 4-5.5, controls pick-up rate 80-90%, pads 30-35 DEG C of temperature, pad time 10-20
Second, to obtain sufficient cross-linking reaction, guarantee good finishing effect；Prebake is to remaining moisture percentage 6-8%；It bakes: 170-
175 DEG C, 45-60 seconds.
Claims (8)
1. a kind of environment-friendly type wash and wear finisher, which is characterized in that contain the group of following mass-volume concentration in the wash and wear finisher
Point:
The easy-care finish resin are as follows: modified hydroxymethyl-2 dihydroxy-ethylene urea；
The catalyst is SFA, i.e. SO4^2-Fe2O3- γ-Al2O3 solid super acid catalyst；
The bleeding agent is JFC-S, i.e. polyoxyethylene ether compound；
The softening agent is softening agent PEN, that is, polyethylene emulsion, softening agent 608 i.e. double amino modified polysiloxanes, softening agent
One or more of the emulsification mixture of HC, that is, polymer fatty acid and tertiary amine salt.
2. environment-friendly type wash and wear finisher as described in claim 1, which is characterized in that softening agent PEN is in wash and wear finisher
Dosage is 20-80g/L；Dosage of the softening agent 608 in wash and wear finisher is 10-30g/L；Softening agent HC is in wash and wear finisher
Dosage be 20-40g/L.
3. environment-friendly type wash and wear finisher as described in claim 1, which is characterized in that containing following in the wash and wear finisher
The component of mass-volume concentration:
The wash and wear finisher is suitable for noniron finish all-cotton fabric.
4. environment-friendly type wash and wear finisher as described in claim 1, which is characterized in that containing following in the wash and wear finisher
The component of mass-volume concentration:
The wash and wear finisher is suitable for noniron finish polyester-cotton blend or viscose glue, that is, spun rayon.
5. environment-friendly type wash and wear finisher as claimed in claim 4, which is characterized in that also added in the wash and wear finisher
There is the polyurethane-modified organosilicon of 300-600g/L.
6. a kind of application method of environment-friendly type wash and wear finisher as described in claim 1, which is characterized in that will be to noniron finish
The cloth cover PH of fabric be adjusted in neutral range, the fabric to noniron finish is put into above-mentioned wash and wear finisher and is padded
It arranges, the PH for adjusting working solution with glacial acetic acid controls pick-up rate 70-90%, pad 25-35 DEG C of temperature, pad the time in 4-5.5
5-20 seconds；Prebake is to remaining moisture percentage 5-8%: baking: 145-150 DEG C, 3-10 minutes；Or 170-175 DEG C, 45-60 seconds.
7. the application method of environment-friendly type wash and wear finisher as claimed in claim 6, which is characterized in that described to noniron finish
Fabric is all-cotton fabric；Cloth cover PH to the fabric of noniron finish is adjusted in neutral range, by the fabric to noniron finish
It is put into above-mentioned wash and wear finisher and carries out padding finishing, the PH for adjusting working solution with glacial acetic acid controls pick-up rate 70- in 4-5
80%, 25-30 DEG C of temperature is padded, time 5-10 second is padded；Prebake is to remaining moisture percentage 5-7%；It bakes: 145-150 DEG C, 3-
10 minutes.
8. the application method of environment-friendly type wash and wear finisher as claimed in claim 6, which is characterized in that described to noniron finish
Fabric is polyester-cotton blend or viscose glue, that is, spun rayon；Cloth cover PH to the fabric of noniron finish is adjusted in neutral range, it will be to
The fabric of noniron finish, which is put into above-mentioned wash and wear finisher, carries out padding finishing, adjusts the PH of working solution in 4-5.5 with glacial acetic acid,
Pick-up rate 80-90% is controlled, 30-35 DEG C of temperature is padded, pads time 10-20 second；Prebake is to remaining moisture percentage 6-8%；Roasting
It dries: 170-175 DEG C, 45-60 seconds.
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| CN112853752A (en) * | 2021-02-09 | 2021-05-28 | 鲁泰纺织股份有限公司 | Preparation method of delayed baking non-ironing finishing liquid for cotton fabric, product and application of finishing liquid |
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| CN115161843A (en) * | 2022-06-13 | 2022-10-11 | 雅戈尔服装制造有限公司 | Processing method of natural antibacterial ultra-soft China hemp real silk high-count high-density fine fabric |
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| CN112878048A (en) * | 2021-02-09 | 2021-06-01 | 鲁泰纺织股份有限公司 | Preparation method of delayed baking non-ironing finishing liquid for cotton fabric, product and application of finishing liquid |
| CN115161843A (en) * | 2022-06-13 | 2022-10-11 | 雅戈尔服装制造有限公司 | Processing method of natural antibacterial ultra-soft China hemp real silk high-count high-density fine fabric |
| CN115161843B (en) * | 2022-06-13 | 2024-04-26 | 雅戈尔服装制造有限公司 | Processing method of natural antibacterial super-soft China hemp silk high-count high-density fine fabric |
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