CN109554022A - A kind of cork paper and its preparation process with metal-like - Google Patents

A kind of cork paper and its preparation process with metal-like Download PDF

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Publication number
CN109554022A
CN109554022A CN201811453801.8A CN201811453801A CN109554022A CN 109554022 A CN109554022 A CN 109554022A CN 201811453801 A CN201811453801 A CN 201811453801A CN 109554022 A CN109554022 A CN 109554022A
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CN
China
Prior art keywords
parts
metal
paper
cork paper
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811453801.8A
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Chinese (zh)
Inventor
高春伟
苟鸿炜
黄宏明
黄玲
姜福荣
林晓伟
钱玉龙
盛明龙
张�浩
庄慧春
邹婷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Rongfeng Paper Co Ltd
Original Assignee
Zhejiang Rongfeng Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Rongfeng Paper Co Ltd filed Critical Zhejiang Rongfeng Paper Co Ltd
Priority to CN201811453801.8A priority Critical patent/CN109554022A/en
Publication of CN109554022A publication Critical patent/CN109554022A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/385Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46Non-macromolecular organic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of cork papers with metal-like, including body paper and with tailor-made oil ink print in the text and pattern of the initial surface;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The special ink is made of raw material from the following weight: 22~28 parts of aqueous polyurethane emulsion, 55~68 parts of polyacrylate dispersion, 11~14 parts of 1799 type poly-vinyl alcohol solution, 12~18 parts of mill base, 15~19 parts of filler, 0.2~0.4 part of defoaming agent, 0.2~0.35 part of levelling agent, 1.5~2.5 parts of thickener, 12~1.5 parts of alcohol ester, 1.2~1.8 parts of neopelex.The cork paper with metal-like that the present invention obtains has good metal-like, and glossiness is good, bright color, beautiful, popular with consumers;Special ink each component of the invention is uniformly dispersed, and is not likely to produce precipitating iso-metamorphism, and printing effect is good, and printing product has metal-like, surfacing;The mechanical properties such as wear-resisting, scratch-resistant, hardness of paint film are good.

Description

A kind of cork paper and its preparation process with metal-like
Technical field
The present invention relates to cigarette paper fields, and in particular to a kind of cork paper and its preparation process with metal-like.
Background technique
Cork paper (also known as " tipping paper ") be it is a kind of connected for cigarette with filter tip it is special with paper, be cigarette uniquely with The place of the lips and teeth contact of people.In the prior art, tipping paper prints on base paper for tipping paper by way of with ink printing coating Brush text, color and pattern make tipping paper meet the requirement of cigarette product.
Currently, the ink that many cork paper printing houses use mostly is the ink of alcohol-soluble and ester dissolubility, these ink groups Contain a large amount of volatile organic solvent in point, not only atmospheric environment is polluted, and prints water with the ink of this type After loose paper, cork paper surface can remain a certain amount of volatile organic solvent, there is certain harmfulness to human health.
Moreover, existing cork paper prints ink, color is single, and without metal-like, low in glossiness, color is bad; In addition, it is not wear-resisting, scratch-resistant, mechanical property be not poor.
Based on the above situation, the invention proposes a kind of cork paper and its preparation process with metal-like, can be effective Solve problem above.
Summary of the invention
The purpose of the present invention is to provide a kind of cork paper and its preparation process with metal-like.The present invention by Printing word and pattern form on aluminized paper, and use tailor-made oil ink print, bring out the best in each other, the obtained water with metal-like Loose paper has good metal-like, and glossiness is good, bright color, beautiful, popular with consumers;Special ink of the invention Each component is uniformly dispersed, and is not likely to produce precipitating iso-metamorphism, and printing effect is good, and printing product has metal-like, surfacing;It is resistance to The mechanical properties such as mill, scratch-resistant, hardness of paint film are good.
The present invention is achieved through the following technical solutions:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 22~28 parts of aqueous polyurethane emulsion, 55~68 parts of polyacrylate dispersion, 1799 types 11~14 parts of poly-vinyl alcohol solution, 12~18 parts of mill base, 15~19 parts of filler, 0.2~0.4 part of defoaming agent, levelling agent 0.2~ 0.35 part, 1.5~2.5 parts of thickener, 12~1.5 parts of alcohol ester, 1.2~1.8 parts of neopelex.
The present invention is formed by the printing word on aluminized paper and pattern, and uses tailor-made oil ink print, is brought out the best in each other, is obtained The cork paper with metal-like arrived has good metal-like, and glossiness is good, bright color, beautiful, by consumer blueness It looks at;Special ink each component of the invention is uniformly dispersed, and is not likely to produce precipitating iso-metamorphism, and printing effect is good, and printing product has Metal-like, surfacing;The mechanical properties such as wear-resisting, scratch-resistant, hardness of paint film are good.
In addition, based on aqueous polyurethane emulsion and polyacrylate dispersion, it is poly- to add suitable 1799 type by the present invention Glycohol solution is water-based ink, and no hazardous solvent is nontoxic, pollution-free, and adhesive force is strong, water-tolerant.
Preferably, the special ink is made of raw material from the following weight: 26 parts of aqueous polyurethane emulsion, polyacrylic acid 62.5 parts of ester lotion, 12.5 parts of 1799 type poly-vinyl alcohol solution, 16 parts of mill base, 17 parts of filler, 0.28 part of defoaming agent, levelling agent 0.26 part, 1.65 parts of thickener, 12 parts of alcohol ester, 1.55 parts of neopelex.
Preferably, the special ink is made of raw material from the following weight: 24.5 parts of aqueous polyurethane emulsion, polypropylene 60 parts of acid esters lotion, 11.5 parts of 1799 type poly-vinyl alcohol solution, 15.5 parts of mill base, 16.5 parts of filler, 0.33 part of defoaming agent, levelling 0.29 part of agent, 2.25 parts of thickener, 12 parts of alcohol ester, 1.6 parts of neopelex.
Preferably, the mass concentration of the 1799 type poly-vinyl alcohol solution is 2~3.5%.
The system phase same sex is good in this way, and modest viscosity.
Preferably, the filler is super fine calcium carbonate.
The super fine calcium carbonate for introducing proper proportion preferably increases the cork paper with metal-like of the invention The mechanical properties such as wear-resisting, scratch-resistant, hardness of paint film are improved.
Preferably, the partial size of the super fine calcium carbonate is 3~18nm.
It is hard that the wear-resisting of the cork paper with metal-like of the invention, scratch-resistant, paint film can be preferably increased in this way The mechanical properties such as degree are improved.
Preferably, the defoaming agent is organic silicone oil.
The defoaming agent has good Miscibility, and antifoaming speed is fast, and defoaming effect is good, can lasting foam inhibition.
Preferably, the levelling agent is the BOW-333 levelling agent of Shanghai gold cypress industry Co., Ltd.
BOW-333 levelling agent is smooth, smooth, equal after so that the cork paper with metal-like of the invention is printed It is even.
Preferably, the thickener is casein sodium.
Casein sodium is nontoxic, and health has good system thickening effect.
The present invention also provides a kind of preparation processes of cork paper with metal-like, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it printed with the resulting special ink of step C, finally The cork paper printed is moved into dry section, low temperature drying is carried out, obtains the cork paper with metal-like.
Compared with prior art, the present invention have the following advantages that and the utility model has the advantages that
The present invention is formed by the printing word on aluminized paper and pattern, and uses tailor-made oil ink print, is brought out the best in each other, is obtained The cork paper with metal-like arrived has good metal-like, and glossiness is good, bright color, beautiful, by consumer blueness It looks at;Special ink each component of the invention is uniformly dispersed, and is not likely to produce precipitating iso-metamorphism, and printing effect is good, and printing product has Metal-like, surfacing;The mechanical properties such as wear-resisting, scratch-resistant, hardness of paint film are good.
In addition, based on aqueous polyurethane emulsion and polyacrylate dispersion, it is poly- to add suitable 1799 type by the present invention Glycohol solution is water-based ink, and no hazardous solvent is nontoxic, pollution-free, and adhesive force is strong, water-tolerant.
Specific embodiment
The present invention is described in further detail below with reference to embodiment, embodiments of the present invention are not limited thereto.
Test method described in following embodiments or test method are unless otherwise specified conventional method;The reagent And material is obtained from routine business approach, or prepare in conventional manner unless otherwise specified.
Embodiment 1:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 22~28 parts of aqueous polyurethane emulsion, 55~68 parts of polyacrylate dispersion, 1799 types 11~14 parts of poly-vinyl alcohol solution, 12~18 parts of mill base, 15~19 parts of filler, 0.2~0.4 part of defoaming agent, levelling agent 0.2~ 0.35 part, 1.5~2.5 parts of thickener, 12~1.5 parts of alcohol ester, 1.2~1.8 parts of neopelex.
Embodiment 2:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 22~28 parts of aqueous polyurethane emulsion, 55~68 parts of polyacrylate dispersion, 1799 types 11~14 parts of poly-vinyl alcohol solution, 12~18 parts of mill base, 15~19 parts of filler, 0.2~0.4 part of defoaming agent, levelling agent 0.2~ 0.35 part, 1.5~2.5 parts of thickener, 12~1.5 parts of alcohol ester, 1.2~1.8 parts of neopelex.
Preferably, the special ink is made of raw material from the following weight: 26 parts of aqueous polyurethane emulsion, polyacrylic acid 62.5 parts of ester lotion, 12.5 parts of 1799 type poly-vinyl alcohol solution, 16 parts of mill base, 17 parts of filler, 0.28 part of defoaming agent, levelling agent 0.26 part, 1.65 parts of thickener, 12 parts of alcohol ester, 1.55 parts of neopelex.
Preferably, the special ink is made of raw material from the following weight: 24.5 parts of aqueous polyurethane emulsion, polypropylene 60 parts of acid esters lotion, 11.5 parts of 1799 type poly-vinyl alcohol solution, 15.5 parts of mill base, 16.5 parts of filler, 0.33 part of defoaming agent, levelling 0.29 part of agent, 2.25 parts of thickener, 12 parts of alcohol ester, 1.6 parts of neopelex.
Preferably, the mass concentration of the 1799 type poly-vinyl alcohol solution is 2~3.5%.
Preferably, the filler is super fine calcium carbonate.
Preferably, the partial size of the super fine calcium carbonate is 3~18nm.
Preferably, the defoaming agent is organic silicone oil.
Preferably, the levelling agent is the BOW-333 levelling agent of Shanghai gold cypress industry Co., Ltd.
Preferably, the thickener is casein sodium.
The preparation process of the cork paper with metal-like of the present embodiment, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it printed with the resulting special ink of step C, finally The cork paper printed is moved into dry section, low temperature drying is carried out, obtains the cork paper with metal-like.
Embodiment 3:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 22 parts of aqueous polyurethane emulsion, 55 parts of polyacrylate dispersion, 1799 type polyvinyl alcohol 11 parts of solution, 12 parts of mill base, 15 parts of filler, 0.2 part of defoaming agent, 0.2 part of levelling agent, 1.5 parts of thickener, 12 parts of alcohol ester, ten 1.2 parts of dialkyl benzene sulfonic acids sodium.
Preferably, the mass concentration of the 1799 type poly-vinyl alcohol solution is 2%.
Preferably, the filler is super fine calcium carbonate.
Preferably, the partial size of the super fine calcium carbonate is 3~18nm.
Preferably, the defoaming agent is organic silicone oil.
Preferably, the levelling agent is the BOW-333 levelling agent of Shanghai gold cypress industry Co., Ltd.
Preferably, the thickener is casein sodium.
The preparation process of the cork paper with metal-like of the present embodiment, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it printed with the resulting special ink of step C, finally The cork paper printed is moved into dry section, low temperature drying is carried out, obtains the cork paper with metal-like.
Embodiment 4:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 28 parts of aqueous polyurethane emulsion, 68 parts of polyacrylate dispersion, 1799 type polyvinyl alcohol 14 parts of solution, 18 parts of mill base, 19 parts of filler, 0.4 part of defoaming agent, 0.35 part of levelling agent, 2.5 parts of thickener, alcohol ester 12 Part, 1.8 parts of neopelex.
Preferably, the mass concentration of the 1799 type poly-vinyl alcohol solution is 3.5%.
Preferably, the filler is super fine calcium carbonate.
Preferably, the partial size of the super fine calcium carbonate is 3~18nm.
Preferably, the defoaming agent is organic silicone oil.
Preferably, the levelling agent is the BOW-333 levelling agent of Shanghai gold cypress industry Co., Ltd.
Preferably, the thickener is casein sodium.
The preparation process of the cork paper with metal-like of the present embodiment, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it printed with the resulting special ink of step C, finally The cork paper printed is moved into dry section, low temperature drying is carried out, obtains the cork paper with metal-like.
Embodiment 5:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 26 parts of aqueous polyurethane emulsion, 62.5 parts of polyacrylate dispersion, 1799 type polyethylene 12.5 parts of alcoholic solution, 16 parts of mill base, 17 parts of filler, 0.28 part of defoaming agent, 0.26 part of levelling agent, 1.65 parts of thickener, alcohol ester ten 2 1.35 parts, 1.55 parts of neopelex.
Preferably, the mass concentration of the 1799 type poly-vinyl alcohol solution is 3%.
Preferably, the filler is super fine calcium carbonate.
Preferably, the partial size of the super fine calcium carbonate is 3~18nm.
Preferably, the defoaming agent is organic silicone oil.
Preferably, the levelling agent is the BOW-333 levelling agent of Shanghai gold cypress industry Co., Ltd.
Preferably, the thickener is casein sodium.
The preparation process of the cork paper with metal-like of the present embodiment, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it printed with the resulting special ink of step C, finally The cork paper printed is moved into dry section, low temperature drying is carried out, obtains the cork paper with metal-like.
Embodiment 6:
A kind of cork paper with metal-like, including body paper and with tailor-made oil ink print in the text of the initial surface And pattern;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper;The tailor-made oil Ink is made of raw material from the following weight: 24.5 parts of aqueous polyurethane emulsion, 60 parts of polyacrylate dispersion, 1799 type polyethylene 11.5 parts of alcoholic solution, 15.5 parts of mill base, 16.5 parts of filler, 0.33 part of defoaming agent, 0.29 part of levelling agent, 2.25 parts of thickener, alcohol 12 parts of ester, 1.6 parts of neopelex.
Preferably, the mass concentration of the 1799 type poly-vinyl alcohol solution is 2.5%.
Preferably, the filler is super fine calcium carbonate.
Preferably, the partial size of the super fine calcium carbonate is 3~18nm.
Preferably, the defoaming agent is organic silicone oil.
Preferably, the levelling agent is the BOW-333 levelling agent of Shanghai gold cypress industry Co., Ltd.
Preferably, the thickener is casein sodium.
The preparation process of the cork paper with metal-like of the present embodiment, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it printed with the resulting special ink of step C, finally The cork paper printed is moved into dry section, low temperature drying is carried out, obtains the cork paper with metal-like.
Compared with prior art, the present invention have the following advantages that and the utility model has the advantages that
The present invention is formed by the printing word on aluminized paper and pattern, and uses tailor-made oil ink print, is brought out the best in each other, is obtained The cork paper with metal-like arrived has good metal-like, and glossiness is good, bright color, beautiful, by consumer blueness It looks at;Special ink each component of the invention is uniformly dispersed, and is not likely to produce precipitating iso-metamorphism, and printing effect is good, and printing product has Metal-like, surfacing;The mechanical properties such as wear-resisting, scratch-resistant, hardness of paint film are good.
The above is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is all according to According to technical spirit any simple modification to the above embodiments of the invention, equivalent variations, protection of the invention is each fallen within Within the scope of.

Claims (10)

1. a kind of cork paper with metal-like, it is characterised in that: including body paper and with tailor-made oil ink print in described original The text and pattern on surface;The body paper is aluminized paper;The text and pattern are printed in the layer surface of aluminizing of the aluminized paper; The special ink is made of raw material from the following weight: 22~28 parts of aqueous polyurethane emulsion, polyacrylate dispersion 55~ 68 parts, 11~14 parts of 1799 type poly-vinyl alcohol solution, 12~18 parts of mill base, 15~19 parts of filler, 0.2~0.4 part of defoaming agent, stream 0.2~0.35 part of flat agent, 1.5~2.5 parts of thickener, 12~1.5 parts of alcohol ester, 1.2~1.8 parts of neopelex.
2. the cork paper according to claim 1 with metal-like, it is characterised in that: the special ink is by following heavy The raw material of amount part is made: 26 parts of aqueous polyurethane emulsion, 62.5 parts of polyacrylate dispersion, 1799 type poly-vinyl alcohol solutions 12.5 Part, 16 parts of mill base, 17 parts of filler, 0.28 part of defoaming agent, 0.26 part of levelling agent, 1.65 parts of thickener, 12 parts of alcohol ester, ten 1.55 parts of dialkyl benzene sulfonic acids sodium.
3. the cork paper according to claim 1 with metal-like, it is characterised in that: the special ink is by following heavy The raw material of amount part is made: 24.5 parts of aqueous polyurethane emulsion, 60 parts of polyacrylate dispersion, 1799 type poly-vinyl alcohol solutions 11.5 Part, 15.5 parts of mill base, 16.5 parts of filler, 0.33 part of defoaming agent, 0.29 part of levelling agent, 2.25 parts of thickener, alcohol ester 12 Part, 1.6 parts of neopelex.
4. the cork paper according to claim 1 with metal-like, it is characterised in that: the 1799 type polyvinyl alcohol is molten The mass concentration of liquid is 2~3.5%.
5. the cork paper according to claim 1 with metal-like, it is characterised in that: the filler is ultra tiny carbonic acid Calcium.
6. the cork paper according to claim 1 with metal-like, it is characterised in that: the grain of the super fine calcium carbonate Diameter is 3~18nm.
7. the cork paper according to claim 1 with metal-like, it is characterised in that: the defoaming agent is organosilicon Oil.
8. the cork paper according to claim 1 with metal-like, it is characterised in that: the levelling agent is Shanghai gold cypress The BOW-333 levelling agent of wood industry Co., Ltd.
9. the cork paper according to claim 1 with metal-like, it is characterised in that: the thickener is caseinic acid Sodium.
10. a kind of a kind of preparation process of the cork paper with metal-like as described in any one of claim 1 to 9, special Sign is, including the following steps:
A, the raw material of special each parts by weight of ink is weighed;
B, the weighed raw material of step A institute is added in blending tank, using machine mixer, is allowed to uniformly mixed;
C, then into sand mill, 20~40min of grinding distribution obtains special ink for discharging;
D, aluminized paper is preheated, is installed on printing machine, it is printed with the resulting special ink of step C, it finally will print The cork paper brushed moves into dry section, carries out low temperature drying, obtains the cork paper with metal-like.
CN201811453801.8A 2018-11-30 2018-11-30 A kind of cork paper and its preparation process with metal-like Pending CN109554022A (en)

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Application publication date: 20190402