CN109749583B - 防腐耐磨涂层材料及其制备方法 - Google Patents
防腐耐磨涂层材料及其制备方法 Download PDFInfo
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- CN109749583B CN109749583B CN201910086172.8A CN201910086172A CN109749583B CN 109749583 B CN109749583 B CN 109749583B CN 201910086172 A CN201910086172 A CN 201910086172A CN 109749583 B CN109749583 B CN 109749583B
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- 238000000576 coating method Methods 0.000 title claims abstract description 66
- 239000011248 coating agent Substances 0.000 title claims abstract description 64
- 238000005260 corrosion Methods 0.000 title claims abstract description 43
- 239000000463 material Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000000839 emulsion Substances 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 41
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000010445 mica Substances 0.000 claims abstract description 40
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 40
- 230000007797 corrosion Effects 0.000 claims abstract description 38
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003822 epoxy resin Substances 0.000 claims abstract description 31
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 31
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 239000003112 inhibitor Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000002270 dispersing agent Substances 0.000 claims abstract description 21
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 15
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 108
- 238000003756 stirring Methods 0.000 claims description 70
- 238000002156 mixing Methods 0.000 claims description 62
- 239000007864 aqueous solution Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 27
- 238000001035 drying Methods 0.000 claims description 27
- 239000002244 precipitate Substances 0.000 claims description 21
- -1 zinc dimethacrylate ethanol Chemical compound 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 19
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 17
- 239000012046 mixed solvent Substances 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical group [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 15
- 239000011684 sodium molybdate Substances 0.000 claims description 14
- 235000015393 sodium molybdate Nutrition 0.000 claims description 14
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 13
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 13
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 12
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 claims description 11
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 10
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 10
- 229940079864 sodium stannate Drugs 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 claims description 10
- 108010009736 Protein Hydrolysates Proteins 0.000 claims description 9
- 239000000413 hydrolysate Substances 0.000 claims description 9
- 230000001105 regulatory effect Effects 0.000 claims description 9
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 9
- 238000005303 weighing Methods 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 238000010992 reflux Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- 238000005119 centrifugation Methods 0.000 claims description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 235000019441 ethanol Nutrition 0.000 description 30
- 239000011259 mixed solution Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 229910001069 Ti alloy Inorganic materials 0.000 description 11
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 7
- 125000003916 ethylene diamine group Chemical group 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 6
- 230000001376 precipitating effect Effects 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000007547 defect Effects 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000005536 corrosion prevention Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Icorr,μA·cm<sup>-2</sup> | 摩擦系数 | 硬度,H | |
实施例1 | 0.83 | 0.71 | 2 |
实施例2 | 0.61 | 0.59 | 3 |
实施例3 | 0.32 | 0.41 | 5 |
实施例4 | 0.39 | 0.49 | 4 |
实施例5 | 0.43 | 0.54 | 4 |
实施例6 | 0.35 | 0.45 | 5 |
实施例7 | 0.12 | 0.26 | 6 |
Claims (7)
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110540402A (zh) * | 2019-10-10 | 2019-12-06 | 马鞍山海华耐磨材料科技有限公司 | 一种用于铸件表面的防腐耐磨材料 |
CN111171709A (zh) * | 2020-01-22 | 2020-05-19 | 四川航铁碳微新材料科技有限公司 | 一种功能涂层材料的制备方法及其制备的涂料 |
CN111704845A (zh) * | 2020-06-24 | 2020-09-25 | 宁波计氏金属新材料有限公司 | 一种铁基表面具有防腐功能的涂层处理方法 |
CN114716188B (zh) * | 2022-03-18 | 2022-09-16 | 中意世兴实业(武汉)有限公司 | 一种轻质混凝土及其制备方法 |
CN117625027B (zh) * | 2023-12-18 | 2024-07-19 | 浙江上青元电力科技有限公司 | 一种高强度海洋运输用化工桶防腐缓蚀剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2003147250A (ja) * | 2001-11-12 | 2003-05-21 | Kuraray Co Ltd | 水性インキ組成物 |
CN102931149A (zh) * | 2012-11-15 | 2013-02-13 | 中国科学院深圳先进技术研究院 | 纳米二氧化硅-纳米氮化硅复合材料及其制备方法 |
CN105153874A (zh) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | 一种高附着力耐磨水性导静电防腐涂料 |
CN108219628A (zh) * | 2018-01-09 | 2018-06-29 | 河北晨阳工贸集团有限公司 | 一种耐海洋腐蚀的航空发动机去离子水漆及其制备方法 |
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- 2019-01-29 CN CN201910086172.8A patent/CN109749583B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2003147250A (ja) * | 2001-11-12 | 2003-05-21 | Kuraray Co Ltd | 水性インキ組成物 |
CN102931149A (zh) * | 2012-11-15 | 2013-02-13 | 中国科学院深圳先进技术研究院 | 纳米二氧化硅-纳米氮化硅复合材料及其制备方法 |
CN105153874A (zh) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | 一种高附着力耐磨水性导静电防腐涂料 |
CN108219628A (zh) * | 2018-01-09 | 2018-06-29 | 河北晨阳工贸集团有限公司 | 一种耐海洋腐蚀的航空发动机去离子水漆及其制备方法 |
Non-Patent Citations (2)
Title |
---|
《纳米氮化硅粉体的表面改性研究》;徐博等;《淮北煤炭师范学院学报(自然科学版)》;20080630;第29卷(第2期);第1.2节 * |
《表面改性对氮化硅粉体及其涂层影响的研究》;徐金鑫等;《渤海大学学报(自然科学》;20110630;第32卷(第2期);第1.1-1.2节 * |
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Effective date of registration: 20210826 Address after: 314000 floor 4, building C, No. 3418, Wanguo Road, Jiaxing City, Zhejiang Province Applicant after: Zhejiang Huizhi Industrial Co.,Ltd. Address before: 335400 Room 202, unit 1, building 5, health center, No. 3, Xinjiang South Road, Guixi City, Yingtan City, Jiangxi Province Applicant before: Occupying army |
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Address after: 314000 floor 4, building C, No. 3418, Wanguo Road, Jiaxing City, Zhejiang Province Patentee after: Jiaxing Sugude Plastic Industry Co.,Ltd. Address before: 314000 floor 4, building C, No. 3418, Wanguo Road, Jiaxing City, Zhejiang Province Patentee before: Zhejiang Huizhi Industrial Co.,Ltd. |
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Denomination of invention: Anti corrosion and wear-resistant coating materials and their preparation methods Effective date of registration: 20231225 Granted publication date: 20210928 Pledgee: Industrial and Commercial Bank of China Limited Jiaxing Xiuzhou Branch Pledgor: Jiaxing Sugude Plastic Industry Co.,Ltd. Registration number: Y2023980073181 |