CN109860681A - A kind of electrochemical appliance - Google Patents
A kind of electrochemical appliance Download PDFInfo
- Publication number
- CN109860681A CN109860681A CN201910109789.7A CN201910109789A CN109860681A CN 109860681 A CN109860681 A CN 109860681A CN 201910109789 A CN201910109789 A CN 201910109789A CN 109860681 A CN109860681 A CN 109860681A
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- electrochemistry region
- oxidant
- reducing agent
- feed channel
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- 230000005518 electrochemistry Effects 0.000 claims abstract description 460
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 366
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- 239000000203 mixture Substances 0.000 claims abstract description 171
- 230000005611 electricity Effects 0.000 claims abstract description 160
- 239000000126 substance Substances 0.000 claims abstract description 123
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- 238000000034 method Methods 0.000 claims description 204
- 230000008569 process Effects 0.000 claims description 198
- 239000002245 particle Substances 0.000 claims description 87
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- 239000003990 capacitor Substances 0.000 claims description 35
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- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 48
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- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
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- 240000002853 Nelumbo nucifera Species 0.000 description 2
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- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
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- RFVVBBUVWAIIBT-UHFFFAOYSA-N beryllium nitrate Chemical compound [Be+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O RFVVBBUVWAIIBT-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
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- 229910052700 potassium Inorganic materials 0.000 description 2
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- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
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- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- IJCCOEGCVILSMZ-UHFFFAOYSA-L copper;dichlorate Chemical compound [Cu+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O IJCCOEGCVILSMZ-UHFFFAOYSA-L 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005370 electroosmosis Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- ZICFUFGMZGWZMA-UHFFFAOYSA-L iron(2+) diiodate Chemical compound [Fe+2].[O-]I(=O)=O.[O-]I(=O)=O ZICFUFGMZGWZMA-UHFFFAOYSA-L 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000005404 monopole Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- GTTYPHLDORACJW-UHFFFAOYSA-N nitric acid;sodium Chemical compound [Na].O[N+]([O-])=O GTTYPHLDORACJW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000019396 potassium bromate Nutrition 0.000 description 1
- 229940094037 potassium bromate Drugs 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229960005076 sodium hypochlorite Drugs 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- GTQFPPIXGLYKCZ-UHFFFAOYSA-L zinc chlorate Chemical compound [Zn+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O GTQFPPIXGLYKCZ-UHFFFAOYSA-L 0.000 description 1
- TUDPEWOTGHYZBQ-UHFFFAOYSA-L zinc;dibromate Chemical compound [Zn+2].[O-]Br(=O)=O.[O-]Br(=O)=O TUDPEWOTGHYZBQ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Battery Electrode And Active Subsutance (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Electrotherapy Devices (AREA)
Abstract
The invention discloses a kind of electrochemical appliances, including electrochemistry region, the electrochemistry region is connected to setting with reducing agent feed channel, the electrochemistry region is connected to setting with oxidant feed channel, the electrochemistry region includes the area alternating current Jie electricity, and it is work normality that the export of the electronics in the electrochemistry region, which imports,.Electrochemical appliance disclosed in this invention will terminate traditional chemical energy electric energy conversion electrochemical appliance with the history for existing for necessary condition of electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.), this kind of device that terminates also can not be used securely and reliably to the history of oxidant reduction agent composition, industrialization for the chemical energy electric energy conversion electrochemical appliance of efficient, long-life, low cost provides new approach, and will redefine engine.
Description
Technical field
The present invention relates to electricity field, electrochemical field more particularly to a kind of electrochemical appliances.
Background technique
Conventional electrochemical device is required to non-electronic charged particle (such as negative oxygen ion or proton) and transmits between two electrodes,
For example, it is desired to which the positive charged particle and electronics that electrochemistry region (electrode) generates are removed, or need to produce in electrochemistry region
Raw electronegative non-electronic charged particle removes.Non-electronic charged particle not only consumes electric energy in the transmission of two interpolars, but also
It is required to transmit non-electronic charged particle and does not transmit electronics and electrolyte (such as the hydrogen fuel cell with many particular/special requirements
Proton exchange membrane, solid oxide electrolyte etc.), because of the complexity of electrolyte, manufacturing technology is unqualified always, and
As the basic reason for restricting electrochemical appliance (such as fuel cell etc.) improved efficiency, life-span upgrading and cost reduction, also
The problem the most serious of electrochemical appliance (such as fuel cell etc.) efficient industrialization is hindered through becoming.If one can be invented
Kind, will termination tradition electrification not to remove model electrochemical device of the non-electronic charged particle as necessary condition from electrochemistry region
It learns device (such as fuel cell etc.) and necessity is existed for electrolyte (such as proton exchange membrane, solid oxide electrolyte etc.)
The conventional electrochemical device that terminates also cannot securely and reliably be used the history of reducing agent oxidant mixture by the history of condition, and
The industrialization for converting electrochemical appliance for efficient, long-life, inexpensive chemical energy electric energy provides new approach, and will redefine
Engine.Therefore, it is necessary to invent a kind of model electrochemical device.
Summary of the invention
To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:
A kind of electrochemical appliance of scheme 1., including electrochemistry region, the electrochemistry region and reducing agent feed channel connect
Logical setting, the electrochemistry region are connected to setting with oxidant feed channel, and the electrochemistry region includes that alternating current connects electricity
Area, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region is connected to setting, the electrochemistry region and oxidant feed with reducing agent feed channel
Channel connection setting, the electrochemistry region includes the area alternating current Jie electricity, reducing agent feed channel feed reducing agent
Alternately, the export of the electronics in the electrochemistry region is led for process and the process of oxidant feed channel feed oxidant
Enter for the normality that works;
Or, the electrochemistry region is connected to setting, the electrochemistry region and oxidant feed with reducing agent feed channel
Channel connection setting, the electrochemistry region includes the area alternating current Jie electricity, reducing agent feed channel feed reducing agent
There is overlapping in process and the process of oxidant feed channel feed oxidant, the export of the electronics in the electrochemistry region is led
Enter for the normality that works;
Or, the electrochemistry region is connected to setting, the electrochemistry region and oxidant feed with reducing agent feed channel
Channel connection setting, the electrochemistry region include the area alternating current Jie electricity, the interrupted feed reduction in reducing agent feed channel
There is overlapping, the electrification school district in the feed process of the interrupted feed oxidant of the feed process of agent and oxidant feed channel
It is work normality that the export of the electronics in domain, which imports,.
A kind of electrochemical appliance of scheme 2., including electrochemistry region, the electrochemistry region are arranged in the cavity, the chamber
Body is connected to setting with reducing agent feed channel, and the cavity is connected to setting, the electrochemistry region packet with oxidant feed channel
The area alternating current Jie electricity is included, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the chamber with reducing agent feed channel
Body is connected to setting with oxidant feed channel, and the electrochemistry region includes the area alternating current Jie electricity, and the reducing agent feed is logical
The process of road feed reducing agent and the process of oxidant feed channel feed oxidant alternately, the electrochemistry region
Electronics export import be work normality;
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the chamber with reducing agent feed channel
Body is connected to setting with oxidant feed channel, and the electrochemistry region includes the area alternating current Jie electricity, and the reducing agent feed is logical
There is overlapping, the electrochemistry region in the process of road feed reducing agent and the process of oxidant feed channel feed oxidant
Electronics export import be work normality;
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the chamber with reducing agent feed channel
Body is connected to setting with oxidant feed channel, and the electrochemistry region includes the area alternating current Jie electricity, and the reducing agent feed is logical
There is weight in the feed process of the interrupted feed oxidant of feed process and oxidant feed channel of the interrupted feed reducing agent in road
Folded, it is work normality that the export of the electronics in the electrochemistry region, which imports,.
A kind of electrochemical appliance of scheme 3., including electrochemistry region, the electrochemistry region through reducing agent control switch with
The connection setting of reducing agent feed channel, the electrochemistry region is connected to oxidant feed channel through oxidant control switch and sets
It sets, the electrochemistry region includes the area alternating current Jie electricity, and it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region is connected to setting, the electrochemistry with reducing agent feed channel through reducing agent control switch
Region is connected to setting with oxidant feed channel through oxidant control switch, and the electrochemistry region includes that alternating current connects electricity
Area, the reducing agent control switch by control device controlled and the oxidant control switch by control device controlled realization described in
The process of reducing agent feed channel feed reducing agent and the process of oxidant feed channel feed oxidant alternately, institute
It is work normality that the export for stating the electronics in electrochemistry region, which imports,;
Or, the electrochemistry region is connected to setting, the electrochemistry with reducing agent feed channel through reducing agent control switch
Region is connected to setting with oxidant feed channel through oxidant control switch, and the electrochemistry region includes that alternating current connects electricity
Area, the reducing agent control switch by control device controlled and the oxidant control switch by control device controlled realization described in
There is overlapping, institute in the process of reducing agent feed channel feed reducing agent and the process of oxidant feed channel feed oxidant
It is work normality that the export for stating the electronics in electrochemistry region, which imports,;
Or, the electrochemistry region is connected to setting, the electrochemistry with reducing agent feed channel through reducing agent control switch
Region is connected to setting with oxidant feed channel through oxidant control switch, and the electrochemistry region includes that alternating current connects electricity
Area, the reducing agent control switch by control device controlled and the oxidant control switch by control device controlled realization described in
The confession of the interrupted feed oxidant of feed process and oxidant feed channel of the interrupted feed reducing agent in reducing agent feed channel
It passes through journey and there is overlapping, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region is connected to setting, the electrochemistry with reducing agent feed channel through reducing agent control switch
Region is connected to setting with oxidant feed channel through oxidant control switch, and the electrochemistry region includes that alternating current connects electricity
Area, the reducing agent control switch by control device controlled and the oxidant control switch by control device controlled realization described in
Reducing agent feed channel is opened and oxidant feed channel is discontinuously opened or the reducing agent control switch is by control device
Control and the oxidant control switch are controlled by control device realizes the unlatching of oxidant feed channel and the reducing agent
Feed channel is discontinuously opened, and it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region is connected to setting and the electrochemistry through reducing agent control switch with reducing agent feed channel
Region is connected to setting with oxidant feed channel, and the electrochemistry region includes the area alternating current Jie electricity, the reducing agent control
Switch is controlled by control device realizes that reducing agent feed channel is discontinuously opened, and the export of the electronics in the electrochemistry region is led
Enter for the normality that works;
Or, the electrochemistry region is connected to setting and the electrochemistry through oxidant control switch with oxidant feed channel
Region is connected to setting with reducing agent feed channel, and the electrochemistry region includes the area alternating current Jie electricity, the oxidant control
Switch is controlled by control device realizes that oxidant feed channel is discontinuously opened, and the export of the electronics in the electrochemistry region is led
Enter for the normality that works.
A kind of electrochemical appliance of scheme 4., including electrochemistry region, the electrochemistry region are arranged in the cavity, the chamber
Body is connected to setting with reducing agent feed channel through reducing agent control switch, and the cavity is supplied through oxidant control switch and oxidant
Channel connection setting is sent, the electrochemistry region includes the area alternating current Jie electricity, and the export of the electronics in the electrochemistry region is led
Enter for the normality that works;
Or, the electrochemistry region setting is in the cavity, the cavity is logical through reducing agent control switch and reducing agent feed
Road connection setting, the cavity are connected to setting, the electrochemistry region packet with oxidant feed channel through oxidant control switch
Include the area alternating current Jie electricity, the reducing agent control switch is controlled by control device and the oxidant control switch is filled by control
It sets and controls the process and oxidant feed channel feed oxidant for realizing reducing agent feed channel feed reducing agent
Alternately, it is work normality that the export of the electronics in the electrochemistry region imports to process;
Or, the electrochemistry region setting is in the cavity, the cavity is logical through reducing agent control switch and reducing agent feed
Road connection setting, the cavity are connected to setting, the electrochemistry region packet with oxidant feed channel through oxidant control switch
Include the area alternating current Jie electricity, the reducing agent control switch is controlled by control device and the oxidant control switch is filled by control
It sets and controls the process and oxidant feed channel feed oxidant for realizing reducing agent feed channel feed reducing agent
There is overlapping in process, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region setting is in the cavity, the cavity is logical through reducing agent control switch and reducing agent feed
Road connection setting, the cavity are connected to setting, the electrochemistry region packet with oxidant feed channel through oxidant control switch
Include the area alternating current Jie electricity, the reducing agent control switch is controlled by control device and the oxidant control switch is filled by control
It sets control and realizes that the feed process of the interrupted feed reducing agent in reducing agent feed channel and oxidant feed channel are interrupted
There is overlapping in the feed process of feed oxidant, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region setting is in the cavity, the cavity is logical through reducing agent control switch and reducing agent feed
Road connection setting, the cavity are connected to setting, the electrochemistry region packet with oxidant feed channel through oxidant control switch
Include the area alternating current Jie electricity, the reducing agent control switch is controlled by control device and the oxidant control switch is filled by control
It sets control and realizes that the reducing agent control switch is opened and the reducing agent is discontinuously opened or realized to the oxidant control switch
Control switch is discontinuously opened and the oxidant control switch is opened, and it is work that the export of the electronics in the electrochemistry region, which imports,
Normality;
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the chamber with reducing agent feed channel
Body is connected to setting with oxidant feed channel through oxidant control switch, and the electrochemistry region includes the area alternating current Jie electricity,
The oxidant control switch is controlled realization by control device and is discontinuously opened, and the export importing of the electronics in the electrochemistry region is
Work normality;
Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the chamber with oxidant feed channel
Body is connected to setting with reducing agent feed channel through reducing agent control switch, and the electrochemistry region includes the area alternating current Jie electricity,
The reducing agent control switch is controlled realization by control device and is discontinuously opened, and the export importing of the electronics in the electrochemistry region is
Work normality.
A kind of electrochemical appliance of scheme 5., including electrochemistry region, the electrochemistry region and reducing agent and oxidant
The connection setting of mixture feed channel, the electrochemistry region includes the area alternating current Jie electricity, the electronics in the electrochemistry region
Export import be work normality;
Or, the electrochemistry region is connected to setting, the electrochemistry with the mixture feed channel of reducing agent and oxidant
Region includes the area alternating current Jie electricity, mixture feed channel continuous feeding mixture, the electronics in the electrochemistry region
Export import be work normality;
Or, the electrochemistry region is connected to setting, the electrochemistry with the mixture feed channel of reducing agent and oxidant
Region includes the area alternating current Jie electricity, the interrupted feed mixture in mixture feed channel, the electronics in the electrochemistry region
Export import be work normality.
A kind of electrochemical appliance of scheme 6., including electrochemistry region, the electrochemistry region are arranged in the cavity, the chamber
Body is connected to setting with the mixture feed channel of reducing agent and oxidant, and the electrochemistry region includes the area alternating current Jie electricity,
It is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region setting is in the cavity, the cavity is logical with the mixture feed of reducing agent and oxidant
Road connection setting, the electrochemistry region includes the area alternating current Jie electricity, mixture feed channel continuous feeding mixture,
It is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region setting is in the cavity, the cavity is logical with the mixture feed of reducing agent and oxidant
Road connection setting, the electrochemistry region includes the area alternating current Jie electricity, the interrupted feed mixture in mixture feed channel,
It is work normality that the export of the electronics in the electrochemistry region, which imports,.
A kind of electrochemical appliance of scheme 7., including electrochemistry region, the electrochemistry region through mixture control switch with
Reducing agent is connected to setting with the mixture feed channel of oxidant, and the electrochemistry region includes the area alternating current Jie electricity, described
It is work normality that the export of the electronics in electrochemistry region, which imports,;
Or, the electrochemistry region is connected to through mixture control switch with the mixture feed channel of reducing agent and oxidant
Setting, the electrochemistry region include the area alternating current Jie electricity, and the mixture control switch is controlled by control device realizes institute
Mixture feed channel continuous feeding mixture is stated, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region is connected to through mixture control switch with the mixture feed channel of reducing agent and oxidant
Setting, the electrochemistry region include the area alternating current Jie electricity, and the mixture control switch is controlled by control device realizes institute
The interrupted feed mixture in mixture feed channel is stated, it is work normality that the export of the electronics in the electrochemistry region, which imports,.
A kind of electrochemical appliance of scheme 8., including electrochemistry region, the electrochemistry region are arranged in the cavity, the chamber
Body is connected to setting with the mixture feed channel of reducing agent and oxidant through mixture control switch, and the electrochemistry region includes
The area alternating current Jie electricity, it is work normality that the export of the electronics in the electrochemistry region, which imports,;
Or, the electrochemistry region setting is in the cavity, the cavity is through mixture control switch and reducing agent and oxidation
The mixture feed channel of agent is connected to setting, and the electrochemistry region includes the area alternating current Jie electricity, and the mixture control is opened
It closes to be controlled by control device and realizes that mixture feed channel continuous feeding mixture, the electronics in the electrochemistry region are led
Import out is work normality;
Or, the electrochemistry region setting is in the cavity, the cavity is through mixture control switch and reducing agent and oxidation
The mixture feed channel of agent is connected to setting, and the electrochemistry region includes the area alternating current Jie electricity, and the mixture control is opened
It closes to be controlled by control device and realizes that the interrupted feed mixture in mixture feed channel, the electronics in the electrochemistry region are led
Import out is work normality.
Scheme 9. on the basis of either a program, is further selectively selected the electrochemistry region in scheme 1 to 8
In the electric field with the setting of power supply electric communication or electrochemistry region setting;Or, by the electrochemistry region and capacitor, direct current
Power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit,
Rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three
Conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten
Conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction electricity effect
Setting.
For scheme 10. in scheme 1 to 9 on the basis of either a program, being selectively chosen passes through the electrochemistry region
Dielectric or electrolyte and electric conductor on the electrochemistry region have non-electronic conducting electrical relation, or, making the electrification
School district domain through on electric conductor dielectric or electrolyte and the electric conductor there is non-electronic conducting electrical relation, or, making described
Electrochemistry region through on electric conductor A dielectric or electrolyte and electric conductor there is non-electronic conducting electrical relation, or, making described
The electricity on another face of dielectric or electrolyte again through the electric conductor A on a face of the electrochemistry region through electric conductor A
Medium or electrolyte and electric conductor have non-electronic conducting electrical relation.
For scheme 11. such as in scheme 1 to 10 on the basis of either a program, being selectively chosen makes the electrochemistry region
Rotation setting.
Aforementioned schemes of the present invention further can selectively select to be inserted between the reducing agent and the oxidant
Inert substance and/or dead band duration.
In the present invention, so-called " it is work normality that the export of the electronics in the electrochemistry region, which imports, " refers to from the electricity
It is to continue working process that chemical regions, which export electronics and import electronics to the electrochemistry region, i.e., electrification disclosed in this invention
Device is learned in working condition, electronics is exported from the electrochemistry region and imports electronics to the electrochemistry region and held for one kind
Continuous process.In other words, the electrochemistry region with alternating current corresponding and described electrochemistry region and alternating current phase
It corresponds to continue working process.
In the present invention, there may be output electric energy for a certain step that the export of the electronics in the area the alternating current Jie electricity imports
And/or the case where absorbing electric energy, but its summation is output electric energy.
In the present invention, the area the alternating current Jie electricity there may be output electric energy and/or absorb electric energy the case where, but its
Summation is output electric energy.
In the present invention, it is negative to be selectively chosen the setting on the circuit of the electronics export importing in the electrochemistry region
Load, terminal are electrically connected structure and/or setting power supply.
In the present invention, so-called " inductor conductor " refers to all externally output magnetic force energy and leading from outer absorption magnetic force energy
Body.Such as transformer coil, electrical-coil, conductor bars for dynamoelectric machines etc..
In the present invention, so-called " phase converter " is the direction vector and its voltage for instigating electric current (or charged particle stream)
Angled device, the circuit for example including capacitor, the circuit including inductance and including capacitor also include inductance circuit
Deng.
In the present invention, the principle of electrochemical appliance disclosed in this invention is carried out as described below:
Through detailed analysis, it can be found that there is the basic logic of universality using the process of redox reaction power generation, specifically
Be analyzed as follows: the process to be generated electricity using redox reaction, is exported from reducing agent by electronics, forms reducing agent cation, then
By electronics derived from institute imported into reducing agent cation and oxidant coexistence make three react generate the reducing agent and
The product of the oxidizing reduction reaction externally exports electric energy on the path that electronics export and electronics import.In tradition
In hydrogen-oxygen fuel cell, such as PEMFC, under the effect of the catalyst, hydrogen molecule is separated into proton and electronics, and proton is made to pass through matter
Proton exchange enters the oxygen side with catalyst, and electronics is loaded from hydrogen side and imported into proton and what oxygen coexisted has catalyst
Oxygen side, proton (H+), oxygen (O2) and electronics (e-) reaction generation water.This means that the process to be generated electricity using redox reaction
With following basic logic: electronics is made into reducing agent positively ionized from reducing agent export, then by electronics imported into reducing agent just from
The coexistence of son and oxidant makes reducing agent cation, oxidant and electronics three react the generation reducing agent and the oxidation
The product of agent redox reaction, this overall process is external output electric energy, and the output of electric energy is leading by electronics
Realization is imported out.This basic logic is it is meant that we can not be by the constraint of conventional fuel cell concrete form, as long as full
The requirement of this basic logic of foot, so that it may externally export electric energy using the redox reaction of Oxidizing and Reducing Agents.And this
Exactly from electrochemistry region, export electronics makes reducing agent form reducing agent cation to the basic process of the disclosed device of invention, then
Make electronics imported into the electrochemistry region to coexist with oxidant and the reducing agent cation, thus make electronics and oxidant and
Reducing agent cation three, which reacts, generates the product of the oxidant and the reducing agent redox reaction, and then realizes
Under the premise of there is no by necessity derived from the reducing agent cation, also it is being not present other non-electronic charged particles
Under the premise of derived necessity, electric energy is externally exported.
Disclosed in this invention include reducing agent, oxidant alternating action device principle it is as follows: utilize electrochemistry
Region is alternately contacted with reducing agent and oxidant or is alternately contacted using reducing agent and oxidant with electrochemistry region, and reducing agent is made
Positive charged particle and electronics are generated in the electrochemistry region, exports electronics from the electrochemistry region, makes electronics to described
Electrochemistry region imports, and positive charged particle, the oxidant described in the electrochemistry region and electron reaction generate described go back
The product that former agent and the oxidant react is imported using the export of electronics and realizes output electric energy and/or absorption electric energy,
So circulation, realization continues working process, and (when importing electronics to the electrochemistry region, in some cases, electronics is in institute
It states electrochemistry region and oxidant reaction generates negative charged particles C, the negative charged particles C and the positive charged particle reaction are raw
At the product that the reducing agent and the oxidant react, imported using the export of electronics realize output electric energy and/or
Electric energy is absorbed, is so recycled, realization continues working process).In realizing this electrochemical process, it is selectively chosen, institute
It states electrochemistry region, external circuit, capacitor and reception and constitutes circuit and/or the electrochemistry region, outer for the region of electron
Circuit, non-electronic charged particle vibrate area and reception and constitute circuit for the region of electron.It, can be to institute in this device
It states electrochemistry region and implements electro ultrafiltration, electro ultrafiltration can control export and/or importing with strengthening electronic, thus can be effective
It avoids reducing agent and oxidant from mixing and redox reaction directly occurs, improve safety, reliability and efficiency.In this device
In, it can also first implement electro ultrafiltration to it before the electrochemistry region and material effect, purpose is also to avoid reducing agent
Redox reaction directly occurs with oxidant mixing, improves safety, reliability and efficiency.
Disclosed in this invention include reducing agent and oxidant mixture effect device principle it is as follows: utilize electricity
Chemical regions contact with the mixture of reducing agent and oxidant or make the mixture of reducing agent and oxidant to connect with electrochemistry region
Touching, exports electronics from the electrochemistry region using electro ultrafiltration, and then the reducing agent is made to form positive charged particle, Xiang Suoshu
Electrochemistry region imports electronics, the positive charged particle and the oxidant and electron reaction generates the reducing agent and the oxygen
The reaction product of agent, next step, Xiang Suoshu electrochemistry region import electronics, lead electronics from the electrochemistry region
Out, under the action of electronics imports and exports, the reducing agent and the oxidant reaction generate the reducing agent and the oxidation
The reaction product of agent absorbs electric energy and/or output electric energy on the channel that electronics exports and/or imports, so recycles, realize
Continuing working process, (in some cases, when importing electronics to the electrochemistry region, the oxidant and electron reaction are raw
At electronics C, the positive charged particle described in the electrochemistry region and electronics C reaction generate the reducing agent and the oxidation
The reaction product of agent absorbs electric energy and/or output electric energy on the channel that electronics exports and/or imports, so recycles, realize
Continue working process).In realizing this electrochemical process, it is selectively chosen, the electrochemistry region, external circuit, electricity
Hold and receives and constitute circuit and/or the electrochemistry region, external circuit, the vibration of non-electronic charged particle for the region of electron
It swings area and receives and constitute circuit for the region of electron.In this device, to be effectively prevented from the reducing agent and described
Redox reaction directly occurs for oxidant mixing, can first implement to it before the electrochemistry region and material effect
Electro ultrafiltration.
Disclosed in this invention include reducing agent and oxidant the principle of device that discontinuously acts on of mixture it is as follows: remove
Outside the influence discontinuously acted on, the principle of the present apparatus and the principle of the device for the mixture effect for including reducing agent and oxidant are complete
It is identical, and interrupted function is that can be better protected from or eliminate reducing agent described in mixture and the oxidant in electricity
Pole participates in directly carrying out the ability that redox reaction loses output electric energy in the case where (the i.e. described electrochemistry region participates in), into
And the efficiency of device disclosed in this invention is improved, as following reducing agents and oxidant mixture discontinuously act on working principle diagram institute
Show, under the influence of mixture discontinuously acts on, a certain electrode may be implemented and only exist reducing agent (except non-electronic charged particle)
It functions, and another electrode only exists the state that oxidant (except non-electronic charged particle) functions, or realizes a certain
The high concentration object (except non-electronic charged particle) that electrode only exists reducing agent functions, and another electrode only exists oxidant
The state that functions of high concentration object (except non-electronic charged particle), any state either among these, all favorably
In the efficiency for promoting electrochemical reaction.Certainly as described above, be selectively chosen using external means (such as foreign current,
External electrical field etc.) control electronics export import step, promote the efficiency of electrochemical reaction.Similarly, this electrochemistry is being realized
In the process, it is selectively chosen, the electrochemistry region, external circuit, capacitor and reception and is constituted back for the region of electron
Road and/or the electrochemistry region, external circuit, non-electronic charged particle oscillation area and reception and the region composition for electron
Circuit.
In the present invention, the partial circuit working principle of the electrical return of disclosed device is to utilize non-electronic band electrochondria
Sub reciprocating vibration in the electrolyte, which is realized alternation conducting and/or stood facing each other using non-electronic charged particle with electronics, realizes that alternation is led
It is logical, and then interior circuit and external circuit is made to form closed circuit, realize electrochemical process.
In the present invention, it is work normality that the export of the electronics in the electrochemistry region, which imports,.
In the present invention, so-called " it is work normality that the export of the electronics in the electrochemistry region, which imports, " refers to from the electricity
It is to continue working process that chemical regions, which export electronics and import electronics to the electrochemistry region, i.e., electrification disclosed in this invention
Device is learned in working condition, electronics is exported from the electrochemistry region and imports electronics to the electrochemistry region and held for one kind
The continuous course of work.In other words, corresponding and described electrochemistry region and alternation are electric with alternating current in the electrochemistry region
Stream is opposite to should be the process of continuing working.
In the present invention, disclosed device is that a part of electrochemical appliance is selectively chosen in specific implementation
Using the electrochemistry region as an electrode, using electric conductor as another electrode, two electrode cooperatings complete chemical energy
Electric energy conversion, is also selectively chosen using an electrochemistry region as an electrode, by another electrochemistry
The conversion of chemical energy electric energy is completed as another electrode, two electrode cooperatings in region.
In the present invention, disclosed device is selectively chosen (to be wrapped in electrochemical appliance as half electrochemical appliance
Include the device region of an electrode), it is also selectively chosen and serves as manufacture electrochemical appliance.
In the present invention, when the reducing agent and the oxidant are certain two kinds of predetermined substance, electrochemical reaction is being realized
In the process, having the reaction of the third substance participation cyclicity, (so-called cyclicity reaction, which refers to, generates certain at an electrode
Substance, and the reaction that this substance is consumed at another electrode), such as the reducing agent is methanol, the oxidant is
When oxygen, in acid condition, water is had as the third substance and participates in cyclicity reaction, is i.e. water produces at the electrode for absorbing electronics
It is raw, and be consumed at the electrode of output electronics, and under alkaline condition, hydroxyl, which is had, as the third substance participates in recycling
Property reaction, hydroxyl absorb electronics electrode at generate, output electronics electrode at be consumed.Such as methanol fuel cell
Electrochemical reaction process concrete condition it is as follows:
Overall reaction under alkaline condition: 2CH3OH+3O2+4OH-=2CO3 2-+6H2O
Anode reaction: O2+4e-+2H2O=4OH-
Negative reaction: CH3OH-6e-+8OH-=CO3 2-+6H2O
Overall reaction in acid condition: 2CH3OH+3O2=2CO2+4H2O
Anode reaction: O2+4e-+4H+=2H2O
Negative reaction: CH3OH-6e-+H2O=6H++CO2
For another example the electrochemical reaction process concrete condition of methane fuel cell is as follows:
Overall reaction under alkaline condition: CH4+2O2+2OH-=CO3 2-+3H2O
Anode reaction: 2O2+8e-+4H2O=8OH-
Negative reaction: CH4-8e-+10OH-=CO3 2-+7H2O
Overall reaction in acid condition: CH4+2O2=CO2+2H2O
Anode reaction: 2O2+8e-+8H+=4H2O
Negative reaction: CH4-8e-+2H2O=8H++CO2
In the present invention, according to device disclosed in this invention, substance and the effect in electrode (such as electrochemistry region) are preferential
In electricity and the effect of electrode, this form may be implemented the due electrochemical process of the present invention completely, but reducing agent and oxidation
Agent will appear in many cases to be existed simultaneously at same electrode (when especially with the mixture of reducing agent and oxidant),
If this state is precisely that startup stage or electrode did not had in the period of electro ultrafiltration, at this moment reducing agent and oxidant can be direct
The conversion process between redox reaction forfeiture and electric energy occurs, in order to avoid the generation of this state, alternative selection is pre-
Electro ultrafiltration first is implemented to electrode, and it is so-called " to the region application electro ultrafiltration for participating in electrochemical reaction, so that it is anti-to participate in electrochemistry
The substance answered be difficult to directly carry out redox reaction " purpose be that this.
In the present invention, under certain temperature and/or pressure, so-called electrochemistry region, which is selectively chosen, to be set as not wrapping
The conductive region of catalyst is included, because it is anti-can still to carry out electrochemistry without using catalyst under certain temperature and/or pressure
It answers.
In the present invention, so-called catalytic domain is selectively chosen under certain temperature and/or pressure and is set as not including urging
The region of agent, because high temperature and pressure is also a kind of catalytic process for promoting reaction.
It in the present invention, is selectively chosen and electro ultrafiltration is applied to the electrochemistry region, to realize to the electrochemistry
Reducing agent and oxygen is reduced or avoided prior to the interaction between substance and the electrochemistry region in the electro ultrafiltration in region
Agent directly carries out the case where redox reaction loses output electric energy.
In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through
The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional
Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes
It realizes, however the conducting of the non-electronic charged particle between two electrodes of electrochemical reaction (such as electrochemistry region and electric conductor)
May or may not then exist.
In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity
The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected
Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current
Variation is to realize, however the non-electronic charged particle between two electrodes of electrochemical reaction (such as electrochemistry region and electric conductor)
Conducting may or may not then exist.
In the present invention, it is that the Q generated at P is instigated to be stored in institute that the so-called Q for making the generation at P, which is stored at the P,
The electrode zone represented at P is stated, including the Q to be unnecessarily transmitted to the electrode zone polarity with representative at the P
The process of opposite electrode zone.
In the present invention, in realizing the chemical energy device for converting electric energy, need for certain charged particle to be stored in a certain
It is waited in region and participates in reaction in the next step, it is to instigate to produce at P that the so-called Q for making the generation at P, which is stored at the P,
Raw Q is stored in the electrode zone represented at the P, including being unnecessarily transmitted to the Q and representative at the P
The process of the opposite polarity electrode zone of electrode zone.
In the present invention, the reducing agent used in the electrochemical appliance and oxidant are with the reducing agent and the oxidation
In the presence of the form of the mixture of agent, rubbing with the reducing agent and the oxidant further can be selectively selected
You exist than the form of mixture, or to deposit in the form of the mixture of the explosion limit reducing agent below and the oxidant
, or to exist in the form of the mixture of the local explosion limit reducing agent below and the oxidant, or with pole of exploding
The form of the mixture of above reducing agent of limit and the oxidant exists, or with described in more than local explosion limit also
The form of the mixture of former agent and the oxidant exists.
In the present invention, the mixture of so-called reducing agent and oxidant further can selectively select to be set as reducing agent and
Molar mixture, the explosion limit reducing agent below and the mixture of oxidant, local explosion limit of oxidant are below
It is more than the mixture of more than mixture of reducing agent and oxidant, explosion limit reducing agent and oxidant or local explosion limit
Reducing agent and oxidant mixture.
In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio
Mixture within 10%.
In the present invention, the export of the electronics in the electrochemistry region imports the electronics referred to do not include during being electrically separated
Appearance and accumulation.
In the present invention, the export of the electronics in the electrochemistry region is imported to continue working process.
In the present invention, electrochemistry region state corresponding with alternating electromotive force and alternating current is to continue working
Journey.
The electrochemical appliance disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e. electrochemistry region
It is corresponding with alternating electromotive force and alternating current.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic
Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration
One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted
The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.
In the present invention, in the device between two electrodes (such as electrochemistry region and electric conductor) there are electrolyte, it may be selected
Selecting to property, which makes non-electronic charged particle both, can pass through electrolyte, reach another electrode from an electrode, can also be in electrolyte
Middle reciprocating vibration realizes the effect of alternating current conducting.
In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention,
In the present invention, two kinds of substances due to participating in electrochemical reaction exist with same electrochemistry region to be contacted, and electrochemistry region
Corresponding with alternating electromotive force and alternating current, i.e., the electromotive force in the electrochemistry region in the present invention is alternating electromotive force, is absorbed
And/or the electric current of output electric energy is alternating current, and this is through the lasting sex work normality of whole work process, it is this to hold
Continuous sex work normality eliminates the necessity of non-electronic charged particle transmission between two electrodes, therefore no matter makes to be in electricity between two electrodes
Sub- state of isolation, non-electronic charged particle state of isolation have the shape for the electrolyte that non-electronic charged particle is connected between two electrodes
State is in other states, as long as can be realized the Oscillating flow of electronics, can work normally.There is electricity between two electrodes
In the device for solving matter, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be electrolysed
Reciprocating vibration realizes the effect of alternating current conducting in matter.This provides brand-new approach for the manufacture and use of fuel cell.
In the present invention, the alternation of electric current and substance replace and the effect of the alternation and mixture of substances of electric current is formed by
Alternation process is a kind of lasting course of work, is a kind of work normality, and its purpose is to eliminate non-electronic band
Charged particle two interelectrode transmitting necessity, to promote the science that chemical energy exchanges the electrochemical appliance of electric energy for, in turn
Promote service life, reliability, low cost and the efficiency of electrochemical appliance corresponding with device disclosed in this invention.This electricity
The purpose of principle and purpose of chemical devices and conventional fuel cell are catalyst regeneration is temporary to exchange Oxidizing and Reducing Agents
Feed channel, which forms the principle of temporary electrode change in polarity and purpose, has essential distinction, also and to prevent, weaken and remove
The principle and purpose of the frequently pole-reversing electroosmosis of electrode attachment have essential distinction.
In the present invention, from a certain region export electronic processes duration with to this region import electronic processes duration it
Than between 1/6 and 6, between 1/5 and 5, between 1/4 and 4, between 1/3 and 3, between 1/2.5 and 2.5,1/2
And between 2, between 1/1.5 and 1.5, between 1/1.3 and 1.3, between 1/1.2 and 1.2 or between 1/1.1 and 1.1,
Or it is equal with the duration of electronic processes is imported to this region from the duration of a certain region export electronic processes.
In the present invention, during the export of electronics imports, electro ultrafiltration can be used;Or, the export in electronics imports
During, it is selectively chosen using capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductor wire
Circle, motor, reversible electric machine, has charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit
The motor of additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its
Seven conjunctions, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13
Conjunction, its 14 conjunction, its 15 conjunction.
In the present invention, during exporting electric energy and/or absorbing electric energy, selectively selection uses electro ultrafiltration;Or,
During exporting electric energy and/or absorbing electric energy, selectively selection uses capacitor, DC power supply, AC power source, alternation electricity
Source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit,
Motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five
Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its ten
The conjunction of binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.
In the present invention, the purpose of so-called " during exporting electric energy and/or absorbing electric energy, using electro ultrafiltration " is benefit
The process of output electric energy is controlled or strengthened with electro ultrafiltration and/or absorbs the process of electric energy, in this way can with the efficiency of lifting process and
Safety, such as an electrochemical process may take a long time to complete, but if can be made using electric process
The reaction rate of the slower procedure segment of electrochemical reaction rates is promoted, and then is improved efficiency.
In the present invention, so-called electro ultrafiltration, which refers to, brings it about displacement and/or stream to electronics application using electric field, electric current etc.
Dynamic effect.
In the present invention, it is more big more be conducive to electrochemistry that capacitance is formed by between the electrochemistry region and the electric conductor
The promotion of reaction density, therefore when being electrochemically reacted using device disclosed in this invention, the electrochemical school district should be made
Capacitance between domain and the electric conductor increases as much as possible.
It, can be in the electrochemistry in order to increase the capacitance between the electrochemistry region and the electric conductor in the present invention
Plasma, ionic liquid, ionized gas or solion are set between region and the electric conductor, and make ion in the electricity
It is vibrated between chemical regions and the electric conductor, and/or in electrochemistry areas adjacent oscillation and near the electric conductor
Oscillation, to realize the purpose for increasing the capacitance between the electrochemistry region and the electric conductor.
In the present invention, to realize that specific charged particle is stored in electrochemistry region, need to join the electrochemistry region
Alternate change physical environment or make the electrochemistry region between the different material of electrochemical reaction and participate in electrochemical reaction
The mixture of different material contacts, and is just able to achieve.Fundamentally, as long as the electrochemistry region is made to participate in electrochemical reaction
Different material between alternate change physical environment or make the electrochemistry region and participate in the mixed of the different material of electrochemical reaction
Object contact is closed, can be achieved with the purpose that the specific charged particle is stored in electrochemistry region, no matter the electrochemistry region has
There are two types of the conductive channel of charged particle, (such as one of is proton conductive channel, i.e. there is conducting certain band between two electrodes
The electrolyte of charged particle, another kind be electronic conduction channel) or the electrochemistry region there was only electronic conduction channel, change sentence
It talks about, as long as making the electrochemistry region alternate change physical environment or described between the different material for participating in electrochemical reaction
Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved with the specific charged particle storage
Participate in the purpose that electrochemical reaction is realized in reaction in electrochemistry region and in the next step, no matter two electrodes (such as electrochemistry
Region and electric conductor) between whether there is electrolyte.
In the present invention, in electrochemistry region, tool there are two types of the conductive channel of charged particle, (such as lead for proton by one of which
, i.e. there is the electrolyte that specific charged particle is connected between two electrodes in circulation passage, another kind is electronic conduction channel) electrochemistry dress
In setting, alternate change physical environment or made described between the different material for participating in electrochemical reaction by making the electrochemistry region
Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved to eliminate from the electrochemistry region
The necessity for removing the non-electronic charged particle generated in the electrochemistry region, can also realize that non-electronic charged particle is stored in
The electrochemistry region and the purpose for participating in reaction realization electrochemical reaction in the next step.The alternate change of physical environment or
The electrochemistry region and the mixture for the different material for participating in electrochemical reaction are contacted, can make to be stored in the electrochemical school district
Non-electronic charged particle in domain participates in reacting in the next step, realizes electrochemical process, therefore from the electrochemical school district
The necessity that non-electronic charged particle is exported in domain completely disappears.The case where necessity derived from non-electronic charged particle disappears
Under, although some non-electronic charged particle that ought to be stored in the electrochemistry region is exported, also have non-electronic
Charged particle is stored in the electrochemistry region and waits next reaction step, in other words, if the electrochemistry region
The alternate change physical environment between the different material for participating in electrochemical reaction, or it is mixed with the different material of participation electrochemical reaction
Object contact is closed, although there are electrolyte between two electrodes (such as electrochemistry region and electric conductor), also has non-electronic band electrochondria
Son is stored in the electrochemistry region and participation reaction in the next step is waited to realize electrochemical reaction process.
Electrochemical appliance disclosed in this invention, it is negative there are electrolyte can be reduced in the case where electrolyte between two electrodes
Lotus extends its service life and is conducive to the balance and stability operation of system.
In the present invention, in the device that electrochemistry region only has electronic conduction channel (the i.e. described electrochemistry region with it is described
The interior circuit or external circuit in conductor section are in electronics and non-electronic charged particle state of isolation), the electrochemistry region is being joined
Alternate change physical environment and the electrochemistry region and electrochemical reaction is participated in not between the different material of electrochemical reaction
The mixture of commaterial contacts, and non-electronic charged particle can be made to be stored in the electrochemistry region, the change of physical environment or
Contacting the electrochemistry region with the mixture for the different material for participating in electrochemical reaction can make to be stored in the electrochemical school district
The non-electronic charged particle in domain participates in reaction in the next step and realizes electrochemical process, that is, eliminates and move from electrochemistry region
The necessity of non-electronic charged particle out.Express herein, in conventional electrochemical device, electrochemistry region (i.e. electrode) is at least wrapped
Include two kinds of charged particle conductings, such as an electronic conduction channel, a proton conductive channel.
For electrochemical appliance disclosed in this invention in specific work process, the different step that the export of electronics imports can be with
The case where in the presence of output electric energy and absorbing electric energy, but its summation is output electric energy.
Electrochemical appliance disclosed in this invention self-evidently includes the participation of substance.
Electrochemical appliance disclosed in this invention is in use, oxidant alternative selection is set as: oxygen, compression are empty
Gas, oxygen, liquid oxygen, air, liquefied air, fluorine, chlorine, bromine, iodine, ozone, nitric acid, the concentrated sulfuric acid, hypochlorous acid, chromic acid, Peracetic acid,
Perchloric acid, chlorate, nitrate, permanganate, perchlorate, bichromate, Calcium perchlorate, ammonium perchlorate, sodium perchlorate, height
Potassium chlorate, lithium perchlorate, magnesium perchlorate, barium perchlorate, perchloric acid strontium, silver perchlorate, ammonium chlorate, sodium chlorate, potassium chlorate, chloric acid
Magnesium, calcium chlorate, copper chlorate, zinc chlorate, chloric acid thallium, silver chlorate, potassium permanganate, acerdol, barium permanganate, lithium nitrate, nitric acid
Sodium, potassium nitrate, calcium nitrate, cesium nitrate, beryllium nitrate, potassium bromate, zinc bromate, ammonium periodate, calcium iodate, iron iodate, sodium dichromate,
Potassium bichromate, iron chloride, ammonium ceric nitrate, sodium hypochlorite, SODIUM PERCARBONATE, sodium perborate, calcium hypochlorite, sodium dichloro cyanurate,
Copper oxide, di-iron trioxide, sodium peroxide, manganese dioxide, nitrogen dioxide, potassium peroxide, magnesium dioxide, calcium dioxide, peroxide
Change hydrogen, chromium trioxide, strontium dioxide, sodium dioxide, silver oxide, acetone, acrylonitrile, benzaldehyde, dibenzoyl peroxide, benzene
Quinone, carbon tetrabromide are set as chloramines etc.;Reducing agent alternative selection is set as: hydrogen, alkane, alkene, alkynes, aromatic hydrocarbon,
Halogenated hydrocarbons, alcohol compound, phenolic compound, aldehyde compound, ketone compounds, hydroxyl acid compounds, ester type compound,
Sodium, aluminium, zinc, lithium, potassium, magnesium, manganese, carbon, calcium, barium, vanadium, chromium, iron, cobalt, copper, boron, silicon, phosphorus, tin, mercury, lead, carbon dust, coal dust end,
Sulphur, lithium aluminium hydride reduction, diethyl aluminium hydride sodium, sodium borohydride, potassium borohydride, carbon monoxide, hydrogen sulfide, hydrazine, ammonia, hydrogen chloride,
Hydrogen iodide, sulfur dioxide, hydrogen peroxide, vulcanized sodium, stannous chloride, formaldehyde, sulfurous acid, sulfuric acid, oxalic acid, ethyl alcohol, sodium sulfite,
Sodium hydrogensulfite, ferrous sulfate, methanol, natural gas, coal gas, methane, coke, diesel oil, dimethyl ether, kerosene, gasoline, hydrogen one aoxidize
Carbon mix is set as heavy oil etc..
In the present invention, electrochemical action may be present between the reducing agent and the oxidant.
In the present invention, the reducing agent and the oxidant, can under conditions of electrochemical appliance disclosed in this invention
Electrochemical reaction occurs.
In the present invention, the reducing agent is simple substance, compound or mixture, and ion or solion are not belonging to the reduction
Agent.
In the present invention, the oxidant is simple substance, compound or mixture, and ion or solion are not belonging to the oxidation
Agent.
Electrochemical appliance disclosed in this invention is in the nature chemical energy device for converting electric energy.
It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention
Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field,
Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it
Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11
Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control
The export of system and/or strengthening electronic imports.
It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention
Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field,
Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it
Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11
Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control
The export of system and/or strengthening electronic imports, and control and/or the export of strengthening electronic importing can effectively avoid reducing agent and oxidation
Redox reaction directly occurs for agent mixing, improves safety, reliability and efficiency, and control and/or strengthening electronic are led
Safety, reliability and the effect that can be effectively promoted using reducing agent and oxidant existing device as a mixture are imported out
Rate.
In the present invention, " during electronics exports and/or imports, capacitor, DC power supply, AC power source, alternation are used
Power supply, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillation electricity
Road, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its
Five conjunctions, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction,
The purpose of the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction " be by electro ultrafiltration control and/
Or the export of strengthening electronic imports.A certain step in this control process is power consumption, but whole process is power supply.
Electrochemical appliance of the present invention " is exported and/or is led in electronics when using the mixture of reducing agent and oxidant
During entering, pumped using capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle,
Phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, with additional rotation inertia
Motor or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight
The conjunction of item, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14
Conjunction, its 15 conjunction " purpose be not only to control by electro ultrafiltration and/or the export of strengthening electronic imports, and be logical
The export for crossing strengthening electronic imports the effective means for preventing reducing agent and oxidant from directly carrying out redox reaction.This control
A certain step in the process is power consumption, but whole process is power supply.
In the present invention, " during electronics exports and/or imports, capacitor, DC power supply, AC power source, alternation are used
Power supply, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillation electricity
Road, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its
Five conjunctions, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction,
The purpose of the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction " is not only through electro ultrafiltration control
The export of system and/or strengthening electronic imports, and is to prevent reducing agent and oxidant direct by the export importing of strengthening electronic
Carry out the effective means of redox reaction.A certain step in this control process is power consumption, but whole process is power supply
's.
It in the present invention, further can selectively select that catalyst corresponding with the reducing agent is made to be set as catalyst A, with
It is different that the corresponding catalyst of the oxidant is set as catalyst B, the catalyst A and the catalyst B, in this case,
Catalyst in the electrochemistry region, which is selectively chosen, is set as the random mixed of the catalyst A and catalyst B
Select the catalyst A for being set as contacting near catalytic domain with closing the catalyst choice in object or the electrochemistry region
The band electrochondria between the catalyst A and the catalyst B can be increased with the mixture of the catalyst B in order to improve efficiency
The mobility of son.
In the present invention, the purpose for being inserted into the inert substance is to evade the reducing agent and the oxidant described
Exist while at electrochemistry region, or the reduction reducing agent and the oxidant exist simultaneously at the electrochemistry region
Chance.
In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode
Point.
It, can be according to the operating temperature of the property and the electrochemistry region of the reducing agent and the oxidant in the present invention
Select different catalyst.
In the present invention, Xiang Suoshu electrochemistry region import concentration proportion in the local explosion limit reducing agent below and
The mixture of the oxidant may include fire retardant, such as nitrogen, carbon dioxide etc. are added in the mixture of hydrogen and oxygen.
In the present invention, in the device that the electrochemistry region is under set temperature, the set temperature can be set as high
In equal to 100 DEG C.
In the present invention, in the device that the electrochemistry region is under set temperature, the set temperature can be set as low
In equal to 90 DEG C.
In the present invention, the reducing agent and the oxidant are to refer to that electrochemical reaction occurs in the electrochemistry region
Substance.
In the present invention, in the device for including AC power source, the reaction of the reducing agent and the oxidant can be suction
The reaction for receiving electric energy is also possible to export the reaction of electric energy, but generally exports electric energy.
In the present invention, in the device for including alternating source, the reaction of the reducing agent and the oxidant can be suction
The reaction for receiving electric energy is also possible to export the reaction of electric energy, but generally exports electric energy.
In the present invention, eliminating from the necessity that electrochemistry region removes non-electronic charged particle means only to need to remove electricity
Son, rather than electronics charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next
Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes
Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, in this device, is selectively chosen electricity in it
The conducting on road is that the reciprocating vibration of charged particle in capacitor and/or its internal part by being formed between its internal part is realized
, and using external circuit output electric energy and/or absorb electric energy.
In the present invention, eliminating from the necessity that electrochemistry region removes two kinds of charged particles means only to need to remove electricity
Son, and another charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next
Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes
Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, and in this device, the conducting of interior circuit is to pass through
The reciprocating vibration of charged particle is realized in the capacitor and/or its internal part formed between its internal part, and utilizes dispatch from foreign news agency
Road exports electric energy and/or absorbs electric energy.
In the present invention, the export importing of electronics is a kind of work normality, and the export importing of so-called electronics refers to through external circuit
The export of the electronics carried out imports.
In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electric conductor, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, such as refer to J feed channel for J and K as synonym, J feed channel and the setting of K regional connectivity
Interior substance can contact the structural relation of setting with the region K.
In the present invention, such as using J and K as synonym, the region K is arranged in the cavity, and J feed channel is connected to the cavity
The structural relation for referring to that the substance in J feed channel can contact setting with the region K is set.
In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led
The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit
Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed
Circuit be set as interior circuit.
In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute
The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit
It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non-
Electronic conduction electrical relation is formed by circuit and is set as interior circuit.
In the present invention, the area Jie electricity that so-called " area alternating current Jie electricity " refers to alternating current is selectively chosen and sets
For a part of relative subject, also alternative selection is set as the conduction region contacted with relative subject, is also selectively chosen
It is set as the conduction region that there is capacitance relation with relative subject.It includes that the area alternating current Jie electricity is this that so-called relative subject, which is exactly in A,
A in description.
In the present invention, so-called " area alternating current Jie electricity " refers to for providing alternate electric energy and/or absorbing alternate electric energy
The area Jie electricity.
In the present invention, the electrochemistry region, the electric conductor electronics export import be work normality.
In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become
The changed electromotive force of electromotive force or size of change.
In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction
Stream, the changed electric current of size or alternating current.
In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period,
Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.
In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.
In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.
In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B
Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship;Or, so-called A and B has non-electrical
Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected
Select electronic conduction relationship to property.
In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc.
At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the conductor region
Son conducting electrical relation " include the electrochemistry region and the conductor region through electronic conduction area, insulator, dielectric and/or
The non-electronic conducting electrical relation that two solion ponds of ion conducting body isolation have.In this device, optionally
Selection makes at least one in the electrochemistry region and the conductor region and capacitive region and/or non-electronic charged particle transmitter
Form electrical relation.
In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can
Selectively selection is set as metallic conductor area, carbon conductor region etc..
In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from
The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant
Non-electronic charged particle transmitter is selected, such as when the reducing agent is H2, the oxidant is O2When, the non-electronic electrification
Particle conduction object alternative selects proton exchange membrane.
In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into
Row selection.
In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics
Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed
The electricity conducting relationship etc. that particle reciprocating vibration is formed.
In the present invention, so-called electrochemistry region, so-called electric conductor are equal with electrode.
In the present invention, the region that electronics export imports is equal with electrode.
It in the present invention, is selectively chosen, the electrochemistry region and electric conductor have dielectric capacitance relationship, and electricity is situated between
Matter can be gas, liquid, solid or vacuum.
In the present invention, so-called dielectric capacitance relationship refers to the capacitance relation through dielectric formation, and dielectric can be
Gas, liquid, solid or vacuum.
In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance,
All capacitors such as pseudo capacitance, fake capacitance.
In the present invention, so-called " reversible electric machine " refers to the motor that can mutually convert between motor and generator,
For example, the motor that can be generated electricity when exportable rotary power, rotation when power supply.
In the present invention, it is selectively chosen and uses circumferential magnetic monopole direct current using DC reversible electromotor or selectivity selection
Reversible electric machine.
In the present invention, when the purpose using reversible electric machine is the power supply using reversible electric machine when exportable power reception power
The characteristics of can generating electricity, realizes the reinforcing and control imported to electronics export with electrode cooperating, and then realizes to electrochemistry mistake
The optimization of journey.
It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when the electricity of electrode
When kinetic potential reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, sets when the electromotive force of electrode is reduced to
When determining degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so again and again
Carry out cyclic process;In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy;
It is selectively chosen, control device is set between reversible electric machine and electrode;Be selectively chosen, load with reversible electric machine,
Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.
It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when electrode is in electricity
When electromotive force reaches setting degree under the action of chemical reaction and/or reversible electric machine, electrode is in electrochemical reaction and/or accumulation electricity
It powers under the action of lotus to reversible electric machine and pushes reversible electric machine movement, it is reversible when the electromotive force of electrode is reduced to setting degree
Motor implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so carries out cyclic process again and again;
In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy;Optionally select
It selects, control device is set between reversible electric machine and electrode;It being selectively chosen, load is arranged in series with reversible electric machine, electrode,
Or load is arranged in parallel with reversible electric machine.
It in the present invention, is selectively chosen, makes electrode move reversible electric machine reversible electric machine power supply, when the electricity of electrode
When kinetic potential is reduced to setting degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, when
When the electromotive force of electrode reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, so again and again
Carry out cyclic process;In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy;
It is selectively chosen, control device is set between reversible electric machine and electrode;Be selectively chosen, load with reversible electric machine,
Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.
It in the present invention, is selectively chosen, makes electrode under the action of electrochemical reaction and/or stored charge to reversible
Motor power supply moves reversible electric machine, and when the electromotive force of electrode is reduced to setting degree, reversible electric machine utilizes itself and its connection
The kinetic energy power generation of moving part to electrode implement electro ultrafiltration, when electrode under the action of electrochemical reaction and/or reversible electric machine electromotive force
When reaching setting degree, electrode pushes reversible electricity to reversible electric machine power supply under the action of electrochemical reaction and/or stored charge
Machine movement, so carries out cyclic process again and again;In circulation, there is the process for providing electric energy and absorbing electric energy in electrode, but
Circulation is whole to be to provide electric energy;It is selectively chosen, control device is set between reversible electric machine and electrode;Optionally
Selection, load are arranged in series with reversible electric machine, electrode, or load is arranged in parallel with reversible electric machine.
In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific
The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC
Film and solid oxide electrolyte etc..
In the present invention, so-called " being inserted into inert substance between the reducing agent and the oxidant " refers to goes back described
Former agent is contacted with electrochemistry region and the oxidant contacted with this electrochemistry region between make inert substance and this electrochemical school district
Domain contact, the purpose is to keep the boundary between the electrochemical reaction of the reducing agent and the electrochemical reaction of the oxidant more clear
It is clear.
In the present invention, so-called " dead band duration is inserted between the reducing agent and the oxidant " refers to goes back described
Former agent is contacted with electrochemistry region and the oxidant contacted with this electrochemistry region between be arranged dead band duration, the purpose is to keep away
Exempt from the reducing agent and oxidant mixing, makes the electrochemical process of the reducing agent and the electrochemical process of the oxidant
Between boundary it is apparent, so-called dead band duration refers to the time interval of setting, and specific duration is according to the reducing agent and institute
State the property of oxidant, the temperature in electrochemistry region and catalyst whether there is or not and stopping of needing of the reducing agent and the oxidant
Time etc. is stayed to determine.
In the present invention, so-called " inert substance " refers to the object not reacted with the reducing agent and the oxidant
Matter.
In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including
Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature, then for example in setting temperature
Metallic region under degree.
It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention
The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification
School district domain includes two or three in these three conditions.
In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition
Structure.
In the present invention, so-called " local explosion limit " refers under conditions of the electrochemistry region, the reducing agent
The concentration ratio that cannot be exploded with the oxidant.
In the present invention, include the catalyst device in, the catalyst be set as include noble metal catalyst, or
The catalyst be set as include rare earth element catalyst.
In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode
Substance (including vacuum), for example, electrolyte, dielectric etc..
In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.
In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets
For external circuit.
In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.
In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.
In the present invention, so-called " motor with additional rotation inertia " refers to the requirement with basis to rotary inertia,
The motor of additional setting rotary inertia.
In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several
The identical component of title.
In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field
Part, unit or system etc..
Beneficial effects of the present invention are as follows: electrochemical appliance disclosed in this invention will termination traditional chemical energy electric energy conversion
Electrochemical appliance with the history for existing for necessary condition of electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.),
This kind of device that terminates also can not securely and reliably be used to the history of oxidant reduction agent composition, for efficient, long-life, low cost
The industrialization of chemical energy electric energy conversion electrochemical appliance provide new approach, and engine will be redefined.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the embodiment of the present invention 1;
Fig. 2 is the structural schematic diagram of the embodiment of the present invention 2;
Fig. 3 is the structural schematic diagram of the embodiment of the present invention 3;
Fig. 4 is the structural schematic diagram of the embodiment of the present invention 4;
Fig. 5 is the structural schematic diagram of the embodiment of the present invention 5;
Fig. 6 is the structural schematic diagram of the embodiment of the present invention 6;
Fig. 7 is the structural schematic diagram of the embodiment of the present invention 7;
Fig. 8 is the structural schematic diagram of the embodiment of the present invention 8;
Fig. 9 is the structural schematic diagram of the embodiment of the present invention 9;
Figure 100-1 is the schematic diagram of the embodiment of the present invention 10;
Figure 100-2 is the schematic diagram of the embodiment of the present invention 11;
Figure 100-3 is the schematic diagram of the embodiment of the present invention 12;
Figure 100-4 is the schematic diagram of the embodiment of the present invention 13;
Figure 100-5 is the schematic diagram of the embodiment of the present invention 14;
Figure 100-6 is the schematic diagram of the embodiment of the present invention 15;
Figure 100-7 is the schematic diagram of the embodiment of the present invention 16;
Figure 200-1 is the schematic diagram of the embodiment of the present invention 17;
Figure 200-2 is the schematic diagram of the embodiment of the present invention 18;
Figure 200-3 is the schematic diagram of the embodiment of the present invention 19;
Figure 200-4 is the schematic diagram of the embodiment of the present invention 20;
Figure 200-5 is the schematic diagram of the embodiment of the present invention 21;
Figure 200-6 is the schematic diagram of the embodiment of the present invention 22;
Figure 200-7 is the schematic diagram of the embodiment of the present invention 23;
Scheming X-1 is the basic logic chart for exchanging electric energy for chemical energy;
Figure X-2 is reducing agent oxidant electrochemical reaction controlled process figure;
In figure:
1 electrochemistry region, 3 reducing agent feed channels, 4 oxidant feed channels, 5 cavitys, 6 reducing agent control switches, 7 oxygen
Agent control switch, 8 mixture feed channels, 9 mixture control switches, 10 control devices.
Specific embodiment
Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.
Embodiment 1
Electrochemical appliance as shown in Figure 1, including electrochemistry region 1, the electrochemistry region 1 and reducing agent feed channel
3 connection settings, the electrochemistry region 1 are connected to setting with oxidant feed channel 4, and the electrochemistry region 1 includes alternation electricity
The area Liu Jie electricity, it is work normality that the export of the electronics in the electrochemistry region 1, which imports,.
As can embodiment in conversion, optionally make the mistake of 3 feed reducing agent of reducing agent feed channel
The process of 4 feed oxidant of journey and oxidant feed channel is alternately.
As can embodiment in conversion, optionally make the mistake of 3 feed reducing agent of reducing agent feed channel
There is overlapping in the process of 4 feed oxidant of journey and oxidant feed channel.
As can embodiment in conversion, optionally make the interrupted feed reducing agent in reducing agent feed channel 3
The interrupted feed oxidant of feed process and oxidant feed channel 4 feed process exist overlapping.
Embodiment 2
Electrochemical appliance as shown in Figure 2, including electrochemistry region 1, the electrochemistry region 1 are arranged in cavity 5, institute
It states cavity 5 and is connected to setting with reducing agent feed channel 3, the cavity 5 is connected to setting, the electrification with oxidant feed channel 4
School district domain 1 includes the area alternating current Jie electricity, and it is work normality that the export of the electronics in the electrochemistry region 1, which imports,.
As can embodiment in conversion, optionally make the mistake of 3 feed reducing agent of reducing agent feed channel
The process of 4 feed oxidant of journey and oxidant feed channel is alternately.
As can embodiment in conversion, optionally make the mistake of 3 feed reducing agent of reducing agent feed channel
There is overlapping in the process of 4 feed oxidant of journey and oxidant feed channel.
As can embodiment in conversion, optionally make the interrupted feed reducing agent in reducing agent feed channel 3
The interrupted feed oxidant of feed process and oxidant feed channel 4 feed process exist overlapping.
Embodiment 3
Electrochemical appliance as shown in Figure 3, including electrochemistry region 1, the electrochemistry region 1 is through reducing agent control switch
6 are connected to setting with reducing agent feed channel 3, and the electrochemistry region 1 is through oxidant control switch 7 and oxidant feed channel 4
Connection setting, the electrochemistry region 1 include the area alternating current Jie electricity, and the export importing of the electronics in the electrochemistry region 1 is
Work normality;
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 by control device controlled realize 3 feed reducing agent of reducing agent feed channel process and
The process of 4 feed oxidant of oxidant feed channel is alternately.
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 by control device controlled realize 3 feed reducing agent of reducing agent feed channel process and
There is overlapping in the process of 4 feed oxidant of oxidant feed channel.
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 is controlled the confession for realizing the interrupted feed reducing agent in reducing agent feed channel 3 by control device
There is overlapping in the feed process for passing through the interrupted feed oxidant of journey and oxidant feed channel 4.
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 is controlled by control device and realizes that reducing agent feed channel 3 is opened and the oxidant supplies
It send channel 4 discontinuously to open, or controls the reducing agent control switch 6 and the oxidant control by control device
System switch 7 is controlled by control device realizes that oxidant feed channel 4 is opened and reducing agent feed channel 3 is discontinuously opened
It opens.
As can embodiment in conversion, set the oxidant control switch 7 not, and make institute
It states reducing agent control switch 6 and is controlled the discontinuously unlatching of realization reducing agent feed channel 3 by control device.
As can embodiment in conversion, set the reducing agent control switch 6 not, and make institute
It states oxidant control switch 7 and is controlled the discontinuously unlatching of realization oxidant feed channel 4 by control device.
Embodiment 4
Electrochemical appliance as shown in Figure 4, including electrochemistry region 1, the electrochemistry region 1 are arranged in cavity 5, institute
It states cavity 5 and is connected to setting with reducing agent feed channel 3 through reducing agent control switch 6, the cavity 5 is through oxidant control switch 7
Setting is connected to oxidant feed channel 4, the electrochemistry region 1 includes the area alternating current Jie electricity, the electrochemistry region 1
It is work normality that the export of electronics, which imports,;
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 by control device controlled realize 3 feed reducing agent of reducing agent feed channel process and
The process of 4 feed oxidant of oxidant feed channel is alternately.
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 by control device controlled realize 3 feed reducing agent of reducing agent feed channel process and
There is overlapping in the process of 4 feed oxidant of oxidant feed channel.
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 is controlled the confession for realizing the interrupted feed reducing agent in reducing agent feed channel 3 by control device
There is overlapping in the feed process for passing through the interrupted feed oxidant of journey and oxidant feed channel 4.
As can embodiment in conversion, control the reducing agent control switch 6 by control device
And the oxidant control switch 7 is controlled by control device and realizes the unlatching of reducing agent control switch 6 and the oxidant control
System switch 7 discontinuously opens or realizes that the reducing agent control switch 6 is discontinuously opened and the oxidant control switch 7 is opened.
As can embodiment in conversion, set the reducing agent control switch 6 not, and make institute
It states oxidant control switch 7 and is controlled realization discontinuously unlatching by control device.
As can embodiment in conversion, set the oxidant control switch 7 not, and make institute
It states reducing agent control switch 6 and is controlled realization discontinuously unlatching by control device.
Embodiment 5
Electrochemical appliance as shown in Figure 5, including electrochemistry region 1, the electrochemistry region 1 and reducing agent and oxidant
Mixture feed channel 8 be connected to setting, the electrochemistry region 1 include the area alternating current Jie electricity, the electrochemistry region 1
It is work normality that the export of electronics, which imports,.
As can embodiment in conversion, optionally make 8 continuous feeding mixture of mixture feed channel.
As can embodiment in conversion, optionally make the interrupted feed mixture in mixture feed channel 8.
Embodiment 6
Electrochemical appliance as shown in FIG. 6, including electrochemistry region 1, the electrochemistry region 1 are arranged in cavity 5, institute
It states cavity 5 and is connected to setting with the mixture feed channel 8 of reducing agent and oxidant, the electrochemistry region 1 includes alternating current
The area Jie electricity, it is work normality that the export of the electronics in the electrochemistry region 1, which imports,.
As can embodiment in conversion, optionally make 8 continuous feeding mixture of mixture feed channel.
As can embodiment in conversion, optionally make the interrupted feed mixture in mixture feed channel 8.
Embodiment 7
Electrochemical appliance as shown in Figure 7, including electrochemistry region 1, the electrochemistry region 1 is through mixture control switch
9 are connected to setting with the mixture feed channel 8 of reducing agent and oxidant, and the electrochemistry region 1 includes the area alternating current Jie electricity,
It is work normality that the export of the electronics in the electrochemistry region 1, which imports,.
As can embodiment in conversion, control the mixture control switch 9 by control device 10
System realizes 8 continuous feeding mixture of mixture feed channel.
As can embodiment in conversion, control the mixture control switch 9 by control device 10
System realizes the interrupted feed mixture in mixture feed channel 8.
Embodiment 8
Electrochemical appliance as shown in Figure 8, including electrochemistry region 1, the electrochemistry region 1 are arranged in cavity 5, institute
It states cavity 5 and is connected to setting, the electrochemistry with the mixture feed channel 8 of reducing agent and oxidant through mixture control switch 9
Region 1 includes the area alternating current Jie electricity, and it is work normality that the export of the electronics in the electrochemistry region 1, which imports,.
Embodiment 9
Electrochemical appliance as shown in Figure 9 further makes the mixture control switch 9 on the basis of embodiment 8
It is controlled by control device 10 and realizes 8 continuous feeding mixture of mixture feed channel.
As can embodiment in conversion, also optionally make the mixture control switch 9 by control device 10
The interrupted feed mixture in mixture feed channel 8 is realized in control.
As disposable embodiment, above-mentioned all embodiments of the invention and its disposable embodiment can be into one
Step selectively selects to be arranged by the electrochemistry region 1 with the setting of power supply electric communication or by the electrochemistry region 1 in electricity
In;Or selectively select, the electrochemistry region 1 is led with capacitor, DC power supply, AC power source, alternating source, inductance
It is body, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible
Motor, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six
The conjunction of item, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial,
Its 13 conjunction, its 14 conjunction, the effect setting of its 15 conjunction electricity.
As disposable embodiment, above-mentioned all embodiments of the invention and its disposable embodiment can be into one
Selectively selection makes the electrochemistry region 1 through the dielectric or electrolyte and electric conductor tool on the electrochemistry region 1 to step
There is non-electronic conducting electrical relation, or, making the electrochemistry region 1 through the dielectric or electrolyte and the conduction on electric conductor
Body have non-electronic conducting electrical relation, or, make the electrochemistry region 1 through on electric conductor A dielectric or electrolyte with lead
Electric body has non-electronic conducting electrical relation, or, make dielectric on a face of the electrochemistry region 1 through electric conductor A or
Dielectric or electrolyte and electric conductor on another face of electrolyte again through the electric conductor A are closed with non-electronic conducting electricity
System.
As disposable embodiment, above-mentioned all embodiments of the invention and its disposable embodiment can be into one
Step, which selectively selects to rotate in the electrochemistry region 1, to be arranged.
As disposable embodiment, above-mentioned all embodiments of the invention and its disposable embodiment can be into one
Step selectively selects to be inserted into inert substance and/or dead band duration between the reducing agent and the oxidant.
It is disclosed in this invention only electrochemistry region electrochemical appliance in the specific implementation, be selectively chosen by
Electrochemistry region makes two electrode cooperatings complete chemical energy electric energy as an electrode using electric conductor as another electrode
Conversion;It is also selectively chosen using electrochemistry region as an electrode, using another electrochemistry region as another electricity
Pole, two electrode cooperatings complete the conversion of chemical energy electric energy.
Embodiment 10
Figure 100-1 is under unitary electrode (such as electrochemistry region 1 in the present invention), and substance A and substance B replace with electrode
The process chart of contact, electrochemical appliance of the invention is selectively chosen to work according to following courses of work.
In Figure 100-1,1a is electrode, A representative species A (reducing agent), B representative species B (oxidant).When substance A and electricity
When pole contacts (1. shown process in figure), the electronics of substance A is exported forming material A cation A under electro ultrafiltration+It (restores
Agent cation A+), as the reducing agent cation A+When running up to setting degree (amount of accumulation depend on electro ultrafiltration intensity and
Electrical relation possessed by electrode), substance A and substance B switching (as in figure 3. and 4. shown in process), and it is negative to pass through electronics
It carries 5a and imported into electrode, substance B, substance A cation A at electrode+Substance A and substance B redox are generated with electron reaction
The product C (5. shown in such as figure) of reaction.Next two-way can be divided to continue, is as 5. passed through in figure all the wayTo 1.
It is shown, apply the electro ultrafiltration in direction same as described above again, and switch substance A and substance B again, and then realize and follow in cycles
Ring work;Another way is as 5. passed through in figureShown in 7., apply the electro ultrafiltration in direction contrary to the above, and continue to make substance B
Contacted with electrode, so so that substance B and electronics is coexisted in electrode (substance B can receive that electronically form substance B negative in some cases
Ion B-or oxidant anion B-, does not show in figure), when electronics or oxidant anion B-run up to setting degree
When (in such as figure 9. shown in), switching substance A and substance B and make electronics through load 5a from electrode export (such as figure 10. andIt is shown),
Reducing agent cation, electronics and oxidant react herein generates C (in such as figureIt is shown), reversed electricity next is implemented to electrode
Act on and continue to make substance A contacted with electrode reach in figure 1. shown in state, and then realize cycle operation in cycles.This figure
Shown in principle and process be unitary electrode the course of work.The purpose of electro ultrafiltration is that control is made with electrochemical reaction, electricity is strengthened
With can come from external power supply, the chemical potential in electrochemical reaction can come from, can be from the electric energy by storing process
(for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not
Have and lost, and be stored at electrode, is released together when electric current is reversed.
Embodiment 11
Figure 100-2 is H under unitary electrode (such as electrochemistry region 1 in the present invention)2And O2It alternates and contacts with electrode
Process chart, electrochemical appliance of the invention optionally according to the course of work work.
In Figure 100-2,1a is electrode.The principle and process that this figure illustrates are identical as Figure 100-1, only in Figure 100-1
Reducing agent substance A is with H2To represent, oxidant species B is with O2To represent, reducing agent cation A+It is then H+.Original shown in this figure
Reason and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is that control can come with electrochemical reaction, electro ultrafiltration is strengthened
From external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process electric energy (for example, through
The electric energy of capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but there is no damaged the electric energy consumed during electro ultrafiltration
It loses, and is stored at electrode, released together when electric current is reversed.
Embodiment 12
Figure 100-3 is CH under unitary electrode (such as electrochemistry region 1 in the present invention)3OH and O2It is alternateed with electrode
The process chart of contact, electrochemical appliance of the invention optionally work according to the course of work.
In Figure 100-3,1a is electrode.The principle and process that this figure illustrates are identical as Figure 100-1, only in Figure 100-1
Reducing agent substance A is with CH3OH is representative, and oxidant species B is with O2To represent.Furthermore compared with Figure 100-1, shown in Figure 100-3
Principle and H in the process2O takes part in electrochemical reaction process as recycled material.Principle shown in this figure and process are single
The course of work of electrode.The purpose of electro ultrafiltration is control and strengthen electrochemical reaction, and electro ultrafiltration can come from external power supply, can be with
Chemical potential in electrochemical reaction can be from the electric energy by storing process (for example, through capacitor or oscillating circuit
Electric energy) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electricity
At pole, released together when electric current is reversed.
Embodiment 13
Figure 100-4 is under unitary electrode (such as the present invention in electrochemistry region 1), the mixture of substance A and substance B with
The process chart that electrode contacts with each other, electrochemical appliance of the invention optionally work according to the course of work.
In Figure 100-4,1a is electrode, A representative species A (reducing agent), B representative species B (oxidant).When substance A and object
When the mixture and electrode of matter B contact (1. shown process in figure), the electronics of the substance A under electro ultrafiltration in mixture is exported
Forming material A cation A+(i.e. reducing agent cation A+), as the reducing agent cation A+(accumulation when running up to setting degree
Amount depend on electro ultrafiltration intensity and electrode possessed by electrical relation), make electronics by load 5a imported into electrode, in electricity
Substance B, substance A cation A at pole+With the product C of electron reaction generation substance A and substance B redox reaction (in such as figure
Shown in 4.).Next two-way can be divided to continue, is as, 5. to shown in 1., applied side same as described above again in figure all the way
To electro ultrafiltration, that is, reach in figure 1. shown in state, and then realize cycle operation in cycles;Another way be as in figure 5. to 6.
It is shown, apply the electro ultrafiltration in direction contrary to the above, and then make substance B forming material B anion B—That is oxidant anion B—
(in some cases may forming material A, substance B and electronics coexist in the situation of electrode, do not shown in figure), work as oxidant
Anion B—Or electron accumulation to setting degree when (in such as figure 8. shown in), make electronics through load 5a from electrode export (9. such as figure
It is shown) form reducing agent cation A+, it is formed by reducing agent cation A+, oxidant (substance B) and electronics or reducing agent just from
Sub- A+With oxidant anion B—Reaction generates C (also as 9. shown in figure), next implements reversed electro ultrafiltration to electrode and reaches
In figure 1. shown in state, and then realize cycle operation in cycles.Although existing always at electrode during shown in Figure 100-4
There is reducing agent and oxidant always in substance A and substance B, but due to electro ultrafiltration there are reducing agents and oxidant can not be straight
Row redox reaction is tapped into, and then avoids or weakens mixture and directly carry out redox reaction forfeiture power supply at electrode
The process of ability.Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is control and strengthens
Electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by
Electric energy (for example, electric energy through capacitor or oscillating circuit) of storing process etc..Electro ultrafiltration consumes electric energy, but during electro ultrafiltration
The electric energy of consumption is not lost, and is stored at electrode, is released together when electric current is reversed.
Embodiment 14
Figure 100-5 is the mixture and electricity of substance A and substance B under unitary electrode (such as electrochemistry region 1 in the present invention)
The process chart of extremely mutual makes discontinuous contact, electrochemical appliance of the invention optionally work according to the course of work.
In Figure 100-5,1a is electrode, A representative species A (reducing agent), B representative species B (oxidant).Except substance A and object
Outside the mixture of matter B and the influence of the mutual makes discontinuous contact of electrode, shown in principle shown in Figure 100-5 and process and Figure 100-4
It is identical, the purpose of mixture and electrode makes discontinuous contact be in order to reduce at electrode the mixture of substance A and substance B i.e. reducing agent and
Time existing for the mixture of oxidant, to realize the better control to electrochemical process.In such as figure 3., 4., 5. process
It is shown, it contacts with each other and is formed by circulation discontinuously, there is considerable time intervals to only exist a kind of substance i.e. at electrode
It only exists reducing agent or only exists oxidant (substance B and electronics are regarded as substance B anion B when coexisting—Rather than substance
B).Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is that control and reinforcing electrochemistry are anti-
It answers, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process
Electric energy (for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electricity consumed during electro ultrafiltration
It can not be lost, and be stored at electrode, be released together when electric current is reversed.
Embodiment 15
Figure 100-6 is H under unitary electrode (such as electrochemistry region 1 in the present invention)2And O2Mixture and electrode phase
The process chart mutually contacted, electrochemical appliance of the invention optionally work according to the course of work.
In Figure 100-6,1a is electrode.Principle and process shown in Figure 100-6 are identical as Figure 100-4, only in Figure 100-4
Substance A with H2To represent, substance B is with O2To represent.Principle shown in this figure and process are the course of work of unitary electrode.Electricity
The purpose of effect is that control can come from external power supply, can come from electrochemical reaction with electrochemical reaction, electro ultrafiltration is strengthened
Chemical potential, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration disappears
Consuming electric power, but the electric energy consumed during electro ultrafiltration is not lost, and be stored at electrode, when electric current is reversed
It releases together.
Embodiment 16
Figure 100-7 is CH under unitary electrode (such as electrochemistry region 1 in the present invention)3OH and O2Mixture and electrode
The process chart to contact with each other, electrochemical appliance of the invention optionally work according to the course of work.
In Figure 100-7,1a is electrode.Principle and process shown in Figure 100-7 are identical as Figure 100-4, only in Figure 100-4
Substance A with CH3OH is representative, and substance B is with O2To represent.In addition to this, compared with principle and process shown in Figure 100-4, such as
Water shown in scheming takes part in electrochemical reaction as recycled material.Principle shown in this figure and process are the worked of unitary electrode
Journey.The purpose of electro ultrafiltration is that control can come from external power supply, it is anti-to can come from electrochemistry with electrochemical reaction, electro ultrafiltration is strengthened
Chemical potential in answering can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electricity is made
With consumption electric energy, but the electric energy consumed during electro ultrafiltration is being lost, and is stored at electrode, anti-to electric current
To when release together.
Embodiment 17
Figure 200-1 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, the process chart that substance A and substance B are alternately contacted with electrode, electrochemical appliance of the present invention is optionally
Selection works according to following courses of work.
In Figure 200-1,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and A representative species A (reducing agent), B are represented
Substance B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Work as substance A
When contacting with electrode 1a (1. shown process in figure), the electronics of substance A is exported to electric conductor 2a and then makes object under electro ultrafiltration
Matter A forming material A cation A+(i.e. reducing agent cation A+), as the reducing agent cation A+(product when running up to setting degree
Tired amount depend on electro ultrafiltration intensity and electrode possessed by electrical relation), substance A and substance B switching are (in such as figure 3. and 4.
Shown in process), and electronics is made from electric conductor to imported into electrode by load 5a, substance B, substance A cation A at electrode+
The product C (in such as figure 5. shown in) of substance A and substance B redox reaction is generated with electron reaction.Next it can be divided to two
Road continues, and is as 5. passed through in figure all the wayShown in 1., apply the electro ultrafiltration in direction same as described above again, and again
Switch substance A and substance B, and then realizes cycle operation in cycles;Another way is as 5. passed through in figureShown in 7., apply
The electro ultrafiltration in direction contrary to the above, and continue to contact substance B with electrode, so make substance B and electronics coexist in electrode (
Substance B, which can receive, in some cases electronically forms substance B anion B-or oxidant anion B-, does not show in figure),
When electronics or oxidant anion B-run up to setting degree (9. shown in such as figure), switches substance A and substance B and make electricity
Son through load 5a from electrode export to electric conductor (in such as figure 10. andIt is shown), reducing agent cation, electronics and oxidant are in institute
It states reaction at electrode 1a and generates C (in such as figureIt is shown), next to electrode implement reversed electro ultrafiltration and continuing make substance A with
Electrode contact reach in figure 1. shown in state, and then realize cycle operation in cycles.Principle shown in this figure and process are
Including having the course of work of the electrode of electrical relation and electric conductor through interpolar spacer.The purpose of electro ultrafiltration is control and strengthens
Electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by
Electric energy (for example, electric energy through capacitor or oscillating circuit) of storing process etc..Electro ultrafiltration consumes electric energy, but during electro ultrafiltration
The electric energy of consumption is not lost, and is stored at electrode, is released together when electric current is reversed.
Embodiment 18
Figure 200-2 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, H2And O2The process chart of contact is alternateed with electrode, electrochemical appliance of the present invention is selectively chosen
It works according to following courses of work.
In Figure 200-2,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and wherein electric conductor is exported in electrodic electron
Play the role of another electrode in importing process.Except the substance A (reducing agent) in Figure 200-1 is with H2To represent, substance B (oxygen
Agent) with O2Outer to represent, principle and the course of work shown in Figure 200-2 are identical as principle shown in Figure 200-1 and process.Electricity
The purpose of effect is that control can come from external power supply, can come from electrochemical reaction with electrochemical reaction, electro ultrafiltration is strengthened
Chemical potential, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration disappears
Consuming electric power, but the electric energy consumed during electro ultrafiltration is not lost, and be stored at electrode, when electric current is reversed
It releases together.
Embodiment 19
Figure 200-3 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, CH3OH and O2The process chart of contact is alternateed with electrode, electrochemical appliance of the present invention is optionally
Selection works according to following courses of work.
In Figure 200-3,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and wherein electric conductor is exported in electrodic electron
Play the role of another electrode in importing process.Except the substance A (reducing agent) in Figure 200-1 is with CH3OH is representative, substance B
(oxidant) is with O2To represent, H2O is participated in outside reaction as recycled material, principle and the course of work shown in Figure 200-3 and figure
Principle shown in 200-1 is identical with process.The purpose of electro ultrafiltration is that control can come from outer with electrochemical reaction, electro ultrafiltration is strengthened
Portion's power supply can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor
Or the electric energy of oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and
It is stored at electrode, is released together when electric current is reversed.
Embodiment 20
Figure 200-4 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, the process chart that the mixture and electrode of substance A and substance B contact with each other, electrochemical appliance of the present invention can
It selectively selects to work according to following courses of work.
In Figure 200-4,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and A representative species A (reducing agent), B are represented
Substance B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Work as substance A
(1. shown process in figure), the electronics quilt of the substance A under electro ultrafiltration in mixture when being contacted with the mixture and electrode of substance B
It exports to electric conductor 2a and then makes substance A forming material A cation A+(i.e. reducing agent cation A+), when the reducing agent just from
Sub- A+When running up to setting degree (electrical relation possessed by intensity and electrode of the amount of accumulation depending on electro ultrafiltration), make electronics
It is imported into electrode from electric conductor through load 5a, substance B, substance A cation A at electrode+Substance A and object are generated with electron reaction
The product C (4. shown in such as figure) of matter B redox reaction.Next two-way can be divided to continue, is as in figure all the way
5. applying the electro ultrafiltration in direction same as described above again shown in 1., that is, reach 1. shown state, and then realization Zhou Erfu in figure
Beginning cycle operation;Another way is as, 5. to shown in 6., applied the electro ultrafiltration in direction contrary to the above, and then make substance B shape in figure
At substance B anion B—That is oxidant anion B—(in some cases may forming material A, substance B and electronics coexist in
The situation of electrode is not shown in figure), as oxidant anion B—Or electron accumulation to setting degree when (in such as figure 8. shown in),
So that electronics is exported to electric conductor (in such as figure 9. shown in) from electrode through load 5a and forms reducing agent cation A+, it is formed by reduction
Agent cation A+, oxidant (substance B) and electronics or reducing agent cation A+With oxidant anion B—Reaction generates C (also as schemed
In 9. shown in), next to electrode implement reversed electro ultrafiltration reach in figure 1. shown in state, and then realize and recycle in cycles
Work.Although there is substance A always at electrode during shown in Figure 200-4 and substance B have reducing agent and oxidation always
Agent, but since the presence of electro ultrafiltration, reducing agent and oxidant can not directly carry out redox reaction, and then avoid or weaken
Mixture directly carries out the process that redox reaction loses power supply capacity at electrode.The purpose of electro ultrafiltration be control with it is strong
Change electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from through
Cross the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. of storing process.Electro ultrafiltration consumes electric energy, but in electro ultrafiltration process
The electric energy of middle consumption is not lost, and is stored at electrode, is released together when electric current is reversed.
Embodiment 21
Figure 200-5 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, the mixture of substance A and substance B and the process chart of the mutual makes discontinuous contact of electrode, electrochemistry dress of the present invention
It sets to be selectively chosen and work according to following courses of work.
In Figure 200-5,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and A representative species A (reducing agent), B are represented
Substance B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Except substance A
Outside the mixture of substance B and the influence of the mutual makes discontinuous contact of electrode, principle and the course of work shown in Figure 200-5 and Figure 200-
Principle shown in 4 is identical with process.The purpose of mixture and electrode makes discontinuous contact is that reduction reducing agent and oxidant mixture are deposited
Duration, improve safety, controllability and reliability.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, electro ultrafiltration
It can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from the electric energy (example by storing process
Such as, the electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not
It is lost, and is stored at electrode, released together when electric current is reversed.
Embodiment 22
Figure 200-6 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, H2And O2Mixture and the process chart that contacts with each other of electrode, electrochemical appliance of the present invention is optionally
Selection works according to following courses of work.
In Figure 200-6,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and wherein electric conductor is exported in electrodic electron
Play the role of another electrode in importing process.Except substance A (reducing agent) is with H2To represent, substance B (oxidant) is with O2For generation
Off-balancesheet, principle and the course of work shown in Figure 200-6 are identical as principle shown in Figure 200-4 and process.Electro ultrafiltration can come from
External power supply can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through electricity
The perhaps electric energy of oscillating circuit) etc..The purpose of electro ultrafiltration is to control and strengthen electrochemical reaction, electro ultrafiltration consumption electric energy, but
The electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, is released together when electric current is reversed.
Embodiment 23
Figure 200-7 show including electrode (such as the present invention in electrochemistry region 1) and corresponding with this electrode leads
Electric body, CH3OH and O2Mixture and the process chart that contacts with each other of electrode, electrochemical appliance of the present invention may be selected
Property select according to following courses of work work.
In Figure 200-7,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, and wherein electric conductor is exported in electrodic electron
Play the role of another electrode in importing process.Except substance A (reducing agent) is with CH3OH is representative, and substance B (oxidant) is with O2
Outer, the H to represent2It is outer that O as recycled material participates in reaction, shown in principle and the course of work shown in Figure 200-7 and Figure 200-4
Principle is identical with process.The purpose of electro ultrafiltration is control and strengthen electrochemical reaction, and electro ultrafiltration can come from external power supply, can be with
Chemical potential in electrochemical reaction can be from the electric energy by storing process (for example, through capacitor or oscillating circuit
Electric energy) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electricity
At pole, released together when electric current is reversed.
The principle of the electrochemical appliance of the invention is described as follows:
Scheming X-1 is the basic logic chart for exchanging electric energy for chemical energy.All are that with the process that chemical energy exchanges electric energy for
Electronics is exported from reducing agent, so that reducing agent is formed reducing agent cation, electronics is then imported into reducing agent cation and oxygen again
In the coexisting body of agent, and then realize that reducing agent cation, oxidant and electronics three react generation reducing agent and oxidant is anti-
The product that should be generated, the summation that the electronics export during this imports is to export the process of electric energy.Figure X-1 is using hydrogen as also
The diagram that the representative of former agent, the representative using oxygen as oxidant carry out this basic logic.
Figure X-2 is reducing agent oxidant electrochemical reaction controlled process figure.Reducing agent and oxidant at electrode (such as this
Electrochemistry region 1 in invention) reaction that could occur, the electrochemical reaction of electric energy can be either exported, it still cannot be defeated
The direct oxidation reduction reaction of the reducing agent of electric energy and oxidant, essence out are all reducing agent, oxidant and electrode effect three
The indispensable reaction of person, and electrode to the effect of chemical reaction is realized by electro ultrafiltration.It means that by changing electricity
The electrical property (or electriferous state) of pole can control this kind of reaction.For example, if electrode is made to have electronegativity (i.e. affine
The ability of electronics is reinforced, or the ability of the affine electronics electronically formed by export), so that it may so that reducing agent is being formed reducing agent just
Ion process occurs and can be with Accelerating reduction dosage form at the process of reducing agent cation, if making electrode that there is electropositivity (to release
The ability of electric discharge is reinforced, or because what importing electronically formed provides the ability of electronics), so that it may make oxidant and reducing agent just
Ion react and can the reacting of accelerated oxidation agent and reducing agent cation (in other words, make oxidant formed oxidant bear from
Subprocess occur and can accelerated oxidation dosage form at oxidant anion process).(such as catalyst participation) is participated in electrode
Reducing agent and oxidant directly carry out needing electrode is not i.e. positively charged (not have without negative electricity during redox reaction
Electropositivity does not also have electronegativity, not within the rule by the electropositivity of itself or electronegativity of electro ultrafiltration, in other words, needs electricity
The electronegativity and electropositivity of pole are not changed), otherwise redox reaction can not be carried out directly.This means that as long as we change
The electrical property (changing its electropositivity, electronegativity, change its charging property) of variable electrode, so that it may avoid or weaken reducing agent and oxidation
Agent directly carries out redox reaction heat release and loses the process for exporting electric energy, to realize the mixing for using reducing agent and oxidant
Object carries out the safety and controllability of chemical energy electric energy conversion process, also may be implemented in reducing agent and oxidant handoff procedure
Probabilistic control caused by the mixed process being difficult to avoid that.Representative of the X-2 using hydrogen as reducing agent is schemed, using oxygen as oxygen
The representative of agent, using D as the representative in electrode (such as electrochemistry region 1 in the present invention), for by implementing electricity to electrode
Effect changes it electrically and then the process of control chemical reaction is shown, in figure, D+Indicate the electrode with electronegativity (i.e.
The electrode that the ability of affine electronics is reinforced, i.e., because electronics is exported the electrode that its electron affinity energy power is reinforced), D—Indicate tool
There is electropositive electrode (i.e. electrode that the ability of release electronics is reinforced, i.e., because electronics is imported into its ability quilt for discharging electronics
The electrode of reinforcing).
Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application
Protection scope.
It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention
Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention
It encloses.
Claims (18)
1. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) and reducing agent supply
Channel (3) connection setting is sent, the electrochemistry region (1) is connected to setting, the electrochemistry region with oxidant feed channel (4)
It (1) include the area alternating current Jie electricity, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, the electrochemistry region (1) is connected to setting, the electrochemistry region (1) and oxidant with reducing agent feed channel (3)
Feed channel (4) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, reducing agent feed channel (3)
The process of feed reducing agent and the process of oxidant feed channel (4) feed oxidant alternately, it is described electrification school district
It is work normality that the export of the electronics in domain (1), which imports,;
Or, the electrochemistry region (1) is connected to setting, the electrochemistry region (1) and oxidant with reducing agent feed channel (3)
Feed channel (4) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, reducing agent feed channel (3)
There is overlapping, the electrification school district in the process of feed reducing agent and the process of oxidant feed channel (4) feed oxidant
It is work normality that the export of the electronics in domain (1), which imports,;
Or, the electrochemistry region (1) is connected to setting, the electrochemistry region (1) and oxidant with reducing agent feed channel (3)
Feed channel (4) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, reducing agent feed channel (3)
There is weight in the feed process of the interrupted feed oxidant of the feed process of interrupted feed reducing agent and oxidant feed channel (4)
Folded, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,.
2. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is arranged in cavity
(5) in, the cavity (5) is connected to setting with reducing agent feed channel (3), and the cavity (5) and oxidant feed channel (4) are even
Logical setting, the electrochemistry region (1) includes the area alternating current Jie electricity, and the export of the electronics of the electrochemistry region (1) imports
For the normality that works;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to reducing agent feed channel (3) to be set
It sets, the cavity (5) is connected to setting with oxidant feed channel (4), and the electrochemistry region (1) includes that alternating current connects electricity
Area, the process of reducing agent feed channel (3) feed reducing agent and the mistake of oxidant feed channel (4) feed oxidant
Alternately, it is work normality that the export of the electronics of the electrochemistry region (1) imports to journey;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to reducing agent feed channel (3) to be set
It sets, the cavity (5) is connected to setting with oxidant feed channel (4), and the electrochemistry region (1) includes that alternating current connects electricity
Area, the process of reducing agent feed channel (3) feed reducing agent and the mistake of oxidant feed channel (4) feed oxidant
There is overlapping in journey, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to reducing agent feed channel (3) to be set
It sets, the cavity (5) is connected to setting with oxidant feed channel (4), and the electrochemistry region (1) includes that alternating current connects electricity
Area, discontinuously the feed process of feed reducing agent and oxidant feed channel (4) discontinuously supply in reducing agent feed channel (3)
The feed process of oxidant is sent to there is overlapping, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,.
3. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is through reducing agent control
System switch (6) is connected to setting with reducing agent feed channel (3), and the electrochemistry region (1) is through oxidant control switch (7) and oxygen
Agent feed channel (4) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, the electrochemistry region (1)
Electronics export import be work normality;
Or, the electrochemistry region (1) is connected to setting, the electricity with reducing agent feed channel (3) through reducing agent control switch (6)
Chemical regions (1) are connected to setting, electrochemistry region (1) packet with oxidant feed channel (4) through oxidant control switch (7)
Include the area alternating current Jie electricity, the reducing agent control switch (6) by control device controlled and the oxidant control switch (7) by
The process and oxidant feed channel (4) of reducing agent feed channel (3) feed reducing agent are realized in control device control
Alternately, it is work normality that the export of the electronics of the electrochemistry region (1) imports to the process of feed oxidant;
Or, the electrochemistry region (1) is connected to setting, the electricity with reducing agent feed channel (3) through reducing agent control switch (6)
Chemical regions (1) are connected to setting, electrochemistry region (1) packet with oxidant feed channel (4) through oxidant control switch (7)
Include the area alternating current Jie electricity, the reducing agent control switch (6) by control device controlled and the oxidant control switch (7) by
The process and oxidant feed channel (4) of reducing agent feed channel (3) feed reducing agent are realized in control device control
There is overlapping in the process of feed oxidant, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, the electrochemistry region (1) is connected to setting, the electricity with reducing agent feed channel (3) through reducing agent control switch (6)
Chemical regions (1) are connected to setting, electrochemistry region (1) packet with oxidant feed channel (4) through oxidant control switch (7)
Include the area alternating current Jie electricity, the reducing agent control switch (6) by control device controlled and the oxidant control switch (7) by
The feed process and the oxidant feed of reducing agent feed channel (3) interrupted feed reducing agent are realized in control device control
There is overlapping in the feed process of the interrupted feed oxidant in channel (4), it is work that the export of the electronics of the electrochemistry region (1), which imports,
Make normality;
Or, the electrochemistry region (1) is connected to setting, the electricity with reducing agent feed channel (3) through reducing agent control switch (6)
Chemical regions (1) are connected to setting, electrochemistry region (1) packet with oxidant feed channel (4) through oxidant control switch (7)
Include the area alternating current Jie electricity, the reducing agent control switch (6) by control device controlled and the oxidant control switch (7) by
Control device control realizes that reducing agent feed channel (3) are opened and oxidant feed channel (4) is discontinuously opened or institute
State reducing agent control switch (6) by control device controlled and the oxidant control switch (7) by control device controlled realize institute
It states oxidant feed channel (4) unlatching and reducing agent feed channel (3) is discontinuously opened, the electricity of the electrochemistry region (1)
It is work normality that the export of son, which imports,;
Or, the electrochemistry region (1) be connected to through reducing agent control switch (6) with reducing agent feed channel (3) setting and it is described
Electrochemistry region (1) is connected to setting with oxidant feed channel (4), and the electrochemistry region (1) includes the area alternating current Jie electricity,
The reducing agent control switch (6) is controlled by control device realizes that reducing agent feed channel (3) are discontinuously opened, the electrification
It is work normality that the export of the electronics in school district domain (1), which imports,;
Or, the electrochemistry region (1) be connected to through oxidant control switch (7) with oxidant feed channel (4) setting and it is described
Electrochemistry region (1) is connected to setting with reducing agent feed channel (3), and the electrochemistry region (1) includes the area alternating current Jie electricity,
The oxidant control switch (7) is controlled by control device realizes that oxidant feed channel (4) are discontinuously opened, the electrification
It is work normality that the export of the electronics in school district domain (1), which imports,.
4. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is arranged in cavity
(5) in, the cavity (5) is connected to setting, cavity (5) warp with reducing agent feed channel (3) through reducing agent control switch (6)
Oxidant control switch (7) is connected to setting with oxidant feed channel (4), and the electrochemistry region (1) includes that alternating current connects
Electric area, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is through reducing agent control switch (6) and reduction
Agent feed channel (3) connection setting, the cavity (5), which is connected to through oxidant control switch (7) with oxidant feed channel (4), to be set
Set, the electrochemistry region (1) includes the area alternating current Jie electricity, the reducing agent control switch (6) controlled by control device and
The oxidant control switch (7) is controlled the process for realizing reducing agent feed channel (3) feed reducing agent by control device
Alternately with the process of oxidant feed channel (4) feed oxidant, the export of the electronics of the electrochemistry region (1)
Importing is work normality;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is through reducing agent control switch (6) and reduction
Agent feed channel (3) connection setting, the cavity (5), which is connected to through oxidant control switch (7) with oxidant feed channel (4), to be set
Set, the electrochemistry region (1) includes the area alternating current Jie electricity, the reducing agent control switch (6) controlled by control device and
The oxidant control switch (7) is controlled the process for realizing reducing agent feed channel (3) feed reducing agent by control device
There is overlapping, the export of the electronics of the electrochemistry region (1) with the process of oxidant feed channel (4) feed oxidant
Importing is work normality;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is through reducing agent control switch (6) and reduction
Agent feed channel (3) connection setting, the cavity (5), which is connected to through oxidant control switch (7) with oxidant feed channel (4), to be set
Set, the electrochemistry region (1) includes the area alternating current Jie electricity, the reducing agent control switch (6) controlled by control device and
The oxidant control switch (7) is controlled by control device realizes reducing agent feed channel (3) interrupted feed reducing agent
There is overlapping, the electrification school district in the feed process of the interrupted feed oxidant of feed process and oxidant feed channel (4)
It is work normality that the export of the electronics in domain (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is through reducing agent control switch (6) and reduction
Agent feed channel (3) connection setting, the cavity (5), which is connected to through oxidant control switch (7) with oxidant feed channel (4), to be set
Set, the electrochemistry region (1) includes the area alternating current Jie electricity, the reducing agent control switch (6) controlled by control device and
The oxidant control switch (7) is controlled by control device realizes reducing agent control switch (6) unlatching and the oxidant
The reducing agent control switch (6) discontinuously unlatching and the oxidant control switch (7) are discontinuously opened or realized to control switch (7)
It opens, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to reducing agent feed channel (3) to be set
It sets, the cavity (5) is connected to setting, the electrochemistry region with oxidant feed channel (4) through oxidant control switch (7)
It (1) include the area alternating current Jie electricity, the oxidant control switch (7) is controlled realization by control device and discontinuously opened, the electricity
It is work normality that the export of the electronics of chemical regions (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to oxidant feed channel (4) to be set
It sets, the cavity (5) is connected to setting, the electrochemistry region with reducing agent feed channel (3) through reducing agent control switch (6)
It (1) include the area alternating current Jie electricity, the reducing agent control switch (6) is controlled realization by control device and discontinuously opened, the electricity
It is work normality that the export of the electronics of chemical regions (1), which imports,.
5. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) and reducing agent and
The mixture feed channel (8) of oxidant is connected to setting, and the electrochemistry region (1) includes the area alternating current Jie electricity, the electricity
It is work normality that the export of the electronics of chemical regions (1), which imports,;
Or, the electrochemistry region (1) is connected to setting, the electrification with the mixture feed channel (8) of reducing agent and oxidant
School district domain (1) includes the area alternating current Jie electricity, mixture feed channel (8) continuous feeding mixture, the electrification school district
It is work normality that the export of the electronics in domain (1), which imports,;
Or, the electrochemistry region (1) is connected to setting, the electrification with the mixture feed channel (8) of reducing agent and oxidant
School district domain (1) includes the area alternating current Jie electricity, the interrupted feed mixture in mixture feed channel (8), the electrification school district
It is work normality that the export of the electronics in domain (1), which imports,.
6. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is arranged in cavity
(5) in, the cavity (5) is connected to setting, the electrochemistry region with the mixture feed channel (8) of reducing agent and oxidant
It (1) include the area alternating current Jie electricity, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) supplies with the mixture of reducing agent and oxidant
Channel (8) connection setting is sent, the electrochemistry region (1) includes the area alternating current Jie electricity, and mixture feed channel (8) is even
Continuous feed mixture, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) supplies with the mixture of reducing agent and oxidant
Channel (8) connection setting is sent, the electrochemistry region (1) includes the area alternating current Jie electricity, and mixture feed channel (8) is disconnected
Continuous feed mixture, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,.
7. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is through mixture control
System switch (9) is connected to setting with the mixture feed channel (8) of reducing agent and oxidant, and the electrochemistry region (1) includes handing over
The area time-dependent current Jie electricity, it is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, mixture feed channel of the electrochemistry region (1) through mixture control switch (9) Yu reducing agent and oxidant
(8) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, and the mixture control switch (9) is filled by control
It sets (10) control and realizes that mixture feed channel (8) continuous feeding mixture, the electronics of the electrochemistry region (1) are led
Import out is work normality;
Or, mixture feed channel of the electrochemistry region (1) through mixture control switch (9) Yu reducing agent and oxidant
(8) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, and the mixture control switch (9) is filled by control
It sets (10) control and realizes that mixture feed channel (8) discontinuously feed mixture, the electronics of the electrochemistry region (1) are led
Import out is work normality.
8. a kind of electrochemical appliance, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is arranged in cavity
(5) in, the cavity (5) is connected to the mixture feed channel (8) of reducing agent and oxidant through mixture control switch (9) and sets
It sets, the electrochemistry region (1) includes the area alternating current Jie electricity, and it is work that the export of the electronics of the electrochemistry region (1), which imports,
Make normality;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is through mixture control switch (9) and reduction
Agent is connected to setting with the mixture feed channel (8) of oxidant, and the electrochemistry region (1) includes the area alternating current Jie electricity, institute
It states mixture control switch (9) and is controlled realization mixture feed channel (8) continuous feeding mixture by control device (10),
It is work normality that the export of the electronics of the electrochemistry region (1), which imports,;
Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is through mixture control switch (9) and reduction
Agent is connected to setting with the mixture feed channel (8) of oxidant, and the electrochemistry region (1) includes the area alternating current Jie electricity, institute
It states mixture control switch (9) and is controlled realization mixture feed channel (8) discontinuously feed mixture by control device (10),
It is work normality that the export of the electronics of the electrochemistry region (1), which imports,.
9. the electrochemical appliance as described in any one of claims 1 to 8, it is characterised in that: the electrochemistry region (1) and power supply
Electric communication setting or the electrochemistry region (1) setting are in the electric field;Or, the electrochemistry region (1) and capacitor, direct current
It is source, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, whole
Flow device, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three it
Conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten it
Conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, the effect of its 15 conjunction electricity are set
It sets.
10. the electrochemical appliance as described in any one of claims 1 to 8, it is characterised in that: the electrochemistry region (1) is through institute
The dielectric or electrolyte and electric conductor stated on electrochemistry region (1) have non-electronic conducting electrical relation, or, the electrochemistry
Region (1) through on electric conductor dielectric or electrolyte and the electric conductor there is non-electronic conducting electrical relation, or, the electricity
Chemical regions (1) through on electric conductor A dielectric or electrolyte and electric conductor there is non-electronic conducting electrical relation, or, described
On another face of dielectric or electrolyte again through the electric conductor A on a face of the electrochemistry region (1) through electric conductor A
Dielectric or electrolyte and electric conductor have non-electronic conducting electrical relation.
11. electrochemical appliance as claimed in claim 9, it is characterised in that: the electrochemistry region (1) is through the electrochemistry region
(1) dielectric or electrolyte and electric conductor on have non-electronic conducting electrical relation, or, the electrochemistry region (1) is through leading
Dielectric or electrolyte and the electric conductor on electric body have non-electronic conducting electrical relation, or, the electrochemistry region (1)
Through on electric conductor A dielectric or electrolyte and electric conductor there is non-electronic conducting electrical relation, or, the electrochemistry region
(1) dielectric or electricity on another face of the dielectric or electrolyte on a face again through the electric conductor A through electric conductor A
Xie Zhiyu electric conductor has non-electronic conducting electrical relation.
12. the electrochemical appliance as described in any one of claim 1 to 8 and 11, it is characterised in that: the electrochemistry region (1)
Rotation setting.
13. electrochemical appliance as claimed in claim 9, it is characterised in that: electrochemistry region (1) the rotation setting.
14. electrochemical appliance as claimed in claim 10, it is characterised in that: electrochemistry region (1) the rotation setting.
15. the electrochemical appliance as described in any one of claim 1 to 8 and 11 and 13 and 14, it is characterised in that: in the reduction
Inert substance and/or dead band duration are inserted between agent and the oxidant.
16. electrochemical appliance as claimed in claim 9, it is characterised in that: be inserted between the reducing agent and the oxidant
Inert substance and/or dead band duration.
17. electrochemical appliance as claimed in claim 10, it is characterised in that: be inserted between the reducing agent and the oxidant
Inert substance and/or dead band duration.
18. electrochemical appliance as claimed in claim 12, it is characterised in that: be inserted between the reducing agent and the oxidant
Inert substance and/or dead band duration.
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CN201910109788.2A Pending CN109802206A (en) | 2018-11-29 | 2019-02-11 | A kind of electrochemical appliance |
CN201910109787.8A Pending CN109802205A (en) | 2018-11-29 | 2019-02-11 | A kind of electrochemical appliance |
CN201910109785.9A Pending CN109802204A (en) | 2018-11-29 | 2019-02-11 | A kind of chemical energy device for converting electric energy |
CN201910109789.7A Pending CN109860681A (en) | 2018-11-29 | 2019-02-11 | A kind of electrochemical appliance |
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CN201910109787.8A Pending CN109802205A (en) | 2018-11-29 | 2019-02-11 | A kind of electrochemical appliance |
CN201910109785.9A Pending CN109802204A (en) | 2018-11-29 | 2019-02-11 | A kind of chemical energy device for converting electric energy |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1149933A (en) * | 1994-03-21 | 1997-05-14 | 兹特克公司 | Electrochemical converter having optimal pressure distribution |
CN1419717A (en) * | 2000-03-24 | 2003-05-21 | 科学基因有限公司 | Mixed reactant fuel cells with magnetic curren channel porous electrode |
JP2004058028A (en) * | 2002-07-31 | 2004-02-26 | National Institute Of Advanced Industrial & Technology | Electrochemical cell type chemical reaction system |
WO2008100182A1 (en) * | 2007-02-13 | 2008-08-21 | Anatoli Ivanovich Mamaev | Method for converting chemical energy into electric power and a converting device |
CN105637123A (en) * | 2013-07-31 | 2016-06-01 | 奥克海德莱克斯控股有限公司 | Electro-synthetic or electro-energy cell with gas diffusion electrode(s) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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FR3008235A1 (en) * | 2013-07-04 | 2015-01-09 | Michelin & Cie | METHOD FOR STOPPING A FUEL CELL SYSTEM, AND FUEL CELL SYSTEM |
-
2019
- 2019-02-11 CN CN201910109788.2A patent/CN109802206A/en active Pending
- 2019-02-11 CN CN201910109787.8A patent/CN109802205A/en active Pending
- 2019-02-11 CN CN201910109785.9A patent/CN109802204A/en active Pending
- 2019-02-11 CN CN201910109789.7A patent/CN109860681A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1149933A (en) * | 1994-03-21 | 1997-05-14 | 兹特克公司 | Electrochemical converter having optimal pressure distribution |
CN1419717A (en) * | 2000-03-24 | 2003-05-21 | 科学基因有限公司 | Mixed reactant fuel cells with magnetic curren channel porous electrode |
JP2004058028A (en) * | 2002-07-31 | 2004-02-26 | National Institute Of Advanced Industrial & Technology | Electrochemical cell type chemical reaction system |
WO2008100182A1 (en) * | 2007-02-13 | 2008-08-21 | Anatoli Ivanovich Mamaev | Method for converting chemical energy into electric power and a converting device |
CN105637123A (en) * | 2013-07-31 | 2016-06-01 | 奥克海德莱克斯控股有限公司 | Electro-synthetic or electro-energy cell with gas diffusion electrode(s) |
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CN109802206A (en) | 2019-05-24 |
CN109802205A (en) | 2019-05-24 |
CN109802204A (en) | 2019-05-24 |
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Application publication date: 20190607 |