CN109698241A - The flexible thin-film transistor and its manufacturing method of high-dielectric-coefficient grid medium layer - Google Patents

The flexible thin-film transistor and its manufacturing method of high-dielectric-coefficient grid medium layer Download PDF

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Publication number
CN109698241A
CN109698241A CN201811621372.0A CN201811621372A CN109698241A CN 109698241 A CN109698241 A CN 109698241A CN 201811621372 A CN201811621372 A CN 201811621372A CN 109698241 A CN109698241 A CN 109698241A
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layer
soi
film
silicon
photoetching
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秦国轩
裴智慧
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Tianjin University
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Tianjin University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78603Thin film transistors, i.e. transistors with a channel being at least partly a thin film characterised by the insulating substrate or support
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78651Silicon transistors

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Thin Film Transistor (AREA)

Abstract

The present invention relates to flexible device fields, to propose flexible material transistor.The present invention, the flexible thin-film transistor of high-dielectric-coefficient grid medium layer, tin indium oxide ITO bottom gate thin film and barium zirconium phthalate BZT gate dielectric film are formed on PET flexible material substrate by way of magnetron sputtering, BZT gate dielectric layer top is one layer of monocrystalline silicon thin film, the source of this layer of monocrystalline silicon thin film is the silicon thin film of SOI, doped region pattern is formed by carrying out photoetching process in the top layer silicon of SOI, doped region at two is formed by ion implanting and the technique of annealing, square hole layer is formed by way of photoetching and reactive ion etching RIE in top layer silicon again, wet etching is carried out in hydrofluoric acid, remove intermediate SiO2, finally by the mode that photoetching and vacuum electron beam are deposited, doped region is respectively formed with source-drain electrode at two.Present invention is mainly applied to the manufactures of flexible material transistor design.

Description

The flexible thin-film transistor and its manufacturing method of high-dielectric-coefficient grid medium layer
Technical field
The present invention relates to flexible device fields, and in particular to a kind of high-dielectric-coefficient grid medium layer based on silicon nanometer film Bottom gate thin film transistor structure design and preparation method.
Background technique
Flexible electronic be by organic and inorganic material electronics element manufacturing on flexible, Drawability plastics or thin metal matrix plate New electronic science and technology, all there is extensive use in fields such as information, the energy, medical treatment, national defence.Such as print RFID tag (RFID), electronics surface mount, Organic Light Emitting Diode OLED, flexible electronic displays etc..With traditional integrated circuit (IC) Technology is the same, and the main drive of flexible electronic technology development is manufacturing process and equipment.With more on the substrate of more large format Low cost, which produces the smaller flexible electronic device of characteristic size, becomes the key of manufacture.The present invention is based on silicon using a kind of The novel process of nanometer film preparation forms bottom gate thin film using magnetron sputtering, and ion etching and hydrofluoric acid (HF) are wet after photoetching The technology of method etching, by the silicon nanometer film stripping on silicon-on-insulator (SOI) and is transferred to the poly- terephthaldehyde of flexible On sour glycol ester (PET) substrate, metal source and drain electrodes are then formed by photoetching and vacuum electron beam evaporation coating technique, are had in the future Hope that, in wearable electronic, extensive flexible integration circuit etc. obtains extensive use.
Summary of the invention
In order to overcome the deficiencies of the prior art, the present invention is directed to propose flexible material transistor.For this purpose, the skill that the present invention takes Art scheme is the flexible thin-film transistor of high-dielectric-coefficient grid medium layer, passes through the side of magnetron sputtering on PET flexible material substrate Formula is formed with tin indium oxide ITO bottom gate thin film and barium zirconium phthalate BZT gate dielectric film, and BZT gate dielectric layer top is one layer of monocrystalline The source of silicon thin film, this layer of monocrystalline silicon thin film is the silicon thin film of SOI, so-called SOI, be middle layer be silica SiO2, up and down Layer is the three-decker of silicon, forms doped region pattern by carrying out photoetching process in the top layer silicon of SOI, by ion implanting and The technique of annealing forms doped region at two, then forms square hole by way of photoetching and reactive ion etching RIE in top layer silicon Layer, carries out wet etching in hydrofluoric acid, removes intermediate SiO2, finally by photoetching and the mode of vacuum electron beam vapor deposition Doped region is respectively formed with source-drain electrode at two.
The flexible thin-film transistor manufacturing method of high-dielectric-coefficient grid medium layer, steps are as follows:
A, it selects PET flexible material as substrate, puts PET into the beaker for filling acetone soln first, then super It is cleaned 5 minutes in sound wave washer, it then will in ultrasonic cleaner by the PET cleaned with acetone using aqueous isopropanol Acetone cleans up, and obtains more clean substrate.
B, 200nm thickness ito film and 100nm thickness BZT bottom dielectric grid layer film are plated on PET substrate using magnetron sputtering.
C, SOI material is selected, is cleaned in ultrasonic cleaner using acetone, acetone is then cleaned using isopropanol Residue dries up SOI.
D, 1813 positive photo glues are coated on the surface SOI, and uses sol evenning machine, setting revolving speed is 4000rpm, rotation time For 30s, photoresist is got rid of uniformly, then carries out being lithographically formed specific doped region using litho machine and the mask plate made Pattern then carries out N-type injection by the way of ion implanting, and parameter is that Implantation Energy is 40Kev, dosage 4*1015cm- 2, it generates source and drain doped region and after rapid thermal annealing 10s, photoetching is removed in acetone soln under the conditions of 750 DEG C of temperature Glue.
E, according to label ready-made on mask plate, by the square hole of spacing 5um arrangement in source and drain doping area and mask plate Layer carries out alignment photoetching, the small aperture layer of square of spacing 5um arrangement is formed after development on SOI, then using ion etching Mode removes the silicon on square aperture.
F, in the hydrofluoric acid of 3:1 (HF) solution, ready-made SOI before being put into, buried oxide layer after two hours on SOI will be by Corrosion is clean, and subsequent silicon nanometer film layer will fall off, and silicon nanometer film layer is transferred to the flexibility for having plated ITO and gate dielectric layer On PET substrate, drying.
G, the gluing in the silicon nanometer film being transferred on PET is directed at photoetching, forms the photoengraving pattern of source-drain electrode, uses The mode of vacuum electron beam vapor deposition forms the metal source and drain electrodes layer of 100nm, and after removing photoresist, the preparation of device is completed.
The features of the present invention and beneficial effect are:
Device in the present invention has higher integrated level, has and is more widely applied.In addition, the present invention is integrated in plastics Transistor device on substrate still can satisfy the normal work of device when plastic supporting base bending, can wear intelligently It wears, artificial skin, biologic medical, photoelectric device etc. acquirement are more widely applied.
Detailed description of the invention:
Attached drawing 1 is the sectional view of flexible bottom gate high dielectric constant film transistor.
Attached drawing 2 is the working principle diagram of invention, and meaning representated by each section region is made that mark in figure in figure Note.
Specific embodiment
It is an object of the invention to design and prepare a kind of bottom of high-dielectric-coefficient grid medium layer based on flexible PET substrate Grid structure transistor is designed in relatively simple technique and is prepared underdriven soft using the low temperature process of magnetron sputtering Property thin film transistor (TFT), extreme enrichment use of the transistor as circuit components, so that the flexible device is in large-scale integrated The application of circuit and photoelectric device provides possibility.
Technical program of the present invention lies in ITO bottom gate thin film and BZT are formed on PET substrate using magnetron sputtering technique Gate dielectric film then forms doped region in such a way that photoetching process forms doped region pattern and ion implanting on SOI, adopts Square hole layer is formed with the mode of photoetching and ion etching, silicon nanometer film layer is formed by the way of wet process HF etching, by turning Silicon nano thin-film is transferred on PET substrate by shifting technology, forms source finally by the mode that photoetching and vacuum electron beam are deposited Drain electrode, this completes the preparations of transistor.
The main operational principle of the flexibility bottom gate high-dielectric-coefficient grid medium layer film transistor is by bottom gate electricity It is biased on extremely, will form electron inversion floor in place of gate dielectric layer in source and drain doping area, as the conducting channel of device, Break-over of device, then adds bias between source-drain electrode, and whether device will start to work, be connected by grid voltage control device And electric current between the source and drain of device, in addition, flexible substrate can reduce the ghost effect of traditional silicon substrate substrate transistor, and can To work under different bending degree, be high-performance flexible circuit large-scale integrated and wearable electronic it is extensive Using providing possibility.
Apply certain bias in ITO bottom gate thin film, when the voltage of application is smaller or no-bias, silicon nano thin-film Since the generation of not no inversion layer will not generate electric current even if adding voltage between source and drain between source and drain, device closes layer It is disconnected.When voltage is sufficiently large, silicon nanometer thin film layer will generate electron inversion layer, script crystal at the surface contacted with grid oxide layer Surface transoid of the electron number greater than hole number will generated at gate dielectric layer surface by managing hollow more silicon nano thin-film of living in caves Area, this region are referred to as the channel region of device, then, are biased in the source-drain electrode of n-type doping, can generate the electricity between source and drain Stream, break-over of device.Device in the present invention has higher integrated level, has and is more widely applied.In addition, the present invention is integrated in Transistor device in plastic supporting base still can satisfy the normal work of device when plastic supporting base bending, can be in intelligence Wearing, artificial skin, biologic medical, photoelectric device etc. acquirement are more widely applied.
Specific manufacture craft is as follows:
A, it selects PET flexible material as substrate, puts PET into the beaker for filling acetone soln first, then super It is cleaned 5 minutes in sound wave washer, it then will in ultrasonic cleaner by the PET cleaned with acetone using aqueous isopropanol Acetone cleans up, and obtains more clean substrate.
B, 200nm thickness ito film and 100nm thickness BZT bottom dielectric grid layer film are plated on PET substrate using magnetron sputtering.
C, SOI material is selected, is cleaned in ultrasonic cleaner using acetone, acetone is then cleaned using isopropanol Residue dries up SOI.
D, 1813 positive photo glues are coated on the surface SOI, and uses sol evenning machine, setting revolving speed is 4000rpm, rotation time For 30s, photoresist is got rid of uniformly, then carries out being lithographically formed specific doped region using litho machine and the mask plate made Pattern then carries out N-type injection by the way of ion implanting, and parameter is that Implantation Energy is 40Kev, dosage 4*1015cm- 2, it generates source and drain doped region and after rapid thermal annealing 10s, photoetching is removed in acetone soln under the conditions of 750 DEG C of temperature Glue.
E, according to label ready-made on mask plate, by the square hole of spacing 5um arrangement in source and drain doping area and mask plate Layer carries out alignment photoetching, the small aperture layer of square of spacing 5um arrangement is formed after development on SOI, then using ion etching Mode removes the silicon on square aperture.
F, in the hydrofluoric acid of 3:1 (HF) solution, ready-made SOI before classical prescription aperture layer is put into, burying on SOI after two hours Oxygen layer will be corroded completely, and subsequent silicon nanometer film layer will fall off, and silicon nanometer film layer is transferred to and has plated ITO and gate dielectric layer Flexible PET substrate on, drying.
G, the gluing in the silicon nanometer film being transferred on PET is directed at photoetching, forms the photoengraving pattern of source-drain electrode, uses The mode of vacuum electron beam vapor deposition forms the metal source and drain electrodes layer of 100nm, and after removing photoresist, the preparation of device is completed.

Claims (2)

1. a kind of flexible thin-film transistor of high-dielectric-coefficient grid medium layer, characterized in that pass through magnetic on PET flexible material substrate The mode of control sputtering is formed with tin indium oxide ITO bottom gate thin film and barium zirconium phthalate BZT gate dielectric film, BZT gate dielectric layer top One layer of monocrystalline silicon thin film, the source of this layer of monocrystalline silicon thin film is the silicon thin film of SOI, so-called SOI, be middle layer be silica SiO2, upper and lower level is the three-decker of silicon, forms doped region pattern by carrying out photoetching process in the top layer silicon of SOI, passes through Ion implanting and the technique of annealing form doped region at two, then pass through the side of photoetching and reactive ion etching RIE in top layer silicon Formula forms square hole layer, and wet etching is carried out in hydrofluoric acid, removes intermediate SiO2, finally by photoetching and vacuum electron beam The mode of vapor deposition doped region at two is respectively formed with source-drain electrode.
2. a kind of flexible thin-film transistor manufacturing method of high-dielectric-coefficient grid medium layer, characterized in that steps are as follows:
A, it selects PET flexible material as substrate, puts PET into the beaker for filling acetone soln first, then in ultrasonic wave Cleaned 5 minutes in washer, then using aqueous isopropanol by the PET cleaned with acetone in ultrasonic cleaner by acetone It cleans up, obtains more clean substrate.
B, 200nm thickness ito film and 100nm thickness BZT bottom dielectric grid layer film are plated on PET substrate using magnetron sputtering.
C, SOI material is selected, is cleaned in ultrasonic cleaner using acetone, acetone residue is then cleaned using isopropanol Object dries up SOI.
D, 1813 positive photo glues are coated on the surface SOI, and uses sol evenning machine, setting revolving speed is 4000rpm, and rotation time is 30s gets rid of photoresist uniformly, then carries out being lithographically formed specific doped region figure using litho machine and the mask plate made Case then carries out N-type injection by the way of ion implanting, and it is 40Kev, dosage 4*1015cm-2 that parameter, which is Implantation Energy, It generates source and drain doped region and after rapid thermal annealing 10s, photoresist is removed in acetone soln under the conditions of 750 DEG C of temperature.
E, according to label ready-made on mask plate, by the square aperture layer of spacing 5um arrangement in source and drain doping area and mask plate into Row alignment photoetching forms the small aperture layer of square of spacing 5um arrangement, then by the way of ion etching on SOI after development By the silicon removal on square aperture.
F, in the hydrofluoric acid HF solution of 3:1, ready-made SOI before being put into, the buried oxide layer after two hours on SOI will be corroded dry Only, subsequent silicon nanometer film layer will fall off, and silicon nanometer film layer is transferred to the flexible PET substrate for having plated ITO and gate dielectric layer On, drying.
G, the gluing in the silicon nanometer film being transferred on PET is directed at photoetching, the photoengraving pattern of source-drain electrode is formed, using vacuum The mode of electron beam evaporation plating forms the metal source and drain electrodes layer of 100nm, and after removing photoresist, the preparation of device is completed.
CN201811621372.0A 2018-12-28 2018-12-28 The flexible thin-film transistor and its manufacturing method of high-dielectric-coefficient grid medium layer Pending CN109698241A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110459605A (en) * 2019-07-29 2019-11-15 天津大学 The heterogeneous gate dielectric layer flexible silicon thin film transistor (TFT) of multilayer material and its manufacturing method
CN110620155A (en) * 2019-09-24 2019-12-27 天津大学 Heterogeneous gate dielectric layer flexible silicon thin film transistor and manufacturing method thereof
CN111029402A (en) * 2019-11-14 2020-04-17 天津大学 Flexible bottom gate thin film transistor of zirconium-titanium oxide gate dielectric layer and manufacturing method thereof
CN111029341A (en) * 2019-11-14 2020-04-17 天津大学 Flexible bottom gate flash memory device with calcium copper titanate gate dielectric layer and manufacturing method thereof
CN111081536A (en) * 2019-11-05 2020-04-28 天津大学 Method for manufacturing passive radio frequency device machine
GB2589415A (en) * 2019-07-31 2021-06-02 Univ Northwestern Polytechnical An in-plane displacement sensing unit based on a simplified optical nanometer scale resonant cavity
CN114078974A (en) * 2020-08-21 2022-02-22 天津大学 SiO growth by high temperature2Preparation method of silicon nano flexible thin film transistor of gate dielectric layer

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CN1694278A (en) * 2004-04-29 2005-11-09 三星Sdi株式会社 Organic thin film transistor including organic acceptor film
US20100283054A1 (en) * 2008-08-04 2010-11-11 Koichi Hirano Flexible semiconductor device and method for manufacturing same
CN108689702A (en) * 2018-05-08 2018-10-23 天津大学 A kind of high-k low-loss barium zirconium phthalate dielectric material and preparation method thereof
CN108831929A (en) * 2018-05-04 2018-11-16 天津大学 Silicon nanometer film flexible flat grid single-groove road thin film transistor (TFT) and manufacturing method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1694278A (en) * 2004-04-29 2005-11-09 三星Sdi株式会社 Organic thin film transistor including organic acceptor film
US20100283054A1 (en) * 2008-08-04 2010-11-11 Koichi Hirano Flexible semiconductor device and method for manufacturing same
CN108831929A (en) * 2018-05-04 2018-11-16 天津大学 Silicon nanometer film flexible flat grid single-groove road thin film transistor (TFT) and manufacturing method
CN108689702A (en) * 2018-05-08 2018-10-23 天津大学 A kind of high-k low-loss barium zirconium phthalate dielectric material and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110459605A (en) * 2019-07-29 2019-11-15 天津大学 The heterogeneous gate dielectric layer flexible silicon thin film transistor (TFT) of multilayer material and its manufacturing method
GB2589415A (en) * 2019-07-31 2021-06-02 Univ Northwestern Polytechnical An in-plane displacement sensing unit based on a simplified optical nanometer scale resonant cavity
GB2589415B (en) * 2019-07-31 2022-05-04 Univ Northwestern Polytechnical An in-plane displacement sensing unit based on a simplified optical nanometer scale resonant cavity
CN110620155A (en) * 2019-09-24 2019-12-27 天津大学 Heterogeneous gate dielectric layer flexible silicon thin film transistor and manufacturing method thereof
CN111081536A (en) * 2019-11-05 2020-04-28 天津大学 Method for manufacturing passive radio frequency device machine
CN111029402A (en) * 2019-11-14 2020-04-17 天津大学 Flexible bottom gate thin film transistor of zirconium-titanium oxide gate dielectric layer and manufacturing method thereof
CN111029341A (en) * 2019-11-14 2020-04-17 天津大学 Flexible bottom gate flash memory device with calcium copper titanate gate dielectric layer and manufacturing method thereof
CN111029341B (en) * 2019-11-14 2023-12-12 天津大学 Copper calcium titanate gate dielectric layer flexible bottom gate flash memory device and manufacturing method thereof
CN114078974A (en) * 2020-08-21 2022-02-22 天津大学 SiO growth by high temperature2Preparation method of silicon nano flexible thin film transistor of gate dielectric layer
CN114078974B (en) * 2020-08-21 2023-09-26 天津大学 SiO growth at high temperature 2 Preparation method of silicon nanometer flexible thin film transistor with gate dielectric layer

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