CN106223077A - One dyeing and finishing method growing flax people's cotton blended fabric - Google Patents
One dyeing and finishing method growing flax people's cotton blended fabric Download PDFInfo
- Publication number
- CN106223077A CN106223077A CN201610592650.9A CN201610592650A CN106223077A CN 106223077 A CN106223077 A CN 106223077A CN 201610592650 A CN201610592650 A CN 201610592650A CN 106223077 A CN106223077 A CN 106223077A
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- CN
- China
- Prior art keywords
- fabric
- dyeing
- people
- quaternary ammonium
- cotton blended
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004744 fabric Substances 0.000 title claims abstract description 100
- 238000004043 dyeing Methods 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 37
- 229920000742 Cotton Polymers 0.000 title claims abstract description 29
- 241000208202 Linaceae Species 0.000 title claims abstract description 14
- 235000004431 Linum usitatissimum Nutrition 0.000 title claims abstract description 14
- 229920001661 Chitosan Polymers 0.000 claims abstract description 46
- 239000000975 dye Substances 0.000 claims abstract description 37
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000985 reactive dye Substances 0.000 claims abstract description 30
- 238000001035 drying Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 238000002203 pretreatment Methods 0.000 claims abstract description 11
- 239000000344 soap Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 239000007788 liquid Substances 0.000 claims description 34
- 238000005406 washing Methods 0.000 claims description 30
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
- 238000004061 bleaching Methods 0.000 claims description 23
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 21
- 239000000460 chlorine Substances 0.000 claims description 21
- 229910052801 chlorine Inorganic materials 0.000 claims description 21
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 230000000149 penetrating effect Effects 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- 239000007844 bleaching agent Substances 0.000 claims description 16
- 238000002386 leaching Methods 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 13
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 238000007493 shaping process Methods 0.000 claims description 10
- 238000004513 sizing Methods 0.000 claims description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 10
- 238000006298 dechlorination reaction Methods 0.000 claims description 9
- 239000012224 working solution Substances 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004382 Amylase Substances 0.000 claims description 7
- 102000013142 Amylases Human genes 0.000 claims description 7
- 108010065511 Amylases Proteins 0.000 claims description 7
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 claims description 7
- -1 amine compound Chemical class 0.000 claims description 7
- 235000019418 amylase Nutrition 0.000 claims description 7
- 230000033228 biological regulation Effects 0.000 claims description 7
- 239000001488 sodium phosphate Substances 0.000 claims description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 7
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 235000013877 carbamide Nutrition 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000009432 framing Methods 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 230000005012 migration Effects 0.000 claims description 5
- 238000013508 migration Methods 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 239000004669 nonionic softener Substances 0.000 claims description 5
- 238000005554 pickling Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 235000010265 sodium sulphite Nutrition 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000003906 humectant Substances 0.000 claims 1
- 238000005096 rolling process Methods 0.000 claims 1
- 239000002932 luster Substances 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 description 28
- 230000000694 effects Effects 0.000 description 15
- 239000012986 chain transfer agent Substances 0.000 description 8
- 229920000297 Rayon Polymers 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000009990 desizing Methods 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 241000218236 Cannabis Species 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 150000007529 inorganic bases Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001089 thermophoresis Methods 0.000 description 2
- KGPGFQWBCSZGEL-ZDUSSCGKSA-N GSK690693 Chemical compound C=12N(CC)C(C=3C(=NON=3)N)=NC2=C(C#CC(C)(C)O)N=CC=1OC[C@H]1CCCNC1 KGPGFQWBCSZGEL-ZDUSSCGKSA-N 0.000 description 1
- AKQOBHZKBDHWQI-BZEFIUHZSA-N O[C@H]1C[C@@H](CCC1)N1C(C2(C3=C1N=C(N=C3)NC1=CC=C(C=C1)S(=O)(=O)NC([2H])([2H])[2H])CC2)=O Chemical compound O[C@H]1C[C@@H](CCC1)N1C(C2(C3=C1N=C(N=C3)NC1=CC=C(C=C1)S(=O)(=O)NC([2H])([2H])[2H])CC2)=O AKQOBHZKBDHWQI-BZEFIUHZSA-N 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229940127108 compound 5g Drugs 0.000 description 1
- 239000001978 cystine tryptic agar Substances 0.000 description 1
- JFOZKMSJYSPYLN-QHCPKHFHSA-N lifitegrast Chemical compound CS(=O)(=O)C1=CC=CC(C[C@H](NC(=O)C=2C(=C3CCN(CC3=CC=2Cl)C(=O)C=2C=C3OC=CC3=CC=2)Cl)C(O)=O)=C1 JFOZKMSJYSPYLN-QHCPKHFHSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
- C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
- C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C27/00—Compound processes or apparatus, for finishing or dressing textile fabrics, not otherwise provided for
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C9/00—Singeing
- D06C9/02—Singeing by flame
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
Abstract
The invention discloses a dyeing and finishing method growing flax people's cotton blended fabric, comprise the steps: S1, pre-treatment, S2, dyeing, S3, Final finishing；Wherein, the concrete operations of described dyeing include: by described blend fabric after chitosan quaternary ammonium salt treatment, pad the dye liquor of reactive dye, infrared preliminary drying to fabric moisture percentage is 20 50%, and drying at 80 120 DEG C to fabric moisture percentage is 0 10%, then bakes 0.5 3min at 150 170 DEG C, cold water is washed, soap, hot water wash, dry.The dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric that the present invention proposes, not only method is simple, steady quality, and gives that described blend fabric color and luster is even, color fastness is high and whippy advantage.
Description
Technical field
The present invention relates to dyeing and finishing processing technique field, particularly relate to a dyeing and finishing method growing flax people's cotton blended fabric.
Background technology
People cotton has another name called viscose rayon, is a principal item of staple fibre.It is formed alkali by native cellulose through alkalization
Cellulose, then generate cellulose xanthate ester with Carbon bisulfide effect, the viscous solution obtained in being dissolved in sig water claims viscose glue,
Viscose glue after wet spinning and a series for the treatment of process viscose rayon.Caulis et Folium Lini belongs to phloem fiber, is mainly composed of fiber
Cellulose fiber.Natural flax fiber grades impurity containing pectin, lignin, waxiness and ash, generally up to 20%, its molecule aggregation
Degree is more than 10000, and degree of crystallinity reaches 70%.Flax fiber fracture strength is higher, and wet strength is high, and breaking ductility is low.Therefore, with
Caulis et Folium Lini is that the fabric pretreatment difficulty of component is big, it is desirable to high.
Being obtained fabric by Caulis et Folium Lini/people's cotton blending or intertexture is a kind of novel garment material, and it has fiber crops concurrently and other are fine
Tie up solid, the advantages such as breathability is strong, good hygroscopicity, high resiliency, comfortable and easy to wear.But Caulis et Folium Lini, the cotton respective feature of people but give dye
Whole processing brings certain difficulty, if dealing with improperly, equally existing wiriness, easily wrinkle, poor flexibility, wearing next to the skin spinosity
Gargalesthesia and the shortcoming such as washing shrinkage is big.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a dyeing and finishing side growing flax people's cotton blended fabric
Method, not only method is simple, steady quality, and gives that described blend fabric color and luster is even, color fastness is high and whippy excellent
Point.
The dyeing and finishing method growing flax people's cotton blended fabric that the present invention proposes, comprises the steps: S1, pre-treatment, S2,
Dyeing, S3, Final finishing；Wherein, the concrete operations of described dyeing include: by described blend fabric through chitosan quaternary ammonium salt treatment
After, padding the dye liquor of reactive dye, infrared preliminary drying to fabric moisture percentage is to dry at 20-50%, 80-120 DEG C to fabric to contain
Wet rate is 0-10%, then bakes 0.5-3min at 150-170 DEG C, and cold water is washed, and soaps, hot water wash, dries.
Preferably, described blend fabric is included through the concrete operations of chitosan quaternary ammonium salt treatment: by described blend fabric
Padding in the dressing liquid comprising chitosan quaternary ammonium salt, two leachings two are rolled, and pad temperature and are 30-50 DEG C, and pick-up is 90-100%,
Preliminary drying 1-3min at 80-100 DEG C, then at 110-130 DEG C, bakee 5-10min, after cold water is washed, dry at 60-80 DEG C；Wherein institute
State the dressing liquid comprising chitosan quaternary ammonium salt to include: chitosan quaternary ammonium salt 5-20g/L, organic amine compound 1-5g/L, alkaline agent
1-20g/L, penetrating agent 1-10g/L, surplus are water.
Preferably, the preparation method of described chitosan quaternary ammonium salt includes: added by chitosan in isopropanol, adds content and is
The sodium hydroxide solution of 25-35wt% stirs, and adds ether agent of CTA, reacts 2-4h 40-60 DEG C of stirred in water bath,
Add hydrochloric acid and regulate sucking filtration to neutrality, obtain described chitosan quaternary ammonium salt, wherein chitosan, isopropanol, CTA, sodium hydroxide
The weight proportion of solution is 1:6-8:1-1.5:1.5-2.
Preferably, described in pad the dye liquor of reactive dye during, pad temperature and be 30-70 DEG C, pick-up is 60-
100%, the dye liquor of described reactive dye includes: reactive dye 1-20g/L, sodium trichloroacetate 5-10g/L, trichloroacetic acid 0.1-
1g/L, carbamide 5-20g/L, penetrating agent 1-5g/L, reservehao S 1-5g/L, migration inhibitor 1-10g/L, surplus is water.
Preferably, described in the temperature soaped be 90-98 DEG C, the consumption of soaping agent is 1-3g/L, and the time of soaping is 10-
30min；The temperature of described hot water wash is 60-80 DEG C, and the thermal washing time is 5-15min.
Preferably, the concrete operations of described pre-treatment include:
S11, singing, singe with gassing frame, speed is 75-90m/min, and two positive two is anti-, four road burners, grade of singing
4-5 level, amylase fire extinguishing at 60-70 DEG C, insulation clot is banked up 2-3h；
S12, kiering, room temperature pads working solution, and two leachings two are rolled, and pick-up is 60-90%, and speed is 30-40m/min, work
Include as liquid: Caustic soda 15-20g/L, soda 5-15g/L, sodium sulfite 1-5g/L, tertiary sodium phosphate 1-3g/L, digesting agent 5-10g/
L, wetting agent 1-5g/L, decatize 20-40min of banking up at 105-110 DEG C, 80-90 DEG C of washing；
S13, bleaching, pad Chlorine Bleach under room temperature, Chlorine Bleach includes: effective chlorine 3-9g/L, and regulation pH value is 9.5-10, protects
Temperature is banked up 0.1-0.3h, uses the aqueous sulfuric acid pickling dechlorination of 2.5-3.5g/L, stacking at room temperature 0.2-0.4h, washing, room temperature
Under pad oxygen bleaching liquid again, oxygen bleaching liquid includes: hydrogen peroxide 5-8g/L, hydrogen peroxide stabilizer 1-5g/L, penetrating agent 1-3g/L, sodium phosphate
Bank up at 1-3g/L, 90-100 DEG C decatize 0.2-0.5h, 80-90 DEG C of washing.
Preferably, the concrete operations of described Final finishing include:
S31, tentering, be placed in hot blast framing shaping machine and carry out tentering process, and temperature is 180-200 DEG C, and speed is 35-
50m/min；
S32, softness, pad the dressing liquid of the neutral nonionic softener sg comprising 20-40g/L, two leaching one bundles, pick-up
For 65-75%, decatize 1-2min at 105-110 DEG C, washing, dry；
S33, preshrunk, carry out preshrunk process in being placed in sanforizer, sanforizer speed is 30-70m/min, steam
Pressure is 2-2.5kg/m2；
S34, sizing, use vapour iron to press sizing at 120-135 DEG C, and shaping time is 1-2min.
Proposing a dyeing and finishing method growing flax people's cotton blended fabric in the present invention, it includes pre-treatment, dyeing and rear whole
Manage three steps；
First, in pre-treatment, singing fabric, owing to Caulis et Folium Lini is without degumming process, and filoplume is many, and fiber is thick
Firmly, therefore, the burner temperature that restriction of singing is higher, it is ensured that cloth cover is uniform, and cloth cover fineness reaches more than 4 grades, then uses
Roll amylase mode to put out a fire, both can reach the purpose of fire extinguishing, decrease again one desizing operation, and enzyme desizing operation guarantee is moved back
Slurry effect, will not cause strength loss to fabric；Hereafter fabric is carried out kiering, it is contemplated that Caulis et Folium Lini and the spy of the cotton two kinds of fibers of people
Property, select suitable concentration Caustic soda to carry out kiering, while removing Caulis et Folium Lini surface glue metallic substance, can greatly avoid the wound of fiber
Evil；Simultaneously so that described fabric obtains preferable bleaching effect, the oxygen bleaching liquid of Chlorine Bleach and suitable concentration is used to float
In vain, select to use the Chlorine Bleach of chlorinity, can make the pigment in fabric, Cortex Cannabis removal effect more obvious, meanwhile,
Using suitable concentration to obtain sulfuric acid solution and carry out dechlorination, both can reach dechlorination purpose, the heavy metal ion of the most removable cloth cover, for rear
Sequence oxygen bleaching creates conditions；Owing to impurity and the pigment content of Caulis et Folium Lini are higher, floating through chlorine, mainly remove fiber crops knot, whiteness is the most poor,
In order to realize printing and dyeing, it is necessary to again bleach through hydrogen peroxide, fabric is made to reach certain whiteness requirement, and in described oxygen bleaching liquid
Also use penetrating agent, sodium phosphate as auxiliary agent so that fiber macromole becomes mellow and full, it is thus achieved that while durability gloss, improve
Fabric absorbs the ability of dyestuff.
Secondly, in dyeing, in order to solve the colouring inequality that Caulis et Folium Lini people's cotton blended fabric is dyeed by traditional activated dyestuff, Gu
The defect of the low grade of color rate, the present invention, in dyeing course, after being arranged by cotton for Caulis et Folium Lini people dressing liquid through chitosan quaternary ammonium salt, passes through
Fabric is carried out cation-modified by chitosan quaternary ammonium salt, due to this chitosan derivatives water soluble, treats dye fabric hydrophilic
Can affect little, the inside of cellulose fibre therefore on the premise of not affecting dye-uptake, can be penetrated into, it is ensured that described blending is knitted
The fibrous inside of thing obtains good modified effect, and fiber ectonexine is modified uniformly so that fabric eventually with positive electricity performance, its
Can combine with the sulfonic group anion on reactive dye, greatly reduce the water soluble characteristic of reactive dye, hence it is evident that improve
The dyestuff affinity to fabric fibre, such that it is able to be adsorbed onto further on fabric fibre by the reactive dye in dye liquor, continues
React with fabric fibre, improve the degree of fixation of reactive dye；The organic amine compound added in the most described dressing liquid is the most not
Only can regulate the cationic of quaternary ammonium salt-modified fabric so that it is the anionic property of adaptive different activities dyestuff, further enhance
The affinity of the two, thus the beneficially colourability of fabric and the raising of degree of fixation, and organic amine compound can assist
Follow-up inorganic base carries out fixation, both can ensure that color fixing agent and dyestuff fully can spread it is thus possible to effective fixation in fiber, again
Dyestuff hydrolysis on fiber can be reduced thus can have the highest degree of fixation；During upper dye, the present invention is in order to further
Dye and fixation efficiency in raising, use trichloroacetic acid and sodium trichloroacetate as composite solid toner, contaminate relative to traditional activity
Material dyeing, the employing of described color fixing agent not only reduces the hydrolytic process of reactive dye, and to reactive dye also non-selectivity,
The consumption of saving salt simultaneously, decreases the requirement to equipment, can carry out on conventional padding mangle, be thus greatly improved dye-uptake and
Fixation rate.
Further, in Final finishing, tentering arranges temperature and uses 180-200 DEG C, can either ensure that cropping is dried, reach optimal
Feel, do not result in thermophoresis and the skew of sensitive color coloured light of reducing dye yet；Fabric is carried out soft finish simultaneously, give
The elastic effect that fabric is good；In order to improve fabric feel further, by with painting cloth washing shrinkage as foundation, compare fabric finished product
Shrink require that regulation preshrinking rate carries out preshrunk, thus contribute to the dimensionally stable of fabric；Last flatiron at a certain temperature is fixed
Type so that the good hand feeling of fabric is smooth, gloss is soft, improves the wearability of fabric.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
One dyeing and finishing method growing flax people's cotton blended fabric, it is characterised in that comprise the steps:
S1, pre-treatment, its concrete operations include:
S11, singing, singe with gassing frame, speed is 75m/min, and two positive two is anti-, four road burners, class 5 of singing
Level, amylase fire extinguishing at 60 DEG C, insulation clot is banked up 3h；
S12, kiering, room temperature pads working solution, and two leachings two are rolled, and pick-up is 60%, and speed is 40m/min, working solution bag
Include: Caustic soda 15g/L, soda 15g/L, sodium sulfite 1g/L, tertiary sodium phosphate 3g/L, digesting agent 5g/L, wetting agent 5g/L, 105 DEG C
Under bank up decatize 40min, 80 DEG C of washings；
S13, bleaching, pad Chlorine Bleach under room temperature, Chlorine Bleach includes: effective chlorine 3g/L, and regulation pH value is 9.5-10, insulation
Bank up 0.3h, uses the aqueous sulfuric acid pickling dechlorination of 2.5g/L, stacking at room temperature 0.4h, washing, pads oxygen bleaching liquid under room temperature again,
Oxygen bleaching liquid includes: hydrogen peroxide 5g/L, hydrogen peroxide stabilizer 5g/L, penetrating agent 1g/L, sodium phosphate 3g/L, decatize of banking up at 90 DEG C
0.5h, 80 DEG C of washings；
S2, dyeing, its concrete operations include: described blend fabric padded in the dressing liquid comprising chitosan quaternary ammonium salt,
Two leachings two are rolled, and padding temperature is 30 DEG C, and pick-up is 100%, preliminary drying 3min at 80 DEG C, then bakee 10min at 110 DEG C, cold
After washing, at 60 DEG C dry, described in comprise chitosan quaternary ammonium salt dressing liquid include: chitosan quaternary ammonium salt 20g/L, organic amine
Compound 1g/L, alkaline agent 20g/L, penetrating agent 1g/L, surplus are water, then pad the dye liquor of reactive dye, and padding temperature is 70 DEG C,
Pick-up is 60%, and the dye liquor of described reactive dye includes: reactive dye 20g/L, sodium trichloroacetate 5g/L, trichloroacetic acid 1g/
L, carbamide 5g/L, penetrating agent 5g/L, reservehao S 1g/L, migration inhibitor 10g/L, surplus is water, and infrared preliminary drying contains to fabric
Wet rate is 20%, and drying at 120 DEG C to fabric moisture percentage is 0%, then bakes 0.5min at 170 DEG C, and cold water is washed, soap at 98 DEG C
Wash 10min, thermal washing 5min at 80 DEG C, to dry, the preparation method of wherein said chitosan quaternary ammonium salt includes: added by chitosan different
In propanol, add the sodium hydroxide solution that content is 35wt% and stir, add ether agent of CTA, stir in 40 DEG C of water-baths
Mix reaction 4h, add hydrochloric acid and regulate sucking filtration to neutrality, obtain described chitosan quaternary ammonium salt, chitosan, isopropanol, CTA, hydrogen-oxygen
The weight proportion changing sodium solution is 1:6:1.5:1.5；
S3, Final finishing, its concrete operations include:
S31, tentering, be placed in hot blast framing shaping machine and carry out tentering process, and temperature is 180 DEG C, and speed is 50m/min；
S32, softness, pad the dressing liquid of the neutral nonionic softener sg comprising 20g/L, and two leaching one bundles, pick-up is
75%, decatize 2min at 105 DEG C, washing, dry；
S33, preshrunk, carry out preshrunk process in being placed in sanforizer, sanforizer speed is 30m/min, vapour pressure
Power is 2.5kg/m2；
S34, sizing, use vapour iron to press sizing at 120 DEG C, and shaping time is 2min.
Embodiment 2
One dyeing and finishing method growing flax people's cotton blended fabric, it is characterised in that comprise the steps:
S1, pre-treatment, its concrete operations include:
S11, singing, singe with gassing frame, speed is 90m/min, and two positive two is anti-, four road burners, class 4 of singing
Level, amylase fire extinguishing at 70 DEG C, insulation clot is banked up 2h；
S12, kiering, room temperature pads working solution, and two leachings two are rolled, and pick-up is 90%, and speed is 30m/min, working solution bag
Include: Caustic soda 20g/L, soda 5g/L, sodium sulfite 5g/L, tertiary sodium phosphate 1g/L, digesting agent 10g/L, wetting agent 1g/L, 110 DEG C
Under bank up decatize 20min, 90 DEG C of washings；
S13, bleaching, pad Chlorine Bleach under room temperature, Chlorine Bleach includes: effective chlorine 9g/L, and regulation pH value is 9.5-10, insulation
Bank up 0.1h, uses the aqueous sulfuric acid pickling dechlorination of 3.5g/L, stacking at room temperature 0.2h, washing, pads oxygen bleaching liquid under room temperature again,
Oxygen bleaching liquid includes: hydrogen peroxide 8g/L, hydrogen peroxide stabilizer 1g/L, penetrating agent 3g/L, sodium phosphate 1g/L, decatize of banking up at 100 DEG C
0.2h, 90 DEG C of washings；
S2, dyeing, its concrete operations include: described blend fabric padded in the dressing liquid comprising chitosan quaternary ammonium salt,
Two leachings two are rolled, and padding temperature is 50 DEG C, and pick-up is 90%, preliminary drying 1min at 100 DEG C, then bakee 5min, cold water at 130 DEG C
After washing, at 80 DEG C dry, described in comprise chitosan quaternary ammonium salt dressing liquid include: chitosan quaternary ammonium salt 5g/L, organic amine
Compound 5g/L, alkaline agent 1g/L, penetrating agent 10g/L, surplus are water, then pad the dye liquor of reactive dye, and padding temperature is 30 DEG C, rolls
Remaining rate is 100%, and the dye liquor of described reactive dye includes: reactive dye 1g/L, sodium trichloroacetate 10g/L, trichloroacetic acid 0.1g/
L, carbamide 20g/L, penetrating agent 1g/L, reservehao S 5g/L, migration inhibitor 1g/L, surplus is water, and infrared preliminary drying contains to fabric
Wet rate is 50%, and drying at 80 DEG C to fabric moisture percentage is 10%, then bakes 3min at 150 DEG C, and cold water is washed, and soaps at 90 DEG C
30min, thermal washing 15min at 60 DEG C, dry, and the preparation method of wherein said chitosan quaternary ammonium salt includes: added by chitosan different
In propanol, add the sodium hydroxide solution that content is 25wt% and stir, add ether agent of CTA, stir in 60 DEG C of water-baths
Mix reaction 2h, add hydrochloric acid and regulate sucking filtration to neutrality, obtain described chitosan quaternary ammonium salt, chitosan, isopropanol, CTA, hydrogen-oxygen
The weight proportion changing sodium solution is 1:8:1:2；
S3, Final finishing, its concrete operations include:
S31, tentering, be placed in hot blast framing shaping machine and carry out tentering process, and temperature is 200 DEG C, and speed is 35m/min；
S32, softness, pad the dressing liquid of the neutral nonionic softener sg comprising 40g/L, and two leaching one bundles, pick-up is
65%, decatize 1min at 110 DEG C, washing, dry；
S33, preshrunk, carry out preshrunk process in being placed in sanforizer, sanforizer speed is 70m/min, vapour pressure
Power is 2kg/m2；
S34, sizing, use vapour iron to press sizing at 135 DEG C, and shaping time is 1min.
Embodiment 3
One dyeing and finishing method growing flax people's cotton blended fabric, it is characterised in that comprise the steps:
S1, pre-treatment, its concrete operations include:
S11, singing, singe with gassing frame, speed is 85m/min, and two positive two is anti-, four road burners, class 4 of singing
Level, amylase fire extinguishing at 65 DEG C, insulation clot is banked up 2.5h；
S12, kiering, room temperature pads working solution, and two leachings two are rolled, and pick-up is 75%, and speed is 35m/min, working solution bag
Include: Caustic soda 17g/L, soda 10g/L, sodium sulfite 3g/L, tertiary sodium phosphate 2g/L, digesting agent 8g/L, wetting agent 3g/L, 107 DEG C
Under bank up decatize 30min, 85 DEG C of washings；
S13, bleaching, pad Chlorine Bleach under room temperature, Chlorine Bleach includes: effective chlorine 6g/L, and regulation pH value is 9.5-10, insulation
Bank up 0.2h, uses the aqueous sulfuric acid pickling dechlorination of 3.0g/L, stacking at room temperature 0.3h, washing, pads oxygen bleaching liquid under room temperature again,
Oxygen bleaching liquid includes: hydrogen peroxide 7g/L, hydrogen peroxide stabilizer 3g/L, penetrating agent 2g/L, sodium phosphate 2g/L, decatize of banking up at 95 DEG C
0.3h, 85 DEG C of washings；
S2, dyeing, its concrete operations include: described blend fabric padded in the dressing liquid comprising chitosan quaternary ammonium salt,
Two leachings two are rolled, and padding temperature is 40 DEG C, and pick-up is 95%, preliminary drying 2min at 90 DEG C, then bakee 8min, cold water at 120 DEG C
After washing, at 70 DEG C dry, described in comprise chitosan quaternary ammonium salt dressing liquid include: chitosan quaternary ammonium salt 12g/L, organic amine
Compound 3g/L, alkaline agent 10g/L, penetrating agent 5g/L, surplus are water, then pad the dye liquor of reactive dye, and padding temperature is 50 DEG C, rolls
Remaining rate is 80%, and the dye liquor of described reactive dye includes: reactive dye 10g/L, sodium trichloroacetate 8g/L, trichloroacetic acid 0.5g/
L, carbamide 13g/L, penetrating agent 3g/L, reservehao S 3g/L, migration inhibitor 5g/L, surplus is water, and infrared preliminary drying contains to fabric
Wet rate is 35%, and drying at 100 DEG C to fabric moisture percentage is 5%, then bakes 1min at 160 DEG C, and cold water is washed, and soaps at 94 DEG C
20min, thermal washing 10min at 70 DEG C, dry, and the preparation method of wherein said chitosan quaternary ammonium salt includes: added by chitosan different
In propanol, add the sodium hydroxide solution that content is 30wt% and stir, add ether agent of CTA, stir in 50 DEG C of water-baths
Mix reaction 3h, add hydrochloric acid and regulate sucking filtration to neutrality, obtain described chitosan quaternary ammonium salt, chitosan, isopropanol, CTA, hydrogen-oxygen
The weight proportion changing sodium solution is 1:7:1.2:1.7；
S3, Final finishing, its concrete operations include:
S31, tentering, be placed in hot blast framing shaping machine and carry out tentering process, and temperature is 190 DEG C, and speed is 45m/min；
S32, softness, pad the dressing liquid of the neutral nonionic softener sg comprising 30g/L, and two leaching one bundles, pick-up is
70%, decatize 1.5min at 106 DEG C, washing, dry；
S33, preshrunk, carry out preshrunk process in being placed in sanforizer, sanforizer speed is 50m/min, vapour pressure
Power is 2.2kg/m2；
S34, sizing, use vapour iron to press sizing at 130 DEG C, and shaping time is 1.5min.
Caulis et Folium Lini people's cotton blended fabric finished product obtained through dyeing and finishing in embodiment 1-3 is tested, result as in the table below:
Proposing a dyeing and finishing method growing flax people's cotton blended fabric in the present invention, it includes pre-treatment, dyeing and rear whole
Manage three steps；
First, in pre-treatment, singing fabric, owing to Caulis et Folium Lini is without degumming process, and filoplume is many, and fiber is thick
Firmly, therefore, the burner temperature that restriction of singing is higher, it is ensured that cloth cover is uniform, and cloth cover fineness reaches more than 4 grades, then uses
Roll amylase mode to put out a fire, both can reach the purpose of fire extinguishing, decrease again one desizing operation, and enzyme desizing operation guarantee is moved back
Slurry effect, will not cause strength loss to fabric；Hereafter fabric is carried out kiering, it is contemplated that Caulis et Folium Lini and the spy of the cotton two kinds of fibers of people
Property, select suitable concentration Caustic soda to carry out kiering, while removing Caulis et Folium Lini surface glue metallic substance, can greatly avoid the wound of fiber
Evil；Simultaneously so that described fabric obtains preferable bleaching effect, the oxygen bleaching liquid of Chlorine Bleach and suitable concentration is used to float
In vain, select to use the Chlorine Bleach of chlorinity, can make the pigment in fabric, Cortex Cannabis removal effect more obvious, meanwhile,
Using suitable concentration to obtain sulfuric acid solution and carry out dechlorination, both can reach dechlorination purpose, the heavy metal ion of the most removable cloth cover, for rear
Sequence oxygen bleaching creates conditions；Owing to impurity and the pigment content of Caulis et Folium Lini are higher, floating through chlorine, mainly remove fiber crops knot, whiteness is the most poor,
In order to realize printing and dyeing, it is necessary to again bleach through hydrogen peroxide, fabric is made to reach certain whiteness requirement, and in described oxygen bleaching liquid
Also use penetrating agent, sodium phosphate as auxiliary agent so that fiber macromole becomes mellow and full, it is thus achieved that while durability gloss, improve
Fabric absorbs the ability of dyestuff.
Secondly, in dyeing, in order to solve the colouring inequality that Caulis et Folium Lini people's cotton blended fabric is dyeed by traditional activated dyestuff, Gu
The defect of the low grade of color rate, the present invention, in dyeing course, after being arranged by cotton for Caulis et Folium Lini people dressing liquid through chitosan quaternary ammonium salt, passes through
Fabric is carried out cation-modified by chitosan quaternary ammonium salt, due to this chitosan derivatives water soluble, treats dye fabric hydrophilic
Can affect little, the inside of cellulose fibre therefore on the premise of not affecting dye-uptake, can be penetrated into, it is ensured that described blending is knitted
The fibrous inside of thing obtains good modified effect, and fiber ectonexine is modified uniformly so that fabric eventually with positive electricity performance, its
Can combine with the sulfonic group anion on reactive dye, greatly reduce the water soluble characteristic of reactive dye, hence it is evident that improve
The dyestuff affinity to fabric fibre, such that it is able to be adsorbed onto further on fabric fibre by the reactive dye in dye liquor, continues
React with fabric fibre, improve the degree of fixation of reactive dye；The organic amine compound added in the most described dressing liquid is the most not
Only can regulate the cationic of quaternary ammonium salt-modified fabric so that it is the anionic property of adaptive different activities dyestuff, further enhance
The affinity of the two, thus the beneficially colourability of fabric and the raising of degree of fixation, and organic amine compound can assist
Follow-up inorganic base carries out fixation, both can ensure that color fixing agent and dyestuff fully can spread it is thus possible to effective fixation in fiber, again
Dyestuff hydrolysis on fiber can be reduced thus can have the highest degree of fixation；During upper dye, the present invention is in order to further
Dye and fixation efficiency in raising, use trichloroacetic acid and sodium trichloroacetate as composite solid toner, contaminate relative to traditional activity
Material dyeing, the employing of described color fixing agent not only reduces the hydrolytic process of reactive dye, and to reactive dye also non-selectivity,
The consumption of saving salt simultaneously, decreases the requirement to equipment, can carry out on conventional padding mangle, be thus greatly improved dye-uptake and
Fixation rate.
Further, in Final finishing, tentering arranges temperature and uses 180-200 DEG C, can either ensure that cropping is dried, reach optimal
Feel, do not result in thermophoresis and the skew of sensitive color coloured light of reducing dye yet；Fabric is carried out soft finish simultaneously, give
The elastic effect that fabric is good；In order to improve fabric feel further, by with painting cloth washing shrinkage as foundation, compare fabric finished product
Shrink require that regulation preshrinking rate carries out preshrunk, thus contribute to the dimensionally stable of fabric；Last flatiron at a certain temperature is fixed
Type so that the good hand feeling of fabric is smooth, gloss is soft, improves the wearability of fabric.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. a dyeing and finishing method growing flax people's cotton blended fabric, it is characterised in that comprise the steps: S1, pre-treatment, S2, dye
Color, S3, Final finishing；Wherein, the concrete operations of described dyeing include: by described blend fabric after chitosan quaternary ammonium salt treatment,
Padding the dye liquor of reactive dye, infrared preliminary drying to fabric moisture percentage is to dry to fabric moisture percentage at 20-50%, 80-120 DEG C
For 0-10%, then baking 0.5-3min at 150-170 DEG C, cold water is washed, and soaps, hot water wash, dries.
The dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric the most according to claim 1, it is characterised in that by described blend fabric
Include through the concrete operations of chitosan quaternary ammonium salt treatment: described blend fabric is padded the dressing liquid comprising chitosan quaternary ammonium salt
In, two leachings two are rolled, and pad temperature and are 30-50 DEG C, and pick-up is preliminary drying 1-3min at 90-100%, 80-100 DEG C, then at 110-
Bakee 5-10min at 130 DEG C, after cold water is washed, dry at 60-80 DEG C；The wherein said dressing liquid bag comprising chitosan quaternary ammonium salt
Include: chitosan quaternary ammonium salt 5-20g/L, organic amine compound 1-5g/L, alkaline agent 1-20g/L, penetrating agent 1-10g/L, surplus are
Water.
The dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric the most according to claim 2, it is characterised in that described chitosan quaternary ammonium
The preparation method of salt includes: added by chitosan in isopropanol, adds the sodium hydroxide solution stirring that content is 25-35wt% equal
Even, add ether agent of CTA, react 2-4h 40-60 DEG C of stirred in water bath, add hydrochloric acid and regulate sucking filtration to neutrality, obtain
Described chitosan quaternary ammonium salt, wherein chitosan, isopropanol, CTA, the weight proportion of sodium hydroxide solution are 1:6-8:1-1.5:
1.5-2。
4. according to the dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric described in any one of claim 1-3, it is characterised in that described leaching
During rolling the dye liquor of reactive dye, padding temperature and be 30-70 DEG C, pick-up is 60-100%, the dye liquor of described reactive dye
Including: reactive dye 1-20g/L, sodium trichloroacetate 5-10g/L, trichloroacetic acid 0.1-1g/L, carbamide 5-20g/L, penetrating agent 1-
5g/L, reservehao S 1-5g/L, migration inhibitor 1-10g/L, surplus is water.
5. according to the dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric described in any one of claim 1-4, it is characterised in that described soap
The temperature washed is 90-98 DEG C, and the consumption of soaping agent is 1-3g/L, and the time of soaping is 10-30min；The temperature of described hot water wash is
60-80 DEG C, the thermal washing time is 5-15min.
6. according to the dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric described in any one of claim 1-5, it is characterised in that before described
The concrete operations processed include:
S11, singing, singe with gassing frame, speed is 75-90m/min, and two positive two is anti-, four road burners, class 4-5 of singing
Level, amylase fire extinguishing at 60-70 DEG C, insulation clot is banked up 2-3h；
S12, kiering, room temperature pads working solution, and two leachings two are rolled, and pick-up is 60-90%, and speed is 30-40m/min, working solution
Including: Caustic soda 15-20g/L, soda 5-15g/L, sodium sulfite 1-5g/L, tertiary sodium phosphate 1-3g/L, digesting agent 5-10g/L, profit
Humectant 1-5g/L, decatize 20-40min of banking up at 105-110 DEG C, 80-90 DEG C of washing；
S13, bleaching, pad Chlorine Bleach under room temperature, Chlorine Bleach includes: effective chlorine 3-9g/L, and regulation pH value is 9.5-10, is incubated heap
Set to 0 .1-0.3h, use the aqueous sulfuric acid pickling dechlorination of 2.5-3.5g/L, stacking at room temperature 0.2-0.4h, wash, under room temperature again
Padding oxygen bleaching liquid, oxygen bleaching liquid includes: hydrogen peroxide 5-8g/L, hydrogen peroxide stabilizer 1-5g/L, penetrating agent 1-3g/L, sodium phosphate 1-
Bank up at 3g/L, 90-100 DEG C decatize 0.2-0.5h, 80-90 DEG C of washing.
7. according to the dyeing and finishing method of Caulis et Folium Lini people's cotton blended fabric described in any one of claim 1-6, it is characterised in that after described
The concrete operations arranged include:
S31, tentering, be placed in hot blast framing shaping machine and carry out tentering process, and temperature is 180-200 DEG C, and speed is 35-50m/
min；
S32, softness, pad the dressing liquid of the neutral nonionic softener sg comprising 20-40g/L, and two leaching one bundles, pick-up is
Decatize 1-2min at 65-75%, 105-110 DEG C, washing, dry；
S33, preshrunk, carry out preshrunk process in being placed in sanforizer, sanforizer speed is 30-70m/min, steam pressure
For 2-2.5kg/m2；
S34, sizing, use vapour iron to press sizing at 120-135 DEG C, and shaping time is 1-2min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107447499A (en) * | 2017-06-21 | 2017-12-08 | 叶泉清 | A kind of preparation method of modified sisal hemp carpet |
| CN108316014A (en) * | 2017-01-17 | 2018-07-24 | 绍兴飞亚印染有限公司 | A kind of flax viscose pre-treating technology |
| CN109505155A (en) * | 2018-10-25 | 2019-03-22 | 安徽亚源印染有限公司 | A kind of short wet crease-resistant dyeing and finishing technology of steaming of sodolin |
| CN110250597A (en) * | 2019-07-24 | 2019-09-20 | 吴宝琴 | A kind of soft antibacterial type underwear fabric and preparation method thereof |
| CN111962301A (en) * | 2020-08-15 | 2020-11-20 | 绍兴兴隆染织有限公司 | Dyeing and finishing process of rayon fabric |
| CN113123125A (en) * | 2021-04-13 | 2021-07-16 | 山东魏桥特宽幅印染有限公司 | Preparation method of pure-mint antibacterial cool fabric and fabric prepared by adopting method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108316014A (en) * | 2017-01-17 | 2018-07-24 | 绍兴飞亚印染有限公司 | A kind of flax viscose pre-treating technology |
| CN107447499A (en) * | 2017-06-21 | 2017-12-08 | 叶泉清 | A kind of preparation method of modified sisal hemp carpet |
| CN109505155A (en) * | 2018-10-25 | 2019-03-22 | 安徽亚源印染有限公司 | A kind of short wet crease-resistant dyeing and finishing technology of steaming of sodolin |
| CN110250597A (en) * | 2019-07-24 | 2019-09-20 | 吴宝琴 | A kind of soft antibacterial type underwear fabric and preparation method thereof |
| CN111962301A (en) * | 2020-08-15 | 2020-11-20 | 绍兴兴隆染织有限公司 | Dyeing and finishing process of rayon fabric |
| CN113123125A (en) * | 2021-04-13 | 2021-07-16 | 山东魏桥特宽幅印染有限公司 | Preparation method of pure-mint antibacterial cool fabric and fabric prepared by adopting method |
| CN113136731A (en) * | 2021-04-16 | 2021-07-20 | 江苏艾丽森纺织科技有限公司 | Cotton fabric printing and dyeing process |
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Application publication date: 20161214 |