CN108948918A - A kind of high temperature resistant radiation shielding coating - Google Patents

A kind of high temperature resistant radiation shielding coating Download PDF

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Publication number
CN108948918A
CN108948918A CN201810659631.2A CN201810659631A CN108948918A CN 108948918 A CN108948918 A CN 108948918A CN 201810659631 A CN201810659631 A CN 201810659631A CN 108948918 A CN108948918 A CN 108948918A
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China
Prior art keywords
high temperature
temperature resistant
radiation shielding
shielding coating
rosin resin
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CN201810659631.2A
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Chinese (zh)
Inventor
李振飞
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Anhui Hi Polymer Material Co Ltd
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Anhui Hi Polymer Material Co Ltd
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Priority to CN201810659631.2A priority Critical patent/CN108948918A/en
Publication of CN108948918A publication Critical patent/CN108948918A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to a kind of high temperature resistant radiation shielding coatings, are made of following component: acrylic emulsion, chitin modified rosin resin, potassium citrate, D-sorbite, mica powder, defoaming agent, sodium citrate, nanometer calcium carbonate, water;The present invention is selected by carrying out to each component, so that having significant synergistic effect between each component, is acted synergistically by adding chitin modified rosin resin and mica powder, the adhesive force of coating, high temperature resistant, radiation protection and ageing-resistant performance can be greatly improved.

Description

A kind of high temperature resistant radiation shielding coating
Technical field
The invention belongs to technical field of biological environmental protection, and in particular to a kind of high temperature resistant radiation shielding coating.
Background technique
Radiation proof material has become a big project of current material subject, with various high radiation devices appearance and extensively Using the research of radiation proof material has caused the common concern of people.And various radiation sources exist in people's life, also force Attention of the people to radiation proof material;Radiation has been classified as the fourth-largest ring after water source, atmosphere, noise by the World Health Organization Border pollution sources, become the stealth " killer " for endangering human health, and protection radiation has become a top priority.Currently, radiation shielding coating Mostly using heavy metal or rare metal powder and its oxide are added in coating composition, especially contain Ba, Pb, U, Lu Equal metallic compounds, or use composite deposite, but it is inevitable also bring constructional difficulties, adhesive force is inadequate, while function is not enough etc. Defect, thus radiation shielding coating is also only applied in some special industries and special dimension, and answered in the fields such as people's lives With less.Therefore the radiation shielding coating that exploitation has both other additional properties becomes the task of top priority;With other additional properties Radiation shielding coating had not only been able to satisfy the basic function of coating, but also widened its application field, also complied with that coating is multi-functional, multi-field development Requirement.
Summary of the invention
The present invention is achieved by the following technical solutions: a kind of high temperature resistant radiation shielding coating, which is characterized in that by weight Part meter is made of following component: acrylic emulsion 90, chitin modified rosin resin 12-15, potassium citrate 3.3, D-sorbite 5.5, mica powder 3-4, defoaming agent 1.5, sodium citrate 3.3, nanometer calcium carbonate 6-8, water 78.
Further, the mica Powder Particle Size is 1500 mesh.
Further, the nanometer calcium carbonate granularity is 75nm.
Further, the chitin modified rosin resin the preparation method comprises the following steps:
(1) after evenly mixing by rosin resin and the rare earth chloride of its quality 0.08%, it is added in melting kettle, is passed through indifferent gas Body protection, is warming up to 215 DEG C of fusing rosin, after being completely melt, heat preservation;
(2) it keeps being passed through inert gas shielding, starts to stir with 1500r/min revolving speed, then put into rosin resin quality again 2.5% maleic acid adjusts the temperature to 202 DEG C, insulated and stirred 45min;
(3) chitosan of rosin resin quality 10% is added again, with the stirring of 2500r/min revolving speed, and is warming up to 235 DEG C, is kept the temperature Stirring 2 hours;
(4) it vacuumizes, after keeping 42min, release, temperature is reduced to 150 DEG C naturally, keeps the temperature 25min;
(5) be eventually adding the 2,6-di-tert-butyl p-cresol of rosin resin quality 0.25%, stirring 2 as a child, filtering, using going Ionized water cleaning, drying to constant weight to get.
Further, the rare earth chloride is lanthanum chloride.
Further, the inert gas be nitrogen, it is any in neon.
Further, described to vacuumize to be evacuated to 0.01MPa.
Further, the defoaming agent is organic silicon defoamer.
Further, the water is deionized water.
The present invention has the advantage that the present invention is selected by carrying out to each component compared with prior art, so that each component Between there is significant synergistic effect, acted synergistically by adding chitin modified rosin resin and mica powder, can be significantly Raising coating adhesive force, high temperature resistant, radiation protection and ageing-resistant performance, in high temperature resistant radiation shielding coating provided by the invention Cooperate between each component, have complementary advantages so that the coating keep good adhesion under the premise of, have excellent anti-corrosion, The characteristics such as radiation protection, fire-retardant, antibacterial, tolerance high temperature, anti-cracking, cold-hot alternation, storage stability, in petroleum and petrochemical industry, smelting The special dimensions such as gold, electric power, national defence have a extensive future.The preparation method of above-mentioned high temperature resistant radiation shielding coating provided by the invention It is easy to operate, it is easy to accomplish.
Specific embodiment
Embodiment 1
A kind of high temperature resistant radiation shielding coating, which is characterized in that be made by weight of following component: acrylic emulsion 90, shell Glycan modified rosin resin 15, potassium citrate 3.3, D-sorbite 5.5, mica powder 4, defoaming agent 1.5, sodium citrate 3.3, nanometer Calcium carbonate 8, water 78.
Further, the mica Powder Particle Size is 1500 mesh.
Further, the nanometer calcium carbonate granularity is 75nm.
Further, the chitin modified rosin resin the preparation method comprises the following steps:
(1) after evenly mixing by rosin resin and the rare earth chloride of its quality 0.08%, it is added in melting kettle, is passed through indifferent gas Body protection, is warming up to 215 DEG C of fusing rosin, after being completely melt, heat preservation;
(2) it keeps being passed through inert gas shielding, starts to stir with 1500r/min revolving speed, then put into rosin resin quality again 2.5% maleic acid adjusts the temperature to 202 DEG C, insulated and stirred 45min;
(3) chitosan of rosin resin quality 10% is added again, with the stirring of 2500r/min revolving speed, and is warming up to 235 DEG C, is kept the temperature Stirring 2 hours;
(4) it vacuumizes, after keeping 42min, release, temperature is reduced to 150 DEG C naturally, keeps the temperature 25min;
(5) be eventually adding the 2,6-di-tert-butyl p-cresol of rosin resin quality 0.25%, stirring 2 as a child, filtering, using going Ionized water cleaning, drying to constant weight to get.
Further, the rare earth chloride is lanthanum chloride.
Further, the inert gas be nitrogen, it is any in neon.
Further, described to vacuumize to be evacuated to 0.01MPa.
Further, the defoaming agent is organic silicon defoamer.
Further, the water is deionized water.
Embodiment 2
A kind of high temperature resistant radiation shielding coating, which is characterized in that be made by weight of following component: acrylic emulsion 90, shell Glycan modified rosin resin 12, potassium citrate 3.3, D-sorbite 5.5, mica powder 3, defoaming agent 1.5, sodium citrate 3.3, nanometer Calcium carbonate 6, water 78.
Further, the mica Powder Particle Size is 1500 mesh.
Further, the nanometer calcium carbonate granularity is 75nm.
Further, the chitin modified rosin resin the preparation method comprises the following steps:
(1) after evenly mixing by rosin resin and the rare earth chloride of its quality 0.08%, it is added in melting kettle, is passed through indifferent gas Body protection, is warming up to 215 DEG C of fusing rosin, after being completely melt, heat preservation;
(2) it keeps being passed through inert gas shielding, starts to stir with 1500r/min revolving speed, then put into rosin resin quality again 2.5% maleic acid adjusts the temperature to 202 DEG C, insulated and stirred 45min;
(3) chitosan of rosin resin quality 10% is added again, with the stirring of 2500r/min revolving speed, and is warming up to 235 DEG C, is kept the temperature Stirring 2 hours;
(4) it vacuumizes, after keeping 42min, release, temperature is reduced to 150 DEG C naturally, keeps the temperature 25min;
(5) be eventually adding the 2,6-di-tert-butyl p-cresol of rosin resin quality 0.25%, stirring 2 as a child, filtering, using going Ionized water cleaning, drying to constant weight to get.
Further, the rare earth chloride is lanthanum chloride.
Further, the inert gas be nitrogen, it is any in neon.
Further, described to vacuumize to be evacuated to 0.01MPa.
Further, the defoaming agent is organic silicon defoamer.
Further, the water is deionized water.
Embodiment 3
A kind of high temperature resistant radiation shielding coating, which is characterized in that be made by weight of following component: acrylic emulsion 90, shell Glycan modified rosin resin 13, D-sorbite 5.5, mica powder 3.5, defoaming agent 1.5, sodium citrate 3.3, is received potassium citrate 3.3 Rice calcium carbonate 7, water 78.
Further, the mica Powder Particle Size is 1500 mesh.
Further, the nanometer calcium carbonate granularity is 75nm.
Further, the chitin modified rosin resin the preparation method comprises the following steps:
(1) after evenly mixing by rosin resin and the rare earth chloride of its quality 0.08%, it is added in melting kettle, is passed through indifferent gas Body protection, is warming up to 215 DEG C of fusing rosin, after being completely melt, heat preservation;
(2) it keeps being passed through inert gas shielding, starts to stir with 1500r/min revolving speed, then put into rosin resin quality again 2.5% maleic acid adjusts the temperature to 202 DEG C, insulated and stirred 45min;
(3) chitosan of rosin resin quality 10% is added again, with the stirring of 2500r/min revolving speed, and is warming up to 235 DEG C, is kept the temperature Stirring 2 hours;
(4) it vacuumizes, after keeping 42min, release, temperature is reduced to 150 DEG C naturally, keeps the temperature 25min;
(5) be eventually adding the 2,6-di-tert-butyl p-cresol of rosin resin quality 0.25%, stirring 2 as a child, filtering, using going Ionized water cleaning, drying to constant weight to get.
Further, the rare earth chloride is lanthanum chloride.
Further, the inert gas be nitrogen, it is any in neon.
Further, described to vacuumize to be evacuated to 0.01MPa.
Further, the defoaming agent is organic silicon defoamer.
Further, the water is deionized water.
Coating property index of the present invention:
1, paint film appearance: flat and smooth
2, viscosity (23 ± 1 DEG C of viscosimeters, S): 82
3, fineness≤33 μm
4, high temperature resistant (130 DEG C) >=510h
5, hardness >=2H
6, salt spray resistance (120h grades) >=2
7, water resistance (29 ± 1 DEG C of 240h): it is not blistering, it does not fall off
8, oil resistant (90# gasoline, 56h): it is not blistering, it does not fall off
9, alkali resistance (GB/T9755-2001): more than 60 hours
10, artificial weathering ageing resistance (GB/T9755-2001): more than 1220 hours.

Claims (9)

1. a kind of high temperature resistant radiation shielding coating, which is characterized in that be made by weight of following component: acrylic emulsion 90, Chitin modified rosin resin 12-15, potassium citrate 3.3, D-sorbite 5.5, mica powder 3-4, defoaming agent 1.5, sodium citrate 3.3, nanometer calcium carbonate 6-8, water 78.
2. a kind of high temperature resistant radiation shielding coating as described in claim 1, which is characterized in that the mica Powder Particle Size is 1500 mesh.
3. a kind of high temperature resistant radiation shielding coating as described in claim 1, which is characterized in that the nanometer calcium carbonate granularity is 75nm。
4. a kind of high temperature resistant radiation shielding coating as described in claim 1, which is characterized in that the chitin modified rosin resin system Preparation Method are as follows:
(1) after evenly mixing by rosin resin and the rare earth chloride of its quality 0.08%, it is added in melting kettle, is passed through indifferent gas Body protection, is warming up to 215 DEG C of fusing rosin, after being completely melt, heat preservation;
(2) it keeps being passed through inert gas shielding, starts to stir with 1500r/min revolving speed, then put into rosin resin quality again 2.5% maleic acid adjusts the temperature to 202 DEG C, insulated and stirred 45min;
(3) chitosan of rosin resin quality 10% is added again, with the stirring of 2500r/min revolving speed, and is warming up to 235 DEG C, is kept the temperature Stirring 2 hours;
(4) it vacuumizes, after keeping 42min, release, temperature is reduced to 150 DEG C naturally, keeps the temperature 25min;
(5) be eventually adding the 2,6-di-tert-butyl p-cresol of rosin resin quality 0.25%, stirring 2 as a child, filtering, using going Ionized water cleaning, drying to constant weight to get.
5. a kind of high temperature resistant radiation shielding coating as claimed in claim 4, which is characterized in that the rare earth chloride is lanthanum chloride.
6. a kind of high temperature resistant radiation shielding coating as claimed in claim 4, which is characterized in that the inert gas is nitrogen, neon In it is any.
7. a kind of high temperature resistant radiation shielding coating as claimed in claim 4, which is characterized in that described to vacuumize to be evacuated to 0.01MPa。
8. a kind of high temperature resistant radiation shielding coating as described in claim 1, which is characterized in that the defoaming agent is organosilicon defoaming Agent.
9. a kind of high temperature resistant radiation shielding coating as described in claim 1, which is characterized in that the water is deionized water.
CN201810659631.2A 2018-06-25 2018-06-25 A kind of high temperature resistant radiation shielding coating Withdrawn CN108948918A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230058216A (en) * 2021-10-22 2023-05-03 주식회사 오리온이엔씨 Sealant Composition with Radiation Shielding Function, and Method for Manufacturing the Same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107974112A (en) * 2017-11-29 2018-05-01 马鞍山市恒特重工科技有限公司 A kind of mining machinery surface weather-resistant coating

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107974112A (en) * 2017-11-29 2018-05-01 马鞍山市恒特重工科技有限公司 A kind of mining machinery surface weather-resistant coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230058216A (en) * 2021-10-22 2023-05-03 주식회사 오리온이엔씨 Sealant Composition with Radiation Shielding Function, and Method for Manufacturing the Same
KR102559070B1 (en) 2021-10-22 2023-07-25 주식회사 오리온이엔씨 Sealant Composition with Radiation Shielding Function, and Method for Manufacturing the Same

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