CN109851425A - Liquid fertilizer and preparation method thereof containing electrolyzed alkaline water - Google Patents
Liquid fertilizer and preparation method thereof containing electrolyzed alkaline water Download PDFInfo
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- CN109851425A CN109851425A CN201910086764.XA CN201910086764A CN109851425A CN 109851425 A CN109851425 A CN 109851425A CN 201910086764 A CN201910086764 A CN 201910086764A CN 109851425 A CN109851425 A CN 109851425A
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Abstract
The invention discloses a kind of liquid fertilizer and preparation method thereof containing electrolyzed alkaline water, comprising: electrolysis water A, diatomite, graphene oxide, chitosan, potassium fulvate, sodium tetraborate, 5- nitroguaiacol sodium salt, burdock extract, mint extract, EM bacterium, stalk fermentation product；Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, dilutes alkaline stoste to obtain electrolysis water；The present invention is by preparing liquid fertilizer added with the nutritional ingredient for being conducive to plant growth in electrolysis water, it is rich in alkaline electrolysis fertilizer stoste and plays extremely important various elements to crop growth, and rich potassium ion, electronics (e-) and low surface tension (small molecule water) rich in electrolysis water, the photosynthesis of leaves of plants, stem and fruit can not only be effectively facilitated, promote the growth of leaves of plants, stem and fruit, the trace element ion in soil can also quickly be made, promote absorption of the root system to microelement.
Description
Technical field
The present invention relates to a kind of method for preparing fertilizer, and in particular to a kind of liquid fertilizer and its system containing electrolyzed alkaline water
Preparation Method.
Background technique
On the one hand traditional chemical fertilizer and pesticide are beneficial to the growth of crops, increase economic benefit, be on the other hand but easy
Remain in crop and soil, to have the health for endangering the mankind, destroys the harm of ecological environment.Currently, there has been proposed
A kind of completely new electrolysis agricultural water fertilizer, its main feature is that the method using electrolysis adjusts the inorganic of the ion grown containing useful plants
The parameters such as the pH and orp of salting liquid, so as to achieve the effect that promote plant growth simultaneously and remove pest and disease damage.PH is greater than 13
Electrolyte agricultural water fertilizer can destroy the surface texture of worm's ovum to inhibit insect pest, orp is greater than the electrolyte Agricultural Water of 1100mV
It is fertile then germ can be killed to inhibit the generation of disease.Strong acidic electrolyzed water main function is to kill bacterium, can be prevented and treated such as grass
The diseases such as certain kind of berries powdery mildew can substantially reduce the dosage of chemical pesticide while obtaining ideal control efficiency；Strong basicity electrolysis water
Main function be oil removing grease removal, degerming, deodorization, go that agriculture is residual, removes formaldehyde, fresh food vegetables can be carried out with sterilizing and edible
It sterilizes in bacterium production process.
However, conventional crop implantation methods carry out farming species just with the electrolysis water that electrolytic water generating device generates
Plant, due to lack be conducive to crop growth fertilizer, and strong acidic electrolyzed water to crops sterilize while also will largely be conducive to
The microorganism of plant growth is eliminated so that crops are restricted in volume increase, therefore, study a kind of fertilizer containing electrolysis water and
There is important economy and environmental benefit using the method that the fertilizer carries out crop planting.
Summary of the invention
It is excellent it is an object of the invention to solve at least the above problems and/or defect, and provide at least to will be described later
Point.
In order to realize these purposes and other advantages according to the present invention, a kind of liquid containing electrolyzed alkaline water is provided
Fertilizer, the liquid fertilizer includes following components in parts by weight: electrolysis water A100~120 part, 0.1~0.5 part of diatomite, oxygen
0.05-0.5 parts of graphite alkene, 1~3 part of chitosan, 0.5~0.8 part of potassium fulvate, 0.1~0.3 part of sodium tetraborate, 5- nitro
0.05~0.15 part of guaiacol sodium, 0.01~0.03 part of burdock extract, 0.02~0.04 part of mint extract, EM bacterium 0.1
~0.4 part, 10~20 parts of stalk fermentation product；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is obtained for 10~50 times
Electrolysis water；
The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the quality of potassium in the alkalinity stoste
Score >=2.0%；The pH of the alkalinity stoste is 13.20~13.70.
Preferably, the diatomite is modification infusorial earth, preparation method are as follows: configuration dopamine hydrochloric acid solution is adjusted
Then diatomite is added in dopamine hydrochloric acid solution and impregnates, oscillation is protected from light 24~36 hours, then by diatom by pH to 8~10
Soil separation, 30~35 DEG C of drying, obtains modification infusorial earth；The concentration of the dopamine hydrochloric acid solution is 5~12mg/mL；It is described
The mass ratio of diatomite and dopamine hydrochloric acid solution is 1:10~15.
Preferably, the chitosan is modification of chitosan, preparation method are as follows: by weight, take 10~15 chitosans
It is added in 100~120 parts 60~70 DEG C of water, then 10~30min of insulated and stirred is passed through with the speed of 100~120mL/min
Ozone, be passed through ozone time be 30~60min, after being passed through ozone, using carbon dioxide laser to mixed liquor into
Row 1~3min of laser treatment, then uses ethanol precipitation, and drying obtains modification of chitosan；The laser of the carbon dioxide laser
Power be 10~12W, wavelength 10.6um, 1.5~2.5mm of spot diameter, carbon dioxide laser emit dipulse, out when light between
For 90ms, interval time 90ms, single pulse energy is 1.2~2.5kJ.
Preferably, the graphene oxide is modified graphene oxide, preparation method are as follows: its process are as follows: will aoxidize
Graphene is placed in Low Temperature Plasma Treating instrument 8~12min of processing, then by weight, takes 10~20 parts treated oxygen
Graphite alkene, 1~5 part of aluminate coupling agent and 80~100 parts of deionized waters, are stirred, are then ultrasonically treated, and handle the time
30~60min obtains modified graphene oxide；During ultrasound, nano bubble is passed through into mixed liquor.
Preferably, the atmosphere of the Low Temperature Plasma Treating instrument is oxygen；The Low Temperature Plasma Treating instrument
Frequency is 35~55KHz, and power is 35~60W, and the pressure of oxygen is 20~50Pa；The nano bubble is oxygen, nitrogen, argon
Any one or the combination of several of them in gas or carbon dioxide；The frequency of the ultrasonic treatment is 30~45KHz, ultrasonic power
Density is 800~1200W/L, and ultrasound uses intermitant irradiation, and irradiation time/stopping irradiation time of intermitant irradiation is 15~20s/
5~10s.
Preferably, the stalk fermentation product the preparation method comprises the following steps: by weight, take 100~120 parts of corn stovers,
50~80 parts of wheat stalks, 30~50 parts of conch meals, 300~400 parts of animal wastes, 20~25 parts of calcium superphosphate, potassium chloride 25
~35 parts, 30~50 parts of peat soil, 10~20 parts of humic acid are added in fermentor, add 400~1200 parts of electrolysis water B, close
Fermentor is closed, mixing speed is 500~600rpm/min, and temperature is 35~45 DEG C, and fermentation time is 2~5 days；Fermentation is completed
Afterwards, 200~250 parts and 100~150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 1~2 day, after crossing 2mm sieve, obtains
Stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted 5
~30 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, in the acidity stoste
Mass fraction≤0.01% of sodium；The pH of the acidity stoste is 1.5~2.0.
The present invention also provides a kind of preparation methods such as the above-mentioned liquid fertilizer containing electrolyzed alkaline water, including following step
It is rapid:
Step 1: electrolysis water A100~120 part, 0.1~0.5 part of diatomite, 0.05-0.5 parts of graphene oxide, shell are gathered
Sugar 1~3 part, 0.5~0.8 part of potassium fulvate, 0.1~0.3 part of sodium tetraborate, 0.05~0.15 part of 5- nitroguaiacol sodium salt,
0.01~0.03 part of burdock extract, 0.02~0.04 part of mint extract be uniformly mixed, then be added high-voltage pulse at
It manages in room and is pre-processed using high-pressure pulse electric；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1~0.4 part and 10~20 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed in the grinding of four axis
On instrument, four axis bevellers are opened, drives stainless steel spherical container randomly to rotate 30min, is then allowed to stand 5~10d of fermentation, obtains liquid
State fertilizer.
Preferably, the spacing of two-plate is 3~5cm in the high-voltage pulse process chamber；High-voltage pulse processing parameter are as follows:
Impulse amplitude is 15~20KV, and pulse frequency is 1500~2000Hz, and pulse width is 12~15us；
The feed inlet of the stainless steel spherical container is sealed by threaded cap, and threaded cap is spherical with stainless steel after being tightly connected
The surface of container flushes；The shaft revolving speed of the four axis beveller is 150~200rpm, and the stochastic transition time is 10~20s.
The present invention is include at least the following beneficial effects: the present invention in electrolysis water by being added with the battalion conducive to plant growth
It forms and point prepares liquid fertilizer, make alkaline electrolysis fertilizer stoste rich in playing extremely important various members to crop growth
Element, and rich potassium ion, electronics (e-) and low surface tension (small molecule water) rich in electrolysis water, can not only effectively facilitate
The photosynthesis of leaves of plants, stem and fruit promotes the growth of leaves of plants, stem and fruit, can also quickly make the micro member in soil
Element ionization promotes absorption of the root system to microelement.
Further advantage, target and feature of the invention will be partially reflected by the following instructions, and part will also be by this
The research and practice of invention and be understood by the person skilled in the art.
Specific embodiment:
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification
Text can be implemented accordingly.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein do not allot one or more
The presence or addition of a other elements or combinations thereof.
Embodiment 1:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
A120 parts of water, 0.4 part of diatomite, 0.3 part of graphene oxide, 1 part of chitosan, 0.8 part of potassium fulvate, 0.3 part of sodium tetraborate, 5-
0.15 part of nitroguaiacol sodium salt, 0.03 part of burdock extract, 0.04 part of mint extract, 0.4 part of EM bacterium, stalk fermentation product
20 parts；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70.
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by A120 parts of electrolysis water, 0.4 part of diatomite, 0.3 part of graphene oxide, 1 part of chitosan, potassium fulvate
0.8 part, 0.3 part of sodium tetraborate, 0.15 part of 5- nitroguaiacol sodium salt, 0.03 part of burdock extract, 0.04 part of mint extract
It is uniformly mixed, is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；The high-voltage pulse processing
The spacing of two-plate is 5cm in room；High-voltage pulse processing parameter are as follows: impulse amplitude 18KV, pulse frequency 1800Hz, pulse
Width is 12us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.4 part and 20 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 10d, obtain liquid fertilizer；It is described
The feed inlet of stainless steel spherical container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 15s.
Embodiment 2:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of diatomite, 0.2 part of graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate, 0.2 part of sodium tetraborate,
0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, Production in Straw Fermentation
15 parts of object；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of diatomite, 0.2 part of graphene oxide, 2 parts of chitosan, potassium fulvate
0.6 part, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract stir
Mix it is uniformly mixed, then be added high-voltage pulse process chamber in using high-pressure pulse electric pre-process；The high-voltage pulse process chamber
The spacing of middle two-plate is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, pulse are wide
Degree is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 3:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate, sodium tetraborate 0.2
Part, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, stalk fermentation
15 parts of product；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modification infusorial earth the preparation method comprises the following steps: configuration dopamine hydrochloric acid solution, adjust pH to 10, then by diatomite
It is added in dopamine hydrochloric acid solution and impregnates, be protected from light oscillation 36 hours, then separate diatomite, 35 DEG C of drying obtain modified silicon
Diatomaceous earth；The concentration of the dopamine hydrochloric acid solution is 10mg/mL；The mass ratio of the diatomite and dopamine hydrochloric acid solution is 1:
12；Diatomite is modified using method of the invention, improves the compatibility of the other compositions of diatomite and liquid fertilizer,
Further improve the fertilizer efficiency of liquid fertilizer.
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 4:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of diatomite, 0.2 part of graphene oxide, 2 parts of modification of chitosan, 0.6 part of potassium fulvate, sodium tetraborate 0.2
Part, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, stalk fermentation
15 parts of product；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modification of chitosan the preparation method comprises the following steps: by weight, take 15 chitosans to be added in 120 parts 70 DEG C of water, protect
Temperature stirring 20min, is then passed through ozone with the speed of 120mL/min, and the time for being passed through ozone is 30min, and being passed through ozone terminates
Afterwards, laser treatment 3min is carried out to mixed liquor using carbon dioxide laser, then uses ethanol precipitation, drying is modified
Chitosan；The laser power of the carbon dioxide laser is 12W, wavelength 10.6um, spot diameter 2mm, carbon dioxide laser
Device emit dipulse, out when light between be 90ms, interval time 90ms, single pulse energy be 1.8kJ；Using side of the invention
Method is modified chitosan, reduces the molecular weight of chitosan, improves the dissolubility of chitosan, further improves liquid
The bactericidal properties of chitosan in fertilizer.
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of diatomite, 0.2 part of graphene oxide, 2 parts of modification of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 5:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of diatomite, 0.2 part of modified graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate, sodium tetraborate 0.2
Part, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, stalk fermentation
15 parts of product；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modified graphene oxide the preparation method comprises the following steps: graphene oxide is placed in Low Temperature Plasma Treating instrument
10min is managed, then by weight, takes 15 parts treated graphene oxide, 3 parts of aluminate coupling agents and 100 parts of deionized waters,
It is stirred, is then ultrasonically treated, handle time 60min, obtain modified graphene oxide；During ultrasound, to mixing
Nano bubble is passed through in feed liquid；The atmosphere of the Low Temperature Plasma Treating instrument is oxygen；The Low Temperature Plasma Treating instrument
Frequency be 45KHz, power 50W, the pressure of oxygen is 30Pa；The nano bubble is oxygen；The frequency of the ultrasonic treatment
Rate is 45KHz, ultrasonic power density 1000W/L, and ultrasound uses intermitant irradiation, irradiation time/stopping spoke of intermitant irradiation
It is 20s/5s according to the time；Modified graphene prepared by the method for the present invention, which further improves graphene oxide, fertilizer
The enrichment for imitating ingredient, improves the fertilizer efficiency of liquid fertilizer.
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of diatomite, 0.2 part of modified graphene oxide, 2 parts of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 6:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of modification of chitosan, 0.6 part of potassium fulvate, tetraboric acid
0.2 part of sodium, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, straw
15 parts of stalk tunning；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modification infusorial earth the preparation method comprises the following steps: configuration dopamine hydrochloric acid solution, adjust pH to 10, then by diatomite
It is added in dopamine hydrochloric acid solution and impregnates, be protected from light oscillation 36 hours, then separate diatomite, 35 DEG C of drying obtain modified silicon
Diatomaceous earth；The concentration of the dopamine hydrochloric acid solution is 10mg/mL；The mass ratio of the diatomite and dopamine hydrochloric acid solution is 1:
12；
The modification of chitosan the preparation method comprises the following steps: by weight, take 15 chitosans to be added in 120 parts 70 DEG C of water, protect
Temperature stirring 20min, is then passed through ozone with the speed of 120mL/min, and the time for being passed through ozone is 30min, and being passed through ozone terminates
Afterwards, laser treatment 3min is carried out to mixed liquor using carbon dioxide laser, then uses ethanol precipitation, drying is modified
Chitosan；The laser power of the carbon dioxide laser is 12W, wavelength 10.6um, spot diameter 2mm, carbon dioxide laser
Device emit dipulse, out when light between be 90ms, interval time 90ms, single pulse energy be 1.8kJ；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 7:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of modification infusorial earth, 0.2 part of modified graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate, tetraboric acid
0.2 part of sodium, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, straw
15 parts of stalk tunning；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modification infusorial earth the preparation method comprises the following steps: configuration dopamine hydrochloric acid solution, adjust pH to 10, then by diatomite
It is added in dopamine hydrochloric acid solution and impregnates, be protected from light oscillation 36 hours, then separate diatomite, 35 DEG C of drying obtain modified silicon
Diatomaceous earth；The concentration of the dopamine hydrochloric acid solution is 10mg/mL；The mass ratio of the diatomite and dopamine hydrochloric acid solution is 1:
12；
The modified graphene oxide the preparation method comprises the following steps: graphene oxide is placed in Low Temperature Plasma Treating instrument
10min is managed, then by weight, takes 15 parts treated graphene oxide, 3 parts of aluminate coupling agents and 100 parts of deionized waters,
It is stirred, is then ultrasonically treated, handle time 60min, obtain modified graphene oxide；During ultrasound, to mixing
Nano bubble is passed through in feed liquid；The atmosphere of the Low Temperature Plasma Treating instrument is oxygen；The Low Temperature Plasma Treating instrument
Frequency be 45KHz, power 50W, the pressure of oxygen is 30Pa；The nano bubble is oxygen；The frequency of the ultrasonic treatment
Rate is 45KHz, ultrasonic power density 1000W/L, and ultrasound uses intermitant irradiation, irradiation time/stopping spoke of intermitant irradiation
It is 20s/5s according to the time；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 8:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of diatomite, 0.2 part of modified graphene oxide, 2 parts of modification of chitosan, 0.6 part of potassium fulvate, tetraboric acid
0.2 part of sodium, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, straw
15 parts of stalk tunning；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modified graphene oxide the preparation method comprises the following steps: graphene oxide is placed in Low Temperature Plasma Treating instrument
10min is managed, then by weight, takes 15 parts treated graphene oxide, 3 parts of aluminate coupling agents and 100 parts of deionized waters,
It is stirred, is then ultrasonically treated, handle time 60min, obtain modified graphene oxide；During ultrasound, to mixing
Nano bubble is passed through in feed liquid；The atmosphere of the Low Temperature Plasma Treating instrument is oxygen；The Low Temperature Plasma Treating instrument
Frequency be 45KHz, power 50W, the pressure of oxygen is 30Pa；The nano bubble is oxygen；The frequency of the ultrasonic treatment
Rate is 45KHz, ultrasonic power density 1000W/L, and ultrasound uses intermitant irradiation, irradiation time/stopping spoke of intermitant irradiation
It is 20s/5s according to the time；
The modification of chitosan the preparation method comprises the following steps: by weight, take 15 chitosans to be added in 120 parts 70 DEG C of water, protect
Temperature stirring 20min, is then passed through ozone with the speed of 120mL/min, and the time for being passed through ozone is 30min, and being passed through ozone terminates
Afterwards, laser treatment 3min is carried out to mixed liquor using carbon dioxide laser, then uses ethanol precipitation, drying is modified
Chitosan；The laser power of the carbon dioxide laser is 12W, wavelength 10.6um, spot diameter 2mm, carbon dioxide laser
Device emit dipulse, out when light between be 90ms, interval time 90ms, single pulse energy be 1.8kJ；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Embodiment 9:
A kind of liquid fertilizer containing electrolyzed alkaline water, the liquid fertilizer include following components in parts by weight: electrolysis
100 parts of water A, 0.2 part of modification infusorial earth, 0.2 part of modified graphene oxide, 2 parts of modification of chitosan, 0.6 part of potassium fulvate, four
0.2 part of Boratex, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract, EM bacterium 0.1
Part, 15 parts of stalk fermentation product；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 30 times
Water；The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70；
The modification infusorial earth the preparation method comprises the following steps: configuration dopamine hydrochloric acid solution, adjust pH to 10, then by diatomite
It is added in dopamine hydrochloric acid solution and impregnates, be protected from light oscillation 36 hours, then separate diatomite, 35 DEG C of drying obtain modified silicon
Diatomaceous earth；The concentration of the dopamine hydrochloric acid solution is 10mg/mL；The mass ratio of the diatomite and dopamine hydrochloric acid solution is 1:
12；
The modified graphene oxide the preparation method comprises the following steps: graphene oxide is placed in Low Temperature Plasma Treating instrument
10min is managed, then by weight, takes 15 parts treated graphene oxide, 3 parts of aluminate coupling agents and 100 parts of deionized waters,
It is stirred, is then ultrasonically treated, handle time 60min, obtain modified graphene oxide；During ultrasound, to mixing
Nano bubble is passed through in feed liquid；The atmosphere of the Low Temperature Plasma Treating instrument is oxygen；The Low Temperature Plasma Treating instrument
Frequency be 45KHz, power 50W, the pressure of oxygen is 30Pa；The nano bubble is oxygen；The frequency of the ultrasonic treatment
Rate is 45KHz, ultrasonic power density 1000W/L, and ultrasound uses intermitant irradiation, irradiation time/stopping spoke of intermitant irradiation
It is 20s/5s according to the time；
The modification of chitosan the preparation method comprises the following steps: by weight, take 15 chitosans to be added in 120 parts 70 DEG C of water, protect
Temperature stirring 20min, is then passed through ozone with the speed of 120mL/min, and the time for being passed through ozone is 30min, and being passed through ozone terminates
Afterwards, laser treatment 3min is carried out to mixed liquor using carbon dioxide laser, then uses ethanol precipitation, drying is modified
Chitosan；The laser power of the carbon dioxide laser is 12W, wavelength 10.6um, spot diameter 2mm, carbon dioxide laser
Device emit dipulse, out when light between be 90ms, interval time 90ms, single pulse energy be 1.8kJ；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer containing electrolyzed alkaline water, comprising the following steps:
Step 1: by 100 parts of electrolysis water A, 0.2 part of modification infusorial earth, 0.2 part of graphene oxide, 2 parts of chitosan, yellow corruption
0.6 part of sour potassium, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, mint extract 0.02
Part is uniformly mixed, and is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；At the high-voltage pulse
The spacing for managing two-plate in room is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, arteries and veins
Rushing width is 15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Comparative example 1:
A kind of liquid fertilizer, the liquid fertilizer includes following components in parts by weight: 100 parts of water, 0.2 part of diatomite,
0.2 part of graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt,
0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, 15 parts of stalk fermentation product；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of electrolysis water B are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, fermentation time
It is 5 days；After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains
To stalk fermentation product；The electrolysis water B obtains acid stoste through electrolysis using sodium chloride as electrolyte, and acid stoste is diluted
15 times obtain electrolysis water B；The oxidation-reduction potential ORP of the acidity stoste is 900mv~1200mv, sodium in the acidity stoste
Mass fraction≤0.01%；The pH of the acidity stoste is 1.5~2.0；
A kind of preparation method of such as above-mentioned liquid fertilizer, comprising the following steps:
Step 1: by 100 parts of water, 0.2 part of diatomite, 0.2 part of graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate,
0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract be stirred
Uniformly, it is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；The two poles of the earth in the high-voltage pulse process chamber
The spacing of plate is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, pulse width are
15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Comparative example 2:
A kind of liquid fertilizer, the liquid fertilizer includes following components in parts by weight: 100 parts of water, 0.2 part of diatomite,
0.2 part of graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate, 0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt,
0.02 part of burdock extract, 0.02 part of mint extract, 0.1 part of EM bacterium, 15 parts of stalk fermentation product；
The stalk fermentation product the preparation method comprises the following steps: by weight, taking 120 parts of corn stovers, 80 parts of wheat stalks, 30
Part conch meal, 400 parts of animal wastes, 25 parts of calcium superphosphate, 35 parts of potassium chloride, 50 parts of peat soil, 20 parts of humic acid, are added fermentation
In tank, 1200 parts of water are added, sealed fermenting tank, mixing speed 600rpm/min, temperature is 45 DEG C, and fermentation time is 5 days；
After fermentation, 250 parts and 150 parts of plant ash of fishbone dust are added, closed stirring sterilizes after 2 days, after crossing 2mm sieve, obtains stalk
Tunning；
A kind of preparation method of such as above-mentioned liquid fertilizer, comprising the following steps:
Step 1: by 100 parts of water, 0.2 part of diatomite, 0.2 part of graphene oxide, 2 parts of chitosan, 0.6 part of potassium fulvate,
0.2 part of sodium tetraborate, 0.1 part of 5- nitroguaiacol sodium salt, 0.02 part of burdock extract, 0.02 part of mint extract be stirred
Uniformly, it is then added in high-voltage pulse process chamber and is pre-processed using high-pressure pulse electric；The two poles of the earth in the high-voltage pulse process chamber
The spacing of plate is 5cm；High-voltage pulse processing parameter are as follows: impulse amplitude 20KV, pulse frequency 2000Hz, pulse width are
15us；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, EM bacterium is then added
0.1 part and 15 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers, it opens
Four axis bevellers drive stainless steel spherical container randomly to rotate 30min, are then allowed to stand fermentation 8d, obtain liquid fertilizer；It is described not
The feed inlet of rust steel ball shape container is sealed by threaded cap, and threaded cap is neat with the surface of stainless steel spherical container after being tightly connected
It is flat；The shaft revolving speed of the four axis beveller is 150rpm, and the stochastic transition time is 20s.
Liquid fertilizer prepared by above-described embodiment 1~9 and comparative example 1~2 is subjected to fertilization effect verifying, using patent text
The method for offering embodiment 1 in CN201710825304.5 carries out potato planting, and by the alkaline electrolysis fertilizer in the embodiment 1
Stoste replaces with the liquid fertilizer in the embodiment of the present invention 1~9 and comparative example 1~2；Experimental result is as shown in table 1；
Table 1
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details and example shown and described herein.
Claims (8)
1. a kind of liquid fertilizer containing electrolyzed alkaline water, which is characterized in that the liquid fertilizer includes following in parts by weight
Component: electrolysis water A100~120 part, 0.1~0.5 part of diatomite, 0.05-0.5 parts of graphene oxide, 1~3 part of chitosan, Huang
Rotten acid 0.5~0.8 part of potassium, 0.1~0.3 part of sodium tetraborate, 0.05~0.15 part of 5- nitroguaiacol sodium salt, burdock extract
0.01~0.03 part, 0.02~0.04 part of mint extract, 0.1~0.4 part of EM bacterium, 10~20 parts of stalk fermentation product；
Wherein, alkaline stoste is obtained through electrolysis using potassium carbonate as electrolyte, the dilution of alkaline stoste is electrolysed for 10~50 times
Water；
The oxidation-reduction potential ORP of the alkalinity stoste is -900mv~-1200mv, the mass fraction of potassium in the alkalinity stoste
>=2.0%；The pH of the alkalinity stoste is 13.20~13.70.
2. as described in claim 1 containing the liquid fertilizer of electrolyzed alkaline water, which is characterized in that the diatomite is modified silicon
Diatomaceous earth, preparation method are as follows: configuration dopamine hydrochloric acid solution adjusts pH to 8~10, dopamine hydrochloric acid then is added in diatomite
It is impregnated in solution, is protected from light oscillation 24~36 hours, then separates diatomite, 30~35 DEG C of drying obtain modification infusorial earth；Institute
The concentration for stating dopamine hydrochloric acid solution is 5~12mg/mL；The mass ratio of the diatomite and dopamine hydrochloric acid solution be 1:10~
15。
3. as described in claim 1 containing the liquid fertilizer of electrolyzed alkaline water, which is characterized in that the chitosan is modified shell
Glycan, preparation method are as follows: by weight, take 10~15 chitosans to be added in 100~120 parts 60~70 DEG C of water, heat preservation is stirred
10~30min is mixed, ozone is then passed through with the speed of 100~120mL/min, the time for being passed through ozone is 30~60min, is passed through
After ozone, 1~3min of laser treatment is carried out to mixed liquor using carbon dioxide laser, ethanol precipitation is then used, dries
It is dry, obtain modification of chitosan；The laser power of the carbon dioxide laser is 10~12W, wavelength 10.6um, spot diameter
1.5~2.5mm, carbon dioxide laser emit dipulse, out when light between be 90ms, interval time 90ms, single pulse energy
Amount is 1.2~2.5kJ.
4. as described in claim 1 containing the liquid fertilizer of electrolyzed alkaline water, which is characterized in that the graphene oxide is to change
Property graphene oxide, preparation method are as follows: its process are as follows: graphene oxide is placed in Low Temperature Plasma Treating instrument and handles 8
Then by weight~12min takes 10~20 parts treated graphene oxide, 1~5 part of aluminate coupling agent and 80~100
Part deionized water, is stirred, is then ultrasonically treated, and handles 30~60min of time, obtains modified graphene oxide；In ultrasound
During, nano bubble is passed through into mixed liquor.
5. as claimed in claim 4 containing the liquid fertilizer of electrolyzed alkaline water, which is characterized in that at the low temperature plasma
The atmosphere for managing instrument is oxygen；The frequency of the Low Temperature Plasma Treating instrument is 35~55KHz, and power is 35~60W, oxygen
Pressure is 20~50Pa；The nano bubble is any one or a few the group in oxygen, nitrogen, argon gas or carbon dioxide
It closes；The frequency of the ultrasonic treatment is 30~45KHz, and ultrasonic power density is 800~1200W/L, and ultrasound uses interval spoke
According to irradiation time/stopping irradiation time of intermitant irradiation is 15~20s/5~10s.
6. as described in claim 1 containing the liquid fertilizer of electrolyzed alkaline water, which is characterized in that the stalk fermentation product
The preparation method comprises the following steps: by weight, taking 100~120 parts of corn stovers, 50~80 parts of wheat stalks, 30~50 parts of conch meals, 300
~400 parts of animal wastes, 20~25 parts of calcium superphosphate, 25~35 parts of potassium chloride, 30~50 parts of peat soil, humic acid 10~20
Part, it is added in fermentor, adds 400~1200 parts of electrolysis water B, sealed fermenting tank, mixing speed is 500~600rpm/
Min, temperature are 35~45 DEG C, and fermentation time is 2~5 days；After fermentation, 200~250 parts of fishbone dust and plant ash is added
100~150 parts, closed stirring sterilizes after 1~2 day, after crossing 2mm sieve, obtains stalk fermentation product；The electrolysis water B is with chlorination
Sodium obtains acid stoste through electrolysis as electrolyte, and the dilution of acid stoste is obtained electrolysis water B for 5~30 times；The acidity stoste
Oxidation-reduction potential ORP be 900mv~1200mv, it is described acidity stoste in sodium mass fraction≤0.01%；The acidity
The pH of stoste is 1.5~2.0.
7. a kind of preparation method of the liquid fertilizer as described in any one of claims 1 to 6 containing electrolyzed alkaline water, feature
It is, comprising the following steps:
Step 1: by electrolysis water A100~120 part, 0.1~0.5 part of diatomite, 0.05-0.5 parts of graphene oxide, chitosan 1
~3 parts, 0.5~0.8 part of potassium fulvate, 0.1~0.3 part of sodium tetraborate, 0.05~0.15 part of 5- nitroguaiacol sodium salt, fructus arctii
0.01~0.03 part of extract, 0.02~0.04 part of mint extract be uniformly mixed, then be added high-voltage pulse process chamber
It is middle to be pre-processed using high-pressure pulse electric；
Step 2: the pretreated feed liquid of high-pressure pulse electric is added in stainless steel spherical container, be then added EM bacterium 0.1~
0.4 part and 10~20 parts of stalk fermentation product, sealing, and the stainless steel spherical container after sealing is placed on four axis bevellers,
Four axis bevellers are opened, drives stainless steel spherical container randomly to rotate 30min, is then allowed to stand 5~10d of fermentation, obtains liquid fertilizer
Material.
8. the preparation method of the liquid fertilizer containing electrolyzed alkaline water as claimed in claim 7, which is characterized in that
The spacing of two-plate is 3~5cm in the high-voltage pulse process chamber；High-voltage pulse processing parameter are as follows: impulse amplitude 15
~20KV, pulse frequency are 1500~2000Hz, and pulse width is 12~15us；
The feed inlet of the stainless steel spherical container by threaded cap seal, threaded cap be tightly connected after with stainless steel spherical container
Surface flush；The shaft revolving speed of the four axis beveller is 150~200rpm, and the stochastic transition time is 10~20s.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112500250A (en) * | 2020-12-23 | 2021-03-16 | 西南科技大学 | Preparation method of ecological environment-friendly special fertilizer for wheat |
| CN112919967A (en) * | 2021-03-02 | 2021-06-08 | 青海高原地沣肥业有限公司 | Method for preparing organic fertilizer from municipal sludge |
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| CN112500250B (en) * | 2020-12-23 | 2022-03-04 | 西南科技大学 | Preparation method of ecological environment-friendly special fertilizer for wheat |
| CN112919967A (en) * | 2021-03-02 | 2021-06-08 | 青海高原地沣肥业有限公司 | Method for preparing organic fertilizer from municipal sludge |
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