CN104357250A - Composite floor cleaner and application thereof - Google Patents
Composite floor cleaner and application thereof Download PDFInfo
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- CN104357250A CN104357250A CN201410691403.5A CN201410691403A CN104357250A CN 104357250 A CN104357250 A CN 104357250A CN 201410691403 A CN201410691403 A CN 201410691403A CN 104357250 A CN104357250 A CN 104357250A
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- composite floor
- floor board
- sanitising agent
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Abstract
The invention discloses a composite floor cleaner and an application thereof. The composite floor cleaner comprises 5-10 parts by weight of polyoxyethylene lauryl ether, 5 parts by weight of Cocamide DEA, 5-10 parts by weight of an alkaline regulator, 10-15 parts by weight of saponin decoction, 0.1-0.2 part by weight of an emulsifier and 0.4-0.5 part by weight of a chelating agent. The composite floor cleaner can be used for cleaning scratched imprints off a composite floor and is capable of effectively cleaning the scratched imprints, blots and the like of the composite floor, as well as is capable of effectively killing bacteria on the surface of the composite floor, preventing the breeding of bacteria, and brightening the composite floor.
Description
Technical field
The present invention relates to composite floor board cleaning applications, particularly relate to a kind of composite floor board sanitising agent, also relate to this composite floor board sanitising agent and to grow dim in clean composite floor board the application of trace.
Background technology
Composite floor board, in manufacture with use procedure, due to improper use caking agent and other composite floor board nursing materialss, leaves residue; Or manufacture and use procedure in spot, rusty stain, bacteria breed, causes composite floor board to grow dim, has the marking, has a strong impact on the attractive in appearance of composite floor board.
In order to remove spot, the marking in composite floor board, market has occurred some sanitising agents clean timber floor or ceramic tile, these sanitising agents mainly adopt the various different component of such as polypropylene vinegar polymkeric substance, wax, tensio-active agent, solvent and softening agent and so on to improve gloss.Such as Chinese patent application CN 1487991A discloses a kind of composition that is clean and raising floor gloss that is used for, and wherein softening agent tributoxyethyl phosphate can clean and improve the gloss of floor coating.Chinese patent application CN 103131551A discloses a kind of floor cleaner, its formula comprises following component: dimethyl silicone oil 20 ~ 40 parts, lauryl alcohol polyvinyl ether 8 ~ 16 parts, ethylene glycol phenolic ether 10 ~ 14 parts, trimethyl propane 10 ~ 16 parts, oleic acid 12 ~ 24 parts, 60 ~ 80 parts, beeswax, 20 ~ 40 parts, turps, 10 ~ 20 parts, rosin; This sanitising agent formula can kill the bacterium in floor, prevents bacterium from increasing, and has the smell of delicate fragrance, can also play the effect of anti-skidding waxing.Chinese patent application CN 103555457A discloses a kind of floor cleaner, has comprised component following: Virahol 8 parts, 11 parts, dichloro cresols, o-Tolylacetic acid 3 parts, 1,2-dimethoxy benzene 4 parts, empgen BB 11 parts, alcohol 2 parts, Metagin vinegar 4 parts, Tegosept E second vinegar 5 parts, ten the second light industry bureau base stearic acid 4 parts, Tegosept E third vinegar 7 parts, 1 part, essence, Phenoxyethanol 3 parts, the chlorination of dodecyl dimethyl joint base presses 4 parts, pure water 10 parts; This formula may be used for removing floor tile dirt, can continue anti-bacteria and grow, flushing-free.Disclose a kind of floor cleaner in Chinese patent application CN 102358872A patent, it consists of ethylene glycol solvent 1 ~ 20 part, nonionic surface active agent 1 ~ 30 part and water optionally composition; This formula is for removing floor dirt.Chinese patent application CN 102367397A discloses a kind of marine organism antibiosis floor cleaning agent, there is the formula comprising following weight percent: marine organisms cytokines 3.0 ~ 8.0, the cruel sodium salt 6.0 ~ 8.0 of organic phosphoric acid, tripoly phosphate sodium STPP 3.0 ~ 4.0, diethylene glycol monobutyl ether 1.0 ~ 2.0, chitin antibacterial agent 1.0 ~ 3.0, purifies waste water to 100, this formula is used for the cleaning of smooth surface, the effect such as have sterilization, oil removing, paraffin removal, mildew-resistant, eliminate the unusual smell.Chinese patent application CN 102443502A discloses a kind of pulvis of the cleaning-sterilizing for wood floors, by mass percentage, sodium carbonate by 75% ~ 80%, the C12 sodium branched alkyl benzene sulfonate of 10% ~ 15%, tripoly phosphate sodium STPP, the pine tar of 0.5% ~ 2%, the Starso of 3% ~ 8% of 3% ~ 8% form, this formula can make timber floor recover light, clean as new.Chinese patent application CN 103328623A provides a kind of cleaning compositions formula: the soap accounting for the maximum about 50wt% of composition; Account for the slipproofing agent of the maximum about 20wt% of composition; Account for stain control agent and the water of the maximum about 20wt% of composition, this formula provides a kind of clean coating, the especially method of stone surface.U.S. Patent application 4230605 discloses a kind of composition of clean floor, and said composition comprises the trimer be made up of methyl methacrylate vinegar, Butyl acrylate and vinylformic acid and the tensio-active agent comprising diethanolamine.No. 4861518, U.S. Patent application discloses a kind of floor cleaner of not film forming, comprises the nonionic surface active agent containing monoethanolamine or ethylene glycol monobutyl ether and polyoxyethylene glycol.No. 5342551, U.S. Patent application discloses a kind of glycol ether that utilizes as the floor coating scavenging agent of solvent and citric acid monoethanolamine.
In prior art; sanitising agent for floor is not all that composite floor board that spot, rusty stain or the bacteria breed brought for binding agent in composite floor board or nursing materials causes such as to grow dim at the problem; and do not have for composite floor board, particularly for the sanitising agent of this special floors such as the marking that grow dim of composite floor board care institution generation in the market yet; composite floor board manufacturing enterprise and floor user are badly in need of wanting one to make composite floor board rapid cleaning and light, effectively can also clean in composite floor board the composite floor board sanitising agent of the trace that grows dim.
Summary of the invention
The technical problem to be solved in the present invention to overcome in prior art composite floor board in manufacture and use procedure, what spot and bacteria breed caused the grow dim marking, be difficult to the technical problem of clearing up, a kind of quick sterilization is provided, effectively removes the trace that grows dim, make the sanitising agent of the fast quick-recovery light of composite floor board.
For solving the problems of the technologies described above, provide a kind of composite floor board sanitising agent, comprise the ethoxylated dodecyl alcohol of 5 ~ 10 weight parts, the coconut oil diethanol amide of 5 weight parts, the alkaline conditioner of 5 ~ 10 weight parts, the Chinese honey locust of 10 ~ 15 weight parts boil liquid, the emulsifying agent of 0.1 ~ 0.2 weight part, the sequestrant of 0.4 ~ 0.5 weight part.
Above-mentioned composite floor board sanitising agent, preferably, described alkaline conditioner is sodium hydroxide or potassium hydroxide.
Above-mentioned composite floor board sanitising agent, preferably, described emulsifying agent is coconut fatty acid.
Above-mentioned composite floor board sanitising agent, preferably, described sequestrant is tetrasodium ethylenediamine tetraacetate.
Above-mentioned composite floor board sanitising agent, preferably, described composite floor board sanitising agent also comprises the dispersion agent of 0.5 weight part, and dispersion agent is acrylic ester polymer.
Above-mentioned composite floor board sanitising agent, preferably, described composite floor board sanitising agent also comprises sterilant, and the concentration of described sterilant in described composite floor board sanitising agent is 1.3g/L.
Above-mentioned composite floor board sanitising agent, preferably, described sterilant is benzalkonium chloride.
Above-mentioned composite floor board sanitising agent, preferably, described composite floor board sanitising agent also comprises the perfume compound of 0.05 weight part, the staining agent of 0.05 weight part.
Above-mentioned composite floor board sanitising agent, preferably, described perfume compound is cream jasmin france or rose compound; Described staining agent is that alkalescence is red 46, one or more in rhodizonic acid, pigment Blue-61 and Basic Yellow 28.
As a total technical conceive, present invention also offers above-mentioned composite floor board sanitising agent and to grow dim in clean composite floor board the application of trace.
Innovative point of the present invention is:
The invention provides a kind of composite floor board sanitising agent, comprise ethoxylated dodecyl alcohol and coconut oil diethanol amide.Applicant finds that the trace main component of growing dim of composite floor board is wax, urea-formaldehyde resin adhesive, Phenol aldehyde resin, formaldehyde derivatives, spot, and grease and corrosion of metal etc., especially urea-formaldehyde resin adhesive, and general sanitising agent is all difficult to remove.And current sanitising agent all cannot clean the composite partss such as paraffin, grease, urea-formaldehyde resin adhesive.
Paraffin is a kind of straight-chain paraffin, primarily of normal paraffin C
nh
2n+2composition, carbonatoms is generally 22 ~ 36, and molecular weight ranges is 360 ~ 540.In order to effectively remove this straight-chain paraffin, the present invention adds ethoxylated dodecyl alcohol in composite floor board sanitising agent, and ethoxylated dodecyl alcohol has good solvability to paraffin.
Urea-formaldehyde resin adhesive is the linear structure urea-formaldehyde resin that polymeric precursors that under acidic conditions, urea and formaldehyde generation nucleophilic addition(Adn) generate is polymerized: H
2n-CO-NH
2+ 2H-CHO=HOCH
2-NH-CO-NH-CH
2oH; If in the basic conditions, above-mentioned linear structure Resin adhesive can become HOCH
2-N (CH
2oH)-CO-N (CH
2oH)-CH
2oH.And hydroxyl in this structure is solvable, also can with the R-CNH in coconut oil diethanol amide
2there is dehydration reaction, thus urea-formaldehyde resin adhesive spot is dissolved.
Phenol aldehyde resin is that Sauerstoffatom in the formaldehyde molecule hydrogen atom in phenol molecule in hydroxyl ortho position or contraposition is combined and produces water and be polymerized the linear phenolic resin obtained.Containing a complete phenolic hydroxyl group in the structure of resol, phenolic hydroxyl group shows slightly acidic, and so can react when running into highly basic thus resin structure is changed affects its performance.Resol is formed by polycondensation in addition, then hydrolysis reaction also can occur under strongly alkaline conditions and discharge free phenols urea formaldehyde OH-C
5h
4-CH
2oH.This monomer-soluble, also can with the R-CNH in coconut oil diethanol amide
2there is dehydration reaction thus Phenol aldehyde resin spot is dissolved.
Formaldehyde derivatives is that contriver finds first in composite floor board grows dim trace.This is because composite floor board is when using some formaldehyde removing care productss, formaldehyde and these care productss create the by products such as some formaldehyde derivatives, cause composite floor board to grow dim.These derivatives are COOH-N (CH mainly
2) the schiff bases material of-R1 class, this substance and alkali and Metal Production presence of Schiff-base complex, also can with the R-CNH in coconut oil diethanol amide
2react (carboxyl and amido react), thus be eliminated.
Simultaneously in order to better remove grease, the present invention also adds Chinese honey locust and boils liquid.Grease is higher fatty acid, and molecular formula is generally R1-COO-R2, and lipid acid and sodium hydroxide energy direct reaction generate solvable sodium soap.The composition such as the palmitinic acid contained in Chinese honey locust, stearic acid, oleic acid, sub-sterol, Sitosterol, nonacosane, can become reconciled with straight-chain paraffin and lipid acid and dissolve each other.These compositions can remove grease and paraffin spot well.
As preferred implementation method, the present invention also adds emulsifying agent in composite floor board sanitising agent, emulsifying agent is a class tensio-active agent, when it is dispersed in dispersate surperficial, forms film or electrostatic double layer, disperse phase can be made with electric charge, the small droplets of disperse phase so just can be stoped to condense mutually, make spot and clean-out system form stable heterogeneous system, be conducive to reaction, the processes such as dissolving, chelating are carried out.And coconut fatty acid mainly plays emulsion dispersion effect as emulsifying agent of the present invention; Coconut fatty acid and alkali have effect simultaneously, and can become coconut fatty acid sodium, this coconut fatty acid sodium forms good emulsifying effect in system.
Tetrasodium ethylenediamine tetraacetate is also added as the sequestrant of composite floor board sanitising agent of the present invention and hardness regulator in composite floor board sanitising agent, tetrasodium ethylenediamine tetraacetate can with the surface metal corrosion chelatropic reaction that may exist in composite floor board, thus remove corrosion of metal class spot.
Dispersion agent is a kind of interfacial agent simultaneously in molecule with lipophilicity and wetting ability two kinds of opposite nature in composite floor board sanitising agent, can homogeneous dispersion those be difficult to be dissolved in the inorganic of liquid, the solid particulate of organic coloring agent, also can prevent sedimentation and the cohesion of solid particulate simultaneously, form stable suspension.The present invention selects acrylic ester polymer as dispersion agent, this acrylic ester polymer is highly stable in composite floor board sanitising agent system of the present invention, organism in the affine system of energy and inorganics, make it stably dispersing, be convenient to from solid phase surface by spot mass transfer to liquid phase, and the sol system that stable formation is stable in the liquid phase, thus clean solid surface spot.
The present invention selects benzalkonium chloride as sterilant, and benzalkonium chloride can combine with Gleditschiasaponin, also kills and good restraining effect bacterium and fungal growth.
Perfume compound, staining agent according to individual need, can be selected.But because composite floor board sanitising agent provided by the invention is alkaline, not all staining agent all can be used.The present invention selects that alkalescence is red 46, rhodizonic acid, pigment Blue-61 and Basic Yellow 28 as staining agent, not only stable existence in composite floor board sanitising agent, can also and the cooperation of sequestrant, avoid precipitated metal to be separated.
Present invention also offers a kind of composite floor board sanitising agent, comprise ethoxylated dodecyl alcohol, sodium lauryl sulphate.Wherein sodium lauryl sulphate is cats product, can lower stained surface active tension, and the solubilize active ingredients of spot more easily and in clean-out system is reacted.
Compared with prior art, the invention has the advantages that:
The invention provides and a kind of to grow dim trace (mainly wax, urea-formaldehyde resin adhesive, Phenol aldehyde resin, formaldehyde derivatives, spot for composite floor board, and grease and corrosion of metal etc.) carry out the composite floor board sanitising agent that cleans, can clean rapidly grow dim, spot, and can effectively kill bacterium on composite floor board face, prevent bacterial growth, the effect of bright composite floor board can also be played simultaneously.
Embodiment
Below in conjunction with concrete preferred embodiment, the invention will be further described, but protection domain not thereby limiting the invention.
Embodiment
The material adopted in following examples and instrument are commercially available.It is that the Chinese honey locust removing seed (can the section of being cut into) is cleaned up and puts into stainless steel vessel that the Chinese honey locust adopted in the present embodiment boils liquid, add water (water is about 5 times of Chinese honey locust) afterwards big fire boil little fire and endure to Chinese honey locust soft rotten slowly.After cooling, filter.Refund in pot by the stoste after filtration again, infusion second time, endures while stir certain hour, test liquid proportion, when proportion reaches 1.1 ~ 1.2, can be off the pot, and after cooling, refilter once, for preparing composite floor board sanitising agent.Chinese honey locust contains the compositions such as gleditschiasaponin, palmitinic acid, stearic acid, oleic acid, sub-sterol, Sitosterol, nonacosane.
The perfume compound adopted in the present embodiment is the imitation fruit of synthetic and the concentrated perfume oil of natural perfume smell.In composite floor board sanitising agent, add distinct fragrance agent, make it have certain aromatising flavour.Perfume compound can be the pleasant flavouring agent such as cream jasmin france, rose compound.
The staining agent adopted in the present embodiment is natural or the coloured material of synthetic.In composite floor board sanitising agent, add certain staining agent, make composite floor board sanitising agent have certain color.Staining agent can be that alkalescence is red 46, rhodizonic acid, the one in pigment Blue-61, Basic Yellow 28, or they allocate gained mutually.
According to the formulated embodiment 1 and 2 of following table 1, the composite floor board sanitising agent of comparative example 1 to 4.
The formula table of table 1 composite floor board sanitising agent
In Table 1, the perfume compound that embodiment 1 and 2 adopts is jasmine flower essence, and the staining agent of employing is Pigment blue; The perfume compound that comparative example 3 adopts is Muscat Hamburg fine powder; The perfume compound that comparative example 1,2 and 4 adopts is jasmine flower essence; The staining agent that comparative example 2 adopts is Basic Yellow 28; The staining agent that comparative example 1,3 and 4 adopts is pigment Blue-61.
By embodiment 1 and 2, the composite floor board sanitising agent of comparative example 1 to 4 sprays to and grows dim on the composite floor board of print stain, after waiting certain hour (being generally about 5 minutes), cleans 2 times, and then dry with dry wipe with clean wet rag.Marking mode is adopted to pass judgment in each embodiment composite floor board sanitising agent to the cleaning effect on floor.
Cleaning force is marked: spraying composite floor board cleaning and smoothing agent to remove in 2 minutes grow dim, spot, count 90 points; Within 4 minutes, remove grow dim, spot, count 80 points; To remove beyond 10 minutes grow dim, spot, count 60 points; Can not remove grow dim, spot, count 40 points;
Luminance brightness is marked: compare bright degree with new production compoiste wood floor and give a mark.After clean, floor light is as new, counts 90 points; After spraying washing, the floor marking still exists, and brightness is unchanged, scores 40 points; All the other between these, brightness flop is obvious, and count 80 points, brightness slightly changes, and counts 60 points.
Sterilization is marked: bactericidal assay result is by the score of intestinal bacteria killing rate.According to the standard of " disinfection technology standard " (version in 2002), put by solution of the present invention in 37 DEG C of constant incubators after 3 months, carry out bactericidal assay to intestinal bacteria, effect l min, killing rate is all greater than 90%, scores 90 points; Killing rate is greater than 80%, scores 80 points; Killing rate is greater than 60%, scores 60 points; Killing rate, lower than 50%, is scored 40 points.
By embodiment 1 and 2, the cleaning effect appraisal result that the composite floor board sanitising agent of comparative example 1 to 4 cleans composite floor board is listed in table 2.
Table 2: embodiment 1 and 2, the composite floor board sanitising agent of comparative example 1 to 4 is to composite floor board cleaning effect grade form
| Embodiment | Cleaning force is marked | Luminance brightness is marked | Sterilization is marked | Statistics |
| Comparative example 1 | 40 | 40 | 80 | 160 |
| Comparative example 2 | 60 | 80 | 90 | 230 |
| Embodiment 1 | 90 | 90 | 90 | 270 |
| Embodiment 2 | 90 | 90 | 90 | 270 |
| Comparative example 3 | 60 | 40 | 80 | 180 |
| Comparative example 4 | 40 | 40 | 60 | 140 |
As can be seen from Table 2: 6 kinds of different composite floor board cleaning and smoothing agents ability that is clean with regard to it and that strengthen gloss compares.The trace removal effect of growing dim of embodiment 1 and embodiment 2 pairs of composite floor boards is best, this is because in the formula of the composite floor board sanitising agent of embodiment 2 and 3, liquid, ethoxylated dodecyl alcohol, coconut oil diethanol amide is boiled containing Chinese honey locust, wherein Chinese honey locust boils liquid, ethoxylated dodecyl alcohol mainly tensio-active agent, and coconut oil diethanol amide is then mainly used in formaldehyde derivatives reaction.Formaldehyde derivatives is COOH-N (CH mainly
2) the schiff bases material of-R1 class.This substance and alkali and Metal Production presence of Schiff-base complex, also can with the R-CNH in coconut oil diethanol amide
2react (carboxyl and amido react), thus be eliminated.Therefore, to the trace that grows dim in composite floor board, there is good cleaning effect.
Can know from the comparing of embodiment 2 and comparative example 4, after adding alkaline conditioner in composite floor board sanitising agent, the cleaning effect of composite floor board sanitising agent obviously raises, prove that composite floor board sanitising agent system system is necessary for strong basicity, strong alkaline condition can make Phenol aldehyde resin, and urea-formaldehyde resin adhesive resolves into and the R-CNH in coconut oil diethanol amide
2there is dehydration reaction, thus Phenol aldehyde resin and urea-formaldehyde resin adhesive spot are dissolved.Can allow formaldehyde derivatives simultaneously, as the schiff bases material of COOH-N (CH2)-R1 class and alkali and Metal Production presence of Schiff-base complex, react with the R-CNH2 in coconut oil diethanol amide (carboxyl and amido react) again, thus be eliminated.
Embodiment 3
A kind of composite floor board sanitising agent, adopt calcium dodecylbenzene sulphonate as emulsifying agent, concrete proportioning is:
Ethoxylated dodecyl alcohol 5wt%, Chinese honey locust boils liquid 10wt%, coconut oil diethanol amide 5wt%, sodium hydroxide 8wt%, calcium dodecylbenzene sulphonate 0.2wt%, tetrasodium ethylenediamine tetraacetate 0.4wt%, acrylic ester polymer 0.2wt%, benzalkonium chloride 1.3g/L, jasmine flower essence 0.05wt%, pigment Blue-61 is 0.05wt%, adds deionized water to 100%.
The composite floor board sanitising agent of embodiment 3 is marked according to aforesaid standards of grading, score 180 points.
Comparative example 5
A kind of composite floor board sanitising agent, concrete proportioning is:
Ethoxylated dodecyl alcohol 5wt%, Chinese honey locust boils liquid 10wt%, coconut oil diethanol amide 5wt%, sodium hydroxide 8wt%, benzalkonium chloride 1.3g/L, jasmine flower essence 0.05wt%, and pigment Blue-61 is 0.05wt%, adds deionized water to 100%.
The composite floor board sanitising agent of comparative example 5 is marked according to aforesaid standards of grading, score 160 points.
Comparative example 6
A kind of composite floor board sanitising agent, concrete proportioning is:
Ethoxylated dodecyl alcohol 2wt%, Chinese honey locust boils liquid 10wt%, coconut oil diethanol amide 2wt%, sodium hydroxide 2wt%, coconut fatty acid 0.2wt%, tetrasodium ethylenediamine tetraacetate 0.4wt%, acrylic ester polymer 0.2wt%, benzalkonium chloride 1.3g/L, jasmine flower essence 0.05wt%, pigment Blue-61 is 0.05wt%, adds deionized water to 100%.
The composite floor board sanitising agent of comparative example 6 is marked according to aforesaid standards of grading, score 180 points.
The above is only preferred embodiment of the present invention, not does any pro forma restriction to the present invention.Although the present invention discloses as above with preferred embodiment, but and be not used to limit the present invention.Any those of ordinary skill in the art, when not departing from spirit of the present invention and technical scheme, the Method and Technology content of above-mentioned announcement all can be utilized to make many possible variations and modification to technical solution of the present invention, or be revised as the Equivalent embodiments of equivalent variations.Therefore, every content not departing from technical solution of the present invention, according to technical spirit of the present invention to any simple modification made for any of the above embodiments, equivalent replacement, equivalence change and modification, all still belongs in the scope of technical solution of the present invention protection.
Claims (10)
1. a composite floor board sanitising agent, it is characterized in that, comprise the ethoxylated dodecyl alcohol of 5 ~ 10 weight parts, the coconut oil diethanol amide of 5 weight parts, the alkaline conditioner of 5 ~ 10 weight parts, the Chinese honey locust of 10 ~ 15 weight parts boil liquid, the emulsifying agent of 0.1 ~ 0.2 weight part, the sequestrant of 0.4 ~ 0.5 weight part.
2. composite floor board sanitising agent according to claim 1, is characterized in that, described alkaline conditioner is sodium hydroxide or potassium hydroxide.
3. composite floor board sanitising agent according to claim 1, is characterized in that, described emulsifying agent is coconut fatty acid.
4. composite floor board sanitising agent according to claim 1, is characterized in that, described sequestrant is tetrasodium ethylenediamine tetraacetate.
5. composite floor board sanitising agent according to claim 1, is characterized in that, described composite floor board sanitising agent also comprises the dispersion agent of 0.2 weight part, and described dispersion agent is acrylic ester polymer.
6. composite floor board sanitising agent according to any one of claim 1 to 5, is characterized in that, described composite floor board sanitising agent also comprises sterilant, and the concentration of described sterilant in described composite floor board sanitising agent is 1.3g/L.
7. composite floor board sanitising agent according to claim 6, is characterized in that, described sterilant is benzalkonium chloride.
8. composite floor board sanitising agent according to any one of claim 1 to 5, is characterized in that, described composite floor board sanitising agent also comprises the perfume compound of 0.05 weight part, the staining agent of 0.05 weight part.
9. composite floor board sanitising agent according to claim 8, is characterized in that, described perfume compound is cream jasmin france or rose compound; Described staining agent is that alkalescence is red 46, one or more in rhodizonic acid, pigment Blue-61 and Basic Yellow 28.
10. composite floor board sanitising agent according to any one of a claim 1 to 9 grows dim the application of trace in clean composite floor board.
Priority Applications (1)
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|---|---|---|---|
| CN201410691403.5A CN104357250A (en) | 2014-11-25 | 2014-11-25 | Composite floor cleaner and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410691403.5A CN104357250A (en) | 2014-11-25 | 2014-11-25 | Composite floor cleaner and application thereof |
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| CN104357250A true CN104357250A (en) | 2015-02-18 |
Family
ID=52524566
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|---|---|---|---|
| CN201410691403.5A Pending CN104357250A (en) | 2014-11-25 | 2014-11-25 | Composite floor cleaner and application thereof |
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|---|---|
| CN (1) | CN104357250A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106987451A (en) * | 2017-03-19 | 2017-07-28 | 长沙协浩吉生物工程有限公司 | A kind of compound method of toilet Wall or floor tile ferment cleaning agent |
| CN106987458A (en) * | 2017-03-19 | 2017-07-28 | 长沙协浩吉生物工程有限公司 | A kind of compound method of toilet Wall or floor tile ferment cleaning agent |
| CN107287045A (en) * | 2016-03-31 | 2017-10-24 | 济南昊泽环保科技有限公司 | A kind of compoiste wood floor and floor tile cleaning agent |
| CN109294750A (en) * | 2018-11-06 | 2019-02-01 | 西安优派日化有限公司 | Antibacterial cleaning nanometer water of one kind and preparation method thereof |
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Cited By (4)
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| CN107287045A (en) * | 2016-03-31 | 2017-10-24 | 济南昊泽环保科技有限公司 | A kind of compoiste wood floor and floor tile cleaning agent |
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| CN109294750A (en) * | 2018-11-06 | 2019-02-01 | 西安优派日化有限公司 | Antibacterial cleaning nanometer water of one kind and preparation method thereof |
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Application publication date: 20150218 |