CN105601343B - A kind of change colour picks the production method of colored Antique Imitation Tiles - Google Patents
A kind of change colour picks the production method of colored Antique Imitation Tiles Download PDFInfo
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- CN105601343B CN105601343B CN201610049106.XA CN201610049106A CN105601343B CN 105601343 B CN105601343 B CN 105601343B CN 201610049106 A CN201610049106 A CN 201610049106A CN 105601343 B CN105601343 B CN 105601343B
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- glaze
- ceramic tile
- yellow
- pick
- silicon oxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
A kind of change colour picks the production method of colored Antique Imitation Tiles, the yellow glaze modulated is mainly applied and applied on base substrate by it, then carry out picking flower process processing, pick the decorative pattern grain pattern for carving surface, enter kiln and be warming up to 1250 DEG C of firing temperature 1150 DEG C under reducing atmosphere, natural cooling after being incubated 10 20 minutes, sanding and polishing processing is carried out to the ceramic tile surface of firing, again in ceramic tile surface even application colloidal photon crystal structure color glaze, 500~550 DEG C of secondary heat treatment is carried out afterwards, it is set to carry out selective reflecting to visible ray, refraction, diffraction or interference and caused a variety of colors, ceramic tile surface is observed from different angles, coordinate simultaneously and pick flower process, the color change of riot of color can be produced, reach certain decorative effect;There is the present invention discoloration to pick the decorative characteristics for spending decorative pattern modelled after an antique, can be in building decoration, the extensive use of decorative porcelain field.
Description
Technical field
The present invention relates to a kind of Imitative Ancient Porcelains that can be widely applied to the fields such as building decoration ceramics, interior decoration ceramics
Brick, it is specifically related to a kind of change colour and picks the production method of colored Antique Imitation Tiles.
Background technology
Antique Imitation Tiles belong to common ceramic tile, copy conventional pattern typically using acid corrosion, autoclaving, surface polishing, table
The processes such as face silk-screen printing carry out doing old processing.Its essence and ceramic tile of glazing, on glaze colours mainly based on dumb light, city
There is the main tone of product on field:Yellow, coffee color, white, black, kermesinus etc., product mainly look for change on color
Innovation is asked, and is that grain pattern pattern is fired forms in smooth billet surface printing in terms of ceramic tile patterns grain pattern, texture moulding
Single shortage third dimension and stereovision.
And the discoloration glazed tile of in the market is mostly the change with ambient light, or the difference with visual angle,
Brick face shows different colours, gives people a kind of bright and colourful beautiful enjoyment.The characteristics of this brick also have added in glaze it is a kind of by
The colouring agent of rare-earth oxide composition, causes glaze paint that the absorption and reflection of selectivity is presented, is absorbed in visible-range
It is different from degree of reflection and multiple color occur.But such a brick is that the color from surface is innovated, and lacks certain glaze
Face texture variations.
The content of the invention
It is an object of the invention to provide a kind of change colour to pick the production method of colored Antique Imitation Tiles.
To reach above-mentioned purpose, the technical solution adopted by the present invention is:
1) preparation of yellow glaze:
By mass percentage by 55-70% feldspar, 20-30% quartz, 5-10% calcite, 1-5% talcum,
2-5% zirconium vanadium yellow material is well mixed to obtain compound, then adds the trimerization phosphorus of mixture quality 0.4% into compound again
Sour sodium and 1% CMC are well mixed, and are finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze;
2) yellow glaze slip is equably applied to apply and glaze paint is formed on base substrate, then carried out picking after flower process handles to obtain and pick glaze
Sample, enter kiln and be warming up to 1150-1250 DEG C under reducing atmosphere, be incubated 10-20 minutes, natural cooling obtains yellow glaze flower
Line ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product;
4) deposited one layer of nano silicon oxide crystal film with photon is applied in ridge design ceramic tile surface of semi-finished, then at 500~550 DEG C
Burn till, obtain discoloration and pick colored Antique Imitation Tiles.
The nano silicon oxide crystal film with photon is the nanometer silicon oxide colloid micro mist using 200~350nm, and by its point
The slurry for being prepared into that mass concentration is 0.5-2% in ethanol solution is dispersed in, then this slurry is sprayed with the coating thickness of 1-2 microns
In ridge design ceramic tile surface of semi-finished, nano silicon oxide crystal film with photon is formed.
Then the present invention picks traditional hand of colored porcelain due to imposing on the glaze iso-surface patch decorative pattern of yellow glaze using Yao county kiln
Method removes the glaze paint part beyond decorative pattern, after kiln-firing, and is polished grinding process to ceramic tile surface, makes the table of ceramic tile
Face texture is more clear lively, adds the variations in detail of decorative pattern texture, produces the texture of whole ceramic tile surface and more strengthens
Strong contrast, either third dimension and fidelity are obtained for reinforcement.To ceramic tile surface even application colloidal photon crystal structure
Color glaze, in order to which ceramic tile surface is had to the rich colors of more riot of color in different angle and directions.
Compared with the prior art the present invention, there is the ceramic tile that enables to produce to be formed more rich in third dimension and clearly
The advantages of texture is lively, and surface color and polish is rich in more life-like presentation.
Brief description of the drawings
The ceramic tile blank that Fig. 1 is the present invention applies the profile after yellow glaze;
Fig. 2 is to ceramic tile surface pick the profile after glaze;
Fig. 3 is that the profile after polishing is polished to ceramic tile surface after firing cooling;
Fig. 4 is that ceramic tile carcass sprays the profile after colloidal photon crystal structure color glaze;
Fig. 5 is the positive effect figure of ceramic tile
Embodiment
The present invention is described in further detail with reference to embodiment.
Embodiment 1:
1) preparation of yellow glaze:
By mass percentage by 55% feldspar, 30% quartz, 10% calcite, 3% talcum, 2% zirconium vanadium
Yellow material is well mixed to obtain compound, then adds the sodium tripolyphosphate and 1% of mixture quality 0.4% into compound again
CMC is well mixed, and is finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze slip;
2) glaze slip is equably applied to apply and glaze paint 2 (referring to Fig. 1) is formed on base substrate 1, then carry out picking flower process handling
To the sample 3 (referring to Fig. 2) after glaze is picked, enter kiln and be warming up to 1150 DEG C under reducing atmosphere, be incubated 20 minutes, natural cooling produces
To yellow glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product 4 (referring to Fig. 3);
4) 200~350nm nanometer silicon oxide colloid micro mist is used, and is dispersed in ethanol solution and is prepared into quality
Concentration is 0.5% slurry, then this slurry is sprayed on into the surface of ridge design ceramic tile semi-finished product 4, shape with 2 microns of coating thickness
Into nano silicon oxide crystal film with photon 5 (referring to Fig. 4), after burnt till then at 500 DEG C, obtain discoloration and pick colored Antique Imitation Tiles (referring to Fig. 5).
Embodiment 2:
1) preparation of yellow glaze:
By mass percentage by 60% feldspar, 20% quartz, 10% calcite, 5% talcum, 5% zirconium vanadium
Yellow material is well mixed to obtain compound, then adds the sodium tripolyphosphate and 1% of mixture quality 0.4% into compound again
CMC is well mixed, and is finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze slip;
2) glaze slip is equably applied to apply and glaze paint 2 (referring to Fig. 1) is formed on base substrate 1, then carry out picking flower process handling
To the sample 3 (referring to Fig. 2) after glaze is picked, enter kiln and be warming up to 1200 DEG C under reducing atmosphere, be incubated 15 minutes, natural cooling produces
To yellow glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product 4 (referring to Fig. 3);
4) 200~350nm nanometer silicon oxide colloid micro mist is used, and is dispersed in ethanol solution and is prepared into quality
Concentration is 2% slurry, then this slurry is sprayed on into the surface of ridge design ceramic tile semi-finished product 4 with 1 micron of coating thickness, is formed
Nano silicon oxide crystal film with photon 5 (referring to Fig. 4), after burnt till then at 500 DEG C, obtain discoloration and pick colored Antique Imitation Tiles (referring to Fig. 5).
Embodiment 3:
1) preparation of yellow glaze:
It is by mass percentage that 70% feldspar, 20% quartz, 5% calcite, 2% talcum, 3% zirconium vanadium is yellow
Coloring material for mixing it is uniform compound, the sodium tripolyphosphate and 1% of mixture quality 0.4% is then added into compound again
CMC is well mixed, and is finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze slip;
2) glaze slip is equably applied to apply and glaze paint 2 (referring to Fig. 1) is formed on base substrate 1, then carry out picking flower process handling
To the sample 3 (referring to Fig. 2) after glaze is picked, enter kiln and be warming up to 1250 DEG C under reducing atmosphere, be incubated 10 minutes, natural cooling produces
To yellow glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product 4 (referring to Fig. 3);
4) 200~350nm nanometer silicon oxide colloid micro mist is used, and is dispersed in ethanol solution and is prepared into quality
Concentration is 1% slurry, then this slurry is sprayed on into the surface of ridge design ceramic tile semi-finished product 4, shape with 1.5 microns of coating thickness
Into nano silicon oxide crystal film with photon 5 (referring to Fig. 4), after burnt till then at 520 DEG C, obtain discoloration and pick colored Antique Imitation Tiles (referring to Fig. 5).
Embodiment 4:
1) preparation of yellow glaze:
It is by mass percentage that 62% feldspar, 25% quartz, 8% calcite, 1% talcum, 4% zirconium vanadium is yellow
Coloring material for mixing it is uniform compound, the sodium tripolyphosphate and 1% of mixture quality 0.4% is then added into compound again
CMC is well mixed, and is finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze slip;
2) glaze slip is equably applied to apply and glaze paint 2 (referring to Fig. 1) is formed on base substrate 1, then carry out picking flower process handling
To the sample 3 (referring to Fig. 2) after glaze is picked, enter kiln and be warming up to 1180 DEG C under reducing atmosphere, be incubated 18 minutes, natural cooling produces
To yellow glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product 4 (referring to Fig. 3);
4) 200~350nm nanometer silicon oxide colloid micro mist is used, and is dispersed in ethanol solution and is prepared into quality
Concentration is 1.5% slurry, then this slurry is sprayed on into the surface of ridge design ceramic tile semi-finished product 4 with 1.5 microns of coating thickness,
Formed nano silicon oxide crystal film with photon 5 (referring to Fig. 4), after burnt till then at 500,500,520,540,530,550 DEG C, become
Color picks colored Antique Imitation Tiles (referring to Fig. 5).
Embodiment 5:
1) preparation of yellow glaze:
It is by mass percentage that 64% feldspar, 23% quartz, 6% calcite, 4% talcum, 3% zirconium vanadium is yellow
Coloring material for mixing it is uniform compound, the sodium tripolyphosphate and 1% of mixture quality 0.4% is then added into compound again
CMC is well mixed, and is finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze slip;
2) glaze slip is equably applied to apply and glaze paint 2 (referring to Fig. 1) is formed on base substrate 1, then carry out picking flower process handling
To the sample 3 (referring to Fig. 2) after glaze is picked, enter kiln and be warming up to 1230 DEG C under reducing atmosphere, be incubated 13 minutes, natural cooling produces
To yellow glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product 4 (referring to Fig. 3);
4) 200~350nm nanometer silicon oxide colloid micro mist is used, and is dispersed in ethanol solution and is prepared into quality
Concentration is 0.8% slurry, then this slurry is sprayed on into the surface of ridge design ceramic tile semi-finished product 4, shape with 2 microns of coating thickness
Into nano silicon oxide crystal film with photon 5 (referring to Fig. 4), after burnt till then at 530 DEG C, obtain discoloration and pick colored Antique Imitation Tiles (referring to Fig. 5).
Embodiment 6:
1) preparation of yellow glaze:
It is by mass percentage that 59% feldspar, 28% quartz, 9% calcite, 2% talcum, 2% zirconium vanadium is yellow
Coloring material for mixing it is uniform compound, the sodium tripolyphosphate and 1% of mixture quality 0.4% is then added into compound again
CMC is well mixed, and is finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze slip;
2) glaze slip is equably applied to apply and glaze paint 2 (referring to Fig. 1) is formed on base substrate 1, then carry out picking flower process handling
To the sample 3 (referring to Fig. 2) after glaze is picked, enter kiln and be warming up to 1200 DEG C under reducing atmosphere, be incubated 10 minutes, natural cooling produces
To yellow glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtain ridge design ceramic tile half into
Product 4 (referring to Fig. 3);
4) 200~350nm nanometer silicon oxide colloid micro mist is used, and is dispersed in ethanol solution and is prepared into quality
Concentration is 1.8% slurry, then this slurry is sprayed on into the surface of ridge design ceramic tile semi-finished product 4 with 1.3 microns of coating thickness,
Formed nano silicon oxide crystal film with photon 5 (referring to Fig. 4), after burnt till then at 550 DEG C, obtain discoloration and pick colored Antique Imitation Tiles (referring to figure
5)。
Claims (2)
1. a kind of change colour picks the production method of colored Antique Imitation Tiles, it is characterised in that:
1) preparation of yellow glaze:
By mass percentage by 55-70% feldspar, 20-30% quartz, 5-10% calcite, 1-5% talcum, 2-
5% zirconium vanadium yellow material is well mixed to obtain compound, then adds the tripolyphosphate of mixture quality 0.4% into compound again
Sodium and 1% CMC are well mixed, and are finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3Obtain yellow glaze;
2) yellow glaze slip is equably applied to apply on base substrate (1) and forms glaze paint (2), then carried out picking flower process handling to obtain and pick glaze
Sample (3) afterwards, enter kiln and be warming up to 1150-1250 DEG C under reducing atmosphere, be incubated 10-20 minutes, natural cooling obtains Huang
Color glaze decorative pattern ceramic tile;
3) grinding process is polished to yellow glaze decorative pattern ceramic tile surface using polishing and burnishing machine, obtains ridge design ceramic tile semi-finished product
(4);
4) deposited one layer of nano silicon oxide crystal film with photon (5) is applied on ridge design ceramic tile semi-finished product (4) surface, then at 500~550
DEG C burn till, obtain discoloration and pick colored Antique Imitation Tiles.
2. according to claim 1 change colour picks the production method of colored Antique Imitation Tiles, it is characterised in that:The nano silicon oxide light
Sub- crystal film (5) is the nanometer silicon oxide colloid micro mist using 200~350nm, and is dispersed in ethanol solution and is prepared into
Mass concentration is 0.5-2% slurry, then this slurry is sprayed on into ridge design ceramic tile semi-finished product with the coating thickness of 1-2 microns
Surface, form nano silicon oxide crystal film with photon.
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CN106431503A (en) * | 2016-09-20 | 2017-02-22 | 陕西科技大学 | Variable-color engraved archaized tile and preparation method |
CN106565279A (en) * | 2016-10-21 | 2017-04-19 | 陕西火凤凰艺术陶瓷有限责任公司 | Method for quick glazing of ceramic multicolor glaze |
CN111470883A (en) * | 2020-04-07 | 2020-07-31 | 陕西科技大学 | SiO (silicon dioxide)2Photonic crystal structure color coating and preparation process thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1350995A (en) * | 2000-10-31 | 2002-05-29 | 王晓朝 | Process for preparing green-enamel black porcelain |
CN1690010A (en) * | 2004-04-29 | 2005-11-02 | 焦作市金谷斋文化艺术传播有限责任公司 | Process for making a chinaware |
CN104030730A (en) * | 2014-06-10 | 2014-09-10 | 平定县冠窑砂器陶艺有限公司 | Method for performing black glaze engraving sandblasting on surface of sand ware |
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JPH06128064A (en) * | 1992-10-15 | 1994-05-10 | Inax Corp | Method for decorating tile |
DE102007021820A1 (en) * | 2007-05-07 | 2008-11-13 | Chemische Fabrik Budenheim Kg | Laser pigments for ceramics |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1350995A (en) * | 2000-10-31 | 2002-05-29 | 王晓朝 | Process for preparing green-enamel black porcelain |
CN1690010A (en) * | 2004-04-29 | 2005-11-02 | 焦作市金谷斋文化艺术传播有限责任公司 | Process for making a chinaware |
CN104030730A (en) * | 2014-06-10 | 2014-09-10 | 平定县冠窑砂器陶艺有限公司 | Method for performing black glaze engraving sandblasting on surface of sand ware |
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