CN108165211A - A kind of adhesive containing modified Nano bamboo charcoal powder - Google Patents
A kind of adhesive containing modified Nano bamboo charcoal powder Download PDFInfo
- Publication number
- CN108165211A CN108165211A CN201611115599.9A CN201611115599A CN108165211A CN 108165211 A CN108165211 A CN 108165211A CN 201611115599 A CN201611115599 A CN 201611115599A CN 108165211 A CN108165211 A CN 108165211A
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- CN
- China
- Prior art keywords
- parts
- bamboo charcoal
- charcoal powder
- modified nano
- nano bamboo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of adhesive containing modified Nano bamboo charcoal powder includes the component of following parts by weight：100 150 parts of polyvinyl alcohol resin, 2 50 80 parts of ethyl benzofurans, lead 20 30 parts of dibatyl phithalate, 15 20 parts of polystyrene, 10 15 parts of dixylenyl phosphate, 20 30 parts of isophorone diisocyanate, 5 10 parts of nitrile rubber, 10 15 parts of calcium carbonate, 58 parts of titanium dioxide, 5 20 parts of nano-sized magnesium hydroxide, 15 20 parts of modified Nano bamboo charcoal powder, 10 15 parts of lignin, 35 parts of gas-phase silica, 35 parts of sodium alginate, 20 30 parts of quartz sand, 13 parts of boron powder, 5 10 parts of bath of glass, 0.7 0.9 parts of dibutyl tin laurate, 24 parts of micaceous iron oxide, 13 parts of silane coupling agent, 10 15 parts of modified coal ash.The present invention is by adding in the ingredients to adhesive such as modified Nano bamboo charcoal powder, lignin, the toxicity and pollution on the environment of adhesive can be effectively eliminated, simultaneously, add in modified coal ash, significantly improve the dispersing uniformity of each component, the adhesion intensity of adhesive can be improved, and there is at low cost, excellent effect.The adhesive of the present invention has the characteristics that adhesive strength is high, pollution-free, storage period is longer, harmless to human body, environmentally protective.
Description
Technical field
The present invention relates to the present invention relates to a kind of jointing material, particularly a kind of gluings containing modified Nano bamboo charcoal powder
Agent.
Background technology
Adhesive is that one kind can be the similar or inhomogeneous combined substance of material tight.With science and technology
With the development of national economy, adhesive has been widely used in timber processing, architectural engineering, textile printing and dyeing, shoemaking, leather, electricity
The every profession and trades such as son, automobile, machinery, aerospace, biologic medical and high-tech area.At present, in order to improve the certain of adhesive
Performance often adds in some modifying agent, thickener, tackifier, emulsifier etc. in adhesive, and some in these substances are toxic
, some are even extremely toxic, and most meeting generation environment pollutions.
Invention content
It is more preferable and both resistance to that a kind of feature of environmental protection is provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art
It is hot, ageing-resistant, and a kind of adhesive containing modified Nano bamboo charcoal powder of adhesive strength can be improved.
The object of the present invention is achieved like this：
A kind of adhesive containing modified Nano bamboo charcoal powder includes the component of following parts by weight：Polyvinyl alcohol resin 100-
150 parts, 50-80 parts of 2- ethyl benzofurans, neck 20-30 parts of dibatyl phithalate, 15-20 parts of polystyrene, xylyl
10-15 parts of phosphate, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, titanium dioxide 5-
8 parts, 5-20 parts of nano-sized magnesium hydroxide, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of gas-phase silica, sea
3-5 parts of mosanom, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, 0.7-0.9 parts of dibutyl tin laurate, cloud
Female iron oxide 2-4 parts, 1-3 parts of silane coupling agent, 10-15 parts of modified coal ash.
The preparation method of the modified Nano bamboo charcoal powder is：Bamboo charcoal powder impregnates 5-8h with 10-15% sodium hydroxide solutions,
Then it is washed with deionized, dries, add 2,4,6 trisphenols for being equivalent to its weight 1-2%, the a- cyano third of 1-3%
The crosslink agent DCP of olefin(e) acid ethyl ester, 1-3%, 3000-5000 revs/min is stirred 30-50 minutes, and drying is ground into nanometer powder, i.e.,
It can.
The modified coal ash is prepared by following steps：First flyash in 100-110 DEG C of baking oven is dried, then will
Flyash after drying is put into high-speed kneading machine, adds in aluminate coupling agent, the 2-4% for being equivalent to flyash weight 3-5%
Wooden sodium sulfonate, the triethyl citrate of 2-4%, the atoleine of 1-2% and 2-5% talcum powder, after mixed at high speed, dry
Dry, attrition grinding is into superfines.
A kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, including following preparation process：
(1) by recipe ratio will by polyvinyl alcohol resin, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene,
Dixylenyl phosphate, isophorone diisocyanate, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to
100-130 DEG C, high-speed stirred 3-4h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1-2h, be cooled to room temperature, packaging is
It can.
The advantages and positive effects of the present invention are：
The present invention can effectively eliminate gluing by adding in the ingredients to adhesive such as modified Nano bamboo charcoal powder, lignin
The toxicity and pollution on the environment of agent, meanwhile, add in modified coal ash, hence it is evident that the dispersing uniformity of each component is improved,
The adhesion intensity of adhesive can be improved, and there is at low cost, excellent effect.The adhesive of the present invention has bonding by force
The features such as degree is high, pollution-free, storage period is longer, it is harmless to human body, it is environmentally protective.
Specific embodiment
The embodiment of the present invention is described in detail below；It should be noted that the present embodiment is narrative, it is not limited
, it is impossible to protection scope of the present invention is limited with this.
Embodiment 1：
Following percentage is weight percentage, and the method not referred to is the known method of those skilled in the art.
Include the component of following parts by weight：130 parts of polyvinyl alcohol resin, 70 parts of 2- ethyls benzofuran, neck phthalic acid
20 parts of dibutyl ester, 15 parts of polystyrene, 13 parts of dixylenyl phosphate, 25 parts of isophorone diisocyanate, nitrile rubber 7
Part, 10 parts of calcium carbonate, 5 parts of titanium dioxide, 6 parts of nano-sized magnesium hydroxide, 18 parts of modified Nano bamboo charcoal powder, 15 parts of lignin, gas phase are white
4 parts of carbon black, 4 parts of sodium alginate, 25 parts of quartz sand, 2 parts of boron powder, 6 parts of bath of glass, 0.8 part of dibutyl tin laurate, mica oxygen
Change 3 parts of iron, 2 parts of silane coupling agent, 13 parts of modified coal ash.
Wherein, the preparation method of modified Nano bamboo charcoal powder is：Bamboo charcoal powder impregnates 8h, Ran Houyong with 15% sodium hydroxide solution
Deionized water wash, drying, add 2,4,6 trisphenols for being equivalent to its weight 2%, 3% a- cyanacrylates,
3% crosslink agent DCP, 5000 revs/min are stirred 50 minutes, and drying is ground into nanometer powder, you can.
Modified coal ash is prepared by following steps：First flyash is dried in 110 DEG C of baking ovens, then by the powder after drying
Coal ash is put into high-speed kneading machine, add in be equivalent to the aluminate coupling agent of flyash weight 5%, 3% wooden sodium sulfonate,
3% triethyl citrate, 2% atoleine and 4% talcum powder, after mixed at high speed, drying, attrition grinding is into superfine powder
End.
A kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, including following preparation process：(1) by recipe ratio
It will be by polyvinyl alcohol resin, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, dixylenyl phosphate, different Buddhist
That ketone diisocyanate, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 130 DEG C, high-speed stirred 3h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1h, be cooled to room temperature, packaging.
Embodiment 2：
A kind of adhesive containing modified Nano bamboo charcoal powder includes the component of following parts by weight：Polyvinyl alcohol resin 100
It is part, 50 parts of 2- ethyls benzofuran, 20 parts of dibatyl phithalate of neck, 15 parts of polystyrene, 10 parts of dixylenyl phosphate, different
20 parts of isophorone diisocyanate, 5 parts of nitrile rubber, 10 parts of calcium carbonate, 7 parts of titanium dioxide, nano-sized magnesium hydroxide 5, part, modification are received
15 parts of bamboo charcoal powder of rice, 10 parts of lignin, 3 parts of gas-phase silica, 3 parts of sodium alginate, 20 parts of quartz sand, 1 part of boron powder, bath of glass 5
Part, 0.7 part of dibutyl tin laurate, 2 parts of micaceous iron oxide, 2 parts of silane coupling agent, 10 parts of modified coal ash.
Wherein, the preparation method of modified Nano bamboo charcoal powder is：Bamboo charcoal powder impregnates 7h, Ran Houyong with 10% sodium hydroxide solution
Deionized water wash, drying, add 2,4,6 trisphenols for being equivalent to its weight 2%, 1% a- cyanacrylates,
1% crosslink agent DCP, 3000 revs/min are stirred 30 minutes, and drying is ground into nanometer powder, you can.
Modified coal ash is prepared by following steps：First flyash is dried in 100 DEG C of baking ovens, then by the powder after drying
Coal ash is put into high-speed kneading machine, add in be equivalent to the aluminate coupling agent of flyash weight 3%, 2% wooden sodium sulfonate,
2% triethyl citrate, 1% atoleine and 2% talcum powder, after mixed at high speed, drying, attrition grinding is into superfine powder
End.
A kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, including following preparation process：(1) by recipe ratio
It will be by polyvinyl alcohol resin, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, dixylenyl phosphate, different Buddhist
That ketone diisocyanate, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 100 DEG C, high-speed stirred 3h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1h, be cooled to room temperature, packaging.
Claims (4)
1. a kind of adhesive containing modified Nano bamboo charcoal powder, it is characterised in that：Include the component of following parts by weight：Polyvinyl alcohol
100-150 parts of resin, 50-80 parts of 2- ethyl benzofurans, neck 20-30 parts of dibatyl phithalate, 15-20 parts of polystyrene,
10-15 parts of dixylenyl phosphate, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate,
5-8 parts of titanium dioxide, 5-20 parts of nano-sized magnesium hydroxide, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, gas-phase silica
3-5 parts, 3-5 parts of sodium alginate, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, dibutyl tin laurate 0.7-
0.9 part, 2-4 parts of micaceous iron oxide, 1-3 parts of silane coupling agent, 10-15 parts of modified coal ash.
2. a kind of adhesive containing modified Nano bamboo charcoal powder according to claim 1, it is characterised in that：The modification
The preparation method of nano bamboo powdered carbon is：Bamboo charcoal powder impregnates 5-8h with 10-15% sodium hydroxide solutions, is then washed with deionized water
It washs, dries, add and be equivalent to 2,4,6 trisphenols of its weight 1-2%, the a- cyanacrylates of 1-3%, 1-3%
Crosslink agent DCP, 3000-5000 revs/min is stirred 30-50 minutes, and drying is ground into nanometer powder, you can.
3. a kind of adhesive containing modified Nano bamboo charcoal powder according to claim 1, it is characterised in that：The modification
Flyash is prepared by following steps：First flyash in 100-110 DEG C of baking oven is dried, is then put into the flyash after drying
In high-speed kneading machine, addition is equivalent to the aluminate coupling agent of flyash weight 3-5%, the wooden sodium sulfonate of 2-4%, 2-4%
Triethyl citrate, the atoleine of 1-2% and the talcum powder of 2-5%, after mixed at high speed, drying, attrition grinding is into ultra-fine
Powder.
4. a kind of preparation method of the adhesive containing modified Nano bamboo charcoal powder, it is characterised in that：Including following preparation process：
It (1) will be by polyvinyl alcohol resin, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, diformazan by recipe ratio
Phenyl phosphate ester, isophorone diisocyanate, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 100-
130 DEG C, high-speed stirred 3-4h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1-2h, be cooled to room temperature, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611115599.9A CN108165211A (en) | 2016-12-07 | 2016-12-07 | A kind of adhesive containing modified Nano bamboo charcoal powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611115599.9A CN108165211A (en) | 2016-12-07 | 2016-12-07 | A kind of adhesive containing modified Nano bamboo charcoal powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108165211A true CN108165211A (en) | 2018-06-15 |
Family
ID=62526096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611115599.9A Pending CN108165211A (en) | 2016-12-07 | 2016-12-07 | A kind of adhesive containing modified Nano bamboo charcoal powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108165211A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114939916A (en) * | 2022-05-23 | 2022-08-26 | 广西科学院 | Microwave hot pressing method for manufacturing shaving board |
-
2016
- 2016-12-07 CN CN201611115599.9A patent/CN108165211A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114939916A (en) * | 2022-05-23 | 2022-08-26 | 广西科学院 | Microwave hot pressing method for manufacturing shaving board |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180615 |