CN109641786A - 用于自主汽车的玻璃 - Google Patents
用于自主汽车的玻璃 Download PDFInfo
- Publication number
- CN109641786A CN109641786A CN201780053609.7A CN201780053609A CN109641786A CN 109641786 A CN109641786 A CN 109641786A CN 201780053609 A CN201780053609 A CN 201780053609A CN 109641786 A CN109641786 A CN 109641786A
- Authority
- CN
- China
- Prior art keywords
- glass
- glass plate
- glazing
- infrared
- glazing according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 108
- 238000010521 absorption reaction Methods 0.000 claims abstract description 19
- 238000001914 filtration Methods 0.000 claims abstract description 3
- 241000446313 Lamella Species 0.000 claims abstract 2
- 239000010410 layer Substances 0.000 claims description 31
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 17
- 238000000576 coating method Methods 0.000 claims description 17
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- QDOXWKRWXJOMAK-UHFFFAOYSA-N chromium(III) oxide Inorganic materials O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 9
- 239000002346 layers by function Substances 0.000 claims description 9
- 230000005855 radiation Effects 0.000 claims description 9
- 230000005540 biological transmission Effects 0.000 claims description 8
- 238000003475 lamination Methods 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 238000004040 coloring Methods 0.000 claims description 4
- 238000013507 mapping Methods 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- 239000006117 anti-reflective coating Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 26
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000006132 parent glass Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000008447 perception Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000005315 stained glass Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229910019923 CrOx Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910017947 MgOx Inorganic materials 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910003070 TaOx Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NCXOIRPOXSUZHL-UHFFFAOYSA-N [Si].[Ca].[Na] Chemical compound [Si].[Ca].[Na] NCXOIRPOXSUZHL-UHFFFAOYSA-N 0.000 description 1
- FGKRRBWIHMRUCR-UHFFFAOYSA-N [Sn].[Ti].[Zr] Chemical compound [Sn].[Ti].[Zr] FGKRRBWIHMRUCR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PSNPEOOEWZZFPJ-UHFFFAOYSA-N alumane;yttrium Chemical compound [AlH3].[Y] PSNPEOOEWZZFPJ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- JYMITAMFTJDTAE-UHFFFAOYSA-N aluminum zinc oxygen(2-) Chemical compound [O-2].[Al+3].[Zn+2] JYMITAMFTJDTAE-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- RJSRQTFBFAJJIL-UHFFFAOYSA-N niobium titanium Chemical compound [Ti].[Nb] RJSRQTFBFAJJIL-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000011224 oxide ceramic Substances 0.000 description 1
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- ZARVOZCHNMQIBL-UHFFFAOYSA-N oxygen(2-) titanium(4+) zirconium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4] ZARVOZCHNMQIBL-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229910021426 porous silicon Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- -1 titanium-zirconium-aluminium Chemical compound 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/10—Compositions for glass with special properties for infrared transmitting glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10082—Properties of the bulk of a glass sheet
- B32B17/10119—Properties of the bulk of a glass sheet having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10614—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising particles for purposes other than dyeing
- B32B17/10633—Infrared radiation absorbing or reflecting agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0092—Compositions for glass with special properties for glass with improved high visible transmittance, e.g. extra-clear glass
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01S—RADIO DIRECTION-FINDING; RADIO NAVIGATION; DETERMINING DISTANCE OR VELOCITY BY USE OF RADIO WAVES; LOCATING OR PRESENCE-DETECTING BY USE OF THE REFLECTION OR RERADIATION OF RADIO WAVES; ANALOGOUS ARRANGEMENTS USING OTHER WAVES
- G01S17/00—Systems using the reflection or reradiation of electromagnetic waves other than radio waves, e.g. lidar systems
- G01S17/88—Lidar systems specially adapted for specific applications
- G01S17/93—Lidar systems specially adapted for specific applications for anti-collision purposes
- G01S17/931—Lidar systems specially adapted for specific applications for anti-collision purposes of land vehicles
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01S—RADIO DIRECTION-FINDING; RADIO NAVIGATION; DETERMINING DISTANCE OR VELOCITY BY USE OF RADIO WAVES; LOCATING OR PRESENCE-DETECTING BY USE OF THE REFLECTION OR RERADIATION OF RADIO WAVES; ANALOGOUS ARRANGEMENTS USING OTHER WAVES
- G01S7/00—Details of systems according to groups G01S13/00, G01S15/00, G01S17/00
- G01S7/48—Details of systems according to groups G01S13/00, G01S15/00, G01S17/00 of systems according to group G01S17/00
- G01S7/481—Constructional features, e.g. arrangements of optical elements
- G01S7/4811—Constructional features, e.g. arrangements of optical elements common to transmitter and receiver
- G01S7/4813—Housing arrangements
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Computer Networks & Wireless Communication (AREA)
- General Physics & Mathematics (AREA)
- Radar, Positioning & Navigation (AREA)
- Remote Sensing (AREA)
- Electromagnetism (AREA)
- Glass Compositions (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
Abstract
本发明涉及一种汽车嵌装玻璃，其包括(i)至少一块玻璃板，其在从750至1050nm的波长范围内具有低于5m‑1的吸收系数、并且具有外面和内面，以及(ii)红外滤光片。根据本发明，在从750至1050nm的波长范围内、并且优选在从750至950nm的波长范围内的基于红外的遥感装置被置于所述玻璃板的所述内面上不含所述红外滤光片层的区域中。
Description
本发明涉及一种包括基于红外的遥感装置并且特别地是LiDAR传感器的玻璃。更特别地，本发明涉及一种待集成到自主汽车中的包括新一代LiDAR传感器的玻璃。
现今，趋势是使用越来越多的未来将被完全使用的自主汽车。例如，未来的自主汽车(也被称为无人驾驶汽车、自我驾驶汽车、机器人汽车)是能够感测其环境并且无需人工输入而导航的车辆。
自主车辆使用雷达、LiDAR(光探测与测距(Light Detection And Ranging)的首字母缩写)、GPS、里程计和计算机视觉来探测周围环境。先进的控制***解释感知信息，以识别适当的导航路径、以及障碍物和相关标识。自主汽车具有能够分析感知数据以在道路上的不同汽车之间进行区分的控制***，这对于规划到希望目的地的路径非常有用。
现今，自主汽车包括“蘑菇状”LiDAR传感器，这些传感器全部沿着金属车身冒出。那些“蘑菇”例如置于车顶上或汽车后视件中。除了不美观之外，它们令人印象深刻并且占据了很多空间，这与准备具有非常光滑且弯曲的线条(与外部传感器不兼容)的未来汽车设计的汽车设计师的期望不一致。LiDAR传感器也可以置于保险杠上。
具有集成的LiDAR的挡风玻璃也是已知的。然而，新一代LiDAR与经涂覆的玻璃不兼容，然而普通玻璃或经涂覆的玻璃并且特别地经涂覆的挡风玻璃越来越多地被汽车制造商用于例如热舒适性。
因此，对使用令人印象深刻且不美观的LiDAR传感器如用于自主汽车的“蘑菇”或保险杠上的LiDAR的替代物存在需求。
根据本发明，基于红外的遥感装置LiDAR传感器是新一代LIDAR，其基于扫描、旋转或固态Lidar并且使得能够对车辆周围的环境进行3D测绘。因此，基于IR的传感器允许对汽车的周围环境进行精确测绘，所述测绘用于正确地驾驶所述自主汽车并且防止与障碍物的任何碰撞。
LiDAR(也写为Lidar、LIDAR或LADAR)是通过用激光照射目标来测量距离的技术。它们特别是扫描、旋转或固态Lidar。扫描或旋转激光器都沿着金属车身冒出，而固态LiDAR发射从物体反射的光脉冲。
因此，现今对基于红外(IR)的遥感装置/传感器存在需求，所述遥感装置/传感器能够对车辆周围的环境进行物体检测和3D测绘，如安装在自主汽车内部并且特别是安装在挡风玻璃上的LiDAR。基于IR的传感器允许对汽车的周围环境进行精确测绘，所述测绘用于正确地驾驶所述自主汽车并且防止与障碍物的任何碰撞。
因此，来自现有技术的解决方案不能应对LiDAR新一代的要求，特别是因为具有集成的Lidar的玻璃不被认为是可能的解决方案。
目前，不存在允许IR信号以足够强度通过车身或玻璃部件如汽车的挡风玻璃或后窗玻璃的解决方案。
因此，本发明提出了一种解决方案，其中LiDAR新一代传感器可以集成在自主汽车内部，所述传感器结合了高探测范围、最小的设计变化以及更高的安全性。
通过以下方式此解决方案是可能的：在挡风玻璃或汽车嵌装玻璃上集成LiDAR传感器，所述挡风玻璃或汽车嵌装玻璃表现出足够的IR透射率来使传感器适当地运行。
为简单起见，在以下说明书中的玻璃板的编号是指常规地用于嵌装玻璃的编号命名。因此，与车辆外的环境接触的嵌装玻璃的面被称为侧面1，并且与内部介质(也就是说客厢)接触的表面被称为面2。对于层压式嵌装玻璃，与车辆的外部环境接触的玻璃板被称为侧面1，并且与内部部分即客厢接触的表面被称为面4。
为了避免疑问，术语“外部”和“内部”是指作为在车辆中的嵌装玻璃在安装期间所述嵌装玻璃的取向。
同样为了避免疑问，本发明适用于所有运输工具，如汽车、火车、飞机...。
因此，本发明涉及一种汽车嵌装玻璃，其包括：
a.至少一块玻璃板，其在从750至1050nm的波长范围内具有低于5m-1的吸收系数、并且具有外面和内面，
b.红外滤光片。
根据本发明，在从750至1050nm的波长范围内的基于红外的遥感装置被置于所述玻璃板的内面上不含所述红外滤光片的区域中。
根据本发明，所述玻璃板在从750至1050nm的波长范围内具有低于5m-1的吸收系数。为了量化玻璃板在红外范围内的低吸收，在本说明书中，使用在从750至1050nm的波长范围内的吸收系数。所述吸收系数是由在给定环境中的吸收度与电磁辐射经过的光程长度之间的比率定义的。它以m-1表示。因此它独立于所述材料的厚度，但它是所吸收辐射的波长以及所述材料的化学性质的函数。
在玻璃的情况下，在选定波长λ的吸收系数(μ)可以从透射率(T)的测量值以及所述材料的折射率n计算(thick＝厚度)，n、ρ和T的值是选定波长λ的函数：
其中，ρ＝(n-1)2/(n+1)2。
与常规玻璃(如所述的“透明玻璃”，对于其，此系数约为30m-1数量级)相比，根据本发明的玻璃板优选在750-1050nm的波长范围(通常用于涉及本发明的光学技术中)内具有非常低的吸收系数。特别地，根据本发明的玻璃板在从750至1050nm的波长范围内具有低于5m-1的吸收系数。
优选地，所述玻璃板具有低于3m-1、或甚至低于2m-1、并且甚至更优选地低于1m-1、或甚至低于0.8m-1的吸收系数。
根据本发明的优选的实施例，玻璃板在750至950nm的波长范围内具有吸收系数。
低吸收呈现出额外的优点，即最终的IR透射率受材料中光程的影响较小。其意指对于具有高张角的大视野(FOV)传感器，在各种角度下感知的强度(在不同区域中是图像)将更均匀，尤其是当传感器光学联接到嵌装玻璃时。
因此，当自主车辆遇到不适合自主操作的出乎意料的驾驶环境如道路建设或障碍时，通过根据本发明的嵌装玻璃车辆传感器可以捕获关于车辆和出乎意料的驾驶环境的数据，包括图像、雷达和LiDAR数据等。捕获的数据可以发送至远程操作员。所述远程操作员可以远程手动操作车辆或者向自主车辆发出命令以在各种车辆***上执行。可以优化发送至远程操作员的捕获数据以节约带宽，如通过发送捕获数据的有限子集。
根据本发明，所述玻璃板由可属于不同类别的玻璃制成，所述玻璃具有在从750至1050nm的波长范围内具有低于5m-1的吸收系数的特质。因此，所述玻璃可以是钠钙硅型玻璃、硅铝酸盐、硼硅酸盐...。
优选地，具有高水平近红外辐射透射率的玻璃板是超透明玻璃。
优选地，本发明的基础玻璃组成包含以玻璃的重量百分比表示的总含量的以下项：
更优选地，根据本发明的基础玻璃组成包含以玻璃的总重量百分比表示的含量的以下项:
更优选地，出于较低的生产成本的原因，根据本发明的所述至少一块玻璃板是由钠钙玻璃制成。有利地，根据此实施例，所述基础玻璃组成包含以玻璃的总重量百分比表示的含量的以下项:
除了其基础组成之外，玻璃可以包括天然和根据所希望的效果的量进行适配的其他组分。
本发明中提出的获得在高红外(IR)中非常透明的玻璃而对其美学或其颜色的影响弱或没有影响的解决方案是在玻璃组成中结合低铁量和特定含量范围内的铬。
因此，根据第一实施例，玻璃板优选具有以下组成，所述组成包含以玻璃的总重量百分比表示的含量的以下项：
总铁(表示为Fe2O3) 0.002％-0.06％
Cr2O3 0.0001％-0.06％。
此种结合低水平的铁和铬的玻璃组成在红外反射方面示出特别好的性能，并且示出在可见光的高透明度和有点显著的色彩，近似于被称为“超透明”的玻璃。这些组成在国际申请WO 2014128016A1、WO 2014180679A1、WO 2015011040A1、WO 2015011041A1、WO2015011042A1、WO 2015011043A1和WO 2015011044A1中描述，将其通过引用结合在本申请中。根据此第一具体的实施例，所述组成优选包含相对于玻璃的总重量按重量计从0.002％-0.06％的铬含量(表示为Cr2O3)。此种铬含量有可能进一步改进红外反射。
根据第二实施例，玻璃板具有以下组成，所述组成包含以玻璃的总重量百分比表示的含量的以下项：
总铁(表示为Fe2O3) 0.002％-0.06％
Cr2O3 0.0015％-1％
Co 0.0001％-1％。
此类基于铬和钴的玻璃组成在红外反射方面显示出特别好的性能，同时在美学/颜色方面提供了令人关注的可能性(带蓝色的中性色至强烈着色甚至达到不透明)。此类组成在欧洲专利申请号13 198454.4中描述，将其通过引用结合在此。
根据第三实施例，玻璃板具有以下组成，所述组成包含以玻璃的总重量百分比表示的含量的以下项：
总铁(表示为Fe2O3) 0.02％-1％
Cr2O3 0.002％-0.5％
Co 0.0001％-0.5％。
优选地，根据此实施例，所述组成包含：0.06％<总铁≤1％。
此类基于铬和钴的组成被用于获得在蓝-绿色范围内的有色玻璃板，这些有色玻璃板在颜色和光透射率方面与市场上的蓝色和绿色玻璃是可比较的，但是在红外反射方面具有特别好的性能。此类组成在欧洲专利申请EP15172780.7中描述，并且将其通过引用结合到本申请中。
根据第四实施例，玻璃板具有以下组成，所述组成包含以玻璃的总重量百分比表示的含量的以下项：
此类基于铬、钴和硒的玻璃组成已经在红外反射方面显示出特别好的性能，同时在美学/颜色方面提供令人关注的可能性(灰色、中性色至在灰色-古铜色范围内强烈的轻微染色)。此类组成在欧洲专利EP15172779.9的申请中描述，并且将其通过引用结合到本申请中。
根据第一替代实施例，玻璃板具有以下组成，所述组成包含以玻璃的总重量百分比表示的含量的以下项：
总铁(表示为Fe2O3) 0.002％-0.06％
CeO2 0.001％-1％。
此类组成在欧洲专利申请号13 193 345.9中描述，将其通过引用结合在此。
根据另一个替代实施例，所述玻璃具有以下组成，所述组成包含以玻璃的总重量百分比表示的含量的以下项：
总铁(表示为Fe2O3)0.002％-0.06％；
以及以下组分之一：
-范围为按重量计从0.01％至1％的量的锰(以MnO计算)；
-范围为按重量计从0.01％至1％的量的锑(表示为Sb2O3)；
-范围为按重量计从0.01％至1％的量的砷(表示为As2O3)，
或
-范围为按重量计从0.0002％至0.1％的量的铜(表示为CuO)。
此类组成在欧洲专利申请号14 167 942.3中描述，将其通过引用结合在此。
根据本发明，汽车嵌装玻璃可以呈平面板的形式。嵌装玻璃可以是弯曲的。对于汽车嵌装玻璃如对于后窗、侧窗或天窗或尤其是挡风玻璃而言，通常是这种情况。
在汽车应用中，当车辆暴露于阳光时，红外中高透射率玻璃板的存在不利于保持热舒适性。本发明提出的手段是提供具有高选择性(TL/TE)、优选具有大于1或大于1.3的选择性的嵌装玻璃。因此，为了保持在能量透射和热舒适性的适当条件下，除了已经指定的元件之外，根据本发明的嵌装玻璃包括选择性地过滤来自太阳辐射的红外线的器件。
可替代地，可能有利的是与根据本发明的玻璃组合使用具有低于50％、40％、35％、30％、25％、20％、15％、10％、5％、4％、3％、2％或1％的IR透射率的过滤层。
有利地，红外滤光片是具有多层堆叠体的反射层，所述多层堆叠体包括基于反射红外辐射的材料的n个功能层，其中n≥1，和n+1个介电涂层，使得每个功能层被介电涂层包围。
红外反射层的一部分的功能层有利地由贵金属形成。它们可以基于银、金、钯、铂或其混合物或合金，但也基于铜或铝(单独的)、合金或与一种或多种贵金属的合金。优选地，所有功能层都基于银。它是具有非常高的红外辐射反射效率的贵金属。它容易在磁控管装置中实施，并且其成本不是过高的，尤其相对于其效力而言。有利地，银掺杂有百分之几的钯、铝或铜，例如由于按质量计1％至10％，或者可以使用银合金。
介电层、透明涂层、红外反射层的一部分在通过溅射沉积的膜领域中是公知的。合适的材料很多，并且在此不用列出完整清单。这些通常是氧化物、氮氧化物或金属氮化物。在最常见的之中，包括例如SiO2、TiO2、SnO2、ZnO、ZnAlOx、Si3N4、AlN、Al2O3、ZrO2、Nb2O5、YOxTiZrYOx、TiNbox、HfOx、MgOx、TaOx、CrOx和Bi2O3、以及其混合物。还可以列举以下材料：AZO、ZTO、GZO、NiCrOx、TXO、ZSO、TZO、TNO、TZSO、TZAO和TZAYO。术语AZO涉及掺杂有铝的氧化锌或锌和铝的混合氧化物，其优选从由待沉积的氧化物形成的陶瓷靶在中性或轻微氧化的气氛中喷射获得。类似地，ZTO或GZO表述分别涉及在中性或轻微氧化的气氛中从陶瓷靶获得的钛和锌或锌和镓的混合氧化物。术语TXO涉及由氧化钛陶瓷靶获得的氧化钛。术语ZSO是指在氧化的气氛中从沉积的合金的金属靶或者在中性或轻微氧化的气氛下从相应氧化物的陶瓷靶获得的混合的锌-锡氧化物。表述TZO、TNO、TZSO、TZAO或TZAYO分别涉及在中性或轻微氧化的气氛下从陶瓷靶获得的混合的钛锆氧化物、钛-铌、钛-锆-锡、钛-锆-铝或钛-锆-铝-钇。所有这些上述的材料均可用于形成本发明中使用的介电膜。
优选地，布置在一个或每个功能层下的介电涂层包括与所述一个或多个功能层直接接触的基于氧化锌的层，所述氧化锌任选地例如掺杂有铝或镓、或者与氧化锡合金化。氧化锌可以对功能层的稳定性和耐腐蚀性具有特别有利的作用，尤其是就金钱而论。它还有利于基于银的层的电导率的改进并且因此获得低发射率。
例如，在已知的磁控管装置中，在减压磁控管溅射下溅射堆叠体的不同层。然而，本发明不限于这种具体的层沉积方法。
根据本发明的具体实施例，这些组件的层可以安排在***到层压件中的载体板(特别是PET)上、或者通过直接施用安排在玻璃板上。
基于以上所述作为金属层的替代物，红外反射层可以包括多个非金属层，使得其作为带通滤光片(所述带以红外电磁波谱区域附近为中心)运行。
根据本发明的优选的实施例，所述汽车嵌装玻璃是包括与至少一个热塑性夹层层压的外玻璃板和内玻璃板的层压式嵌装玻璃，并且其中所述外玻璃板和内玻璃板是在从750至1050nm并且优选从750至950nm的波长范围内具有低于5m-1的吸收系数的高水平近红外辐射透射的玻璃板。然后，优选将反射红外辐射的层置于面2上，意指置于安装在车辆上并与外部环境接触的第一玻璃板的内面上。
根据本发明的另一个实施例，红外滤光片是吸收红外线的热塑性夹层。此种热塑性夹层例如是掺杂有ITO的PVB。
根据本发明的另一个实施例，红外滤光片是着色的玻璃。
根据本发明的一个实施例，玻璃板具有低于红外透射率值的光透射率值。特别地，根据本发明的另一个实施例，可见光中的光透射率值低于10％并且红外透射率值高于50％。
根据本发明的另一个有利的实施例，玻璃板覆盖有至少一个IR透明的着色的和/或反射涂层，以便使外部看不到传感器的不美观元件，同时确保良好水平的运行性能。此涂层可以例如由至少一个黑色油墨层构成，所述黑色油墨层在可见光学范围内没有(或具有非常低)透射率，但在本申请所关注的红外范围内具有高透明度。此种油墨可以由有机化合物制成，所述有机化合物可以在400-750nm范围内达到<5％的透射率，并且在850-950nm范围内达到>70％的透射率。
根据本发明的另一个实施例，可以将在850-1100nm近红外光中高度透射的、同时有效地阻挡300-750nm UV和可见光的黑色红外透明膜层压到一个或多个玻璃板上，以使外部看不到传感器的不美观元件，同时确保良好水平的运行性能。
可替代地，可以将具有类似特性的有色热塑性塑料如也被称为PMMA的聚(甲基丙烯酸甲酯)、丙烯酸树脂或丙烯酸玻璃与玻璃板组合使用。也可以使用聚碳酸酯塑料或其他合适的塑料材料。可以将有色热塑性塑料与本领域技术人员公知的合适的夹层层压到玻璃上。
根据本发明的另一个实施例，玻璃板可以覆盖有多层涂层，所述多层涂层被优化以选择性地反射可见光范围，同时保持高IR透射率。因此寻求如在产品上观察到的一些特性。当此种层沉积在适当的玻璃组成上时，这些特性确保完整***的总IR吸收度低。所述涂层可以在单一汽车嵌装玻璃元件的面1或/和2上、或者在层压式汽车嵌装玻璃的面1或/和4上提供，这取决于其耐久性。
根据本发明，LiDAR仪器是光电***，其由至少一个激光发射器、至少一个包括光收集器(望远镜或其他光学器件)的接收器和至少一个将光转换成电信号和电子处理链信号(提取所寻求信息)的光探测器构成。
在一块玻璃板嵌装玻璃的情况下，将LiDAR置于玻璃板的内面(即面2)上不含红外滤光片层的区域中。
优选地，将LiDAR置于嵌装玻璃的上部，并且更优选地接近于镜架。
根据本发明的另一个实施例，汽车嵌装玻璃是层压式嵌装玻璃，其中将LiDAR置于内玻璃板的内面即面4上其中不存在IR过滤器件的玻璃板区域上。
根据本发明的优选的实施例，汽车嵌装玻璃是挡风玻璃。因此，将基于红外的遥感装置置于挡风玻璃的面4上没有红外反射层的区域上。确实，在红外反射涂层的情况下，例如通过去涂层或通过掩模以LiDAR位于面4上(或者在一块玻璃板嵌装玻璃的情况下在面2上)没有涂层的这个区域上的方式提供不含涂层的区域，以确保其功能。不含涂层区域通常具有基于红外的遥感装置的形状和尺寸。在红外吸收膜的情况下，将膜切割成LiDAR的尺寸，使得LiDAR位于没有膜的这个区域上，以确保其功能。
根据本发明的一个实施例，汽车嵌装玻璃是超薄嵌装玻璃。
有利地，基于IR的遥感装置光学联接到嵌装玻璃的内面上。例如，可以使用适合玻璃的折射率和LiDAR的外部透镜的柔软材料。
根据本发明的另一个有利的实施例，所述玻璃板涂覆有至少一个减反射层。根据本发明的减反射层例如可以是基于具有低折射率的多孔硅的层或者它可以由若干层(堆叠体)组成，特别是具有低和高折射率的介电材料交替层并且终止于具有低折射率的层的层堆叠体。此种涂层可以在单一嵌装玻璃”的面1或/和2上、或者在层压式嵌装玻璃的面1或/和4上提供。还可以使用纹理化的玻璃板。也可以使用蚀刻或涂层技术来避免反射。
Claims (17)
1.一种汽车嵌装玻璃，其包括：
a.至少一块玻璃板，其在从750至1050nm的波长范围内具有低于5m-1的吸收系数、并且具有外面和内面，
b.红外滤光片
其中，在从750至1050nm的波长范围内、并且优选在从750至950nm的波长范围内的基于红外的遥感装置被置于所述玻璃板的所述内面上不含所述红外滤光片层的区域中。
2.根据权利要求1所述的嵌装玻璃，其特征在于，所述至少一块玻璃板具有低于1m-1的吸收系数。
3.根据权利要求1或2所述的嵌装玻璃，其特征在于，基于红外的遥感装置光学联接到所述嵌装玻璃的所述内面。
4.根据前述权利要求中任一项所述的汽车嵌装玻璃，其特征在于，所述嵌装玻璃是包括与至少一个热塑性夹层层压的外玻璃板和内玻璃板的层压式嵌装玻璃，并且其中，所述外玻璃板和内玻璃板是具有低于5m-1的吸收系数的高水平近红外辐射透射率的玻璃板，并且其中，所述基于红外的遥感装置被置于面4上。
5.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，所述内玻璃板具有低于红外透射率值的光透射率值。
6.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，至少一块玻璃板覆盖有至少一个红外透明的着色的和/或反射涂层。
7.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，所述至少一块玻璃板包含以玻璃的总重量百分比表示的含量的以下项：
-总铁(表示为Fe2O3)0.002％至0.06％
-Cr2O3 0.0001％至0.06％。
8.根据前述权利要求1至6中任一项所述的嵌装玻璃，其特征在于，所述至少一块玻璃板包含以玻璃的总重量百分比表示的含量的以下项:
-总铁(表示为Fe2O3)0.002％至0.06％
-Cr2O3 0.0015％至1％
-Co 0.0001％至1％。
9.根据前述权利要求1至6中任一项所述的嵌装玻璃，其特征在于，所述至少一块玻璃板包含以玻璃的总重量百分比表示的含量的以下项:
-总铁(表示为Fe2O3)0.02％至1％
-Cr2O3 0.002％至0.5％
-Co 0.0001％至0.5％。
10.根据前述权利要求1至6中任一项所述的嵌装玻璃，其特征在于，所述至少一块玻璃板包含以玻璃的总重量百分比表示的含量的以下项:
-总铁(表示为Fe2O3)从0.002％至1％
-Cr2O3 0.001％至0.5％
-Co 0.0001％至0.5％
-Se 0.0003％至0.5％。
11.根据权利要求1至6中任一项所述的嵌装玻璃，其特征在于，所述至少一块玻璃是超透明玻璃。
12.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，红外滤光片层***是多层堆叠体，所述多层堆叠体包括反射红外辐射的材料的n个功能层，其中n≥1，和n+1个介电涂层，使得每个功能层被介电涂层包围。
13.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，所述红外滤光片层***是基于银的。
14.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，所述红外滤光片层***是其中提供去涂层区域的涂层，基于红外的遥感装置置于所述去涂层区域上。
15.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，所述基于红外的遥感装置是基于扫描、旋转或固态LiDAR并且使得能够对车辆周围的环境进行3D测绘的LIDAR***。
16.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，减反射涂层被提供在所述汽车嵌装玻璃的表面上。
17.根据前述权利要求中任一项所述的嵌装玻璃，其特征在于，所述嵌装玻璃是挡风玻璃。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16180197 | 2016-07-19 | ||
| EP16180197.2 | 2016-07-19 | ||
| EP16200695.1 | 2016-11-25 | ||
| EP16200695 | 2016-11-25 | ||
| PCT/EP2017/067921 WO2018015312A1 (en) | 2016-07-19 | 2017-07-14 | Glass for autonomous car |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109641786A true CN109641786A (zh) | 2019-04-16 |
| CN109641786B CN109641786B (zh) | 2022-07-15 |
Family
ID=59350950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780053609.7A Active CN109641786B (zh) | 2016-07-19 | 2017-07-14 | 用于自主汽车的玻璃 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US11407677B2 (zh) |
| EP (1) | EP3487823B1 (zh) |
| JP (1) | JP7145145B2 (zh) |
| CN (1) | CN109641786B (zh) |
| WO (1) | WO2018015312A1 (zh) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112839804A (zh) * | 2019-09-20 | 2021-05-25 | 法国圣戈班玻璃厂 | 具有连接的近红外观察***的车辆用层压窗玻璃和装置 |
| CN114126923A (zh) * | 2019-07-18 | 2022-03-01 | 旭硝子欧洲玻璃公司 | 用于自主汽车的玻璃 |
| CN115103764A (zh) * | 2020-12-01 | 2022-09-23 | 法国圣戈班玻璃厂 | 车辆用层压窗玻璃和具有连接的近红外视觉***的设备 |
| CN115226397A (zh) * | 2021-02-19 | 2022-10-21 | 法国圣戈班玻璃厂 | 层压窗玻璃、其制备方法和具有近红外视觉***的相关设备 |
| CN115226396A (zh) * | 2021-02-19 | 2022-10-21 | 法国圣戈班玻璃厂 | 层压窗玻璃、具有近红外视觉***的相关设备 |
| CN115416453A (zh) * | 2022-08-25 | 2022-12-02 | 重庆长安汽车股份有限公司 | 一种降低新能源汽车热负荷的玻璃及车辆 |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EA039340B1 (ru) * | 2018-07-06 | 2022-01-14 | Агк Гласс Юроп | Остекление с оптически прозрачной областью датчика |
| US11613104B2 (en) | 2018-08-03 | 2023-03-28 | Agc Glass Europe | Glazing with optical device |
| EP3853184A1 (en) | 2018-09-17 | 2021-07-28 | AGC Glass Europe | Glass sheet with high near-ir transmission and very low visible transmission |
| FR3094266B1 (fr) | 2019-03-27 | 2021-04-02 | Saint Gobain | Vitrage feuilleté réfléchissant les infrarouges |
| CN113692394B (zh) | 2019-04-03 | 2023-08-11 | 旭硝子欧洲玻璃公司 | 具有高近ir透射率和极低可见光透射率的玻璃板 |
| EP3947307A1 (en) | 2019-04-03 | 2022-02-09 | AGC Glass Europe | Glass sheet with high near-ir transmission and very low visible transmission |
| JP7356286B2 (ja) * | 2019-06-26 | 2023-10-04 | ダイキョーニシカワ株式会社 | 車両用距離センサの取付構造 |
| WO2021110946A1 (en) * | 2019-12-05 | 2021-06-10 | Agc Glass Europe | Glazing unit with a housing |
| EP4070409A1 (en) * | 2019-12-05 | 2022-10-12 | AGC Glass Europe | 4g and/or 5g signal communication device |
| FR3105943B1 (fr) | 2020-01-03 | 2023-05-19 | Saint Gobain | Vitrage feuillete de vehicule et dispositif avec systeme de vision proche infrarouge associe et sa fabrication |
| EP4158376A1 (en) | 2020-05-25 | 2023-04-05 | AGC Glass Europe | Baffle of a detection device for automotive vehicle |
| WO2022064226A1 (en) * | 2020-09-28 | 2022-03-31 | Pilkington Group Limited | Laminated glazing |
| FR3121384B1 (fr) | 2021-03-31 | 2023-03-24 | Saint Gobain | Vitrage de vehicule et dispositif avec systeme de detection proche infrarouge associe |
| FR3121873A1 (fr) | 2021-04-14 | 2022-10-21 | Saint-Gobain Glass France | Vitrage feuillete de vehicule, dispositif avec systeme de detection proche infrarouge associe |
| FR3120012B1 (fr) | 2021-02-19 | 2023-12-29 | Saint Gobain | Vitrage feuillete de vehicule, sa fabrication et dispositif avec systeme de vision proche infrarouge associe |
| WO2023001706A2 (en) * | 2021-07-20 | 2023-01-26 | Agc Glass Europe | Ir transmissive pane |
| CN118354899A (zh) | 2021-12-03 | 2024-07-16 | 旭硝子欧洲玻璃公司 | 包括检测装置的装饰元件 |
| CN118401368A (zh) | 2021-12-03 | 2024-07-26 | 旭硝子欧洲玻璃公司 | 包括检测装置的装饰元件 |
| WO2023242128A1 (en) | 2022-06-13 | 2023-12-21 | Agc Glass Europe | Calibration method for an automotive glazing |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973511A (en) * | 1988-12-01 | 1990-11-27 | Monsanto Company | Composite solar/safety film and laminated window assembly made therefrom |
| EP1462244A1 (en) * | 2003-03-28 | 2004-09-29 | Pilkington Automotive Limited | Tinted laminated vehicle glazing |
| CN101428965A (zh) * | 2008-12-05 | 2009-05-13 | 福耀玻璃工业集团股份有限公司 | 车窗用防紫外线玻璃 |
| US20110199674A1 (en) * | 2009-01-24 | 2011-08-18 | Martin Melcher | Laminate that screens infrared radiation, is transparent to visible light, and has an optical window that allows infrared light to pass, method for the production thereof, and use thereof |
| WO2015091106A1 (en) * | 2013-12-19 | 2015-06-25 | Agc Glass Europe | Glass sheet having high transmission of infrared radiation |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02258655A (ja) | 1988-12-16 | 1990-10-19 | Nippon Sheet Glass Co Ltd | 熱線反射性合せ板 |
| LU88486A1 (fr) * | 1994-05-11 | 1995-12-01 | Glaverbel | Verre gris sodo-calcique |
| US7783403B2 (en) | 1994-05-23 | 2010-08-24 | Automotive Technologies International, Inc. | System and method for preventing vehicular accidents |
| DE60014633T3 (de) | 1999-05-20 | 2017-07-27 | Agc Flat Glass Europe Sa | Glasscheibe für kraftfahrzeuge miteiner durch sonnenlicht steurnden beschichtung versehen mit einem datenübertragungsfenster |
| WO2001014136A1 (en) | 1999-08-26 | 2001-03-01 | Glaverbel | Glazing |
| US20030228476A1 (en) | 2001-10-22 | 2003-12-11 | Harry Buhay | Methods of changing the visible light transmittance of coated articles and coated articles made thereby |
| DE102004017890A1 (de) | 2003-12-17 | 2005-07-21 | Daimlerchrysler Ag | Kraftfahrzeug mit sensorgesteuerten Sicherungssystemen |
| US7150916B2 (en) | 2004-03-11 | 2006-12-19 | Centre Luxembourg De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including tin oxide interlayer for high bend applications |
| DE102004050158B3 (de) | 2004-10-15 | 2006-04-06 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Transparente Scheibe mit einer beheizbaren Beschichtung |
| US8256821B2 (en) | 2004-12-15 | 2012-09-04 | Magna Donnelly Engineering Gmbh | Accessory module system for a vehicle window |
| JP5076896B2 (ja) * | 2005-08-16 | 2012-11-21 | 旭硝子株式会社 | 車両窓用合わせガラス |
| US8025957B2 (en) | 2007-05-09 | 2011-09-27 | Ppg Industries Ohio, Inc. | Vehicle transparency |
| GB0710808D0 (en) | 2007-06-06 | 2007-07-18 | Pilkington Automotive Ltd | Tinted laminated vehicle glazing |
| DE102007042028A1 (de) | 2007-09-05 | 2009-03-12 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Scheibe mit einem Detektor für elektromagnetische Strahlung |
| DE102008014089A1 (de) | 2008-03-13 | 2009-09-17 | Daimler Ag | Fahrzeug mit einer auf eine Fahrzeugscheibe gerichteten Kamera |
| BE1019346A3 (fr) | 2010-05-25 | 2012-06-05 | Agc Glass Europe | Vitrage de controle solaire. |
| US8664132B2 (en) | 2010-09-03 | 2014-03-04 | Ppg Industries Ohio, Inc. | High transmittance glass |
| BE1019905A3 (fr) | 2011-04-12 | 2013-02-05 | Agc Glass Europe | Vitrage chauffant. |
| BE1020296A3 (fr) | 2011-11-15 | 2013-07-02 | Agc Glass Europe | Feuille de verre a haute transmission energetique. |
| WO2014128016A1 (fr) | 2013-02-19 | 2014-08-28 | Agc Glass Europe | Feuille de verre à haute transmission aux rayonnements infrarouges |
| US20160018949A1 (en) | 2013-03-20 | 2016-01-21 | Agc Glass Europe | Glass sheet having high infrared radiation transmission |
| JP5683629B2 (ja) | 2013-03-27 | 2015-03-11 | オムロンオートモーティブエレクトロニクス株式会社 | レーザレーダ装置 |
| EP3909924B1 (fr) | 2013-05-07 | 2023-12-13 | AGC Glass Europe | Feuille de verre à haute transmission aux rayonnements infrarouges |
| GB201309386D0 (en) * | 2013-05-24 | 2013-07-10 | Pilkington Group Ltd | A Glazing |
| KR20150000095A (ko) | 2013-06-24 | 2015-01-02 | 현대모비스 주식회사 | 헤드업 디스플레이 장치 및 라이다 센서를 위한 윈드 실드 |
| US20160152511A1 (en) | 2013-07-24 | 2016-06-02 | Agc Glass Europe | High infrared transmission glass sheet |
| WO2015011041A1 (en) | 2013-07-24 | 2015-01-29 | Agc Glass Europe | High infrared transmission glass sheet |
| EP3024786B1 (en) | 2013-07-24 | 2020-06-24 | AGC Glass Europe | High infrared transmission glass sheet |
| JP2016525064A (ja) | 2013-07-24 | 2016-08-22 | エージーシー グラス ユーロップ | 高赤外線透過ガラスシート |
| US20160159681A1 (en) | 2013-07-24 | 2016-06-09 | Agc Glass Europe | High infrared transmission glass sheet |
| FR3010074B1 (fr) * | 2013-09-05 | 2019-08-02 | Saint-Gobain Glass France | Procede de fabrication d'un materiau comprenant un substrat muni d'une couche fonctionnelle a base d'oxyde d'etain et d'indium |
| US20150192677A1 (en) | 2014-01-03 | 2015-07-09 | Quanergy Systems, Inc. | Distributed lidar sensing system for wide field of view three dimensional mapping and method of using same |
| JP6843614B2 (ja) | 2014-05-08 | 2021-03-17 | 日本板硝子株式会社 | ウインドシールド |
| FR3021967B1 (fr) * | 2014-06-06 | 2021-04-23 | Saint Gobain | Procede d'obtention d'un substrat revetu d'une couche fonctionnelle |
| US9575184B2 (en) | 2014-07-03 | 2017-02-21 | Continental Advanced Lidar Solutions Us, Inc. | LADAR sensor for a dense environment |
| JP6035300B2 (ja) | 2014-09-18 | 2016-11-30 | 本田技研工業株式会社 | ノイズ除去機構 |
| CA2998306C (en) * | 2015-10-23 | 2020-05-05 | Saint-Gobain Glass France | Method for producing a composite pane having an infrared-reflecting coating on a carrier film |
| FR3046375A1 (fr) * | 2015-12-30 | 2017-07-07 | Saint Gobain | Vitrage feuillete de vehicule avec ecran amoled |
| JP6617565B2 (ja) * | 2016-01-06 | 2019-12-11 | Ａｇｃ株式会社 | 合わせガラス |
| EP3272718A1 (en) * | 2016-07-20 | 2018-01-24 | AGC Glass Europe | Glass sheet with a high luminous transmittance and warm-toned edges |
-
2017
- 2017-07-14 JP JP2019502789A patent/JP7145145B2/ja active Active
- 2017-07-14 CN CN201780053609.7A patent/CN109641786B/zh active Active
- 2017-07-14 EP EP17739997.9A patent/EP3487823B1/en active Active
- 2017-07-14 WO PCT/EP2017/067921 patent/WO2018015312A1/en unknown
- 2017-07-14 US US16/318,290 patent/US11407677B2/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973511A (en) * | 1988-12-01 | 1990-11-27 | Monsanto Company | Composite solar/safety film and laminated window assembly made therefrom |
| EP1462244A1 (en) * | 2003-03-28 | 2004-09-29 | Pilkington Automotive Limited | Tinted laminated vehicle glazing |
| CN101428965A (zh) * | 2008-12-05 | 2009-05-13 | 福耀玻璃工业集团股份有限公司 | 车窗用防紫外线玻璃 |
| US20110199674A1 (en) * | 2009-01-24 | 2011-08-18 | Martin Melcher | Laminate that screens infrared radiation, is transparent to visible light, and has an optical window that allows infrared light to pass, method for the production thereof, and use thereof |
| WO2015091106A1 (en) * | 2013-12-19 | 2015-06-25 | Agc Glass Europe | Glass sheet having high transmission of infrared radiation |
Non-Patent Citations (1)
| Title |
|---|
| 田英良、孙诗兵主编: "《新编玻璃工艺学》", 30 June 2009, 中国轻工业出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114126923A (zh) * | 2019-07-18 | 2022-03-01 | 旭硝子欧洲玻璃公司 | 用于自主汽车的玻璃 |
| CN112839804A (zh) * | 2019-09-20 | 2021-05-25 | 法国圣戈班玻璃厂 | 具有连接的近红外观察***的车辆用层压窗玻璃和装置 |
| CN115103764A (zh) * | 2020-12-01 | 2022-09-23 | 法国圣戈班玻璃厂 | 车辆用层压窗玻璃和具有连接的近红外视觉***的设备 |
| CN115226397A (zh) * | 2021-02-19 | 2022-10-21 | 法国圣戈班玻璃厂 | 层压窗玻璃、其制备方法和具有近红外视觉***的相关设备 |
| CN115226396A (zh) * | 2021-02-19 | 2022-10-21 | 法国圣戈班玻璃厂 | 层压窗玻璃、具有近红外视觉***的相关设备 |
| CN115416453A (zh) * | 2022-08-25 | 2022-12-02 | 重庆长安汽车股份有限公司 | 一种降低新能源汽车热负荷的玻璃及车辆 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3487823B1 (en) | 2020-06-03 |
| JP7145145B2 (ja) | 2022-09-30 |
| CN109641786B (zh) | 2022-07-15 |
| US11407677B2 (en) | 2022-08-09 |
| EP3487823A1 (en) | 2019-05-29 |
| JP2019527665A (ja) | 2019-10-03 |
| WO2018015312A1 (en) | 2018-01-25 |
| US20190225534A1 (en) | 2019-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109641786A (zh) | 用于自主汽车的玻璃 | |
| CN110461786A (zh) | 用于自主汽车的玻璃 | |
| US11613104B2 (en) | Glazing with optical device | |
| CN110461787A (zh) | 用于自主汽车的玻璃 | |
| CN110494401A (zh) | 用于自主汽车的玻璃 | |
| CN109641788A (zh) | 用于自主汽车的玻璃 | |
| JP2018537697A (ja) | Ｌｏｗ‐Ｅコーティングおよび容量性切換領域を有するパネルを含むパネル装置 | |
| EP3487720A1 (de) | Fensterscheibe mit kapazitivem schaltbereich zur berührungslosen steuerung einer funktion | |
| CN114126923A (zh) | 用于自主汽车的玻璃 | |
| CN110461785A (zh) | 用于自主汽车的玻璃 | |
| CN115742492A (zh) | 车窗玻璃及车辆 | |
| EA036101B1 (ru) | Стекло для автономного автомобиля | |
| EA041238B1 (ru) | Остекление с оптическим устройством | |
| EP4410756A1 (en) | Vehicle window assembly and vehicle | |
| EA037116B1 (ru) | Стекло для беспилотного автомобиля |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |