CN109206776A - 一种抗静电聚氯乙烯发泡板 - Google Patents

一种抗静电聚氯乙烯发泡板 Download PDF

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CN109206776A
CN109206776A CN201710536149.5A CN201710536149A CN109206776A CN 109206776 A CN109206776 A CN 109206776A CN 201710536149 A CN201710536149 A CN 201710536149A CN 109206776 A CN109206776 A CN 109206776A
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parts
polyvinyl chloride
antistatic
foamed board
chloride foamed
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姜志梁
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Zhenjiang Rui Ze Culture Communication Co Ltd
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Zhenjiang Rui Ze Culture Communication Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0028—Use of organic additives containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2489/00—Characterised by the use of proteins; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

本发明涉及一种抗静电聚氯乙烯发泡板，由以下重量份数的组分组成：聚氯乙烯树脂，150份；明胶，10‑15份；防老剂ODA，5份；高耐磨炭黑，15份；玻璃纤维，10‑15份；光稳定剂，8‑10份；润滑剂，5‑10份；泡沫稳定剂，1‑3份；增白剂，3‑5份；抗静电剂，5‑10份。本发明塑料加入了乙氧基化脂肪族烷基胺作为抗静电剂，提高了塑料的抗静电性能。

Description

一种抗静电聚氯乙烯发泡板
技术领域
本发明涉及一种塑料，具体涉及一种抗静电聚氯乙烯发泡板。
背景技术
聚氯乙烯发泡板是用聚甲醛塑料粒子通过挤出机高温挤出，经过相应的模具口挤出得到不同厚度的板材，是一种高熔点、高结晶性的热塑性工程塑料，因聚甲醛板所具有的良好特性，非常适合在自动车床上机加工，特别适合用来制造精密零件。
然而由于聚氯乙烯本身存在耐热、耐老化、耐大气老化性较差，使得用其制得的聚氯乙烯发泡板的使用寿命非常短，从而降低了其使用范围。
有鉴于上述的缺陷，本设计人，积极加以研究创新，以期创设一种新型结构的聚氯乙烯发泡板，使其更具有产业上的利用价值。
发明内容
为解决上述技术问题，本发明的目的是提供一种抗静电聚氯乙烯发泡板。
本发明的技术方案如下：
一种抗静电聚氯乙烯发泡板，其特征在于，由以下重量份数的组分组成：
进一步的，所述玻璃纤维为2-5mm的玻璃纤维。
进一步的，所述光稳定剂为钛白粉。
进一步的，所述润滑剂为氧化聚乙烯。
进一步的，所述泡沫稳定剂为脂肪酸乙醇酰胺。
进一步的，所述增白剂为增白剂TA。
进一步的，所述抗静电剂为乙氧基化脂肪族烷基胺。
借由上述方案，本发明至少具有以下优点：
本发明塑料加入了乙氧基化脂肪族烷基胺作为抗静电剂，提高了聚乙烯发泡板的抗静电性能。
上述说明仅是本发明技术方案的概述，为了能够更清楚了解本发明的技术手段，并可依照说明书的内容予以实施，以下以本发明的较佳实施例。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步详细描述。以下实施例用于说明本发明，但不用来限制本发明的范围。
一种抗静电聚氯乙烯发泡板的制备方法，包括以下原料聚聚氯乙烯树脂，明胶，防老剂ODA，高耐磨炭黑，玻璃纤维，光稳定剂，润滑剂，泡沫稳定剂，增白剂，抗静电剂。将上述原料混合后，加入到挤塑机中，在120℃下混合均匀，再采用螺杆机挤出，得到聚氯乙烯发泡板。
制备的具体组分如下。
实施例1
实施例2
实施例3
本发明塑料加入了乙氧基化脂肪族烷基胺作为抗静电剂，提高了塑料的抗静电性能。
以上所述仅是本发明的优选实施方式，并不用于限制本发明，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变型，这些改进和变型也应视为本发明的保护范围。

Claims (7)

1.一种抗静电聚氯乙烯发泡板，其特征在于，由以下重量份数的组分组成：
2.根据权利要求1所述的一种抗静电聚氯乙烯发泡板，其特征在于：所述玻璃纤维为2-5mm的玻璃纤维。
3.根据权利要求1所述的一种抗静电聚氯乙烯发泡板，其特征在于：所述光稳定剂为钛白粉。
4.根据权利要求1所述的一种抗静电聚氯乙烯发泡板，其特征在于：所述润滑剂为氧化聚乙烯。
5.根据权利要求1所述的一种抗静电聚氯乙烯发泡板，其特征在于：所述泡沫稳定剂为脂肪酸乙醇酰胺。
6.根据权利要求1所述的一种抗静电聚氯乙烯发泡板，其特征在于：所述增白剂为增白剂TA。
7.根据权利要求1所述的一种抗静电聚氯乙烯发泡板，其特征在于：所述抗静电剂为乙氧基化脂肪族烷基胺。
CN201710536149.5A 2017-07-04 2017-07-04 一种抗静电聚氯乙烯发泡板 Pending CN109206776A (zh)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109529A (zh) * 1984-12-31 1986-09-10 宏荣化成株式会社 合成树脂改性剂及其用途组成物
JPH09124826A (ja) * 1995-11-02 1997-05-13 Sekisui Chem Co Ltd 硬質塩化ビニル系樹脂発泡体
CN102477192A (zh) * 2010-11-29 2012-05-30 山东博拓塑业股份有限公司 抗静电聚氯乙烯发泡板材
CN103554714A (zh) * 2013-10-11 2014-02-05 吴江市天源塑胶有限公司 一种抗静电塑料
CN104341693A (zh) * 2014-10-22 2015-02-11 青岛东泰诚恩新材料科技发展有限公司 一种抗静电pvc塑料地板配方
CN104448631A (zh) * 2014-12-15 2015-03-25 山东博拓塑业股份有限公司 高耐候聚氯乙烯发泡广告板及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109529A (zh) * 1984-12-31 1986-09-10 宏荣化成株式会社 合成树脂改性剂及其用途组成物
JPH09124826A (ja) * 1995-11-02 1997-05-13 Sekisui Chem Co Ltd 硬質塩化ビニル系樹脂発泡体
CN102477192A (zh) * 2010-11-29 2012-05-30 山东博拓塑业股份有限公司 抗静电聚氯乙烯发泡板材
CN103554714A (zh) * 2013-10-11 2014-02-05 吴江市天源塑胶有限公司 一种抗静电塑料
CN104341693A (zh) * 2014-10-22 2015-02-11 青岛东泰诚恩新材料科技发展有限公司 一种抗静电pvc塑料地板配方
CN104448631A (zh) * 2014-12-15 2015-03-25 山东博拓塑业股份有限公司 高耐候聚氯乙烯发泡广告板及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
冯亚青 王利军等合编: "《高等学校教学用书 助剂化学及工艺学》", 30 June 1997, 化学工业出版社 *

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Application publication date: 20190115