CN110423140A - A kind of process using inkjet printing production Portoro - Google Patents
A kind of process using inkjet printing production Portoro Download PDFInfo
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- CN110423140A CN110423140A CN201910557784.0A CN201910557784A CN110423140A CN 110423140 A CN110423140 A CN 110423140A CN 201910557784 A CN201910557784 A CN 201910557784A CN 110423140 A CN110423140 A CN 110423140A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of processes using inkjet printing production Portoro; belong to Portoro production field; after blank forming for producing the Portoro; it successively carries out applying overglaze, ink-jet printed, roller print protection glaze, throwing glaze process in billet surface, carries out high temperature firing finished product in roller kilns later.Make glaze that there is better stereovision and texture using bilayer superposition glaze technology, throwing glaze formula by improvement is more full true to nature by the pattern of Portoro, it is more nearly former stone skin texture, it promotes brightness and light transmittance is promoted, combined type throws base machine and keeps the ceramic body after throwing more smooth, and solves water wave print using advanced ink-jet printer, white point and not true enough the lively problem of texture, silk screen is replaced to protect glaze with the roller protection glaze that 0.2%-0.3% is added after ink-jet printed, effectively improve venting phenomenon, substantially increase production capacity, ceramic tile passes through rough polishing machine, middle throwing machine, the noble and unsullied bright wax-polishing machine of precision polisher makes ceramic tile have mirror effect.
Description
Technical field
The present invention relates to Portoro production fields, more particularly to a kind of technique side using inkjet printing production Portoro
Method.
Background technique
Portoro glazed tile has the characteristics that colour-fast, soil pick-up, magnificent texture and noble gloss is not extremely true to nature
Ground reduces the skin texture of true stone, and formaldehydeless and radiationless advantage escorts for the health of resident, but traditional Portoro
Production technology is easy to appear the defects such as water wave print, white point, production capacity be low, influences aesthetic feeling, and complex process, spends human and material resources,
The useless screen printing glaze pollution generated is big, and the excellent rate of product is low, therefore, how to make Portoro more rich in true stone skin texture, more standby China
Beautiful texture and noble gloss reduce cost, are manufacturer's problems in the urgent need to address.
Summary of the invention
In order to overcome the drawbacks of the prior art, technical problem to be solved by the present invention lies in propose a kind of to beat using ink-jet
The process of print production Portoro makes glaze have better stereovision and texture, by changing using bilayer superposition glaze technology
Good throwing glaze formula is more full true to nature by the pattern of Portoro, is more nearly former stone skin texture, brightness and light transmittance and traditional
Compared to there has also been very big promotion, throwing base machine and innovating using combined type and changing original piece material of throwing makes ceramic blank after throwing
Body is more smooth, and using advanced ink-jet printer and uses the advanced ceramics ink customized from ink producer, strict control
Pattern is more clear by the green body temperature of ink jet printer while extending the high load capacity working time of ink jet printer, with ink-jetting process generation
For traditional roller printing, ideally solves the problems, such as that water wave print, white point and texture are not true lively enough, used after ink-jet printed
The roller protection glaze that 0.2%-0.3% is added replaces silk screen to protect glaze, not only effectively improves venting phenomenon, but also greatly improve
The ceramic tile of production capacity, kiln discharge makes ceramic tile have mirror effect by rough polishing machine, middle throwing machine, precision polisher noble and unsullied bright wax-polishing machine.
To achieve this purpose, the present invention adopts the following technical scheme:
The present invention provides a kind of processes using inkjet printing production Portoro, for producing the base of the Portoro
After body formed, successively carry out applying overglaze, ink-jet printed, roller print protection glaze, throwing glaze process in billet surface, later in roller kilns
Middle progress high temperature firing finished product；
It is wherein described to apply overglaze used in overglaze process by weight percentage, including following components: overglaze dry powder:
50%-60% calcines alpha-aluminium oxide: 0.5%-0.9%, burns talcum: 1%-3%, zirconium silicate: 10%-15%, water: 27%-
30%；Wherein the overglaze dry powder by weight percentage, including following chemical constituent: SiO2:55%-65%, Al2O3:
25%-35%, K2O:2%-10%, Na2O:1%-6%；And ball mill wet ball grinding is added in overglaze component, and pass through 325
Simultaneously the overglaze is made except iron in mesh screen；
The ink-jet printed mode is that ceramic ink jet machine prints dark fund floral pattern；
Roller print used in the roller print protection glaze process protects glaze by weight percentage, including following components:
Throw glaze: 20%-30, water: 7%-9%, stamp-pad ink: 70%-75% helps flat agent: 0.2%-0.3%；
It is described to throw throwing glaze practical in glaze process, by weight percentage, including following components: throw glaze dry powder: 70%-
75%, burn talcum: 1%-3%, water: 28%-30%；Wherein the throwing glaze dry powder is by weight percentage, including following
Chemical constituent: SiO2: 40%-50%, Al2O3: 5%-15%, K2O:2%-6%, Na2O:1%-5%, CaO:5%-15%,
MgO:2%-6%；And glaze component will be thrown ball mill is added and carry out wet grinding, and by 325 mesh screens and except iron be made it is described
Throw glaze；
The finished product of the Portoro produce the following steps are included:
A: the green body after molding is smooth by combined type throwing base machine throwing；
B: the overglaze is imposed on the green body by step A in such a way that bell jar drenches glaze；
C: the green body that overglaze is applied by step B is printed into dark fund floral pattern using ceramic ink jet machine；
D: roller print protection glaze will be carried out by the green body in step C；
E: the throwing glaze is imposed in such a way that bell jar drenches glaze on the green body in step D by roller protection glaze；
F: high temperature firing, 1080 DEG C of firing temperature-will be carried out in being sent into roller kilns by the green body of step E
1200 DEG C, simultaneously finished product is made in firing period 52min；
G: will be polished by the Portoro by kiln discharge of step F by rough polishing machine, middle throwing machine, precision polisher,
In rough polishing machine described above, the abrading block of the middle throwing machine and the precision polisher is Elastic abrasive body；
H: the Portoro after polishing is used into nanometer black wax water waxing glazing by super clean bright wax-polishing machine.
Preferably, the throwing piece material for throwing base machine has wool felt, dishcloth, is adopted according to the surface smoothness of ceramic body
Different materials is taken to combine.
Preferably, the bell jar is made of stainless steel bell jar, copper band, funnel, and wherein copper band divides fine copper material and screen mesh type,
The use of copper band is determined according to the flatness of glaze.
Preferably, the ingredient of the Elastic abrasive body contains diamond dust, different according to the Mohs' hardness of glaze, using different cutting edges of a knife or a sword
The Elastic abrasive body of sharp degree and different Elastic abrasive body combinations.
The invention has the benefit that
A kind of process using inkjet printing production Portoro provided by the invention, is made using bilayer superposition glaze technology
Glaze has better stereovision and texture, and the throwing glaze formula by improvement is more full true to nature by the pattern of Portoro, more
Close to original stone skin texture, there has also been very big promotions compared with traditional for brightness and light transmittance, throw base machine using combined type and innovate
Changing original throwing piece material keeps the ceramic body after throwing more smooth, and using advanced ink-jet printer and use is from ink
The advanced ceramics ink of man, water factory customization, strict control are more clear pattern by the green body temperature of ink jet printer while extending spray
The high load capacity working time of black machine, traditional roller printing is replaced with ink-jetting process, ideally solve water wave print, white point and line
Not true enough the lively problem of reason, the ink-jet printed rear roller with addition 0.2%-0.3% protect glaze that silk screen is replaced to protect glaze, no
Venting phenomenon is only effectively improved, and substantially increases production capacity, the ceramic tile of kiln discharge is high by rough polishing machine, middle throwing machine, precision polisher
Clean bright wax-polishing machine makes ceramic tile have mirror effect.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer and more explicit, by the following examples to the present invention into one
Step is described in detail.
A kind of process using inkjet printing production Portoro, after the blank forming for producing the Portoro, In
Billet surface successively carries out applying overglaze, ink-jet printed, roller print protection glaze, throwing glaze process, carries out high temperature in roller kilns later
It is burnt into finished product；
Wherein apply overglaze used in overglaze process by weight percentage, including following components: overglaze dry powder: 50%-
60%, alpha-aluminium oxide: 0.5%-0.9% is calcined, talcum: 1%-3%, zirconium silicate: 10%-15%, water: 27%-30% is burnt；Its
Middle overglaze dry powder by weight percentage, including following chemical constituent: SiO2:55%-65%, Al2O3:25%-35%,
K2O:2%-10%, Na2O:1%-6%；And ball mill wet ball grinding is added in its component, and by 325 mesh screens and remove iron
Overglaze is made；Ink-jet printed mode is that ceramic ink jet machine prints dark fund floral pattern；It is rolled used in roller print protection glaze process
Cylinder print protects glaze by weight percentage, including following components: glaze: 20%-30 is thrown, water: 7%-9%, and stamp-pad ink: 70%-75%,
Help flat agent: 0.2%-0.3%；Throwing glaze practical in glaze process is thrown, by weight percentage, including following components: throw glaze dry powder:
70%-75% burns talcum: 1%-3%, water: 28%-30%；Wherein throw glaze dry powder by weight percentage, including following chemistry
Component: SiO2: 40%-50%, Al2O3: 5%-15%, K2O:2%-6%, Na2O:1%-5%, CaO:5%-15%, MgO:
2%-6%；And ball mill is added in its component and carries out wet grinding, and throwing glaze is made by 325 mesh screens and except iron.
In order to enable the pattern of the Portoro arrived is more full true to nature, the ultimate attainment true stone skin texture of reduction.
A kind of such as above-mentioned process using inkjet printing production Portoro, the finished product production of Portoro includes following step
It is rapid:
S1: by the calcining alpha-aluminium oxide of overglaze A, 0.5%-0.9% of 50%-60%, burning talcum, the 10%- of 1%-3%
The water addition ball mill wet ball grinding of 15% zirconium silicate, 27%-30%, crosses 325 mesh screens and except overglaze is made in iron；
S2: by the water addition ball mill progress wet process for burning talcum, 28%-30% of throwing glaze B, 1%-3% of 70%-75%
Grinding crosses 325 mesh screens and except throwing glaze is made in iron；
S3: ceramic body is thrown into the throwing of base machine by combined type and is put down；
S4: manufactured overglaze in above-mentioned (S1) is imposed on into the ceramic blank by above-mentioned S3 process in such a way that bell jar drenches glaze
On body；
S5: the ceramic body for drenching overglaze is printed into dark fund floral pattern using ceramic ink jet machine；
S6: the ceramic body that dark fund floral pattern was beaten in above-mentioned (S4) is subjected to roller print protection glaze；
S7: throwing glaze manufactured in above-mentioned (S2) is imposed in above-mentioned (S6) in such a way that bell jar drenches glaze and printed roller protection
On the ceramic body of glaze；
S8: the ceramic body for throwing glaze will be drenched in above-mentioned (S6) and carries out high temperature firing, firing temperature in ceramic roller kiln
1080 DEG C -1200 DEG C, firing period 52min；
S9: by the Portoro ceramic tile of kiln discharge by rough polishing machine, middle throwing machine, precision polisher, wherein the abrading block of polishing machine is special
The Elastic abrasive body of ultrafine super-dense super clean；
S10: the ceramic tile after polishing is waxed into glazing further using nanometer black wax water by super clean bright wax-polishing machine, is thrown
The throwing piece material of base machine has wool felt, dishcloth, takes different materials to combine according to the surface smoothness of ceramic body.
Further, bell jar is made of stainless steel bell jar, copper band, funnel, and wherein copper band divides fine copper material and screen mesh type, root
The mode using bell jar leaching glaze of copper band is determined according to the flatness of glaze, wherein parameter are as follows: 26 ± 5s of flow rate of slurry, specific gravity 1.90
± 0.05g/mL, glaze volume 456 ± 7.6g/ piece, fineness be after 325 mesh screen residues siccative weight percent be 0.4%~
0.7%.
Further, the ingredient of Elastic abrasive body contains diamond dust, different according to the Mohs' hardness of glaze, using different sharp
The Elastic abrasive body of degree and different Elastic abrasive body combinations.
It to sum up learns, using overglaze and throwing glaze bilayer superposition glaze technology makes glaze have better stereovision and texture, warp
The throwing glaze formula for crossing improvement is more full true to nature by the pattern of Portoro, is more nearly former stone skin texture, brightness and light transmittance and biography
System compared to there has also been very big promotions.To make ceramic body more smooth, base machine is thrown using combined type and innovates change original
Some throwing piece materials, and ink-jet printer is used, control makes pattern be more clear while extend by the green body temperature of ink jet printer
The high load capacity working time of ink jet printer.Furthermore using ink-jetting process replace traditional roller printing, solve water wave print, white point and
Not true enough the lively problem of texture, the ink-jet printed rear roller with addition 0.2%-0.3% protect glaze that silk screen is replaced to protect glaze,
Venting phenomenon is not only effectively improved, but also substantially increases production capacity, the ceramic tile of kiln discharge passes through rough polishing machine, middle throwing machine, precision polisher
Noble and unsullied bright wax-polishing machine makes ceramic tile have mirror effect.
The present invention produces Portoro by a kind of following specific embodiments use inkjet printing that the present invention is further explained
Preparation process.
Embodiment 1:
Composition of raw materials: ceramic body is using general ceramic brick body；
Following weight is weight percentage meter
Wherein the compositing range of overglaze is SiO2: 55%-65%, Al2O3: 25%-35%, K2O:2%-10%, Na2O:
1%-6%.
The compositing range for wherein throwing glaze is SiO2: 40%-50%, Al2O3: 5%-15%, K2O:2%-6%, Na2O:
1%-5%, CaO:5%-15%, MgO:2%-6%.
Production process: first by above-mentioned overglaze and throwing glaze and grind in ball mill, then cross screen out iron it is spare-ceramic blank
Body drenches overglaze-under the bell jar added with copper band after throwing base machine and throwing flat brick face-throwing base and prints dark fund by ceramic ink jet machine
Floral pattern-roller kilns drying-print roller protection glaze-leaching high-penetration high-brightness throws glaze-and carries out high temperature firing-in ceramic roller kiln
Noble and unsullied bright wax-polishing machine waxing glazing is polished-passed through by rough polishing machine, middle throwing machine, precision polisher.It should be added that wherein
The parameter of ink jet printer printing are as follows: 24-26 meter/min of print speed, ink jet printer channel is sequentially blue respectively, brown, yellow, black
Color, package are yellow, package is red；In addition the Elastic abrasive body of special ultrafine super-dense super clean, the combination specifically produced are used in step S9
Mode such as table 1；
| Quantity (group) | 4 | 4 | 4 | 4 |
| Middle throwing (mesh number) | 400 | 500 | 600 | 800 |
| Pressure (MPa) | 0.2 | 0.2 | 0.2 | 0.2 |
| Essence throws (mesh number) | 1000 | 1200 | 1500 | 2000 |
| Pressure (MPa) | 0.2 | 0.2 | 0.2 | 0.2 |
During throwing glaze, ceramic tile surface and rotation in Elastic abrasive body contact, thus reach ceramic tile surface polish and
By glaze brighten, and using the Elastic abrasive body of different sharpness and different Elastic abrasive body combinations, reach best
Throw glaze effect.
The product prepared from embodiment 1 learns that using overglaze and throwing glaze bilayer superposition glaze technology makes glaze with better
Stereovision and texture, the throwing glaze formula by improvement is more full true to nature by the pattern of Portoro, is more nearly former stone skin texture, bright
There has also been very big promotions compared with traditional for degree and light transmittance.To make ceramic body more smooth, base is thrown using combined type
Machine simultaneously innovates the original throwing piece material of change, and uses ink-jet printer, ink-jet printed to use 5D inkjet printing technology, (i.e.
Computer numerical controlled technology and the exquisite combination of technology of deploying to ensure effective monitoring and control of illegal activities, the Portoro texture that forging goes out is abundanter by tens than general Portoro
Times, brick complexion coloured silk is quite true to nature, and pattern is abundant, is widely used in large area and elaborates, and controls program, application by multi-C stereo
" printing high up in the air ", vividly prints texture, the printing effect in Convex and concave stereoscopic face is reachable on various convex-concave surface bricks and oblique angle face
40mm, image analytic degree are up to 600dpi, and pixel more can reach 12,000,000, are 5 times of traditional brick) image quality is apparent, and level is more
Clearly, so that more three-dimensional, Gao Qinghua；Keep pattern more full true to nature, the ultimate attainment true stone skin texture of reduction, and using a kind of complete
The throwing glaze of the new high grade of transparency and high brightness and strong color development is in combination, and Portoro is made to show a kind of magnificent texture and noble quality
Gloss；Control is more clear pattern by the green body temperature of ink jet printer while extending the high load capacity working time of ink jet printer.This
It is outer that traditional roller printing is replaced using ink-jetting process, solve the problems, such as that water wave print, white point and texture are not true lively enough, spray
It replaces silk screen to protect glaze with the roller protection glaze that 0.2%-0.3% is added after ink-printed, not only effectively improves venting phenomenon, and
And production capacity is substantially increased, the ceramic tile of kiln discharge makes ceramic tile have mirror surface by rough polishing machine, middle throwing machine, the noble and unsullied bright wax-polishing machine of precision polisher
Effect.
The present invention is described with reference to the preferred embodiments, and those skilled in the art know, of the invention not departing from
In the case where spirit and scope, various changes or equivalence replacement can be carried out to these features and embodiment.The present invention is not by this
The limitation of specific embodiment disclosed in place, other embodiments fallen into claims hereof belong to protection of the present invention
Range.
Claims (4)
1. a kind of process using inkjet printing production Portoro, it is characterised in that:
After blank forming for producing the Portoro, successively carry out applying overglaze, ink-jet printed, roller print protection in billet surface
Glaze throws glaze process, carries out high temperature firing finished product in roller kilns later；
It is wherein described to apply overglaze used in overglaze process by weight percentage, including following components: overglaze dry powder: 50%-
60%, alpha-aluminium oxide: 0.5%-0.9% is calcined, talcum: 1%-3%, zirconium silicate: 10%-15%, water: 27%-30% is burnt；Its
Described in overglaze dry powder by weight percentage, including following chemical constituent: SiO2:55%-65%, Al2O3:25%-35%,
K2O:2%-10%, Na2O:1%-6%；And ball mill wet ball grinding is added in overglaze component, and remove iron by 325 mesh screens
The overglaze is made；
The ink-jet printed mode is that ceramic ink jet machine prints dark fund floral pattern；
Roller print used in the roller print protection glaze process protects glaze by weight percentage, including following components: throw glaze:
20%-30, water: 7%-9%, stamp-pad ink: 70%-75% helps flat agent: 0.2%-0.3%；
It is described to throw throwing glaze practical in glaze process, by weight percentage, including following components: glaze dry powder: 70%-75% is thrown,
Burn talcum: 1%-3%, water: 28%-30%；Wherein the throwing glaze dry powder by weight percentage, including following chemical group
Point: SiO2: 40%-50%, Al2O3: 5%-15%, K2O:2%-6%, Na2O:1%-5%, CaO:5%-15%, MgO:2%-
6%；And glaze component will be thrown, ball mill progress wet grinding is added, and by 325 mesh screens except the throwing glaze is made in iron；
The finished product of the Portoro produce the following steps are included:
A: the green body after molding is smooth by combined type throwing base machine throwing；
B: the overglaze is imposed on the green body by step A in such a way that bell jar drenches glaze；
C: the green body that overglaze is applied by step B is printed into dark fund floral pattern using ceramic ink jet machine；
D: roller print protection glaze will be carried out by the green body in step C；
E: the throwing glaze is imposed in such a way that bell jar drenches glaze on the green body in step D by roller protection glaze；
F: carrying out high temperature firing for being re-fed into roller kilns by the green body of step E, and 1080 DEG C -1200 DEG C of firing temperature,
Simultaneously finished product is made in firing period 52min；
G: will be polished by the Portoro by kiln discharge of step F by rough polishing machine, middle throwing machine, precision polisher, wherein on
The abrading block for stating the rough polishing machine, the middle throwing machine and the precision polisher is Elastic abrasive body；
H: the Portoro after polishing is used into nanometer black wax water waxing glazing by super clean bright wax-polishing machine.
2. a kind of process using inkjet printing production Portoro according to claim 1, it is characterised in that:
The throwing piece material for throwing base machine has wool felt, dishcloth, and different materials is taken according to the surface smoothness of ceramic body
Matter combination.
3. a kind of process using inkjet printing production Portoro according to claim 1, it is characterised in that:
The bell jar is made of stainless steel bell jar, copper band, funnel, and wherein copper band divides fine copper material and screen mesh type, according to glaze
The use of flatness decision copper band.
4. a kind of process using inkjet printing production Portoro according to claim 1, it is characterised in that:
The ingredient of the Elastic abrasive body contains diamond dust, different according to the Mohs' hardness of glaze, using the bullet of different sharpness
Property abrading block and different Elastic abrasive body combinations.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110978221A (en) * | 2019-11-20 | 2020-04-10 | 江西和美陶瓷有限公司 | Preparation process for solving polishing yellow edge problem of gray glazed brick |
| CN111002446A (en) * | 2019-12-02 | 2020-04-14 | 广东清远蒙娜丽莎建陶有限公司 | Ceramic polished anti-skid wax, smooth-surface anti-skid and anti-fouling full-glazed ceramic tile and preparation method thereof |
| CN111689768B (en) * | 2020-06-28 | 2021-03-19 | 广西蒙娜丽莎新材料有限公司 | Co-firing method of whole-body ink-jet black golden flower fully-polished brick and common archaized brick |
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| CN110978221A (en) * | 2019-11-20 | 2020-04-10 | 江西和美陶瓷有限公司 | Preparation process for solving polishing yellow edge problem of gray glazed brick |
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| CN111002446A (en) * | 2019-12-02 | 2020-04-14 | 广东清远蒙娜丽莎建陶有限公司 | Ceramic polished anti-skid wax, smooth-surface anti-skid and anti-fouling full-glazed ceramic tile and preparation method thereof |
| CN111002446B (en) * | 2019-12-02 | 2021-08-24 | 广东清远蒙娜丽莎建陶有限公司 | Ceramic polished anti-skid wax, smooth-surface anti-skid and anti-fouling full-glazed ceramic tile and preparation method thereof |
| CN111689768B (en) * | 2020-06-28 | 2021-03-19 | 广西蒙娜丽莎新材料有限公司 | Co-firing method of whole-body ink-jet black golden flower fully-polished brick and common archaized brick |
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