CN109338728A - A kind of preparation method of the mould proof wallpaper of scrubbing resistance - Google Patents

A kind of preparation method of the mould proof wallpaper of scrubbing resistance Download PDF

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Publication number
CN109338728A
CN109338728A CN201811078418.9A CN201811078418A CN109338728A CN 109338728 A CN109338728 A CN 109338728A CN 201811078418 A CN201811078418 A CN 201811078418A CN 109338728 A CN109338728 A CN 109338728A
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wallpaper
obtains
deionized water
scrubbing resistance
preparation
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CN201811078418.9A
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胡次兵
周立
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Foshan Science And Technology Co Ltd
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Foshan Science And Technology Co Ltd
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Priority to CN201811078418.9A priority Critical patent/CN109338728A/en
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    • D—TEXTILES; PAPER
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
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    • D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
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    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
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    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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    • D06P1/613—Polyethers without nitrogen
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    • D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
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  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
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Abstract

The present invention relates to a kind of preparation methods of the mould proof wallpaper of scrubbing resistance, belong to wallpaper field.The present invention uses basilar fibers of the porous fibrous material as wallpaper, then basilar fibers is formed it into mixed and disorderly porous primary backing by water jet process, and the resin protection film of outer layer is also porous, these mixed and disorderly holes constitute the access of connecting wall and room air, the moisture of wall can be distributed by access, so that the mould proof wallpaper of scrubbing resistance has good gas permeability, aqueous vapor will not be made to gather between wall and wallpaper, causing wallpaper to tilt influences beauty, then in one layer of titanium dioxide nanoparticle of its surface uniform fold, the nano-titanium dioxide being distributed in access can carry out photocatalysis to the aqueous vapor of dealing, mould is prevented to breed, room air can also be purified simultaneously；Wallpaper is coated finally by resin material and sodium alginate, forms porous protective film, obtains the mould proof wallpaper of scrubbing resistance.

Description

A kind of preparation method of the mould proof wallpaper of scrubbing resistance
Technical field
The present invention relates to a kind of preparation methods of the mould proof wallpaper of scrubbing resistance, belong to wallpaper field.
Background technique
Wallpaper was the luxury goods that imperial palace noble specially enjoys at that time originating from the renaissant mural painting in Europe, now with The development of printing technology and Chemical Engineering Technology etc., one kind that printed matter gradually replaces mural painting and becomes Modern Interior Decoration common are built Ornament materials is built, it is using paper, plastics or non-woven fabrics as substrate, after coated or calendering, then through printing, embossing or foaming Etc. a kind of decorative material for wall surface made of techniques.
Current, as the improvement of people's living standards, wallpaper due to environmentally protective, luxurious style, texture it is soft, The advantages that colour image is abundant, decorative effect elegant and increasingly have been favored by people, especially in some developed countries, Oneself becomes popular house decorative material by warp with wallpaper, is all constantly increasing every year；And wallpaper is various informative, can satisfy not Same interest, the crowd of different hobby and different places finishing requirements, also can it is comfortable to people, loosen, warm life cycle In border, such as overseas play popular at present (such as Japan and Korea S., U.S. film, in TV play), it may be seen that its average family is sleeping The public places such as room, parlor and hotel, hotel, market, hospital, KTV mostly use wallpaper as ornament materials greatly.
Current domestic wallpaper mainly has natural material wallpaper and two kinds of textile fabric wallpaper.The natural wallpaper coloured silk of domestic production is used The natural fibers such as kudzu, sisal hemp, jute, tabernaemontanus bulrush grass, tabernaemontanus bulrush grass core, the stem or leaf of cattail, angelica, bamboo chip are raw material.Textile fabric wallpaper is with silk, sheep The fibers such as hair, silk floss, fiber crops are made into surface layer, using gauze or paper as substrate, through pressing.Present natural material wall wallpaper and textile fabric Wallpaper has been realized in environmental requirement in terms of raw materials for production, production process, product three.
Due to the difference of raw material, the decorative effect of wallpaper is far from each other.It is natural fiber kudzu, sisal hemp, jute, the stem or leaf of cattail, salty Wallpaper made of careless, tabernaemontanus bulrush grass, tabernaemontanus bulrush grass core, surface three-dimensional sense is strong, and decorative effect is obvious, mats formation and will increase the abundant of space in parlor Sense；Wallpaper made of textile fabric is relatively finer and smoother, mat formation bedroom, study can allow people feel the Nature cordiality with it is quiet.
However be close to due to wallpaper with wall in reality, moist wall or time-division in rainy season, there was dampness in the air, and the time is longer When, wallpaper gas permeability is bad, is extremely easy to become damp and rotten, and tilts and fades, and mould growth seriously affects beauty.It is existing mould proof The mode of addition chemical anti mildew agent is usually taken in wallpaper, and biohazardous is high and effect is less desirable.
Summary of the invention
The technical problems to be solved by the invention: being easy to cause moisture to gather due to poor air permeability for wallpaper now, The problem of mould breeds, proposes a kind of preparation method of mould proof wallpaper of scrubbing resistance.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
(1) it by polylactic acid, polycarbonate, polyethylene merging methylene chloride, stirs evenly, obtains spinning solution；
(2) spinning solution merging electrostatic spinning apparatus is subjected to spinning, obtains porous nano-fibre after dry 4h；
(3) porous nano-fibre is woven at cloth, it is then reinforced by water jet process, obtains fiber wallpaper；
(4) it takes polyoxethylene octylphenyl phenol ether and deionized water to stir evenly, obtains pretreatment fluid, fiber wallpaper is placed in pre- place In reason liquid and 30min is impregnated, obtains pre-processing fine wallpaper；
(5) it takes nano-titanium dioxide, lauryl sodium sulfate, vinyltriethoxysilane and deionized water to be uniformly mixed, surpasses Sound 30min obtains suspension, then will pre-process fine wallpaper and impregnates 30min in suspension, obtains fiber wallpaper；
(6) it takes polyvinyl alcohol and deionized water to be mixed and heated, obtains polyvinyl alcohol liquid, adjusted with 0.01mol/L hydrochloric acid solution The pH to 3 of polyvinyl alcohol liquid, obtains Acidic Liquid；
(7) 14mol/L formalin is added dropwise in oxytropism liquid, then adjusts pH to 8 with sodium hydroxide solution, obtains reaction solution A；
(8) it takes potassium bichromate, sodium tripolyphosphate, tributyl phosphate, polyacrylamide and deionized water to be mixed, is reacted Liquid B；
(9) aqueous fluorocarbon resin, ultramarine, fatty alcohol polyoxyethylene ether, sodium alginate, deionized water and reaction solution B, stirring are equal It is even, dyeing liquor is obtained, dyeing liquor pH is adjusted to 6 with acetum, then fiber wallpaper is dyed, is obtained after dry resistance to Clean mould proof wallpaper.
Step (1) polylactic acid, polycarbonate, polyethylene and methylene chloride mass ratio be 2:2:1:5.
Step (4) the polyoxethylene octylphenyl phenol ether and the mass ratio of deionized water are 1:20.
Step (5) nano-titanium dioxide, lauryl sodium sulfate, vinyltriethoxysilane and deionized water Mass ratio is 5:1:1:50.
Step (6) polyvinyl alcohol and the mass ratio of deionized water are 1:20.
Step (7) Acidic Liquid and the mass ratio of formalin are 8:1.
The quality of step (8) potassium bichromate, sodium tripolyphosphate, tributyl phosphate, polyacrylamide and deionized water Than for 1:2:1:1:20.
Step (9) the water-based fluorocarbon resin, ultramarine, fatty alcohol polyoxyethylene ether, sodium alginate, deionized water and reaction The mass ratio of liquid B is 20:2:1:2:60:20.
The present invention is compared with other methods, and advantageous effects are:
(1) basilar fibers of the porous fibrous material as wallpaper is used, then reinforces basilar fibers by water jet process Cheng Bu then in one layer of titanium dioxide nanoparticle of its surface uniform fold, and dyes it, finally by resin material Wallpaper is coated with sodium alginate, forms porous protective film, obtains the mould proof wallpaper of scrubbing resistance；
(2) porous nanofiber can provide sufficient attachment point for nano-titanium dioxide, and water jet process can be by fiber While reinforcing, form it into mixed and disorderly porous primary backing, and the resin protection film of outer layer be also it is porous, these are mixed and disorderly Hole constitutes the access of connecting wall and room air, and the moisture of wall can be distributed by access, so that scrubbing resistance Mould proof wallpaper has good gas permeability, and aqueous vapor will not be made to gather between wall and wallpaper, and causing wallpaper to tilt influences beauty It sees；
(3) nano-titanium dioxide being distributed in access can carry out photocatalysis to the aqueous vapor of dealing, have to what is be mingled in aqueous vapor Evil object and bacterial decomposition are killed, and prevent mould from breeding, while can also purify to room air.
Specific embodiment
By in 20 ~ 40g polylactic acid, 20 ~ 40g polycarbonate, 10 ~ 20g polyethylene merging 50 ~ 100g methylene chloride, stir Uniformly, spinning solution is obtained；Spinning solution merging electrostatic spinning apparatus is subjected to spinning, obtains porous nano-fibre after dry 4h；It will Porous nano-fibre is woven at cloth, is then reinforced by water jet process, obtains fiber wallpaper；Take 1 ~ 2g polyoxethylene octylphenyl phenol Ether and 20 ~ 40g deionized water stir evenly, and obtain pretreatment fluid, are placed in pretreatment fluid and impregnate 30min for fiber wallpaper, It obtains pre-processing fine wallpaper；Take 5 ~ 10g nano-titanium dioxide, 1 ~ 2g lauryl sodium sulfate, 1 ~ 2g vinyl triethoxyl silicon Alkane and 50 ~ 100g deionized water are uniformly mixed, and ultrasonic 30min obtains suspension, then will pre-process fine wallpaper in suspension 30min is impregnated, fiber wallpaper is obtained；It takes 2 ~ 4g polyvinyl alcohol and 40 ~ 80g deionized water to be mixed and heated, obtains polyvinyl alcohol Liquid adjusts the pH to 3 of polyvinyl alcohol liquid with 0.01mol/L hydrochloric acid solution, obtains Acidic Liquid；In oxytropism liquid be added dropwise 5 ~ Then 10g14mol/L formalin adjusts pH to 8 with 0.1mol/L sodium hydroxide solution, obtains reaction solution A；Take 1 ~ 2g weight chromium Sour potassium, 2 ~ 4g sodium tripolyphosphate, 1 ~ 2g tributyl phosphate, 1 ~ 2g polyacrylamide and 20 ~ 40g deionized water are mixed, and obtain To reaction solution B；Take 20 ~ 40g water-based fluorocarbon resin, 2 ~ 4g ultramarine, 1 ~ 2g fatty alcohol polyoxyethylene ether, 2 ~ 4g sodium alginate, 60 ~ 120g deionized water and 20 ~ 40g reaction solution B, stir evenly, obtain dyeing liquor, with 0.1mol/L acetum by dyeing liquor pH 6 are adjusted to, then fiber wallpaper is dyed, obtains the mould proof wallpaper of scrubbing resistance after dry.
By in 20g polylactic acid, 20g polycarbonate, 10g polyethylene merging 50g methylene chloride, stirs evenly, obtain spinning Liquid；Spinning solution merging electrostatic spinning apparatus is subjected to spinning, obtains porous nano-fibre after dry 4h；By porous nano-fibre machine It is made into cloth, is then reinforced by water jet process, obtains fiber wallpaper；Take 1g polyoxethylene octylphenyl phenol ether and 20g deionized water It stirs evenly, obtains pretreatment fluid, fiber wallpaper is placed in pretreatment fluid and impregnates 30min, obtain pre-processing fine wallpaper；It takes 5g nano-titanium dioxide, 1g lauryl sodium sulfate, 1g vinyltriethoxysilane and 50g deionized water are uniformly mixed, and are surpassed Sound 30min obtains suspension, then will pre-process fine wallpaper and impregnates 30min in suspension, obtains fiber wallpaper；Take 2g poly- Vinyl alcohol and 40g deionized water are mixed and heated, and obtain polyvinyl alcohol liquid, adjust polyvinyl alcohol with 0.01mol/L hydrochloric acid solution The pH to 3 of liquid, obtains Acidic Liquid；5g14mol/L formalin is added dropwise in oxytropism liquid, it is then molten with 0.1mol/L sodium hydroxide Liquid adjusts pH to 8, obtains reaction solution A；Take 1g potassium bichromate, 2g sodium tripolyphosphate, 1g tributyl phosphate, 1g polyacrylamide and 20g deionized water is mixed, and obtains reaction solution B；Take 20g water-based fluorocarbon resin, 2g ultramarine, 1g fatty alcohol polyoxyethylene ether, 2g sodium alginate, 60g deionized water and 20g reaction solution B, stir evenly, obtain dyeing liquor, will be contaminated with 0.1mol/L acetum Color liquid pH is adjusted to 6, then dyes to fiber wallpaper, obtains the mould proof wallpaper of scrubbing resistance after dry.
By in 30g polylactic acid, 30g polycarbonate, 15g polyethylene merging 75g methylene chloride, stirs evenly, obtain spinning Liquid；Spinning solution merging electrostatic spinning apparatus is subjected to spinning, obtains porous nano-fibre after dry 4h；By porous nano-fibre machine It is made into cloth, is then reinforced by water jet process, obtains fiber wallpaper；Take 1.5g polyoxethylene octylphenyl phenol ether and 30g deionization Water stirs evenly, and obtains pretreatment fluid, and fiber wallpaper is placed in pretreatment fluid and impregnates 30min, obtains pre-processing fine wallpaper； Take 7g nano-titanium dioxide, 1.5g lauryl sodium sulfate, 1.5g vinyltriethoxysilane and the mixing of 75g deionized water equal Even, ultrasonic 30min obtains suspension, then will pre-process fine wallpaper and impregnates 30min in suspension, obtains fiber wallpaper；It takes 3g polyvinyl alcohol and 60g deionized water are mixed and heated, and obtain polyvinyl alcohol liquid, adjust poly- second with 0.01mol/L hydrochloric acid solution The pH to 3 of enol liquid, obtains Acidic Liquid；7g14mol/L formalin is added dropwise in oxytropism liquid, then uses 0.1mol/L hydroxide Sodium solution adjusts pH to 8, obtains reaction solution A；Take 1.5g potassium bichromate, 3g sodium tripolyphosphate, 1.5g tributyl phosphate, 1.5g poly- Acrylamide and 30g deionized water are mixed, and obtain reaction solution B；Take 30g water-based fluorocarbon resin, 3g ultramarine, 1.5g fatty alcohol Polyoxyethylene ether, 3g sodium alginate, 80g deionized water and 30g reaction solution B, stir evenly, obtain dyeing liquor, use 0.1mol/L Dyeing liquor pH is adjusted to 6 by acetum, is then dyed to fiber wallpaper, obtains the mould proof wallpaper of scrubbing resistance after dry.
By in 40g polylactic acid, 40g polycarbonate, 20g polyethylene merging 100g methylene chloride, stirs evenly, obtain spinning Liquid；Spinning solution merging electrostatic spinning apparatus is subjected to spinning, obtains porous nano-fibre after dry 4h；By porous nano-fibre machine It is made into cloth, is then reinforced by water jet process, obtains fiber wallpaper；Take 2g polyoxy
Ethylene octyl phenol ether and 40g deionized water stir evenly, and obtain pretreatment fluid, and fiber wallpaper is placed in pretreatment fluid And 30min is impregnated, it obtains pre-processing fine wallpaper；Take 10g nano-titanium dioxide, 2g lauryl sodium sulfate, three second of 2g vinyl Oxysilane and 100g deionized water are uniformly mixed, and ultrasonic 30min obtains suspension, then will be pre-processed fine wallpaper and are being suspended 30min is impregnated in liquid, obtains fiber wallpaper；It takes 4g polyvinyl alcohol and 80g deionized water to be mixed and heated, obtains polyvinyl alcohol Liquid adjusts the pH to 3 of polyvinyl alcohol liquid with 0.01mol/L hydrochloric acid solution, obtains Acidic Liquid；It is added dropwise in oxytropism liquid Then 10g14mol/L formalin adjusts pH to 8 with 0.1mol/L sodium hydroxide solution, obtains reaction solution A；Take 2g dichromic acid Potassium, 4g sodium tripolyphosphate, 2g tributyl phosphate, 2g polyacrylamide and 40g deionized water are mixed, and obtain reaction solution B；It takes 40g water-based fluorocarbon resin, 4g ultramarine, 2g fatty alcohol polyoxyethylene ether, 4g sodium alginate, 120g deionized water and 40g reaction solution B is stirred evenly, and obtains dyeing liquor, and dyeing liquor pH is adjusted to 6 with 0.1mol/L acetum, is then carried out to fiber wallpaper Dyeing obtains the mould proof wallpaper of scrubbing resistance after dry.The mould proof wallpaper of scrubbing resistance prepared by the present invention and existing wallpaper is taken to be detected, Specific testing result such as following table table 1:
Detection method: measuring according to GB/T 3920-2008 " textile color stability test colour fastness to rubbing ", and color fastness is commented Grade is evaluated by GB/T 251-2008 " textile color stability test evaluation staining gray scale ", with grade the lowest For final test result.
The mould proof wallpaper performance characterization of 1 scrubbing resistance of table
The mould proof wallpaper of scrubbing resistance prepared by the present invention as shown in Table 1, abrasion-resistant ability and washability are all very strong, have wide city Field value and application prospect.

Claims (8)

1. a kind of preparation method of scrubbing resistance antibacterial wallpaper, which is characterized in that specific production step are as follows:
(1) it by polylactic acid, polycarbonate, polyethylene merging methylene chloride, stirs evenly, obtains spinning solution；
(2) spinning solution merging electrostatic spinning apparatus is subjected to spinning, obtains porous nano-fibre after dry 4h；
(3) porous nano-fibre is woven at cloth, it is then reinforced by water jet process, obtains fiber wallpaper；
(4) it takes polyoxethylene octylphenyl phenol ether and deionized water to stir evenly, obtains pretreatment fluid, fiber wallpaper is placed in pre- place In reason liquid and 30min is impregnated, obtains pre-processing fine wallpaper；
(5) it takes nano-titanium dioxide, lauryl sodium sulfate, vinyltriethoxysilane and deionized water to be uniformly mixed, surpasses Sound 30min obtains suspension, then will pre-process fine wallpaper and impregnates 30min in suspension, obtains fiber wallpaper；
(6) it takes polyvinyl alcohol and deionized water to be mixed and heated, obtains polyvinyl alcohol liquid, adjusted with 0.01mol/L hydrochloric acid solution The pH to 3 of polyvinyl alcohol liquid, obtains Acidic Liquid；
(7) 14mol/L formalin is added dropwise in oxytropism liquid, then adjusts pH to 8 with sodium hydroxide solution, obtains reaction solution A；
(8) it takes potassium bichromate, sodium tripolyphosphate, tributyl phosphate, polyacrylamide and deionized water to be mixed, is reacted Liquid B；
(9) aqueous fluorocarbon resin, ultramarine, fatty alcohol polyoxyethylene ether, sodium alginate, deionized water and reaction solution B, stirring are equal It is even, dyeing liquor is obtained, dyeing liquor pH is adjusted to 6 with acetum, then fiber wallpaper is dyed, is obtained after dry resistance to Clean antibacterial wallpaper.
2. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (1) is described poly- Lactic acid, polycarbonate, polyethylene and methylene chloride mass ratio be 2:2:1:5.
3. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (4) is described poly- Ethylene oxide octyl phenol ether and the mass ratio of deionized water are 1:20.
4. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (5) is described to be received Rice titanium dioxide, lauryl sodium sulfate, vinyltriethoxysilane and deionized water mass ratio be 5:1:1:50.
5. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (6) is described poly- Vinyl alcohol and the mass ratio of deionized water are 1:20.
6. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (7) described acid Property liquid and formalin mass ratio be 8:1.
7. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (8) is described heavy Potassium chromate, sodium tripolyphosphate, tributyl phosphate, polyacrylamide and deionized water mass ratio be 1:2:1:1:20.
8. a kind of preparation method of scrubbing resistance antibacterial wallpaper as described in claim 1, which is characterized in that step (9) described water Property fluorocarbon resin, ultramarine, fatty alcohol polyoxyethylene ether, sodium alginate, deionized water and reaction solution B mass ratio be 20:2:1: 2:60:20。
CN201811078418.9A 2018-09-17 2018-09-17 A kind of preparation method of the mould proof wallpaper of scrubbing resistance Pending CN109338728A (en)

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