CN109652166A - A kind of volatility drawing oil free of cleaning and preparation method thereof - Google Patents
A kind of volatility drawing oil free of cleaning and preparation method thereof Download PDFInfo
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- CN109652166A CN109652166A CN201811530559.XA CN201811530559A CN109652166A CN 109652166 A CN109652166 A CN 109652166A CN 201811530559 A CN201811530559 A CN 201811530559A CN 109652166 A CN109652166 A CN 109652166A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/56—Boundary lubrication or thin film lubrication
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
Abstract
The present invention relates to the punching drawing oil fields of sheet metal, provide a kind of volatility drawing oil free of cleaning, and component includes at least: low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate, esters containing amino carboxylic acid, borate, release agent；The preparation method of volatility drawing oil free of cleaning is additionally provided, step includes at least: first borate and cyclodextrin being added in container and are stirred blending；It adds low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate, esters containing amino carboxylic acid, release agent and continues stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Description
Technical field
The present invention relates to the punching drawing oil field of sheet metal, a kind of volatility drawing oil free of cleaning and its system are further related to
Preparation Method.
Background technique
Traditional drawing oil mainly has mineral oil, volatile oil, boronation soap base dry film, soap base compound etc., with
The disadvantage of the raising of stainless steel stretched requirement, conventional lubrication oil is gradually exposed.If mineral oil difficulty mixes, containing harmful and
Inflammable constituent, it is difficult to cleaning and directly welding；Volatile oil is inflammable, toxic, small to tool protective effect, increases in workshop
The content of VOC；Boronation soap base dry film can generate deposit on mold, borax particle be generated at punching press, in wet environment meeting
Softening becomes sticky；And then there is soap base compound punching press position to be also easy to produce bonding phenomenon, cause to corrode to soft metal, and when cleaning
The shortcomings that generating foam.
Borate is a kind of excellent lubricating oil extreme-pressure wear-resistant agent, but borate is slightly soluble in water, is not suitable for contact water
Equipment, therefore which also limits the uses of borate family extreme pressure anti-wear additives.Therefore need to invent a kind of excellent combination property
Drawing oil, not only oil product has extraordinary lubricant effect, also has self-cleaning function, can exempt processing later period needs to gold
The cleaning of metal work-pieces or generation residual are caused to workpiece damage and service performance, and nontoxic and fire-fighting etc. does not have
There is security risk, the processing of various equipment can also be widely used in.
Summary of the invention
In order to solve the above-mentioned technical problem, the first aspect of the invention provides a kind of volatility drawing oil free of cleaning,
Component includes at least: low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate, esters containing amino carboxylic acid, borate, demoulding
Agent.
As a kind of perferred technical scheme, heretofore described esters containing amino carboxylic acid and the weight ratio of borate are
1:(0.1-0.8)。
As a kind of perferred technical scheme, heretofore described esters containing amino carboxylic acid and the weight ratio of borate are
1:(0.2-0.6)。
As a kind of perferred technical scheme, heretofore described esters containing amino carboxylic acid are selected from 3- amino -2- thiophene first
Sour methyl esters, 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester, ethyl 1- [(methoxycarbonyl group) amino] cyclobutane-carboxylic acid ester, 5-
Aminooimidazole simultaneously (1,2-a) pyridine-2-carboxylic acids ethyl ester, methyl 4- (aminosulfonylamino) -3- thiophene carboxylate, ethyl 5-
(ethylamino) -2- methyl-1,3- oxazole -4- carboxylate, methyl 2- amino -4- quinazoline carboxylate, ethyl 2- amino -1,3-
Benzothiazole -5- carboxylate, butyl 5- amino -1,3- thiazole -2- carboxylate, methyl 1- (methylcarbamoyl) -2- aziridine
Carboxylate, thiazolamine -5- carboxylic acid, ethyl ester, 5- aminooimidazole simultaneously one of (1,2-a) pyridine-2-carboxylic acids ethyl ester or a variety of
Combination.
As a kind of perferred technical scheme, heretofore described borate is selected from kodalk, potassium metaborate, three boric acid
One of potassium, boric acid cerium, lanthanum borate, antifungin, aluminium borate or a variety of combinations.
As a kind of perferred technical scheme, heretofore described borate is nano boric acid salt；The nano boric acid salt
Partial size be 30-120nm.
As a kind of perferred technical scheme, component further includes cyclodextrin in the present invention.
As a kind of perferred technical scheme, the weight ratio of heretofore described borate and cyclodextrin is 1:(0.5-2).
As a kind of perferred technical scheme, heretofore described cyclodextrin is beta-cyclodextrin and/or gamma-cyclodextrin.
The second aspect of the invention provides the preparation method of the drawing oil free of cleaning of volatility described in one kind, and step is extremely
It less include: that first borate and cyclodextrin are added in container to be stirred blending；It is poly- to add low aromatic solvent naphtha, alkyl phenol
Ethylene oxide ether phosphate, esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, and it is free of cleaning to finally obtain volatility
Drawing oil.
The utility model has the advantages that heretofore described volatility drawing oil free of cleaning has the excellent effect of following three aspects:
First, the present invention in drawing oil can be after process finished piece(s), oil product has excellent volatile performance, can remove from clearly
The step of washing, and the gas volatilized is nontoxic, will not damage to environmental and human health impacts, safety and environmental protection.
Second, drawing oil in the present invention, in process, by very excellent lubrication effect can be shown after punching press
Fruit guarantees that the lubricating oil film of metal surface is not destroyed, will not generate boundary lubrication, has high resistance to pressure, not only improves
Work pieces process efficiency can also be widely used in various unmanageable metal products；
Third, the present invention in select borate do extreme-pressure anti-wear oil, the drawing oil water resistant stability of preparation is excellent, in oil
After product volatilization, a kind of protective film will form in metal surface, there is extraordinary adhesive force to metal surface, can be adapted for wet
The metal product for spending big environment or contact water, can protect metal surface will not generate foreign matter and be corroded by the external world, open up
Wide application range of the drawing oil in the field of metal processing.
Content and other features, aspects and advantages above-mentioned in the application are easier to understand with reference to following details.
Specific embodiment
Unless otherwise indicated, from context cues or belong to the convention of the prior art, otherwise number all in the application
It is all based on weight with percentage, and test and characterizing method used is all synchronous with the submission date of the application.If existing
There is defining for the concrete term disclosed in technology inconsistent with any definition provided herein, then with provided herein
Subject to term definition.
It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment
Description, not to the limitation of its protection scope.
Word " preferred ", " preferably ", " preferred " in the present invention etc. refer to, can provide certain in some cases
The embodiment of the present invention of a little beneficial effects.However, other embodiments may also under identical circumstances or in the case of other
It is preferred.In addition, not implying that other embodiments are unavailable to the statement of one or more preferred embodiments, it is not yet
It is intended to exclude other embodiments except the scope of the present invention.
First aspect in the present invention provides a kind of volatility drawing oil free of cleaning, and component includes at least: low aromatic hydrocarbons
Solvent naphtha, alkyl phenol polyoxyethylene ether phosphate, esters containing amino carboxylic acid, borate, release agent.
In some preferred embodiments, heretofore described volatility drawing oil free of cleaning, by weight, component
Include at least: 60-100 parts of low aromatic solvent naphthas, 0.5-3 parts of alkyl phenol polyoxyethylene ether phosphates, 2-5 parts contain aminocarboxylic acid ester
Class, 0.2-4 parts of borates, 0.5-1.5 parts of release agents.
In some preferred embodiments, heretofore described volatility drawing oil free of cleaning, by weight, group
Divide and include at least: 70-90 parts of low aromatic solvent naphthas, 1-2 parts of alkyl phenol polyoxyethylene ether phosphates, 3-4 parts contain aminocarboxylic acid ester
Class, 0.6-2.5 parts of borates, 0.8-1.3 parts of release agents.
In some highly preferred embodiments, heretofore described volatility drawing oil free of cleaning, by weight,
Component includes at least: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl phenol polyoxyethylene ether phosphates, and 3.5 parts contain aminocarboxylic acid ester
Class, 1.4 parts of borates, 1.1 parts of release agents.
Low aromatic solvent naphtha
In some embodiments, heretofore described low aromatic solvent naphtha be selected from SHD25, SHD30, SHD40, SHD65,
One of SHD80, SHD100, SH-2731 or a variety of combinations；Preferably, the low aromatic solvent naphtha be selected from SHD40,
One of SHD65, SHD80, SH-2731 or a variety of combinations；It is furthermore preferred that the low aromatic solvent naphtha is SHD40.
Esters containing amino carboxylic acid
In some embodiments, heretofore described esters containing amino carboxylic acid and the weight ratio of borate are 1:
(0.1-0.8)；Preferably, the esters containing amino carboxylic acid and the weight ratio of borate are 1:(0.2-0.6)；It is furthermore preferred that
The esters containing amino carboxylic acid and the weight ratio of borate are 1:0.4.
In some embodiments, heretofore described esters containing amino carboxylic acid be selected from 3- amino -2- thiophenecarboxylate,
2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester, ethyl 1- [(methoxycarbonyl group) amino] cyclobutane-carboxylic acid ester, 5- amino miaow
Azoles simultaneously (1,2-a) pyridine-2-carboxylic acids ethyl ester, methyl 4- (aminosulfonylamino) -3- thiophene carboxylate, ethyl 5- (ethyl ammonia
Base) -2- methyl-1,3- oxazole -4- carboxylate, methyl 2- amino -4- quinazoline carboxylate, ethyl 2- amino -1,3- benzo thiophene
Azoles -5- carboxylate, butyl 5- amino -1,3- thiazole -2- carboxylate, methyl 1- (methylcarbamoyl) -2- aziridine carboxylate,
Simultaneously one of (1,2-a) pyridine-2-carboxylic acids ethyl ester or a variety of combinations of thiazolamine -5- carboxylic acid, ethyl ester, 5- aminooimidazole；
Preferably, esters containing amino carboxylic acid are selected from butyl 5- amino -1,3-thiazoles -2- carboxylate, ethyl 1- [(methoxycarbonyl group) amino]
One of cyclobutane-carboxylic acid ester, thiazolamine -5- carboxylic acid, ethyl ester, ethyl 2- amino -1,3- benzothiazole -5- carboxylate or
A variety of combinations；It is furthermore preferred that esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylate.
Borate
In some embodiments, heretofore described borate is selected from kodalk, potassium metaborate, three potassium borates, boron
One of sour cerium, lanthanum borate, antifungin, aluminium borate or a variety of combinations；Preferably, the borate be selected from kodalk,
One of potassium metaborate, three potassium borates, boric acid cerium, lanthanum borate or a variety of combinations；It is furthermore preferred that the borate is selected from partially
One or more combinations of Boratex, potassium metaborate, three potassium borates；Highly preferred, the borate is potassium metaborate.
In some embodiments, heretofore described borate is nano boric acid salt；The partial size of the nano boric acid salt
For 30-120nm；Preferably, the partial size of the nano boric acid salt is 40-100nm；It is furthermore preferred that the grain of the nano boric acid salt
Diameter is 50-90nm；Highly preferred, the partial size of the nano boric acid salt is 60nm.
Heretofore described nano boric acid salt the preparation method comprises the following steps: the aqueous solution of boric acid and metal salt be added to be mixed with it is steady
Determine in the hexamethylene of agent, form water-in-oil emulsion, using heating dehydration, filtering, can be prepared by nanoscale borate.
Cyclodextrin
In some embodiments, heretofore described volatility stretching oil ingredient free of cleaning further includes cyclodextrin.
In some embodiments, the weight ratio of heretofore described borate and cyclodextrin is 1:(0.5-2)；It is preferred that
, the weight ratio of the borate and cyclodextrin is 1:(1-1.5)；It is furthermore preferred that the weight ratio of the borate and cyclodextrin
For 1:1.3.
In some embodiments, heretofore described cyclodextrin is beta-cyclodextrin and/or gamma-cyclodextrin；Preferably, institute
Stating cyclodextrin is gamma-cyclodextrin.
Release agent
Release agent in the present invention there is no particular requirement that all release agents for the field of metal processing are all applied to this
Invention, including but not limited to oleamide.
The second aspect of the invention provides a kind of preparation method of volatility drawing oil free of cleaning, and step is at least
It include: that first borate and cyclodextrin are added in container to be stirred blending；Add low aromatic solvent naphtha, alkyl phenol polyoxy
Ethylene ether phosphate, esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing free of cleaning
Stretch oil.
In some preferred embodiments, the preparation method of volatility drawing oil free of cleaning, step include at least:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 80-150 DEG C, mixing time
30min-60min；
(2) after vessel temp restores to 40-70 DEG C, low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphoric acid are added
Ester, esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
In some preferred embodiments, the preparation method of the volatility drawing oil free of cleaning, step is at least wrapped
It includes:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 100-130 DEG C, when stirring
Between 40min-55min；
(2) after vessel temp restores to 50-60 DEG C, low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphoric acid are added
Ester, esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
In some highly preferred embodiments, the preparation method of the volatility drawing oil free of cleaning, step is at least
Include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Volatility drawing oil free of cleaning in the present invention, since the water resistant ability of borate is poor, meeting after water suction
Become water and crystalline state, especially nano boric acid salt is easier to reunite, to limit connecing for borate family drawing oil
The use in the equipment of water is touched, it is found by the applicant that the present invention selects borate to be used in compounding with cyclodextrin, so that drawing oil
Not only there is very excellent extreme boundary lubrication, can also solve the problems, such as that metaborate water resistant stability is poor, be applicable to connect
The equipment for touching water, especially potassium metaborate is put with gamma-cyclodextrin when being used together, and in process, can be showed by after punching press
Fabulous extreme boundary lubrication effect out, even if metal surface is subject to large compressive will not to generate boundary lubrication, and oil product is waved
After hair, in the protective film that metal surface will form, there is extraordinary adhesive force to metal surface, so that the metal product of processing
It not only can protect metal surface not precipitating foreign matter and do not corroded by the external world, could be applicable to the environment of contact water, thus it is speculated that can
Can the reason is that: for cyclodextrin when being compounded with potassium metaborate, cyclodextrin can generate certain protective effect to nanometer potassium metaborate,
So that metaboric acid avoid with water contact, during being subject to processing by punching press after, protected nanometer potassium metaborate can be released
It puts, forms one layer of extreme pressure film, shear strength enhancing, so that the lubricant effect of drawing oil is also increased in metal surface
By force.In addition, butyl 5- amino -1,3-thiazoles -2- carboxylic acid ester component in drawing oil can sprawl to form film in metal surface, and contain
There is cyclodextrin not only can improve butyl by the active force between alcoholic extract hydroxyl group and butyl 5- amino -1,3- thiazole -2- carboxylate
For 5- amino -1,3-thiazoles -2- carboxylate in the spreadability of metal surface, cyclodextrin and 5- amino -1,3-thiazoles -2- carboxylate are total
Protective layer can be formed to potassium metaborate extreme pressure film again with the film sprawled, can also continue in metal works after not by extreme pressure
Potassium metaborate is protected, ultimately forms compound tunic, and the thiazolyl group in 5- amino -1,3-thiazoles -2- carboxylate
There can be synergistic effect with potassium metaborate, enhance the corrosion-resistant and inoxidizability to metal, it has been found that work as amino -1 5-,
The dosage of 3- thiazole -2- carboxylate is greater than the dosage of potassium metaborate, can just reach more excellent water resistant effect.
This reaction is specifically described below by embodiment.Following embodiment is served only for doing furtherly the present invention
It is bright, it should not be understood as the limitation of the present invention, protection, professional and technical personnel in the field makes non-according to the content of foregoing invention
The modifications and adaptations of essence, still fall within protection scope of the present invention.
Embodiment 1
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:1.3, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 2
A kind of volatility drawing oil free of cleaning, by weight, component includes: 60 parts of low aromatic solvent naphthas, 0.5 part of alkyl
Phenol polyethenoxy ether phosphate, 2 parts of esters containing amino carboxylic acid, 0.2 part of borate, 0.5 part of release agent；
The low aromatic solvent naphtha is SHD80；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 30nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:0.5, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 80 DEG C, mixing time
30min；
(2) after vessel temp restores to 40 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 3
A kind of volatility drawing oil free of cleaning, by weight, component includes: 70 parts of low aromatic solvent naphthas, 1 part of alkyl phenol
Polyoxyethylene ether phosphate, 3 parts of esters containing amino carboxylic acid, 0.6 part of borate, 0.8 part of release agent；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 50nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:1, the cyclodextrin is beta-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 100 DEG C, mixing time
40min；
(2) after vessel temp restores to 50 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 4
A kind of volatility drawing oil free of cleaning, by weight, component includes: 90 parts of low aromatic solvent naphthas, 2 parts of alkyl phenols
Polyoxyethylene ether phosphate, 4 parts of esters containing amino carboxylic acid, 2.5 parts of borates, 1.3 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 90nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:1.5, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 130 DEG C, mixing time
55min；
(2) after vessel temp restores to 60 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 5
A kind of volatility drawing oil free of cleaning, by weight, component includes: 100 parts of low aromatic solvent naphthas, 3 parts of alkyl
Phenol polyethenoxy ether phosphate, 5 parts of esters containing amino carboxylic acid, 4 parts of borates, 1.5 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 120nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:2, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 150 DEG C, mixing time
60min；
(2) after vessel temp restores to 70 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 6
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are ethyl 1- [(methoxycarbonyl group) amino] ring
Butane carboxylic acid；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oil
Amide；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight of the borate and cyclodextrin
Than for 1:1.3, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 7
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer kodalk, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:1.3, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 8
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:1.3, the cyclodextrin is alpha-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 9
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is potassium metaborate；The release agent is oleamide；The drawing oil group free of cleaning of volatility described in the embodiment
Dividing further includes cyclodextrin, and the weight ratio of the borate and cyclodextrin is 1:1.3, and the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 10
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:0.1, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 11
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 3.5 parts of esters containing amino carboxylic acid, 1.4 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oleoyl
Amine；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Embodiment 12
A kind of volatility drawing oil free of cleaning, by weight, component includes: 80 parts of low aromatic solvent naphthas, 1.5 parts of alkyl
Phenol polyethenoxy ether phosphate, 1 part of esters containing amino carboxylic acid, 5 parts of borates, 1.1 parts of release agents；
The low aromatic solvent naphtha is SHD40；The esters containing amino carboxylic acid are butyl 5- amino -1,3-thiazoles -2- carboxylic
Acid esters；The borate is nanometer potassium metaborate, and the partial size of the nanometer potassium metaborate is 60nm；The release agent is oleoyl
Amine；The stretching oil ingredient free of cleaning of volatility described in the embodiment further includes cyclodextrin, the weight ratio of the borate and cyclodextrin
For 1:1.3, the cyclodextrin is gamma-cyclodextrin；
The preparation method of the volatility drawing oil free of cleaning, step include:
(1) first borate and cyclodextrin are added in container and are stirred blending, temperature is 120 DEG C, mixing time
50min；
(2) after vessel temp restores to 55 DEG C, add low aromatic solvent naphtha, alkyl phenol polyoxyethylene ether phosphate,
Esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility drawing oil free of cleaning.
Performance test
1, physicochemical property test result
It is tested for the property using drawing oil prepared by embodiment 1-12 as test object, kinematic viscosity uses GB/T-265
It is tested；Flash-point is tested using ASTM D-93；Corrosivity is tested using GB-5069；Test environment: temperature 20
DEG C, humidity 85%, place 48h after, test result is as shown in table 1:
Table 1
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention, all
The equivalent changes and modifications that content is done according to the present invention are encompassed by the scope of the patents of the invention.
Claims (10)
1. a kind of volatility drawing oil free of cleaning, which is characterized in that component includes at least: low aromatic solvent naphtha, alkyl phenol polyoxy
Ethylene ether phosphate, esters containing amino carboxylic acid, borate, release agent.
2. a kind of volatility drawing oil free of cleaning as described in claim 1, which is characterized in that the esters containing amino carboxylic acid with
The weight ratio of borate is 1:(0.1-0.8).
3. a kind of volatility drawing oil free of cleaning as claimed in claim 2, which is characterized in that the esters containing amino carboxylic acid with
The weight ratio of borate is 1:(0.2-0.6).
4. a kind of volatility drawing oil free of cleaning as described in claim 1, which is characterized in that the choosing of esters containing amino carboxylic acid
From 3- amino -2- thiophenecarboxylate, 2- amino -4- trifluoromethyl pyrimidine -5- carboxylic acid, ethyl ester, ethyl 1- [(methoxycarbonyl group) ammonia
Base] cyclobutane-carboxylic acid ester, 5- aminooimidazole simultaneously (1,2-a) pyridine-2-carboxylic acids ethyl ester, methyl 4- (aminosulfonylamino) -3-
Thiophene carboxylate, ethyl 5- (ethylamino) -2- methyl-1,3- oxazole -4- carboxylate, methyl 2- amino -4- quinazoline carboxylic acid
Ester, ethyl 2- amino -1,3- benzothiazole -5- carboxylate, butyl 5- amino -1,3- thiazole -2- carboxylate, methyl 1- (methyl
Carbamyl) -2- aziridine carboxylate, thiazolamine -5- carboxylic acid, ethyl ester, 5- aminooimidazole simultaneously (1,2-a) pyridine-2-carboxylic acids
One of ethyl ester or a variety of combinations.
5. a kind of volatility drawing oil free of cleaning as described in claim 1, which is characterized in that the borate is selected from metaboric acid
One of sodium, potassium metaborate, three potassium borates, boric acid cerium, lanthanum borate, antifungin, aluminium borate or a variety of combinations.
6. a kind of volatility drawing oil free of cleaning as claimed in claim 5, which is characterized in that the borate is nano boric acid
Salt；The partial size of the nano boric acid salt is 30-120nm.
7. a kind of volatility drawing oil free of cleaning as claimed in any one of claims 1 to 6, which is characterized in that the volatility is exempted from
It further includes cyclodextrin that cleaning, which stretches oil ingredient,.
8. a kind of volatility drawing oil free of cleaning as claimed in claim 7, which is characterized in that the borate and cyclodextrin
Weight ratio is 1:(0.5-2).
9. a kind of volatility drawing oil free of cleaning as claimed in claim 8, which is characterized in that the cyclodextrin is beta-cyclodextrin
And/or gamma-cyclodextrin.
10. a kind of preparation method of the volatility drawing oil free of cleaning as described in claim any one of 7-9, which is characterized in that step
Suddenly it includes at least: first borate and cyclodextrin being added in container and are stirred blending；Add low aromatic solvent naphtha, alkyl
Phenol polyethenoxy ether phosphate, esters containing amino carboxylic acid, release agent continue stirring to as clear as crystal shape, finally obtain volatility and exempt from
Clean drawing oil.
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