CN107116946A - Light-cured type automotive trim transfer foil - Google Patents
Light-cured type automotive trim transfer foil Download PDFInfo
- Publication number
- CN107116946A CN107116946A CN201710314984.4A CN201710314984A CN107116946A CN 107116946 A CN107116946 A CN 107116946A CN 201710314984 A CN201710314984 A CN 201710314984A CN 107116946 A CN107116946 A CN 107116946A
- Authority
- CN
- China
- Prior art keywords
- parts
- light
- layer
- transfer foil
- automotive trim
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1729—Hot stamping techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention provides a kind of curing type automotive trim transfer foil, its decorative layer includes magnetosphere, chromatograph, substrate layer and the ductile bed for being sequentially overlapped setting, the different vapor deposited metal layers of at least two colors are provided with phase the same side of the ductile bed, the peel ply includes following component：30 parts~50 parts of water-soluble organic silicon resin, 20 parts~40 parts of edible vegetable oil ethyl ester, 15 parts~30 parts of paraffin, 20 parts~50 parts of hydroxymethyl cellulose, 1 part~20 parts of butanone, 5 parts~20 parts of acrylate monomer, by weight percentage.The present invention reach can free deisgn product surface glossiness, do the purpose of the surface picture and text effect of the mute combination of light extraction, new peel ply has no effect on the recoatability of follow-up coating with the complete adhesion of decorative layer, and the adhesion property of the peel ply and PET printing elements is very good.
Description
Technical field
The present invention relates to a kind of interior trim transfer foil, more particularly to a kind of thermoprint for automotive trim part product surface,
The mute degree of surface light and the mute pattern of light brought with photocurable layers.
Background technology
Stamping systems hot stamping technology is a kind of specialty printing technique without ink, and it is by certain pressure and temperature, fortune
With the masterplate on thermoprinting machine, printed matter and stamping systems is pressurized mutually in a short time, by metal foil or pigment foil according to
The picture and text of thermoprint masterplate are transferred to by the surface of boiling hot printed matter.It is clear, beautiful that product pattern after being processed by hot stamping process has
See, the characteristic such as wear-resisting, weather-proof, and the class of product can be lifted.
Along with the fierceness of product competition, the material of packaging increasingly enriches, existing with photocuring protective layer
Automotive trim type IMD film, with good case hardness, compared with the type IMD film of ordinary hot curing protective coat, scratch-resistant, chemical resistance
Deng all having a clear superiority, application is also increasingly extensive.But it is due to not develop suitable peel ply, it is impossible to freely design
The glossiness of product surface, can not do the surface effect of the mute combination of light extraction.The combination with decorative surfaces of present automotive trim is more and more individual
Property, design becomes increasingly complex, customer requirement can not be met sometimes, makes its application limited.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of light-cured type automotive trim transfer foil, using what is be newly formulated
Peel ply, is used cooperatively with photocurable layers, reach can free deisgn product surface glossiness, do the surface of the mute combination of light extraction
Picture and text effect, is specifically adopted the following technical scheme that：
A kind of light-cured type automotive trim transfer foil, including base membrane layer, peel ply, light curing resin layer, the decoration being sequentially overlapped
Layer, aluminium coated and adhesive layer, the decorative layer include magnetosphere, chromatograph, substrate layer and the ductile bed for being sequentially overlapped setting, the modeling
Property layer phase the same side on be provided with the different vapor deposited metal layers of at least two colors, the peel ply includes such as the following group
Point：
30 parts~50 parts of water-soluble organic silicon resin, 20 parts~40 parts of edible vegetable oil ethyl ester, 15 parts~30 parts of paraffin, hydroxymethyl cellulose
20 parts~50 parts, 1 part~20 parts of butanone, 5 parts~20 parts of acrylate monomer, by weight percentage.
Further, the chromatograph is made up of the component of following weight fraction：
60~100 parts of polyamide-imide resin, 15 parts~30 parts of modified polyether, 1 part~5 parts of cyanate, BMI
15 parts~25 parts, 5 parts~20 parts of hindered phenol, 10 parts~30 parts of zinc oxide, 1 part~3 parts of atoleine, 5~10 parts of auxiliary agent, wherein
The isocyanate functional group of the molecular end of polyamide-imide resin is closed agent closing, and the modified polyether is to contain carboxyl
Or the polyethers of 2- ammonia propoxyl group.
Preferably, the light curing resin layer is using UV light oil reservoirs, its smooth bright surface layer or with certain roughness
Mute surface layer.
Preferably, the opposite side of the ductile bed is provided with the vapor deposited metal layers of the third color.
Preferably, the surface of the vapor deposited metal layers is rough diffraction structure.
For peel ply, single paraffin before having abandoned, then use water-soluble organic silicon resin, edible vegetable oil ethyl ester and stone
Wax is mixed according to certain ratio, mixed using this due to the soluble characteristic of water-soluble organic silicon resin and edible vegetable oil ethyl ester
Compound can both keep effective stripping performance, and the effect due to paraffin after stripping can form diaphragm, play guarantor
The effect of sheath, with satisfied Scratch Resistance energy, and can make fine pattern svelteness, not scumming.Using methylol
Cellulose can provide adhesive force and protection intensity.
From above technical scheme, the present invention reach can free deisgn product surface glossiness, do the mute knot of light extraction
The purpose of the surface picture and text effect of conjunction, new peel ply has no effect on the recoating of follow-up coating with the complete adhesion of decorative layer
Property, the adhesion property of the peel ply and PET printing elements is very good, under the conditions of injection limit high pressure-temperature（50 ° of mold temperature
C +10°C；Melt glue temperature：250°C–270°C）Will not softening and shedding, the technical indicator such as adhesive force and splitting meets related
Detection requirement, splitting index 18cN, adhesive force >=96%；This peels off layer film and has high-fire resistance and pliability, levelability concurrently
Good, the mute pattern of article surface light after injection is not cracked, and does not fall off, smooth attractive in appearance；Decorative layer is sunk using the gas phase of different colours
Product metal level carries out vision differentiation, and the anti-counterfeiting performance of product is together improved with the identification function of liquid crystal layer.
Brief description of the drawings
Fig. 1 is layer structure schematic diagram of the invention.
Embodiment
A kind of preferred embodiment to the present invention is described in detail below in conjunction with the accompanying drawings.
The present invention provides a kind of light-cured type automotive trim transfer foil, and reference picture 1, the stamping systems is included from inside to outside successively
Base membrane layer 1, peel ply 2, light curing resin layer 3, decorative layer 4, aluminium coated 5 and the adhesive layer 6 of superposition, the decorative layer include
It is sequentially overlapped on magnetosphere 41, chromatograph 42, substrate layer 43 and the ductile bed 44 of setting, phase the same side of the ductile bed and is provided with least
The different vapor deposited metal layers of two colors.
The light curing resin layer 3 uses UV light oil reservoirs, its smooth bright surface layer or the mute surface layer with certain roughness.
Two different vapor deposited metal layers of color 441,442 are provided with phase the same side of the ductile bed 44, two gas phases are sunk
Product metal level can be spaced, and can also be connected, the opposite side for stating ductile bed is provided with the vapor deposited metal layers of the third color
443, two vapor deposited metal layers of the 3rd vapor deposited metal layers 343 and homonymy are staggeredly arranged.Three vapor deposition of gold
The color of category layer can be distinguished, and had the identification thing such as alphanumeric, figure in metal level, formed on the surface of vapor deposited metal layers
Rough diffraction structure.
Embodiment 1
The peel ply includes following component：
30 parts of water-soluble organic silicon resin
20 parts of edible vegetable oil ethyl ester
15 parts of paraffin
20 parts of hydroxymethyl cellulose
1 part of butanone
5 parts of acrylate monomer.
The chromatograph is made up of the component of following weight fraction：
60 parts of polyamide-imide resin；
15 parts of modified polyether；
1 part of cyanate；
15 parts of BMI；
5 parts of hindered phenol；
10 parts of zinc oxide；
1 part of atoleine；
5 parts of antioxidant.
Embodiment 2
The peel ply includes following component：
50 parts of water-soluble organic silicon resin
40 parts of edible vegetable oil ethyl ester
30 parts of paraffin
50 parts of hydroxymethyl cellulose
20 parts of butanone
20 parts of acrylate monomer.
The chromatograph is made up of the component of following weight fraction：
100 parts of polyamide-imide resin；
30 parts of modified polyether；
5 parts of cyanate；
25 parts of BMI；
20 parts of hindered phenol；
30 parts of zinc oxide；
3 parts of atoleine；
10 parts of toughener.
Embodiment 3
The peel ply includes following component：
40 parts of water-soluble organic silicon resin
30 parts of edible vegetable oil ethyl ester
25 parts of paraffin
35 parts of hydroxymethyl cellulose
10 parts of butanone
15 parts of acrylate monomer.
The chromatograph is made up of the component of following weight fraction：
80 parts of polyamide-imide resin；
25 parts of modified polyether；
3 parts of cyanate；
20 parts of BMI；
15 parts of hindered phenol；
20 parts of zinc oxide；
2 parts of atoleine；
8 parts of inorganic reinforcement.
Using water-soluble organic silicon resin, the mixture that edible vegetable oil ethyl ester and paraffin are drawn according to certain ratio, with compared with
Good peel strength, the mixture can both keep effective stripping performance, and the diaphragm formed after stripping plays guarantor
The effect of sheath, and fine pattern svelteness can be made, not scumming.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention
Enclose and be defined, on the premise of design spirit of the present invention is not departed from, technical side of the those of ordinary skill in the art to the present invention
In various modifications and improvement that case is made, the protection domain that claims of the present invention determination all should be fallen into.
Claims (5)
1. a kind of light-cured type automotive trim transfer foil, including base membrane layer, peel ply, light curing resin layer, the dress being sequentially overlapped
Adorn layer, aluminium coated and adhesive layer, it is characterised in that the decorative layer includes the magnetosphere, chromatograph, substrate layer for being sequentially overlapped setting
And ductile bed, the different vapor deposited metal layers of at least two colors, the stripping are provided with phase the same side of the ductile bed
Layer includes following component：
30 parts~50 parts of water-soluble organic silicon resin, 20 parts~40 parts of edible vegetable oil ethyl ester, 15 parts~30 parts of paraffin, hydroxymethyl cellulose
20 parts~50 parts, 1 part~20 parts of butanone, 5 parts~20 parts of acrylate monomer, by weight percentage.
2. light-cured type automotive trim transfer foil according to claim 1, it is characterised in that the chromatograph is by following weight
The component of fraction is made：
60~100 parts of polyamide-imide resin, 15 parts~30 parts of modified polyether, 1 part~5 parts of cyanate, BMI
15 parts~25 parts, 5 parts~20 parts of hindered phenol, 10 parts~30 parts of zinc oxide, 1 part~3 parts of atoleine, 5~10 parts of auxiliary agent, wherein
The isocyanate functional group of the molecular end of polyamide-imide resin is closed agent closing, and the modified polyether is to contain carboxyl
Or the polyethers of 2- ammonia propoxyl group.
3. light-cured type automotive trim transfer foil according to claim 1, it is characterised in that the light curing resin layer is adopted
UV light oil reservoirs are used, its smooth bright surface layer or the mute surface layer with certain roughness.
4. light-cured type automotive trim transfer foil according to claim 1, it is characterised in that the opposite side of the ductile bed
It is provided with the vapor deposited metal layers of the third color.
5. light-cured type automotive trim transfer foil according to claim 1, it is characterised in that the vapor deposited metal layers
Surface be rough diffraction structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710314984.4A CN107116946A (en) | 2017-05-07 | 2017-05-07 | Light-cured type automotive trim transfer foil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710314984.4A CN107116946A (en) | 2017-05-07 | 2017-05-07 | Light-cured type automotive trim transfer foil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107116946A true CN107116946A (en) | 2017-09-01 |
Family
ID=59727540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710314984.4A Pending CN107116946A (en) | 2017-05-07 | 2017-05-07 | Light-cured type automotive trim transfer foil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107116946A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108944111A (en) * | 2018-07-23 | 2018-12-07 | 库尔兹压烫科技（合肥）有限公司 | The notebook decoration transfer printing foil of high temperature resistant toughness |
| CN110588226A (en) * | 2019-09-04 | 2019-12-20 | 广州市盛勤实业有限公司 | Industrial washing-resistant gold stamping film and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN200995575Y (en) * | 2006-12-18 | 2007-12-26 | 汕头市东田转印有限公司 | Transfer film with decorative-layer protection |
| CN101941339A (en) * | 2009-07-06 | 2011-01-12 | 珠海东诚光固化材料有限公司 | Ultraviolet light cured transfer printing film and preparation method and application thereof |
| JP2011005677A (en) * | 2009-06-24 | 2011-01-13 | Dainippon Printing Co Ltd | Transfer sheet |
| CN103921583A (en) * | 2014-04-09 | 2014-07-16 | 库尔兹压烫科技（合肥）有限公司 | Novel efficient hot-stamping foil |
| CN203844435U (en) * | 2014-05-15 | 2014-09-24 | 库尔兹压烫科技（合肥）有限公司 | Anti-scrubbing wood grain hot stamping foil |
| CN204605245U (en) * | 2015-04-16 | 2015-09-02 | 库尔兹压烫科技（合肥）有限公司 | A kind of decoration transfer printing paper tinsel |
| CN204659235U (en) * | 2015-04-08 | 2015-09-23 | 江***力汽车装备有限公司 | A kind of stamping systems |
-
2017
- 2017-05-07 CN CN201710314984.4A patent/CN107116946A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN200995575Y (en) * | 2006-12-18 | 2007-12-26 | 汕头市东田转印有限公司 | Transfer film with decorative-layer protection |
| JP2011005677A (en) * | 2009-06-24 | 2011-01-13 | Dainippon Printing Co Ltd | Transfer sheet |
| CN101941339A (en) * | 2009-07-06 | 2011-01-12 | 珠海东诚光固化材料有限公司 | Ultraviolet light cured transfer printing film and preparation method and application thereof |
| CN103921583A (en) * | 2014-04-09 | 2014-07-16 | 库尔兹压烫科技（合肥）有限公司 | Novel efficient hot-stamping foil |
| CN203844435U (en) * | 2014-05-15 | 2014-09-24 | 库尔兹压烫科技（合肥）有限公司 | Anti-scrubbing wood grain hot stamping foil |
| CN204659235U (en) * | 2015-04-08 | 2015-09-23 | 江***力汽车装备有限公司 | A kind of stamping systems |
| CN204605245U (en) * | 2015-04-16 | 2015-09-02 | 库尔兹压烫科技（合肥）有限公司 | A kind of decoration transfer printing paper tinsel |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108944111A (en) * | 2018-07-23 | 2018-12-07 | 库尔兹压烫科技（合肥）有限公司 | The notebook decoration transfer printing foil of high temperature resistant toughness |
| CN110588226A (en) * | 2019-09-04 | 2019-12-20 | 广州市盛勤实业有限公司 | Industrial washing-resistant gold stamping film and preparation method thereof |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170901 |
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| RJ01 | Rejection of invention patent application after publication |