CN103589281A - High temperature resistant anticorrosion coating based on graphene and preparation method thereof - Google Patents
High temperature resistant anticorrosion coating based on graphene and preparation method thereof Download PDFInfo
- Publication number
- CN103589281A CN103589281A CN201310538981.0A CN201310538981A CN103589281A CN 103589281 A CN103589281 A CN 103589281A CN 201310538981 A CN201310538981 A CN 201310538981A CN 103589281 A CN103589281 A CN 103589281A
- Authority
- CN
- China
- Prior art keywords
- graphene
- fire
- resistant anticorrosion
- anticorrosion paint
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a high temperature resistant anticorrosion coating based on graphene and a preparation method thereof. The high temperature anticorrosion coating comprises the following components by the mass percentage: 5-60% of epoxy resin, 3-30% of polyphenylene sulfide resin, 3-30% of amino resin, 1-10% of a pigment, 1-20% of graphene, 3-50% of n-butyl alcohol, 0.1-0.3% of a defoaming agent, 0.1-10% of polyhydroxy acid sodium salt, 0.1-5% of benzenedicarboxylic acid dibutyl ester, 0.5-1.0% of bentonite, and 0.2-0.5% of a leveling agent. Compared with the prior art, the prepared coating has the advantages of quite excellent waterproof and anticorrosion performance, high temperature resistance, weather resistance, alkali resistance, impact resistance, artificial aging resistance and the like, and the preparation method has the advantages of good controllability, simple operation, low production cost, and easy industrialized production.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, especially relate to a kind of fire-resistant anticorrosion paint based on Graphene and preparation method thereof.
Background technology
High-temperature resistant coating is a kind of important coating, is applicable to chimney air flue, high temperature steam pipeline, heat exchanger, High Temperature Furnaces Heating Apparatus, high temperature desulfurizing equipment, petroleum and petrochemical industry cracker, engine parts and vapor pipe anticorrosion.The special fire-resistant anticorrosion paint of other is used widely in space flight and aviation, petroleum and petrochemical industry, metallurgy, electric power, national defence field.Since the forties organosilicon suitability for industrialized production, the high-temperature resistant coating of preparing with its product, at high-temperature electric machine, electrical apparatus insulation aspect is widely applied.For example organosilicon aluminium powder paint, for the fire-resistant anticorrosion paint of aircraft engine, has been obtained great achievement, and organosilicon glass-ceramic coating, has met the requirement of higher temperature rot-resistant.But due to the bad mechanical property of organosilicon own, sticking power, wear resistance, solvent resistance is low, and waste water and gas is more in producing, contaminate environment is inflammable, simultaneously harmful, therefore, more and more can not meet the requirement of modern electrical machine, electrical equipment, aerospace and resistance to Special Medium.
Graphene is a kind of novel material of the individual layer sheet structure consisting of carbon atom.Be a kind ofly by carbon atom, with sp2 hybridized orbital, to form the flat film that hexangle type is honeycomb lattice, only have the two-dimensional material of a carbon atom thickness.Graphene be at present the thinnest be in the world the hardest nano material also, it is almost completely transparent, only absorbs 2.3% light; Thermal conductivity is up to 5300W/mK, and higher than carbon nanotube and diamond, under normal temperature, its electronic mobility surpasses 15000cm
2/ Vs, ratio nano carbon pipe or silicon wafer height again, and resistivity only approximately 10
-6Ω cm, lower than copper or silver, be the current material of resistivity minimum in the world.At present, also report no matter Graphene is directly on copper or nickel, to prepare, or transfer on other metals, all can provide anti-corrosion protection.Copper coating is cultivated single-layer graphene, adopts chemical Vapor deposition process, slow seven times than naked copper of corrosion meetings, and nickel coating is cultivated multi-layer graphene, corrodes slower more than 20 times than naked nickel.Single-layer graphene has identical anti-corrosion protection effect, and just as conventional organic coating, but the latter is thick more than five times.Graphene coating can be used as desirable anticorrosive coating, because in some field, shallow layer is more favourable, and such as micromodule, interconnection products, aircraft components and implanting device etc. is all like this.And single-layer graphene is applied to the method more complicated of metallic surface and condition is harsh, not easy to operate.
Chinese patent CN 102702959A has announced a kind of improved refractory metal protective system, content is composed of the following components by mass percentage: GHNK high temperature resistant binder 30-40 part, polyaniline/graphene composite material is 15-20 part, tinting pigment is 15-20 part, superfine talcum powder is 5-10 part, ultrafine mica powder is 5-10 part, kaolin is 5-10 part, SN-612 flow agent is 0.2-0.5 part, wetting agent X-405 is 0.3-0.5 part, dimethylethanolamine is 0.1-0.3 part, sanitas 981 is 0.1-0.3 part, GHP101 thickening material is 0.5-1 part, tributyl phosphate is 0.1-0.3 part, water is 4-13 part.The coating that this invention makes has the advantages such as splendid waterproof anti-corrosion, high temperature resistant, alkali resistance, weathering resistance, scrub resistance and artificial ageing resistance, can realize passivation and the inhibition of metal base, avoid causing the use of the heavy metals such as chromium of environmental pollution simultaneously.But its main component polyaniline/graphene composite material complicated process of preparation, and main utilize be polyaniline high conductivity, raw material cheap, the characteristic such as be easy to synthesize, but research shows that the preservative activity that polyaniline and Graphene are not mutually promoted, polyaniline and Graphene do not realize its real effect.
Chinese patent CN 103265881A discloses a kind of fire-resistant anticorrosion paint that comprises poly-aryl silicone resin, by following composition, according to weight ratio, formed: 40～50 parts of poly-aryl silicone resins, 20～30 parts of P-hydroxybenzoic acid glycidyl esters, 5～10 parts of acrylic resins, 10～15 parts of mica powders, 10～15 parts of Graphenes, 5～10 parts of vinyl acetic monomers, 10～20 parts of thinners.Thinner is butanols or dimethylbenzene.The fire-resistant anticorrosion paint of making can reach 400～500 ℃ by tolerable temperature, has good preservative effect simultaneously.Although this patent be take Graphene and is added as main stuffing, but in its preparation method, just use the hybrid mode stirring can not make graphene uniform disperse, thereby do not have that its size is little, electronics transmission speed is fast, good conductivity, hardness advantages of higher, and its key effect that explain oneself Graphene does not play in this coating.
Summary of the invention
Object of the present invention is exactly to provide a kind of fire-resistant anticorrosion paint based on Graphene and preparation method thereof in order to overcome the defect of above-mentioned prior art existence, by adding of Graphene, the high temperature resistant and antiseptic property of this protective system is significantly improved.
Object of the present invention can be achieved through the following technical solutions:
A kind of fire-resistant anticorrosion paint based on Graphene, composed of the following components by mass percentage: epoxy resin 5-60%, polyphenylene sulfide 3-30%, aminoresin 3-30%, pigment 1-10%, Graphene 1-20%, propyl carbinol 3-50%, defoamer 0.1-0.3%, poly-hydroxy acid sodium salt 0.1-10%, dibutyl phthalate 0.1-5%, wilkinite 0.5-1.0%, flow agent 0.2-0.5%.
Further, described epoxy resin is selected from 665 commercially available organosilicon epoxy resins or ES-06 organosilicon epoxy resin.
Further, described aminoresin is selected from a kind of in 520 commercially available urea-formaldehyde resins, 582 terpolycyantoamino-formaldehyde resins or 576-1 trimeric cyanamide benzene guanamine resin.
Further, described pigment is selected from a kind of in titanium dioxide, zinc oxide, red iron oxide or phthalocyanine green.
Further, described Graphene is made by oxidation reduction process or high temperature reduction method.
Further, described defoamer is selected from tributyl phosphate, polyethers defoamer, silica-type defoamer or methyl-silicone oil.
Further, described polyethers defoamer is selected from a kind of in commercially available GP type defoamer, GPE type defoamer or GPES type defoamer; Described silica-type defoamer is polysiloxane defoamers.
Further, described poly-hydroxy acid sodium salt is poly-2-hydroxyl acrylic sodium salt.
Further, described flow agent is selected from a kind of in silicone oil, polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane or alkyl-modified organo-siloxane.
A preparation method for the fire-resistant anticorrosion paint of Graphene, the method comprises the following steps:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 30-180 minute;
(2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns;
(3) after mixing, material step (1) and step (2) being made stirs 10-120 minute, after adding wilkinite, continue to stir 10-60 minute, then at grinding machine for grinding 10-120 minute, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Compared with prior art, the present invention joins Graphene, epoxy resin and polyphenylene sulfide in propyl carbinol, ultrasonic agitation 30-180 minute, and join together with other component in shredder and be fully ground to below 30 microns, make full and uniform the mixing with other component of Graphene, the premium properties of Graphene is not fully exerted.Meanwhile, epoxy resin and polyphenylene sulfide are under the effect of Graphene, and high temperature resistant, erosion resistance strengthens greatly, can reach 700 ℃ by tolerable temperature.Meanwhile, the present invention also has the following advantages and beneficial effect:
(1) the two-dimentional laminated structure of Graphene is layering in coating, has formed fine and close physical isolation layer, has strengthened the antiseptic property of coating;
(2) Graphene size is minimum, and thickness only has a carbon atom thick, can make in its cavity and defect that is filled into easily coating, stops and delayed small molecules corrosive medium to invade metallic matrix, has strengthened the antiseptic property of coating;
(3) thermal conductivity of Graphene, up to 5300W/mK, has very strong thermal conductivity, and the interpolation of Graphene has strengthened the high thermal resistance of coating greatly;
(4) under Graphene normal temperature, electronic mobility surpasses 15000cm
2/ Vs, has good conductive capability fast, and the interpolation of Graphene has improved the antiseptic power of carrying material;
(5) Graphene has very strong water-repellancy, very poor to the wettability of water, and Graphene can stop water molecules to enter into metal base surface by figure layer, thereby strengthens the antiseptic power of coating;
(6) coating that the present invention makes has the advantages such as splendid waterproof anti-corrosion, high temperature resistant, weathering resistance, alkali resistance, shock-resistant and artificial ageing resistance;
(7) preparation method's controllability of the present invention is good, simple to operate, and production cost is low, is easy to suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
By following mass percent, be equipped with each component: epoxy resin (665 commercially available organosilicon epoxy resins) 20%, polyphenylene sulfide 20%, aminoresin (520 commercially available urea-formaldehyde resins) 20%, pigment (titanium dioxide) 5%, Graphene 10%, propyl carbinol 14%, defoamer (tributyl phosphate) 0.2%, poly-2-hydroxyl acrylic sodium salt 6%, dibutyl phthalate 4%, wilkinite 0.5%, flow agent (silicone oil) 0.3%.
By following steps, make the fire-resistant anticorrosion paint based on Graphene:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 150 minutes;
(2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns;
(3) after mixing, stirs 90 minutes material step (1) and step (2) being made, add after wilkinite and continue to stir 40 minutes, then, grinding machine for grinding 90 minutes, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Embodiment 2
By following mass percent, be equipped with each component: epoxy resin (ES-06 organosilicon epoxy resin) 25%, polyphenylene sulfide 25%, aminoresin (582 terpolycyantoamino-formaldehyde resin) 15%, pigment (zinc oxide) 5%, Graphene 10%, propyl carbinol 10%, defoamer (GP type defoamer) 0.2%, poly-hydroxy acid sodium salt 5.5%, dibutyl phthalate 3%, wilkinite 0.8%, flow agent (polydimethylsiloxane) 0.5%.
By following steps, make the fire-resistant anticorrosion paint based on Graphene:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 150 minutes;
(2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns;
(3) after mixing, stirs 90 minutes material step (1) and step (2) being made, add after wilkinite and continue to stir 40 minutes, then, grinding machine for grinding 90 minutes, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Embodiment 3
By following mass percent, be equipped with each component: epoxy resin (ES-06 organosilicon epoxy resin) 40%, polyphenylene sulfide 10%, aminoresin (576-1 trimeric cyanamide benzene guanamine resin) 10%, pigment (red iron oxide) 8%, Graphene 5%, propyl carbinol 20%, defoamer (GPE type defoamer) 0.3%, poly-hydroxy acid sodium salt 3.5%, dibutyl phthalate 2%, wilkinite 0.8%, flow agent (polyether polyester modified organic silicon oxygen alkane) 0.4%.
By following steps, make the fire-resistant anticorrosion paint based on Graphene:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 150 minutes;
(2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns;
(3) after mixing, stirs 90 minutes material step (1) and step (2) being made, add after wilkinite and continue to stir 40 minutes, then, grinding machine for grinding 90 minutes, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Performance test to the fire-resistant anticorrosion paint based on Graphene of embodiment 1～3 gained is carried out according to GB, and test result is in Table 1.
The performance of table 1 fire-resistant anticorrosion paint
Embodiment 4
A kind of fire-resistant anticorrosion paint based on Graphene, composed of the following components by mass percentage: epoxy resin (665 commercially available organosilicon epoxy resins) 5%, polyphenylene sulfide 30%, aminoresin (520 commercially available urea-formaldehyde resins) 30%, pigment (phthalocyanine green) 10%, Graphene (being made by oxidation reduction process) 20%, propyl carbinol 3%, defoamer (GPES type defoamer) 0.3%, poly-2-hydroxyl acrylic sodium salt 0.1%, dibutyl phthalate 0.1%, wilkinite 1.0%, flow agent (alkyl-modified organo-siloxane) 0.5%.
A preparation method for the fire-resistant anticorrosion paint of Graphene, the method comprises the following steps:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 30 minutes; (2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns; (3) after mixing, stirs 10 minutes material step (1) and step (2) being made, add after wilkinite and continue to stir 10 minutes, then, grinding machine for grinding 10 minutes, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Embodiment 5
A kind of fire-resistant anticorrosion paint based on Graphene, composed of the following components by mass percentage: epoxy resin (commercially available ES-06 organosilicon epoxy resin) 60%, polyphenylene sulfide 3%, aminoresin (520 commercially available urea-formaldehyde resins) 3%, pigment (titanium dioxide) 1%, Graphene (being made by high temperature reduction method) 1%, propyl carbinol 16.2%, defoamer (polysiloxane defoamers) 0.1%, poly-2-hydroxyl acrylic sodium salt 10%, dibutyl phthalate 5%, wilkinite 0.5%, flow agent (polyether polyester modified organic silicon oxygen alkane) 0.2%.
A preparation method for the fire-resistant anticorrosion paint of Graphene, the method comprises the following steps:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in E butanols to ultrasonic agitation 180 minutes; (2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns; (3) after mixing, stirs 120 minutes material step (1) and step (2) being made, add after wilkinite and continue to stir 60 minutes, then, grinding machine for grinding 120 minutes, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Embodiment 6
A kind of fire-resistant anticorrosion paint based on Graphene, composed of the following components by mass percentage: epoxy resin (665 commercially available organosilicon epoxy resins) 10%, polyphenylene sulfide 10%, aminoresin (520 commercially available urea-formaldehyde resins) 10%, pigment (phthalocyanine green) 5%, Graphene (being made by oxidation reduction process) 6%, propyl carbinol 50%, defoamer (methyl-silicone oil) 0.2%, poly-2-hydroxyl acrylic sodium salt 5.8%, dibutyl phthalate 2%, wilkinite 0.7%, flow agent (alkyl-modified organo-siloxane) 0.3%.
A preparation method for the fire-resistant anticorrosion paint of Graphene, the method comprises the following steps:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 120 minutes; (2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns; (3) after mixing, stirs 60 minutes material step (1) and step (2) being made, add after wilkinite and continue to stir 30 minutes, then, grinding machine for grinding 60 minutes, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Claims (10)
1. the fire-resistant anticorrosion paint based on Graphene, it is characterized in that, composed of the following components by mass percentage: epoxy resin 5-60%, polyphenylene sulfide 3-30%, aminoresin 3-30%, pigment 1-10%, Graphene 1-20%, propyl carbinol 3-50%, defoamer 0.1-0.3%, poly-hydroxy acid sodium salt 0.1-10%, dibutyl phthalate 0.1-5%, wilkinite 0.5-1.0%, flow agent 0.2-0.5%.
2. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described epoxy resin is selected from 665 commercially available organosilicon epoxy resins or ES-06 organosilicon epoxy resin.
3. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described aminoresin is selected from a kind of in 520 commercially available urea-formaldehyde resins, 582 terpolycyantoamino-formaldehyde resins or 576-1 trimeric cyanamide benzene guanamine resin.
4. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described pigment is selected from a kind of in titanium dioxide, zinc oxide, red iron oxide or phthalocyanine green.
5. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described Graphene is made by oxidation reduction process or high temperature reduction method.
6. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described defoamer is selected from tributyl phosphate, polyethers defoamer, silica-type defoamer or methyl-silicone oil.
7. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 6, is characterized in that, described polyethers defoamer is selected from a kind of in commercially available GP type defoamer, GPE type defoamer or GPES type defoamer; Described silica-type defoamer is polysiloxane defoamers.
8. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described poly-hydroxy acid sodium salt is poly-2-hydroxyl acrylic sodium salt.
9. a kind of fire-resistant anticorrosion paint based on Graphene according to claim 1, is characterized in that, described flow agent is selected from a kind of in silicone oil, polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane or alkyl-modified organo-siloxane.
10. a preparation method for the fire-resistant anticorrosion paint based on Graphene as described in as arbitrary in claim 1～10, is characterized in that, the method comprises the following steps:
(1) Graphene, epoxy resin and polyphenylene sulfide are joined in propyl carbinol to ultrasonic agitation 30-180 minute;
(2) aminoresin, pigment, defoamer, poly-hydroxy acid sodium salt, dibutyl phthalate, flow agent are measured in accordance with regulations and added in shredder, be ground to fineness and be less than 30 microns;
(3) after mixing, material step (1) and step (2) being made stirs 10-120 minute, after adding wilkinite, continue to stir 10-60 minute, then at grinding machine for grinding 10-120 minute, filter, obtain the fire-resistant anticorrosion paint based on Graphene, then seal, pack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310538981.0A CN103589281B (en) | 2013-11-04 | 2013-11-04 | A kind of fire-resistant anticorrosion paint based on Graphene and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310538981.0A CN103589281B (en) | 2013-11-04 | 2013-11-04 | A kind of fire-resistant anticorrosion paint based on Graphene and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103589281A true CN103589281A (en) | 2014-02-19 |
| CN103589281B CN103589281B (en) | 2015-09-09 |
Family
ID=50079613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310538981.0A Expired - Fee Related CN103589281B (en) | 2013-11-04 | 2013-11-04 | A kind of fire-resistant anticorrosion paint based on Graphene and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103589281B (en) |
Cited By (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130665A (en) * | 2014-07-21 | 2014-11-05 | 关锦池 | Solvent-free epoxy coating |
| CN104194585A (en) * | 2014-09-18 | 2014-12-10 | 周诚 | Graphene-modified resin powder coating and production process thereof |
| CN104403502A (en) * | 2014-12-01 | 2015-03-11 | 湖南东博墨烯科技有限公司 | Graphene-based nano zero-valence silicone coating and preparation method thereof |
| CN104479494A (en) * | 2014-12-01 | 2015-04-01 | 湖南东博墨烯科技有限公司 | Graphene-based nanometre zero-valent zinc coating and preparation method thereof |
| CN104497868A (en) * | 2015-01-14 | 2015-04-08 | 徐继武 | Graphene waterproof paint |
| CN104650714A (en) * | 2015-02-02 | 2015-05-27 | 安徽省东瑞装饰材料有限公司 | Flame-retardant waterproof coating for interior wall of building and preparation method thereof |
| CN104650722A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof coating with good flexible permeability and preparation method thereof |
| CN104650719A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Sterilizing freezing-tolerance waterproof paint and preparation method thereof |
| CN104650727A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Multifunctional environment-friendly waterproof paint and preparation method thereof |
| CN104650726A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Thermal insulation high-elasticity waterproof paint and preparation method thereof |
| CN104650723A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Mildew-proof anti-static waterproof paint and preparation method thereof |
| CN104650718A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Scraping-resistant waterproof external wall coating and preparation method thereof |
| CN104650720A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Low-temperature-resistant anti-leakage waterproof paint and preparation method thereof |
| CN104650721A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof paint with high corrosion resistance and adhesive property and preparation method of waterproof paint |
| CN104650716A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Antiaging waterproofing paint with good stability and method for preparing antiaging waterproofing paint with good stability |
| CN104650725A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof coating with excellent filming property and preparation method thereof |
| CN104650728A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Wear-resistant scrub-resistant waterproof paint and preparation method thereof |
| CN104650715A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof coating with excellent anti-aging wear-resisting property and preparation method of waterproof coating |
| CN104650717A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | High-weather resistance low-discoloration-tendency waterproof paint and preparation method thereof |
| CN104650724A (en) * | 2015-02-02 | 2015-05-27 | 安徽省东瑞装饰材料有限公司 | Building heat-insulating waterproof paint and preparation method thereof |
| CN104673089A (en) * | 2015-02-02 | 2015-06-03 | 安徽枞阳县渡江充气设备制造有限公司 | High-efficiency durable waterproof coating and preparation method thereof |
| CN104672965A (en) * | 2015-02-02 | 2015-06-03 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof paint with high adhesive force and crack resistance and preparation method of waterproof paint |
| CN104673088A (en) * | 2015-02-02 | 2015-06-03 | 安徽省东瑞装饰材料有限公司 | Waterproof coating for building roof and preparation method of waterproof coating |
| CN104673087A (en) * | 2015-02-02 | 2015-06-03 | 安徽省东瑞装饰材料有限公司 | Anti-flaking waterproof coating material for buildings and preparation method thereof |
| CN104927660A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Moss-control floor coating |
| CN105038118A (en) * | 2015-07-07 | 2015-11-11 | 苏州珍展科技材料有限公司 | Urea-formaldehyde resin-based composite material and preparation method thereof |
| CN105086682A (en) * | 2014-10-30 | 2015-11-25 | 合肥蓝天家具制造有限责任公司 | Graphene anticorrosion paint |
| CN105176390A (en) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | High-temperature-resistant water-based coating for metal surface and preparation method thereof |
| CN105348745A (en) * | 2015-11-30 | 2016-02-24 | 青岛爱尔家佳新材料有限公司 | Damping material used for transmission system and preparation method of damping material |
| CN105482435A (en) * | 2014-09-29 | 2016-04-13 | 中国科学院苏州纳米技术与纳米仿生研究所 | Three-dimensional-corrugated-graphene heat dissipating slurry, preparation method therefor and application of three-dimensional-corrugated-graphene heat dissipating slurry |
| CN105585930A (en) * | 2015-10-29 | 2016-05-18 | 中国航空工业集团公司北京航空材料研究院 | Graphene paint for steel fastening parts and preparation method of graphene paint |
| CN105647338A (en) * | 2014-11-28 | 2016-06-08 | 中国科学院金属研究所 | Graphene/epoxy resin composite anticorrosive paint with high isolation and preparation method |
| CN105969069A (en) * | 2016-07-04 | 2016-09-28 | 苏州云舒新材料科技有限公司 | Graphene-modified epoxy resin anticorrosive coating |
| CN106085139A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of anticorrosive paint |
| CN106189717A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of photochromic anticorrosive paint |
| CN106243921A (en) * | 2016-08-15 | 2016-12-21 | 陈曦 | A kind of wear, alkali resistant nano anticorrosive coating and preparation method thereof |
| CN106243943A (en) * | 2016-08-22 | 2016-12-21 | 广东纳路纳米科技有限公司 | A kind of modified white graphite alkene composite anticorrosion coating and preparation thereof |
| CN106349874A (en) * | 2016-08-29 | 2017-01-25 | 佛山市高明区尚润盈科技有限公司 | Anticorrosion coating preparing method |
| CN106366849A (en) * | 2016-08-29 | 2017-02-01 | 佛山市高明区尚润盈科技有限公司 | Preparation method of antibacterial, anti-radiation and anticorrosion paint |
| CN106366848A (en) * | 2016-08-29 | 2017-02-01 | 佛山市高明区尚润盈科技有限公司 | Preparation method of anti-corrosion, antibacterial and formaldehyde-scavenging paint |
| CN106433084A (en) * | 2016-06-21 | 2017-02-22 | 江苏金陵特种涂料有限公司 | Graphene modified polyaryletherketone polymer material and preparation method thereof |
| CN106433449A (en) * | 2016-08-26 | 2017-02-22 | 燕园众欣纳米科技（北京）有限公司 | Graphene-type high-temperature-resistant anti-corrosion paint and preparation method |
| CN106543875A (en) * | 2016-10-26 | 2017-03-29 | 中国科学院长春应用化学研究所 | A kind of high temperature resistant Graphene anticorrosive paint composition |
| CN106871705A (en) * | 2017-02-21 | 2017-06-20 | 广东万家乐燃气具有限公司 | A kind of etch-proof heat exchanger preparation method with Graphene diaphragm of heat transfer efficient |
| CN108006330A (en) * | 2017-11-13 | 2018-05-08 | 武汉中电节能有限公司 | A kind of energy-efficient long distance delivery heat supply network method |
| CN108047885A (en) * | 2017-12-25 | 2018-05-18 | 北京欧美中科学技术研究院 | A kind of pipeline anti-corrosive paint |
| CN108148482A (en) * | 2017-12-15 | 2018-06-12 | 浙江海洋大学 | Anticorrosive paint peculiar to vessel and preparation method thereof |
| CN108610912A (en) * | 2016-12-09 | 2018-10-02 | 天津安南科技有限公司 | A kind of coating electronic device new material and preparation method thereof |
| CN108610690A (en) * | 2016-12-05 | 2018-10-02 | 赵中华 | A method of it is fire-retardant for electric wire |
| CN108610665A (en) * | 2016-12-02 | 2018-10-02 | 张连瑞 | A kind of preparation method of pylon anticorrosive coating |
| CN108676461A (en) * | 2018-05-04 | 2018-10-19 | 砺剑防务技术集团有限公司 | Poly- silicon ceramic high-temperature resistant anticorrosive paint and preparation method thereof |
| CN108913021A (en) * | 2018-07-25 | 2018-11-30 | 远科秦皇岛节能环保科技开发有限公司 | A kind of preparation method of the dilute composite material film of superhigh temperature graphite |
| CN109627901A (en) * | 2018-12-06 | 2019-04-16 | 安徽超哥精密科技有限公司 | A kind of fire-retardant, impact resistance automotive coatings material |
| CN109839024A (en) * | 2017-09-29 | 2019-06-04 | 中国石油化工股份有限公司 | One kind being used for CO2The plate heat exchanger and its preparation method of trapping |
| CN109943196A (en) * | 2019-03-27 | 2019-06-28 | 浙江中科应化科技有限公司 | A kind of heat-resistant antifriction type nano hybridization epoxy coating |
| CN110194839A (en) * | 2019-06-25 | 2019-09-03 | 西北师范大学 | A kind of preparation and application of graphene quantum dot/polyphenyl thioether composite material |
| CN110218469A (en) * | 2019-06-25 | 2019-09-10 | 东方电气集团东方汽轮机有限公司 | A kind of high temperature resistant graphene conductive water-based anticorrosive paint |
| CN110760232A (en) * | 2019-10-26 | 2020-02-07 | 维新制漆（江西）有限公司 | Nano silicon-carbon modified graphene special anticorrosive paint and preparation method thereof |
| CN111876072A (en) * | 2020-07-07 | 2020-11-03 | 无锡中油瑞德防腐科技有限公司 | Graphene modified polyphenylene sulfide water-based paint and preparation method thereof |
| CN113773720A (en) * | 2021-09-10 | 2021-12-10 | 南京卓煌工业技术有限公司 | Storage tank base composite anticorrosive material and method |
| CN115746649A (en) * | 2022-10-27 | 2023-03-07 | 武汉纺织大学 | Anticorrosive paint for metal and preparation and application thereof |
| CN116535929A (en) * | 2023-04-03 | 2023-08-04 | 百氏高涂料（苏州）有限公司 | Graphene high-temperature-resistant and oxidation-resistant water-based paint and preparation method thereof |
| CN117511391A (en) * | 2024-01-08 | 2024-02-06 | 浙江德力装备有限公司 | Electrostatic spraying composition and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1887996A (en) * | 2006-07-12 | 2007-01-03 | 山东省科学院新材料研究所 | Heat resistant anticorrosive composite polyphenylene sulfide epoxy paint and its prepn |
| CN102702959A (en) * | 2012-06-08 | 2012-10-03 | 冯斌 | Improved high-temperature-resistant metal anti-corrosive paint |
| US20130048917A1 (en) * | 2011-08-31 | 2013-02-28 | Tesla Nanocoatings, Inc. | Composition for Corrosion Prevention |
| CN103173095A (en) * | 2013-03-06 | 2013-06-26 | 常州第六元素材料科技股份有限公司 | Zinc-rich epoxy anticorrosion paint and preparation method thereof |
| CN103265881A (en) * | 2013-05-30 | 2013-08-28 | 苏州艾特斯环保材料有限公司 | High temperature resistant anticorrosive paint comprising polyaryl organic silicon resin |
-
2013
- 2013-11-04 CN CN201310538981.0A patent/CN103589281B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1887996A (en) * | 2006-07-12 | 2007-01-03 | 山东省科学院新材料研究所 | Heat resistant anticorrosive composite polyphenylene sulfide epoxy paint and its prepn |
| US20130048917A1 (en) * | 2011-08-31 | 2013-02-28 | Tesla Nanocoatings, Inc. | Composition for Corrosion Prevention |
| CN102702959A (en) * | 2012-06-08 | 2012-10-03 | 冯斌 | Improved high-temperature-resistant metal anti-corrosive paint |
| CN103173095A (en) * | 2013-03-06 | 2013-06-26 | 常州第六元素材料科技股份有限公司 | Zinc-rich epoxy anticorrosion paint and preparation method thereof |
| CN103265881A (en) * | 2013-05-30 | 2013-08-28 | 苏州艾特斯环保材料有限公司 | High temperature resistant anticorrosive paint comprising polyaryl organic silicon resin |
Cited By (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130665A (en) * | 2014-07-21 | 2014-11-05 | 关锦池 | Solvent-free epoxy coating |
| CN104194585A (en) * | 2014-09-18 | 2014-12-10 | 周诚 | Graphene-modified resin powder coating and production process thereof |
| CN105482435B (en) * | 2014-09-29 | 2018-03-20 | 中国科学院苏州纳米技术与纳米仿生研究所 | Three-dimensional drape shape graphene radiating slurry, its preparation method and application |
| CN105482435A (en) * | 2014-09-29 | 2016-04-13 | 中国科学院苏州纳米技术与纳米仿生研究所 | Three-dimensional-corrugated-graphene heat dissipating slurry, preparation method therefor and application of three-dimensional-corrugated-graphene heat dissipating slurry |
| CN105086682A (en) * | 2014-10-30 | 2015-11-25 | 合肥蓝天家具制造有限责任公司 | Graphene anticorrosion paint |
| CN105647338A (en) * | 2014-11-28 | 2016-06-08 | 中国科学院金属研究所 | Graphene/epoxy resin composite anticorrosive paint with high isolation and preparation method |
| CN104403502A (en) * | 2014-12-01 | 2015-03-11 | 湖南东博墨烯科技有限公司 | Graphene-based nano zero-valence silicone coating and preparation method thereof |
| CN104479494A (en) * | 2014-12-01 | 2015-04-01 | 湖南东博墨烯科技有限公司 | Graphene-based nanometre zero-valent zinc coating and preparation method thereof |
| CN104497868A (en) * | 2015-01-14 | 2015-04-08 | 徐继武 | Graphene waterproof paint |
| CN104650717A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | High-weather resistance low-discoloration-tendency waterproof paint and preparation method thereof |
| CN104650719A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Sterilizing freezing-tolerance waterproof paint and preparation method thereof |
| CN104650718A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Scraping-resistant waterproof external wall coating and preparation method thereof |
| CN104650720A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Low-temperature-resistant anti-leakage waterproof paint and preparation method thereof |
| CN104650721A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof paint with high corrosion resistance and adhesive property and preparation method of waterproof paint |
| CN104650716A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Antiaging waterproofing paint with good stability and method for preparing antiaging waterproofing paint with good stability |
| CN104650725A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof coating with excellent filming property and preparation method thereof |
| CN104650728A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Wear-resistant scrub-resistant waterproof paint and preparation method thereof |
| CN104650715A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof coating with excellent anti-aging wear-resisting property and preparation method of waterproof coating |
| CN104650714A (en) * | 2015-02-02 | 2015-05-27 | 安徽省东瑞装饰材料有限公司 | Flame-retardant waterproof coating for interior wall of building and preparation method thereof |
| CN104650724A (en) * | 2015-02-02 | 2015-05-27 | 安徽省东瑞装饰材料有限公司 | Building heat-insulating waterproof paint and preparation method thereof |
| CN104673089A (en) * | 2015-02-02 | 2015-06-03 | 安徽枞阳县渡江充气设备制造有限公司 | High-efficiency durable waterproof coating and preparation method thereof |
| CN104672965A (en) * | 2015-02-02 | 2015-06-03 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof paint with high adhesive force and crack resistance and preparation method of waterproof paint |
| CN104673088A (en) * | 2015-02-02 | 2015-06-03 | 安徽省东瑞装饰材料有限公司 | Waterproof coating for building roof and preparation method of waterproof coating |
| CN104673087A (en) * | 2015-02-02 | 2015-06-03 | 安徽省东瑞装饰材料有限公司 | Anti-flaking waterproof coating material for buildings and preparation method thereof |
| CN104650722A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Waterproof coating with good flexible permeability and preparation method thereof |
| CN104650723A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Mildew-proof anti-static waterproof paint and preparation method thereof |
| CN104650726A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Thermal insulation high-elasticity waterproof paint and preparation method thereof |
| CN104650727A (en) * | 2015-02-02 | 2015-05-27 | 安徽枞阳县渡江充气设备制造有限公司 | Multifunctional environment-friendly waterproof paint and preparation method thereof |
| CN104927660A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Moss-control floor coating |
| CN105038118A (en) * | 2015-07-07 | 2015-11-11 | 苏州珍展科技材料有限公司 | Urea-formaldehyde resin-based composite material and preparation method thereof |
| CN105038118B (en) * | 2015-07-07 | 2018-04-03 | 王鸳 | Urea resin matrix composite material and preparation method thereof |
| CN105176390A (en) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | High-temperature-resistant water-based coating for metal surface and preparation method thereof |
| CN105585930A (en) * | 2015-10-29 | 2016-05-18 | 中国航空工业集团公司北京航空材料研究院 | Graphene paint for steel fastening parts and preparation method of graphene paint |
| CN105348745A (en) * | 2015-11-30 | 2016-02-24 | 青岛爱尔家佳新材料有限公司 | Damping material used for transmission system and preparation method of damping material |
| CN106433084B (en) * | 2016-06-21 | 2018-07-06 | 江苏金陵特种涂料有限公司 | Graphene modified polyether ketone material and preparation method thereof |
| CN106433084A (en) * | 2016-06-21 | 2017-02-22 | 江苏金陵特种涂料有限公司 | Graphene modified polyaryletherketone polymer material and preparation method thereof |
| CN105969069A (en) * | 2016-07-04 | 2016-09-28 | 苏州云舒新材料科技有限公司 | Graphene-modified epoxy resin anticorrosive coating |
| CN106243921A (en) * | 2016-08-15 | 2016-12-21 | 陈曦 | A kind of wear, alkali resistant nano anticorrosive coating and preparation method thereof |
| CN106243921B (en) * | 2016-08-15 | 2018-03-16 | 陈曦 | A kind of wear, alkali resistant nano anticorrosive coating and preparation method thereof |
| CN106243943A (en) * | 2016-08-22 | 2016-12-21 | 广东纳路纳米科技有限公司 | A kind of modified white graphite alkene composite anticorrosion coating and preparation thereof |
| CN106243943B (en) * | 2016-08-22 | 2018-07-20 | 广东纳路纳米科技有限公司 | A kind of modified white graphite alkene composite anticorrosion coating and its preparation |
| WO2018036422A1 (en) * | 2016-08-22 | 2018-03-01 | 广东纳路纳米科技有限公司 | Modified white graphene composite anti-corrosion coating and preparation thereof |
| CN106433449A (en) * | 2016-08-26 | 2017-02-22 | 燕园众欣纳米科技（北京）有限公司 | Graphene-type high-temperature-resistant anti-corrosion paint and preparation method |
| CN106085139A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of anticorrosive paint |
| CN106366848A (en) * | 2016-08-29 | 2017-02-01 | 佛山市高明区尚润盈科技有限公司 | Preparation method of anti-corrosion, antibacterial and formaldehyde-scavenging paint |
| CN106366849A (en) * | 2016-08-29 | 2017-02-01 | 佛山市高明区尚润盈科技有限公司 | Preparation method of antibacterial, anti-radiation and anticorrosion paint |
| CN106349874A (en) * | 2016-08-29 | 2017-01-25 | 佛山市高明区尚润盈科技有限公司 | Anticorrosion coating preparing method |
| CN106189717A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区尚润盈科技有限公司 | A kind of preparation method of photochromic anticorrosive paint |
| CN106543875A (en) * | 2016-10-26 | 2017-03-29 | 中国科学院长春应用化学研究所 | A kind of high temperature resistant Graphene anticorrosive paint composition |
| CN106543875B (en) * | 2016-10-26 | 2019-05-24 | 中国科学院长春应用化学研究所 | A kind of high temperature resistant graphene anticorrosive paint composition |
| CN108610665A (en) * | 2016-12-02 | 2018-10-02 | 张连瑞 | A kind of preparation method of pylon anticorrosive coating |
| CN108610690A (en) * | 2016-12-05 | 2018-10-02 | 赵中华 | A method of it is fire-retardant for electric wire |
| CN108610912A (en) * | 2016-12-09 | 2018-10-02 | 天津安南科技有限公司 | A kind of coating electronic device new material and preparation method thereof |
| CN106871705A (en) * | 2017-02-21 | 2017-06-20 | 广东万家乐燃气具有限公司 | A kind of etch-proof heat exchanger preparation method with Graphene diaphragm of heat transfer efficient |
| CN109839024A (en) * | 2017-09-29 | 2019-06-04 | 中国石油化工股份有限公司 | One kind being used for CO2The plate heat exchanger and its preparation method of trapping |
| CN108006330A (en) * | 2017-11-13 | 2018-05-08 | 武汉中电节能有限公司 | A kind of energy-efficient long distance delivery heat supply network method |
| CN108148482A (en) * | 2017-12-15 | 2018-06-12 | 浙江海洋大学 | Anticorrosive paint peculiar to vessel and preparation method thereof |
| CN108047885A (en) * | 2017-12-25 | 2018-05-18 | 北京欧美中科学技术研究院 | A kind of pipeline anti-corrosive paint |
| CN108047885B (en) * | 2017-12-25 | 2020-06-30 | 北京欧美中科学技术研究院 | Pipeline anticorrosive paint |
| CN108676461A (en) * | 2018-05-04 | 2018-10-19 | 砺剑防务技术集团有限公司 | Poly- silicon ceramic high-temperature resistant anticorrosive paint and preparation method thereof |
| CN108913021A (en) * | 2018-07-25 | 2018-11-30 | 远科秦皇岛节能环保科技开发有限公司 | A kind of preparation method of the dilute composite material film of superhigh temperature graphite |
| CN109627901A (en) * | 2018-12-06 | 2019-04-16 | 安徽超哥精密科技有限公司 | A kind of fire-retardant, impact resistance automotive coatings material |
| CN109943196A (en) * | 2019-03-27 | 2019-06-28 | 浙江中科应化科技有限公司 | A kind of heat-resistant antifriction type nano hybridization epoxy coating |
| CN110218469B (en) * | 2019-06-25 | 2021-04-20 | 东方电气集团东方汽轮机有限公司 | High-temperature-resistant graphene conductive water-based anticorrosive paint |
| CN110194839A (en) * | 2019-06-25 | 2019-09-03 | 西北师范大学 | A kind of preparation and application of graphene quantum dot/polyphenyl thioether composite material |
| CN110218469A (en) * | 2019-06-25 | 2019-09-10 | 东方电气集团东方汽轮机有限公司 | A kind of high temperature resistant graphene conductive water-based anticorrosive paint |
| CN110760232A (en) * | 2019-10-26 | 2020-02-07 | 维新制漆（江西）有限公司 | Nano silicon-carbon modified graphene special anticorrosive paint and preparation method thereof |
| CN111876072A (en) * | 2020-07-07 | 2020-11-03 | 无锡中油瑞德防腐科技有限公司 | Graphene modified polyphenylene sulfide water-based paint and preparation method thereof |
| CN113773720A (en) * | 2021-09-10 | 2021-12-10 | 南京卓煌工业技术有限公司 | Storage tank base composite anticorrosive material and method |
| CN115746649A (en) * | 2022-10-27 | 2023-03-07 | 武汉纺织大学 | Anticorrosive paint for metal and preparation and application thereof |
| CN116535929A (en) * | 2023-04-03 | 2023-08-04 | 百氏高涂料（苏州）有限公司 | Graphene high-temperature-resistant and oxidation-resistant water-based paint and preparation method thereof |
| CN117511391A (en) * | 2024-01-08 | 2024-02-06 | 浙江德力装备有限公司 | Electrostatic spraying composition and preparation method and application thereof |
| CN117511391B (en) * | 2024-01-08 | 2024-04-16 | 浙江德力装备有限公司 | Electrostatic spraying composition and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103589281B (en) | 2015-09-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103589281B (en) | A kind of fire-resistant anticorrosion paint based on Graphene and preparation method thereof | |
| CN103740192B (en) | A kind of fluorine resin coating of Graphene modification | |
| CN103614071B (en) | A kind of pipeline outer wall organosilicon anticorrosion paint of resistance to 800 DEG C of high temperature and preparation method | |
| CN107916047A (en) | Graphene anticorrosive paint and preparation method | |
| CN105713481B (en) | A kind of graphene modified epoxy zinc rich primer and preparation method thereof | |
| CN103205181B (en) | A kind of nanometer heavy-duty coating | |
| CN103122197A (en) | Resin-based flexible ceramic protective coating | |
| CN102134444A (en) | Temperature-resistance thermal-insulation heavy-duty anticorrosion coating | |
| CN103214914B (en) | A kind of nanometer heavy-duty coating | |
| CN102382554A (en) | Heat preservation and insulation heavy duty anti-corrosion coating with low thermal conductivity and preparation method thereof | |
| CN107974195A (en) | A kind of titanium alloy high-bond high-temperature-resistant insulating paint and preparation method thereof | |
| CN109897532A (en) | A kind of graphene coating material and preparation method thereof protected in advance for four main tubes of boiler high temperature corrosion | |
| CN105778709A (en) | Electrostatic conductive and corrosion-resistant epoxy resin-graphene coating and preparation method thereof | |
| CN108395808A (en) | A kind of high heat conductance high temperature resistant heavy anti-corrosion paint and preparation method thereof | |
| CN104962121A (en) | High-temperature-resistant and anticorrosive composite ceramic coating | |
| CN110183934A (en) | A kind of wear-resisting type bi-component graphene anticorrosive paint | |
| CN103305094A (en) | Composite organic coating based on phenolic epoxy vinyl resin and preparation method thereof | |
| CN102051107B (en) | Light-colored thick paste type epoxy static conductive anticorrosive paint and preparation method thereof | |
| CN103214655B (en) | Modified epoxy resin and high-solid anticorrosive coating prepared therewith | |
| CN110467837A (en) | A kind of graphene inorganic phosphate aluminium paint and its coating production | |
| CN103665875B (en) | A kind of preparation method of conductive silicon rubber | |
| CN103788727A (en) | Protective paint for steel structure surface and preparation method thereof | |
| Gao et al. | Bifunctional oxygen-vacancy abundant perovskite nanosheets for improving protective performance of epoxy coatings | |
| CN103275671A (en) | Flame-retardant and heat-conducting organosilicone pouring sealant for carbon nano tube | |
| CN105925135A (en) | Heat dissipation powder coating for engine surface layer and preparation method of heat dissipation powder coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150909 Termination date: 20181104 |