CN109231824B - Method for manufacturing black golden fancy glaze ceramic - Google Patents

Method for manufacturing black golden fancy glaze ceramic Download PDF

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Publication number
CN109231824B
CN109231824B CN201810604531.XA CN201810604531A CN109231824B CN 109231824 B CN109231824 B CN 109231824B CN 201810604531 A CN201810604531 A CN 201810604531A CN 109231824 B CN109231824 B CN 109231824B
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parts
glaze
black
golden flower
golden
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CN109231824A (en
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***
李文溪
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Fujian Dehua Longnan Ceramics Co ltd
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Fujian Dehua Longnan Ceramics Co ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to the technical field of ceramic manufacturing, in particular to a black golden flower glaze and a manufacturing method of ceramic with a black golden flower glaze effect. The black golden flower glaze is characterized by comprising black ground glaze and golden flower glaze, a specially-made raw material formula is selected, unique glazing and firing processes are adopted according to the characteristics of the glaze, the fired black golden flower glaze ceramic surface has black basic color tone, golden yellow stripes are intermittently and uniformly distributed in a stripe shape, and a layer of golden flower which is brilliant yellow is scattered on the black satin surface, so that a steady and noble feeling is brought to people, the black golden flower glaze has unique decoration and artistic effects, can be used as an creation carrier of home decoration and artworks, reduces the use of natural stones, reduces the production cost, saves stone resources, and has positive social and economic benefits.

Description

Method for manufacturing black golden fancy glaze ceramic
Technical Field
The invention relates to the technical field of ceramic manufacturing, in particular to a black golden flower glaze and a manufacturing method of ceramic with a black golden flower glaze effect.
Background
The black golden flower stone is one of the very rare stone varieties, has soft, beautiful and solemn texture, elegant style, is an ideal material for decorating luxurious buildings and is also a traditional material for artistic carving, and in indoor decoration, the black golden flower stone is often processed into various shapes and plates to be used as wall surfaces, floors, tables and columns of buildings and is also commonly used as a material for memorial buildings such as steles, towers, statues and the like; in the process of manufacturing the artwork, the black golden flower stone is carved into practical artwork such as stationery, lamps and utensils.
With the continuous improvement of social and economic levels, the requirements on high-grade indoor decoration effect and ornaments are also continuously improved, but the stone resources are limited and the processing cost is high, so if the glaze with the black golden flower stone effect can be provided and the ceramic material is used for replacing the existing black golden flower stone and used as a carrier for indoor decoration and artwork manufacturing, the use of the stone can be reduced, the production cost is reduced, the stone resources are saved, and the positive social and economic benefits are achieved.
Disclosure of Invention
In order to solve the defects of the prior art, the invention provides a black golden flower glaze, a preparation method and a preparation process thereof.
In order to achieve the purpose, the invention provides a black golden flower glaze which comprises a black ground coat and a golden flower glaze, wherein the black ground coat comprises the following components: 20-30 parts of feldspar, 15-20 parts of kiln dust, 10-15 parts of kaolin, 15-20 parts of sodium carbonate, 5-10 parts of spodumene, 5-10 parts of cobaltite, 5-10 parts of ferric oxide, 1-5 parts of manganese dioxide, 1-5 parts of barium carbonate and 1-5 parts of sodium fluoroaluminate;
the golden flower glaze comprises the following components: 25-10 parts of potash feldspar, 10-15 parts of limestone, 10-15 parts of zircon, 5-10 parts of kaolin, 5-10 parts of calcite, 5-10 parts of calcined talc, 5-10 parts of nickel oxide, 1-5 parts of zinc oxide, 1-5 parts of copper oxide, 1-5 parts of manganese dioxide, 1-5 parts of copper dioxide, 1-5 parts of titanium dioxide, 1-5 parts of nickel oxide and 1-5 parts of quartz.
Preferably, the black ground coat consists of the following components: 23 parts of feldspar, 18 parts of kiln dust, 12 parts of kaolin, 16 parts of sodium carbonate, 6 parts of spodumene, 8 parts of cobaltite, 6 parts of ferric oxide, 4 parts of manganese dioxide, 4 parts of barium carbonate and 1 part of sodium fluoroaluminate.
Preferably, the golden flower glaze comprises the following components: 24 parts of potash feldspar, 13 parts of limestone, 14 parts of zircon, 7 parts of kaolin, 6 parts of calcite, 8 parts of calcined talc, 6 parts of nickel sesquioxide, 2 parts of zinc oxide, 3 parts of copper oxide, 1 part of manganese dioxide, 4 parts of copper dioxide, 3 parts of titanium dioxide, 2 parts of nickel oxide and 1 part of quartz.
Preferably, the black ground coat consists of the following components: 25 parts of feldspar, 16 parts of kiln dust, 14 parts of kaolin, 18 parts of sodium carbonate, 8 parts of spodumene, 5 parts of cobaltite, 8 parts of ferric oxide, 1 part of manganese dioxide, 2 parts of barium carbonate and 3 parts of sodium fluoroaluminate.
Preferably, the golden flower glaze comprises the following components: 18 parts of potash feldspar, 12 parts of limestone, 11 parts of zircon, 8 parts of kaolin, 9 parts of calcite, 6 parts of calcined talc, 6 parts of talc, 7 parts of nickel sesquioxide, 3 parts of zinc oxide, 2 parts of copper oxide, 4 parts of manganese dioxide, 2 parts of copper dioxide, 5 parts of titanium dioxide, 3 parts of nickel oxide and 4 parts of quartz.
A method for manufacturing a ceramic product with black golden flower glaze comprises the following steps:
step 1, preparing a ceramic blank for later use;
step 2, preparing black ground glaze and golden flower glaze, and adjusting the concentration of the black ground glaze and the golden flower glaze, wherein the concentration of the black ground glaze is 50-55 Baume degrees, and the concentration of the golden flower glaze is 30-35 Baume degrees;
step 3, applying black ground coat and then applying golden fancy glaze on the ceramic blank;
and 4, putting the glazed ceramic blank into a kiln, and firing and forming at 1350-1400 ℃ for 6-8 hours.
Further, in step 2, the concentration of the black ground coat is 51, and the concentration of the golden glaze is 32.
Further, in the step 3, the glazing mode of the black ground coat is glazing or dipping glaze, and the glazing mode of the golden glaze is glaze spraying or glaze dropping.
Further, in the step 3, slightly shaking or rotating the ceramic blank body after the golden flower glaze is glazed, so that the golden flower glaze is stunned and opened to form natural patterns.
It can be known from the above description that the black golden flower glaze and the manufacturing method of the black golden flower glaze ceramic provided by the invention select the special raw material formula and adopt the unique glazing and firing process according to the characteristics of the glaze, the fired black golden flower glaze ceramic has black basic tone on the surface, golden yellow stripes are intermittently and uniformly distributed in a stripe shape, and a layer of golden flower is scattered on the black satin surface, so that a steady and noble feeling is brought to people, the black golden flower glaze and the manufacturing method of the black golden flower glaze ceramic have unique decoration and artistic effects, can be used as creation carriers of family decoration and artworks, reduce the use of natural stones, reduce the production cost, save stone resources and have positive social and economic benefits.
Detailed Description
The invention is further described below by means of specific embodiments.
The black golden flower glaze comprises a black ground coat and a golden flower glaze, wherein the black ground coat comprises the following components: 20-30 parts of feldspar, 15-20 parts of kiln dust, 10-15 parts of kaolin, 15-20 parts of sodium carbonate, 5-10 parts of spodumene, 5-10 parts of cobaltite, 5-10 parts of ferric oxide, 1-5 parts of manganese dioxide, 1-5 parts of barium carbonate and 1-5 parts of sodium fluoroaluminate;
the golden flower glaze comprises the following components: 25-10 parts of potash feldspar, 10-15 parts of limestone, 10-15 parts of zircon, 5-10 parts of kaolin, 5-10 parts of calcite, 5-10 parts of calcined talc, 5-10 parts of nickel oxide, 1-5 parts of zinc oxide, 1-5 parts of copper oxide, 1-5 parts of manganese dioxide, 1-5 parts of copper dioxide, 1-5 parts of titanium dioxide, 1-5 parts of nickel oxide and 1-5 parts of quartz.
The first embodiment is as follows:
the black golden flower glaze comprises a black ground coat and a golden flower glaze, wherein the black ground coat comprises the following components: the black ground coat comprises the following components: 23 parts of feldspar, 18 parts of kiln dust, 12 parts of kaolin, 16 parts of sodium carbonate, 6 parts of spodumene, 8 parts of cobaltite, 6 parts of ferric oxide, 4 parts of manganese dioxide, 4 parts of barium carbonate and 1 part of sodium fluoroaluminate;
the golden flower glaze comprises the following components: 24 parts of potash feldspar, 13 parts of limestone, 14 parts of zircon, 7 parts of kaolin, 6 parts of calcite, 8 parts of calcined talc, 6 parts of nickel sesquioxide, 2 parts of zinc oxide, 3 parts of copper oxide, 1 part of manganese dioxide, 4 parts of copper dioxide, 3 parts of titanium dioxide, 2 parts of nickel oxide and 1 part of quartz.
The second embodiment is as follows:
the black golden flower glaze comprises a black ground coat and a golden flower glaze, wherein the black ground coat comprises the following components: the black ground coat comprises the following components: 25 parts of feldspar, 16 parts of kiln dust, 14 parts of kaolin, 18 parts of sodium carbonate, 8 parts of spodumene, 5 parts of cobaltite, 8 parts of ferric oxide, 1 part of manganese dioxide, 2 parts of barium carbonate and 3 parts of sodium fluoroaluminate.
The golden flower glaze comprises the following components: 18 parts of potash feldspar, 12 parts of limestone, 11 parts of zircon, 8 parts of kaolin, 9 parts of calcite, 6 parts of calcined talc, 6 parts of talc, 7 parts of nickel sesquioxide, 3 parts of zinc oxide, 2 parts of copper oxide, 4 parts of manganese dioxide, 2 parts of copper dioxide, 5 parts of titanium dioxide, 3 parts of nickel oxide and 4 parts of quartz.
A method for manufacturing a ceramic product with black golden flower glaze comprises the following steps of:
step 1, preparing a ceramic blank for later use;
step 2, preparing a black ground coat and a golden flower glaze, and adjusting the concentration of the black ground coat and the golden flower glaze, wherein the concentration of the black ground coat is 50-55 baume degrees, the concentration of the golden flower glaze is 30-35 baume degrees, the concentration of the optimized black ground coat is 51, and the concentration of the golden flower glaze is 32;
step 3, firstly applying black ground coat and then applying golden fancy glaze on the ceramic blank, wherein the glazing mode of the black ground coat is glazing or dipping, the glazing mode of the golden fancy glaze is glaze spraying or dripping, and the ceramic blank is slightly shaken or rotated after the golden fancy glaze is applied, so that the golden fancy glaze is in open halo to form natural patterns;
and 4, putting the glazed ceramic blank into a kiln, and firing and forming at 1350-1400 ℃ for 6-8 hours.
The black golden flower glaze and the manufacturing method of the black golden flower glaze ceramic select a special raw material formula and adopt unique glazing and firing processes according to the characteristics of the glaze, the surface of the fired black golden flower glaze ceramic has black basic tone, golden yellow stripes are intermittently and uniformly distributed in a stripe shape, and a layer of golden yellow flower is scattered on the black satin surface, so that a steady and noble feeling is brought to people, the black golden flower glaze and the manufacturing method of the black golden flower glaze ceramic have unique decoration and artistic effects, can be used as creation carriers of family decorations and artworks, reduce the use of natural stones, reduce the production cost, save stone resources and have positive social and economic benefits.
The above description is only an embodiment of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by using the design concept should fall within the scope of infringing the present invention.

Claims (4)

1. The manufacturing method of the black golden flower glaze ceramic product is characterized by comprising a black ground coat and a golden flower glaze, wherein the black ground coat comprises the following components: 20-30 parts of feldspar, 15-20 parts of kiln dust, 10-15 parts of kaolin, 15-20 parts of sodium carbonate, 5-10 parts of spodumene, 5-10 parts of cobaltite, 5-10 parts of ferric oxide, 1-5 parts of manganese dioxide, 1-5 parts of barium carbonate and 1-5 parts of sodium fluoroaluminate;
the golden fancy glaze comprises the following components: 25-10 parts of potash feldspar, 10-15 parts of limestone, 10-15 parts of zircon, 5-10 parts of kaolin, 5-10 parts of calcite, 5-10 parts of calcined talc, 5-10 parts of nickel oxide, 1-5 parts of zinc oxide, 1-5 parts of copper oxide, 1-5 parts of manganese dioxide, 1-5 parts of copper dioxide, 1-5 parts of titanium dioxide, 1-5 parts of nickel oxide and 1-5 parts of quartz. (ii) a
The manufacturing method of the black golden flower glaze ceramic product comprises the following specific steps:
step 1, preparing a ceramic blank for later use;
step 2, preparing black ground glaze and golden flower glaze, and adjusting the concentration of the black ground glaze and the golden flower glaze, wherein the concentration of the black ground glaze is 50-55 Baume degrees, and the concentration of the golden flower glaze is 30-35 Baume degrees;
step 3, applying black ground coat and then applying golden fancy glaze on the ceramic blank;
and 4, putting the glazed ceramic blank into a kiln, and firing and forming at 1350-1400 ℃ for 6-8 hours.
2. The method for manufacturing the ceramic product with the black golden flower glaze according to claim 1, wherein in the step 2, the concentration of the black ground glaze is 51 baume degrees, and the concentration of the golden flower glaze is 32 baume degrees.
3. The method for manufacturing the ceramic product with black golden flower glaze according to claim 1, wherein the method comprises the following steps: in the step 3, the glazing mode of the black ground coat is glazing or dipping glaze, and the glazing mode of the golden glaze is glaze spraying or glaze dropping.
4. The method for manufacturing a ceramic product with black golden flower glaze according to claim 1 or 3, wherein the ceramic product is prepared by the following steps: in the step 3, slightly shaking or rotating the ceramic blank after the golden flower glaze is glazed, so that the golden flower glaze is in halo open to form natural patterns.
CN201810604531.XA 2016-04-28 2016-04-28 Method for manufacturing black golden fancy glaze ceramic Active CN109231824B (en)

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CN107162602A (en) * 2017-06-07 2017-09-15 景德镇陶瓷大学 A kind of formula of glaze base bonding agent and preparation method thereof
CN107759090B (en) * 2017-11-21 2020-12-01 广东道氏技术股份有限公司 Glaze material with effect of imitating black gold sand marble and application thereof
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CN110423140A (en) * 2019-06-26 2019-11-08 景德镇欧神诺陶瓷有限公司 A kind of process using inkjet printing production Portoro
CN110642591A (en) * 2019-09-25 2020-01-03 张军召 Jun porcelain with rust golden flower colored glaze and preparation method thereof
CN112374909A (en) * 2020-11-23 2021-02-19 王建勋 Firing process of black gold bowl
CN114907013B (en) * 2022-04-21 2024-01-12 景德镇陶瓷大学 Preparation and application method of one-time firing black-white interphase ink glaze
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