CN108373650A - A kind of aqueous PET ink for screen printing and preparation method thereof - Google Patents
A kind of aqueous PET ink for screen printing and preparation method thereof Download PDFInfo
- Publication number
- CN108373650A CN108373650A CN201810264699.0A CN201810264699A CN108373650A CN 108373650 A CN108373650 A CN 108373650A CN 201810264699 A CN201810264699 A CN 201810264699A CN 108373650 A CN108373650 A CN 108373650A
- Authority
- CN
- China
- Prior art keywords
- screen printing
- aqueous
- parts
- ink
- pet ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
Abstract
The present invention provides a kind of aqueous PET ink for screen printing and preparation method thereof.The aqueous PET ink for screen printing of the present invention, by weight, the raw material for preparing of the aqueous PET ink for screen printing includes following component：50~80 parts of polyester resin complex liquid, 10~20 parts of cosolvent, 0.1~0.5 part of dispersant, 0.5~1 part of antifoaming agent, 0.5~1 part of levelling agent, 0.5~1 part of acid-base balance agent, 2~8 parts of slow drying solvent, 8~35 parts of pigment, deionized water surplus.The preparation method of the present invention is simple for process, prepares raw material and is free of organic solvent, using water as solvent, aqueous PET ink for screen printing obtained has good adhesive force to base material, high glaze, and transparency is good, with excellent levelability, there is good load to pigment, dyestuff；There is good adhesive force to various plastic films；With good water resistance, uv-resistance and alcohol resistance；And smell is small, easy for construction.
Description
Technical field
The invention belongs to technical field of ink, it is related to a kind of aqueous PET ink for screen printing and preparation method thereof.
Background technology
PET ink for screen printing is a kind of for PET material (polyethylene terephthalate), PET adhesive labels, part
The ink that acrylic material thin film switch is produced, it is printed in material surface using screen printing mode, has excellent print
Brush workability and post-processing.Currently, PET ink in the market is essentially oil-based ink, containing a large amount of organic solvent, to ring
Border and human body have certain harm, and in recent years, the management and control due to market to organic solvent, people tend to the oil with environment-friendly type
Ink substitutes oil-based ink, and to mitigate the pollution to environment and the harm to human body, therefore, water-based ink becomes becoming for market development
Gesture.
Water-based ink is a kind of water-based ink, is free of or contains only a small amount of organic solvent, mainly using water as molten
Agent can not only be suitble to the growth requirement in market, can also reduce production cost.It has the property roughly the same with oil-based ink
Can, there is good attachment to base material, has good patience, and smell smaller, construction more convenient.
Water-based ink is ground through Compound Machining by water-soluble resin, advanced pigment, solvent and auxiliary agent.Water solubility tree
Fat mainly plays binder in ink, keeps granules of pigments evenly dispersed, enable ink have certain mobility, generate with
The adhesion strength of stock material makes ink form uniform film layer after printing.Form and aspect in ink depend primarily on pigment, face
Material is evenly distributed in binder with graininess, and granules of pigments, which can generate light, to be absorbed, reflection, reflects and transmit
Effect, therefore certain color can be presented.It is general to require pigment that there is bright-coloured color and luster, tinting strength, tinting power appropriate and covering power, with
And higher dispersion degree.The effect of solvent is dissolving resin, and ink is made to have certain mobility, can be suitable in printing process
Transfer is realized sharply, and the viscosity and drying property of ink are adjusted.The solvent of water-based ink is mainly water and a small amount of second
Alcohol.Usual auxiliaries mainly have：PH stable agent, drying retardant, antifoaming agent, diluent etc..
CN104804523A discloses a kind of PET material high viscosity UV solidifications ink for screen printing, and meter in parts by weight includes
Following component：20~30 parts of epoxy resin, 10~20 parts of polyurethane solutions, 15~25 parts of aldehyde ketone resin liquid, methacrylic acid contracting
1~5 part of water glyceride, 3~9 parts of adhesion promoter, 5~15 parts of Nano filling, 1~6 part of ultraviolet initiator, antifoaming agent 2
~7 parts, 3~8 parts of wetting agent, 8~15 parts of thickener.PET material prepared by the invention cures ink for screen printing with high viscosity UV, can
Instead of traditional solvent-based ink so that ink solidification speed is fast, environmentally friendly.But adhesion property needs further
It improves.
Invention content
In view of the deficiencies of the prior art, one of the objects of the present invention is to provide aqueous PET ink for screen printing, raw material is prepared not
Containing organic solvent, using water as solvent, there is good adhesive force to base material, high glaze, transparency is good, has excellent patience, and
And smell is small, it is easy for construction.
For this purpose, the present invention uses following technical scheme：
A kind of aqueous PET ink for screen printing, by weight, the raw material for preparing of the aqueous PET ink for screen printing includes as follows
Component：
Preferably, a kind of aqueous PET ink for screen printing of the invention, by weight, the system of the aqueous PET ink for screen printing
Standby raw material includes following component：
50~80 parts of polyester resin complex liquid, for example, polyester resin complex liquid parts by weight be 50 parts, 55 parts, 60 parts, 65
Part, 70 parts, 75 parts, 80 parts.
10~20 parts of cosolvent, for example, cosolvent parts by weight be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16
Part, 17 parts, 18 parts, 19 parts, 20 parts.
0.1~0.5 part of dispersant, such as the parts by weight of dispersant are 0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part.
0.5~1 part of antifoaming agent, such as the parts by weight of antifoaming agent are 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1 part.
0.5~1 part of levelling agent, such as the parts by weight of levelling agent are 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1 part.
0.5~1 part of acid-base balance agent, for example, acid-base balance agent parts by weight be 0.5 part, 0.6 part, 0.7 part, 0.8 part,
0.9 part, 1 part.
2~8 parts of slow drying solvent, such as the parts by weight of slow drying solvent are 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts.
8~35 parts of pigment, such as the parts by weight of pigment are 8 parts, 9 parts, 10 parts, 15 parts, 20 parts, 25 parts, 30 parts, 35 parts.
Deionized water surplus.
Aqueous PET ink for screen printing produced by the present invention, it has good attachment to PET material, has excellent printing
And flow leveling, also there is attachment to PC, PVC material, is equally applicable to the ABS material of part；Be widely used in electronic apparatus,
Everyday articles, stationery, the industries such as packages printing, advertising display, toy are a kind of brand-new plastic cement decorative inks, have
Extensive market prospects adapt to the development trend in epoch.
The polyester resin complex liquid is the mixture of aqueous saturated polyester lotion and water-soluble polyester；
Preferably, the mass ratio of the aqueous saturated polyester lotion and the water-soluble polyester is 1:(2~3), such as institute
The mass ratio for stating aqueous saturated polyester lotion and the water-soluble polyester is 1:2、1:2.1、1:2.2、1:2.3、1:2.4、1:
2.5、1:2.6、1:2.7、1:2.8、1:2.9、1:3。
The solid content of the aqueous saturated polyester lotion be 20~40%, such as solid content be 20%, 25%, 30%,
35%, 40%；Tg points be 50~60 DEG C, such as Tg points be 50 DEG C, 51 DEG C, 52 DEG C, 53 DEG C, 54 DEG C, 55 DEG C, 56 DEG C, 57 DEG C, 58
℃、59℃、60℃；Viscosity be 50~500cps, such as viscosity be 50cps, 100cps, 200cps, 300cps, 400cps,
500cps；PH is 7~7.5, such as pH is 7,7.1,7.2,7.3,7.4,7.5.
Preferably, the aqueous saturated polyester lotion is selected from WBS-3300, WBS- of Dongguan City Jing Jia trade Co., Ltds
One kind in 3000 and WZ-32008 or at least two mixture.
The solid content of the water-soluble polyester be 30~40%, such as solid content be 30%, 31%, 32%, 33%,
34%, 35%, 36%, 37%, 38%, 39%, 40%；Tg points be 50~70 DEG C, such as Tg points be 50 DEG C, 55 DEG C, 60 DEG C, 65
℃、70℃；PH is 4~5, such as pH is 4,4.1,4.2,4.3,4.4,4.5,4.6,4.7,4.8,4.9,5.
Preferably, the water-soluble polyester moral is selected from the MJ196-80 or Wuxi black cloth chemical industry of the bright resin Co., Ltd of celebrating
The TS-9196 of Co., Ltd.
The viscosity of the aqueous PET ink for screen printing be 20000~40000cps, such as viscosity be 20000cps,
25000cps、30000cps、35000cps、40000cps；PH is 7~7.5, such as pH is 7,7.1,7.2,7.3,7.4,7.5.
The mixture of the one kind or at least two of the cosolvent in butyl glycol ether, MMB and NMP.
One kind or at least two in dispersant 923,904 and 928 of the dispersant selected from De Qian Chemical Co., Ltd.s
Mixture.
The antifoaming agent Y105, T115's and Di Hui Chemical Co., Ltd.s of Foshan City selected from the new four seas Chemical Group in Hubei
One kind in DH-X2205 or at least two mixture.
Preferably, the levelling agent is selected from the BYK-411 and/or BYK-430 of BYK companies.
Preferably, the acid-base balance agent is selected from acid-base balance agent 920, MB-16 and the NB-11 of De Qian Chemical Co., Ltd.s
In one kind or at least two mixture.
Preferably, the slow drying solvent is selected from slow curing type alcohols and/or alcohol ester.
Preferably, the pigment is aqueous toner.
The second object of the present invention is to provide a kind of preparation method of aqueous PET ink for screen printing, the preparation method packet
Include following steps：
1) 10~20 parts of cosolvent, 50~80 parts of polyester resin complex liquid, deionized water by weight, is added,
Stirring and dissolving；
2) sequentially added in the mixture by weight, obtained to step 1) 0.1~0.5 part dispersant, 0.5~1
The levelling agent, 0.5~1 part of antifoaming agent, 0.5~1 part of acid-base balance agent, 2~8 parts of slow drying solvent of part, stir evenly；
3) 8~35 parts of pigment is added in the mixture by weight, obtained to step 2), stirs evenly；
4) the mixture milled processed for obtaining step 3) obtains the aqueous PET ink for screen printing.
In step 1), the stirring carries out in blender, and the time of the stirring is 1~3h.
Preferably, in step 4), the grinding carries out in grinder, and the pass of the grinding is 2~7 times, when
It when pigment is white and is colored, grinds 2~5 times, when pigment is black, grinds 6~7 times；It is polished described PET aqueous
The fineness of printing ink is 10 μm or less.
Compared with prior art, beneficial effects of the present invention are：
(1) aqueous PET ink for screen printing of the invention prepares raw material and is free of organic solvent, using water as solvent, by rationally adjusting
The type and proportioning of whole each raw material have the performance roughly the same with oil-based ink, have good adhesive force, bloom to base material
Pool, transparency is good, has excellent levelability, has good load to pigment, dyestuff；(such as to various plastic films
PET, PC, PVC etc.) there is good adhesive force；With good water resistance, uv-resistance and, alcohol resistance；And smell is small,
It is easy for construction.
(2) preparation method of aqueous PET ink for screen printing of the invention, preparation process is simple, environmentally safe, to human body
It is safe from harm, can not only be suitble to the growth requirement in market, production cost, alternative oil-based ink extensive use can also be reduced
In printing industry.
Specific implementation mode
The technical solution further illustrated the present invention below by specific implementation mode.
Unless specific instructions, various raw materials of the invention are commercially available buys, or is prepared according to the conventional method of this field
It obtains.
The aqueous PET ink for screen printing of the present invention, by weight, the raw material for preparing of the aqueous PET ink for screen printing includes
Following component：
The preparation method of the aqueous PET ink for screen printing of the present invention includes the following steps：
1) 10~20 parts of cosolvent, 50~80 parts of polyester resin complex liquid, deionized water by weight, is added,
Stirring and dissolving；
2) sequentially added in the mixture by weight, obtained to step 1) 0.1~0.5 part dispersant, 0.5~1
The levelling agent, 0.5~1 part of antifoaming agent, 0.5~1 part of acid-base balance agent, 2~8 parts of slow drying solvent of part, stir evenly；
3) 8~35 parts of pigment is added in the mixture by weight, obtained to step 2), stirs evenly；
4) the mixture milled processed for obtaining step 3) obtains the aqueous PET ink for screen printing.
The raw material of the aqueous PET ink for screen printing of the embodiment of the present invention 1-3 and proportioning comparison as shown in table 1, of the invention
The raw material and proportioning of the PET ink for screen printing of example 1-5 are as shown in table 2.
Table 1
Table 2
Ink made from aqueous PET ink for screen printing made from embodiment 1-3 and comparative example 1-5 is tested for the property,
Experimental result is as shown in table 3.
Wherein, the test method of adhesive force is：PET ink for screen printing is printed on cloth, 20 sights are firmly scraped with nail
It examines and whether falls, glued 20 times with 3M gummed papers and seen whether to fall.
The test method of ethanol-tolerant is：PET ink for screen printing is printed on cloth, is wiped 50 times with alcohol 500g power, is seen
Whether examine has significant change.
The test method of water resistance is：The cloth that PET ink for screen printing is printed is put into washing machine, temperature 50 C,
8h is washed, has seen whether obviously to fall off.
The test method of uv-resistance is：The printed cloth of PET ink for screen printing is tested 8 hours in UV machines, observation is
It is no to have xanthochromia.
Table 3
The aqueous PET ink for screen printing of the present invention prepares raw material and is free of organic solvent, using water as solvent, has and oiliness is oily
The roughly the same performance of ink, has good adhesive force to base material, and high glaze, transparency is good, has excellent levelability, to face
Material, dyestuff have good load；There is good adhesive force to various plastic films (such as PET, PC, PVC)；With good
Good water resistance, uv-resistance and alcohol resistance；And smell is small, easy for construction.The preparation of the aqueous PET ink for screen printing of the present invention
Method, preparation process is simple, environmentally safe, is safe from harm to human body, can not only be suitble to the growth requirement in market, also may be used
To reduce production cost, alternative oil-based ink is widely used in printing industry.
The present invention illustrates detailed process equipment and the technological process of the present invention by above-described embodiment, but the present invention is not
It is confined to above-mentioned detailed process equipment and technological process, that is, does not mean that the present invention has to rely on above-mentioned detailed process equipment and work
Skill flow could be implemented.Person of ordinary skill in the field is it will be clearly understood that any improvement in the present invention, to product of the present invention
The equivalence replacement of each raw material and the addition of auxiliary element, the selection of concrete mode etc., all fall within protection scope of the present invention and public affairs
Within the scope of opening.
Claims (10)
1. a kind of aqueous PET ink for screen printing, which is characterized in that by weight, the aqueous PET ink for screen printing prepares raw material
Including following component：
2. aqueous PET ink for screen printing according to claim 1, which is characterized in that the polyester resin complex liquid is aqueous
The mixture of saturated polyester lotion and water-soluble polyester；
Preferably, the mass ratio of the aqueous saturated polyester lotion and the water-soluble polyester is 1:(2~3).
3. aqueous PET ink for screen printing according to claim 2, which is characterized in that the aqueous saturated polyester lotion is consolidated
Content is that 20~40%, Tg points are 50~60 DEG C, and viscosity is 50~500cps, and pH is 7~7.5；
Preferably, the aqueous saturated polyester lotion is selected from WBS-3300, WBS-3000 of Dongguan City Jing Jia trade Co., Ltds
With in WZ-32008 one kind or at least two mixture.
4. aqueous PET ink for screen printing according to claim 2 or 3, which is characterized in that the solid content of the water-soluble polyester
It it is 50~70 DEG C for 30~40%, Tg points, pH is 4~5；
Preferably, the water-soluble polyester moral is selected from the MJ196-80 for celebrating the resin Co., Ltd that becomes clear or Wuxi black cloth chemical industry is limited
The TS-9196 of company.
5. the aqueous PET ink for screen printing according to one of claim 1-4, which is characterized in that the aqueous PET ink for screen printing
Viscosity be 20000~40000cps, pH be 7~7.5.
6. the aqueous PET ink for screen printing according to one of claim 1-5, which is characterized in that the cosolvent is selected from second two
One kind in alcohol butyl ether, MMB and NMP or at least two mixture.
7. the aqueous PET ink for screen printing according to claim 1-6 mono-, which is characterized in that the dispersant is selected from moral modestization
Learn Co., Ltd dispersant 923,904 and 928 in one kind or at least two mixture.
8. the aqueous PET ink for screen printing according to claim 1-7, which is characterized in that the antifoaming agent is selected from Hubei new four
Y105, T115 of extra large Chemical Group and one kind in the DH-X2205 of Di Hui Chemical Co., Ltd.s of Foshan City or at least two it is mixed
Close object；
Preferably, the levelling agent is selected from the BYK-411 and/or BYK-430 of BYK companies；
Preferably, in acid-base balance agent 920, MB-16 and NB-11 of the acid-base balance agent selected from De Qian Chemical Co., Ltd.s
It is a kind of or at least two mixture；
Preferably, the slow drying solvent is selected from slow curing type alcohols and/or alcohol ester；
Preferably, the pigment is aqueous toner.
9. a kind of preparation method of such as aqueous PET ink for screen printing of claim 1-8 any one of them, which is characterized in that described
Preparation method includes the following steps：
1) 10~20 parts of cosolvent, 50~80 parts of polyester resin complex liquid, deionized water, stirring by weight, is added
Dissolving；
2) sequentially added in the mixture by weight, obtained to step 1) 0.1~0.5 part dispersant, 0.5~1 part
Levelling agent, 0.5~1 part of antifoaming agent, 0.5~1 part of acid-base balance agent, 2~8 parts of slow drying solvent, stir evenly；
3) 8~35 parts of pigment is added in the mixture by weight, obtained to step 2), stirs evenly；
4) the mixture milled processed for obtaining step 3) obtains the aqueous PET ink for screen printing.
10. preparation method according to claim 9, which is characterized in that in step 1), it is described stirring be in blender into
Capable, the time of the stirring is 1~3h；
Preferably, in step 4), the grinding carries out in grinder, and the pass of the grinding is 2~7 times, ground
The fineness of the aqueous PET ink for screen printing is 10 μm or less afterwards.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810264699.0A CN108373650A (en) | 2018-03-28 | 2018-03-28 | A kind of aqueous PET ink for screen printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810264699.0A CN108373650A (en) | 2018-03-28 | 2018-03-28 | A kind of aqueous PET ink for screen printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108373650A true CN108373650A (en) | 2018-08-07 |
Family
ID=63031783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810264699.0A Pending CN108373650A (en) | 2018-03-28 | 2018-03-28 | A kind of aqueous PET ink for screen printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108373650A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804340A (en) * | 2019-11-22 | 2020-02-18 | 浙江龙游道明光学有限公司 | Single-component silk-screen printing ink for treatment-free PET (polyethylene terephthalate) material |
| CN111138904A (en) * | 2020-02-20 | 2020-05-12 | 深圳市崯涛油墨科技有限公司 | Composite board silk-screen printing ink with mirror-surface-protecting silver logo pattern and preparation method thereof |
| CN113308144A (en) * | 2021-06-18 | 2021-08-27 | 重庆智菱油墨科技有限公司 | Shading water-based ink and preparation method thereof |
| CN114196257A (en) * | 2021-12-27 | 2022-03-18 | 中山市中益油墨涂料有限公司 | Water-based silk-screen metal pigment printing ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409046A (en) * | 2013-08-20 | 2013-11-27 | 广东新供销天保再生资源发展有限公司 | Water-based PET (polyethylene terephthalate) undercoat paint, and preparation method and application thereof |
| CN106634188A (en) * | 2016-10-29 | 2017-05-10 | 李勇军 | PET water-based ink |
| CN107177234A (en) * | 2017-06-23 | 2017-09-19 | 福建东南艺术纸品股份有限公司 | A kind of ink and its production technology |
-
2018
- 2018-03-28 CN CN201810264699.0A patent/CN108373650A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409046A (en) * | 2013-08-20 | 2013-11-27 | 广东新供销天保再生资源发展有限公司 | Water-based PET (polyethylene terephthalate) undercoat paint, and preparation method and application thereof |
| CN106634188A (en) * | 2016-10-29 | 2017-05-10 | 李勇军 | PET water-based ink |
| CN107177234A (en) * | 2017-06-23 | 2017-09-19 | 福建东南艺术纸品股份有限公司 | A kind of ink and its production technology |
Non-Patent Citations (2)
| Title |
|---|
| 涂料工艺编委会编: "《涂料工艺（第三版）》", 31 December 1997, 化学工业出版社 * |
| 高晶等: "《柔性版印刷500问》", 30 September 2016, 文化发展出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804340A (en) * | 2019-11-22 | 2020-02-18 | 浙江龙游道明光学有限公司 | Single-component silk-screen printing ink for treatment-free PET (polyethylene terephthalate) material |
| CN111138904A (en) * | 2020-02-20 | 2020-05-12 | 深圳市崯涛油墨科技有限公司 | Composite board silk-screen printing ink with mirror-surface-protecting silver logo pattern and preparation method thereof |
| CN113308144A (en) * | 2021-06-18 | 2021-08-27 | 重庆智菱油墨科技有限公司 | Shading water-based ink and preparation method thereof |
| CN114196257A (en) * | 2021-12-27 | 2022-03-18 | 中山市中益油墨涂料有限公司 | Water-based silk-screen metal pigment printing ink and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108373650A (en) | A kind of aqueous PET ink for screen printing and preparation method thereof | |
| CN104263069B (en) | A kind of aqueous thermosetting glass printing ink and preparation method thereof | |
| CN101747818B (en) | Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof | |
| CN107266963B (en) | PVC decorative film gravure surface printing water-based ink and color diluted gold oil thereof | |
| CN107523143A (en) | A kind of general no fat mill base of water nano and preparation method thereof | |
| CN106833113B (en) | Ink suitable for glass hot bending forming and application of ink in mobile phone | |
| CN104449030B (en) | Solvent type gravure pearlescent ink and preparation method thereof | |
| CN103333544A (en) | Ultraviolet curing printing ink as well as preparation method and security product thereof | |
| CN107083138A (en) | A kind of glass wine bottle base material water soluble acrylic acid amido coatings soaked based on resistance to wine | |
| CN107418300A (en) | Acidproof etching protection ink and preparation method thereof and construction method | |
| CN102093780B (en) | Non-woven fabric environmental-protection water-based ink and preparation method thereof | |
| CN108641472A (en) | General plastic intaglio printing water-based ink and preparation method | |
| CN107325640A (en) | A kind of application of aqueous ink-jet inks in tipping paper digital printing technique | |
| CN105968942A (en) | LED-solidified water transfer printing ink and preparation method thereof | |
| CN108641573A (en) | A kind of sealer and preparation method thereof with the efficiently anti-muscle energy that rises | |
| CN107353795A (en) | A kind of water-based orange-peel paint of low VOC content | |
| CN107556815A (en) | A kind of water-based printing ink and preparation method thereof | |
| CN101475763B (en) | Printing ink printed on finishing oil and preparation thereof | |
| CN105925190A (en) | Anti-static and scratch-resisting transparent matte gloss oil | |
| CN103131256B (en) | Manufacturing method of soy-protein-type water-based decorative paper printing ink | |
| CN103232752B (en) | Screen printing ink for UV (ultraviolet) paint surface and preparation method thereof | |
| CN105949978A (en) | Antiaging high-covering-power matte gloss oil | |
| CN107400411B (en) | High-speed printing water-based gravure ink for non-absorbent substrate | |
| CN107337959B (en) | A kind of environmental printing ink | |
| CN109913040A (en) | A kind of aqueous chalk and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180807 |