CN110148671A - Organic electronic device encapsulation multilayer light-cured resin covers packaging method comprehensively - Google Patents

Organic electronic device encapsulation multilayer light-cured resin covers packaging method comprehensively Download PDF

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Publication number
CN110148671A
CN110148671A CN201910292615.9A CN201910292615A CN110148671A CN 110148671 A CN110148671 A CN 110148671A CN 201910292615 A CN201910292615 A CN 201910292615A CN 110148671 A CN110148671 A CN 110148671A
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Prior art keywords
electronic device
organic electronic
comprehensively
packaging method
cured resin
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CN201910292615.9A
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Chinese (zh)
Inventor
林群
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Nanjing Fushibao New Materials Co Ltd
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Nanjing Fushibao New Materials Co Ltd
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Priority to CN201910292615.9A priority Critical patent/CN110148671A/en
Publication of CN110148671A publication Critical patent/CN110148671A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/80Constructional details
    • H10K10/88Passivation; Containers; Encapsulations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80Constructional details
    • H10K30/88Passivation; Containers; Encapsulations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/84Passivation; Containers; Encapsulations
    • H10K50/844Encapsulations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

The invention discloses a kind of organic electronic device encapsulation multilayer light-cured resins to cover packaging method comprehensively, specifically: it passes sample and enters in nitrogen glove box, film inertia UV solidifies protective glue on organic assembly.High water oxygen barrier UV solidification glue (high water oxygen barrier film) on glass or flexible cover plate of film covers the encapsulation coating that film is completed on sample in nitrogen glove box simultaneously, smooth pressing.Device is put into solidification under uv lamps and completes encapsulation and bonding.Compared with prior art, the invention has the following beneficial effects: packaging technologies and material in view of the protection to device, while encapsulation being rapidly completed as far as possible, reduces the risk of device damage.In encapsulation process, encapsulated layer can be covered on above device comprehensively, reduce etching, positioning printing and etc..This can protect device accidental injury, can also be improved film rate and reduce process costs.

Description

Organic electronic device encapsulation multilayer light-cured resin covers packaging method comprehensively
Technical field
The invention belongs to organic electronic devices to encapsulate studying technological domain, in particular to a kind of organic electronic device encapsulation is more Layer light-cured resin covers packaging method comprehensively.
Background technique
Novel organic electronic device, organic light emission, organic electro-optic device, organic detectors and organic field-effect tube due to The advantages that its own frivolous, energy saving and self-luminous, power generation, in display and solid-state lighting, the energy, detector, mobile phone is wearable Field has broad application prospects.Its outstanding characteristic will affect the exploitation of next-generation display electronic product, be flexible electronic The main force of display.
However according to long-term, a large amount of organic electronics studies have shown that the steam and oxygen gas component in air to Organic Electricity Sub- device has fatal influence, and it is various that reason mainly has steam and oxygen molecule to have organic and other each nanometer thin film layers Different reactions and influence, to there is very big harm to the integral device service life.If can be carried out to organic electro-optic device The encapsulation of effect stops steam/oxygen to touch each organic function layer, so that it may greatly improve device lifetime.
As many novel encapsulation coating materials and direct combination encapsulating structure are invented and are used, organic electronic device Packaging effect and performance obtained huge promotion, and existing high encapsulation, the organic electronic display screen of long-life is It emerges.But organic electronic device packaging technology is complicated, with high costs, the disadvantages such as packaging efficiency is low cause the production capacity of organic assembly Lowly, at high cost, the device is complicated changes, and especially to large area, the encapsulation of flexible device has great difficulty and challenge, such as OLED large screen, organic field-effect tube, the encapsulation such as organic solar batteries.Additionally due to organic electronic device, especially flexible Thickness of detector is very thin, and material and nanometer layer are very sensitive and fragile, and encapsulating structure and the improper of technique easily cause production The damage and damage of product, cause the decline of yields.
The information disclosed in the background technology section is intended only to increase the understanding to general background of the invention, without answering When being considered as recognizing or imply that the information constitutes the prior art already known to those of ordinary skill in the art in any form.
Summary of the invention
The purpose of the present invention is to provide a kind of organic electronic device encapsulation multilayer light-cured resins to cover encapsulation side comprehensively The problems such as method, structure is complicated to overcome in current organic packages structure, and step is various, and at high cost and speed of production is slow.
To achieve the above object, the present invention provides a kind of organic electronic device encapsulation multilayer light-cured resins to cover comprehensively Packaging method, comprising: S1 prepares organic electronic device or organic function layer in substrate;The inertia light of S2 coating on it is solid Change the high-barrier photocurable layers on layer, and encapsulation cover plate;S3 will be coated with resin cover plate and be covered in the solidification glue of substrate, Light repoussage encapsulates cover plate, and disposable UV irradiation solidification, wherein step S2 and S3 is carried out in inert gas environment.
Preferably, in above-mentioned technical proposal S1, substrate is selected from metal, quartzy, silica, glass, the hard materials such as silicon wafer, It is also possible to the flexiplast of various high water oxygen barriers, polymer, resin material.
Preferably, in above-mentioned technical proposal S1, organic electronic device and organic function layer are selected from organic luminescent device OLED, quantum luminescent device GLED, polymer light-emitting device PLED, small organic molecule, polymer, perovskite photoelectric device, light Electric explorer and solar battery and organic, polymer field-effect tube.
Preferably, in above-mentioned technical proposal S2, inertia photocuring glue-line, material is selected from light-cured resin, light-solidifying poly Close object.It is not damaged to organic electronic device, it is reactionless.
Preferably, in above-mentioned technical proposal S2, inertia photocuring glue-line can be scratched, sprinkling, roll- by spin coating To-roll, the liquid films method such as printing are completed.
Preferably, in above-mentioned technical proposal S2, inertia photocuring glue-line, thickness can be from 0.1-10 microns.
Preferably, in above-mentioned technical proposal S2, encapsulation cover plate is selected from the metal that high water oxygen stops, glass, silicon wafer, oxidation The fexible film that silicon, metal oxide and high water oxygen stop, one of substrate.
Preferably, in above-mentioned technical proposal S2, high-barrier photocurable layers can obstruct UV solidified resin selected from high water oxygen, Polymer etc..
Preferably, in above-mentioned technical proposal S2, high-barrier photocurable layers, thickness can be from 1-50 microns.
Preferably, in above-mentioned technical proposal S3, resin cover plate will be coated with and be covered in the solidification glue of substrate, can be portion Divide covering, can also be encapsulated with all standing.
Preferably, in above-mentioned technical proposal S3, light repoussage encapsulates cover plate, can be flat metal, silicon wafer, glass Deng making gas in two kinds of solidification glues be discharged and eliminate gap.
Preferably, in above-mentioned technical proposal S3, disposable UV irradiation solidification, is that once irradiating is completed at the same time two layers of solidification glue While solidify.
Preferably, in above-mentioned technical proposal S2, inertia photocuring glue-line and high-barrier cured layer can be monolayer immobilization tree Rouge/glue, and be multilayer film layer.
Basic principle of the invention is that inertia protection solidification glue and high water oxygen obstruct packaging plastic separate type film, remerges exposure UV light completes disposal solidifying and encapsulation.After completing encapsulation, sample, inertia packaging plastic, high water oxygen barrier packaging plastic and above Encapsulation covering version complete seamless disposal solidifying adhesion.Due to the gradually plated film work of the multilayered structure of reduction in whole process Skill, all using optic-solidified adhesive, coating process and material are relatively simple, and technique can significantly simplify.2 kinds of solidification glues can be with simultaneously It is completed at the same time film, another rise merges, and package speed and condition are unified, greatly reduces process costs and improves production speed Degree.In addition, we use, property exposure curing again after the covering of 2 kinds of solidification glues merges, two kinds of colloids for being before curing can be with Interface efficiently combine wants to permeate, greatly reduce and occur defect in gradually encapsulation process, localized voids can not adhesion the case where. It protects device from damage as first layer by inertia solidification glue, completes to be completed at the same time resistance after mixed two layers of solidification adhesive curing The work of water blocking Oxygen permeation, and cover plate is encapsulated on device top in perfect adhesion.Other packaging plastic films and solidification process It is all real to complete in an inert atmosphere, such as completed in the glove box of nitrogen, argon gas inert gas.This simple packaging technology Reduce sample transmission step and time, equipment cost.Water and oxygen content should be less than 1 Ppm in glove box.In encapsulation process The substrate of use is the flexible substrates that glass and high water oxygen stop, and organic electronic device is used to water oxygen and thermo-responsive organic small Mulecular luminescence device (OLED).Top encapsulated layer is hindered using high water oxygen barrier UV solidified resin film in glass glass or high water oxygen In the flexible substrates of gear, inertia protects optic-solidified adhesive film on organic assembly.It is covered on sample by upper encapsulated layer, once UV solidification.
Specific encapsulating structure and encapsulation emphasis are as follows:
1. passing sample to enter in nitrogen glove box, film inertia UV solidifies protective glue on organic assembly.
2. the high water oxygen barrier UV solidification glue of film (high water oxygen resistance on glass or flexible cover plate in nitrogen glove box simultaneously Diaphragm).
3. the encapsulation coating that film is completed is covered on sample, smooth pressing.
4. device, which is put solidification under uv lamps, completes encapsulation and bonding.
Compared with prior art, the guarantor to device is considered the invention has the following beneficial effects: packaging technology and material Shield, while encapsulation being rapidly completed as far as possible, reduce the risk of device damage.In encapsulation process, encapsulated layer can be covered on comprehensively Above device, reduce etching, positioning printing and etc..This can protect device accidental injury, can also be improved film speed Rate and reduction process costs.
This programme can increase substantially the efficiency of encapsulation in existing encapsulating structure and reduce packaging cost, have following excellent Point:
It A. will not damage device with the inertia cured layer of device contacts.
B. high-barrier cured layer has good water oxygen barriering efficiency.
C. multiple layers of cured glue can use quickly, and easy method completes film.
D. multiple layers of cured glue cannot destroy mutually.
E. the seamless adhesion of multiple layers of cured glue.
Simple 1, whole solidifications can be completed in 2 UV irradiations.
Detailed description of the invention:
The large area encapsulation scheme structure and flow diagram that Fig. 1 multilayer light-cured resin covers comprehensively.
In figure: glass or flexible substrate (high water oxygen barrier) 1, organic electronic device or functional layer 2, inertia UV solidification glue 3, Top package board (glass, flexible substrate) 4, high water oxygen obstruct UV solidification glue 5.
Specific embodiment:
Specific embodiments of the present invention will be described in detail below, it is to be understood that protection scope of the present invention is not had The limitation of body embodiment.
Unless otherwise explicitly stated, otherwise in entire disclosure and claims, term " includes " or its change Changing such as "comprising" or " including " etc. will be understood to comprise stated element or component, and not exclude other Element or other component parts.
According to the design and processes of invention, encapsulation scheme is very simple, practical, using following steps:
The first step, be ready to can glass or high-barrier flexible PET substrate, surface can be cleaned.And it is put into vacuum drying Steam and oxygen of the case removal more than absorption.It is raw that glass or high-barrier flexible PET substrate are put into organic light-emitting diode equipment Long and preparation OLED device.
Sample is passed to 20 degree by second step, and water, oxygen is less than in the nitrogen glove box of 1ppm.Pass through spin coating proceeding film One layer of inertia UV solidified resin is about 1-2 microns thick.
Third step, while second step, the film 5 on the glass of encapsulation covering or high-barrier flexible PET cover plate The thick inertia high-barrier packaging plastic of micron.
4th step, encapsulation coating are placed on sample, and with smooth glass, silicon wafer is pressed lightly on.This can make two kinds of UV Glue perfection combines, and intermediate gas and removal gap is discharged.
5th step opens UV lamp and irradiates entire sample cure package coating, complete after 2-4 minutes on the basis of four steps Device solidification.
1 packaging time of list compares (laboratory hand operation)
Testing scheme Packaging time Sealed in unit Encapsulating material
Metal oxide/UV solidification glue encapsulation scheme 4-5 hours CVD/ vacuum chamber, film applicator, UV lamp Metal oxide, UV solidification glue.
Encapsulation scheme of the present invention 10-15 minutes Nitrogen glove box, film applicator, UV lamp 2 kinds of UV solidification glues
, it is much higher than UV solidification glue with cost the time required to metal oxide plated film as can be known from the above table.
Selection scheme as one preferred, substrate is selected from metal, quartzy, silica, glass, the hard materials such as silicon wafer, It is also possible to the flexiplast of various high water oxygen barriers, polymer, resin material.
Selection scheme as one preferred, organic electronic device and organic function layer are selected from organic luminescent device OLED, quantum luminescent device GLED, polymer light-emitting device PLED, small organic molecule, polymer, perovskite photoelectric device, light Electric explorer and solar battery and organic, polymer field-effect tube.
Selection scheme as one preferred, inertia photocuring glue-line, material are selected from light-cured resin, light-solidifying poly Close object.It is not damaged to organic electronic device, it is reactionless.
Selection scheme as one preferred, inertia photocuring glue-line can be scratched, sprinkling, roll- by spin coating To-roll, the liquid films method such as printing are completed.
Selection scheme as one preferred, inertia photocuring glue-line, thickness can be from 0.1-10 microns.
Selection scheme as one preferred, encapsulation cover plate are selected from the metal that high water oxygen stops, glass, silicon wafer, oxidation The fexible film that silicon, metal oxide and high water oxygen stop, one of substrate.
Selection scheme as one preferred, high-barrier photocurable layers can obstruct UV solidified resin selected from high water oxygen, gather Close object etc..
Selection scheme as one preferred, high-barrier photocurable layers, thickness can be from 1-50 microns.
Selection scheme as one preferred will be coated with resin cover plate and be covered in the solidification glue of substrate, can be portion Divide covering, can also be encapsulated with all standing.
Selection scheme as one preferred, light repoussage encapsulate cover plate, can be flat metal, silicon wafer, glass etc., The gas in two kinds of solidification glues is set to be discharged and eliminate gap.
Selection scheme as one preferred, disposable UV irradiation solidification, is that once irradiating is completed at the same time two layers of solidification glue While solidify.
Selection scheme as one preferred, inertia photocuring glue-line and high-barrier cured layer can be monolayer immobilization tree Rouge/glue, and be multilayer film layer.
The aforementioned description to specific exemplary embodiment of the invention is in order to illustrate and illustration purpose.These descriptions It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can much be changed And variation.The purpose of selecting and describing the exemplary embodiment is that explaining specific principle of the invention and its actually answering With so that those skilled in the art can be realized and utilize a variety of different exemplary implementation schemes of the invention with And various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (13)

1. organic electronic device encapsulation multilayer light-cured resin covers packaging method comprehensively characterized by comprising S1 preparation exists Organic electronic device or organic function layer in substrate;In the inertia photocurable layers of S2 coating on it, and encapsulation cover plate High-barrier photocurable layers;S3 will be coated with resin cover plate and be covered in the solidification glue of substrate, light repoussage encapsulation cover plate, and one Secondary property UV irradiation solidification, wherein step S2 and S3 is carried out in inert gas environment.
2. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S1, substrate is selected from metal, quartzy, silica, glass, the hard materials such as silicon wafer, is also possible to various high water oxygens resistances Every flexiplast, polymer, resin material.
3. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S1, organic electronic device and organic function layer are selected from organic luminescent device OLED, quantum luminescent device GLED, Polymer light-emitting device PLED, small organic molecule, polymer, perovskite photoelectric device, photodetector and solar battery, with And organic, polymer field-effect tube.
4. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S2, inertia photocuring glue-line, material is selected from light-cured resin, photo-curable polymer.
5. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S2, inertia photocuring glue-line can be scratched, sprinkling, roll-to-roll, the liquid films such as printing by spin coating Method is completed.
6. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S2, inertia photocuring glue-line, thickness can be from 0.1-10 microns.
7. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S2, encapsulation cover plate is selected from the metal that high water oxygen stops, glass, silicon wafer, silica, metal oxide, Yi Jigao The fexible film that water oxygen stops, one of substrate.
8. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S2, high-barrier photocurable layers can obstruct UV solidified resin, polymer etc. selected from high water oxygen.
9. organic electronic device encapsulation multilayer light-cured resin according to claim 1 covers packaging method, special comprehensively Sign is, in S2, high-barrier photocurable layers, thickness can be from 1-50 microns.
10. organic electronic device encapsulation multilayer light-cured resin covers packaging method, feature according to claim 1 comprehensively It is, in S3, resin cover plate will be coated with and be covered in the solidification glue of substrate, can be part covering, can also be sealed with all standing Dress.
11. organic electronic device encapsulation multilayer light-cured resin covers packaging method, feature according to claim 1 comprehensively It is, in S3, light repoussage encapsulates cover plate, can be flat metal, silicon wafer, glass etc. makes the gas in two kinds of solidification glues Discharge and elimination gap.
12. organic electronic device encapsulation multilayer light-cured resin covers packaging method, feature according to claim 1 comprehensively It is, in S3, disposable UV irradiation solidification, is solidification while once irradiating is completed at the same time two layers of solidification glue.
13. organic electronic device encapsulation multilayer light-cured resin covers packaging method, feature according to claim 1 comprehensively It is, in S2, inertia photocuring glue-line and high-barrier cured layer can be monolayer immobilization resin/glue, and be multilayer film layers.
CN201910292615.9A 2019-04-12 2019-04-12 Organic electronic device encapsulation multilayer light-cured resin covers packaging method comprehensively Pending CN110148671A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110676391A (en) * 2019-09-27 2020-01-10 苏州威格尔纳米科技有限公司 Packaging method of perovskite thin film battery pack
CN110838547A (en) * 2019-11-08 2020-02-25 福仕保(江苏)新材料有限公司 Vacuum sputtering mixed light-cured resin packaging process for organic electronic device
CN110838544A (en) * 2019-11-08 2020-02-25 福仕保(江苏)新材料有限公司 Integrated structure design and preparation process for preparing and packaging ultrathin flexible organic electronic device
CN111240131A (en) * 2020-03-17 2020-06-05 中国科学院云南天文台 Manufacturing method of transparent hemispherical cover and transparent hemispherical cover
WO2024097417A1 (en) * 2022-11-04 2024-05-10 Caelux Corporation Encapsulated perovskite modules and solar cells containing the same

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Publication number Priority date Publication date Assignee Title
CN110676391A (en) * 2019-09-27 2020-01-10 苏州威格尔纳米科技有限公司 Packaging method of perovskite thin film battery pack
CN110838547A (en) * 2019-11-08 2020-02-25 福仕保(江苏)新材料有限公司 Vacuum sputtering mixed light-cured resin packaging process for organic electronic device
CN110838544A (en) * 2019-11-08 2020-02-25 福仕保(江苏)新材料有限公司 Integrated structure design and preparation process for preparing and packaging ultrathin flexible organic electronic device
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CN111240131A (en) * 2020-03-17 2020-06-05 中国科学院云南天文台 Manufacturing method of transparent hemispherical cover and transparent hemispherical cover
WO2024097417A1 (en) * 2022-11-04 2024-05-10 Caelux Corporation Encapsulated perovskite modules and solar cells containing the same

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Application publication date: 20190820