CN109825057A - 一种高增透防紫外性好的改性pet/pc合金及其制备方法 - Google Patents
一种高增透防紫外性好的改性pet/pc合金及其制备方法 Download PDFInfo
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- CN109825057A CN109825057A CN201910105916.6A CN201910105916A CN109825057A CN 109825057 A CN109825057 A CN 109825057A CN 201910105916 A CN201910105916 A CN 201910105916A CN 109825057 A CN109825057 A CN 109825057A
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- 239000000956 alloy Substances 0.000 title claims abstract description 57
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- 239000011347 resin Substances 0.000 claims abstract description 46
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 239000012745 toughening agent Substances 0.000 claims abstract description 16
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 11
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 11
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 68
- 238000006243 chemical reaction Methods 0.000 claims description 53
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 37
- 239000000047 product Substances 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 28
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 28
- 238000005886 esterification reaction Methods 0.000 claims description 22
- 238000005859 coupling reaction Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 19
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 15
- 239000012964 benzotriazole Substances 0.000 claims description 15
- 230000032050 esterification Effects 0.000 claims description 15
- -1 nitro diazonium benzene hydrochloride Chemical group 0.000 claims description 15
- 238000006068 polycondensation reaction Methods 0.000 claims description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- 239000007795 chemical reaction product Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 14
- 238000000967 suction filtration Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 10
- UJSXTAVTTLYGFS-UHFFFAOYSA-N 4-(benzotriazol-2-yl)-6-hydroxybenzene-1,3-dicarboxylic acid Chemical compound C1=CC2=NN(N=C2C=C1)C3=CC(=C(C=C3C(=O)O)C(=O)O)O UJSXTAVTTLYGFS-UHFFFAOYSA-N 0.000 claims description 9
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 8
- WAMBUHSSUGGLJO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;2-(oxiran-2-ylmethoxymethyl)oxirane Chemical compound C1OC1COCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 WAMBUHSSUGGLJO-UHFFFAOYSA-N 0.000 claims description 7
- AKRNUYASPHNEMD-UHFFFAOYSA-N 5-diazo-6-nitrocyclohexa-1,3-diene hydrochloride Chemical group C1=CC(C(=[N+]=[N-])C=C1)[N+](=O)[O-].Cl AKRNUYASPHNEMD-UHFFFAOYSA-N 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 7
- KUMNEOGIHFCNQW-UHFFFAOYSA-N diphenyl phosphite Chemical compound C=1C=CC=CC=1OP([O-])OC1=CC=CC=C1 KUMNEOGIHFCNQW-UHFFFAOYSA-N 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 238000001556 precipitation Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 235000010288 sodium nitrite Nutrition 0.000 claims description 7
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 7
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 7
- BCEQKAQCUWUNML-UHFFFAOYSA-N 4-hydroxybenzene-1,3-dicarboxylic acid Chemical class OC(=O)C1=CC=C(O)C(C(O)=O)=C1 BCEQKAQCUWUNML-UHFFFAOYSA-N 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 239000011258 core-shell material Substances 0.000 claims description 5
- 239000004609 Impact Modifier Substances 0.000 claims description 4
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- 239000003054 catalyst Substances 0.000 claims description 4
- 239000003426 co-catalyst Substances 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 229920003163 Eudragit® NE 30 D Polymers 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- 238000009738 saturating Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims 1
- 238000005469 granulation Methods 0.000 claims 1
- 230000003179 granulation Effects 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 5
- 238000012545 processing Methods 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 238000005809 transesterification reaction Methods 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 73
- 239000005020 polyethylene terephthalate Substances 0.000 description 73
- 239000004417 polycarbonate Substances 0.000 description 65
- 239000000306 component Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 229920000515 polycarbonate Polymers 0.000 description 8
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000020477 pH reduction Effects 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 229930185605 Bisphenol Natural products 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 229920006351 engineering plastic Polymers 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000012994 photoredox catalyst Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
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- 238000001035 drying Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid group Chemical group C(C=1C(C(=O)O)=CC=CC1)(=O)O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- VAYMIYBJLRRIFR-UHFFFAOYSA-N 2-tolyl isocyanate Chemical compound CC1=CC=CC=C1N=C=O VAYMIYBJLRRIFR-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
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- 230000002180 anti-stress Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
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- 125000004185 ester group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000005311 nuclear magnetism Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
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Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
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Citations (15)
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US5071995A (en) * | 1988-10-07 | 1991-12-10 | Kuraray Co., Ltd. | 2-hydroxyphenylbenzotriazol compounds and the use thereof |
JPH04153314A (ja) * | 1990-10-16 | 1992-05-26 | Kuraray Co Ltd | 耐光性のすぐれたポリエステル繊維 |
JPH0544110A (ja) * | 1991-07-31 | 1993-02-23 | Kuraray Co Ltd | 水棲生物付着防止効果を有する繊維および繊維製品 |
JPH07189031A (ja) * | 1993-12-24 | 1995-07-25 | Kuraray Co Ltd | 耐光性の良好なポリエステル系繊維 |
US6387992B1 (en) * | 2000-11-27 | 2002-05-14 | Ciba Specialty Chemicals Corporation | Substituted 5-heteroaryl-2-(2-hydroxyphenyl)-2h-benzotriazole UV absorbers, a process for preparation thereof and compositions stabilized therewith |
JP2003119357A (ja) * | 2001-10-16 | 2003-04-23 | Toyobo Co Ltd | ポリエステル樹脂組成物とそれからなる中空成形体 |
TW565557B (en) * | 2000-08-03 | 2003-12-11 | Ciba Sc Holding Ag | Benzotriazoles containing alpha-cumyl groups substituted by heteroatoms and compositions stabilized therewith |
JP2010031207A (ja) * | 2008-07-31 | 2010-02-12 | Teijin Ltd | 共重合ポリエステル樹脂組成物およびそれからなる二軸配向フィルム |
JP2012025811A (ja) * | 2010-07-21 | 2012-02-09 | Shinnakamura Kagaku Kogyo Kk | 紫外線吸収性のベンゾトリアゾール系(共)重合体及びこれを含む塗料並びに該塗料がコーティングされたフィルム |
CN104650557A (zh) * | 2013-11-25 | 2015-05-27 | 青岛同创节能环保工程有限公司 | 弹性体包覆无机粉体填充改性pc/pbt复合材料 |
CN104693763A (zh) * | 2013-12-10 | 2015-06-10 | 青岛同创节能环保工程有限公司 | 一种以回收pc和pbt为基料的共混合金 |
CN104845311A (zh) * | 2014-11-20 | 2015-08-19 | 青岛同创节能环保工程有限公司 | 一种改性聚碳酸酯/聚对苯二甲酸丁二醇酯合金材料 |
CN105177751A (zh) * | 2015-10-20 | 2015-12-23 | 浙江金霞新材料科技有限公司 | 一种有色抗紫外异形细旦涤纶长丝及其制备方法 |
CN106046736A (zh) * | 2016-04-08 | 2016-10-26 | 杭州杭复新材料科技有限公司 | 一种聚酯树脂基光扩散复合材料的制备方法 |
CN107118531A (zh) * | 2017-07-10 | 2017-09-01 | 广东圆融新材料有限公司 | 一种耐化学品性能优异的聚碳酸酯组合物及其制备方法 |
-
2019
- 2019-02-01 CN CN201910105916.6A patent/CN109825057B/zh active Active
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US5071995A (en) * | 1988-10-07 | 1991-12-10 | Kuraray Co., Ltd. | 2-hydroxyphenylbenzotriazol compounds and the use thereof |
JPH04153314A (ja) * | 1990-10-16 | 1992-05-26 | Kuraray Co Ltd | 耐光性のすぐれたポリエステル繊維 |
JPH0544110A (ja) * | 1991-07-31 | 1993-02-23 | Kuraray Co Ltd | 水棲生物付着防止効果を有する繊維および繊維製品 |
JPH07189031A (ja) * | 1993-12-24 | 1995-07-25 | Kuraray Co Ltd | 耐光性の良好なポリエステル系繊維 |
TW565557B (en) * | 2000-08-03 | 2003-12-11 | Ciba Sc Holding Ag | Benzotriazoles containing alpha-cumyl groups substituted by heteroatoms and compositions stabilized therewith |
US6387992B1 (en) * | 2000-11-27 | 2002-05-14 | Ciba Specialty Chemicals Corporation | Substituted 5-heteroaryl-2-(2-hydroxyphenyl)-2h-benzotriazole UV absorbers, a process for preparation thereof and compositions stabilized therewith |
JP2003119357A (ja) * | 2001-10-16 | 2003-04-23 | Toyobo Co Ltd | ポリエステル樹脂組成物とそれからなる中空成形体 |
JP2010031207A (ja) * | 2008-07-31 | 2010-02-12 | Teijin Ltd | 共重合ポリエステル樹脂組成物およびそれからなる二軸配向フィルム |
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CN104650557A (zh) * | 2013-11-25 | 2015-05-27 | 青岛同创节能环保工程有限公司 | 弹性体包覆无机粉体填充改性pc/pbt复合材料 |
CN104693763A (zh) * | 2013-12-10 | 2015-06-10 | 青岛同创节能环保工程有限公司 | 一种以回收pc和pbt为基料的共混合金 |
CN104845311A (zh) * | 2014-11-20 | 2015-08-19 | 青岛同创节能环保工程有限公司 | 一种改性聚碳酸酯/聚对苯二甲酸丁二醇酯合金材料 |
CN105177751A (zh) * | 2015-10-20 | 2015-12-23 | 浙江金霞新材料科技有限公司 | 一种有色抗紫外异形细旦涤纶长丝及其制备方法 |
CN106046736A (zh) * | 2016-04-08 | 2016-10-26 | 杭州杭复新材料科技有限公司 | 一种聚酯树脂基光扩散复合材料的制备方法 |
CN107118531A (zh) * | 2017-07-10 | 2017-09-01 | 广东圆融新材料有限公司 | 一种耐化学品性能优异的聚碳酸酯组合物及其制备方法 |
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