CN109112020A - A kind of instant soap flakes and preparation method thereof - Google Patents
A kind of instant soap flakes and preparation method thereof Download PDFInfo
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- CN109112020A CN109112020A CN201811210413.7A CN201811210413A CN109112020A CN 109112020 A CN109112020 A CN 109112020A CN 201811210413 A CN201811210413 A CN 201811210413A CN 109112020 A CN109112020 A CN 109112020A
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- soap flakes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to daily use chemicals cleaning product technical field, the preparation methods of specially a kind of instant soap flakes and this kind of instant soap flakes.By the present invention in that with the fatty acid salt of specific components, and instant disintegrating agent is added, and the molding expanded level of soap flakes is controlled by film forming agent, it is dissolved rapidly under instant disintegrating agent and the quick dissolution effect of auxiliary material, it promotes soap flakes and meets the molten ability of water speed, it is easy to use to make soap flakes be suitable for machine washing, expand the scope of application of soap flakes.By taking suitable raw material and proportion, it dissolve prepared soap flakes can not only rapidly, also there is good detergency ability, the performance of especially removal protein stain is significant.Soap flakes of different shapes can be prepared by the method for the invention, rule or irregular sheet products are such as made, and can also need to be made different size of soap flakes according to product design, it is convenient quantitatively to use while easy to carry.
Description
Technical field
The present invention relates to daily use chemicals cleaning product technical field more particularly to a kind of instant soap flakes and this kind of instant soap flakes
Preparation method.
Background technique
With the improvement of people's living standards, consumer is to detergent product, more stringent requirements are proposed, it is desirable to detergent
Can efficiently, it is mild, do not stimulate, and simply, conveniently, easily use.Sodium soap (soap) is living as a kind of green and healthy type surface
Property agent increasingly favored in cleaning product, use natural reproducible raw material, such as coconut oil, palm oil glyceride stock warp
Hydrolysis obtains after neutralizing, and is a kind of surfactant of good performance, has excellent dirt-removing power, low irritant and good
Biological degradability, can individually or with other surfactant compounds use, washing industry have a wide range of applications.
Soap product on sale is mostly bulk product currently on the market, is only suitable for hand washing and smears use, is not suitable for machine-washing, make
It uses cumbersome.Other products containing soap such as soap powder, soap lye, wherein soap content is generally very low, mainly compounds other petroleum
Based surfactants.
Summary of the invention
The present invention is not suitable for machine-washing for existing soap product, needs further to expand asking for soap application range of products
Topic, providing one kind can dissolve rapidly, be suitable for machine washing, the preparation side of instant soap flakes easy to use and this kind of instant soap flakes
Method.
To achieve the above object, the present invention uses following technical scheme.
A kind of instant soap flakes are made of the raw material components for including following mass percent:
Fatty acid salt 5.0~70.0%；
Other surfactants 3.0~30.0%；
Film forming agent 1.0~20.0%；
Instant disintegrating agent 5.0~15.0%；
Auxiliary material 4.0~30.0%.
Preferably, the film forming agent is selected from least one of polyvinyl alcohol and the copolymer containing vinyl alcohol monomer, institute
The average molecular weight for stating film forming agent is 10000~100000, and alcoholysis degree is 80%~95%.Film forming agent is the base of detergent tablet
Matter can stick together each component such as surfactant, instant disintegrating agent, the auxiliary material of detergent tablet, make obtained
Detergent tablet has certain tensile strength.The selection of film forming agent need to comprehensively consider film forming, dissolubility and storage stability.
It is furthermore preferred that the average molecular weight of the film forming agent is 50000~80000.
Preferably, the fatty acid salt is made of the Salt of saturated fatty acid and unsaturated fat salt of C6~C20, and fatty acid
The content of the fatty acid salt of C6~C10 is less than 1% in salt, and the content of unsaturated fatty acid salt is greater than 40% in fatty acid salt.Rouge
The solvent borne influence of the pairs of soap flakes of the group of fat hydrochlorate is very big, and Salt of saturated fatty acid and unsaturated fatty acid salt in fatty acid salt
Proportion and the content of fatty acid salt of C6~C10 the soil release performance of soap flakes, mouldability and dissolubility are had a significant impact, fit
It is suitable with when content could balanced soap flakes soil release performance, mouldability and dissolubility, make soap flakes be provided simultaneously with good soil release performance,
Mouldability and dissolubility.
Preferably, other surfactants in anionic surfactant and nonionic surfactant extremely
Few one kind.
Preferably, the anionic surfactant is selected from sulfonate surfactant, sulfated surfactant
At least one of with phosphate salt form surfactant.
Preferably, the nonionic surfactant is selected from C12~C14 alkyl glycosides, C12~C18 fatty alcohol polyoxy second
Alkene ether, the condensation product of C12~C18 alcohol and ethylene oxide/propylene oxide block copolymer, cocoanut fatty acid diethanolamide,
At least one of coconut oil fatty acid monoethanolamide.
Preferably, the instant disintegrating agent be selected from croscarmellose sodium, sodium carboxymethyl starch, hydroxypropul starch,
At least one of crospovidone, low-substituted hydroxypropyl cellulose.
Preferably, the auxiliary material be selected from zeolite, silica, glycerol, chelating agent, enzyme preparation, polymer, antioxidant,
At least one of essence
The preparation method of instant soap flakes described above, comprising the following steps:
(1) water and 60~90 DEG C are heated to being pre-dissolved to be added in pot, film forming agent then is added to being pre-dissolved in pot, stirring is to complete
Portion's dissolution obtains film forming agent solution, keeps the temperature spare；
(2) water is added into ingredients pot, fatty acid salt is then added, is heated to 60~90 DEG C, then adds into ingredients pot
Enter the agent solution that forms a film, stirs to being uniformly dissolved, obtain feed liquid one；
(3) continue to be separately added into other surfactants, non-heat-sensitive in instant disintegrating agent and auxiliary material into ingredients pot
Auxiliary material component stirs to being uniformly dissolved, obtains feed liquid two；
(4) 50 DEG C are cooled to hereinafter, the auxiliary material component of thermal sensitivity in auxiliary material is added to feed liquid two, stirring to being uniformly dissolved,
Obtain slurry；
(5) pulling-on piece is dried to slurry, soap flakes is made after cutting.
Compared with prior art, the beneficial effects of the present invention are: by the present invention in that with the fatty acid salt of specific components, and
Instant disintegrating agent is added, and controls the molding expanded level of soap flakes by film forming agent, quickly promotees in instant disintegrating agent and auxiliary material
It is dissolved rapidly under molten effect, promotes soap flakes and meet the molten ability of water speed, so that soap flakes is made to be suitable for machine washing, it is easy to use, it expands
The scope of application of soap flakes.By taking each raw material suitable in right amount, it dissolve prepared soap flakes can not only rapidly, also have good
The performance of good detergency ability, especially removal protein stain is significant.
Soap flakes of different shapes can be prepared by the method for the invention, and rule or irregular sheet products are such as made, may be used also
Need to be made different size of soap flakes according to product design, it is convenient quantitatively to use while easy to carry.
Specific embodiment
To facilitate the understanding of the present invention, below to invention is more fully described.But the present invention can be with many
Different form is realized, however it is not limited to embodiment described herein.On the contrary, purpose of providing these embodiments is in order to
It is more thorough and comprehensive to the understanding of the disclosure.For those skilled in the art, by reading this explanation
Book disclosure, feature of the invention, beneficial effect and advantage will become obvious.
Embodiment 1-6
Embodiment 1-6 provides the preparation method of a kind of instant soap flakes and instant soap flakes respectively, is used to prepare each of soap flakes
The mass percentage content of raw material components is as shown in table 1.
Instant soap flakes the preparation method is as follows:
(1) water and 60~90 DEG C are heated to being pre-dissolved to be added in pot, PVA then are added to being pre-dissolved in pot, stirring to whole
Dissolution obtains film forming agent solution, keeps the temperature spare；
(2) water is added into ingredients pot, sodium soap is then added, is heated to 60~90 DEG C, then adds into ingredients pot
Enter the agent solution that forms a film, stirs to being uniformly dissolved, obtain feed liquid one；
(3) continue to be separately added into other surfactants, non-heat-sensitive in instant disintegrating agent and auxiliary material into ingredients pot
Auxiliary material component (auxiliary material other than enzyme preparation and essence) stirs to being uniformly dissolved, obtains feed liquid two；
(4) to feed liquid two be cooled to 50 DEG C hereinafter, be added auxiliary material in thermal sensitivity auxiliary material component (enzyme preparation and essence), stir
It mixes to being uniformly dissolved, obtains slurry；
(5) pulling-on piece is dried by roller dryer in slurry, up to soap flakes after cutting.
The mass percentage content of the raw material components of instant soap flakes is prepared in 1 embodiment 1-6 of table
In table 1, the sodium soap in embodiment 1-5 is made of the saturated fatty acid sodium and unsaturated fat sodium of C6~C20,
Unsaturated fatty acid sodium content is 76.3%, remaining is saturated fatty acid sodium, wherein C6~C10 sodium soap content is
0.5%；Sodium soap in embodiment 6 is made of the saturated fatty acid sodium and unsaturated fat sodium of C6~C20, unsaturated fat
Sour sodium content is 42.1%, remaining is saturated fatty acid sodium, wherein C6~C10 sodium soap content is 0.9%；Film forming agent is excellent
Selecting average molecular weight is the PVAC polyvinylalcohol of 50000-80000, and embodiment 1-6 uses PVA1788.
Comparative example 1
A kind of mass percentage content of each raw material component for soap flakes that comparative example 1 provides is as shown in table 2.
2 comparative example 1 of table prepares the mass percentage content of the raw material components of soap flakes
| Material name | Additive amount (wt%) |
| Sodium soap | 50 |
| Sodium sulfate of polyethenoxy ether of fatty alcohol | 13 |
| Fatty acid methyl ester sulfonate | ---- |
| Fatty alcohol polyoxyethylene ether | 8 |
| Cocoanut fatty acid diethanolamide | ---- |
| PVA1788 | 10 |
| Croscarmellose sodium | ---- |
| Starch | 15 |
| Zeolite | ---- |
| Silica | ---- |
| Glycerol | ---- |
| EDTA-4Na | 2 |
| Sodium citrate | ---- |
| Protease | 0.5 |
| Lipase | 0.5 |
| Cellulase | 0.3 |
| Essence | 0.7 |
The composition of sodium soap is identical as embodiment 1 in table 2, preparation method and the embodiment 1 of the soap flakes of comparative example 1
Preparation method is identical.
Comparative example 2
A kind of mass percentage content of each raw material component for soap flakes that comparative example 2 provides is as shown in table 3.
3 comparative example 2 of table prepares the mass percentage content of the raw material components of soap flakes
In table 3, sodium soap is made of the Salt of saturated fatty acid and unsaturated fat salt of C6~C20, unsaturated fatty acid
Sodium content 18%, remaining is saturated fatty acid sodium, wherein C6~C10 sodium soap content is 0.9%.The soap flakes of comparative example 2
Preparation method is identical as the preparation method of embodiment 1.
The dispersion performance and detergency ability of the soap flakes of above-described embodiment and comparative example preparation are tested respectively.
1, dispersion performance test and test result
The method of inspection: by soap flakes obtained by each embodiment and comparative example (size: long * wide=40mm*40mm, thickness 0.7~
It 0.8mm) puts into respectively in 25 DEG C of 1L water, is completely dispersed required time, test result with stopwatch measurement syndetic bar
As shown in table 4 below.
The dispersion performance test result of the soap flakes of table 4 embodiment 1-6 and comparative example 1-2
By table 4 as it can be seen that the soap flakes of comparative example 1 be not added with instant disintegrating agent, comparative example 2 soap flakes in using common soap rouge
Fat acid sodium, the jitter time of products obtained therefrom, which is considerably longer than, is added to instant disintegrating agent and the embodiment 1- using special fatty acid sodium
6 soap flakes.Therefore, sodium soap of the present invention and instant disintegrating agent are used in soap flakes, will substantially reduce soap flakes dispersion
Time, solution rate faster, can effectively prevent in washing process soap flakes insoluble or part are insoluble that soap flakes is caused to be adhered to clothing
On situation occur.
2, detergency ability test and test result
The method of inspection: referring to GB/T13174-2008 " dress material detergent detergency and the measurement for recycling scourability " mark
Standard is tested using tri- kinds of national standard carbon black JB-01, national standard albumen JB-02, national standard sebum JB-03 soiled cottons, and test result is as follows
(result is the decontamination value relative to standard washing powder) shown in table 5.
5 embodiment detergency ability test result of table
| Sample | JB-01 soiled cotton | JB-02 soiled cotton | JB-03 soiled cotton |
| Common commercial laundry powder | 1.12 | 4.53 | 1.11 |
| Common commercial laundry soap | 1.11 | 1.44 | 1.85 |
| Embodiment 1 | 1.2 | 6.3 | 1.5 |
| Embodiment 2 | 1.25 | 6.5 | 1.7 |
| Embodiment 3 | 1.25 | 6.7 | 1.88 |
| Embodiment 4 | 1.3 | 6.7 | 1.78 |
| Embodiment 5 | 1.25 | 6.6 | 1.7 |
| Embodiment 6 | 1.22 | 6.6 | 1.75 |
In detergency ability test, the common commercial laundry powder of test refers to that gross activity object content is 15~19% commercially available to wash
Clothing powder；The common commercial laundry soap of test refers to the following commercial laundry soap of the composition of contained sodium soap in soap: by C6~C20
Salt of saturated fatty acid and unsaturated fat salt composition, unsaturated fatty acid sodium content 19.1%, remaining is saturated fatty acid,
In, C6~C10 sodium soap content 0.8%.
By table 5 as it can be seen that the decontamination comprehensive performance of the soap flakes of embodiment 1-6 be better than common commercial laundry powder, sebum decontamination with
Common commercial laundry soap is close, and albumen decontamination is better than common commercial laundry soap, and whole decontamination is functional.
It is described above that technology contents of the invention are only further illustrated with embodiment, in order to which reader is easier to understand,
But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this
Bright protection.
Claims (10)
1. a kind of instant soap flakes, which is characterized in that be made of the raw material components for including following mass percent:
Fatty acid salt 5.0~70.0%；
Other surfactants 3.0~30.0%；
Film forming agent 1.0~20.0%；
Instant disintegrating agent 5.0~15.0%；
Auxiliary material 4.0~30.0%.
2. instant soap flakes according to claim 1, which is characterized in that the film forming agent is selected from polyvinyl alcohol and contains ethylene
At least one of copolymer of alcohol monomer, the average molecular weight of the film forming agent are 10000~100000, alcoholysis degree 80%
~95%.
3. instant soap flakes according to claim 2, which is characterized in that the average molecular weight of the film forming agent be 50000~
80000。
4. instant soap flakes according to claim 1, which is characterized in that the fatty acid salt by C6~C20 saturated fat
Hydrochlorate and unsaturated fat salt composition, and in fatty acid salt the fatty acid salt of C6~C10 content less than 1%, in fatty acid salt
The content of unsaturated fatty acid salt is greater than 40%.
5. instant soap flakes according to claim 1, which is characterized in that other surfactants are selected from anionic surface
At least one of activating agent and nonionic surfactant.
6. instant soap flakes according to claim 5, which is characterized in that the anionic surfactant is selected from sulfonate type
At least one of surfactant, sulfated surfactant and phosphate salt form surfactant.
7. instant soap flakes according to claim 5, which is characterized in that the nonionic surfactant is selected from C12~C14
Alkyl glycosides, the fatty alcohol polyoxyethylene ether of C12~C18, C12~C18 alcohol and ethylene oxide/propylene oxide block copolymer
At least one of condensation product, cocoanut fatty acid diethanolamide, coconut oil fatty acid monoethanolamide.
8. instant soap flakes according to claim 1, which is characterized in that the instant disintegrating agent is selected from cross-linked carboxymethyl fiber
At least one of plain sodium, sodium carboxymethyl starch, hydroxypropul starch, crospovidone, low-substituted hydroxypropyl cellulose.
9. instant soap flakes according to claim 1, which is characterized in that the auxiliary material be selected from zeolite, silica, glycerol,
At least one of chelating agent, enzyme preparation, polymer, antioxidant, essence.
10. a kind of preparation method of instant soap flakes as described in claim 1, which comprises the following steps:
(1) water and 60~90 DEG C are heated to being pre-dissolved to be added in pot, film forming agent then is added to being pre-dissolved in pot, stirring is to all molten
Solution obtains film forming agent solution, keeps the temperature spare；
(2) water is added into ingredients pot, fatty acid salt is then added, is heated to 60~90 DEG C, then into ingredients pot be added at
Film solution stirs to being uniformly dissolved, obtains feed liquid one；
(3) continue to be separately added into ingredients pot other surfactants, in instant disintegrating agent and auxiliary material non-heat-sensitive auxiliary material
Component stirs to being uniformly dissolved, obtains feed liquid two；
(4) 50 DEG C are cooled to hereinafter, the auxiliary material component of thermal sensitivity in auxiliary material is added to feed liquid two, stirring is obtained to being uniformly dissolved
Slurry；
(5) pulling-on piece is dried to slurry, soap flakes is made after cutting.
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| CN108130248A (en) * | 2018-02-02 | 2018-06-08 | 中山市美而廉清洁用品有限公司 | A kind of preparation method of cold water soap powder |
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