CN108944111A - The notebook decoration transfer printing foil of high temperature resistant toughness - Google Patents
The notebook decoration transfer printing foil of high temperature resistant toughness Download PDFInfo
- Publication number
- CN108944111A CN108944111A CN201810814065.8A CN201810814065A CN108944111A CN 108944111 A CN108944111 A CN 108944111A CN 201810814065 A CN201810814065 A CN 201810814065A CN 108944111 A CN108944111 A CN 108944111A
- Authority
- CN
- China
- Prior art keywords
- parts
- polymerizable monomer
- resin
- high temperature
- notebook
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The present invention provides a kind of notebook decoration transfer printing foil of high temperature resistant toughness, the chromatograph is in percentage by weight, including following component: 30-50 parts of thermoplastic resin, 30-40 parts of soluble polyamide resin, it is halogen-free 25-35 parts of epoxy resin of atom, 20-40 parts of polyfunctional group methacrylate, raw 40-70 parts of matter plasticiser, 10-15 parts of thermal polymerization, 20-30 parts of polymerizable monomer, 1-10 parts of phosphorus flame retardant, 15-30 parts of paraffin, 20-50 parts of hydroxymethyl cellulose, 1-20 parts of butanone, wherein thermoplastic resin is the polyvinyl chloride and its derivative that glass transition temperature (Tg) is 140 DEG C or more, thermal polymerization is when being measured with the acetonitrile solution of 0.1 mass %, absorbance under 380nm is 0.4 or more thermal polymerization.Using the peeling layer being newly formulated, preferable adhesive force is all had on different substrate materials, is combined using the suitable resin of adhesive force and very brittle resin, and the ability for making it possess good adhesive force and the fine lines of thermoprint.
Description
Technical field
The present invention relates to a kind of decoration transfer printing foil more particularly to a kind of notebook decoration transfer printing foils of high temperature resistant toughness.
Background technique
Film interior trim technique is widely used in high-tech industry (automobile, laptop, electronic equipment), relative to spray painting
Technique, more environmentally-friendly, technique is more stable and appearance decorative pattern is alternative more.With development in science and technology, people increasingly favor machine
Body is frivolous, the swift and fierce laptop of appearance corner angle.
Laptop currently on the market is decorated with spray painting, transfer decorative technique in metal finishing and film.Relative to
Spray painting and metal finishing, transfer decorative technique is more environmentally-friendly in film, and design more diversification, three-dimensional sense is stronger, has very big
The requirement for meeting stylishness is gone in space.Relative to spray painting product, transfer decorative handicraft product is in adhesive force and persistence in film
Aspect has apparent advantage.Relative to metal finishing technique, transfer decorative has bigger space to go to meet people to light in film
The requirement of thin fuselage.
These requirements are the tests to film interior trim technique, need preferably to think deeply how to balance frivolous fuselage, swift and fierce
Contradiction between lines and the performance of film interior trim process film, frivolous material, which may cause, breaks showing for ink in injection moulding process
As swift and fierce lines, which may cause, starts have the phenomenon that red ink when injection molding.Need to research and develop the more stable and more flexible film of performance
Interior trim film, goes to meet that market is more frivolous, and the requirement of more swift and more fierce lines needs to have anti-well with stylish ink coating
High temperature and high pressure performance.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of notebook decoration transfer printing foil of high temperature resistant toughness, using new
The chromatograph of formula can be used for decorating the notebook product that there is most harsh geometry to design, with stylish ink coating
It needs that there is good resistant to high temperatures and high-voltage performance, even if under the environment of high temperature and humidity, also not generated color not
, the decoration transfer printing foil of light leakage, specifically adopts the following technical scheme that
A kind of notebook decoration transfer printing foil of high temperature resistant toughness, including base membrane layer, peeling layer, chromatograph, the aluminium coated being sequentially overlapped
And adhesive layer, the chromatograph in percentage by weight, including following component:
30-50 parts of thermoplastic resin, 30-40 parts of soluble polyamide resin, 20-40 parts of simple function group methacrylate, life
40-70 parts of matter plasticiser, 1-5 parts of heat stabilizer, 10-15 parts of thermal polymerization, 20-30 parts of polymerizable monomer, phosphorous flame-retardant
1-10 parts of agent, 15-30 parts of modified polyether, 1-5 parts of cyanate, 5-20 parts of hindered phenol, 10-30 parts of zinc oxide, atoleine 1-3
Part, 5-10 parts of auxiliary agent, wherein simple function group methacrylate contains 2 or more aromatic rings, sulphur atom or bromine atom.
Further, the polymerizable monomer ingredient includes selected from 1 polymerizable functional groups group and 1 or more hydroxyl
At least the one of the polymerizable monomer (A) of base, the polymerizable monomer (B) with acidic-group and bridging property polymerizable monomer (C)
The polymerizable monomer of kind forms.
The thermoplastic resin that chromatograph uses in the present invention, can be improved the compatibility of chromatograph and peeling layer, so that chromatograph has
There is preferable engineering properties, used raw matter plasticiser can absorb for human body and non-hazardous plasticiser.
The present invention, which is reacted by the amino in polyamide with other groups, shows cementability, starts simultaneously to be formed admittedly
Compound can obtain the high adhesiveness for adherend.
If the content of phosphorus flame retardant is less than 1 mass parts, anti-flammability is become inadequate sometimes, on the other hand, if super
10 mass parts are crossed, cementability, flexibility and solder heat resistance reduce sometimes.
The present invention forms brittle resin by polyfunctional group methacrylate, polymerization initiator and polymerizable monomer,
It is combined using the suitable resin of adhesive force and very brittle resin, improves chromatograph brittleness and will not influence chromatograph and aluminium coated
And releasing layer binding force, the ability and large area that blanching foil can be made to have the fine lines of thermoprint on the spot, can be obtained effectively
The less residues of the low boilers such as excellent heat resistance, solvent, unreacted monomer, the small solidified resin forming of phase difference in face
Body.
Polymerizable monomer (B) of the invention, while can be with due to polymerizable group, being able to carry out free radical polymerization
Other monomers are copolymerized, as the polymerizable monomer (B) of the hydroxyl with 1 polymerizable group and 1 or more, without spy
It does not limit, the polymerizable group of polymerizable monomer (B) is preferably able to carry out free radical with the polymerizable group of polymerizable monomer (A)
The group of copolymerization.From the viewpoint of being easy from free radical polymerization, polymerizable group preferably (methyl) propiono, or (methyl) propylene
Amide groups.
It also include a heat stabilizer in chromatograph of the present invention, which includes at least one as composed by following group
Compound: zinc stearate and calcium stearate.By total usage amount of the chromatograph be 100 parts by weight in terms of, the usage amount of the heat stabilizer
Range is 1 parts by weight to 5 parts by weight.The heat stabilizer can inhibit thermoplastic resin during following process and thermal cracking occur
Problem.The usage amount of the heat stabilizer is less than 1 parts by weight, and it is not easy to operate and be restricted to will lead to following process process, and the heat
The usage amount of stabilizer is greater than 5 parts by weight, will lead to that subsequent to be formed by chromatograph engineering properties bad.
Simple function group methacrylate used in the present invention, it is former containing 2 or more aromatic rings, sulphur atom or bromine
Son.Aromatic rings, sulphur atom, bromine atom be the higher structure of refractive index, be easily guided into the structure of acrylic monomers, by by these
Structure imports the side chain of acrylic resin, and the birefringent ingredient generated when integrally applying stress to chromatograph can be made in stretching side
Preferably rise to the refractive index efficiency of side, inhibits light leakage, even if under the environment of high temperature and humidity, also not generated
The decoration transfer printing foil of irregular colour, light leakage.
Specific embodiment
A kind of preferred embodiment of the invention is described in detail below.
The present invention provides a kind of notebook decoration transfer printing foil of high temperature resistant toughness, which includes successively folding from inside to outside
Base membrane layer 1, peeling layer 2, chromatograph, aluminium coated and the adhesive layer added, is newly formulated using chromatograph, even if in high temperature, the ring of high humidity
Under border, the decoration transfer printing foil of irregular colour, light leakage is not generated yet.
Embodiment 1
The chromatograph in percentage by weight, including following component:
30 parts of thermoplastic resin, 30 parts of soluble polyamide resin, 20 parts of simple function group methacrylate, raw matter plasticiser 40
Part, 1 part of heat stabilizer, 10 parts of thermal polymerization, 20 parts of polymerizable monomer, 1 part of phosphorus flame retardant, 15 parts of modified polyether, cyanogen
1 part of acid esters, 5 parts of hindered phenol, 10 parts of zinc oxide, 1 part of atoleine, 5 parts of auxiliary agent, wherein simple function group methacrylate contains
2 aromatic rings.
The polymerizable monomer ingredient is the polymerizable monomer with 1 polymerizable functional groups group and 1 or more hydroxyl
(A)。
Embodiment 2
The chromatograph in percentage by weight, including following component:
50 parts of thermoplastic resin, 40 parts of soluble polyamide resin, 40 parts of simple function group methacrylate, raw matter plasticiser 70
Part, 5 parts of heat stabilizer, 15 parts of thermal polymerization, 30 parts of polymerizable monomer, 10 parts of phosphorus flame retardant, 30 parts of modified polyether, cyanogen
5 parts of acid esters, 20 parts of hindered phenol, 30 parts of zinc oxide, 3 parts of atoleine, 10 parts of auxiliary agent, wherein simple function group methacrylate contains
There are 2 sulphur atoms.
The polymerizable monomer ingredient is the polymerizable monomer (B) with acidic-group.
Embodiment 3
The chromatograph in percentage by weight, including following component:
40 parts of thermoplastic resin, 35 parts of soluble polyamide resin, 30 parts of simple function group methacrylate, raw matter plasticiser 55
Part, 3 parts of heat stabilizer, 12 parts of thermal polymerization, 25 parts of polymerizable monomer, 5 parts of phosphorus flame retardant, 22 parts of modified polyether, cyanogen
2 parts of acid esters, 12 parts of hindered phenol, 20 parts of zinc oxide, 2 parts of atoleine, 7 parts of auxiliary agent, wherein simple function group methacrylate contains
There are 2 bromine atoms.
The polymerizable monomer ingredient is bridging property polymerizable monomer (C).
Embodiment 4
The chromatograph in percentage by weight, including following component:
40 parts of thermoplastic resin, 35 parts of soluble polyamide resin, 30 parts of simple function group methacrylate, raw matter plasticiser 55
Part, 3 parts of heat stabilizer, 12 parts of thermal polymerization, 25 parts of polymerizable monomer, 5 parts of phosphorus flame retardant, 22 parts of modified polyether, cyanogen
2 parts of acid esters, 12 parts of hindered phenol, 20 parts of zinc oxide, 2 parts of atoleine, 7 parts of auxiliary agent, wherein simple function group methacrylate contains
There are 2 bromine atoms.
The polymerizable monomer ingredient includes the polymerism list with 1 polymerizable functional groups group and 1 or more hydroxyl
Three kinds of polymerizable monomers of body (A), the polymerizable monomer (B) with acidic-group and bridging property polymerizable monomer (C) are mixed
It closes.
Embodiment described above is only that preferred embodiments of the present invention will be described, not to model of the invention
It encloses and is defined, without departing from the spirit of the design of the present invention, those of ordinary skill in the art are to technical side of the invention
The various changes and improvements that case is made, should fall within the scope of protection determined by the claims of the present invention.
Claims (2)
1. a kind of notebook decoration transfer printing foil of high temperature resistant toughness, including be sequentially overlapped base membrane layer, peeling layer, chromatograph, aluminize
Layer and adhesive layer, which is characterized in that the chromatograph in percentage by weight, including following component:
30-50 parts of thermoplastic resin, 30-40 parts of soluble polyamide resin, 20-40 parts of simple function group methacrylate, life
40-70 parts of matter plasticiser, 1-5 parts of heat stabilizer, 10-15 parts of thermal polymerization, 20-30 parts of polymerizable monomer, phosphorous flame-retardant
1-10 parts of agent, 15-30 parts of modified polyether, 1-5 parts of cyanate, 5-20 parts of hindered phenol, 10-30 parts of zinc oxide, atoleine 1-3
Part, 5-10 parts of auxiliary agent, wherein simple function group methacrylate contains 2 or more aromatic rings, sulphur atom or bromine atom.
2. the notebook decoration transfer printing foil of high temperature resistant toughness according to claim 1, which is characterized in that the polymerism list
Body ingredient includes being selected from 1 polymerizable functional groups group with the polymerizable monomer (A) of 1 or more hydroxyl, with acidic groups
The polymerizable monomer (B) of group and at least one polymerizable monomer of bridging property polymerizable monomer (C) form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810814065.8A CN108944111A (en) | 2018-07-23 | 2018-07-23 | The notebook decoration transfer printing foil of high temperature resistant toughness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810814065.8A CN108944111A (en) | 2018-07-23 | 2018-07-23 | The notebook decoration transfer printing foil of high temperature resistant toughness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108944111A true CN108944111A (en) | 2018-12-07 |
Family
ID=64463563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810814065.8A Pending CN108944111A (en) | 2018-07-23 | 2018-07-23 | The notebook decoration transfer printing foil of high temperature resistant toughness |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108944111A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112063317A (en) * | 2020-08-03 | 2020-12-11 | 昆山市生力包装材料有限公司 | Electrochemical aluminum for flame-retardant cigarettes and preparation process thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20181207 |