CN109797401A - A kind of electrolytic method - Google Patents
A kind of electrolytic method Download PDFInfo
- Publication number
- CN109797401A CN109797401A CN201910108000.6A CN201910108000A CN109797401A CN 109797401 A CN109797401 A CN 109797401A CN 201910108000 A CN201910108000 A CN 201910108000A CN 109797401 A CN109797401 A CN 109797401A
- Authority
- CN
- China
- Prior art keywords
- electrochemistry region
- region
- electrochemistry
- compound
- electronic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The invention discloses a kind of electrolytic methods, contact electrochemistry region with compound or contact compound with electrochemistry region, make the electrochemistry region by alternating current electro ultrafiltration；Reducing agent and oxidant are alternately exported from the electrochemistry region, or from the molar mixture of electrochemistry region export Oxidizing and Reducing Agents, or exports the biasing mixture of Oxidizing and Reducing Agents from the electrochemistry region.Electrolytic method disclosed in this invention will terminate conventional electrolytic methods and electrolysis unit with the history for existing for necessary condition of electrolyte, for efficiently, the exploitation of long-life, low cost electrolysis unit provide new approach.
Description
Technical field
The present invention relates to electricity field, electrochemical field more particularly to a kind of electrolytic methods.
Background technique
Electrolytic method is using very extensive, but all electrolytic methods so far between electrode to transmit non-electronic band
Charged particle (such as proton, negative oxygen ion etc.) is necessary condition, mean that so all electrolytic methods so far with
It the use of the electrolyte that non-electronic charged particle is connected is necessary condition, and the electrolyte that non-electronic charged particle is connected not only manufactures
It is difficult, using difficulty, and will be greatly reduced electrolytic efficiency.If can invent one kind does not exist for necessary item with electrolyte
The electrolytic method of part will be of great significance.Therefore, it is necessary to invent a kind of Novel electrolytic method.
Summary of the invention
To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:
A kind of electrolytic method of scheme 1., contacts electrochemistry region with compound or connects compound with electrochemistry region
Touching, makes the electrochemistry region by alternating current electro ultrafiltration；Reducing agent and oxidant are alternately exported from the electrochemistry region, or
Oxidant is exported from the molar mixture of electrochemistry region export Oxidizing and Reducing Agents, or from the electrochemistry region
With the biasing mixture of reducing agent.
A kind of electrolytic method of scheme 2., contacts electrochemistry region with compound or connects compound with electrochemistry region
Touching；The electrochemistry region has non-electronic conducting electrical relation or the electricity through non-electronic charged particle transmitter and region B
Chemical regions successively have non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B,
Or the electrochemistry region has non-electronic conducting electrical relation through dielectric and region B；In the electrochemistry region and described
Apply alternating current electro ultrafiltration between the B of region；From the electrochemistry region alternately export reducing agent and oxidant, or from the electricity
Chemical regions export the molar mixture of Oxidizing and Reducing Agents, or export Oxidizing and Reducing Agents from the electrochemistry region
Biasing mixture.
A kind of electrolytic method of scheme 3. contacts electrochemistry region A with compound or connects compound with electrochemistry region A
Touching, contacts electrochemistry region B with compound or contacts compound with electrochemistry region B；The electrochemistry region A is through non-electrical
Subband charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively
There is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B, or
The electrochemistry region A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；In the electrochemical school district
Apply alternating current electro ultrafiltration between domain A and the electrochemistry region B；From the electrochemistry region A alternately export reducing agent and
Oxidant, or from the molar mixture of electrochemistry region A export Oxidizing and Reducing Agents, or from the electrochemistry region
The biasing mixture of A export Oxidizing and Reducing Agents；From electrochemistry region B alternating export reducing agent and oxidant, or from
The molar mixture of the electrochemistry region B export Oxidizing and Reducing Agents, or oxidant is exported from the electrochemistry region B
With the biasing mixture of reducing agent.
A kind of electrolytic method of scheme 4., contacts electrochemistry region with compound or connects compound with electrochemistry region
Touching, makes the electrochemistry region by alternating current electro ultrafiltration；Reducing agent and oxidant are alternately exported from the electrochemistry region, or
Oxidant is exported from the molar mixture of electrochemistry region export Oxidizing and Reducing Agents, or from the electrochemistry region
With the biasing mixture of reducing agent；The electrochemistry region and insulation, isolation space, electrolyte, dielectric, capacitor, etc. from
At least one of daughter, ionic liquid, ionized gas, solion and electronic conduction area are closed with non-electronic conducting electricity
System.
A kind of electrolytic method of scheme 5., contacts electrochemistry region with compound or connects compound with electrochemistry region
Touching；The electrochemistry region has non-electronic conducting electrical relation or the electricity through non-electronic charged particle transmitter and region B
Chemical regions successively have non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B,
Or the electrochemistry region has non-electronic conducting electrical relation through dielectric and region B；In the electrochemistry region and described
Apply alternating current electro ultrafiltration between the B of region；From the electrochemistry region alternately export reducing agent and oxidant, or from the electricity
Chemical regions export the molar mixture of Oxidizing and Reducing Agents, or export Oxidizing and Reducing Agents from the electrochemistry region
Biasing mixture；The electrochemistry region is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ion
At least one of liquid, ionized gas, solion and electronic conduction area are closed with the region B with non-electronic conducting electricity
System.
A kind of electrolytic method of scheme 6. contacts electrochemistry region A with compound or connects compound with electrochemistry region A
Touching, contacts electrochemistry region B with compound or contacts compound with electrochemistry region B；The electrochemistry region A is through non-electrical
Subband charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively
There is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B, or
The electrochemistry region A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；In the electrochemical school district
Apply alternating current electro ultrafiltration between domain A and the electrochemistry region B；From the electrochemistry region A alternately export reducing agent and
Oxidant, or from the molar mixture of electrochemistry region A export Oxidizing and Reducing Agents, or from the electrochemistry region
The biasing mixture of A export Oxidizing and Reducing Agents；From electrochemistry region B alternating export reducing agent and oxidant, or from
The molar mixture of the electrochemistry region B export Oxidizing and Reducing Agents, or oxidant is exported from the electrochemistry region B
With the biasing mixture of reducing agent；The electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, etc. from
At least one of daughter, ionic liquid, ionized gas, solion and electronic conduction area have with the electrochemistry region B
Non-electronic conducting electrical relation.
Scheme 7. on the basis of either a program, further selectively selects for the compound to be set as in scheme 1 to 6
Compound in mixture；Or, the compound is set as water, the reducing agent is hydrogen, and the oxidant is oxygen；Or,
The compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alcohol compound, the oxidation
Agent is oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is ethers
Object is closed, the oxidant is oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, it is described to go back
Former agent is alkane derivative, and the oxidant is oxygen；Or, the compound is set as water, and water and carbon dioxide are common
Reaction is participated in, the reducing agent is alkenes compounds, and the oxidant is oxygen；Or, the compound is set as water, and water
It participates in reacting jointly with carbon dioxide, the reducing agent is alkynes compound, and the oxidant is oxygen.
Scheme 8. on the basis of either a program, is further selectively selected the biasing mixture in scheme 1 to 7
It is set as explosion limit mixture below.
The aforementioned all schemes containing the electrochemistry region of the present invention can further make the electrochemistry area rotation
Setting.
The aforementioned all schemes containing the electrochemistry region A and the electrochemistry region B of the present invention can further by
The electrochemistry region A rotation setting, the electrochemistry region B rotation setting.
In the present invention, the method in only one disclosed electrochemistry region, which is selectively chosen, serves as half electricity of manufacture
Device (including the device region of an electrode i.e. in electrochemical method) is solved, is also selectively chosen and serves as manufacture electrolysis dress
It sets.
In the present invention, under certain temperature and/or pressure, so-called electrochemistry region, which is selectively chosen, to be set as not wrapping
The conductive region of catalyst is included, because it is anti-can still to carry out electrochemistry without using catalyst under certain temperature and/or pressure
It answers.
In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region
In the method for relationship, be selectively chosen make one in the electrochemistry region and the region B through capacitor or through non-
Electronic conduction area (such as the electrolyte such as proton exchange membrane) is again through external circuit and another electric communication, it is possible to realize normality
Work.
It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention
In the method that electrical relation is connected, it is selectively chosen one made in the electrochemistry region A and the electrochemistry region B
Through capacitor or through non-electronic conducting area (such as the electrolyte such as proton exchange membrane) again through external circuit and another electric communication, so
Normality work may be implemented.
In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through
The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional
Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes
It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and described
Electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist
It can be not present.
In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity
The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected
Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current
Variation is to realize, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A
And the electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then can be with
In the presence of can also be not present.
In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio
Mixture within 10%.
In the present invention, the biasing mixture of so-called reducing agent and oxidant refers to that the concentration ratio of reducing agent and oxidant deviates
The mixture of the concentration ratio of reducing agent and oxidant in molar mixture.
The electrolytic method disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e., electrochemistry region with
Alternating electromotive force and alternating current are corresponding.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic
Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration
One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted
The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.
The present invention in specific implementation, is selectively chosen using the electrochemistry region as an electrode, will be conductive
Body is completed the conversion of chemical energy electric energy, is selectively chosen an electricity as another electrode, two electrode cooperatings
Chemical regions are as an electrode, and using another described electrochemistry region as another electrode, two electrode cooperatings are completed
The conversion of chemical energy electric energy.
In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through
The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional
Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes
It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and described
Electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist
It can be not present.
In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity
The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected
Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current
Variation is to realize, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A
And the electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then can be with
In the presence of can also be not present.
In the present invention, in two electrodes (for example, the electrochemistry region and electric conductor, the electrochemistry region A and the electricity
Chemical regions B, the electrochemistry region and the region B) between there are in the method for electrolyte, non-electronic charged particle can both be worn
More electrolyte reaches another electrode from an electrode, can also realize the work that alternating current is connected by reciprocating vibration in the electrolyte
With.
In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention,
This feature eliminates the necessity of charged particle non-electronic between two electrodes transmission, thus no matter make between two electrodes in electronics every
Exhausted state, non-electronic charged particle state of isolation have the state for the electrolyte that non-electronic charged particle is connected between two electrodes, also
It is that can be worked normally in other states as long as can be realized the Oscillating flow of electronics.There are electrolyte between two electrodes
In method, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be past in the electrolyte
Complex oscillation realizes the effect of alternating current conducting.This provides brand-new method for the manufacture and use of novel electrolytic device.
In the present invention, the alternation of electric current and substance replace and the effect of the alternation and substance of electric current is formed by alternation work
It is a kind of lasting course of work as process, is a kind of work normality, and its purpose is to eliminate non-electronic charged particle
In the necessity of two interelectrode transmitting, to promote the science of electrolytic method, and then promotion and the method disclosed in the present
Service life, reliability, low cost and the efficiency of corresponding electrolysis unit.The principle and purpose and tradition of this electrolytic method are fired
The purpose of material battery is catalyst regeneration temporary exchange Oxidizing and Reducing Agents feed channel forms temporary polarity of electrode and becomes
The principle and purpose of change has essential distinction, also and to prevent, weaken and the frequently pole-reversing electroosmosis of clearing electrode attachment
Principle and purpose have essential distinction.
In the present invention, it is formed by that the capacitance the big more to be conducive to electrolysis anti-between the electrochemistry region and the region B
Answer the promotion of density, therefore when carrying out cell reaction using the method disclosed in the present, should make the electrochemistry region and
Capacitance between the region B increases as much as possible.
It, can be in the electrochemical school district in order to increase the capacitance between the electrochemistry region and the region B in the present invention
Plasma, ionic liquid, ionized gas or solion are set between domain and the region B, and make ion in the electrification
It is vibrated between school district domain and the region B, and/or vibrates in the electrochemistry areas adjacent and oscillated around in the region B,
To realize the purpose for increasing the capacitance between the electrochemistry region and the region B.
In the present invention, it is more big more be conducive to electricity that the electrochemistry region A and the electrochemistry region B are formed by capacitance
The promotion of reaction density is solved, therefore when carrying out cell reaction using the method disclosed in the present, the electrochemical school district should be made
Capacitance between domain A and the electrochemistry region B increases as much as possible.
It, can be described in order to increase the capacitance between the electrochemistry region A and the electrochemistry region B in the present invention
Plasma, ionic liquid, ionized gas or solion are set between electrochemistry region A and the electrochemistry region B, and made
Ion vibrates between the electrochemistry region A and the electrochemistry region B, and/or oscillates around in the electrochemistry region A
And oscillated around in the electrochemistry region B, to realize the electricity between increasing the electrochemistry region A and electrochemistry region B
The purpose of capacity.
In the present invention, between the electrochemistry region and the region B and in the electrochemistry region A and the electrification
It is more big more be conducive to the promotion of electrochemical reaction density that capacitance is formed by between the B of school district domain, therefore public using present invention institute
When the method opened is electrochemically reacted, should make between the electrochemistry region and the region B and the electrochemistry region A and
Capacitance between the electrochemistry region B increases as much as possible.
Electrolytic method disclosed in this invention, it is negative there are electrolyte can be reduced in the case where electrolyte between two electrodes
Lotus extends its service life and is conducive to the balance and stability operation of system.
In the present invention, reducing agent and oxidant is can be generated under electro ultrafiltration in the compound.
In the present invention, reducing agent and oxidant is can be generated through electro ultrafiltration in other materials presence in the compound.
In the present invention, the reducing agent is the substance for having reproducibility for the oxidant.
In the present invention, the oxidant is the substance for having oxidisability for the reducing agent.
In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode
Point, the region B alternative selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region A can
Selectivity selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region B alternative selection is set as
The electrode of electrochemical reaction or a part of electrode.
In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electrochemistry region A, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electrochemistry region B, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led
The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit
Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed
Circuit be set as interior circuit.
In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute
The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit
It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non-
Electronic conduction electrical relation is formed by circuit and is set as interior circuit.
In the present invention, the area Jie electricity that so-called " area alternating current Jie electricity " refers to alternating current is selectively chosen and sets
For a part of relative subject, also alternative selection is set as the conduction region contacted with relative subject, is also selectively chosen
It is set as the conduction region that there is capacitance relation with relative subject.It includes that the area alternating current Jie electricity is this that so-called relative subject, which is exactly in A,
A in description.
In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become
The changed electromotive force of electromotive force or size of change.
In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction
Stream, the changed electric current of size or alternating current.
In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period,
Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.
In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.
In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.
In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B
Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship；Or, so-called A and B has non-electrical
Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected
Select electronic conduction relationship to property.
In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc.
At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the region B
Son conducting electrical relation " include the electrochemistry region and the region B through electronic conduction area, insulator, dielectric and/or from
Two solion ponds of son conducting body isolation have non-electronic conducting electrical relation.In this approach, it is selectively chosen
At least one in the electrochemistry region and the region B is set to be formed with capacitive region and/or non-electronic charged particle transmitter
Electrical relation.
In the present invention, it is so-called " the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor,
At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B
With non-electronic conducting electrical relation " it include the electrochemistry region A and the electrochemistry region B through electronic conduction area, insulation
Two solion ponds of body, dielectric and/or ion conducting body isolation have non-electronic conducting electrical relation.In this method
In, be selectively chosen make at least one in the electrochemistry region A and the electrochemistry region B with capacitive region and/or
Non-electronic charged particle transmitter forms electrical relation.
In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can
Selectively selection is set as metallic conductor area, carbon conductor region etc..
In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from
The substance of son, i.e. electrolyte in Conventional electrochemical method, can be according to the electrochemical properties of the reducing agent and the oxidant
Non-electronic charged particle transmitter is selected, such as when the reducing agent is H2, the oxidant is O2When, the non-electronic electrification
Particle conduction object alternative selects proton exchange membrane.
In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into
Row selection.
In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics
Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed
The electricity conducting relationship etc. that particle reciprocating vibration is formed.
There is non-electronic conducting electrical relation with non-electronic conducting electrical relation.
In the present invention, so-called electrochemistry region, so-called region B, so-called electrochemistry region A, so-called electrochemistry
Region B is equal with electrode.
In the present invention, the region that electronics export imports is equal with electrode.
It in the present invention, is selectively chosen, there is dielectric capacitance relationship between electrode.
In the present invention, it is selectively chosen, the electrochemistry region and the region B have dielectric capacitance relationship,
Dielectric can be gas, liquid, solid or vacuum.
It in the present invention, is selectively chosen, the electrochemistry region A and the electrochemistry region B have dielectric capacitance
Relationship, dielectric can be gas, liquid, solid or vacuum.
In the present invention, so-called dielectric capacitance relationship refers to the capacitance relation through dielectric formation, and dielectric can be
Gas, liquid, solid or vacuum.
In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance,
All capacitors such as pseudo capacitance, fake capacitance.
In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific
The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC
Film and solid oxide electrolyte etc..
In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including
Catalyst, ultra microstructure and/or region (such as electrode in electrolytic method etc.) at a set temperature, then for example in setting temperature
Metallic region under degree.
It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention
The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification
School district domain includes two or three in these three conditions.
In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition
Structure.
In the present invention, so-called " explosion limit " refers under conditions of the electrochemistry region, the reducing agent and institute
State the concentration ratio that oxidant cannot explode.
In the present invention, include the catalyst method in, the catalyst be set as include noble metal catalyst, or
The catalyst be set as include rare earth element catalyst.
In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.
In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region
In the method for relationship, one in the electrochemistry region and the region B through capacitor or through non-electronic conducting area (such as matter
The electrolyte such as proton exchange) again through external circuit and another electric communication, it is possible to realize that normality works.
It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention
In the method that electrical relation is connected, one in the electrochemistry region A and the electrochemistry region B is through capacitor or through non-electronic
Area (such as the electrolyte such as proton exchange membrane) are connected again through external circuit and another electric communication, it is possible to realize normality work
Make.
In the present invention, positive and negative non-electronic charged particle mixing is selectively chosen as non-electronic charged particle transmitter
Object.
In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B are alternative
Ground selection is set as same non-electronic charged particle transmitter, is also selectively chosen and is set as non-electronic charged particle not of the same race
How on earth transmitter selects, and should be determined according to the conductance calls of corresponding non-electronic charged particle.
It is the electrochemistry region, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention
When getting along near any the two in dielectric and the region B, at least one of neighbour the two got along is got along neighbour
Locate have ultra microstructure to increase the neighbour area got along, and then increases capacitance.
It is the electrochemistry region A, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention
When getting along near any the two in dielectric and the electrochemistry region B, at least one of neighbour the two got along than
It is adjacent mutually to have ultra microstructure to increase the neighbour area got along everywhere, and then increase capacitance.
In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B can be identical
It can also be different, but alternative when non-electronic charged particle transmitter A and non-electronic charged particle transmitter B are directly contacted
Selection is different, such as non-electronic charged particle transmitter A is proton conductive object, non-electronic charged particle transmitter B be negative oxygen from
Son conducting object.
In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode
Substance (including vacuum), such as electrolyte, dielectric etc..
In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.
In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets
For external circuit.
In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.
In the present invention, " the non-electronic charged particle " refers to the charged particle other than electronics, including proton and ion.
In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several
The identical component of title or substance.
In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field
Part, unit or system etc..
Beneficial effects of the present invention are as follows: electrolytic method disclosed in this invention will termination conventional electrolytic methods and electrolysis dress
Set the history for existing for necessary condition with electrolyte, for efficiently, the exploitation of long-life, inexpensive electrolysis unit provide it is new
Approach.
Specific embodiment
Technical solution of the present invention is further illustrated combined with specific embodiments below.
Embodiment 1
A kind of electrolytic method contacts electrochemistry region with compound or contacts compound with electrochemistry region, makes institute
Electrochemistry region is stated by alternating current electro ultrafiltration；Reducing agent and oxidant are alternately exported from the electrochemistry region.
As disposable embodiment, the embodiment of the present invention 1 is also selectively chosen from the electrochemistry region and leads
The molar mixture of Oxidizing and Reducing Agents out, or the biasing mixing from electrochemistry region export Oxidizing and Reducing Agents
Object.
Embodiment 2
A kind of electrolytic method contacts electrochemistry region with compound or contacts compound with electrochemistry region；It is described
Electrochemistry region has non-electronic conducting electrical relation through non-electronic charged particle transmitter and region B, in the electrochemical school district
Apply alternating current electro ultrafiltration between domain and the region B, alternately exports reducing agent and oxidant from the electrochemistry region.
As disposable embodiment, the embodiment of the present invention 2 be also selectively chosen make the electrochemistry region according to
It is secondary that there is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B, or make the electricity
Chemical regions have non-electronic conducting electrical relation through dielectric and region B.
As disposable embodiment, the embodiment of the present invention 2 and its disposable embodiment are also optionally selected
The molar mixture from electrochemistry region export Oxidizing and Reducing Agents is selected, or exports and aoxidizes from the electrochemistry region
The biasing mixture of agent and reducing agent.
Embodiment 3
A kind of electrolytic method contacts electrochemistry region A with compound or contacts compound with electrochemistry region A, makes
Electrochemistry region B is contacted with compound or is contacted compound with electrochemistry region B, and the electrochemistry region A is through non-electronic band
Charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, in the electrochemistry region A and the electricity
Apply alternating current electro ultrafiltration between chemical regions B, alternately exports reducing agent and oxidant from the electrochemistry region A.
As disposable embodiment, the embodiment of the present invention 3 be also selectively chosen make the electrochemistry region A according to
It is secondary that there is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B,
Or make the electrochemistry region A that there is non-electronic conducting electrical relation through dielectric and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 3 and its disposable embodiment are also optionally selected
The molar mixture from electrochemistry region A export Oxidizing and Reducing Agents is selected, or exports oxygen from the electrochemistry region A
The biasing mixture of agent and reducing agent；From the electrochemistry region B alternately export reducing agent and oxidant, or from the electrification
School district domain B exports the molar mixture of Oxidizing and Reducing Agents, or exports Oxidizing and Reducing Agents from the electrochemistry region B
Biasing mixture.
Embodiment 4
A kind of electrolytic method contacts electrochemistry region with compound or contacts compound with electrochemistry region, makes institute
Electrochemistry region is stated by alternating current electro ultrafiltration, alternately exports reducing agent and oxidant, the electrification from the electrochemistry region
School district domain and insulation have non-electronic conducting electrical relation.
As disposable embodiment, the embodiment of the present invention 4 also optionally exports oxygen from the electrochemistry region
The molar mixture of agent and reducing agent, or the biasing mixture from electrochemistry region export Oxidizing and Reducing Agents.
As disposable embodiment, the embodiment of the present invention 4 and its disposable embodiment are also optionally selected
Select make the electrochemistry region and isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, from
At least one of sub- solution and electronic conduction area have non-electronic conducting electrical relation.
Embodiment 5
A kind of electrolytic method contacts electrochemistry region with compound or contacts compound with electrochemistry region, described
Electrochemistry region has non-electronic conducting electrical relation through non-electronic charged particle transmitter and region B, in the electrochemical school district
Apply alternating current electro ultrafiltration between domain and the region B；Reducing agent and oxidant, institute are alternately exported from the electrochemistry region
Stating electrochemistry region has non-electronic conducting electrical relation through electrolyte and the region B.
As disposable embodiment, the embodiment of the present invention 5 passes through the electrochemistry region successively
Electronic conduction area and non-electronic charged particle transmitter and region B have non-electronic conducting electrical relation, or make the electrochemistry
Region has non-electronic conducting electrical relation through dielectric and region B.
As disposable embodiment, the embodiment of the present invention 5 and its disposable embodiment are also optionally selected
The molar mixture from electrochemistry region export Oxidizing and Reducing Agents is selected, or exports and aoxidizes from the electrochemistry region
The biasing mixture of agent and reducing agent.
As disposable embodiment, the embodiment of the present invention 5 and its aforementioned disposable embodiment can be further
Selectively selection make the electrochemistry region through insulation, isolation space, dielectric, capacitor, plasma, ionic liquid,
At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.
Embodiment 6
A kind of electrolytic method contacts electrochemistry region A with compound or contacts compound with electrochemistry region A, makes
Electrochemistry region B is contacted with compound or is contacted compound with electrochemistry region B；The electrochemistry region A is through non-electronic band
Charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, in the electrochemistry region A and the electricity
Apply alternating current electro ultrafiltration between chemical regions B, alternately exports reducing agent and oxidant from the electrochemistry region A, it is described
Electrochemistry region A has non-electronic conducting electrical relation through insulation and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 6 be also selectively chosen make the electrochemistry region A according to
It is secondary that there is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B,
Or make the electrochemistry region A that there is non-electronic conducting electrical relation through dielectric and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 6 and its disposable embodiment are also optionally
The molar mixture from electrochemistry region A export Oxidizing and Reducing Agents is selected, or is exported from the electrochemistry region A
The biasing mixture of Oxidizing and Reducing Agents；From the electrochemistry region B alternately export reducing agent and oxidant, or from the electricity
Chemical regions B exports the molar mixture of Oxidizing and Reducing Agents, or exports oxidant and reduction from the electrochemistry region B
The biasing mixture of agent.
As disposable embodiment, the embodiment of the present invention 6 and its all disposable embodiments are also alternative
Ground selection makes the electrochemistry region A through completely cutting off space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 1 to 6 and its disposable embodiment can be selected further
Select to selecting property the compound compound being set as in mixture；Or, the compound is set as water, the reducing agent is
Hydrogen, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, it is described to go back
Former agent is alcohol compound, and the oxidant is oxygen；Or, the compound is set as water, and water is joined jointly with carbon dioxide
With react, the reducing agent be ether compound, the oxidant be oxygen；Or, the compound is set as water, and water and two
Carbonoxide participates in reacting jointly, and the reducing agent is alkane derivative, and the oxidant is oxygen；Or, by the compound
It is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alkenes compounds, and the oxidant is oxygen；
Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alkynes compound, institute
Stating oxidant is oxygen.
As disposable embodiment, the embodiment of the present invention 1 to 6 and its disposable embodiment can be selected further
It selects to selecting property the biasing mixture being set as explosion limit mixture below.
As disposable embodiment, above-mentioned all embodiments including electrochemistry region of the present invention and its disposable
Embodiment further can selectively select for the electrochemistry area rotation to be arranged.
As disposable embodiment, the present invention it is above-mentioned it is all include the electrochemistry region A and the electrochemical school district
The embodiment of domain B and its disposable embodiment further can be selected selectively to rotate the electrochemistry region A and set
It sets, the electrochemistry region B rotation setting.
As disposable embodiment, all electrochemistry regions of the present invention, which are selectively chosen, is set as three-dimensional electricity
Pole.
As disposable embodiment, all electrochemistry region A of the present invention, which are selectively chosen, is set as three-dimensional
Electrode.
As disposable embodiment, all electrochemistry region B of the present invention, which are selectively chosen, is set as three-dimensional
Electrode.
As disposable embodiment, the present invention is selectively chosen in the specific implementation by the electrochemistry region
As an electrode, using electric conductor as another electrode, two electrode cooperatings are completed the conversion of chemical energy electric energy, be may be selected
Property select using an electrochemistry region as an electrode, using another described electrochemistry region as another electricity
Pole, two electrode cooperatings complete the conversion of chemical energy electric energy.
It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention
Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention
It encloses.
Claims (12)
1. a kind of electrolytic method, it is characterised in that: make electrochemistry region that compound and electrochemistry region are contacted or made with compound
Contact, makes the electrochemistry region by alternating current electro ultrafiltration；Reducing agent and oxidant are alternately exported from the electrochemistry region,
Or the molar mixture from electrochemistry region export Oxidizing and Reducing Agents, or export and aoxidize from the electrochemistry region
The biasing mixture of agent and reducing agent.
2. a kind of electrolytic method, it is characterised in that: make electrochemistry region that compound and electrochemistry region are contacted or made with compound
Contact；The electrochemistry region has non-electronic conducting electrical relation or described through non-electronic charged particle transmitter and region B
It is successively closed through electronic conduction area and non-electronic charged particle transmitter and region B with non-electronic conducting electricity in electrochemistry region
System or the electrochemistry region have non-electronic conducting electrical relation through dielectric and region B；In the electrochemistry region and institute
State application alternating current electro ultrafiltration between the B of region；From the electrochemistry region alternately export reducing agent and oxidant, or from described
Electrochemistry region exports the molar mixture of Oxidizing and Reducing Agents, or exports oxidant and reduction from the electrochemistry region
The biasing mixture of agent.
3. a kind of electrolytic method, it is characterised in that: make electrochemistry region A that compound and electrochemistry region are contacted or made with compound
A contact, contacts electrochemistry region B with compound or contacts compound with electrochemistry region B；The electrochemistry region A warp
Non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A
Successively closed through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B with non-electronic conducting electricity
System or the electrochemistry region A have non-electronic conducting electrical relation through dielectric and the electrochemistry region B；In the electricity
Apply alternating current electro ultrafiltration between chemical regions A and the electrochemistry region B；From the electrochemistry region A, alternately export is gone back
Former agent and oxidant, or from the molar mixture of electrochemistry region A export Oxidizing and Reducing Agents, or from the electrification
The biasing mixture of school district domain A export Oxidizing and Reducing Agents；From the electrochemistry region B alternately export reducing agent and oxidation
Agent, or led from the molar mixture of electrochemistry region B export Oxidizing and Reducing Agents, or from the electrochemistry region B
The biasing mixture of Oxidizing and Reducing Agents out.
4. a kind of electrolytic method, it is characterised in that: make electrochemistry region that compound and electrochemistry region are contacted or made with compound
Contact, makes the electrochemistry region by alternating current electro ultrafiltration；Reducing agent and oxidant are alternately exported from the electrochemistry region,
Or the molar mixture from electrochemistry region export Oxidizing and Reducing Agents, or export and aoxidize from the electrochemistry region
The biasing mixture of agent and reducing agent；The electrochemistry region and insulation, isolation space, electrolyte, dielectric, capacitor, etc.
At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area are closed with non-electronic conducting electricity
System.
5. a kind of electrolytic method, it is characterised in that: make electrochemistry region that compound and electrochemistry region are contacted or made with compound
Contact；The electrochemistry region has non-electronic conducting electrical relation or described through non-electronic charged particle transmitter and region B
It is successively closed through electronic conduction area and non-electronic charged particle transmitter and region B with non-electronic conducting electricity in electrochemistry region
System or the electrochemistry region have non-electronic conducting electrical relation through dielectric and region B；In the electrochemistry region and institute
State application alternating current electro ultrafiltration between the B of region；From the electrochemistry region alternately export reducing agent and oxidant, or from described
Electrochemistry region exports the molar mixture of Oxidizing and Reducing Agents, or exports oxidant and reduction from the electrochemistry region
The biasing mixture of agent；The electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, from
At least one of sub- liquid, ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the region B
Relationship.
6. a kind of electrolytic method, it is characterised in that: make electrochemistry region A that compound and electrochemistry region are contacted or made with compound
A contact, contacts electrochemistry region B with compound or contacts compound with electrochemistry region B；The electrochemistry region A warp
Non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A
Successively closed through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B with non-electronic conducting electricity
System or the electrochemistry region A have non-electronic conducting electrical relation through dielectric and the electrochemistry region B；In the electricity
Apply alternating current electro ultrafiltration between chemical regions A and the electrochemistry region B；From the electrochemistry region A, alternately export is gone back
Former agent and oxidant, or from the molar mixture of electrochemistry region A export Oxidizing and Reducing Agents, or from the electrification
The biasing mixture of school district domain A export Oxidizing and Reducing Agents；From the electrochemistry region B alternately export reducing agent and oxidation
Agent, or led from the molar mixture of electrochemistry region B export Oxidizing and Reducing Agents, or from the electrochemistry region B
The biasing mixture of Oxidizing and Reducing Agents out；The electrochemistry region A through insulation, isolation space, electrolyte, dielectric,
At least one of capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry
Region B has non-electronic conducting electrical relation.
7. the electrolytic method as described in any one of claims 1 to 6, it is characterised in that: the compound is set as in mixture
Compound；Or, the compound is set as water, the reducing agent is hydrogen, and the oxidant is oxygen；Or, the compound is set
For water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alcohol compound, and the oxidant is oxygen；Or, institute
It states compound and is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is ether compound, and the oxidant is
Oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkane derivative,
The oxidant is oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is
Alkenes compounds, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide,
The reducing agent is alkynes compound, and the oxidant is oxygen.
8. the electrolytic method as described in any one of claims 1 to 6, it is characterised in that: the biasing mixture is set as explosion pole
Limit mixture below.
9. electrolytic method as claimed in claim 7, it is characterised in that: the biasing mixture is set as explosion limit mixing below
Object.
10. the electrolytic method as described in any one of claim 1 to 6 and 9, it is characterised in that: the electrochemistry area rotation is set
It sets；Or, in the method including the electrochemistry region A and electrochemistry region B, the electrochemistry region A rotation setting,
The electrochemistry region B rotation setting.
11. electrolytic method as claimed in claim 7, it is characterised in that: the electrochemistry area rotation setting；Or, including institute
In the method for stating electrochemistry region A and the electrochemistry region B, the electrochemistry region A rotation setting, the electrochemistry region
B rotation setting.
12. electrolytic method as claimed in claim 8, it is characterised in that: the electrochemistry area rotation setting；Or, including institute
In the method for stating electrochemistry region A and the electrochemistry region B, the electrochemistry region A rotation setting, the electrochemistry region
B rotation setting.
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2018109771224 | 2018-08-26 | ||
| CN201810977122 | 2018-08-26 | ||
| CN201810981964 | 2018-08-27 | ||
| CN2018109819647 | 2018-08-27 | ||
| CN201810981960 | 2018-08-27 | ||
| CN2018109819609 | 2018-08-27 | ||
| CN2019100368529 | 2019-01-15 | ||
| CN201910036852 | 2019-01-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109797401A true CN109797401A (en) | 2019-05-24 |
Family
ID=66561937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910108000.6A Pending CN109797401A (en) | 2018-08-26 | 2019-02-02 | A kind of electrolytic method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109797401A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054104A (en) * | 1991-03-01 | 1991-08-28 | 许昌师范专科学校 | Alternating current electrolysis prepares the method for nickel salt |
| CN201003074Y (en) * | 2007-02-08 | 2008-01-09 | 林文章 | Oxyhydrogen machine capable of automatically changing polarity |
-
2019
- 2019-02-02 CN CN201910108000.6A patent/CN109797401A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054104A (en) * | 1991-03-01 | 1991-08-28 | 许昌师范专科学校 | Alternating current electrolysis prepares the method for nickel salt |
| CN201003074Y (en) * | 2007-02-08 | 2008-01-09 | 林文章 | Oxyhydrogen machine capable of automatically changing polarity |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| LaConti et al. | Solid polymer electrolyte electrochemical cells-Electrode and other materials considerations | |
| KR20220104199A (en) | Water electrolysis method and apparatus | |
| CN103682377A (en) | Preparation method of air cathode plate of microbial fuel cell | |
| CN107381776A (en) | A kind of preparation method of microbiological fuel cell processing ion containing heavy metal copper | |
| CN109797401A (en) | A kind of electrolytic method | |
| CN109735868A (en) | A kind of electrolysis unit | |
| CN109536989A (en) | A kind of electrochemistry formated device | |
| WO2018079965A1 (en) | Hybrid power generation system and energy-independent hydrogen-electricity hybrid charging station, which use reverse electrodialysis device capable of efficiently producing hydrogen-electricity | |
| CN211479867U (en) | Capacitor | |
| CN211479869U (en) | Capacitor | |
| KR840004616A (en) | Improved dual layer energy storage | |
| CN109536983A (en) | A kind of electrochemical method for synthesizing | |
| CN110767928B (en) | Thermal regeneration ammonia battery based on electric field enhanced mass transfer and preparation method | |
| KR102041554B1 (en) | Hybrid power generation system and self supporting hydrogen-electricity complex charge station using reverse electrodialysis power generation appartus with effective hydrogen-electricity generation | |
| CN109695043A (en) | A kind of electrochemical reaction implementation method | |
| CN109786792A (en) | A kind of chemical energy electric energy conversion method | |
| RU2277274C1 (en) | Method for converting chemical material energy into ac current energy | |
| CN109802202A (en) | A kind of electrochemical appliance | |
| CN109786793A (en) | A kind of chemical energy electric energy conversion method | |
| CN109802203A (en) | A kind of electrochemical appliance | |
| CN109860681A (en) | A kind of electrochemical appliance | |
| RU2443041C2 (en) | Method for electric energy production by the way of its electrochemical generation and device for its realization | |
| CN109860679A (en) | A kind of chemical energy device for converting electric energy | |
| CN109860678A (en) | A kind of electrochemical reaction implementation method | |
| CN109786803A (en) | A kind of electrochemical appliance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190524 |