CN109488895A - A kind of resistance to breakdown type LED lamp panel - Google Patents

A kind of resistance to breakdown type LED lamp panel Download PDF

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Publication number
CN109488895A
CN109488895A CN201811487019.8A CN201811487019A CN109488895A CN 109488895 A CN109488895 A CN 109488895A CN 201811487019 A CN201811487019 A CN 201811487019A CN 109488895 A CN109488895 A CN 109488895A
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resistance
glue
breakdown
type
led lamp
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CN201811487019.8A
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Chinese (zh)
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CN109488895B (en
Inventor
张彩霞
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Anhui Huangguang Industrial Co Ltd
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Anhui Huangguang Industrial Co Ltd
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Priority to CN201811487019.8A priority Critical patent/CN109488895B/en
Publication of CN109488895A publication Critical patent/CN109488895A/en
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Publication of CN109488895B publication Critical patent/CN109488895B/en
Expired - Fee Related legal-status Critical Current
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21KNON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K9/00Light sources using semiconductor devices as light-generating elements, e.g. using light-emitting diodes [LED] or lasers
    • F21K9/20Light sources comprising attachment means
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V23/00Arrangement of electric circuit elements in or on lighting devices
    • F21V23/003Arrangement of electric circuit elements in or on lighting devices the elements being electronics drivers or controllers for operating the light source, e.g. for a LED array
    • F21V23/004Arrangement of electric circuit elements in or on lighting devices the elements being electronics drivers or controllers for operating the light source, e.g. for a LED array arranged on a substrate, e.g. a printed circuit board
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • C08K2003/282Binary compounds of nitrogen with aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21YINDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
    • F21Y2115/00Light-generating elements of semiconductor light sources
    • F21Y2115/10Light-emitting diodes [LED]

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Insulated Metal Substrates For Printed Circuits (AREA)
  • Led Device Packages (AREA)

Abstract

The present invention relates to a kind of type of resistance to breakdown LED lamp panel, including LED aluminum base plate, the LED aluminum base plate includes aluminum layer and circuit layer, and the type of resistance to breakdown insulating layer is provided between the aluminum layer and circuit layer.Epoxyn is prepared in closed stirred tank, it is passed through ozone stirring inside to stirred tank, the first glue is made, first glue obtains the second glue after filtering using magnetic filter, adhesive coated foil is made in the hair side that second glue is coated in copper foil, the back side of adhesive coated foil is folded with aluminium sheet, it is put into vacuum press progress vacuum hotpressing and obtains aluminum-based copper-clad plate, aluminum-based copper-clad plate is processed to obtain the type of the resistance to breakdown LED lamp panel according to PCB processing procedure.The thermal diffusivity of the type of the resistance to breakdown LED lamp panel is good, and breakdown voltage value promotion has 70%, and resistance to sparking can be excellent.

Description

A kind of resistance to breakdown type LED lamp panel
Technical field
The present invention relates to a kind of type of resistance to breakdown LED lamp panels, belong to LED lamp technical field.
Background technique
LED light has that small in size, power consumption is low, long service life, high brightness, low in calories, sturdy and durable, changeable etc. are excellent Point gradually replaces incandescent lamp in the status in lamps and lanterns market.
For aluminum substrate as substrate most important in LED light, aluminum substrate is that a kind of Metal Substrate with good heat radiating function is covered Copper sheet, general single sided board are made of three-decker, are circuit layer (copper foil), insulating layer and metal-based layer respectively.It is common in LED Illuminating product.There are tow sides, white is welding LED pin on one side, and another side is presented aluminium true qualities, can generally smear thermally conductive It is contacted after solidifying slurry with thermal conduction portions.The breakdown voltage of LED light depends primarily on the dielectric strength of insulating layer.For example, current 75 μ The breakdown voltage of m insulating layer is typically not greater than 5KV (AC), and it is digital in powerful automotive electronics, household electrical appliances that this just limits LED lamp panel The service life in equal fields.
Summary of the invention
The present invention is in view of the deficienciess of the prior art, provide a kind of type of resistance to breakdown LED lamp panel, specific technical solution is such as Under:
A kind of resistance to breakdown type LED lamp panel, including LED aluminum base plate, the LED aluminum base plate include aluminum layer and circuit layer, institute It states and is provided with the type of resistance to breakdown insulating layer between aluminum layer and circuit layer.
As an improvement of the above technical solution, the type of the resistance to breakdown insulating layer the production method is as follows: in closed stirring Kettle prepares epoxyn, the first glue then is made to being passed through ozone stirring inside stirred tank, the first glue uses magnetic The second glue is obtained after filter filtering, the hair side that the second glue is coated in copper foil is toasted 1~3 minute at 200~230 DEG C and is made At adhesive coated foil, the back side of adhesive coated foil is the coating formed after the second glue semi-solid preparation, by the back side of adhesive coated foil and aluminium Plate is folded, and is put into vacuum press and is carried out vacuum hotpressing, is in 180~200 DEG C, the pressure of 0.9~1.1Mpa and vacuum degree Hot pressing 30~50 minutes in the environment of 70~80kpa, natural cooling obtains aluminum-based copper-clad plate after the completion of hot pressing, to aluminum-based copper-clad plate It is processed according to PCB processing procedure, copper foil is processed to circuit layer, and aluminium sheet is processed to aluminum layer, and the coating of semi-solid preparation is solidifying After form the type of resistance to breakdown insulating layer.
As an improvement of the above technical solution, the epoxyn is by epoxy resin, tertiary amines curing agent, miaow Azole promotor, silane coupling agent, heat filling, solvent are according to mass ratio (100~120): (3.5~4.3): (1.2~ 1.6): (2.9~3.6): (80~95): the ratio mixing of (40~55) is made.
As an improvement of the above technical solution, the mass ratio between the ozone and epoxyn be (0.75~ 1):1000。
As an improvement of the above technical solution, after being passed through ozone to the inside of stirred tank, the temperature inside stirred tank is mentioned It rises to 50~55 DEG C and stirs 60~70 minutes at such a temperature and the first glue is made.
As an improvement of the above technical solution, the magnetic filter includes circular electromagnet, and the electromagnet includes iron Shell and the electromagnetic coil inside iron-clad;The inner ring of the electromagnet 31 is provided with strainer;The strainer includes iron net body, institute The edge and iron-clad for stating iron net body are welded to connect, and the iron net body is externally coated with polytetrafluorethylecoatings coatings.
As an improvement of the above technical solution, first glue is when flowing through strainer, to the electromagnetic coil in electromagnet It is powered, electromagnetic coil energization generates magnetic force and iron-clad and iron net body are magnetized, so as to the magnetism that will contain in the first glue Impurity removes, and finally obtains the second glue.
Beneficial effects of the present invention:
It is optimized by the manufacture craft to LED aluminum base plate in existing LED lamp panel, the type of the resistance to breakdown LED light The thermal diffusivity of plate is good, compares existing LED lamp panel, and the breakdown voltage value promotion of LED lamp panel of the present invention has 70%, resistance to breakdown It has excellent performance;LED lamp panel of the present invention is especially suitable for fields such as high-powered automobiles electronics, household electrical appliances numbers.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the type of resistance to breakdown LED lamp panel of the present invention;
Fig. 2 is the structural schematic diagram of LED aluminum base plate of the present invention;
Fig. 3 is the structural schematic diagram of magnetic filter of the present invention.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
Embodiment 1
As shown in Fig. 1~2, the type of the resistance to breakdown LED lamp panel, including LED aluminum base plate 10, the LED aluminum base plate 10 include Aluminum layer 11 and circuit layer 13 are provided with the type of resistance to breakdown insulating layer 12 between the aluminum layer 11 and circuit layer 13.
Prepare epoxyn in closed stirred tank, by 100kg epoxy resin, 3.5kg tertiary amines curing agent, Epoxide-resin glue is made in 1.2kg imidazoles promotor, 2.9kg silane coupling agent, 80kg heat filling, the mixing of 40kg solvent Stick.Then the first glue is made to being passed through ozone stirring inside stirred tank, between the ozone and epoxyn Mass ratio is 0.75:1000.After being passed through ozone to the inside of stirred tank, the temperature inside stirred tank is promoted to 50 DEG C and at this At a temperature of stir 60 minutes the first glue be made.
As shown in figure 3, the magnetic filter includes circular electromagnet 31, the electromagnet 31 is including iron-clad and is located at iron Electromagnetic coil inside shell;The inner ring of the electromagnet 31 is provided with strainer 32;The strainer 32 includes iron net body, the iron net The edge and iron-clad of body are welded to connect, and the iron net body is externally coated with polytetrafluorethylecoatings coatings.First glue is flowing It when through strainer 32, is powered to the electromagnetic coil in electromagnet 31, electromagnetic coil energization generates magnetic force and makes iron-clad and iron net body magnetic Change, the magnetic impurity so as to contain in the first glue removes, and finally obtains the second glue.
First glue obtains the second glue after filtering using magnetic filter, the hair side that the second glue is coated in copper foil is existed 200 DEG C of bakings are made adhesive coated foil for 3 minutes, and the back side of adhesive coated foil is the coating formed after the second glue semi-solid preparation, will apply The back side of glue copper foil is folded with aluminium sheet, is put into vacuum press and is carried out vacuum hotpressing, in 180 DEG C, the pressure of 1.1Mpa and true Reciprocal of duty cycle is hot pressing 50 minutes in the environment of 70kpa, and natural cooling obtains aluminum-based copper-clad plate after the completion of hot pressing, presses to aluminum-based copper-clad plate It is processed according to PCB processing procedure, copper foil is processed to circuit layer 13, and aluminium sheet is processed to aluminum layer 11, and the coating of semi-solid preparation is solid The type of resistance to breakdown insulating layer 12 is formed after change.
The type of the resistance to breakdown insulating layer 12 with a thickness of 75 μm, the breakdown voltage of LED aluminum base plate 10 is 8.5KV (AC).
Embodiment 2
Structure phase of the structure of the LED lamp panel of the type of resistance to breakdown described in the present embodiment with the type of resistance to breakdown LED lamp panel in embodiment 1 Together.The structure of magnetic filter described in the present embodiment is identical as the structure of magnetic filter in embodiment 1.
Prepare epoxyn in closed stirred tank, by 110kg epoxy resin, 4kg tertiary amines curing agent, Epoxy resin gluing is made in 1.5kg imidazoles promotor, 3kg silane coupling agent, 90kg heat filling, the mixing of 50kg solvent Agent.Then the first glue is made to being passed through ozone stirring inside stirred tank, the matter between the ozone and epoxyn Amount is than being 0.9:1000.After being passed through ozone to the inside of stirred tank, the temperature inside stirred tank is promoted to 53 DEG C and in the temperature The first glue is made in 66 minutes in the lower stirring of degree.
First glue obtains the second glue after filtering using magnetic filter, the hair side that the second glue is coated in copper foil is existed 220 DEG C of bakings are made adhesive coated foil for 2 minutes, and the back side of adhesive coated foil is the coating formed after the second glue semi-solid preparation, will apply The back side of glue copper foil is folded with aluminium sheet, is put into vacuum press and is carried out vacuum hotpressing, in 190 DEG C, the pressure and vacuum of 1Mpa Degree be 75kpa in the environment of hot pressing 35 minutes, natural cooling obtains aluminum-based copper-clad plate after the completion of hot pressing, to aluminum-based copper-clad plate according to PCB processing procedure is processed, and copper foil is processed to circuit layer 13, and aluminium sheet is processed to aluminum layer 11, and the coating of semi-solid preparation is solidifying After form the type of resistance to breakdown insulating layer 12.
The type of the resistance to breakdown insulating layer 12 with a thickness of 75 μm, the breakdown voltage of LED aluminum base plate 10 is 9KV (AC).
Embodiment 3
Structure phase of the structure of the LED lamp panel of the type of resistance to breakdown described in the present embodiment with the type of resistance to breakdown LED lamp panel in embodiment 1 Together.The structure of magnetic filter described in the present embodiment is identical as the structure of magnetic filter in embodiment 1.
Prepare epoxyn in closed stirred tank, by 120kg epoxy resin, 4.3kg tertiary amines curing agent, Epoxide-resin glue is made in 1.6kg imidazoles promotor, 3.6kg silane coupling agent, 95kg heat filling, the mixing of 55kg solvent Stick.Then the first glue is made to being passed through ozone stirring inside stirred tank, between the ozone and epoxyn Mass ratio is 1:1000.After being passed through ozone to the inside of stirred tank, the temperature inside stirred tank is promoted to 55 DEG C and in the temperature The first glue is made in 60 minutes in the lower stirring of degree.
First glue obtains the second glue after filtering using magnetic filter, the hair side that the second glue is coated in copper foil is existed 230 DEG C of bakings are made adhesive coated foil for 1 minute, and the back side of adhesive coated foil is the coating formed after the second glue semi-solid preparation, will apply The back side of glue copper foil is folded with aluminium sheet, is put into vacuum press and is carried out vacuum hotpressing, in 200 DEG C, the pressure of 0.9Mpa and true Reciprocal of duty cycle is hot pressing 30 minutes in the environment of 80kpa, and natural cooling obtains aluminum-based copper-clad plate after the completion of hot pressing, presses to aluminum-based copper-clad plate It is processed according to PCB processing procedure, copper foil is processed to circuit layer 13, and aluminium sheet is processed to aluminum layer 11, and the coating of semi-solid preparation is solid The type of resistance to breakdown insulating layer 12 is formed after change.
The type of the resistance to breakdown insulating layer 12 with a thickness of 75 μm, the breakdown voltage of LED aluminum base plate 10 is 8.5KV (AC).
In the above-described embodiments, the heat filling is aluminium nitride, aluminium oxide, aluminium nitride, boron nitride, silicon carbide, oxidation One of magnesium is several.The addition of heat filling can significantly improve the thermal coefficient of the type of resistance to breakdown insulating layer 12.It is described molten Agent is one of ethyl alcohol, acetone, butanone, dimethylformamide, propylene glycol monomethyl ether or several.
It is well known that the dielectric strength of the type of resistance to breakdown insulating layer 12 depends primarily on heat filling in epoxyn Metal impurities amount, metal impurities are since itself can be conductive, and metals content impurity is higher, the type of resistance to breakdown insulating layer 12 Dielectric strength is smaller.Heat filling is usually all to carry out comminution process using metal grinding device, in crushing process, due to Phase mutual friction causes to contain a small amount of metal impurities inside heat filling, it can be common that iron tramp.By to epoxy resin gluing The mode for being passed through ozone inside agent and heating, so that the metal impurities inside epoxyn are oxidized to corresponding oxidation Object, in addition to ferroso-ferric oxide, remaining metal oxide is non-conductive or electric conductivity is very faint, this can significantly improve resistance to breakdown The dielectric strength of type insulating layer 12.Ferroso-ferric oxide is known as magnetic iron oxide, can be adsorbed by magnet.In such a way that magnetic is overanxious The ferroso-ferric oxide that epoxyn contains can be reduced to greatest extent.By double filtration, epoxyn The conductive impurities content that inside is contained is preferably minimized, and the dielectric strength for finally solidifying the obtained type of resistance to breakdown insulating layer 12 is significant Enhancing, the breakdown voltage of the LED aluminum base plate 10 can reach 8.5KV (AC) or more.
In the filter, electromagnet 31 is that annular shape keeps the Distribution of Magnetic Field of its inner ring uniform, and it is miscellaneous to be conducive to raising ferromagnetism The adsorption effect of matter.The presence of the polytetrafluorethylecoatings coatings, which can be avoided, introduces new iron tramp.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (7)

1. a kind of type of resistance to breakdown LED lamp panel, including LED aluminum base plate, the LED aluminum base plate includes aluminum layer and circuit layer, spy Sign is, the type of resistance to breakdown insulating layer is provided between the aluminum layer and circuit layer.
2. a kind of type of resistance to breakdown LED lamp panel according to claim 1, which is characterized in that the type of the resistance to breakdown insulating layer The production method is as follows: epoxyn is prepared in closed stirred tank, then to being passed through ozone stirring system inside stirred tank At the first glue, the first glue obtains the second glue after filtering using magnetic filter, and the second glue is coated in the hair side of copper foil It is toasted at 200~230 DEG C and adhesive coated foil is made within 1~3 minute, the back side of adhesive coated foil is to be formed after the second glue semi-solid preparation Coating folds at the back side of adhesive coated foil with aluminium sheet, be put into vacuum press carry out vacuum hotpressing, 180~200 DEG C, 0.9~ The pressure and vacuum degree of 1.1Mpa is hot pressing 30~50 minutes in the environment of 70~80kpa, and natural cooling obtains after the completion of hot pressing To aluminum-based copper-clad plate, aluminum-based copper-clad plate is processed according to PCB processing procedure, copper foil is processed to circuit layer, and aluminium sheet is processed to Aluminum layer, the coating of semi-solid preparation form the type of resistance to breakdown insulating layer after hardening.
3. a kind of type of resistance to breakdown LED lamp panel according to claim 2, which is characterized in that the epoxyn is By epoxy resin, tertiary amines curing agent, imidazoles promotor, silane coupling agent, heat filling, solvent according to mass ratio (100~ 120): (3.5~4.3): (1.2~1.6): (2.9~3.6): (80~95): the ratio mixing of (40~55) is made.
4. a kind of type of resistance to breakdown LED lamp panel according to claim 2, which is characterized in that the ozone and epoxide-resin glue Mass ratio between stick is (0.75~1): 1000.
5. a kind of type of resistance to breakdown LED lamp panel according to claim 2, which is characterized in that smelly to being passed through inside stirred tank After oxygen, the temperature inside stirred tank is promoted to 50~55 DEG C and stirred at such a temperature the first glue is made within 60~70 minutes.
6. a kind of type of resistance to breakdown LED lamp panel according to claim 2, which is characterized in that the magnetic filter includes annulus Shape electromagnet, the electromagnet include iron-clad and the electromagnetic coil inside iron-clad;The inner ring of the electromagnet 31 is provided with Strainer;The strainer includes iron net body, and the edge and iron-clad of the iron net body are welded to connect, and the iron net body is externally coated with Polytetrafluorethylecoatings coatings.
7. a kind of type of resistance to breakdown LED lamp panel according to claim 6, it is characterised in that: first glue is flowing through filter When net, it is powered to the electromagnetic coil in electromagnet, electromagnetic coil energization generates magnetic force and iron-clad and iron net body is magnetized, so as to It is enough to remove the magnetic impurity contained in the first glue, finally obtain the second glue.
CN201811487019.8A 2018-12-06 2018-12-06 Breakdown-resistant LED lamp panel Expired - Fee Related CN109488895B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989000975A1 (en) * 1987-08-03 1989-02-09 Philipp Leicher Ozone generating apparatus
US20090053643A1 (en) * 2004-09-30 2009-02-26 Kyocera Mita Corporation Magnetic mono-component toner for developing electrostatic latent image and image forming method
CN102402082A (en) * 2010-09-13 2012-04-04 株式会社半导体能源研究所 Liquid crystal display device and method for manufacturing the same
CN102446711A (en) * 2011-11-28 2012-05-09 上海华力微电子有限公司 Method for manufacturing insulating layer in MIM (metal-insulator-metal) capacitor
CN103068154A (en) * 2012-12-19 2013-04-24 浙江远大电子开发有限公司 Aluminium base circuit board and manufacturing method thereof
CN103694644A (en) * 2013-12-30 2014-04-02 景旺电子科技(龙川)有限公司 Epoxy resin composition, metal-based copper-clad plate and manufacturing method thereof
CN203965574U (en) * 2014-07-25 2014-11-26 恩达电路(深圳)有限公司 Aluminium base pressure resistant testing device
CN105038671A (en) * 2015-06-12 2015-11-11 东莞翔思电子科技有限公司 LED aluminum substrate binder and LED aluminum substrate with same
CN106409450A (en) * 2016-09-26 2017-02-15 平高集团有限公司 Method of increasing vacuum surface flashover voltage of insulating dielectric material and modified insulating dielectric material

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989000975A1 (en) * 1987-08-03 1989-02-09 Philipp Leicher Ozone generating apparatus
US20090053643A1 (en) * 2004-09-30 2009-02-26 Kyocera Mita Corporation Magnetic mono-component toner for developing electrostatic latent image and image forming method
CN102402082A (en) * 2010-09-13 2012-04-04 株式会社半导体能源研究所 Liquid crystal display device and method for manufacturing the same
CN102446711A (en) * 2011-11-28 2012-05-09 上海华力微电子有限公司 Method for manufacturing insulating layer in MIM (metal-insulator-metal) capacitor
CN103068154A (en) * 2012-12-19 2013-04-24 浙江远大电子开发有限公司 Aluminium base circuit board and manufacturing method thereof
CN103694644A (en) * 2013-12-30 2014-04-02 景旺电子科技(龙川)有限公司 Epoxy resin composition, metal-based copper-clad plate and manufacturing method thereof
CN203965574U (en) * 2014-07-25 2014-11-26 恩达电路(深圳)有限公司 Aluminium base pressure resistant testing device
CN105038671A (en) * 2015-06-12 2015-11-11 东莞翔思电子科技有限公司 LED aluminum substrate binder and LED aluminum substrate with same
CN106409450A (en) * 2016-09-26 2017-02-15 平高集团有限公司 Method of increasing vacuum surface flashover voltage of insulating dielectric material and modified insulating dielectric material

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