CN109796913A - A kind of adhesive containing modified Nano bamboo charcoal powder - Google Patents
A kind of adhesive containing modified Nano bamboo charcoal powder Download PDFInfo
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- CN109796913A CN109796913A CN201811650200.6A CN201811650200A CN109796913A CN 109796913 A CN109796913 A CN 109796913A CN 201811650200 A CN201811650200 A CN 201811650200A CN 109796913 A CN109796913 A CN 109796913A
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- bamboo charcoal
- charcoal powder
- modified nano
- nano bamboo
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Abstract
A kind of adhesive containing modified Nano bamboo charcoal powder, it comprises the following components in parts by weight: 100-150 parts of polyvinyl alcohol resin, 50-80 parts of 2- ethyl benzofuran, dibatyl phithalate 20-30 parts of neck, 15-20 parts of polystyrene, 10-15 parts of dixylenyl phosphate, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, 5-8 parts of titanium dioxide, 5-20 parts of nano-sized magnesium hydroxide, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of gas-phase silica, 3-5 parts of sodium alginate, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, 0.7-0.9 parts of dibutyl tin dilaurate, 2-4 parts of micaceous iron oxide, silane coupling agent 1- 3 parts, 10-15 parts of modified coal ash.The present invention is by ingredients such as addition modified Nano bamboo charcoal powder, lignin into adhesive, it can effectively eliminate the toxicity and pollution on the environment of adhesive, simultaneously, modified coal ash is added, significantly improve the dispersing uniformity of each component, the adhesion intensity of adhesive can be improved, and have the characteristics that at low cost, excellent effect.Adhesive of the invention has the characteristics that adhesive strength is high, pollution-free, storage period is longer, harmless to human body, environmentally protective.
Description
Technical field
The present invention relates to the present invention relates to a kind of jointing material, especially a kind of gluings containing modified Nano bamboo charcoal powder
Agent.
Background technique
Adhesive is that one kind can be the similar or inhomogeneous combined substance of material tight.With science and technology
With the development of national economy, adhesive has been widely used in timber processing, architectural engineering, textile printing and dyeing, shoemaking, leather, electricity
The every profession and trades such as son, automobile, machinery, aerospace, biologic medical and high-tech area.Currently, in order to improve the certain of adhesive
Some modifying agent, thickener, tackifier, emulsifier etc. is often added in performance in adhesive, and some in these substances are toxic
, some are even extremely toxic, and most meeting generation environment pollutions.
Summary of the invention
It is more preferable and both resistance to that a kind of feature of environmental protection is provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art
It is hot, ageing-resistant, and a kind of adhesive containing modified Nano bamboo charcoal powder of adhesive strength can be improved.
The object of the present invention is achieved like this:
A kind of adhesive containing modified Nano bamboo charcoal powder, comprises the following components in parts by weight: polyvinyl alcohol resin 100-
150 parts, 50-80 parts of 2- ethyl benzofuran, neck dibatyl phithalate 20-30 parts, 15-20 parts of polystyrene, xylyl
10-15 parts of phosphate, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, titanium dioxide 5-
8 parts, 5-20 parts of nano-sized magnesium hydroxide, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of gas-phase silica, sea
3-5 parts of mosanom, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, 0.7-0.9 parts of dibutyl tin dilaurate, cloud
Female iron oxide 2-4 parts, 1-3 parts of silane coupling agent, 10-15 parts of modified coal ash.
The modified Nano bamboo charcoal powder the preparation method comprises the following steps: bamboo charcoal powder with 10-15% sodium hydroxide solution impregnate 5-8h,
Then it is washed with deionized, dries, add the a- cyano third of 2,4,6 trisphenols, 1-3% that are equivalent to its weight 1-2%
The crosslink agent DCP of olefin(e) acid ethyl ester, 1-3%, 3000-5000 revs/min stirring 30-50 minutes, drying, be ground into nanometer powder, i.e.,
It can.
The modified coal ash is prepared by the following steps: first being dried flyash in 100-110 DEG C of baking oven, then will
Flyash after drying is put into high-speed kneading machine, and aluminate coupling agent, the 2-4% for being equivalent to flyash weight 3-5% is added
Wooden sodium sulfonate, the triethyl citrate of 2-4%, the atoleine of 1-2% and 2-5% talcum powder, after mixed at high speed, dry
It is dry, it smashes and grinds into superfines.
A kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, including following preparation step:
(1) by recipe ratio will by polyvinyl alcohol resin, 2- ethyl benzofuran, neck dibatyl phithalate, polystyrene,
Dixylenyl phosphate, isophorone diisocyanate, nitrile rubber, dibutyl tin dilaurate are added to reaction kettle and are heated to
100-130 DEG C, high-speed stirred 3-4h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1-2h, is cooled to room temperature, packaging is
It can.
The advantages and positive effects of the present invention are:
The present invention, into adhesive, can effectively eliminate gluing by ingredients such as addition modified Nano bamboo charcoal powder, lignin
The toxicity and pollution on the environment of agent, meanwhile, modified coal ash is added, hence it is evident that the dispersing uniformity of each component is improved,
The adhesion intensity of adhesive can be improved, and have the characteristics that at low cost, excellent effect.Adhesive of the invention has bonding strong
The features such as high, pollution-free, storage period is longer is spent, it is harmless to human body, it is environmentally protective.
Specific embodiment
The embodiment of the present invention is described in detail below；It should be noted that the present embodiment is narrative, it is not limited
, this does not limit the scope of protection of the present invention.
Embodiment 1:
Following percentage is weight percentage, and the method not referred to is the known method of those skilled in the art.
It comprises the following components in parts by weight: 130 parts of polyvinyl alcohol resin, 70 parts of 2- ethyl benzofuran, neck phthalic acid
20 parts of dibutyl ester, 15 parts of polystyrene, 13 parts of dixylenyl phosphate, 25 parts of isophorone diisocyanate, nitrile rubber 7
Part, 10 parts of calcium carbonate, 5 parts of titanium dioxide, 6 parts of nano-sized magnesium hydroxide, 18 parts of modified Nano bamboo charcoal powder, 15 parts of lignin, gas phase are white
4 parts of carbon black, 4 parts of sodium alginate, 25 parts of quartz sand, 2 parts of boron powder, 6 parts of bath of glass, 0.8 part of dibutyl tin dilaurate, mica oxygen
Change 3 parts of iron, 2 parts of silane coupling agent, 13 parts of modified coal ash.
Wherein, modified Nano bamboo charcoal powder the preparation method comprises the following steps: bamboo charcoal powder with 15% sodium hydroxide solution impregnate 8h, then use
Deionized water washing, drying, add 2,4,6 trisphenols, 3% that are equivalent to its weight 2% a- cyanacrylate,
3% crosslink agent DCP, 5000 revs/min are stirred 50 minutes, and drying is ground into nanometer powder.
Modified coal ash is prepared by the following steps: first being dried flyash in 110 DEG C of baking ovens, then by the powder after drying
Coal ash is put into high-speed kneading machine, be added be equivalent to flyash weight 5% aluminate coupling agent, 3% wooden sodium sulfonate,
3% triethyl citrate, 2% atoleine and 4% talcum powder, after mixed at high speed, drying is smashed and ground into superfine powder
End.
A kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, including following preparation step: (1) recipe ratio is pressed
It will be by polyvinyl alcohol resin, 2- ethyl benzofuran, neck dibatyl phithalate, polystyrene, dixylenyl phosphate, different Buddhist
That ketone diisocyanate, nitrile rubber, dibutyl tin dilaurate are added to reaction kettle and are heated to 130 DEG C, high-speed stirred 3h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1h, is cooled to room temperature, packaging.
Embodiment 2:
A kind of adhesive containing modified Nano bamboo charcoal powder, comprises the following components in parts by weight: polyvinyl alcohol resin 100
It is part, 50 parts of 2- ethyl benzofuran, 20 parts of dibatyl phithalate of neck, 15 parts of polystyrene, 10 parts of dixylenyl phosphate, different
20 parts of isophorone diisocyanate, 5 parts of nitrile rubber, 10 parts of calcium carbonate, 7 parts of titanium dioxide, nano-sized magnesium hydroxide 5, part, modification are received
Rice 15 parts of bamboo charcoal powder, 10 parts of lignin, 3 parts of gas-phase silica, 3 parts of sodium alginate, 20 parts of quartz sand, 1 part of boron powder, bath of glass 5
Part, 0.7 part of dibutyl tin dilaurate, 2 parts of micaceous iron oxide, 2 parts of silane coupling agent, 10 parts of modified coal ash.
Wherein, modified Nano bamboo charcoal powder the preparation method comprises the following steps: bamboo charcoal powder with 10% sodium hydroxide solution impregnate 7h, then use
Deionized water washing, drying, add 2,4,6 trisphenols, 1% that are equivalent to its weight 2% a- cyanacrylate,
1% crosslink agent DCP, 3000 revs/min are stirred 30 minutes, and drying is ground into nanometer powder.
Modified coal ash is prepared by the following steps: first being dried flyash in 100 DEG C of baking ovens, then by the powder after drying
Coal ash is put into high-speed kneading machine, be added be equivalent to flyash weight 3% aluminate coupling agent, 2% wooden sodium sulfonate,
2% triethyl citrate, 1% atoleine and 2% talcum powder, after mixed at high speed, drying is smashed and ground into superfine powder
End.
A kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, including following preparation step: (1) recipe ratio is pressed
It will be by polyvinyl alcohol resin, 2- ethyl benzofuran, neck dibatyl phithalate, polystyrene, dixylenyl phosphate, different Buddhist
That ketone diisocyanate, nitrile rubber, dibutyl tin dilaurate are added to reaction kettle and are heated to 100 DEG C, high-speed stirred 3h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1h, is cooled to room temperature, packaging.
Claims (4)
1. a kind of adhesive containing modified Nano bamboo charcoal powder, it is characterised in that: comprise the following components in parts by weight: polyvinyl alcohol
100-150 parts of resin, 50-80 parts of 2- ethyl benzofuran, neck dibatyl phithalate 20-30 parts, 15-20 parts of polystyrene,
10-15 parts of dixylenyl phosphate, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate,
5-8 parts of titanium dioxide, 5-20 parts of nano-sized magnesium hydroxide, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, gas-phase silica
3-5 parts, 3-5 parts of sodium alginate, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, dibutyl tin dilaurate 0.7-
0.9 part, 2-4 parts of micaceous iron oxide, 1-3 parts of silane coupling agent, 10-15 parts of modified coal ash.
2. a kind of adhesive containing modified Nano bamboo charcoal powder according to claim 1, it is characterised in that: the modification
Nano bamboo powdered carbon the preparation method comprises the following steps: bamboo charcoal powder with 10-15% sodium hydroxide solution impregnate 5-8h, be then washed with deionized water
It washs, dries, add and be equivalent to 2,4,6 trisphenols of its weight 1-2%, the a- cyanacrylate of 1-3%, 1-3%
Crosslink agent DCP, 3000-5000 revs/min stirring 30-50 minutes, drying, be ground into nanometer powder.
3. a kind of adhesive containing modified Nano bamboo charcoal powder according to claim 1, it is characterised in that: the modification
Flyash is prepared by the following steps: first being dried flyash in 100-110 DEG C of baking oven, is then put into the flyash after drying
In high-speed kneading machine, addition is equivalent to the aluminate coupling agent of flyash weight 3-5%, the wooden sodium sulfonate of 2-4%, 2-4%
Triethyl citrate, the atoleine of 1-2% and the talcum powder of 2-5%, after mixed at high speed, drying is smashed and ground at ultra-fine
Powder.
4. a kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, it is characterised in that: including following preparation step:
It (1) will be by polyvinyl alcohol resin, 2- ethyl benzofuran, neck dibatyl phithalate, polystyrene, diformazan by recipe ratio
Phenyl phosphate ester, isophorone diisocyanate, nitrile rubber, dibutyl tin dilaurate are added to reaction kettle and are heated to 100-
130 DEG C, high-speed stirred 3-4h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1-2h, is cooled to room temperature, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811650200.6A CN109796913A (en) | 2018-12-31 | 2018-12-31 | A kind of adhesive containing modified Nano bamboo charcoal powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811650200.6A CN109796913A (en) | 2018-12-31 | 2018-12-31 | A kind of adhesive containing modified Nano bamboo charcoal powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109796913A true CN109796913A (en) | 2019-05-24 |
Family
ID=66558168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811650200.6A Withdrawn CN109796913A (en) | 2018-12-31 | 2018-12-31 | A kind of adhesive containing modified Nano bamboo charcoal powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109796913A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114939916A (en) * | 2022-05-23 | 2022-08-26 | 广西科学院 | Microwave hot pressing method for manufacturing shaving board |
-
2018
- 2018-12-31 CN CN201811650200.6A patent/CN109796913A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114939916A (en) * | 2022-05-23 | 2022-08-26 | 广西科学院 | Microwave hot pressing method for manufacturing shaving board |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190524 |
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| WW01 | Invention patent application withdrawn after publication |