CN102304437B - High-efficiency liquid-phase washing agent with bleaching effect for colored fabric - Google Patents
High-efficiency liquid-phase washing agent with bleaching effect for colored fabric Download PDFInfo
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- CN102304437B CN102304437B CN 201110220314 CN201110220314A CN102304437B CN 102304437 B CN102304437 B CN 102304437B CN 201110220314 CN201110220314 CN 201110220314 CN 201110220314 A CN201110220314 A CN 201110220314A CN 102304437 B CN102304437 B CN 102304437B
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Abstract
The invention discloses a liquid-phase washing agent with bleaching effect for colored fabric, which contains fatty alcohol, polyethenoxy ether, glycerol, ethanol, calcium citrate, sodium citrate, polystyrene, alpha-sodium alkenylsulfonate, polyvinylpyrrolidone, alkali protease, sodium chloride, essence and deionized water. Compared with the prior art, the invention does not contain any oxygen bleacher, and has the characteristics of strong detergent power, favorable biodegradability and high safety for human bodies and clothes.
Description
Technical field:
The present invention relates to a kind of liquid phase washing composition, belong to especially a kind of and have coloured silk to float the oxygen-free of effect be the liquid phase washing composition of SYNTHETIC OPTICAL WHITNER.
Background technology
The spot that runs in the daily life is of a great variety, and frequently has stain to be difficult to remove.Steep etc. such as hair dye, the yellow mark on the collar, bloodstain, the milk that speckles with on the clothing.Generally the human consumer can select color bleaching liquor to remove above-mentioned spot.Because color bleaching liquor can not damage the color (if use chlorine bleaching agent, such as 84 thimerosals, spot can be floated together with the color of clothing itself) of clothing itself.
It is SYNTHETIC OPTICAL WHITNER that color bleaching liquor in the market contains aerobic mostly, and it is a kind of weak property oxygenant, such as hydrogen peroxide, SPC-D, Sodium peroxoborate etc.Such as Chinese patent (application number: 200810222881.6).This type of SYNTHETIC OPTICAL WHITNER can effectively be removed the stain in the daily life.But oxygenant can produce certain destruction to fabric fibre, and skin is also had certain hormesis.
Summary of the invention
Technology total amount to be solved by this invention provides a class to be had coloured silk to float effect oxygen-free is the liquid phase washing composition of SYNTHETIC OPTICAL WHITNER, and it can effectively remove the hair dye of being infected with on the stain that runs in the daily life such as the clothing.
The technical scheme of technical solution problem of the present invention is: a kind of have a liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
A kind of have a liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
A kind of have a liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
Described α-sodium olefin sulfonate is replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium.
Preparation method of the present invention is: at first measure deionized water and the ethanol of specifying deal in the prescription, be placed on after mixing on the magnetic stirring apparatus stir for subsequent use, then measure various washing auxiliary detergents and enzyme stabilizers as: Trisodium Citrate, citrate of lime, sodium-chlor, glycerine etc. add wherein, again add tensio-active agent and under agitation mix, measure at last quantitative required enzyme and be dissolved in to stir in the mixing solutions and get final product.
Detersive enzyme plays a key effect in formula for a product among the present invention.Amylase can make starch become the processable material of molecular weight, thereby reaches the purpose of washing; Cellulase acts on the primitive fiber on the dimensional fabric, reaches the purpose of arrangement, refreshing fabrics, avoid occurring scared, twine the phenomenons such as ball.Prepare enzyme-added liquid washing agent, most critical be to keep the stability of enzyme in water, need to add enzyme stabilizers.Fatty alcohol-polyoxyethylene ether in the prescription is a kind of nonionogenic tenside, as emulsifying agent, and the anti-hard water of the low bubble of low temperature; Glycerine uses as enzyme stabilizers; Citrate of lime is a kind of coenzyme, is used for the maximum activity of activating enzyme; Trisodium Citrate is as sequestrant complexing hardness ions; Ethanol is the phase conditioning agent; Polystyrene is opalizer; Sodium-chlor is thickening material; α-sodium olefin sulfonate is a kind of anion surfactant, and pungency is low, biological degradability good, strong detergency, anti-hard water; LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium is the same α-sodium olefin sulfonate of a kind of anion surfactant effect, and the relative low price effect is slightly poor.
The present invention compared with prior art, oxygen-free is SYNTHETIC OPTICAL WHITNER, have strong detergency, biological degradability good, to human body, the safe characteristics of clothing.
Embodiment:
The present invention is described in detail below in conjunction with embodiment.
The pharmaceutical chemicals that the present invention is used:
Fatty alcohol-polyoxyethylene ether (Shanghai Asia chemical company limited)
LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium (Shanghai Asia chemical company limited)
α-sodium olefin sulfonate (Shanghai Asia chemical company limited)
Glycerine (Chemical Reagent Co., Ltd., Sinopharm Group)
Ethanol (Chemical Reagent Co., Ltd., Sinopharm Group)
Citrate of lime (the consummate reagent in Shanghai company limited)
Trisodium Citrate (Shanghai reagent one factory)
Polystyrene (the consummate reagent in Shanghai company limited)
Polyvinylpyrrolidone (behind the Shanghai chemical plant, Tianshan Mountains)
Cellulase (Pangbo Bioengineering Co Ltd, Nanning)
Sumizyme MP (Pangbo Bioengineering Co Ltd, Nanning)
Lipase (Pangbo Bioengineering Co Ltd, Nanning)
Amylase (Pangbo Bioengineering Co Ltd, Nanning)
Cream rinse (gentle and refined Ran Fa treatment wax)
Spices (lemon, Dongguan City method fragrance Lai Er essence and flavoring agent company limited)
Sudan red (lark prestige Science and Technology Ltd.)
Whiteness instrument (general Shen, Shanghai chemical machinery company limited)
Fabric size: 6.5cm * 6.5cm, washing time 15 min
Embodiment 1:
A kind of have a liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
Embodiment 2:
Embodiment 3:
Embodiment 4:
Embodiment 5:
Embodiment 6:
Embodiment 7:
Embodiment 8:
Embodiment 9:
Embodiment 10:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 1.
Embodiment 11:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 2.
Embodiment 12:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 3.
Embodiment 13:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 4.
Embodiment 14:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 5.
Embodiment 15:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 6.
Embodiment 16:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 7.
Embodiment 17:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 8.
Embodiment 18:
Except α-sodium olefin sulfonate was replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium, all the other were identical with embodiment 9.
Embodiment 19:
1, the preparation of edible oil spot: after the preparation according to standard GB/T/T 13174_2008 JB-04 (edible oil soiled cotton), be put in refrigerator and cooled and hide for subsequent use.
2, the preparation of hair dye soiled cotton: Ran Fa treatment wax and the allotment of Xian Se treatment wax of hair dye is even, evenly spread upon on the cloth for preparing with toothbrush, at room temperature left standstill 10 minutes, then with soiled cotton in vacuum drying oven behind 75 ℃ ± 2 ℃ aging 20 min, place ambient temperature overnight.Being put in refrigerator and cooled next day hides for subsequent use.The material of cloth is terylene, all woolen, cotton.
3, greasiness removal
The color bleaching liquor bought on embodiment 1-18 and the market (the color bleaching liquor of the clean scholar's aerobic of prestige, Walch (Guangzhou) Daily Necessities Co., Ltd.) is embathed 15 min and goes stain to process placing soiled cotton more than one month respectively together under magnetic stirrer.Then mensuration is polluted front whiteness and is washed rear whiteness and compares, and draws washing effect.
4, effect assessment:
Evaluation method according to the scourability of mentioning in the chapter 8 " result's judgement " among standard GB/T/T 13174-2008 " dress material with the mensuration of washing composition detersive power and circulation cleaning performance " is estimated washing effect.
Method: calculate the whiteness retention value, its method of calculation are T=F
2/ F
1In * 100% formula: F
1For front whiteness value is washed in test piece; F
2For washing rear whiteness value.The larger explanation washing effect of T value is better.
Table 1:
The removal effect of hair dye spot (whiteness retention value method)
Table 2: the removal effect of Sudan red edible oil spot (whiteness retention value method)
| All woolen | |
| Wash front whiteness | 48.45 |
| Be infected with whiteness after the spot | 23.00 |
| Whiteness/its whiteness retention value after commercially available color bleaching liquor is removed | 47.5/98.03% |
| Whiteness/its whiteness retention value after embodiment 1 removes | 51.22/105.72% |
| Whiteness/its whiteness retention value after embodiment 2 removes | 50.94/105.14% |
| Whiteness/its whiteness retention value after embodiment 3 removes | 50.41/104.05% |
| Whiteness/its whiteness retention value after embodiment 4 removes | 49.56/102.29% |
| Whiteness/its whiteness retention value after embodiment 5 removes | 50.10/103.4% |
| Whiteness/its whiteness retention value after embodiment 6 removes | 50.98/105.22% |
| Whiteness/its whiteness retention value after embodiment 7 removes | 45.35/93.6% |
| Whiteness/its whiteness retention value after embodiment 8 removes | 45.60/94.12% |
| Whiteness/its whiteness retention value after embodiment 9 removes | 45.16/93.21% |
| Whiteness/its whiteness retention value after embodiment 10 removes | 50.1/103.4% |
| Whiteness/its whiteness retention value after embodiment 11 removes | 50.2/103.61% |
| Whiteness/its whiteness retention value after embodiment 12 removes | 50.0/103.2% |
| Whiteness/its whiteness retention value after embodiment 13 removes | 49.6/102.37% |
| Whiteness/its whiteness retention value after embodiment 14 removes | 49.97/103.14% |
| Whiteness/its whiteness retention value after embodiment 15 removes | 50.0/103.2% |
| Whiteness/its whiteness retention value after embodiment 16 removes | 48.3/99.69% |
| Whiteness/its whiteness retention value after embodiment 17 removes | 48.10/99.28% |
| Whiteness/its whiteness retention value after embodiment 18 removes | 47.22/99.53% |
The conclusion that 5, can draw from above-mentioned data is:
(1) prescription of the present invention is basically identical with commercially available color bleaching liquor effect in the application of removing the stain hair dye.
(2) prescription of the present invention is more effective than commercially available color bleaching liquor on the general spot of removal such as edible oil soiled cotton.
Claims (4)
1. one kind has the liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
2. one kind has the liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
3. one kind has the liquid phase washing composition that coloured silk floats effect, contains the material of following weight percent:
4. according to claim 1,2 or 3 described a kind of liquid phase washing composition that coloured silk floats effect that have, it is characterized in that: described α-sodium olefin sulfonate is replaced with LINER ALKYL BENZENE SULPHONIC ACID SOFT 96 sodium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201110220314 CN102304437B (en) | 2011-08-03 | 2011-08-03 | High-efficiency liquid-phase washing agent with bleaching effect for colored fabric |
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| CN 201110220314 CN102304437B (en) | 2011-08-03 | 2011-08-03 | High-efficiency liquid-phase washing agent with bleaching effect for colored fabric |
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| CN102304437B true CN102304437B (en) | 2013-01-02 |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102942998B (en) * | 2012-10-30 | 2013-12-18 | 湖南日用化学科学研究所有限公司 | Washing auxiliary agent for removing protein stains |
| CN103897839A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | An environmental-friendly detergent |
| CN103897854A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of glass detergent |
| CN103897856A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of liquid detergent |
| CN103113996A (en) * | 2013-01-24 | 2013-05-22 | 江苏创新日化科技有限公司 | Phosphate-free washing powder and production method thereof |
| CN103805368A (en) * | 2014-02-28 | 2014-05-21 | 刘菊 | Color-protective laundry detergent |
| CN104478365B (en) * | 2014-12-25 | 2017-09-22 | 苏州中材非金属矿工业设计研究院有限公司 | A kind of method for improving the hard water resistance performance of aluminium magnesium silicate inorganic gel |
| CN104862150A (en) * | 2015-05-05 | 2015-08-26 | 柳州立洁科技有限公司 | Anti-allergic cloth cleaning fluid |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602985A (en) * | 2008-06-10 | 2009-12-16 | 财团法人工业技术研究院 | Remove the compoistion and method of use of spot |
| CN101649258A (en) * | 2009-08-31 | 2010-02-17 | 广州立白企业集团有限公司 | Tableware detergent with enzyme and preparation method thereof |
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2011
- 2011-08-03 CN CN 201110220314 patent/CN102304437B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602985A (en) * | 2008-06-10 | 2009-12-16 | 财团法人工业技术研究院 | Remove the compoistion and method of use of spot |
| CN101649258A (en) * | 2009-08-31 | 2010-02-17 | 广州立白企业集团有限公司 | Tableware detergent with enzyme and preparation method thereof |
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| CN102304437A (en) | 2012-01-04 |
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