CN110628526A - Hand-protecting liquid detergent - Google Patents
Hand-protecting liquid detergent Download PDFInfo
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- CN110628526A CN110628526A CN201911019491.3A CN201911019491A CN110628526A CN 110628526 A CN110628526 A CN 110628526A CN 201911019491 A CN201911019491 A CN 201911019491A CN 110628526 A CN110628526 A CN 110628526A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Oil, Petroleum & Natural Gas (AREA)
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Abstract
The invention belongs to the technical field of washing products, and particularly relates to a hand-protecting liquid detergent which comprises a liquid detergent bottle for storing the liquid detergent; according to the invention, by adding the cationic surfactant cetyl pyridinium ammonium chloride component into the detergent, the decontamination effect of the detergent is enhanced, and meanwhile, the cationic surfactant cetyl pyridinium ammonium chloride component and the anionic surfactant fatty alcohol-polyoxyethylene ether sodium sulfate form an anionic-cationic system, so that the irritation of active ions to skin is reduced, and the skin care effect of the detergent is effectively enhanced; in addition, the liquid A and the liquid B are separately stored in the two storage cavities by arranging the storage cavity A and the storage cavity B in the liquid detergent bottle, so that the reaction failure of the anionic surfactant sodium alcohol ether sulfate and the cationic surfactant ammonium cetylpyridinium chloride after long-time mixing is reduced, and the protection effect of the two components on hand skin in the cleaning process is enhanced.
Description
Technical Field
The invention belongs to the technical field of washing products, and particularly relates to a hand-protecting liquid detergent.
Background
With the development of society, the pace of life of people is faster and faster, and people always seek higher efficiency in the time of dropping. In the aspect of tableware washing, the detergent is a necessary washing article for kitchens, the demand of people is not limited to the common detergent for a long time, along with the continuous improvement of the living standard of people, more and more families for cleaning tableware, fruits and vegetables by adopting the detergent are provided, in addition, most of the tableware detergent contains linear alkyl sodium benzenesulfonate, the irritation is larger, the degreasing capability is stronger, and the skin can be roughened after long-term contact.
And when the liquid detergent in the traditional liquid detergent bottle is about to use up, because the bottom end of the suction pipe can not be effectively controlled and moved, especially when the bottom of the liquid detergent bottle is uneven, a large amount of liquid detergent is remained in the groove on the bottom surface of the liquid detergent bottle, so that the liquid detergent is difficult to effectively suck out and utilize, and unnecessary liquid detergent is wasted.
In view of the above, the invention provides the hand-protecting liquid detergent which can effectively enhance the cleaning and skin-protecting effects of the liquid detergent and can be taken and used reasonably through the liquid detergent bottle.
Disclosure of Invention
In order to make up for the defects of the prior art, the invention provides the hand-protecting liquid detergent which can effectively enhance the cleaning and skin-protecting effects of the liquid detergent and can be reasonably taken and used through a liquid detergent bottle.
The technical scheme adopted by the invention for solving the technical problems is as follows: the hand-protecting liquid detergent comprises the following main active components in parts by weight:
the preparation method of the hand-protecting liquid detergent comprises the following steps:
s1: adding 50-58 parts of metered deionized water, adding 0.1-1 part of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; the disodium ethylene diamine tetraacetate chelates the metal ions in the deionized water, so that the cleaning effect of the detergent is improved;
s2: after the material is completely dissolved in S1; adding 0.1-1.5 parts of sodium dimethyl benzene sulfonate and 1-10 parts of propylene glycol, and continuously stirring until the materials are completely dissolved; mixing the above components;
s3: stirring the added components in S2 until the components are completely dissolved, dividing the solution into solution A and solution B, heating to 45 ℃, adding 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut diethanol amine fatty acid and 5-10 parts of fatty alcohol polyoxyethylene ether in equal amount, then adding 10-20 parts of sodium fatty alcohol polyoxyethylene ether sulfate into solution A, adding 0.1-0.5 part of cetylpyridinium chloride into solution B, and continuously stirring until the materials are transparent; by respectively adding the anionic surfactant sodium fatty alcohol-polyoxyethylene ether sulfate and the cationic surfactant cetylpyridinium chloride into the liquid A and the liquid B of the liquid detergent, the two components have excellent decontamination, wetting, emulsification, dispersion and foaming performances, and can effectively protect the skin, but insoluble micelles can be formed when the two components are mixed for a long time, and when a small amount of cationic surfactant is added into a washing liquid mainly containing the anionic surfactant for short-time mixing, a complex with low irritation is generated due to electrostatic attraction, so that the possibility of the combination of active ions and protein in the skin cuticle is reduced, the surface activity of a system is greatly improved, and the irritation of the system to the skin can be improved;
s4: stirring the added components until the components are transparent in S3, filtering the components by using a 300-mesh filter screen, and respectively storing the prepared solution A and solution B in a storage cavity A and a storage cavity B of a detergent bottle; by storing the solution A and the solution B separately, the reaction failure of the anionic surfactant sodium alcohol ether sulfate and the cationic surfactant ammonium cetylpyridinium chloride after long-time mixing is reduced, and the protective effect of the two components on hand skin is enhanced;
the components of the high-efficiency hand-protecting detergent are described as follows:
sodium fatty alcohol polyoxyethylene ether sulfate: is easy to dissolve in water, has excellent decontamination, wetting, emulsifying, dispersing and foaming performances, good biodegradation performance and low irritation to skin and eyes.
Cetyl pyridinium ammonium chloride: the cationic surfactant is very easy to dissolve in water and ethanol, and the aqueous solution of the cationic surfactant can generate rich foam by strong oscillation, has excellent surface activity and sterilization toxicity, is often used as a cationic surfactant, and has low irritation to skin and eyes.
Alkyl glycoside: can be compounded with various ionic and nonionic surfactants to generate synergistic action, has good foamability, rich, fine and good solubility of foam, good thickening capability and good skin compatibility, obviously improves the mildness of the formula, and is non-toxic, non-irritant and easy to biodegrade.
Dodecyl dimethyl betaine: colorless to light yellow transparent liquid, has excellent stability under acidic and alkaline conditions and good compatibility; has low irritation to skin, good biodegradability, and excellent decontamination, sterilization, softness, antistatic property, hard water resistance and rust resistance.
Coconut oil fatty acid diethanolamine: the foam is a yellowish to amber viscous liquid, is easy to dissolve in water, and has good functions of foaming, foam stabilization, penetration decontamination, hard water resistance and the like.
Fatty alcohol polyoxyethylene ether: the colorless transparent liquid is white paste, and is used as a nonionic surfactant to play roles in emulsifying, foaming and decontaminating.
Sodium dimethyl benzenesulfonate: white crystalline powder, which can be used in liquid detergents, as coupling agent, hydrotrope, leveling agent, dispersant, and to lower cloud point and viscosity.
Propylene glycol: colorless viscous liquid, nearly tasteless, and slightly sweet, can be used for organic synthesis, and can be used as solvent, dehydrating agent, plasticizer, antifreeze, gas chromatography stationary liquid, etc.
Disodium ethylene diamine tetraacetate: is white crystal particle or powder, odorless and tasteless, and is an important chelating agent capable of chelating metal ions in solution.
Deionized water: the purified water from which the impurities in the form of ions have been removed, a colorless clear liquid, odorless, tasteless, and of higher purity than distilled water.
Preferably, the hand-protecting liquid detergent further comprises 10-20 parts of tea saponin, the structure of the tea saponin is triterpenoid saponin, the triterpenoid saponin is often used as a natural surfactant, the performance is mild, and the hand-protecting liquid detergent has hard water resistance and foaming promotion capability; the components of the cleaning liquid come from the plant body, have small irritation to the skin and excellent skin-friendly property, and reduce the damage of the cleaning liquid to the skin of the hands while enhancing the cleaning effect of the cleaning liquid.
Preferably, the hand-protecting liquid detergent also comprises 0.1-1 part of sodium citrate, wherein the sodium citrate is used as a pH regulator to regulate the pH of A, B liquid, and the pH value of A, B liquid is controlled to be 4.5-6.5; the pH value of the skin of a healthy human body is between 4.5 and 6.5, the pH values of the liquid A and the liquid B of the liquid detergent are adjusted to be in a range suitable for the skin of the human body through the sodium citrate, so that the stimulation and the damage of the liquid detergent to the hand skin are reduced, and the skin care performance of the liquid detergent is effectively enhanced.
Preferably, the liquid detergent bottle comprises a shell, a bottle cap and a pressing nozzle, the bottle cap is positioned at the top end of the shell, and the pressing nozzle is installed on the bottle cap; the pressing sprayer is characterized in that an A storage cavity and a B storage cavity are arranged in the shell, a partition plate is arranged between the A storage cavity and the B storage cavity, the bottom of the pressing sprayer is connected with a straw, the middle of the bottom end of the straw is clamped at the top end of the partition plate, the top end of the partition plate divides the interior of the straw into two chambers, the two chambers at the bottom end of the straw are respectively connected with an A connecting pipe and a B connecting pipe, the other end of the A connecting pipe is located in the A storage cavity, and the other end of the; when the hand-protecting detergent is used for cleaning, pressure is applied to the pressing nozzle, so that the A connecting pipe and the B connecting pipe arranged at the bottom end of the pressing nozzle respectively extrude the A liquid and the B liquid in the A storage cavity and the B storage cavity simultaneously under the action of air pressure inside and outside the pipes, the extruded A liquid and the B liquid are mixed through the suction pipes communicated with the tops of the two connecting pipes and are extruded to the outside of the shell simultaneously under the action of continuous extrusion of the pressing nozzle, at the moment, in the process of cleaning the dish, a cleaning worker mixes the anionic surfactant fatty alcohol polyoxyethylene ether sodium sulfate in the A liquid and the cationic surfactant cetyl pyridinium ammonium chloride in the B liquid, in an anionic-cationic system, a complex with low irritation is generated due to electrostatic attraction, and the possibility of combination of active ions and proteins in a skin stratum corneum is reduced, not only greatly improving the surface activity of the system, but also improving the stimulation of the system to the skin, thereby leading the liquid detergent to have good skin care effect; the invention has the beneficial effects that: by storing the solution A and the solution B in the storage cavities A and B separately, the reaction failure of the anionic surfactant sodium alcohol ether sulfate and the cationic surfactant ammonium cetylpyridinium chloride after long-time mixing is reduced, and the protection effect of the two components on hand skin in the cleaning process is enhanced.
Preferably, an adsorption box is arranged on the bottom surface of the shell, a sliding cavity is arranged inside the adsorption box, a first magnet is arranged inside the sliding cavity, second magnets are arranged at the bottom ends of the connecting pipe A and the connecting pipe B, and the second magnets are opposite to the first magnets in magnetism; when the washing machine works, when the liquid A and the liquid B in the liquid detergent bottle are used up, the bottom ends of the connecting pipe A and the connecting pipe B cannot be effectively controlled and moved, particularly when the bottom of the liquid detergent bottle is uneven, a large amount of liquid detergent is left in the groove in the bottom surface of the liquid detergent bottle and is difficult to effectively suck and utilize, the first magnet and the second magnet are arranged to attract each other, so that the bottom ends of the connecting pipe A and the connecting pipe B on the second magnet are tightly attached to the bottom surface of the shell, the extrusion of the liquid detergent remained at the bottom of the shell is facilitated, the first magnet is controlled to slide in the sliding cavity to drive the second magnet to correspondingly slide, the connecting pipe A and the bottom end of the connecting pipe B which are in movable connection when the second magnet slides, so that a cleaning person can control the bottom ends of the connecting pipe A and the connecting pipe B to move to the position of the liquid detergent which is difficult to clean, therefore, the residual liquid detergent in the liquid detergent bottle is effectively extruded and utilized, and unnecessary waste of the liquid detergent is reduced.
Preferably, the bottom ends of the connecting pipe A and the connecting pipe B are both composed of elastic corrugated pipes, plastic floating balls are connected to the outer surfaces of the corrugated pipes, and the floating force of the floating balls in the liquid A and the liquid B can enable the bottom ends of the connecting pipe A and the connecting pipe B to float above the bottom surface of the shell; when the device works, when the liquid detergent in the liquid detergent bottle is just used, the arranged floating ball floats in the liquid A and the liquid B, the bottom ends of the connecting pipe A and the connecting pipe B are floated above the bottom surface of the shell by buoyancy generated by the floating ball, and the bottom ends of the connecting pipe A and the connecting pipe B are driven to be tightly attached to the bottom surface of the shell when the mutual attraction of the first magnet and the second magnet is reduced, so that the bottom openings of the connecting pipe A and the connecting pipe B are blocked, and the smooth extrusion and use of the liquid detergent are influenced; and when the liquid detergent is used up gradually, the liquid level of the liquid detergent which descends gradually enables the floating ball to drive the corrugated pipe at the bottom ends of the A connecting pipe and the B connecting pipe to stretch along with the liquid level descending, the bottom ends of the A connecting pipe and the B connecting pipe are always positioned in the liquid detergent, when the liquid level of the liquid detergent continuously descends to the end of the liquid detergent, the buoyancy of the floating ball is reduced, the bottom ends of the A connecting pipe and the B connecting pipe are attached to the bottom surface of the shell under the attraction of the first magnet and the second magnet, the liquid detergent which is remained at the bottom of the shell can be sucked out and utilized conveniently and quickly, the waste of resources is reduced, and the stability and the environmental protection performance of the liquid detergent bottle during working are enhanced.
The invention has the following beneficial effects:
1. according to the invention, by adding the cationic surfactant cetyl pyridinium ammonium chloride component into the detergent, the decontamination effect of the detergent is enhanced, and meanwhile, the cationic surfactant cetyl pyridinium ammonium chloride component and the anionic surfactant fatty alcohol-polyoxyethylene ether sodium sulfate form an anionic-cationic system, so that the irritation of active ions to skin is reduced, and the skin care effect of the detergent is effectively enhanced.
2. According to the invention, the A storage cavity and the B storage cavity are arranged in the liquid detergent bottle, and the A liquid and the B liquid are separately stored in the two storage cavities, so that the reaction failure of the anionic surfactant sodium alcohol ether sulfate and the cationic surfactant ammonium cetylpyridinium chloride after long-time mixing is reduced, and the protection effect of the two components on hand skin in the cleaning process is enhanced.
Drawings
The invention will be further explained with reference to the drawings.
FIG. 1 is a diagram of the steps of the preparation method of the present invention;
FIG. 2 is a schematic perspective view of the present invention;
FIG. 3 is a schematic structural view of the present invention;
FIG. 4 is an enlarged view at A in FIG. 3;
FIG. 5 is an enlarged view at B in FIG. 3;
in the figure: the device comprises a shell 1, an A storage cavity 11, a B storage cavity 12, a bottle cap 2, a pressing nozzle 3, a partition plate 4, a straw 5, an A connecting pipe 51, a B connecting pipe 52, a second magnet 53, an adsorption box 6, a sliding cavity 61, a first magnet 62, a corrugated pipe 7 and a floating ball 8.
Detailed Description
In order to make the technical means, the creation features, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the following embodiments.
As shown in fig. 1-5, the hand-protecting liquid detergent disclosed by the invention comprises the following main active components in parts by weight:
the preparation method of the hand-protecting liquid detergent comprises the following steps:
s1: adding 50-58 parts of metered deionized water, adding 0.1-1 part of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; the disodium ethylene diamine tetraacetate chelates the metal ions in the deionized water, so that the cleaning effect of the detergent is improved;
s2: after the material is completely dissolved in S1; adding 0.1-1.5 parts of sodium dimethyl benzene sulfonate and 1-10 parts of propylene glycol, and continuously stirring until the materials are completely dissolved; mixing the above components;
s3: stirring the added components in S2 until the components are completely dissolved, dividing the solution into solution A and solution B, heating to 45 ℃, adding 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut diethanol amine fatty acid and 5-10 parts of fatty alcohol polyoxyethylene ether in equal amount, then adding 10-20 parts of sodium fatty alcohol polyoxyethylene ether sulfate into solution A, adding 0.1-0.5 part of cetylpyridinium chloride into solution B, and continuously stirring until the materials are transparent; by respectively adding the anionic surfactant sodium fatty alcohol-polyoxyethylene ether sulfate and the cationic surfactant cetylpyridinium chloride into the liquid A and the liquid B of the liquid detergent, the two components have excellent decontamination, wetting, emulsification, dispersion and foaming performances, and can effectively protect the skin, but insoluble micelles can be formed when the two components are mixed for a long time, and when a small amount of cationic surfactant is added into a washing liquid mainly containing the anionic surfactant for short-time mixing, a complex with low irritation is generated due to electrostatic attraction, so that the possibility of the combination of active ions and protein in the skin cuticle is reduced, the surface activity of a system is greatly improved, and the irritation of the system to the skin can be improved;
s4: stirring the added components until the components are transparent in S3, filtering the components by using a 300-mesh filter screen, and respectively storing the prepared solution A and solution B in a storage cavity A and a storage cavity B of a detergent bottle; by storing the solution A and the solution B separately, the reaction failure of the anionic surfactant sodium alcohol ether sulfate and the cationic surfactant ammonium cetylpyridinium chloride after long-time mixing is reduced, and the protective effect of the two components on hand skin is enhanced;
the components of the high-efficiency hand-protecting detergent are described as follows:
sodium fatty alcohol polyoxyethylene ether sulfate: is easy to dissolve in water, has excellent decontamination, wetting, emulsifying, dispersing and foaming performances, good biodegradation performance and low irritation to skin and eyes.
Cetyl pyridinium ammonium chloride: the cationic surfactant is very easy to dissolve in water and ethanol, and the aqueous solution of the cationic surfactant can generate rich foam by strong oscillation, has excellent surface activity and sterilization toxicity, is often used as a cationic surfactant, and has low irritation to skin and eyes.
Alkyl glycoside: can be compounded with various ionic and nonionic surfactants to generate synergistic action, has good foamability, rich, fine and good solubility of foam, good thickening capability and good skin compatibility, obviously improves the mildness of the formula, and is non-toxic, non-irritant and easy to biodegrade.
Dodecyl dimethyl betaine: colorless to light yellow transparent liquid, has excellent stability under acidic and alkaline conditions and good compatibility; has low irritation to skin, good biodegradability, and excellent decontamination, sterilization, softness, antistatic property, hard water resistance and rust resistance.
Coconut oil fatty acid diethanolamine: the foam is a yellowish to amber viscous liquid, is easy to dissolve in water, and has good functions of foaming, foam stabilization, penetration decontamination, hard water resistance and the like.
Fatty alcohol polyoxyethylene ether: the colorless transparent liquid is white paste, and is used as a nonionic surfactant to play roles in emulsifying, foaming and decontaminating.
Sodium dimethyl benzenesulfonate: white crystalline powder, which can be used in liquid detergents, as coupling agent, hydrotrope, leveling agent, dispersant, and to lower cloud point and viscosity.
Propylene glycol: colorless viscous liquid, nearly tasteless, and slightly sweet, can be used for organic synthesis, and can be used as solvent, dehydrating agent, plasticizer, antifreeze, gas chromatography stationary liquid, etc.
Disodium ethylene diamine tetraacetate: is white crystal particle or powder, odorless and tasteless, and is an important chelating agent capable of chelating metal ions in solution.
Deionized water: the purified water from which the impurities in the form of ions have been removed, a colorless clear liquid, odorless, tasteless, and of higher purity than distilled water.
As an embodiment of the invention, the hand-protecting liquid detergent further comprises 10-20 parts of tea saponin, wherein the tea saponin is a triterpenoid saponin in structure, is usually used as a natural surfactant, has mild performance, and has hard water resistance and foaming promotion capability; the components of the cleaning liquid come from the plant body, have small irritation to the skin and excellent skin-friendly property, and reduce the damage of the cleaning liquid to the skin of the hands while enhancing the cleaning effect of the cleaning liquid.
In one embodiment of the invention, the hand-protecting detergent component further comprises 0.1-1 part of sodium citrate, wherein the sodium citrate is used as a pH regulator to regulate the pH of A, B liquid, and the pH value of A, B liquid is controlled to be 4.5-6.5; the pH value of the skin of a healthy human body is between 4.5 and 6.5, the pH values of the liquid A and the liquid B of the liquid detergent are adjusted to be in a range suitable for the skin of the human body through the sodium citrate, so that the stimulation and the damage of the liquid detergent to the hand skin are reduced, and the skin care performance of the liquid detergent is effectively enhanced.
As an embodiment of the invention, the liquid detergent bottle comprises a shell 1, a bottle cap 2 and a pressing nozzle 3, wherein the bottle cap 2 is positioned at the top end of the shell 1, and the pressing nozzle 3 is arranged on the bottle cap 2; the inner part of the shell 1 is provided with an A storage cavity 11 and a B storage cavity 12, a partition plate 4 is arranged between the A storage cavity 11 and the B storage cavity 12, the bottom of the pressing spray head 3 is connected with a straw 5, the middle part of the bottom end of the straw 5 is clamped at the top end of the partition plate 4, the inner part of the straw 5 is divided into two chambers by the top end of the partition plate 4, the two chambers at the bottom end of the straw 5 are respectively connected with an A connecting pipe 51 and a B connecting pipe 52, the other end of the A connecting pipe 51 is positioned in the A storage cavity 11, and the other end of the B connecting pipe 52; when the hand-protecting detergent is used for cleaning, pressure is applied to the pressing nozzle 3, so that the A connecting pipe 51 and the B connecting pipe 52 arranged at the bottom end of the pressing nozzle 3 respectively extrude the A liquid and the B liquid in the A storage cavity 11 and the B storage cavity 12 simultaneously under the action of the air pressure inside and outside the pipes, the extruded A liquid and the B liquid are mixed through the suction pipe 5 communicated with the tops of the two connecting pipes and are extruded to the outside of the shell 1 simultaneously under the action of continuous extrusion of the pressing nozzle 3, at the moment, in the process of cleaning the dishes, a cleaning agent, fatty alcohol polyoxyethylene ether sodium sulfate serving as a surfactant in the A liquid and cetyl pyridinium chloride serving as a cationic surfactant in the B liquid are mixed, in an anionic-cationic system, a complex with low irritation is generated due to electrostatic attraction, and the possibility of the combination of active ions and proteins in the skin cuticle is reduced, not only greatly improving the surface activity of the system, but also improving the stimulation of the system to the skin, thereby leading the liquid detergent to have good skin care effect; the invention has the beneficial effects that: by storing the solution A and the solution B in the storage cavity A11 and the storage cavity B12 separately, the reaction failure of the anionic surfactant sodium alcohol ether sulfate and the cationic surfactant ammonium cetyl pyridinium chloride after long-time mixing is reduced, and the protection effect of the two components on the hand skin in the cleaning process is enhanced.
As an embodiment of the present invention, an adsorption box 6 is disposed on the bottom surface of the housing 1, a sliding cavity 61 is disposed inside the adsorption box 6, a first magnet 62 is disposed inside the sliding cavity 61, a second magnet 53 is disposed at the bottom end of each of the a connection pipe 51 and the B connection pipe 52, and the second magnet 53 and the first magnet 62 have opposite magnetism; when the liquid A and the liquid B in the liquid detergent bottle are used up, the bottom ends of the connecting pipe 51 and the connecting pipe 52 of the liquid A and the connecting pipe B cannot be effectively controlled and moved, especially when the bottom of the liquid detergent bottle is uneven, a large amount of liquid detergent is left in the groove on the bottom surface of the liquid detergent bottle and is difficult to effectively suck and utilize, the first magnet 62 and the second magnet 53 which are arranged at the moment attract each other to enable the bottom ends of the connecting pipe 51 and the connecting pipe 52 of the liquid A and the connecting pipe B on the second magnet 53 to be tightly attached to the bottom surface of the shell 1, so that the liquid detergent remained at the bottom of the shell 1 can be conveniently extruded out, the first magnet 62 is controlled to slide in the sliding cavity 61 to drive the second magnet 53 to correspondingly slide, the second magnet 53 drives the connecting pipe 51 and the connecting pipe 52 of the liquid B to slide when the second magnet 53 slides, so that a cleaning person can control the bottom ends of the connecting pipe 51 and the connecting pipe 52 of the liquid A, therefore, the residual liquid detergent in the liquid detergent bottle is effectively extruded and utilized, and unnecessary waste of the liquid detergent is reduced.
As an embodiment of the present invention, the bottom ends of the a connection pipe 51 and the B connection pipe 52 are both composed of an elastic corrugated pipe 7, the outer surface of the corrugated pipe 7 is connected with a plastic floating ball 8, and the floating force of the floating ball 8 in the a liquid and the B liquid can make the bottom ends of the a connection pipe 51 and the B connection pipe 52 float above the bottom surface of the housing 1; when the device works, when the liquid detergent in the liquid detergent bottle is just used, the arranged floating ball 8 floats in the liquid A and the liquid B, the bottom ends of the connecting pipe A51 and the connecting pipe B52 are floated above the bottom surface of the shell 1 by the buoyancy generated by the floating ball 8, the first magnet 62 and the second magnet 53 are reduced to attract each other, the bottom ends of the connecting pipe A51 and the connecting pipe B52 are driven to be closely attached to the bottom surface of the shell 1, and the bottom end openings of the connecting pipe A51 and the connecting pipe B52 are blocked, so that the smooth extrusion and use of the liquid detergent are influenced; and when the liquid detergent is used up gradually, the liquid level of the liquid detergent which gradually descends enables the floating ball 8 to drive the corrugated pipe 7 at the bottom ends of the A connecting pipe 51 and the B connecting pipe 52 to stretch along with the liquid level descending, so that the bottom ends of the A connecting pipe 51 and the B connecting pipe 52 are always positioned in the liquid detergent, when the liquid level of the liquid detergent continuously descends to the end, the buoyancy of the floating ball 8 is reduced, the bottom ends of the A connecting pipe 51 and the B connecting pipe 52 are attached to the bottom surface of the shell 1 under the attraction of the first magnet 62 and the second magnet 53, so that the residual liquid detergent at the bottom of the shell 1 can be sucked out and utilized conveniently and quickly, the waste of resources is reduced, and the stability and the environmental protection performance of the liquid detergent bottle during working are enhanced.
To verify the effect of cetylpyridinium chloride and tea saponin addition in the present invention, the following experiments of examples 1-4 were carried out by the applicant.
Example 1
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; equally dividing the solution into solution A and solution B, heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of cocoanut fatty acid diethanol amine and 8 g of fatty alcohol-polyoxyethylene ether, and continuously stirring until the materials are transparent; adjusting pH to be approximately equal to 5 by 0.3 g of sodium citrate, and continuously stirring to dissolve the sodium citrate; the liquid A and the liquid B which are prepared after being filtered by a 300-mesh filter screen are respectively stored in a storage cavity A and a storage cavity B of a liquid detergent bottle, the same amount of liquid detergent is extruded by a pressing nozzle which extrudes the liquid detergent bottle, the same amount of liquid detergent is used for cleaning 100 plates adhered with greasy dirt impurities, and the time required when 100 plates are cleaned is calculated, the time for cleaning the plates is 58 minutes, the stimulation condition of hands is heavier, and no other side effect or adverse reaction exists.
Example 2
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; equally dividing the solution into solution A and solution B, heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine, 8 g of fatty alcohol-polyoxyethylene ether, 0.2 g of cetylpyridinium chloride and 10 g of tea saponin, and continuously stirring until the materials are transparent; adjusting pH to be approximately equal to 5 by 0.3 g of sodium citrate, and continuously stirring to dissolve the sodium citrate; the liquid A and the liquid B which are prepared after being filtered by a 300-mesh filter screen are respectively stored in a storage cavity A and a storage cavity B of a liquid detergent bottle, the same amount of liquid detergent is extruded by a pressing nozzle which extrudes the liquid detergent bottle, the same amount of liquid detergent is used for cleaning 100 plates adhered with greasy dirt impurities, and the time required when 100 plates are cleaned is calculated, the time for cleaning the plates is 42 minutes, the hand stimulation condition is light, and other side effects and adverse reactions are avoided.
Example 3
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; equally dividing the solution into solution A and solution B, heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine, 8 g of fatty alcohol-polyoxyethylene ether, 0.4 g of cetylpyridinium chloride and 10 g of tea saponin, and continuously stirring until the materials are transparent; adjusting pH to be approximately equal to 5 by 0.3 g of sodium citrate, and continuously stirring to dissolve the sodium citrate; the liquid A and the liquid B which are prepared after being filtered by a 300-mesh filter screen are respectively stored in a storage cavity A and a storage cavity B of a liquid detergent bottle, the same amount of liquid detergent is extruded by a pressing nozzle which extrudes the liquid detergent bottle, the same amount of liquid detergent is used for cleaning 100 plates adhered with greasy dirt impurities, and the time required when 100 plates are cleaned is calculated, the time for cleaning the plates is 40 minutes, the hand stimulation condition is good, and other side effects and adverse reactions are avoided.
Example 4
Adding 50 g of metered deionized water, adding 0.2 g of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved; adding 1 g of sodium dimethyl benzene sulfonate and 4 g of propylene glycol, and continuously stirring until the materials are completely dissolved; equally dividing the solution into solution A and solution B, heating to 45 ℃, adding 10 g of fatty alcohol-polyoxyethylene ether sodium sulfate, 12 g of alkyl glycoside, 14 g of dodecyl dimethyl betaine, 6 g of coconut diethanol amine, 8 g of fatty alcohol-polyoxyethylene ether, 0.2 g of cetylpyridinium chloride and 12 g of tea saponin, and continuously stirring until the materials are transparent; adjusting pH to be approximately equal to 5 by 0.3 g of sodium citrate, and continuously stirring to dissolve the sodium citrate; the liquid A and the liquid B which are prepared after being filtered by a 300-mesh filter screen are respectively stored in a storage cavity A and a storage cavity B of a liquid detergent bottle, the same amount of liquid detergent is extruded by a pressing nozzle which extrudes the liquid detergent bottle, the same amount of liquid detergent is used for cleaning 100 plates adhered with greasy dirt impurities, and the time required when 100 plates are cleaned is calculated, the time for cleaning the plates is 41 minutes, the hand stimulation condition is light, and other side effects and adverse reactions are avoided.
Table one
The table I shows that the addition of cetylpyridinium ammonium chloride and tea saponin into the detergent component can effectively improve the cleaning efficiency of the detergent, effectively reduce the hand irritation of the detergent in the cleaning process, and increase the cleaning efficiency and the hand protection effect of the detergent along with the increase of the cetylpyridinium ammonium chloride and the tea saponin component under the condition of ensuring that the dosages of the disodium ethylene diamine tetraacetate, the sodium dimethyl benzene sulfonate, the propylene glycol, the sodium fatty alcohol polyoxyethylene ether sulfate, the alkyl glycoside, the dodecyl dimethyl betaine, the cocoanut fatty acid diethanol amine and the fatty alcohol polyoxyethylene ether are not changed.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are given by way of illustration of the principles of the present invention, and that various changes and modifications may be made without departing from the spirit and scope of the invention as defined by the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (6)
1. A hand-protecting liquid detergent is characterized in that: the hand-protecting detergent comprises the following main active components in parts by weight:
the preparation method of the hand-protecting liquid detergent comprises the following steps:
s1: adding 50-58 parts of metered deionized water, adding 0.1-1 part of disodium ethylene diamine tetraacetate, and starting stirring until the materials are completely dissolved;
s2: after the material is completely dissolved in S1; adding 0.1-1.5 parts of sodium dimethyl benzene sulfonate and 1-10 parts of propylene glycol, and continuously stirring until the materials are completely dissolved;
s3: stirring the added components in S2 until the components are completely dissolved, dividing the solution into solution A and solution B, heating to 45 ℃, adding 10-20 parts of alkyl glycoside, 10-20 parts of dodecyl dimethyl betaine, 5-10 parts of coconut diethanol amine fatty acid and 5-10 parts of fatty alcohol polyoxyethylene ether in equal amount, then adding 10-20 parts of sodium fatty alcohol polyoxyethylene ether sulfate into solution A, adding 0.1-0.5 part of cetylpyridinium chloride into solution B, and continuously stirring until the materials are transparent;
s4: and (4) stirring the added components until the components are transparent in S3, filtering the components by using a 300-mesh filter screen, and respectively storing the prepared solution A and the prepared solution B in a storage cavity A and a storage cavity B of a detergent bottle.
2. The hand-protecting liquid detergent as claimed in claim 1, which is characterized in that: the S2 also contains 10-20 parts of tea saponin, the tea saponin structure is a triterpenoid saponin, and the triterpenoid saponin is often used as a natural surfactant, has mild performance, and has hard water resistance and foaming promotion capability.
3. The hand-protecting liquid detergent as claimed in claim 1, which is characterized in that: the components added into the solution A and the solution B in the S3 also comprise 0.1-1 part of sodium citrate, the sodium citrate is used as a pH regulator to regulate the pH of the A, B solution, and the pH value of the A, B solution is controlled to be 4.5-6.5.
4. The hand-protecting liquid detergent as claimed in claim 1, which is characterized in that: the liquid detergent bottle comprises a shell (1), a bottle cap (2) and a pressing spray head (3), wherein the bottle cap (2) is positioned at the top end of the shell (1), and the pressing spray head (3) is installed on the bottle cap (2); casing (1) inside A that is provided with stores chamber (11) and B and stores chamber (12), and A stores chamber (11) and B and store and be provided with baffle (4) between chamber (12), it is connected with straw (5) to press down shower nozzle (3) bottom, straw (5) bottom middle part joint is on baffle (4) top, baffle (4) top is divided into two rooms with straw (5) inside partition, and two rooms in straw (5) bottom are connected with A connecting pipe (51) and B connecting pipe (52) respectively, A connecting pipe (51) other end is located A and stores chamber (11), B connecting pipe (52) other end is located B and stores chamber (12).
5. The hand-protecting liquid detergent as claimed in claim 4, which is characterized in that: be equipped with on casing (1) bottom surface and adsorb box (6), adsorb box (6) inside and be provided with slip chamber (61), slip chamber (61) inside be equipped with magnet (62) No. one, A connecting pipe (51) all are equipped with magnet (53) No. two with B connecting pipe (52) bottom, magnet (53) are opposite with magnet (62) magnetism No. two.
6. The hand-protecting liquid detergent as claimed in claim 5, which is characterized in that: the bottom ends of the A connecting pipe (51) and the B connecting pipe (52) are composed of elastic corrugated pipes (7), the outer surface of each corrugated pipe (7) is connected with a plastic floating ball (8), and the floating force of the floating balls (8) in the A liquid and the B liquid can enable the bottom ends of the A connecting pipe (51) and the B connecting pipe (52) to float above the bottom surface of the shell (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911019491.3A CN110628526A (en) | 2019-10-24 | 2019-10-24 | Hand-protecting liquid detergent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911019491.3A CN110628526A (en) | 2019-10-24 | 2019-10-24 | Hand-protecting liquid detergent |
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| Publication Number | Publication Date |
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| CN110628526A true CN110628526A (en) | 2019-12-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201911019491.3A Pending CN110628526A (en) | 2019-10-24 | 2019-10-24 | Hand-protecting liquid detergent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111893001A (en) * | 2020-06-15 | 2020-11-06 | 安徽共盈日化有限公司 | Lemon-flavor detergent and packaging container thereof |
| EP4105307A1 (en) * | 2021-06-15 | 2022-12-21 | Henkel AG & Co. KGaA | Stable viscous dilutable cleaning composition |
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| DE60010443D1 (en) * | 1999-03-15 | 2004-06-09 | Procter & Gamble | FRAGRANCE COMPOSITIONS AND METHOD FOR MASKING POOR AMING ODORS |
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| EP4105307A1 (en) * | 2021-06-15 | 2022-12-21 | Henkel AG & Co. KGaA | Stable viscous dilutable cleaning composition |
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