CN1421498A - Easy-to-clean out aqueous metal-printing ink - Google Patents
Easy-to-clean out aqueous metal-printing ink Download PDFInfo
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- CN1421498A CN1421498A CN 02159173 CN02159173A CN1421498A CN 1421498 A CN1421498 A CN 1421498A CN 02159173 CN02159173 CN 02159173 CN 02159173 A CN02159173 A CN 02159173A CN 1421498 A CN1421498 A CN 1421498A
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Abstract
The easy-to-clean out aqueous metal-printing ink as one kind of water soluble printing material is compounded with connecting material, assistant, pigment and diluent. It may be used in printing and hot transferring metal foil and may be cleared and recovered at high temperature over 250 deg.c. It has no environmental pollution, and as one kind of newly developed clean printing material, it may be used widely in printing various metal foils and metal plates.
Description
Technical field
The invention belongs to the printing and dyeing material ranges, particularly a kind of water-based metal printing-ink of easy-clear.
Background technology
The printing ink that uses in printing industry generally all is to be used for paper printing or to be used for the printing ink print file, or the lettering that directly writes on metal, but this printing ink heatproof is low, and the objectionable constituent that contain can cause environmental pollution.Chinese patent 02124255.0,97111774.8 and 96101181.5 has proposed a kind of cleaning printing technology, directly stamps floral designs through the Printing Zone on tinsel, and the decorative pattern on the tinsel is transferred to decorative pattern on the stock by hot pressing; The residual decorative pattern that has on the tinsel can be eliminated, and clean tinsel is recycled to the Printing Zone and reuses.After realizing, this cleaning printing technology can solve a large amount of water consumptions of printing and dyeing link and serious water pollution problems.In order to realize this purpose, except exploitation corresponding apparatus and technology, also must a kind of special metallic printing ink of research.This printing ink not only will be realized good printing and hot transfer printing on tinsel, also need to have behind 250 ℃ of high temperature still can remove from tinsel, also reclaim and use a kind of like this special performance.This is the special performance that traditional printing ink of all kinds does not possess.
Summary of the invention
The object of the present invention is to provide the printing ink of the water-based metal printing with a kind of easy-clear, comprise and connect material, auxiliary agent, colorant, it is characterized in that: the quality percentage composition of the water-based metal printing-ink prescription of described easy-clear is: connect material 0.1～70%; Auxiliary agent 0.1-90%; Colorant 1-60%; Thinner 1-90%.
One or more mixtures in multipolymer, carboxymethyl or ethyl cellulose that described connection material is polyvinyl alcohol, polyacrylic ester and derivative thereof, aqueous polyurethane, vinylformic acid and acrylamide or sodium salt, stearate, alginates, water glass, xanthan gum, the Sudan Gum-arabic are to have certain toughness or the water-soluble material that becomes toughness of energy.
Described auxiliary agent is one or more a mixture of dispersion agent, weighting agent, flow agent, defoamer, anti, anti-settling agent, thickening material, oxidation inhibitor, sanitas, dryness conditioning agent, and majority is water-soluble or water-dispersible material.Described dispersion agent is the mixture of following one or more: 1. cats product, as vaccenic acid acetate; 2. anion surfactant is as sulfonated lignin; 3. nonionogenic tenside is as fatty alcohol-polyoxyethylene ether; 4. synthetic macromolecule class is as poly-third ethene and derivative thereof.Described weighting agent is the mixture of following one or both, and they are zinc oxide and lime carbonate.Described flow agent is the mixture of following one or more: water glass, cellulose ester, wilkinite, polyethylene wax.Described defoamer is the mixture of following one or more: defoamer AP, defoamer A10, defoamer SPA-102.Described anti is the mixture of following one or more: water-based oxidation inhibitor, as vitamins C, vitamin-E etc.; Uv-absorbing agent UV-531.Described anti-settling agent is the mixture of following one or more: vitriol, amide waxe etc.Described thickening material is the mixture of following one or more: nonionic polyoxyalkylene type oligopolymer, as thickening material SN, modified polyacrylic acid sodium, thickening material VD; Water soluble vinyl tetramethyleneimine multipolymer is as thickening material VL.Described oxidation inhibitor is the mixture of following one or more: oxidation inhibitor 1042, antioxidant 1076, salol.Described sanitas is the mixture of following one or more: phenylformic acid, diiodomethyl are to methyl sulfone, metrizamide 50, N-dimethyl-N-phenyl-N '-(dichloro n-formyl sarcolysine base sulfenyl) sulphamide, Po Ruiwante A4.Described dryness conditioning agent is the unleaded slurry of 46A.
Described colorant be active, disperse, alkalescence, oil is molten or vat dyes or pigment in one or more mixture.
Described thinner is a kind of in tap water, distilled water, deionized water or the softening water.
The invention has the beneficial effects as follows and on multiple tinsel, to realize good printing and hot transfer printing; Belong to water-soluble material, easy-clear reclaims, printing ink and tinsel can both be recycled, few or non-environmental-pollution, be widely used in various tinsels or metal sheet, its metal material can be the printing or the hot transfer printing of fine aluminium, various aluminium alloy, various stainless steel, various steel alloy, tinplate, non-retentive alloy etc.
Embodiment
The present invention is a kind of printing ink of water-based metal printing of easy-clear, comprises and connects material, auxiliary agent, colorant and thinner.The quality percentage composition of its ink formulations is: connect material 0.1～70%; Auxiliary agent 0.1-90%; Colorant 1-60%; Thinner 1-90%.Described connection material is one or more mixtures in polyvinyl alcohol, polyacrylic ester and derivative thereof, aqueous polyurethane, polyacrylamide, carboxymethyl (ethyl) Mierocrystalline cellulose (or sodium salt), stearate, alginates, water glass (water glass), xanthan gum, the Sudan Gum-arabic.Be to have certain toughness or the water-soluble material that becomes toughness of energy mostly.Described auxiliary agent is that dispersion agent, weighting agent, flow agent, defoamer, sanitas, oxidation inhibitor, anti-settling agent, anti, dryness conditioning agent, thickening material mostly are water-soluble or water-dispersible material greatly.Described colorant be active, disperse, alkalescence, oil is molten or vat dyes or pigment in one or more mixture.Described thinner is a kind of in tap water, distilled water, deionized water or the softening water, and the quality percentage composition of its preferred amount ranges is: connect material 0.5-50%; Auxiliary agent 0.1-15%; Colorant 2-50%; Thinner 10-70%.Illustrated for embodiment more below:
1, a blue ink of using on the aluminum or aluminum alloy
Connect material: polyacrylamide 0.6%
Stearate 1.0%
Auxiliary agent: dispersion agent 5,040 2.0%
Rheology modifier LAC 1.0%
Defoamer A10 0.5%
Thickening material 632 0.6%
Colorant: DISPERSE BLUE 2BLN 15.0%
Thinner: tap water 79.3%
2, the red ink of using on the iron/nickel alloy
Connect material: polyvinyl alcohol 5.0%
Auxiliary agent: dispersion agent TP01 2.0%
Rheology modifier LAC 1.0%
Defoamer A10 0.5%
Stearate 2.0
Phenylformic acid 0.5%
Colorant: Disperse Red 3B 4.0%
Thinner: tap water 85.0%
3, the Yellow ink of using on the stainless steel
Connect material: xanthan gum 10.0%
Sudan Gum-arabic 3.0%
Auxiliary agent: dispersion agent 1,204 2.0%
Rheology modifier LAC 1.0%
Defoamer A10 0.5%
Thickening material 635 0.6%
Colorant: DISPERSE YELLOW 54 5.0%
Thinner: tap water 82.4%
Claims (5)
1. the printing ink of the water-based metal of easy-clear printing comprises and connects material, auxiliary agent, colorant and thinner, and it is characterized in that: the quality percentage composition of the water-based metal printing-ink prescription of described easy-clear is: connect material 0.1～70%; Auxiliary agent 0.1-90%; Colorant 1-60%; Thinner 1-90%.
2. according to the printing ink of the water-based metal of the described easy-clear of claim 1 printing, it is characterized in that: described connection material is one or more mixtures in polyvinyl alcohol, polyacrylic ester and derivative thereof, aqueous polyurethane, polyacrylamide, carboxymethyl or ethyl cellulose or sodium salt, Fatty Alcohol(C12-C14 and C12-C18) stearate, alginates, water glass, xanthan gum, the Sudan Gum-arabic, is to have certain toughness or can the water-soluble material that becomes toughness.
3. according to the printing ink of the water-based metal of the described easy-clear of claim 1 printing, it is characterized in that: described auxiliary agent is one or more mixtures in dispersion agent, weighting agent, flow agent, defoamer, sanitas, oxidation inhibitor, anti-settling agent, anti, dryness conditioning agent, the thickening material.
4. according to the printing ink of the water-based metal of the described easy-clear of claim 1 printing, it is characterized in that: described colorant for active, disperse, alkalescence, oil is molten or vat dyes or pigment in one or more mixture.
5. according to the printing ink of the water-based metal of the described easy-clear of claim 1 printing, it is characterized in that: described thinner is a kind of in tap water, distilled water, deionized water or the softening water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02159173 CN100543092C (en) | 2002-12-30 | 2002-12-30 | The water-based metal printing-ink of easy-clear |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02159173 CN100543092C (en) | 2002-12-30 | 2002-12-30 | The water-based metal printing-ink of easy-clear |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1421498A true CN1421498A (en) | 2003-06-04 |
| CN100543092C CN100543092C (en) | 2009-09-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02159173 Expired - Fee Related CN100543092C (en) | 2002-12-30 | 2002-12-30 | The water-based metal printing-ink of easy-clear |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295861A (en) * | 2010-06-25 | 2011-12-28 | 深圳市顾康力化工有限公司 | Water-based ceramic ink |
| CN104263061A (en) * | 2014-08-29 | 2015-01-07 | 英德市雅家涂料有限公司 | Water-soluble grinding-free metal printing ink and preparation method thereof |
| CN104629523A (en) * | 2015-01-22 | 2015-05-20 | 阜阳丰成机械有限公司 | Rust-proof metal printing ink containing pepper essential oil |
| CN106366693A (en) * | 2016-08-05 | 2017-02-01 | 安徽金星包装有限公司 | Printing dye for tinplate |
| CN108047812A (en) * | 2018-01-24 | 2018-05-18 | 佛山市三水金恒金属制品有限公司 | One kind is used for metallic aluminium thermal transfer ink |
| CN108276824A (en) * | 2018-01-24 | 2018-07-13 | 佛山市三水金恒金属制品有限公司 | A kind of preparation method for metallic aluminium thermal transfer ink |
| CN109554022A (en) * | 2018-11-30 | 2019-04-02 | 浙江荣丰纸业有限公司 | A kind of cork paper and its preparation process with metal-like |
| CN111019431A (en) * | 2018-10-10 | 2020-04-17 | 江苏华尚汽车玻璃工业有限公司 | Preparation method of glass printing ink easy to remove |
| CN114231089A (en) * | 2021-12-29 | 2022-03-25 | 深圳市崯涛油墨科技有限公司 | Water-fading water-based protective ink and preparation method thereof |
-
2002
- 2002-12-30 CN CN 02159173 patent/CN100543092C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295861A (en) * | 2010-06-25 | 2011-12-28 | 深圳市顾康力化工有限公司 | Water-based ceramic ink |
| CN104263061A (en) * | 2014-08-29 | 2015-01-07 | 英德市雅家涂料有限公司 | Water-soluble grinding-free metal printing ink and preparation method thereof |
| CN104629523A (en) * | 2015-01-22 | 2015-05-20 | 阜阳丰成机械有限公司 | Rust-proof metal printing ink containing pepper essential oil |
| CN106366693A (en) * | 2016-08-05 | 2017-02-01 | 安徽金星包装有限公司 | Printing dye for tinplate |
| CN108047812A (en) * | 2018-01-24 | 2018-05-18 | 佛山市三水金恒金属制品有限公司 | One kind is used for metallic aluminium thermal transfer ink |
| CN108276824A (en) * | 2018-01-24 | 2018-07-13 | 佛山市三水金恒金属制品有限公司 | A kind of preparation method for metallic aluminium thermal transfer ink |
| CN111019431A (en) * | 2018-10-10 | 2020-04-17 | 江苏华尚汽车玻璃工业有限公司 | Preparation method of glass printing ink easy to remove |
| CN109554022A (en) * | 2018-11-30 | 2019-04-02 | 浙江荣丰纸业有限公司 | A kind of cork paper and its preparation process with metal-like |
| CN114231089A (en) * | 2021-12-29 | 2022-03-25 | 深圳市崯涛油墨科技有限公司 | Water-fading water-based protective ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100543092C (en) | 2009-09-23 |
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