CN109810718A - Industrial continuous oil sludge pyrolysis device - Google Patents

Industrial continuous oil sludge pyrolysis device Download PDF

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Publication number
CN109810718A
CN109810718A CN201711156342.2A CN201711156342A CN109810718A CN 109810718 A CN109810718 A CN 109810718A CN 201711156342 A CN201711156342 A CN 201711156342A CN 109810718 A CN109810718 A CN 109810718A
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CN
China
Prior art keywords
transmission chain
chain belt
pyrolysis
pyrolysis furnace
oil sludge
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711156342.2A
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Chinese (zh)
Inventor
蒲文忠
陈明晟
蒲曼
庞计锁
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Mianyang Youpu Energy Technology Co Ltd
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Mianyang Youpu Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Mianyang Youpu Energy Technology Co Ltd filed Critical Mianyang Youpu Energy Technology Co Ltd
Priority to CN201711156342.2A priority Critical patent/CN109810718A/en
Priority to PCT/CN2018/113920 priority patent/WO2019096019A1/en
Publication of CN109810718A publication Critical patent/CN109810718A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/18Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28Other processes
    • C10B47/32Other processes in ovens with mechanical conveying means
    • C10B47/40Other processes in ovens with mechanical conveying means with endless conveying devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

The invention discloses industrial continuous oil sludge pyrolysis devices, belong to disposal of oily sludge field.Including pyrolysis furnace and heating cabinet, heating cabinet is arranged on the outside of pyrolysis furnace, includes overall height warm area or low-temperature space-high-temperature region inside pyrolysis furnace;Transmission chain belt is equipped in pyrolysis furnace, transmission chain belt multi-layer intercrossed can be distributed, and the end of transmission chain belt is discharge port, and discharge port is connected with one end of rotation seal joint, and the other end of rotation seal joint is connected with cooling cylinder.Transmission chain belt interlaced distribution along the vertical direction in the present apparatus, increases residence time of the oily sludge in pyrolysis furnace, keeps pyrolysis more abundant;Device length is shortened, equipment volume is reduced, saves equipment investment.The rate of transmission chain belt is adjusted using AC frequency conversion stepless time adjustment motor, effectively controls pyrolysis rate and residence time, the accurate granularity and aridity for controlling tailings.

Description

Industrial continuous oil sludge pyrolysis device
Technical field
The present invention relates to greasy filth, oil-sand, greasy dirt process fields, and in particular to a kind of oil sludge continuous pyrolysis device.
Background technique
About 30,000,000 tons of the yield of the annual oily sludge in China, and its processing mode is predominantly burned and landfill, however Both processing modes can not accomplish desired harmless treatment.Dioxin is easy to produce in burning process containing sludge, And dioxin is carcinogenic gaseous matter, influences atmosphere, causes secondary pollution, while both conventional process modes are at high cost.And Oily sludge pyrolytic technique is the effective ways for solving oil in oily sludge.After temperature is heated up, moisture first evaporates, then again Temperature is increased, light oil volatilization, mink cell focus is then cracked into the volatilization of small molecule light oil and collects, and then removes the moisture in greasy filth And oil, obtained dry matter then can direct emission, avoid secondary pollution.The existing equipment master for oily sludge pyrolysis If heated by rotation, energy consumption is high;Occupation area of equipment is big, and manufacturing cost is high;It cannot the good grain for controlling tailings discharging Degree, and greasy filth coking is generated in treatment process, make to be pyrolyzed insufficient, equipment cleaning difficulty.
Summary of the invention
To solve the above-mentioned problems, it the invention proposes a kind of oil sludge continuous pyrolysis device, is transmitted by Multi-layer belt type, It saves pyrolysis furnace and rotates energy consumption, while reducing equipment volume, reduce equipment cost, it is accurate to control tailings granularity and aridity, drop Low secondary pollution.
To achieve the goals above, the present invention is achieved through the following technical solutions:
A kind of industrial continuous oil sludge pyrolysis device, including pyrolysis furnace and heating cabinet, the heating cabinet setting are being split Any side or a few sides on the outside of furnace are solved, it includes overall height warm area inside the pyrolysis furnace that the pyrolysis furnace front, which is equipped with feed inlet, Or low-temperature space-high-temperature region;Transmission chain belt is equipped in the pyrolysis furnace, the end of the transmission chain belt is discharge port, the discharging Mouth is connected with one end of rotation seal joint, and the other end of the rotation seal joint is connected with cooling cylinder;
Transmission chain belt is equipped in the overall height warm area, the transmission chain belt includes at least two layers, it is every layer described between biography Send chain belt interlaced distribution along the vertical direction;
The low-temperature space of the low-temperature space-high-temperature region is adjacent with feed inlet, is equipped with transmission between the low-temperature space-high-temperature region Chain belt is equipped with thermal insulation board between the low-temperature space and high-temperature region, the transmission chain belt of the low-temperature space includes feed end and discharge end; The transmission chain belt of the feed end and discharge end is at least one layer, between every layer of feed end and the transmission chain belt of discharge end Interlaced distribution along the vertical direction;The transmission chain belt of the high-temperature region is at least two layers, and the transmission chain belt of the high-temperature region exists High-temperature region interlaced distribution along the vertical direction;
The burner for the furnace body heating to pyrolysis furnace is equipped in the heating cabinet, the burner and fuel input unit connect It connects.
Further, the feed inlet includes feeding-in solid body mouth, semifluid feed inlet.
Further, oil gas vent and dust-extraction unit are equipped at the top of the pyrolysis furnace.Oil gas is mainly that light oil and water steam Gas, out after oil gas by condensation by water-oil separation, obtained oil product can utilize again.Dust-extraction unit is mainly wet dust removal Device reduces the dust in pyrolysis furnace.
Further, the furnace body of the pyrolysis furnace be rectangle, circle and it is tubular in any one.But it is several to be not limited only to this Kind, the shape of furnace body can be selected and be designed according to specific actual conditions.
Further, the cracking furnace bottom is equipped with scraper plate.Scraper plate is mainly used for scraping the clout in transmission chain belt Out, strengthening device is run.
It further, include low-temperature space and high-temperature region in the low-temperature space-high-temperature region;The burner is arranged in the overall height In warm area or the heating cabinet of high-temperature region.
Further, including control device and transfer motion power device, the control device and transfer motion power device electricity Even;The transfer motion power device is connect with transmission chain belt.
Further, the front end of the feeding-in solid body mouth is connected with the solid conveyor belt for conveying solid substance.
Further, the front end of the semifluid feed inlet is connected with for conveying viscid fluid delivery pump.
Further, the transfer motion power device includes motor, retarder, driving wheel and tensioning wheel, the retarder point It is not connect with driving wheel and motor;The motor is AC frequency conversion stepless time adjustment motor;The tensioning wheel is arranged on driving wheel, The transmission chain belt is arranged between the driving wheel and tensioning wheel.
The industrial continuous oil sludge pyrolysis device of the present invention, the beneficial effect is that:
(1) transmission and the cracking for carrying out solid or half dry solid by transmission chain belt inside pyrolysis furnace, avoid because of furnace Body rotates and increased energy consumption.It is transmitted and is cracked using transmission chain belt, it is more energy saving.
(2) the interlaced distribution along the vertical direction of the transmission chain belt in pyrolysis furnace, increases oily sludge in pyrolysis furnace In residence time, make pyrolysis it is more abundant;
(3) the interlaced distribution along the vertical direction of the transmission chain belt in pyrolysis furnace shortens device length, reduces equipment Volume saves equipment investment.
(4) rate that transmission chain belt is adjusted using AC frequency conversion stepless time adjustment motor, effectively controls pyrolysis rate and stop Time, the accurate granularity and aridity for controlling tailings.
(5) in low-temperature space-high-temperature region pyrolysis furnace, high-temperature region is equipped with burner, and the not set burner of low-temperature space is high The material of warm area is directly entered low-temperature space after coming out, and since low-temperature space is adjacent with feed inlet, the material waste heat that high-temperature region comes out can The raw material of low-temperature space after feed inlet is heated, thermal energy is made full use of.The setting of burner can be reduced, while saving energy consumption. Sludge is contained using pyrolysis, heavy oil conversion therein is collected for light oil, does not generate atmosphere pollution, is recycled, It is environmentally protective.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention without any creative labor, may be used also for those of ordinary skill in the art To obtain other drawings based on these drawings.
Fig. 1 is the structural schematic diagram that pyrolysis furnace is overall height warm area in the present invention;
Fig. 2 is the structural schematic diagram that pyrolysis furnace is low-temperature space-high-temperature region in the present invention and low-temperature space is two layers;
Fig. 3 is that pyrolysis furnace is low-temperature space-high-temperature region in the present invention and low-temperature space is the structural schematic diagram of multilayer;
1- pyrolysis furnace, 2- heating cabinet, 3- transmission chain belt, 4- overall height warm area, 5- low-temperature space, the high-temperature region 6-, 7- discharge port, 8- Rotation seal joint, 9- cooling cylinder, 10- burner, 11- feeding-in solid body mouth, 12- semifluid feed inlet, 13- oil gas vent, 14- are solid Body conveyer belt, 15- fluid delivery pump, 16- scraper plate, 17- dust-extraction unit, 18- thermal insulation board.
Specific embodiment
Combined with specific embodiments below and attached drawing come present invention be described in more detail.
Embodiment 1
A kind of industrial continuous oil sludge pyrolysis device as shown in Figure 1, include pyrolysis furnace 1 and heating cabinet 2, can be according to need Ask by heating cabinet be arranged in pyrolysis furnace outside any side or two sides or three sides or four sides.And adding in the present embodiment For the setting of hot storehouse 2 in 1 downside of pyrolysis furnace, 1 front of pyrolysis furnace is equipped with feed inlet, feed inlet include feeding-in solid body mouth 11, semifluid into Material mouth 12 can be directly transported when raw material is solid by solid conveyor belt 14;When raw material is viscid, at this time may be used Conveying charging is carried out to raw material with fluid delivery pump 15.It include overall height warm area 4 inside pyrolysis furnace 1;Conveyer chain is equipped in pyrolysis furnace 1 The end of band 3, transmission chain belt 3 is discharge port 7, and discharge port 7 is connected with one end of rotation seal joint 8, rotation seal joint 8 The other end is connected with cooling cylinder 9;Transmission chain belt 3 is equipped in overall height warm area 4, transmission chain belt 3 includes between at least two layers, every layer The interlaced distribution along the vertical direction of transmission chain belt 3;The burner 10 for the furnace body heating to pyrolysis furnace 1 is equipped in heating cabinet 2, Burner 10 is connect with combustion gas input unit.Fuel may include coal gas, coal gas, natural gas and fuel oil etc., and according to different Fuel, the change that burner 10 is matched.The furnace body of pyrolysis furnace 1 be rectangle, circle and it is tubular in any one, but not only It is limited to these types, the shape of furnace body can be selected and be designed according to specific actual conditions.Go out at the top of pyrolysis furnace 1 equipped with oil gas Mouth 13 and dust-extraction unit 17.Oil gas is mainly light oil and vapor, out after oil gas by condensation by water-oil separation, obtain Oil product can utilize again.The bottom of pyrolysis furnace 1 is equipped with scraper plate 16, and scraper plate 16 is mainly disposed to close to the place of discharge port 7, just It is struck off in the tailing on the transmission chain band at discharge port 7, ensures equipment trouble-free operation.
And the present invention mainly uses control device and transfer motion power device, control device and biography for the control of transmission chain band Dynamic power device is electrically connected;Transfer motion power device includes AC frequency conversion stepless time adjustment motor, retarder, driving wheel and tensioning wheel, is subtracted Fast device is connect with driving wheel and motor respectively;Tensioning wheel is arranged on driving wheel, and the setting of transmission chain belt 3 is in the driving wheel and opens Between bearing up pulley, driving wheel rotation, and drive transmission chain band to be moved by frictional force.And control device can directly control exchange The frequency of frequency conversion stepless time adjustment motor then controls the revolving speed of retarder and driving wheel, reaches control raw material in pyrolysis furnace 1 Operating rate ensures the granularity and aridity of tailings.
Embodiment 2
A kind of industrial continuous oil sludge pyrolysis device is as shown in Figures 2 and 3, including pyrolysis furnace 1 and heating cabinet 2, can Heating cabinet is arranged in any side or two sides or three sides or four sides in the outside of pyrolysis furnace according to demand.And the present embodiment In the setting of heating cabinet 2 in the downside of pyrolysis furnace 1,1 front of pyrolysis furnace is equipped with feed inlet, and feed inlet includes feeding-in solid body mouth 11, half Fluid feed mouth 12 can be directly transported when raw material is solid by solid conveyor belt 14;When raw material is viscid, Conveying charging can be carried out to raw material with fluid delivery pump 15 at this time.It include low-temperature space-high-temperature region inside pyrolysis furnace 1;In pyrolysis furnace 1 Equipped with transmission chain belt 3, the end of transmission chain belt 3 is discharge port 7, and discharge port 7 is connected with one end of rotation seal joint 8, is rotated The other end of seal nipple 8 is connected with cooling cylinder 9;Low-temperature space 5 is adjacent with feed inlet, and biography is equipped between low-temperature space-high-temperature region Chain belt 3 is sent, thermal insulation board 18 is equipped between low-temperature space 5 and high-temperature region 6, the transmission chain belt 3 of low-temperature space 5 includes feed end and discharging End;The transmission chain belt 3 of feed end and discharge end is at least one layer, edge between every layer of feed end and the transmission chain belt 3 of discharge end The interlaced distribution of vertical direction;The transmission chain belt 3 of high-temperature region 6 is at least two layers, and the transmission chain belt 3 of high-temperature region 6 is in high-temperature region 6 Interlaced distribution along the vertical direction;The burner 10 for the furnace body heating to pyrolysis furnace 1 is equipped in heating cabinet 2, burner 10 is main It is set in the lower section of high-temperature region 6, burner 10 is connect with combustion gas input unit.Fuel may include coal gas, coal gas, natural gas and Fuel oil etc., and the change matched according to different fuel, burner 10.The furnace body of pyrolysis furnace 1 is rectangle, circle and pipe Any one in shape, but it is not limited only to these types, the shape of furnace body can be selected and be designed according to specific actual conditions. Oil gas vent 13 and dust-extraction unit 17 are equipped at the top of pyrolysis furnace 1.Oil gas is mainly light oil and vapor, out after oil gas it is logical Condensation is crossed by water-oil separation, obtained oil product can utilize again.The bottom of pyrolysis furnace 1 is equipped with scraper plate 16, and scraper plate 16 is mainly arranged In the place close to discharge port 7, convenient for striking off to the tailing on the transmission chain band at discharge port 7, ensure that equipment is smoothly transported Row.
And the present invention mainly uses control device and transfer motion power device, control device and institute for the control of transmission chain band Transfer motion power device is stated to be electrically connected;Transfer motion power device includes AC frequency conversion stepless time adjustment motor, retarder, driving wheel and tensioning Wheel, retarder are connect with driving wheel and motor respectively;Tensioning wheel is arranged on driving wheel, and transmission chain belt 3 is arranged in the active Between wheel and tensioning wheel, driving wheel rotation, and drive transmission chain band to be moved by frictional force.And control device can be controlled directly The frequency of AC frequency conversion stepless time adjustment motor processed then controls the revolving speed of retarder and driving wheel, reaches control raw material and is cracking Operating rate in furnace 1 ensures the granularity and aridity of tailings.
It is provided for the embodiments of the invention technical solution above to be described in detail, specific case used herein The principle and embodiment of the embodiment of the present invention are expounded, the explanation of above embodiments is only applicable to help to understand this The principle of inventive embodiments;At the same time, for those skilled in the art, according to an embodiment of the present invention, in specific embodiment party There will be changes in formula and application range, in conclusion the contents of this specification are not to be construed as limiting the invention.

Claims (10)

1. a kind of industrial continuous oil sludge pyrolysis device, it is characterised in that: including pyrolysis furnace and heating cabinet, the heating cabinet Any side or a few sides on the outside of pyrolysis furnace are set, and the pyrolysis furnace front is equipped with feed inlet, includes inside the pyrolysis furnace Overall height warm area or low-temperature space-high-temperature region;Transmission chain belt is equipped in the pyrolysis furnace, the end of the transmission chain belt is discharge port, The discharge port is connected with one end of rotation seal joint, and the other end of the rotation seal joint is connected with cooling cylinder;
Transmission chain belt is equipped in the overall height warm area, the transmission chain belt includes at least two layers, it is every layer described between conveyer chain Band interlaced distribution along the vertical direction;
The low-temperature space of the low-temperature space-high-temperature region is adjacent with feed inlet, is equipped with conveyer chain between the low-temperature space-high-temperature region Band is equipped with thermal insulation board between the low-temperature space and high-temperature region, the transmission chain belt of the low-temperature space includes feed end and discharge end;Institute The transmission chain belt for stating feed end and discharge end is at least one layer, edge between every layer of feed end and the transmission chain belt of discharge end The interlaced distribution of vertical direction;The transmission chain belt of the high-temperature region is at least two layers, and the transmission chain belt of the high-temperature region is in height Warm area interlaced distribution along the vertical direction;
The burner for the furnace body heating to pyrolysis furnace is equipped in the heating cabinet, the burner is connect with fuel input unit.
2. industrial continuous oil sludge pyrolysis device according to claim 1, it is characterised in that: the feed inlet includes solid Body feed inlet, semifluid feed inlet.
3. industrial continuous oil sludge pyrolysis device according to claim 1, it is characterised in that: set at the top of the pyrolysis furnace There are oil gas vent and dust-extraction unit.
4. industrial continuous oil sludge pyrolysis device according to claim 1, it is characterised in that: the furnace body of the pyrolysis furnace For rectangle, circle and it is tubular in any one.
5. industrial continuous oil sludge pyrolysis device according to claim 1, it is characterised in that: the cracking furnace bottom is set There is scraper plate.
6. industrial continuous oil sludge pyrolysis device according to claim 1, it is characterised in that: the low-temperature space-high temperature It include low-temperature space and high-temperature region in area;The burner is arranged in the overall height warm area or the heating cabinet of high-temperature region.
7. industrial continuous oil sludge pyrolysis device according to claim 1, it is characterised in that: including control device and biography Dynamic power device, the control device are electrically connected with the transfer motion power device;The transfer motion power device is connect with transmission chain belt.
8. industrial continuous oil sludge pyrolysis device according to claim 2, it is characterised in that: the feeding-in solid body mouth Front end is connected with the solid conveyor belt for conveying solid substance.
9. industrial continuous oil sludge pyrolysis device according to claim 2, it is characterised in that: the semifluid feed inlet Front end be connected with for conveying viscid fluid delivery pump.
10. industrial continuous oil sludge pyrolysis device according to claim 7, it is characterised in that: the transfer motion power dress It sets including motor, retarder, driving wheel and tensioning wheel, the retarder is connect with driving wheel and motor respectively;The motor is AC frequency conversion stepless time adjustment motor;The tensioning wheel is arranged on driving wheel, the transmission chain belt setting in the driving wheel and Between tensioning wheel.
CN201711156342.2A 2017-11-20 2017-11-20 Industrial continuous oil sludge pyrolysis device Pending CN109810718A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201711156342.2A CN109810718A (en) 2017-11-20 2017-11-20 Industrial continuous oil sludge pyrolysis device
PCT/CN2018/113920 WO2019096019A1 (en) 2017-11-20 2018-11-05 Industrial continuous oily sludge thermal decomposition equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711156342.2A CN109810718A (en) 2017-11-20 2017-11-20 Industrial continuous oil sludge pyrolysis device

Publications (1)

Publication Number Publication Date
CN109810718A true CN109810718A (en) 2019-05-28

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Country Status (2)

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CN (1) CN109810718A (en)
WO (1) WO2019096019A1 (en)

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