CN109294750A - Antibacterial cleaning nanometer water of one kind and preparation method thereof - Google Patents
Antibacterial cleaning nanometer water of one kind and preparation method thereof Download PDFInfo
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- CN109294750A CN109294750A CN201811314357.1A CN201811314357A CN109294750A CN 109294750 A CN109294750 A CN 109294750A CN 201811314357 A CN201811314357 A CN 201811314357A CN 109294750 A CN109294750 A CN 109294750A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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Abstract
The invention discloses a kind of antibacterial cleaning nanometer waters and preparation method thereof, belong to detergent technical field.Using electrolysis water as main cleaning substance, while cooperating nano-emulsion agent, nanometer brightener, makes to clean the optimum grain-diameter range that nanometer water has 1 nanometer~200 nanometers.The antibacterial cleaning nanometer water has preferably emulsification, package cleaning effect to various oily dirts, and cleaning clean effect rapidly and efficiently, and almost without any foam, is easy to use；The antibacterial cleaning nanometer water cooperation fungicide and dirt dispersant, also have effects that effective bacteriostasis property, light, safety and environmental protection, no pollution to the environment, almost noresidue trace after cleaning, the advantages that without rinsing, is suitble to the article with direct body contact such as cleaning ordinary rigid surface, wrist-watch, noble metal jewelry, key.The preparation method is easy to operate, low for equipment requirements, is suitble to industrial production.
Description
[technical field]
The invention belongs to detergent technical fields, and in particular to antibacterial cleaning nanometer water of one kind and preparation method thereof.
[background technique]
Household cleaning agent on the market at present, either neutral, alkalinity, acidic cleaner, most of is all living with surface
Property agent, acidity or alkaline assistant etc. based on form, these ingredients are chemical industry synthesis raw materials, in production and process, no
Only higher cost and contaminated wastewater environment can be generated.Meanwhile people are also easy to produce skin irritatin when these products are used for a long time
Problem or chemical residual and bring health hazards problem, especially certain highly acids or strong basicity detergent, it is not only rotten
Cleaned material surface is lost, and even more serious to human injury.Even neutral products, to the corrosion-free wound in cleaned material surface
Evil, but easy chemical residue preparation after use, contact skin have sensitization carcinogenic risk.In addition with surfactant, acidity or alkali
Detergent based on property auxiliary agent after cleaning, remains more on a surface of an, and it is more to leave decorative pattern, trace, influences appearance
It is bright.
In addition, for the article of ordinary rigid surface, wrist-watch, noble metal jewelry, key etc. and direct body contact, due to
Extraneous dirt, human skin etc. are contacted, the microbial contaminations such as bacterium easy to breed mouldy, discoloration occur, also easily cause skin
The malaise symptoms such as itch, so detergent is while cleaning observable greasy dirt, dirt, to the invisible micro- life of bacterium
Object pollution has inhibiting effect, also it is necessary to, is required with reaching comprehensive cleaning.But common detergent, do not have and inhibits
The effect of microbial contamination.
[summary of the invention]
It is an object of the invention to overcome the above-mentioned prior art, one kind is provided
In order to achieve the above objectives, the present invention is achieved by the following scheme:
A kind of antibacterial cleaning nanometer water disclosed by the invention, by percentage to the quality, including following components:
Preferably, the electrolysis water is the activated cathode electrolyzed alkaline water electrolytically generated using electrolysis wetting system, pH value
It is 8.0~10.5.
Preferably, the nano-emulsion agent selects modified natural palm kernel grease ethoxylate, long-chain C18 carbon carboxylate
Polyoxyethylene (LMEO), isomerous tridecanol polyoxyethylene ether 7EO-8EO, C12-16 fatty acid methyl ester APEO (FMEE),
One or both of sorbitan fatty acid ester polyoxyethylene ether 20EO and C10-16 isomery alcohol alkyl glycosides (APG).
It is further preferred that it is characterized in that, the fatty acid of sorbitan fatty acid ester polyoxyethylene ether 20EO includes
Mono laurate, single palmitinic acid, monostearate and single oleic acid.
Preferably, the nanometer brightener is using the polyether-modified dimethyl silica containing polyether group in side chain or end group
Alkane；
The polyether group is polyoxyethylene groups, polyoxypropylene base or Fatty alcohol polyoxyethylene polyoxypropylene ether base；It is described
Polyether-modified dimethyl siloxane be Dow Corning 2418, MEM-0349, OFX-0193, DC-8194, MEM-8168 or
HV-495。
Preferably, the solvent is using one or both of ethyl alcohol, isopropanol and 1,2-PD.
Preferably, the fungicide uses the bis- benzene guanidine radicals hexanes of 1,6-, 1,6- bis- (N1- rubigan-N5- biguanides bases)
Hexane digluconate, hexamethylene, poly (hexamethylene) hydrochloride, N- tetradecylpyridinium bromination
Ammonium, N- cetyl pyridinium ammonium chloride, double-track suspended self-propelled conveyor, decyl dimethyl ammonium bromide, dodecyldimethylamine base Bian
One or more of ammonium chloride, benzalkonium bromide and benzalkonium chloride.
Preferably, the water is softened water, deionized water or distilled water；And electrolysis water and the control of the volume ratio of water are 2:
1~20:1.
Preferably, the dirt dispersant uses polyacrylic acid sodium salt, sodium polymethacrylate salt, acrylic acid/Malaysia
Acid copolymer sodium salt, polyvinyl acetate copolymer, polyacrylamide, sodium carboxymethylcellulose sodium salt, carboxymethyl starch, Malaysia
One or both of acid copolymer sodium salt and polyvinylpyrrolidone；And dirt dispersant average molecular weight be 1000~
10000。
The invention also discloses the preparation methods of above-mentioned antibacterial cleaning nanometer water, comprising the following steps:
1) activated cathode electrolyzed alkaline water is prepared by being electrolysed wetting system, is electrolysed between wetting system anode and cathode and is furnished with ion
Two Room type electrolytic cells of diaphragm；
2) under agitation, sequentially added into reaction kettle activated cathode electrolyzed alkaline water, solvent, nano-emulsion agent,
Nanometer brightener, fungicide, dirt dispersant and water, stir；
3) it's ripening 12 hours or more is past after 300 mesh screens mixed solution made from step 2), obtained antibacterial clear
Clean nanometer water.
Compared with prior art, the invention has the following advantages:
Antibacterial cleaning nanometer water of the invention with have cleaning, biocidal efficacies electrolyzed alkaline water be main cleaning substance,
Cooperate nano-emulsion agent, nanometer brightener simultaneously, makes to clean the optimum grain-diameter range that nanometer water has 1 nanometer~200 nanometers, it is right
Various oily dirts have preferably emulsification, package cleaning effect, clean clean effect rapidly and efficiently, and almost without any bubble
Foam is easy to use.Cooperate fungicide and dirt dispersant, there is effective bacteriostasis property, bright cleaning effect.It is safe and harmless, it is right
Environmental nonpollution, almost noresidue trace after cleaning.Preparation method disclosed by the invention is easy to operate, is suitble to industrial production.
[specific embodiment]
The invention will be described in further detail with reference to the accompanying drawing:
The purpose of the present invention is to provide a kind of antibacterial cleaning nanometer water and preparation method thereof, principle based on this method
It is as follows:
Electrolysis principle: water is weak electrolyte, and there are H for inside2O、H+、OH?Ionization equilibrium.Electrolysis be exactly by two metals or
Carbon-point (i.e. electrode) is placed in the substance to be decomposed (electrolyte), then connects with the mains, electric current is made to pass through liquid.Compound
Cation moves on to electronegative electrode (cathode), and anion moves on to positively charged electrode (anode), and compound is divided into two poles.
Electrolyzed alkaline water generating process:
Electrolyzed water machine filters tap water using active carbon as filter layer, is allowed to purify and up to standard (reach country and drink water gauge
It is quasi-), then by electrolytically generated active electrolytic water, concentrating on cathode and flowing out is electrolyzed alkaline water.
Water (H2O) by electrolytically generated electrolysis water.Electric current passes through water (H2When O), hydrogen is formed in cathode, and oxygen is then in anode
It is formed.Positively charged ion is to movable cathode, the positively charged ion such as mineral calcium soluble in water, magnesium, potassium, sodium, just
Electrolyzed alkaline water is formed in cathode.
The cell reaction formula of neutral salt:
2NaCl(aq)+4H2O (ionic membrane is set between electrode) → 2 [Na+](aq)+OH(aq)+3H2(g) (cathode)
PH value=8.0~9.5 of electrolyzed alkaline water.
Therefore, the electrolyzed alkaline water that the present invention selects is a kind of to meet safe water.
The characteristics of electrolyzed alkaline water and function: 1) being in alkalescent, can neutralize the various acidic metabolites of saponification, sebum, oleic acid
Equal dirts, remove the dirt on article；2) subset of electrolysis water, penetration is strong with dissolving power, effectively cleaning cleaning action.
3) electrolyzed alkaline water has the negative potential of -150~-500mV, can remove peroxide, has certain bactericidal bacteriostasis.
One, specific embodiment
Embodiment 1
A kind of antibacterial cleaning nanometer water, is calculated in mass percent, comprising:
The preparation method of above-mentioned cleaning nanometer water, comprising the following steps:
Step 1: by being electrolysed the electrolytically generated activated cathode electrolyzed alkaline water of wetting system.It is electrolysed between wetting system anode and cathode
The two Room type electrolytic cells equipped with ion diaphragm.
Step 2: under agitation, sequentially added into reaction kettle electrolysis water, C10-16 isomery alcohol alkyl glycosides APG,
Polyether-modified dimethylamino radical siloxane, hexamethylene, water, stir.
Step 3: will made from step 2 clean 300 mesh filter screen filtrations of nanometer water, and and through ageing in 12 hours or more at
Reason.
Step 4: after sampling observation sample, packed products.
Embodiment 2
A kind of antibacterial cleaning nanometer water, is calculated in mass percent, comprising:
The preparation method of above-mentioned antibacterial cleaning nanometer water, comprising the following steps:
Step 1: by being electrolysed the electrolytically generated activated cathode electrolyzed alkaline water of wetting system.It is electrolysed between wetting system anode and cathode
The two Room type electrolytic cells equipped with ion diaphragm.
Step 2: under agitation, electrolysis water, sorbitan mono-laurate polyoxy are sequentially added into reaction kettle
Vinethene (20EO), polyether-modified dimethylamino radical siloxane, double-track suspended self-propelled conveyor, ethyl alcohol, water are sufficiently stirred
It is even.
Step 3: will made from step 2 clean 300 mesh filter screen filtrations of nanometer water, and and through ageing in 12 hours or more at
Reason.
Step 4: after sampling observation sample, packed products.
Embodiment 3
A kind of antibacterial cleaning nanometer water, is calculated in mass percent, comprising:
The preparation method of above-mentioned antibacterial cleaning nanometer water, comprising the following steps:
Step 1: by being electrolysed the electrolytically generated activated cathode electrolyzed alkaline water of wetting system.It is electrolysed between wetting system anode and cathode
The two Room type electrolytic cells equipped with ion diaphragm.
Step 2: under agitation, electrolysis water, modified natural palm kernel grease ethyoxyl are sequentially added into reaction kettle
Compound, polyether-modified dimethylamino radical siloxane, chlorhexidine gluconate, ethyl alcohol, 1,2- propylene glycol, acrylic acid/maleic acid are total
Polymers sodium salt, water, stir.
Step 3: will made from step 2 clean 300 mesh filter screen filtrations of nanometer water, and and through ageing in 12 hours or more at
Reason.
Step 4: after sampling observation sample, packed products.
Embodiment 4
A kind of antibacterial cleaning nanometer water, is calculated in mass percent, comprising:
The preparation method of above-mentioned antibacterial cleaning nanometer water, comprising the following steps:
Step 1: by being electrolysed the electrolytically generated activated cathode electrolyzed alkaline water of wetting system.It is electrolysed between wetting system anode and cathode
The two Room type electrolytic cells equipped with ion diaphragm.
Step 2: under agitation, electrolysis water, C12-14 fatty acid methyl ester polyoxyethylene are sequentially added into reaction kettle
Ether, modified natural palm kernel grease ethoxylate, polyether-modified dimethylamino radical siloxane, N- cetyl pyridinium chlorination
Ammonium, ethyl alcohol, 1,2-PD, acrylic acid/maleic acid sodium salt, water, stir.
Step 3: will made from step 2 clean 300 mesh filter screen filtrations of nanometer water, and and through ageing in 12 hours or more at
Reason.
Step 4: after sampling observation sample, packed products.
Embodiment 5
A kind of antibacterial cleaning nanometer water, is calculated in mass percent, comprising:
The preparation method of above-mentioned antibacterial cleaning nanometer water, comprising the following steps:
Step 1: by being electrolysed the electrolytically generated activated cathode electrolyzed alkaline water of wetting system.It is electrolysed between wetting system anode and cathode
The two Room type electrolytic cells equipped with ion diaphragm.
Step 2: under agitation, sequentially added into reaction kettle electrolysis water, isomerous tridecanol polyoxyethylene ether 8EO,
Modified natural palm kernel grease ethoxylate, polyether-modified dimethylamino radical siloxane, chlorhexidine gluconate, isopropanol,
1,2-PD, polyacrylic acid sodium salt, sodium carboxymethylcellulose sodium salt, water, stir.
Step 3: will made from step 2 clean 300 mesh filter screen filtrations of nanometer water, and and through ageing in 12 hours or more at
Reason.
Step 4: after sampling observation sample, packed products.
Two, performance test
1, dirt-removing power is tested
Performance in terms of dirt-removing power of antibacterial cleaning nanometer water and commercial products made from above-described embodiment is carried out pair
Than concrete operations are as follows:
Test method: antibacterial cleaning nanometer water produced by the present invention is mainly used for hard-surface cleaning, and test method is selected to press
It is executed according to QB/T4532-2013 " hard floor cleaning agent ", evaluation result is as shown in table 1 below:
The properties of sample test result of the present invention of table 1
| Title | The present invention | Commercial product 1 | Commercial product 2 | Commercial product 3 |
| Detergency | 5 | 4 | 3 | 4 |
| Brightness | 5 | 4 | 3 | 3 |
Note: performance evaluating, 5- is fine, and 4- is preferable, and 3- is good, and 2- is poor, and 1- is poor.
2, bacteriostasis property is tested
Test the contrivance bacteriostasis property.
Experimental method is executed according to GB/T15979-2002 " Disposable Sanitary Accessory sanitary standard ", microorganism fungus kind
Are as follows: Escherichia coli (ATCC 8099), staphylococcus aureus (ATCC 6538), test liquid are sample stoste, action time
For 5min.
Antibacterial cleaning nanometer water bacteriostasis property of the invention test result is as follows table 2.
The sample bacteriostasis property test result of the present invention of table 2
In conclusion antibacterial cleaning nanometer water provided by the invention cooperates simultaneously using electrolysis water as main cleaning substance
Nano-emulsion agent, nanometer brightener make to clean the optimum grain-diameter range that nanometer water has 1 nanometer~200 nanometers.It not only has
Rapid cleaning effect, and can reach and effectively inhibit microbial growth, bright effect, safety and environmental protection, no pollution to the environment, cleaning
Almost noresidue trace afterwards, the advantages that without rinsing, be suitble to cleaning ordinary rigid surface, wrist-watch, noble metal jewelry, key etc. with
The article of direct body contact.Its advantage is embodied in:
1, present invention cleaning nanometer water, which has, cleans and sterilizes double effects, while can increase cleaned material surface-brightening
Degree；
2, the present invention uses electrolysis water for detergent stoste, any substance being harmful to the human body is not added, to environment without dirt
The features such as dye, production cost is low.
3, the present invention uses rear noresidue in use without rinsing.
4, preparation method of the invention operates very simple, low for equipment requirements, is suitble to industrial amplification production.
The contents of the present invention are not limited to cited by embodiment, and those of ordinary skill in the art are by reading description of the invention
And to any equivalent replacement that technical solution of the present invention is taken, all are covered by the claims of the invention.
Claims (10)
1. a kind of antibacterial cleaning nanometer water, which is characterized in that by percentage to the quality, including following components:
2. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the electrolysis water is set using electrolysis water
Standby electrolytically generated activated cathode electrolyzed alkaline water, pH value are 8.0~10.5.
3. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the nano-emulsion agent selects modified natural
Palm kernel grease ethoxylate, long-chain C18 carbon carboxylate polyoxyethylene, isomerous tridecanol polyoxyethylene ether 7EO-8EO, C12-
16 fatty acid methyl ester APEOs, sorbitan fatty acid ester polyoxyethylene ether 20EO and C10-16 isomery alcohol alkyl glycosides
One or both of.
4. antibacterial cleaning nanometer water according to claim 3, which is characterized in that it is characterized in that, sorbitan fatty
The fatty acid of acid ester polyoxyethylene ether 20EO includes mono laurate, single palmitinic acid, monostearate and single oleic acid.
5. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the nanometer brightener uses side chain or end
Polyether-modified dimethyl siloxane in base containing polyether group；
The polyether group is polyoxyethylene groups, polyoxypropylene base or Fatty alcohol polyoxyethylene polyoxypropylene ether base；The polyethers
Modified dimethyl siloxane is Dow Corning 2418, MEM-0349, OFX-0193, DC-8194, MEM-8168 or HV-
495。
6. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the solvent using ethyl alcohol, isopropanol and
One or both of 1,2- propylene glycol.
7. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the fungicide uses the bis- benzene guanidines of 1,6-
Base hexane, 1,6- bis- (N1- rubigan-N5- biguanides base) hexane digluconates, gather at hexamethylene
Hexa-methylene guanidine hydrochloride, N- tetradecylpyridinium ammonium bromide, N- cetyl pyridinium ammonium chloride, double decyl dimethyl chlorinations
One of ammonium, decyl dimethyl ammonium bromide, dodecyldimethylamine base benzyl group ammonium chloride, benzalkonium bromide and benzalkonium chloride are several
Kind.
8. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the water is softened water, deionized water
Or distilled water；And electrolysis water and the control of the volume ratio of water are in 2:1~20:1.
9. antibacterial cleaning nanometer water according to claim 1, which is characterized in that the dirt dispersant uses polypropylene
Acid sodium-salt, sodium polymethacrylate salt, acrylic acid/maleic acid sodium salt, polyvinyl acetate copolymer, polyacrylamide
One of amine, sodium carboxymethylcellulose sodium salt, carboxymethyl starch, maleic acid sodium salt and polyvinylpyrrolidone or two
Kind；And dirt dispersant average molecular weight is 1000~10000.
10. the preparation method of antibacterial cleaning nanometer water described in any one of claim 1~9, which is characterized in that including with
Lower step:
1) activated cathode electrolyzed alkaline water is prepared by being electrolysed wetting system, is electrolysed between wetting system anode and cathode and is furnished with ion diaphragm
Two Room type electrolytic cells；
2) activated cathode electrolyzed alkaline water, solvent, nano-emulsion agent, nanometer under agitation, are sequentially added into reaction kettle
Brightener, fungicide, dirt dispersant and water, stir；
3) it's ripening 12 hours or more is past after 300 mesh screens mixed solution made from step 2), obtains antibacterial cleaning and receives
Meter Shui.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811314357.1A CN109294750A (en) | 2018-11-06 | 2018-11-06 | Antibacterial cleaning nanometer water of one kind and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811314357.1A CN109294750A (en) | 2018-11-06 | 2018-11-06 | Antibacterial cleaning nanometer water of one kind and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110628526A (en) * | 2019-10-24 | 2019-12-31 | 蔡先民 | Hand-protecting liquid detergent |
| CN116509732A (en) * | 2023-05-15 | 2023-08-01 | 广州市拓瑞科技有限公司 | Concentrated solution of sanitary wet towel for pets with functions of cleaning, sterilizing and deodorizing and preparation method thereof |
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| CN1119206A (en) * | 1994-09-21 | 1996-03-27 | 钟世昌 | New-functional multipurpose brightening agent for washing hard surface |
| CN101514272A (en) * | 2009-03-27 | 2009-08-26 | 武汉斯达日用化工有限公司 | Wood floor clean-care agent |
| CN102876496A (en) * | 2012-09-17 | 2013-01-16 | 吴江鑫霞纺织有限公司 | Bright cleaner |
| CN104357250A (en) * | 2014-11-25 | 2015-02-18 | 李灏阳 | Composite floor cleaner and application thereof |
| CN106833950A (en) * | 2016-12-28 | 2017-06-13 | 于文 | Antibacterial floor cleaner and preparation method thereof |
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| CN1119206A (en) * | 1994-09-21 | 1996-03-27 | 钟世昌 | New-functional multipurpose brightening agent for washing hard surface |
| CN101514272A (en) * | 2009-03-27 | 2009-08-26 | 武汉斯达日用化工有限公司 | Wood floor clean-care agent |
| CN102876496A (en) * | 2012-09-17 | 2013-01-16 | 吴江鑫霞纺织有限公司 | Bright cleaner |
| CN104357250A (en) * | 2014-11-25 | 2015-02-18 | 李灏阳 | Composite floor cleaner and application thereof |
| CN106833950A (en) * | 2016-12-28 | 2017-06-13 | 于文 | Antibacterial floor cleaner and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110628526A (en) * | 2019-10-24 | 2019-12-31 | 蔡先民 | Hand-protecting liquid detergent |
| CN116509732A (en) * | 2023-05-15 | 2023-08-01 | 广州市拓瑞科技有限公司 | Concentrated solution of sanitary wet towel for pets with functions of cleaning, sterilizing and deodorizing and preparation method thereof |
| CN116509732B (en) * | 2023-05-15 | 2023-10-20 | 广州市拓瑞科技有限公司 | Concentrated solution of sanitary wet towel for pets with functions of cleaning, sterilizing and deodorizing and preparation method thereof |
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