CN104017636A - Water soluble full-alloy metal grinding fluid - Google Patents
Water soluble full-alloy metal grinding fluid Download PDFInfo
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- CN104017636A CN104017636A CN201410251223.5A CN201410251223A CN104017636A CN 104017636 A CN104017636 A CN 104017636A CN 201410251223 A CN201410251223 A CN 201410251223A CN 104017636 A CN104017636 A CN 104017636A
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Abstract
The invention discloses a water soluble full-alloy metal grinding fluid which belongs to the technical field of metal grinding fluids. The metal grinding fluid is prepared from the following components in percentage by weight: 5-40wt% of an antirust agent, 1-20wt% of a cleaning agent, 0.1-10wt% of a lubricating corrosion inhibitor, 1-20wt% of a penetrant, 1-20wt% of a solubilizer, 10-40wt% of a PH adjustor, 0.5-5wt% of a defoamer and the balance of water. Based on the total weight of the water soluble full-alloy metal grinding fluid, the pH value of the water soluble full-alloy metal grinding fluid is 7-11. The lubricating corrosion inhibitor is long chain nitrogen heterocyclic ring organic ester. The water soluble full-alloy metal grinding fluid has excellent lubricating, rust-preventing, cleaning and cooling performances and can be widely applied to grinding of ferrous metals and nonferrous metals.
Description
Technical field
The invention belongs to metal grinding fluid technical field, be specifically related to the complete synthesis metal grinding fluid of a kind of environment-friendly water-soluble.
Background technology
Along with development and the progress of industrial technology, continuing to bring out of novel material, novel process, is the also more and more accurate and harshness of requirement of metal working fluid to metal working fluid of required consumption in the course of processing.In accurate and ultraprecise processing, select applicable metal working fluid, all most important for ensureing product processing quality, improve working (machining) efficiency and reducing environmental pollution.Oil exhaustion, energy dilemma and a day more serious ecological environmental pollution become people's significant problem urgently to be resolved hurrily, and the application of the water-soluble total synthesis metal processing liquid that this present situation is given oil-containing not in metal manufacture field proposed urgent requirement.
Thereby ground finish is the working method of utilizing emery wheel high speed rotating cutting workpiece, in the course of processing, produce and be out of shape in a large number and formed a large amount of new surface of friction, require grinding fluid to there is the characteristics such as good lubricated, cooling, cleaning, antirust and froth breaking, to extend the durability of emery wheel, the working accuracy of improving workpiece and surfaceness, raising working (machining) efficiency and quality product and to reduce energy consumption.
But oil base grinding fluid and oil-containing water-based milling liquid (comprising emulsion, microemulsion and complete synthesis liquid) relatively, the water-soluble complete synthesis metal grinding fluid of oil-containing is relative not good enough with performance on rustless property in lubricity, easily cause that workpiece surface roughness is large, processing rear surface is returned rapidly rust, thereby brought serious negative influence to later process.Therefore, having excellent water-soluble complete synthesis metal grinding fluid lubricated and rust-preventing characteristic still needs further to develop and improve.
Summary of the invention
Object of the present invention is intended at least solve the shortcoming existing in prior art, proposes a kind of have excellent lubricated, cooling, cleaning, antirust and antifoam performance, the not complete synthesis metal grinding fluid of the environment-friendly water-soluble of oil-containing.
For achieving the above object, technical scheme provided by the invention is as follows:
A kind of water-soluble complete synthesis metal grinding fluid, is made up of following component:
The rust-preventive agent of 5～40 % by weight, preferably 10～35 % by weight;
The clean-out system of 1～20 % by weight, preferably 10～20 % by weight;
The lubricated inhibiter of 0.1～10 % by weight, preferably 0.5～4 % by weight;
The permeate agent of 1～20 % by weight, preferably 1～15 % by weight;
The solubilizing agent of 1～20 % by weight, preferably 1～15 % by weight;
The pH adjusting agent of 10～40 % by weight, preferably 20～35 % by weight;
The defoamer of 0.5～5 % by weight, preferably 1～4 % by weight;
Excess water; In water-soluble complete synthesis metal grinding fluid gross weight; Wherein, the pH value of described water-soluble complete synthesis metal grinding fluid is 7～11, preferably 8-10.
Described lubricated inhibiter is more than one in long-chain benzotriazole carboxylic acid alkane ester, and the structural formula of described long-chain benzotriazole carboxylic acid alkane ester is as follows:
Wherein R is C
12-C
18chain alkyl.
The preparation method of described long-chain benzotriazole carboxylic acid alkane ester is as follows:
(1) in there-necked flask, add 0.01～0.2mol benzotriazole carboxylic acid, 10～150mL SOCl
2and 1～15mL DMF, reflux 1～5 hour;
(2) cooling, add 15～250mL sherwood oil, separate out benzotriazole carboxyl acyl chloride, filter;
(3) in another there-necked flask, add water and the 0.01～0.2mol alkyl alcohol of 2～40g sodium hydroxide, 15～300mL, be placed in frozen water, under agitation condition, benzotriazole carboxyl acyl chloride is added in reaction solution in batches, react 5～10 hours;
(4) reaction solution is poured in 25～500mL water, separated out solid and be benzotriazole carboxylic acid alkane ester, filter.
Described in step (3), alkyl alcohol is selected from more than one in lauryl alcohol, tridecanol, isomerous tridecanol, tetradecyl alcohol, pentadecanol, hexadecanol, heptadecyl alcohol, stearyl alcohol.Be preferably lauryl alcohol and/or stearyl alcohol.
Described rust-preventive agent is selected from sodium carbonate, volatile salt, sodium phosphate, Sodium phosphate dibasic, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, water glass, Sodium Tetraborate, Sodium chromate, potassiumchromate, sodium dichromate 99, potassium bichromate, Sodium orthomolybdate, sodium wolframate, potassium permanganate, sodium acetate, Sodium Benzoate, Sunmorl N 60S, Phenylethanolamine, urotropine, ammoniacal liquor, thanomin, diethanolamine, trolamine, α-amino isopropyl alcohol, cetylamine, oleic acid alkanolamine ester, oleic acid alkylolamide, sodium soap, fatty acid amine ester, phytic acid, sebacic acid, DC11, SL-AH, tridecanyldicarboxylic acid, organic ternary poly carboxylic acid, poly-epoxy succinic acid, sorbitan monooleate, pentaerythritol ester, alcohol ether phosphate, thiophosphatephosphorothioate, benzotriazole, benzotriazole sodium, methyl benzotriazazole, methyl benzotriazazole sodium, butyl benzotriazole, butyl benzotriazole sodium, mercapto benzothiazole, mercaptobenzimidazole, amino triazole, hydroxyquinoline, indoles, morpholine, N, N-dicyclohexyl acrylamide, tetrahydroglyoxaline, thionamic acid, sodium lignosulfonate, sodium methyl silicate, vinyl water glass, γ-amine propyl group water glass, the organic sodium disilicate of polyethers, more than one in poly aspartic acid, preferably more than one in oleic acid alkanolamine ester, phytic acid, sebacic acid, organic ternary poly carboxylic acid, alcohol ether phosphate, benzotriazole.
Described clean-out system is selected from sodium carbonate, sodium phosphate, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, citric acid, EDTA and sodium salt thereof, formic acid, amino acid, oxyacetic acid, oxalic acid, thionamic acid, oxyacetic acid, fatty acid sodium soap, Viscotrol C soda soap, triethanolamine oleate, rosined soap, sodium laurylsulfonate, Witco 1298 Soft Acid, Sodium dodecylbenzene sulfonate, petroleum sodium sulfonate, sodium lauryl sulphate, sulfated castor oil, sulfation peanut oil, sulfation tallow, Dodecyl trimethyl ammonium chloride, Varion CDG-K, alcohol ether carboxylate, alkyl phenol ether carboxylate salt, phosphate ester salt, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, more than one in alkylolamide, be preferably more than one in fatty acid sodium soap, sodium lauryl sulphate, sulfated castor oil, fatty alcohol-polyoxyethylene ether, alkylolamide.
Described permeate agent is selected from more than one in sulfated castor oil, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfuric ester sodium, Seconary Alkane Sulphonate Sodium, secondary alkyl sulphate sodium, α-sodium olefin sulfonate, sodium alkyl naphthalene sulfonate, succsinic acid alkyl ester sodium sulfonate, N-methyl oleoyl amino-ethyl sodium sulfonate, thionamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyethers, phosphoric acid ester, small molecular alcohol, small molecules ketone or small molecules ether; Be preferably more than one in phosphoric acid ester, small molecular alcohol, polyethers; Described small molecular alcohol, small molecules ketone or small molecules ether are no more than 8 carbon atoms.
Described solubilizing agent is selected from methyl alcohol, ethanol, propyl alcohol, propyl carbinol, ethylene glycol, propylene glycol, glycerol, acetone, cyclopropanone, glycol ether, propylene glycol, polyoxyethylene glycol, dibutyl phthalate, sorbitan fatty acid ester, Polyoxyethylene Sorbitol Fatty Acid Esters, sucrose fatty ester, laurin, pentaerythritol tetrapalmitate, methyl glucoside dodecyl ester, N-dodecyl glucosyl group laurylamide, alkyl glycoside, DoJyoxyethylene xylitol stearate, polyethers, more than one in cellulose family, be preferably more than one in ethanol, glycerol, polyoxyethylene glycol, polyethers.
Described pH adjusting agent is selected from more than one in sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, Mono Chloro Acetic Acid, propanedioic acid, sodium hydroxide, potassium hydroxide, ammoniacal liquor, thanomin, diethanolamine, trolamine, α-amino isopropyl alcohol, aminopropanol, diisopropanolamine (DIPA), quadrol, tetramethylphosphonihydroxide hydroxide base amine, hydroxide tetraethyl-amine, hydroxide tetrapropyl amine, choline, piperidines, piperazine, polyethylene imines, sodium carbonate, salt of wormwood, sodium phosphate, potassiumphosphate, Sodium phosphate dibasic, ammonium hydrogen phosphate.Be preferably more than one in trolamine, phosphoric acid, ammonium hydrogen phosphate, sodium hydroxide, potassium hydroxide.
Described defoamer is selected from more than one in silicone emulsion, dimethyl silicone oil, oleic acid chromium, vegetables oil, polysiloxane, polyethers, polyether siloxane copolymers, ethanol, higher alcohols, the fatty acid ester compounded thing of higher alcohols, phenylethyl alcohol oleic acid ester, toluylic acid bay alcohol ester, tributyl phosphate, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxypropylene.Be preferably more than one in polyethers, polyether siloxane copolymers, the fatty acid ester compounded thing of higher alcohols.
Described water-soluble complete synthesis metal grinding fluid adopts deionized water or tap water to be diluted to mass concentration while use be 5～20% dilution working fluid, and pH value is controlled at 7.5～9.5.
Water-soluble complete synthesis metal grinding fluid novelty provided by the present invention and advantage are as follows:
1, in order to promote the not lubricity of the water-soluble complete synthesis metal grinding fluid of oil-containing, and provide inhibition and absorption property to metallic surface, and the present invention has synthesized long-chain nitrogen heterocyclic ring organic ester voluntarily---and benzotriazole carboxylic acid alkane ester (C12～C18) is as lubricated inhibiter.Utilize benzotriazole end to carry out the absorption inhibition on metal (comprising steel, copper, aluminium, cast iron etc.) surface, utilize chain alkyl end to form hydrodynamic lubrication film and realize lubricity, and the lubricant film that the existence of benzotriazole absorption end forms chain alkyl end adsorbs more firmly in metallic surface, thereby make the lubricity of benzotriazole carboxylic acid alkane ester there is better stability and wear resistance.
2, water-soluble complete synthesis metal grinding fluid provided by the present invention uses the composite antirust agent that comprises polymorphic type component, and the metals such as steel, copper, aluminium, cast iron are all had to good rustless property, can be widely used in the ground finish of ferrous metal and non-ferrous metal.
3, water-soluble complete synthesis metal grinding fluid provided by the present invention is composite permeate agent, clean-out system, solubilizing agent and defoamer, in the course of processing, there is good lubricated, cleaning function, non-foaming, iron filings settleability is good, workpiece surface roughness after processing is low, without organic substance residues, place and do not return for a long time rust, can well meet the processing request of high-precision machine tool.
4, water-soluble complete synthesis metal grinding fluid provided by the present invention is the concentrated stoste of metal working fluid that water content is low, and system compatible stability is good, and the placement life-span is long, when use, adopt deionized water or tap water dilution, technique is simple, cheap, and it is not smelly to be stale-proof, long service life.
The aspect that the present invention is additional and advantage in the following description part provide, and part will become obviously from the following description, or recognize by practice of the present invention.
Brief description of the drawings
Fig. 1 has shown the lubricity comparison (experimental installation: Optimal SRV-4 multifunction friction wear testing machine) of control group and experimental group in embodiment 2.
Embodiment
Below will by subordinate list and specific embodiment, the present invention is described further.
The water-soluble complete synthesis metal grinding fluid of embodiment 1 concentrates stoste proportioning example
long-chain nitrogen heterocyclic ring organic ester in the present invention (long-chain benzotriazole carboxylic acid alkane ester) preparation method:
(1) in there-necked flask, add 0.01～0.2mol benzotriazole carboxylic acid, 10～150mL SOCl
2and 1～15mL DMF, reflux 1～5 hour;
(2) cooling, add 15～250mL sherwood oil, separate out benzotriazole carboxyl acyl chloride, filter;
(3) in another there-necked flask, add water and the 0.01～0.2mol alkyl alcohol of 2～40g sodium hydroxide, 15～300mL, be placed in frozen water, under agitation condition, benzotriazole carboxyl acyl chloride is added in reaction solution in batches, react 5～10 hours;
(4) reaction solution is poured in 25～500mL water, separated out solid and be benzotriazole carboxylic acid alkane ester, filter stand-by.
Described alkyl alcohol is selected from more than one in lauryl alcohol, tridecanol, isomerous tridecanol, tetradecyl alcohol, pentadecanol, hexadecanol, heptadecyl alcohol, stearyl alcohol.Be preferably lauryl alcohol and/or stearyl alcohol.
water-soluble complete synthesis metal grinding fluid concentrates former liquid and preparation method thereof:
Appropriate deionized water is put into reactor, add organic acid, organic amine and other pH adjusting agent, stirring heating is warming up to 70～80 DEG C, and reaction is to forming transparent settled solution A; Synthetic long carbochain benzotriazole carboxylic acid alkane ester, solubilizing agent, permeate agent, clean-out system are mixed with residue rust-preventive agent, stir and form liquid B; Under the condition that keeps stirring heating (70～80 DEG C), B is slowly added in A, add rear continuation heated and stirred and clarify to system, be cooled to 30 DEG C, add proper quantity of defoaming agent, the water-soluble complete synthesis metal grinding fluid that is obtaining concentrates stoste.Wherein each material proportioning is specifically in table 1.
The water-soluble complete synthesis metal grinding fluid of table 1 concentrates stoste proportioning sample list (massfraction)
In table 1, the concentrated stoste of the water-soluble complete synthesis metal grinding fluid of example is the orange-yellow settled solution of transparent homogeneous, and without layering phase transformation and gluey appearance, stability in storage is good.Adopt the working fluid after deionized water or tap water dilute 20 times Clear & Transparent, pH value is in 7.5～9.5, the requirement of meet≤2mL/10min of defoaming, surface tension < 40mN/m, and all pass through the rust-preventing characteristic experiment (GB/T6144-2010) of monolithic 24h, the lamination 12h of the materials such as steel, copper, aluminium, cast iron, the equal <0.1500 of frictional coefficient on friction and wear tester (SRV-4), oilness excellence.
The impact of embodiment 2 chain lengths on benzotriazole carboxylic acid alkane ester lubricity and with the lubricity comparison of commercial grinding fluid
Adopt the water-soluble complete synthesis metal grinding fluid stoste of proportioning preparation in example 1～6, wherein add respectively the benzotriazole carboxylic acid alkane ester that adopts different chain length alkyl alcohol to prepare; 20 times of formation working fluids of stoste dilution, test job liquid lubricity on friction and wear tester platform, and be lubricated Performance Ratio with commercial oil-in-water type lubricating fluid, 20 times of dilution working fluids of all-synthetic grinding fluid.
With reference to aforesaid general method, carry out respectively preparation and the lubricity synthetic, water-soluble complete synthesis metal grinding fluid of benzotriazole carboxylic acid alkane ester according to the condition described in following experimental group and control group and test.Commercial oil-in-water type lubricating fluid and all-synthetic grinding fluid directly adopt 20 times of deionized water dilutions, carry out lubricity test after stirring.Concrete:
1. grouping and treatment process
Experimental group 1:
Benzotriazole carboxylic acid alkane ester is synthetic: in there-necked flask, add 0.1mol benzotriazole carboxylic acid, 75mL SOCl
2and 7.5mL DMF, reflux 2 hours; Cooling, add 125mL sherwood oil, separate out benzotriazole carboxyl acyl chloride, filter; The water and the 0.1mol lauryl alcohol that in another there-necked flask, add 20g sodium hydroxide, 150mL, be placed in frozen water, under agitation condition, benzotriazole carboxyl acyl chloride added in reaction solution in batches, reacts 6 hours; Reaction solution is poured in 250mL water, separated out solid and be benzotriazole carboxylic acid lauryl, filter stand-by.
Water-soluble complete synthesis metal grinding fluid preparation: the deionized water of 100g is put into reactor, add 50g organic ternary poly carboxylic acid L190,100g trolamine and 5g phosphoric acid, 5g ammonium hydrogen phosphate and 10g potassium hydroxide, stirring heating is warming up to 70～80 DEG C, and reaction is to forming transparent settled solution A; 2.5g benzotriazole carboxylic acid lauryl, 2.5g benzotriazole, 5g sodium lauryl sulphate, 50g triethanolamine oleate, 50g isooctanol polyethoxylate phosphate, 50g sulfated castor oil, 25gAEO-9,25g ethanol and 10g glycerine are mixed, stir and form liquid B; Under the condition that keeps stirring heating (70～80 DEG C), B is slowly added in A, adding rear continuation heated and stirred to system clarifies, be cooled to 30 DEG C, add the fatty acid ester compounded thing defoamer of 10g higher alcohols, the water-soluble complete synthesis metal grinding fluid that is obtaining concentrates stoste.
Lubricity test: get the concentrated stoste of the above water-soluble complete synthesis metal grinding fluid of 5g, adopt 20 times of deionized water dilutions, after stirring on multifunction friction wear testing machine SRV-4 testing friction lubricity.
Experimental group 2:
Benzotriazole carboxylic acid alkane ester is synthetic: in there-necked flask, add 0.1mol benzotriazole carboxylic acid, 75mL SOCl
2and 7.5mL DMF, reflux 2 hours; Cooling, add 125mL sherwood oil, separate out benzotriazole carboxyl acyl chloride, filter; The water and the 0.1mol stearyl alcohol that in another there-necked flask, add 20g sodium hydroxide, 150mL, be placed in frozen water, under agitation condition, benzotriazole carboxyl acyl chloride added in reaction solution in batches, reacts 6 hours; Reaction solution is poured in 250mL water, separated out solid and be benzotriazole carboxylic acid stearyl ester, filter stand-by.
Water-soluble complete synthesis metal grinding fluid preparation: the deionized water of 100g is put into reactor, add 50g organic ternary poly carboxylic acid L190,100g trolamine and 5g phosphoric acid, 5g ammonium hydrogen phosphate and 10g potassium hydroxide, stirring heating is warming up to 70～80 DEG C, and reaction is to forming transparent settled solution A; 2.5g benzotriazole carboxylic acid stearyl ester, 2.5g benzotriazole, 5g sodium lauryl sulphate, 50g triethanolamine oleate, 50g isooctanol polyethoxylate phosphate, 50g sulfated castor oil, 25gAEO-9,25g ethanol and 10g glycerine are mixed, stir and form liquid B; Under the condition that keeps stirring heating (70～80 DEG C), B is slowly added in A, adding rear continuation heated and stirred to system clarifies, be cooled to 30 DEG C, add the fatty acid ester compounded thing defoamer of 10g higher alcohols, the water-soluble complete synthesis metal grinding fluid that is obtaining concentrates stoste.
Lubricity test: get the concentrated stoste of the above water-soluble complete synthesis metal grinding fluid of 5g, adopt 20 times of deionized water dilutions, after stirring on multifunction friction wear testing machine SRV-4 testing friction lubricity.
Experimental group 3:
Benzotriazole carboxylic acid alkane ester is synthetic: in there-necked flask, add 0.1mol benzotriazole carboxylic acid, 75mL SOCl
2and 7.5mL DMF, reflux 2 hours; Cooling, add 125mL sherwood oil, separate out benzotriazole carboxyl acyl chloride, filter; The water, 0.05mol lauryl alcohol and the 0.05mol stearyl alcohol that in another there-necked flask, add 20g sodium hydroxide, 150mL, be placed in frozen water, under agitation condition, benzotriazole carboxyl acyl chloride added in reaction solution in batches, reacts 6 hours; Reaction solution is poured in 250mL water, separated out solid and be mixing benzotriazole carboxylic acid alkane ester, filter stand-by.
Water-soluble complete synthesis metal grinding fluid preparation: the deionized water of 100g is put into reactor, add 50g organic ternary poly carboxylic acid L190,100g trolamine and 5g phosphoric acid, 5g ammonium hydrogen phosphate and 10g potassium hydroxide, stirring heating is warming up to 70～80 DEG C, and reaction is to forming transparent settled solution A; 2.5g mixing benzotriazole carboxylic acid alkane ester, 2.5g benzotriazole, 5g sodium lauryl sulphate, 50g triethanolamine oleate, 50g isooctanol polyethoxylate phosphate, 50g sulfated castor oil, 25gAEO-9,25g ethanol and 10g glycerine are mixed, stir and form liquid B; Under the condition that keeps stirring heating (70～80 DEG C), B is slowly added in A, adding rear continuation heated and stirred to system clarifies, be cooled to 30 DEG C, add the fatty acid ester compounded thing defoamer of 10g higher alcohols, the water-soluble complete synthesis metal grinding fluid that is obtaining concentrates stoste.
Lubricity test: get the concentrated stoste of the above water-soluble complete synthesis metal grinding fluid of 5g, adopt 20 times of deionized water dilutions, after stirring on multifunction friction wear testing machine SRV-4 testing friction lubricity.
Control group 1:
Water-soluble complete synthesis metal grinding fluid preparation: the deionized water of 102.5g is put into reactor, add 50g organic ternary poly carboxylic acid L190,100g trolamine and 5g phosphoric acid, 5g ammonium hydrogen phosphate and 10g potassium hydroxide, stirring heating is warming up to 70～80 DEG C, and reaction is to forming transparent settled solution A; 2.5g benzotriazole, 5g sodium lauryl sulphate, 50g triethanolamine oleate, 50g isooctanol polyethoxylate phosphate, 50g sulfated castor oil, 25gAEO-9,25g ethanol and 10g glycerine are mixed, stir and form liquid B; Under the condition that keeps stirring heating (70～80 DEG C), B is slowly added in A, adding rear continuation heated and stirred to system clarifies, be cooled to 30 DEG C, add the fatty acid ester compounded thing defoamer of 10g higher alcohols, the water-soluble complete synthesis metal grinding fluid that is obtaining concentrates stoste.
Lubricity test: get the concentrated stoste of the above water-soluble complete synthesis metal grinding fluid of 5g, adopt 20 times of deionized water dilutions, after stirring on multifunction friction wear testing machine SRV-4 testing friction lubricity.
Control group 2:
Lubricity test: get the concentrated stoste of the commercial water-soluble complete synthesis metal grinding fluid of 5g, adopt 20 times of deionized water dilutions, after stirring on multifunction friction wear testing machine SRV-4 testing friction lubricity.
Control group 3:
Lubricity test: get the concentrated stoste of the commercial emulsification type metal grinding fluid of 5g, adopt 20 times of deionized water dilutions, after stirring on multifunction friction wear testing machine SRV-4 testing friction lubricity.
lubricity testing method:
The present invention uses the lubricating property of friction and wear tester platform (SRV-4) test metal working fluid, and specific experiment condition is as follows:
Friction and wear tester platform: Optimal SRV-4 multifunction friction wear testing machine
Friction pair: steel ball---cast iron cylinder table top
Load: 200N
Stroke: 1mm
Frequency: 50Hz
Temperature: 30 DEG C
2. result and analysis:
Detailed results sees the following form 2 and Fig. 1.
The lubricity comparison of table 2 control group and experimental group
As shown in Table 2, the water-soluble complete synthesis metal grinding fluid lubricity poor (seeing control group 2) of commercial not oil-containing, the emulsion lubrication better performances of oil-containing, in experimentation omnidistance steadily (seeing control group 3).And of the present invention not approaching containing water-soluble complete synthesis metal grinding fluid average friction coefficient and the commercial emulsion of benzotriazole carboxylic acid alkane ester, but as can be seen from Figure 1, process stability is not good enough, has significantly fluctuation (seeing control group 1).Add voluntarily after synthetic benzotriazole carboxylic acid alkane ester, no matter be the benzotriazole carboxylic acid alkane ester of benzotriazole carboxylic acid lauryl, benzotriazole carboxylic acid stearyl ester or mixing, average friction coefficient is all between 0.13～0.14, process stability is all better, adding of visible a small amount of benzotriazole carboxylic acid alkane ester, promote greatly the lubricity of the water-soluble complete synthesis metal grinding fluid of the present invention, improved the lubrication stability in friction process.
Claims (10)
1. a water-soluble complete synthesis metal grinding fluid, is characterized in that, is made up of following component: the rust-preventive agent of 5～40 % by weight; The clean-out system of 1～20 % by weight; The lubricated inhibiter of 0.1～10 % by weight; The permeate agent of 1～20 % by weight; The solubilizing agent of 1～20 % by weight; The pH adjusting agent of 10～40 % by weight; The defoamer of 0.5～5 % by weight, excess water; In water-soluble complete synthesis metal grinding fluid gross weight; Wherein, the pH value of described water-soluble complete synthesis metal grinding fluid is 7～11.
2. water-soluble complete synthesis metal grinding fluid according to claim 1, is characterized in that, described lubricated inhibiter is more than one in long-chain benzotriazole carboxylic acid alkane ester, and the structural formula of described long-chain benzotriazole carboxylic acid alkane ester is as follows:
wherein R is C
12-C
18chain alkyl.
3. water-soluble complete synthesis metal grinding fluid according to claim 1, is characterized in that, described rust-preventive agent is selected from sodium carbonate, volatile salt, sodium phosphate, Sodium phosphate dibasic, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, water glass, Sodium Tetraborate, Sodium chromate, potassiumchromate, sodium dichromate 99, potassium bichromate, Sodium orthomolybdate, sodium wolframate, potassium permanganate, sodium acetate, Sodium Benzoate, Sunmorl N 60S, Phenylethanolamine, urotropine, ammoniacal liquor, thanomin, diethanolamine, trolamine, α-amino isopropyl alcohol, cetylamine, oleic acid alkanolamine ester, oleic acid alkylolamide, sodium soap, fatty acid amine ester, phytic acid, sebacic acid, DC11, SL-AH, tridecanyldicarboxylic acid, organic ternary poly carboxylic acid, poly-epoxy succinic acid, sorbitan monooleate, pentaerythritol ester, alcohol ether phosphate, thiophosphatephosphorothioate, benzotriazole, benzotriazole sodium, methyl benzotriazazole, methyl benzotriazazole sodium, butyl benzotriazole, butyl benzotriazole sodium, mercapto benzothiazole, mercaptobenzimidazole, amino triazole, hydroxyquinoline, indoles, morpholine, N, N-dicyclohexyl acrylamide, tetrahydroglyoxaline, thionamic acid, sodium lignosulfonate, sodium methyl silicate, vinyl water glass, γ-amine propyl group water glass, the organic sodium disilicate of polyethers, more than one in poly aspartic acid, preferably more than one in oleic acid alkanolamine ester, phytic acid, sebacic acid, organic ternary poly carboxylic acid, alcohol ether phosphate, benzotriazole.
4. water-soluble complete synthesis metal grinding fluid according to claim 1, it is characterized in that, described clean-out system is selected from sodium carbonate, sodium phosphate, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, citric acid, EDTA and sodium salt thereof, formic acid, amino acid, oxyacetic acid, oxalic acid, thionamic acid, oxyacetic acid, fatty acid sodium soap, Viscotrol C soda soap, triethanolamine oleate, rosined soap, sodium laurylsulfonate, Witco 1298 Soft Acid, Sodium dodecylbenzene sulfonate, petroleum sodium sulfonate, sodium lauryl sulphate, sulfated castor oil, sulfation peanut oil, sulfation tallow, Dodecyl trimethyl ammonium chloride, Varion CDG-K, alcohol ether carboxylate, alkyl phenol ether carboxylate salt, phosphate ester salt, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, a kind of in alkylolamide and more than, be preferably more than one in fatty acid sodium soap, sodium lauryl sulphate, sulfated castor oil, fatty alcohol-polyoxyethylene ether, alkylolamide.
5. water-soluble complete synthesis metal grinding fluid according to claim 1, it is characterized in that, described permeate agent is selected from more than one in sulfated castor oil, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfuric ester sodium, Seconary Alkane Sulphonate Sodium, secondary alkyl sulphate sodium, α-sodium olefin sulfonate, sodium alkyl naphthalene sulfonate, succsinic acid alkyl ester sodium sulfonate, N-methyl oleoyl amino-ethyl sodium sulfonate, thionamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyethers, phosphoric acid ester, small molecular alcohol, small molecules ketone or small molecules ether; Be preferably more than one in phosphoric acid ester, small molecular alcohol, polyethers; Described small molecular alcohol, small molecules ketone or small molecules ether are no more than 8 carbon atoms.
6. water-soluble complete synthesis metal grinding fluid according to claim 1, it is characterized in that, described solubilizing agent is selected from methyl alcohol, ethanol, propyl alcohol, propyl carbinol, ethylene glycol, propylene glycol, glycerol, acetone, cyclopropanone, glycol ether, propylene glycol, polyoxyethylene glycol, dibutyl phthalate, sorbitan fatty acid ester, Polyoxyethylene Sorbitol Fatty Acid Esters, sucrose fatty ester, laurin, pentaerythritol tetrapalmitate, methyl glucoside dodecyl ester, N-dodecyl glucosyl group laurylamide, alkyl glycoside, DoJyoxyethylene xylitol stearate, polyethers, more than one in cellulose family, be preferably more than one in ethanol, glycerol, polyoxyethylene glycol, polyethers.
7. water-soluble complete synthesis metal grinding fluid according to claim 1, it is characterized in that, described pH adjusting agent is selected from sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, Mono Chloro Acetic Acid, propanedioic acid, sodium hydroxide, potassium hydroxide, ammoniacal liquor, thanomin, diethanolamine, trolamine, α-amino isopropyl alcohol, aminopropanol, diisopropanolamine (DIPA), quadrol, tetramethylphosphonihydroxide hydroxide base amine, hydroxide tetraethyl-amine, hydroxide tetrapropyl amine, choline, piperidines, piperazine, polyethylene imines, sodium carbonate, salt of wormwood, sodium phosphate, potassiumphosphate, Sodium phosphate dibasic, more than one in ammonium hydrogen phosphate, be preferably more than one in trolamine, phosphoric acid, ammonium hydrogen phosphate, sodium hydroxide, potassium hydroxide.
8. water-soluble complete synthesis metal grinding fluid according to claim 1, it is characterized in that, described defoamer is selected from more than one in silicone emulsion, dimethyl silicone oil, oleic acid chromium, vegetables oil, polysiloxane, polyethers, polyether siloxane copolymers, ethanol, higher alcohols, the fatty acid ester compounded thing of higher alcohols, phenylethyl alcohol oleic acid ester, toluylic acid bay alcohol ester, tributyl phosphate, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxypropylene; Be preferably more than one in polyethers, polyether siloxane copolymers, the fatty acid ester compounded thing of higher alcohols.
9. water-soluble complete synthesis metal grinding fluid according to claim 1, it is characterized in that, described water-soluble complete synthesis metal grinding fluid adopts deionized water or tap water to be diluted to mass concentration while use be 5～20% dilution working fluid, and pH value is controlled at 7.5～9.5.
10. water-soluble complete synthesis metal grinding fluid according to claim 1, is characterized in that, is made up of: the rust-preventive agent of 10～35 % by weight following component; The clean-out system of 10～20 % by weight; The lubricated inhibiter of 0.5～4 % by weight; The permeate agent of 1～15 % by weight; The solubilizing agent of 1～15 % by weight; The pH adjusting agent of 20～35 % by weight; The defoamer of 1～4 % by weight, excess water; In water-soluble complete synthesis metal grinding fluid gross weight; Wherein, the pH value of described water-soluble complete synthesis metal grinding fluid is 8～10.
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