CN110482859B - Starlight glaze ceramic tile and preparation method thereof - Google Patents
Starlight glaze ceramic tile and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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Abstract
The invention discloses a starlight glaze ceramic tile which comprises a blank layer, a ground glaze layer, a color development glaze layer and a dry particle glaze layer from bottom to top. The preparation method comprises the following steps: (1) pressing the powder into a green body, and drying the green body at 145-160 ℃ for 1-1.5 hours; (2) cleaning the surface of the green body, and spraying water on the surface of the green body to wet the surface of the green body; (3) applying a base coat on the surface of the blank; (4) using screen printing colored glaze; (5) ink-jet printing a pattern; (6) applying transparent bright dry particles on the surface of the brick; (7) firing the blank body obtained in the step (5) in a kiln at 1150-1200 ℃ for 40-60 minutes; (8) and (2) soft polishing is carried out on the transparent bright dry particles protruding on the surface of the fired ceramic tile to obtain the starlight glaze ceramic tile, the protruding surface of the ceramic tile is fine, smooth and soft, but the whole ceramic tile has a shining starlight effect, the pattern definition is good, the product has aesthetic feeling, and the blank of the product in the market is filled.
Description
Technical Field
The invention relates to the technical field of ceramic tile preparation, in particular to a starlight glaze ceramic tile and a preparation method thereof.
Background
With the rapid development of economy and the continuous improvement of living standard of people, consumers begin to have higher requirements on the decoration effect of indoor environment. At present, ceramic tiles in the ceramic building industry are in various categories: polished tiles, archaized tiles, tile tiles, dry grain glazed tiles, full glazed tiles, diamond glazed tiles, and the like. The ceramic tiles of the above categories have various characteristics, and meet different requirements of consumers to a certain extent. However, the products fill the market for many years, the products have single appearance effect and serious homogenization phenomenon, consumers are gradually in aesthetic fatigue, and new products which are unique and can lead trend are lacked in the market.
Accordingly, the prior art is in need of improvement and development.
Disclosure of Invention
The invention aims to provide a starlight glaze ceramic tile and a preparation method thereof, and aims to solve the technical problems that the existing ceramic tile products on the market are single in display effect, serious in homogenization phenomenon and lack of novel products which are unique and can lead trend in the market.
The technical scheme of the invention is as follows:
a preparation method of starlight glaze ceramic tiles comprises the following steps:
(1) pressing the powder into a green body, and drying the green body at 145-160 ℃ for 1-1.5 hours;
(2) cleaning the surface of the green body, and spraying water on the surface of the green body to wet the surface of the green body;
(3) applying a base coat on the surface of the blank;
(4) using screen printing colored glaze;
(5) ink-jet printing a pattern;
(6) applying transparent bright dry particles on the surface of the brick;
(7) firing the blank body obtained in the step (6) in a kiln at 1150-1200 ℃ for 40-60 minutes;
(8) and (4) carrying out soft polishing on the transparent bright dry particles protruding on the surface of the fired ceramic tile to obtain the starlight glaze ceramic tile.
The preparation method of the starlight glaze ceramic tile comprises the step (6) of uniformly paving transparent bright dry grains in a sand shape on the surface of the ceramic tile.
The preparation method of the starlight glaze ceramic tile comprises the step of (4), wherein the screen used in the step is a 100-mesh all-through screen.
The starlight glaze ceramic tile comprises a blank layer, a ground glaze layer, a color development glaze layer and a dry grain glaze layer from bottom to top, wherein transparent bright dry grains used in the dry grain glaze layer comprise, by weight, 35-40 parts of potassium feldspar, 8-15 parts of calcined talc, 8-12 parts of calcite, 25-35 parts of quartz, 8-12 parts of barium carbonate, 10-15 parts of calcined alumina, 4-8 parts of air knife soil and 1-5 parts of zinc oxide.
The preparation method of the starlight glaze ceramic tile comprises the following steps: the fineness of each raw material is controlled to be 80-200 meshes, the raw materials are uniformly stirred in parts and are put into a frit furnace to be calcined until the raw materials are melted into molten slurry liquid, and the calcination temperature is 1450-1550 ℃; putting the molten slurry liquid into water for quenching, and quenching the molten slurry liquid into a glass molten block shape; and (4) crushing the frits and sieving the frits by a 40-200-mesh sieve to obtain transparent bright dry particles.
The starlight glaze ceramic tile is characterized in that the ground glaze used for the ground glaze layer comprises, by weight, 30-45 parts of potassium feldspar, 20-35 parts of albite, 5-10 parts of air knife soil, 15-25 parts of alumina powder, 3-10 parts of quartz, 1-5 parts of wollastonite, 10-15 parts of zirconium silicate, 0.1-0.4 part of methyl cellulose, 0.3-0.6 part of sodium tripolyphosphate and 38-45 parts of water.
The preparation method of the base glaze of the starlight glaze ceramic tile comprises the following steps: adding the raw materials into a ball mill according to parts, ball-milling for 6-8 hours until the fineness is 325 meshes, the screen residue is 0.7-1.0%, and the specific gravity is as follows: 1.88-1.95 g/ml, carrying out iron removal operation when discharging slurry from the ball mill, and sieving with a 140-mesh sieve.
The starlight glaze ceramic tile is characterized in that the coloring glaze used for the coloring glaze layer comprises, by weight, 30-45 parts of potassium feldspar, 5-15 parts of calcined talc, 5-15 parts of quartz, 10-20 parts of barium carbonate, 5-15 parts of alumina powder, 2-8 parts of zinc oxide, 5-10 parts of air knife soil, 15-20 parts of zirconium silicate, 10-20 parts of water and 60-100 parts of printing paste.
The preparation method of the starlight glaze ceramic tile comprises the following steps: adding the raw materials into a ball mill according to parts by weight, ball-milling for 10-12 hours until the fineness is 325 meshes, the screen residue is 0.1-0.3%, and the specific gravity is as follows: 1.45-1.6 g/ml, carrying out iron removal operation when discharging slurry from the ball mill, and sieving with a 140-mesh sieve.
Has the advantages that:
the application provides a formula and a preparation method of a starlight glaze ceramic tile, the obtained ceramic tile has the advantages that the protruding surface dry particles of the ceramic tile are fine, smooth and soft, the whole ceramic tile has a shining starlight effect, the pattern presented is good in definition, the product has aesthetic feeling, is fresh and decorative, the blank of the products in the existing market can be filled, and the various requirements of consumers are met.
Drawings
Fig. 1 is a cross-sectional schematic view of a starlight glaze ceramic tile structure.
Detailed Description
The technical solution of the present invention is further illustrated by the following preferred examples.
Example 1
The preparation method of the starlight glaze ceramic tile comprises the following steps:
(1) pressing the powder into a green body, and drying the green body at 150 ℃ for 1.5 hours;
(2) cleaning the surface of the green body, and spraying water on the surface of the green body to wet the surface of the green body;
(3) applying a base coat on the surface of the blank;
(4) using screen printing coloring glaze, preferably using 100-mesh full-through net;
(5) ink-jet printing a pattern;
(6) applying transparent bright dry grains on the surface of the brick, preferably uniformly paving the transparent bright dry grains on the surface of the brick in a sand shape;
(7) putting the green body obtained in the step (6) into a kiln for firing at 1150 ℃ for 60 minutes;
(8) and (4) carrying out soft polishing on the transparent bright dry particles protruding on the surface of the fired ceramic tile to obtain the starlight glaze ceramic tile.
The starlight glaze ceramic tile comprises a blank layer, a ground glaze layer, a color development glaze layer and a dry grain glaze layer from bottom to top.
The transparent bright dry granules used for the dry granule glaze layer comprise 38 parts of potassium feldspar, 12 parts of calcined talc, 12 parts of calcite, 33 parts of quartz, 8 parts of barium carbonate, 10 parts of calcined alumina, 5 parts of air knife soil and 3 parts of zinc oxide in parts by weight. The preparation method of the transparent bright dry granules comprises the following steps: the fineness of each raw material is controlled to be 90 meshes, the raw materials are uniformly stirred in parts and are put into a frit furnace to be calcined until the raw materials are melted into molten slurry liquid, and the calcination temperature is 1500 ℃; putting the molten slurry liquid into water for quenching, and quenching the molten slurry liquid into a glass molten block shape; the frits were pulverized and sieved through a 100 mesh sieve to obtain transparent bright dry granules.
The ground glaze used for the ground glaze layer comprises, by weight, 40 parts of potassium feldspar, 30 parts of albite, 8 parts of air knife soil, 20 parts of alumina powder, 8 parts of quartz, 5 parts of wollastonite, 12 parts of zirconium silicate, 0.3 part of methyl cellulose, 0.5 part of sodium tripolyphosphate and 42 parts of water. The preparation method of the ground glaze comprises the following steps: adding the raw materials into a ball mill according to parts by weight, ball-milling for 6 hours until the fineness is 325 meshes, the screen residue is 0.8 percent, and the specific gravity is as follows: 1.89g/ml, iron removal operation is carried out when slurry is discharged from the ball mill, and the slurry is sieved by a 140-mesh sieve.
The coloring glaze used for the coloring glaze layer comprises, by weight, 40 parts of potassium feldspar, 10 parts of calcined talc, 10 parts of quartz, 15 parts of barium carbonate, 10 parts of alumina powder, 6 parts of zinc oxide, 8 parts of air knife soil, 17 parts of zirconium silicate, 15 parts of water and 80 parts of printing paste. The preparation method of the coloring glaze comprises the following steps: adding the raw materials into a ball mill according to parts by weight, ball-milling for 11 hours until the fineness is 325 meshes, the screen residue is 0.2%, and the specific gravity: 1.5g/ml, iron removal operation is carried out when discharging slurry from the ball mill, and the slurry is sieved by a 140-mesh sieve.
Example 2
The preparation method of the starlight glaze ceramic tile is the same as that of the example 1.
The starlight glaze ceramic tile comprises a body layer 1, a bottom glaze layer 2, a color development glaze layer 3 and a dry particle glaze layer 4 from bottom to top, and is shown in figure 1.
The transparent bright dry granules used for the dry granule glaze layer comprise 38 parts of potassium feldspar, 12 parts of calcined talc, 10 parts of calcite, 33 parts of quartz, 10 parts of barium carbonate, 10 parts of calcined alumina, 5 parts of air knife soil and 3 parts of zinc oxide in parts by weight. The preparation method of the transparent bright dry granules is the same as that of example 1.
The formulation and preparation method of the ground coat are the same as in example 1.
The formula and preparation method of the colored glaze are the same as those of the example 1.
Example 3
The preparation method of the starlight glaze ceramic tile is the same as that of the example 1.
The starlight glaze ceramic tile comprises a blank layer, a ground glaze layer, a color development glaze layer and a dry grain glaze layer from bottom to top.
The transparent bright dry granules used for the dry granule glaze layer comprise 38 parts of potassium feldspar, 12 parts of calcined talc, 8 parts of calcite, 33 parts of quartz, 12 parts of barium carbonate, 10 parts of calcined alumina, 5 parts of air knife soil and 3 parts of zinc oxide in parts by weight. The preparation method of the transparent bright dry granules is the same as that of example 1.
The formulation and preparation method of the ground coat are the same as in example 1.
The formula and preparation method of the colored glaze are the same as those of the example 1.
The difference between the examples 1, 2 and 3 lies in that the proportions of calcite and barium carbonate in the transparent glossy dry particle formulas are different, the surfaces of the transparent glossy dry particles prepared in the examples 1, 2 and 3 have glossy luster, the light reflection is good, the wear resistance of the transparent glossy dry particles is tested according to the method specified in the No. 7 (determination of the wear resistance of the surface of a glazed brick) of GB/T3810.7-2006 ceramic brick test method, the wear resistance can reach 4 grades (the wear resistance is graded to 1-5 grades, the 5 grades are the highest wear resistance grades), and the stain resistance is good. Wherein, the Mohs hardness of the examples 1 and 3 reaches 6 grades, the Mohs hardness of the example 2 reaches 7 grades, and the polishing solution can bear fine surface polishing without glaze cracking, and has good surface flatness after polishing and no waves and pores.
In the prior art, for ceramic tiles with concave-convex effect on the surface, the surface effect can be roughly divided into matte and bright, and the general preparation method is to directly spray matte dry particles or bright dry particles on the surface of the ceramic tile. However, the matte dry-grain glazed ceramic tile prepared in the way is fine and soft in surface, but easily appears as unclear patterns and dim and hazy colors. The bright dry glazed ceramic tile prepared in the way is clearer in color and pattern, but is easy to appear poor in texture. Both of these are conventional dry-grain tile products on the market today.
The application provides a technology with "starlight" effect, drenches bright light dry grain promptly on the brick face, transparent bright light dry grain protrusion in the brick face after kiln high temperature calcination, and the pit is then formed to the position between the transparent bright light dry grain, and the totality demonstrates unevenness's bright face, and the size of its degree of consistency and concave-convex pit depends on the distribution and the granularity of transparent bright light dry grain, can look actual conditions design and arrange. And then the convex surface is subjected to soft polishing, the part with the convex dry particles presents delicate and soft matte feeling after the soft polishing, the concave pits which are not polished still present a bright state, and the surface of the finally obtained ceramic tile presents a shining starlight effect, is called as a starlight glaze ceramic tile, has aesthetic feeling, is trendy and good in decoration, and can fill the blank of the products in the current market.
In addition, the applicant has found in practice that when using transparent bright dry granules of smaller particle size, the depth of the soft polishing also has an effect on the starlight effect. For example, using the formulation of example 2, the frit was crushed and sieved through a 200 mesh screen to give clear bright dry pellets, and the fired tile was soft-polished. Because the granularity is small, the throwable part of the transparent bright dry particles protruding out of the brick surface is smaller, and at the moment, if the throwing depth is large, the transparent bright dry particles are easy to throw to the pit, the bright light of the pit is polished to be dumb, and the starlight flickering effect of the spot spots can be weakened. If the polishing is shallow, the surface smoothness of the brick surface is not enough, and the texture is easy to appear poor. Therefore, for the transparent bright dry granules with smaller granularity, attention needs to be paid to soft polishing depth, and pits cannot be polished.
Example 4
The preparation method of the starlight glaze ceramic tile is the same as that of the example 2.
The starlight glaze ceramic tile comprises a body layer 1, a bottom glaze layer 2, a color development glaze layer 3 and a dry particle glaze layer 4 from bottom to top, and is shown in figure 1.
The formulation and preparation method of the transparent bright dry particles used in the dry particle glaze layer are the same as those in example 2.
The ground glaze used for the ground glaze layer comprises, by weight, 40 parts of potassium feldspar, 30 parts of albite, 8 parts of air knife soil, 20 parts of alumina powder, 8 parts of quartz, 1 part of wollastonite, 12 parts of zirconium silicate, 0.3 part of methyl cellulose, 0.5 part of sodium tripolyphosphate and 42 parts of water. The preparation method of the ground coat is the same as that of example 2.
The formula and preparation method of the colored glaze are the same as those of the example 2.
Example 5
The preparation method of the starlight glaze ceramic tile is the same as that of the example 2.
The starlight glaze ceramic tile comprises a body layer 1, a bottom glaze layer 2, a color development glaze layer 3 and a dry particle glaze layer 4 from bottom to top, and is shown in figure 1.
The formulation and preparation method of the transparent bright dry particles used in the dry particle glaze layer are the same as those in example 2.
The ground glaze used for the ground glaze layer comprises, by weight, 40 parts of potassium feldspar, 30 parts of albite, 8 parts of air knife soil, 20 parts of alumina powder, 8 parts of quartz, 6 parts of wollastonite, 12 parts of zirconium silicate, 0.3 part of methyl cellulose, 0.5 part of sodium tripolyphosphate and 42 parts of water. The preparation method of the ground coat is the same as that of example 2.
The formula and preparation method of the colored glaze are the same as those of the example 2.
Comparative example 6
The preparation method of the starlight glaze ceramic tile is the same as that of the example 2.
The starlight glaze ceramic tile comprises a body layer 1, a bottom glaze layer 2, a color development glaze layer 3 and a dry particle glaze layer 4 from bottom to top, and is shown in figure 1.
The formulation and preparation method of the transparent bright dry particles used in the dry particle glaze layer are the same as those in example 2.
The ground glaze used for the ground glaze layer comprises, by weight, 40 parts of potassium feldspar, 30 parts of albite, 8 parts of air knife soil, 20 parts of alumina powder, 8 parts of quartz, 12 parts of zirconium silicate, 0.3 part of methyl cellulose, 0.5 part of sodium tripolyphosphate and 42 parts of water. The preparation method of the ground coat is the same as that of example 2.
The formula and preparation method of the colored glaze are the same as those of the example 2.
Examples 2, 4, 5 and comparative example 6 differ in the content of wollastonite in the matte glaze formulation. Wollastonite contains no volatile component, and has relatively small sintering shrinkage and drying shrinkage during reaction, so that the wollastonite is favorable for quick sintering, and the gas separated from a glaze surface is reduced, thereby reducing the formation of glaze bubbles or pinholes. In the embodiments 2 and 4, 1 part of wollastonite and 5 parts of wollastonite are respectively added, so that the obtained ground coat glaze bubbles or pinholes are greatly reduced, and the coloring uniformity and the conformity of subsequent colored glaze are more favorable, so that the pattern definition of the starlight glaze ceramic tile is better, and the product has perfect aesthetic feeling by matching with a shining starlight effect, and particularly when the starlight glaze ceramic tile is designed into a starry sky pattern, the effect is incomparable with the ordinary bright ceramic tile in the market.
Compared with the comparative example 6, wollastonite is not added, the obtained ground coat has the advantages of general glaze effect flatness, more surface micropores, uneven distribution and unfavorable coloring of subsequent colored glaze.
At the same time, although the applicant found that the addition of wollastonite in the formulation resulted in a better effect of the under-glaze, the applicant found in actual research and development that when the wollastonite content is too large, such as 6 parts of wollastonite in example 5, the glaze had an increased number of micropores (increased means compared with examples 2 and 4). It can be seen that the requirements for the content of wollastonite are relatively stringent when it is used.
The application provides a formula and a preparation method of a starlight glaze ceramic tile, the obtained ceramic tile has the advantages that the protruding surface dry particles of the ceramic tile are fine, smooth and soft, the whole ceramic tile has a shining starlight effect, the pattern presented is good in definition, the product has aesthetic feeling, is fresh and decorative, the blank of the products in the existing market can be filled, and the various requirements of consumers are met.
In summary, although the present invention has been described with reference to the preferred embodiments, the above-described preferred embodiments are not intended to limit the present invention, and those skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention, therefore, the scope of the present invention shall be determined by the appended claims.
Claims (9)
1. The preparation method of the starlight glaze ceramic tile is characterized by comprising the following steps: (1) pressing the powder into a green body, and drying the green body at 145-160 ℃ for 1-1.5 hours; (2) cleaning the surface of the green body, and spraying water on the surface of the green body to wet the surface of the green body; (3) applying a base coat on the surface of the blank; (4) using screen printing colored glaze; (5) ink-jet printing a pattern; (6) applying transparent bright dry particles on the surface of the brick; (7) putting the blank body obtained in the step (6) into a kiln for firing at 1150-1200 ℃ for 40-60 minutes; (8) soft polishing is carried out on the transparent bright dry particles protruding on the surface of the fired ceramic tile to obtain the starlight glaze ceramic tile;
the transparent bright dry particles used in the dry particle glaze layer comprise 35-40 parts by weight of potash feldspar, 8-15 parts by weight of calcined talc, 8-12 parts by weight of calcite, 25-35 parts by weight of quartz, 8-12 parts by weight of barium carbonate, 10-15 parts by weight of calcined alumina, 4-8 parts by weight of air knife soil and 1-5 parts by weight of zinc oxide;
the preparation method of the transparent bright dry granules comprises the following steps: the fineness of each raw material is controlled to be 80-200 meshes, the raw materials are uniformly stirred in parts and are put into a frit furnace to be calcined until the raw materials are melted into molten slurry liquid, and the calcining temperature is 1450-1550 ℃; putting the molten slurry liquid into water for quenching, and quenching the molten slurry liquid into a glass molten block shape; and (4) crushing the frits and sieving the frits by a 40-200-mesh sieve to obtain transparent bright dry particles.
2. The process for preparing star-glazed ceramic tile according to claim 1, wherein in step (6), the transparent bright dry granules are uniformly laid on the surface of the tile in the form of sand.
3. The method for preparing an starlight glazed ceramic tile according to claim 1, wherein the screen used in step (4) is a 100-mesh all-through screen.
4. The starlight glaze ceramic tile is characterized by comprising a blank layer, a ground glaze layer, a color development glaze layer and a dry particle glaze layer from bottom to top, wherein transparent bright dry particles used in the dry particle glaze layer comprise, by weight, 35-40 parts of potassium feldspar, 8-15 parts of calcined talc, 8-12 parts of calcite, 25-35 parts of quartz, 8-12 parts of barium carbonate, 10-15 parts of calcined alumina, 4-8 parts of air knife soil and 1-5 parts of zinc oxide.
5. The starlight glaze ceramic tile of claim 4, wherein the preparation method of the transparent bright dry particles comprises the following steps: the fineness of each raw material is controlled to be 80-200 meshes, the raw materials are uniformly stirred in parts and are put into a frit furnace to be calcined until the raw materials are melted into molten slurry liquid, and the calcining temperature is 1450-1550 ℃; putting the molten slurry liquid into water for quenching, and quenching the molten slurry liquid into a glass molten block shape; and (4) crushing the frits and sieving the frits by a 40-200-mesh sieve to obtain transparent bright dry particles.
6. The starlight glaze ceramic tile of claim 4, wherein the ground glaze used in the ground glaze layer comprises 30-45 parts by weight of potassium feldspar, 20-35 parts by weight of albite, 5-10 parts by weight of air knife soil, 15-25 parts by weight of alumina powder, 3-10 parts by weight of quartz, 1-5 parts by weight of wollastonite, 10-15 parts by weight of zirconium silicate, 0.1-0.4 part by weight of methyl cellulose, 0.3-0.6 part by weight of sodium tripolyphosphate and 38-45 parts by weight of water.
7. The starlight glaze ceramic tile of claim 6, wherein the ground glaze is prepared by the following steps: adding the raw materials into a ball mill according to parts by weight, ball-milling for 6-8 hours until the fineness is 325 meshes, the screen residue is 0.7-1.0%, and the specific gravity is as follows: 1.88-1.95 g/ml, carrying out iron removal operation when discharging slurry from the ball mill, and sieving with a 140-mesh sieve.
8. The star-glazed ceramic tile according to claim 4, wherein the coloring glaze used in the coloring glaze layer comprises 30 to 45 parts by weight of potash feldspar, 5 to 15 parts by weight of burnt talc, 5 to 15 parts by weight of quartz, 10 to 20 parts by weight of barium carbonate, 5 to 15 parts by weight of alumina powder, 2 to 8 parts by weight of zinc oxide, 5 to 10 parts by weight of air knife soil, 15 to 20 parts by weight of zirconium silicate, 10 to 20 parts by weight of water and 60 to 100 parts by weight of printing paste.
9. The starlight glaze ceramic tile of claim 8, wherein the preparation method of the colored glaze comprises the following steps: adding the raw materials into a ball mill according to parts by weight, ball-milling for 10-12 hours until the fineness is 325 meshes, the screen residue is 0.1-0.3%, and the specific gravity is as follows: 1.45-1.6 g/ml, carrying out iron removal operation when discharging slurry from the ball mill, and sieving with a 140-mesh sieve.
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