CN109943046A - 一种增强增韧膨胀阻燃剂的制备方法 - Google Patents
一种增强增韧膨胀阻燃剂的制备方法 Download PDFInfo
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- CN109943046A CN109943046A CN201910179936.8A CN201910179936A CN109943046A CN 109943046 A CN109943046 A CN 109943046A CN 201910179936 A CN201910179936 A CN 201910179936A CN 109943046 A CN109943046 A CN 109943046A
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 239000013078 crystal Substances 0.000 claims abstract description 54
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 36
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 36
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 9
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 8
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 70
- 239000004626 polylactic acid Substances 0.000 claims description 70
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 30
- 239000002131 composite material Substances 0.000 claims description 28
- 239000003963 antioxidant agent Substances 0.000 claims description 20
- 230000003078 antioxidant effect Effects 0.000 claims description 20
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 18
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 15
- 239000000908 ammonium hydroxide Substances 0.000 claims description 15
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 15
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- XQQSWXUDAPLMKD-UHFFFAOYSA-N N,N-dimethylheptadecan-1-amine hydrobromide Chemical compound Br.CCCCCCCCCCCCCCCCCN(C)C XQQSWXUDAPLMKD-UHFFFAOYSA-N 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 229910052681 coesite Inorganic materials 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims description 5
- 229960004756 ethanol Drugs 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- XZWYZXLIPXDOLR-UHFFFAOYSA-N metformin Chemical compound CN(C)C(=N)NC(N)=N XZWYZXLIPXDOLR-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
- 229910052905 tridymite Inorganic materials 0.000 claims description 5
- 238000002604 ultrasonography Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 18
- 230000002708 enhancing effect Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 9
- 229920000642 polymer Polymers 0.000 abstract description 8
- 150000001412 amines Chemical class 0.000 abstract description 2
- 238000005119 centrifugation Methods 0.000 abstract description 2
- 239000012757 flame retardant agent Substances 0.000 abstract description 2
- 229920000137 polyphosphoric acid Polymers 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 20
- 235000006708 antioxidants Nutrition 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000005253 cladding Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6548586B1 (en) * | 2001-02-22 | 2003-04-15 | Council Of Scientific & Industrial Research | Composition useful for making in-situ silicon carbide whiskers and fibres |
CN102002184A (zh) * | 2010-10-08 | 2011-04-06 | 华南理工大学 | 一种增强增韧无卤阻燃聚丙烯混合物及其制备方法 |
CN103772929A (zh) * | 2014-01-24 | 2014-05-07 | 严兵 | 一种全降解高分子复合物及制备方法 |
CN105419258A (zh) * | 2015-12-24 | 2016-03-23 | 陕西科技大学 | 一种表面改性镁盐晶须制备可降解阻燃型复合材料的方法 |
CN105462193A (zh) * | 2014-09-03 | 2016-04-06 | 东北林业大学 | 一种晶须增强生物降解聚酯复合材料及制备方法 |
CN105820522A (zh) * | 2016-04-01 | 2016-08-03 | 安徽理工大学 | 一种硫酸钙晶须增强增韧聚乳酸复合材料及其制备方法 |
-
2019
- 2019-03-11 CN CN201910179936.8A patent/CN109943046B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6548586B1 (en) * | 2001-02-22 | 2003-04-15 | Council Of Scientific & Industrial Research | Composition useful for making in-situ silicon carbide whiskers and fibres |
CN102002184A (zh) * | 2010-10-08 | 2011-04-06 | 华南理工大学 | 一种增强增韧无卤阻燃聚丙烯混合物及其制备方法 |
CN103772929A (zh) * | 2014-01-24 | 2014-05-07 | 严兵 | 一种全降解高分子复合物及制备方法 |
CN105462193A (zh) * | 2014-09-03 | 2016-04-06 | 东北林业大学 | 一种晶须增强生物降解聚酯复合材料及制备方法 |
CN105419258A (zh) * | 2015-12-24 | 2016-03-23 | 陕西科技大学 | 一种表面改性镁盐晶须制备可降解阻燃型复合材料的方法 |
CN105820522A (zh) * | 2016-04-01 | 2016-08-03 | 安徽理工大学 | 一种硫酸钙晶须增强增韧聚乳酸复合材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
王迪 等: ""硫酸钙晶须表面包覆二氧化硅的制备及机理分析"", 《无机盐工业》 * |
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Effective date of registration: 20211028 Address after: 200949 d-017, No. 1688, Jinshi Road, Baoshan District, Shanghai Patentee after: Shanghai Yucai Transmission Machinery Co.,Ltd. Address before: 232007 room 1909, Ruijin building, Chaoyang Middle Road, Chaoyang Street, tianjia'an District, Huainan City, Anhui Province Patentee before: Huainan Branch of Anhui bianda Financial Consulting Co.,Ltd. Effective date of registration: 20211028 Address after: 232007 room 1909, Ruijin building, Chaoyang Middle Road, Chaoyang Street, tianjia'an District, Huainan City, Anhui Province Patentee after: Huainan Branch of Anhui bianda Financial Consulting Co.,Ltd. Address before: No.168, Taifeng street, Huainan City, Anhui Province 232000 Patentee before: Anhui University of Science and Technology |
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Effective date of registration: 20240807 Address after: No. 19, Hexi Section 2, Jianan Avenue, Jialing District, Nanchong City, Sichuan Province 637000 Patentee after: SICHUAN SHUAI NEW MATERIAL Co.,Ltd. Country or region after: China Address before: 200949 d-017, No. 1688, Jinshi Road, Baoshan District, Shanghai Patentee before: Shanghai Yucai Transmission Machinery Co.,Ltd. Country or region before: China |