CN110157552A - A kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof - Google Patents
A kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof Download PDFInfo
- Publication number
- CN110157552A CN110157552A CN201910497243.3A CN201910497243A CN110157552A CN 110157552 A CN110157552 A CN 110157552A CN 201910497243 A CN201910497243 A CN 201910497243A CN 110157552 A CN110157552 A CN 110157552A
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- China
- Prior art keywords
- parts
- salt
- dishes
- washes
- tea tree
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C11D2111/14—
Abstract
The invention belongs to daily cleaning product technical field, in particular to a kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof.The parts by weight composition of the salt that washes the dishes is as follows: 1-20 parts of tea tree extract sodium sulphate, 10-90 parts of sodium chloride, 5-90 parts of builder, 0-5 parts of stabilizer, 0-40 parts of dispersing agent.The high-effective cleansing of the natural green of the present invention salt that washes the dishes has many advantages, such as that tableware residual is low after good stability, potent antibacterial, strong detergency, washing, eats rear harmless to the body, easily biological-degradable by mistake, is environmentally friendly, is easy to be acceptable to the market and promote.
Description
Technical field
The invention belongs to daily cleaning product technical field, in particular to a kind of high-effective cleansing of natural green wash the dishes salt and its
Preparation method.
Background technique
With the rapid development of society, scientific and technical with rapid changepl. never-ending changes and improvements, the continuous improvement of living standard, fast pace life are urgent
Make the raising of working efficiency.Dish-washing machine gradually comes into thousand ten thousand as product of the time, the public places such as the hotel Yi Cong, dining room
Family.However, often eat in public places it is found that can also remain oil stain on tableware, therefore, the washing of dish-washing machine
Effect becomes the important barrier that dish-washing machine moves towards daily life.Furthermore dish-washing machine is often in wet environment, it is easy to nourish thin
How bacterium realizes the problem of comparing concern to dish-washing machine progress sterilization processing and consumer while washing the dishes.In addition, mesh
The raw material of preceding most of dish washing detergents is petrochemicals, will cause biggish harm to human health.Tableware uses this
After a little detergent washings, understands the surface that some detergent remains on tableware, then in feeding process, have some petroleum
Chemical products enter human body, damage to human body.With the continuous improvement of people's living standards, people are to dish washing detergent
Safety is increasingly paid close attention to.Therefore it develops a kind of guarantee stain removal bactericidal ability and safe and harmless dishwasher detergent will greatly expand
The market of big dish-washing machine.
Summary of the invention
The purpose of the present invention is primarily to solving current dish-washing machine, existing washing decontamination is not thorough in use
Bottom, dish washer interior breed the technical problems such as bacterium and provide a kind of high-effective cleansing of natural green suitable for various dish-washing machines
Wash the dishes salt and preparation method thereof.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of high-effective cleansing of natural green washes the dishes salt, and the parts by weight composition of the salt that washes the dishes is as follows:
1-20 parts of tea tree extract sodium sulphate, 10-90 parts of sodium chloride, 5-90 parts of builder, 0-5 parts of stabilizer, dispersing agent
0-40 parts.
The high-effective cleansing of the natural green salt that washes the dishes can be powder, bulk or liquid.
The high-effective cleansing of the natural green wash the dishes salt be it is powdered when, the salt that washes the dishes parts by weight composition it is as follows:
2-20 parts of tea tree extract sodium sulphate, 20-70 parts of sodium chloride, 20-80 parts of builder.
The high-effective cleansing of the natural green washes the dishes salt when being blocky, and the parts by weight composition of the salt that washes the dishes is as follows:
2-20 parts of tea tree extract sodium sulphate, 20-60 parts of sodium chloride, 20-70 parts of builder, 1-5 parts of dispersing agent.
The high-effective cleansing of the natural green wash the dishes salt be it is liquid when, the salt that washes the dishes parts by weight composition it is as follows:
2-20 parts of tea tree extract sodium sulphate, 20-40 parts of sodium chloride, 20-40 parts of builder, 25-40 parts of dispersing agent, stablize
0.1-0.5 parts of agent.
Preferably, the tea tree extract sodium sulphate is obtained by laxative remedy:, will under conditions of control temperature is not higher than 40 DEG C
Chlorosulfonic acid is mixed with tea tree extract, later in 0-40 DEG C of reaction 1-6h, is later isolated and purified reaction product described in obtaining
Tea tree extract sodium sulphate.
Further, the mass ratio of the tea tree extract and chlorosulfonic acid is 1-5:1.
Described isolates and purifies to pour into reaction product in mixture of ice and water, is sufficiently stirred in the case where ice-water bath is cooling
It mixes, is later 7-9 with alkali neutralization to pH, later filtering, filtrate condensing crystallizing, tea tree extract sulphur is obtained after filtering and dry again
Sour sodium.
The mass ratio of ice and water is 1-5:1 in the mixture of ice and water.According to the amount of the chlorosulfonic acid of addition, adjustment is corresponding
Mixture of ice and water in ice, water mass ratio, to avoid react it is too violent.
Specifically, the tea tree extract sodium sulphate is obtained by laxative remedy:
It is added tea tree extract in a kettle, 0-30 DEG C of temperature control, in the case where being sufficiently stirred in being slowly added dropwise in 10-120min
Suitable chlorosulfonic acid (mass ratio of tea tree extract and chlorosulfonic acid is 1-5:1), temperature does not exceed 0-40 DEG C when dropwise addition, pays attention to
It spumes, does not overflow material.After adding chlorosulfonic acid, the hydrogen chloride gas matter that is generated in 0-40 DEG C of reaction 1-6h, reaction
Score 5-50% sodium hydroxide solution is measured to absorb.After reaction, reaction mixture is slowly poured into and fills appropriate ice water and mixes
It closes in the processing unit of object (ice: water=1-5:1), is sufficiently stirred simultaneously, it is cooling with ice-water bath outside device.After mixing evenly,
Mass fraction 5-50% sodium hydroxide solution is added dropwise under stiring to carry out being neutralized to pH being 7-9.Mixed liquor is filtered, then by filtrate
Condensing crystallizing filters, dry, both obtains tea tree extract sodium sulphate.
Wherein, the tea tree extract is one of kinds such as camellia, oil tea, thick short stamen tea, short stamen tea or a kind of
Above extract.It is preferably made the tea tree extract that Tea Saponin content is not less than 50%.
The acquisition form of specific extract, and have no special requirements.The root of such as tea tree, stem, leaf, seed it is a kind of or it is a kind of with
Upper tissue drying crushes, juicing extraction method, crystallisation, microwave extraction method, ultrasonic extraction, solution extraction, leaching from
The tea tree that one of heart method, enzymatic treatment method, super critical extraction, fermentation method, freeze-drying or a variety of extracting methods obtain
Extract is all possible.
The builder is natural bases, and one of following or more than one mixture specifically may be selected: tree alkali, grass greatly
The wooden alkali, Peruvian bark tree bark extract, Nuciferine, nicotine, ephedrine, jamaicin, brucine, new brucine, Oxymatrine
Alkali, anisodine, leonurine, tetrahydropalmatine, demethyl coclaurine, matrine, camptothecine, basic amino acid.
The stabilizer is selected from one of following or more than one mixture: starch, agar, algin sodium, pectin,
The biomass stabilizers such as cellulose derivative, various converted starches, gum arabic, guar gum, xanthan gum.
The dispersing agent is selected from one of following or more than one mixture: water, alcohols, natural fat acids, polysaccharide
Class.The nontoxic alcohols of ethyl alcohol, ethylene glycol, glycerine may be selected in such as alcohols, and stearic acid, lemon may be selected in natural fat acids
Acid, gluconic acid etc., polysaccharide may be selected guar gum etc., other certain biological materials that can be used as dispersing agent are also can be with
's.
In the present invention, the application of tea tree extract sodium sulphate is a very big bright spot.
Tea Saponin is rich in tea tree, Tea Saponin is by different aglycons, sugared body and organic acid, with different connection type groups
At, it is a kind of natural nonionic surfactant, there are the function such as good foaming, foam stabilizing, dispersion, decontamination, emulsification, wetting
Can, while Tea Saponin also has outstanding antimicrobial antiviral activity.In addition to this, Tea Saponin derives from the extraction of natural plants,
Can be degradable by microorganism, and it is non-toxic to humans.Therefore, Tea Saponin is the ideal material for making antimicrobial form cleaning chemical products
Material.But Tea Saponin is soluble in hot water, is slightly soluble in warm water, so that the use condition of Tea Saponin cleaning chemical products is restricted.And tea
Contain a large amount of modifiable hydroxyl in saponin, the present invention is modified it using chlorosulfonic acid, and tea tree extract sodium sulphate is made
Novel surfactant, the surfactant have the advantages that anion and nonionic surface active agent simultaneously, can not only increase
Add its solubility, its dirt-removing power also can be enhanced.In addition, Tea Saponin molecule is only that a small amount of hydroxyl is modified, subject characteristic
It will not change, still there is antibacterial, antiviral ability.Meanwhile the sodium sulphate group newly introduced is non-toxic to humans, it is also easily logical
It is Tea Saponin and sulfate that hydrolysis, which is crossed, by the microorganism conversion of nature, does not influence the degradation of microorganism.Therefore, it was modified
Tea tree extract sodium sulphate not only there is outstanding antibacterial dirt-removing power, also have the characteristics that environmentally protective, harmless.
The present invention uses the tea tree extract rich in Tea Saponin as raw material, with chlorosulfonic acid through single step reaction, then passes through subsequent simple place
Reason, is made tea tree extract sodium sulphate, raw material sources are extensive, and at low cost, method of modifying is simple to operation.Still further aspect, tea
It sets in extract also containing substances such as tea polyphenols, tea tree ethereal oils, all has good sterilizing ability, further promote tea tree and extract
The bactericidal effect of object sodium sulphate.
Sodium chloride is mostly used to make flavoring agent in daily life.But in fact, bacterium can be dehydrated death in salt water, therefore
Sodium chloride has good bactericidal effect.In protein aqueous solution, sodium chloride can increase the charge on protein molecule surface,
Enhance the effect of protein and hydrone, so that the solubility of protein in aqueous solution be made to increase, therefore, sodium chloride can have
Effect removes isolating protein.And sodium chloride strong electrolyte person's character, grease can be accelerated and paste the disengaging of block, therefore, sodium chloride can also be with
Effectively remove intractable grease and paste block.
In the present invention, while using the effect of the advantage of tea tree extract sodium sulphate and sodium chloride, the effect of the two is had
Machine combines and realizes cooperative compensating, and the salt that washes the dishes developed to tableware and is washed with high-effective cleansing ability, and while washing the dishes
Bowl machine carries out depth sterilization processing, and without in addition addition fungicide.
To sum up, the present invention by tea tree extract sodium sulphate, sodium chloride, builder, stabilizer and divides by simple method
Powder is homogenously mixed together, and the amount by changing dispersing agent, realizes the preparation of solid and liquid dishwasher salt；Wherein bulk is washed
The regulation of its exterior appearance can be realized, match the sink of all dish-washing machines by the difference of molding die by washing salt.
From the composition for washing the dishes salt, the present invention cleverly utilizes effective decontamination and the sterilizing ability of tea tree extract sodium sulphate
And sodium chloride good dissolubility and sterilizing ability, the washing effect of salt so that enhancing is washed the dishes, and pass through tea tree extract sulphur
The double sterilization function of sour sodium and sodium chloride promotes the sterilizing ability for the salt that washes the dishes.And by tea tree extract sodium sulphate, sodium chloride
After characteristic cooperates with together with the effect of builder, stabilizer, dispersing agent, the salt that washes the dishes of acquisition, which is just provided with, quickly to be dissolved, is strong
Effect goes isolating protein, potent degreasing and the abilities such as sterilization.
The present invention washes the dishes salt raw material green natural, safe and non-toxic, eats by mistake rear harmless to the body, is easily biodegradable, not dirty
Environment is contaminated, quality green safe, without side-effects is highlighted；Salt decontamination of washing the dishes is thorough, in particular for protein, intractable grease
There is superpower removal ability with block etc. is pasted；Sterilizing ability is strong, raw material easily biological-degradable.The present invention salt that washes the dishes is applicable not only to house
Front yard, while being also applied for hotel, restaurant, dining room etc. places dish-washing machine uses.
It washes the dishes the preparation method of salt invention further provides the high-effective cleansing of the natural green, according to the weight ratio
Tea tree extract sodium sulphate, sodium chloride, builder is taken to be sufficiently mixed, drying and crushing obtains powdered form and washes the dishes salt later.
Or tea tree extract sodium sulphate, sodium chloride, builder mixing are taken according to the weight ratio, dispersing agent is added later and fills
Point mixing, drying and crushing and forms later, obtains bulk and washes the dishes salt.
Or tea tree extract sodium sulphate, sodium chloride, builder and stabilizer mixing, Zhi Houjia are taken according to the weight ratio
Enter dispersing agent to be sufficiently mixed uniformly, obtains liquid dishwasher salt.
In the above method, it can use the methods of ball milling or stirring and promote being sufficiently mixed for each component.
The wash the dishes preparation method of salt of the present invention is simple and convenient to operate, is easy to form, is convenient for large-scale industrial production.
Compared with the prior art, the invention has the following advantages:
The high-effective cleansing of natural green of the present invention washes the dishes salt with stability is good, potent antibacterial, strong detergency, washing
Tableware residual is low afterwards, the advantages that eating rear harmless to the body, easily biological-degradable by mistake, is environmentally friendly, is easy to be acceptable to the market and promote.
Specific embodiment
Below the technical scheme of the invention is illustrated by a specific example, but the scope of the present invention is not limited thereto:
Embodiment 1
A kind of high-effective cleansing powder shape of natural green washes the dishes salt, and preparation process in turn includes the following steps:
Weigh 20 parts of tea tree extract sodium sulphate, 50 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.Churned mechanically
Under effect, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.
Wherein tea tree extract sodium sulphate is made by laxative remedy:
(1) choosing the high-quality Wild Camellia oleifera Abel seed in Hunan Huaihua is raw material, tea seed cake is made after manually squeezing de-oiling, by tea seed cake powder
It is broken, tea tree extract is then made by ultrasonic wave assisted extraction method:
(tea seed cake and water quality ratio are put into ultrasonic oscillation instrument for 1:5), at 25~30 DEG C for tea seed cake and water after crushing
Ultrasonic oscillation for a period of time, obtains leaching liquor after tea seed cake is separated.Isolated tea seed cake is used flooding 3 times again, merges institute
There is leaching liquor.Leaching liquor is cleaned with cationic starch flocculant, is filtered to get filtrate, then filtrate is depressurized to steaming between 60-70 DEG C
Hair concentration, crystallisation by cooling filter, dry, obtain the tea tree extract containing 90% Tea Saponin.
(2) it is added tea tree extract in a kettle, 20 DEG C of temperature control, in the case where being sufficiently stirred in chlorine is slowly added dropwise in 60min
Sulfonic acid (mass ratio of tea tree extract and chlorosulfonic acid be 3.5:1), temperature does not exceed 20 DEG C when dropwise addition, pays attention to spuming, not
Overflow material.Add hydrogen chloride gas 40% hydrogen-oxygen of mass fraction generated in 20 DEG C of reaction 3h, reaction after chlorosulfonic acid
Change sodium solution to absorb.After reaction, reaction mixture is slowly poured into the processing unit for filling appropriate mixture of ice and water
(ice: water=4:1), is sufficiently stirred simultaneously, cooling with ice-water bath outside device.After mixing evenly, quality point is added dropwise under stiring
Several 40% sodium hydroxide solutions carry out being neutralized to pH being 7.Mixed liquor is filtered, then by filtrate condensing crystallizing, is filtered, dry, system
Obtain tea tree extract sodium sulphate.
Embodiment 2
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 18 parts of tea tree extract sodium sulphate, 52 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.Churned mechanically
Under effect, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Its
The preparation method of middle tea tree extract sodium sulphate such as embodiment 1.
Embodiment 3
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 16 parts of tea tree extract sodium sulphate, 54 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.Churned mechanically
Under effect, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Its
The preparation method of middle tea tree extract sodium sulphate such as embodiment 1.
Embodiment 4
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 14 parts of tea tree extract sodium sulphate, 56 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.Churned mechanically
Under effect, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Its
The preparation method of middle tea tree extract sodium sulphate such as embodiment 1.
Embodiment 5
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 12 parts of tea tree extract sodium sulphate, 58 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.Churned mechanically
Under effect, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Its
The preparation method of middle tea tree extract sodium sulphate such as embodiment 1.
Embodiment 6
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 10 parts of tea tree extract sodium sulphate, 60 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.Churned mechanically
Under effect, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Its
The preparation method of middle tea tree extract sodium sulphate such as embodiment 1.
Embodiment 7
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.In churned mechanically work
Under, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 8
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 6 parts of tea tree extract sodium sulphate, 64 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.In churned mechanically work
Under, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 9
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 4 parts of tea tree extract sodium sulphate, 66 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.In churned mechanically work
Under, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 10
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 2 parts of tea tree extract sodium sulphate, 68 parts of sea salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.In churned mechanically work
Under, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 11
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 62 parts of lake salt, 20 parts of vegetation alkali, 10 parts of Nuciferines.In churned mechanically work
Under, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Wherein
The preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 12
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 50 parts of sea salt, 12 parts of camptothecines, 20 parts of vegetation alkali, 10 parts of Nuciferines.?
Under the action of mechanical stirring, each component is uniformly mixed, through drying, is crushed, the high-effective cleansing powder shape that natural green is made is washed
Bowl product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 13
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 40 parts of sea salt, 10 parts of Peruvian bark tree bark extracts, 12 parts of basic amino acids,
20 parts of vegetation alkali, 10 parts of Nuciferines.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, day is made
So the high-effective cleansing powder shape of green washes the dishes product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 14
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 22 parts big tree alkali, 10 parts of leonurines, 20 parts of vegetation alkali,
10 parts of Nuciferines.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, the efficient of natural green is made
The powdered product salt that washes the dishes of decontamination.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 15
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 20 parts of sea salt, 20 parts of oxymatrines, 22 parts of camptothecines, 20 portions of vegetations
Alkali, 10 parts of Nuciferines.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, natural green is made
High-effective cleansing powder shape washes the dishes product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 16
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 30 parts of rock salt, 10 parts of anisodines, 20 parts of vegetation alkali, 10 parts of Nuciferines, 12
Part basic amino acid, 10 parts of Peruvian bark tree bark extracts.Under the action of mechanical stirring, each component is uniformly mixed, through drying,
It crushes, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.Wherein the preparation method of tea tree extract sodium sulphate is such as
Embodiment 1.
Embodiment 17
The wash the dishes preparation process of salt of the high-effective cleansing bulk of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 52 parts of sea salt, 15 parts of vegetation alkali, 10 parts of Nuciferines, 15 parts of natural lemon acid
Sodium, 3 parts of ethylene glycol.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, then passes through press machine,
In suitable mold, said mixture is formed, the high-effective cleansing bulk that natural green is made washes the dishes product salt.Wherein tea tree
The preparation method of extract sodium sulphate such as embodiment 1.
Embodiment 18
The wash the dishes preparation process of salt of the high-effective cleansing bulk of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 15 parts of vegetation alkali, 14 parts of matrines, 10 parts of basic amine groups
Acid, 10 parts of jamaicins, 10 parts of food-grade sodium gluconates, 3 parts of glycerine.Under the action of mechanical stirring, each component is mixed
Uniformly, through drying, crushing, then said mixture is formed in suitable mold by press machine, natural green is made
High-effective cleansing bulk wash the dishes product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 19
The wash the dishes preparation process of salt of the high-effective cleansing bulk of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 40 parts of sea salt, 12 parts of vegetation alkali, 15 parts of Peruvian bark tree bark extracts, 10 parts
Camptothecine, 10 parts of natural lemon acid sodium, 1 part of guar gum, 4 parts of ethyl alcohol.Under the action of mechanical stirring, each component is mixed equal
It is even, it through drying, crushes, is then formed said mixture in suitable mold by press machine, natural green is made
High-effective cleansing bulk washes the dishes product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 20
The preparation process of the liquid salt that washes the dishes of the high-effective cleansing of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 30 parts of sea salt, 15 parts of vegetation alkali, 15 parts of Nuciferines, 0.5 part of agar, 3 parts
Ethylene glycol, 10 parts of ethyl alcohol, 31.5 parts of water.Mechanical stirring is carried out, until being uniformly mixed, the high-effective cleansing liquid of natural green is made
Body washes the dishes product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 21
The preparation process of the liquid salt that washes the dishes of the high-effective cleansing of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 35 parts of sea salt, 12 parts big tree alkali, 12 portions of new brucine, 0.1 portion of food
Level sodium carboxymethylcellulose, 3 parts of glycerine, 12 parts of ethyl alcohol, 32.9 parts of water.Mechanical stirring is carried out, until being uniformly mixed, is made
The high-effective cleansing liquid dishwasher product salt of natural green.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Embodiment 22
The preparation process of the liquid salt that washes the dishes of the high-effective cleansing of natural green includes the following steps:
Weigh 8 parts of tea tree extract sodium sulphate, 40 parts of sea salt, 10 parts big tree alkali, 10 parts of new brucine, 0.5 portion of algae egg
White acid sodium, 1 part of ethylene glycol, 8 parts of ethyl alcohol, 31.5 parts of water.Mechanical stirring is carried out, until being uniformly mixed, natural green is made
High-effective cleansing liquid dishwasher product salt.The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Comparative example
Comparative example 1 (uses not modified tea tree extract)
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green in turn includes the following steps in this comparative example:
Weigh 8 parts of tea tree extracts, 30 parts of sea salt, 22 parts big tree alkali, 10 parts of leonurines, 20 parts of vegetation alkali, 10 portions of lotuses
Leaf alkali.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, the high-efficiency cleaning powder of natural green is made
Last shape washes the dishes product salt.
The wherein preparation method of tea tree extract such as embodiment 1.
(sodium chloride is not added) in comparative example 2
The preparation process of the high-effective cleansing liquid dishwasher salt of natural green in turn includes the following steps in this comparative example:
Weigh 8 parts of tea tree extract sodium sulphate, 15 parts of vegetation alkali, 15 parts of Nuciferines, 0.5 part of agar, 3 parts of ethylene glycol, 10
Part ethyl alcohol, 48.5 parts of water.Mechanical stirring is carried out, until being uniformly mixed, the high-effective cleansing liquid dishwasher salt of natural green is made
Product.
The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
(builder is not added) in comparative example 3
The wash the dishes preparation process of salt of the high-effective cleansing powder shape of natural green in turn includes the following steps in this comparative example:
Weigh 8 parts of tea tree extract sodium sulphate, 92 parts of sea salt.Under the action of mechanical stirring, each component is uniformly mixed,
It through drying, crushes, the high-effective cleansing powder shape that natural green is made washes the dishes product salt.
The wherein preparation method of tea tree extract sodium sulphate such as embodiment 1.
Comparative example 4 (replaces tea tree extract sodium sulphate using Tea Saponin sulfuric ester)
In this comparative example the high-effective cleansing powder shape of natural green wash the dishes salt preparation process it is as follows:
Weigh 8 parts of Tea Saponin sulfuric esters, 30 parts of sea salt, 22 parts big tree alkali, 10 parts of leonurines, 20 parts of vegetation alkali, 10 parts
Nuciferine.Under the action of mechanical stirring, each component is uniformly mixed, through drying, crushes, the high-effective cleansing of natural green is made
The powdered product salt that washes the dishes.
Wherein the preparation method of Tea Saponin sulfuric ester uses that application No. is the methods of embodiment 1 in 201410053599.5.
Effect experiment:
1, it is tested using the true washing effect of dish-washing machine:
Copy manual dishwashing with gone in detergent standard GB/T 9985-2000 oil cut rate method to above embodiments and right
Ratio detergent carries out true detergency test in dishwasher into operation condition: by clean plate with electronic scale be precisely weighed for
m0, then by a certain amount of artificial dirt (miscella 15%, wheat flour 15%, whole milk powder 7.5%, fresh whole egg liquid
30%, distilled water 32.5%, mass ratio) it is coated on plate, 4h is hung at room temperature, to imitate stain.Then electricity consumption
Plate after defiling is precisely weighed as m by sub- scale1.Plate after defiling is placed on the wash stand in certain brand dish-washing machine,
The corresponding detergent of 15g is added in detergent tank, setting wash temperature is 30 DEG C, and setting wash time is 10min, is then started
Power supply starts to wash.After washing, plate is taken out, after being rinsed 2 times with clear water, places hang on the top of the shelf at room temperature
The correct amount after 3h that dries in the air is m2。
Use the true washing effect of dish-washing machine
Test result is as follows:
Use the true washing effect test result of dish-washing machine
2, antibiotic property is tested:
According to antibacterial bacteriostatic detergent industry standard QB/T 2738-2005 to above embodiments and comparative example detergent
It carries out antibiotic property test: the above detergent use Sterile standard hard water being dissolved to defined concentration, cleaning solution 5.0mL is drawn and puts
Enter in sterilizing test tubes, 20 DEG C of constant temperature 5min, then draws test bacteria liquid 0.1mL and be added in the test tube of the sample containing 5.0mL, rapidly
It mixes, and timing immediately.After effect to setting time, the mixed liquor 0.1mL of test organisms and sample is taken, is added to and is passed through containing 5.0mL
In the test tube of the neutralizer of sterilizing, mix.After neutralizing 10min, sample liquid 1mL is drawn, is placed in sterilizing plates, each sample liquid or dilute
It releases liquid and is inoculated with two sterilizing plates.It is poured into cool to 40-45 DEG C of nutrient agar 15mL, rotates plate, fill it
Divide uniformly, plate is overturn after agar solidification, (35 ± 2) DEG C culture 48h does the counting of viable bacteria bacterium colony, and compares with control sample, counts
Calculate sterilizing rate.
Test result is as follows:
Antibiotic rate test result
Note: sterilizing rate 1- is directed to staphylococcus aureus；Sterilizing rate 2- is directed to escherichia coli.
3, detergent measures examination:
Using the residual quantity of anionic surfactant in methylene blue laws measurement washing effect, the specific method is as follows:
Plate is washed using above embodiments and comparative example detergent in dish-washing machine, appropriate deionization is used after washing
Water rinses plate, pipettes appropriate rinsing test solution in 250mL separatory funnel, adds water to 100mL, chloroform is added
For 5mL in separatory funnel, repetition is extracted to that chloroform layer is colourless, all chloroform layers through absorbent cotton filter to
In 100mL volumetric flask, then with a little chloroform elution absorbent cotton, constant volume is mixed.With spectrophotometer under wavelength 650nm
Measure absorbance, reference standards curve determination content.
Test result is as follows:
Detergent measures test result
It is any ripe although the present invention is disclosed as above with embodiment, its protection scope being not intended to limit the invention
The technical staff for knowing this technology changes and retouches made without departing from the spirit and scope of the invention, should belong to this
The protection scope of invention.
Claims (10)
- The salt 1. a kind of high-effective cleansing of natural green washes the dishes, which is characterized in that the parts by weight composition of the salt that washes the dishes is as follows:1-20 parts of tea tree extract sodium sulphate, 10-90 parts of sodium chloride, 5-90 parts of builder, 0-5 parts of stabilizer, dispersing agent 0-40 Part.
- The salt 2. high-effective cleansing of natural green as described in claim 1 washes the dishes, which is characterized in that the tea tree extract sulfuric acid Sodium is obtained by laxative remedy: under conditions of control temperature is not higher than 40 DEG C, chlorosulfonic acid being mixed with tea tree extract, later in 0- Reaction product is isolated and purified obtain the tea tree extract sodium sulphate later by 40 DEG C of reaction 1-6 h.
- The salt 3. high-effective cleansing of natural green as claimed in claim 2 washes the dishes, which is characterized in that the tea tree extract is The mass ratio of tea tree extract of the Tea Saponin content not less than 50%, tea tree extract and chlorosulfonic acid is 1-5:1.
- The salt 4. high-effective cleansing of natural green as claimed in claim 2 washes the dishes, which is characterized in that described isolates and purifies to incite somebody to action Reaction product is poured into mixture of ice and water, is sufficiently stirred in the case where ice-water bath is cooling, is later 7-9 with alkali neutralization to pH, it Filtering, filtrate condensing crystallizing afterwards obtain tea tree extract sodium sulphate after filtering and dry again.
- The salt 5. high-effective cleansing of natural green as claimed in claim 4 washes the dishes, which is characterized in that in the mixture of ice and water The mass ratio of ice and water is 1-5:1.
- The salt 6. high-effective cleansing of natural green as described in claim 1 washes the dishes, which is characterized in that the builder is natural Bases；The stabilizer is selected from one of following or more than one mixture: starch, agar, algin sodium, pectin, fiber Plain derivative, various converted starches, gum arabic, guar gum, xanthan gum；The dispersing agent is selected from one of following or one Kind or more mixture: water, alcohols, natural fat acids, polysaccharide.
- The salt 7. high-effective cleansing of natural green as described in claim 1 washes the dishes, which is characterized in that the height of the natural green Effect decontamination washes the dishes salt as powder, bulk or liquid；The high-effective cleansing of the natural green washes the dishes salt as powder, and the parts by weight composition for the salt that washes the dishes is as follows: tea tree extract sulphur Sour sodium 2-20 parts, 20-70 parts of sodium chloride, 20-80 parts of builder；The high-effective cleansing of the natural green washes the dishes salt as bulk, and the parts by weight composition of the salt that washes the dishes is as follows: tea tree is extracted 2-20 parts of object sodium sulphate, 20-60 parts of sodium chloride, 20-70 parts of builder, 1-5 parts of dispersing agent；The high-effective cleansing of the natural green wash the dishes salt be it is liquid, the parts by weight of the salt that washes the dishes composition is as follows: tea tree mentions Take 2-20 parts of object sodium sulphate, 20-40 parts of sodium chloride, 20-40 parts of builder, 25-40 parts of dispersing agent, 0.1-0.5 parts of stabilizer.
- The preparation method of salt 8. the high-effective cleansing of any natural green of claim 1-7 washes the dishes, which is characterized in that according to weight Amount proportion takes tea tree extract sodium sulphate, sodium chloride, builder to be sufficiently mixed, and drying and crushing obtains powdered form and washes the dishes salt later.
- The preparation method of salt 9. the high-effective cleansing of any natural green of claim 1-7 washes the dishes, which is characterized in that according to weight Amount proportion takes tea tree extract sodium sulphate, sodium chloride, builder mixing, and dispersing agent is added later and is sufficiently mixed, later xeraphium It is broken and by press machine punch forming, it obtains bulk and washes the dishes salt.
- The preparation method of salt 10. the high-effective cleansing of any natural green of claim 1-7 washes the dishes, which is characterized in that according to Weight proportion takes tea tree extract sodium sulphate, sodium chloride, builder and stabilizer mixing, and dispersing agent is added later and is sufficiently mixed Uniformly, liquid dishwasher salt is obtained.
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Cited By (1)
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Application publication date: 20190823 |