CN108892458A - Polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof - Google Patents

Polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof Download PDF

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Publication number
CN108892458A
CN108892458A CN201810925755.0A CN201810925755A CN108892458A CN 108892458 A CN108892458 A CN 108892458A CN 201810925755 A CN201810925755 A CN 201810925755A CN 108892458 A CN108892458 A CN 108892458A
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China
Prior art keywords
coiled material
powder
polypropylene fiber
polyethylene polypropylene
waterproof coiled
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Application number
CN201810925755.0A
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Chinese (zh)
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CN108892458B (en
Inventor
秦希武
张雪松
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Songyan Qinhuangdao City Building Materials Co Ltd
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Songyan Qinhuangdao City Building Materials Co Ltd
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Priority to CN201810925755.0A priority Critical patent/CN108892458B/en
Publication of CN108892458A publication Critical patent/CN108892458A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • C04B28/065Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials
    • C04B2111/506Bendable material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses a kind of polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof, it is to be mixed by weight ratio by liquid material and powder scene, wherein liquid material is polymer emulsion, and wherein powder is mixed by weight ratio by sulphate aluminium cement, water-reducing agent, defoaming agent, dispersing agent and formed.The adhesion strength and flexibility of invention adhesive are high, sealing performance is good, meet the requirement of polyethylene polypropylene fiber waterproof coiled material composite water-proof, the bonding suitable for coiled material and substrate, coiled material and coiled material, coiled material seam crossing and privileged sites.Preparation method of the present invention is easy, and adhesive is nontoxic, harmless, pollution-free, belongs to green product.

Description

Polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof
Technical field
The present invention relates to the adhesive that waterproof roll uses, and in particular to a kind of polyethylene polypropylene fiber waterproof coiled material adhesive and Preparation method.
Background technique
Polyethylene polypropylene fiber waterproof coiled material is a kind of waterproof material being widely used, and sales volume occupies in polymer membranes In first place.Polyethylene polypropylene fiber waterproof coiled material using when need with adhesive match composition complex waterproof layer, therefore, for matching The adhesive of set clearly requires, and not only to have good adhesive property, sealing performance, also to have certain soft Toughness, above-mentioned requirements are edited in China Engineering Construction Standardization Association《Polyethylene polypropylene fiber sheet composite water-proof engineering technology rule Journey》In have specific regulation, in addition, in coiled material seam crossing and privileged sites (such as coiled material and iron, aluminium, PVC material) bonding, It is required that adhesive will be firmly bonded, reach waterproof sealing effect.Currently, the polymer modification that polyethylene polypropylene fiber waterproof coiled material uses Cement binding material, wherein cement is all made of ordinary portland cement, and such adhesive and base (cement base) adhesive property are still Can, but its sealing performance, flexibility are poor, and the purpose of the composite water-proof of above-mentioned regulatory requirements is not achieved, more can't resolve and connect The bonding and sealing problem of seam and privileged sites.It is poly- when being increased in adhesive in order to improve its flexibility and sealing performance The content of object is closed, that is, when improving polymer cement ratio, can not be solidified using when ordinary portland cement, therefore it is comprehensive to be badly in need of a kind of performance With excellent polyethylene polypropylene fiber waterproof coiled material adhesive.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of polyethylene polypropylene waterproof roll that performance is comprehensive and excellent Material adhesive and preparation method thereof.The polyethylene polypropylene fiber waterproof coiled material adhesive replaces normal silicate water with sulphate aluminium cement Mud, and a variety of auxiliary agents are added, it when increasing polymer cement ratio, still can solidify, reach and not only seal waterproof but also improve flexible mesh 's.
The present invention is achieved by the following technical solutions.
A kind of polyethylene polypropylene fiber waterproof coiled material adhesive, the polyethylene polypropylene fiber waterproof coiled material adhesive by 1 parts by weight liquid Material and the powder of 1.45~1.75 parts by weight mix composition;The liquid material is styrene-acrylic emulsion, acrylic emulsion, vinyl acetate- Any one in ethylene copolymer emulsion, styrene-butadiene emulsion;The solid content of the liquid material is 50%~56%, viscosity 500mpa~ 2000mpa, pH value 6~8, glass transition temperature are -8 DEG C~-15 DEG C, and the powder is made of the raw material of following parts by weight:Sulphur 100 parts of aluminate cement, 0.8~1.1 part of water-reducing agent, 0.05~0.15 part of defoaming agent, 0.05~0.15 part of dispersing agent.
Further, the polyethylene polypropylene fiber waterproof coiled material adhesive is by the liquid material of 1 parts by weight and the powder of 1.5 parts by weight Material mixing composition.
Further, the water-reducing agent is melamine-type water-reducing agent.
Further, the defoaming agent is organic silicon defoaming agent.
Further, the dispersing agent is sodium polyphosphate.
The preparation method of this polyethylene polypropylene fiber waterproof coiled material adhesive, includes the following steps:
Sulphate aluminium cement is fitted into double helix taper dry powder blender by step 1 according to the formula of the powder, It is added with stirring water-reducing agent, defoaming agent, dispersing agent, mixing machine revolving speed revolves 2-3 revs/min, 57~77 revs/min of rotation, stirs Mix uniform to powder, no agglomeration obtains powder, then by powder material weighing obtained, sealed package;
Step 2 chooses the liquid material weighing, sealed package;
Step 3, in the polyethylene polypropylene fiber waterproof coiled material adhesive in use, according to the mixed of the liquid material and powder Proportion is closed, powder is added in liquid material while stirring using electric mixer, mixing speed is 200 revs/min, stirring to no block Shape object uniformity, obtains this polyethylene polypropylene fiber waterproof coiled material adhesive.
The invention has the advantages that:
This polyethylene polypropylene fiber waterproof coiled material Adhensive performance is excellent, replaces normal silicate water with sulphate aluminium cement Mud, and a variety of auxiliary agents are added, it when increasing polymer cement ratio, still can solidify, be used for polyethylene polypropylene fiber waterproof coiled material waterproof construction, Adhesion strength is high, and flexility, sealing performance are good.
Polyethylene polypropylene fiber waterproof coiled material adhesive of the invention is nontoxic, harmless, pollution-free, belongs to green product.
Specific embodiment
In order to keep the objectives, technical solutions, and advantages of the present invention more explicit, following specific embodiments are to this hair It is bright to be further elaborated.It should be appreciated that the specific embodiment that this place is described is only used to explain the present invention, not For limiting the present invention.
Embodiment
1, the preparation of powder:
In double helix taper dry powder blender, by weight, 100 parts of sulphate aluminium cements, 1.0 parts of melamines are added Type water-reducing agent, 0.1 part of organic silicon defoaming agent, 0.1 part of sodium polyphosphate dispersing agent.Addition sequence is that aluminium sulfate water is first added Mud, is added above-mentioned water-reducing agent, defoaming agent, dispersing agent under stiring, above-mentioned water-reducing agent, defoaming agent, dispersing agent addition regardless of Sequencing, mixing machine revolving speed revolve 2~3 revs/min, 55~77 revs/min of rotation, stir, no agglomeration uniform to powder, so Every bag of 15 ㎏ sealed packages, finished product powder are pressed afterwards.
2, the preparation of liquid material:
Buying or customization meet above-mentioned requirements liquid material, then press every bag of 10 ㎏ sealed packages, finished product liquid material.
3, finished product liquid material is mixed with finished product powder:
Before using the construction of this polyethylene polypropylene fiber waterproof coiled material adhesive, take above-mentioned finished product liquid material, finished product powder by 1: 1.5 weight ratio mixing, is added to powder in liquid material while stirring with electric mixer, and mixing speed is 200 revs/min of left sides The right side stirs to no block uniformity, obtains this polyethylene polypropylene fiber waterproof coiled material adhesive.
Various sample detections are bonded for polyethylene polypropylene fiber waterproof coiled material by this adhesive made from above-described embodiment, it is various Sample includes:Coiled material-coiled material, coiled material-substrate (cement base), coiled material-iron, coiled material-aluminium, coiled material-PVC, send authoritative detection Mechanism is detected, while also carrying out complete detection to adhesive properties itself.
This adhesive performance indexes testing result is shown in Table 1.
Table 1
Find out from 1 testing result of table, the adhesive bonds intensity is high, and sealing performance is good, especially has good Flexibility meets the requirement of polyethylene polypropylene fiber waterproof coiled material composite water-proof, is suitable for coiled material and substrate (cement base), coiled material and volume The bonding of material, coiled material seam crossing and privileged sites (such as coiled material and iron, aluminium, PVC material) all has good bonding and prevents Water sealing property, particular, it must be pointed out that bonding sample is after immersion 168 hours, peel strength is not reduced not only, rises instead, can See that the adhesive water resistance is very excellent.The adhesive is nontoxic, harmless, pollution-free, belongs to green product.
The numerical value that table 1 measures is the liquid material of this polyethylene polypropylene fiber waterproof coiled material adhesive and powder proportion is 1:When 1.5 As a result.When liquid material and powder proportion variation, every testing result is changed, and when liquid material ratio increases, flexibility is It improves, the good fluidity of glue is easy to construct, but coiled material is declined with coiled material adhesive strength, and cost also improves.When powder ratio When example increases, coiled material and coiled material adhesive strength are improved, and flexibility decline, workability is deteriorated.This polyethylene polypropylene fiber waterproof coiled material Performance indexes testing result is shown in Table 2 when liquid material and the powder proportion of adhesive change.
Table 2
By table 2, liquid material:Powder is 1:When 1.45~1.75, every all variations of Testing index, but it is more satisfactory, all may be used To meet waterproofing work needs.But it is comprehensive to consider comprehensively, with liquid material:Powder is 1:It is preferable when 1.5.
The above is only preferred embodiments of the invention, not limitation of the present invention, and present invention is also not necessarily limited to upper State citing, those skilled in the art, within the essential scope of the present invention, make any simple modification, equivalent variations, Addition or replacement, all should belong to protection scope of the present invention.

Claims (6)

1. a kind of polyethylene polypropylene fiber waterproof coiled material adhesive, which is characterized in that the polyethylene polypropylene fiber waterproof coiled material adhesive It is made of the powder mixing of the liquid material and 1.45~1.75 parts by weight of 1 parts by weight;The liquid material is styrene-acrylic emulsion, propylene yogurt Liquid, vinyl acetate-ethylene copolymer emulsion, any one in styrene-butadiene emulsion;The solid content of the liquid material is 50%~56%, Viscosity 500mpa~2000mpa, pH value 6~8, glass transition temperature are -8 DEG C~-15 DEG C;The powder is by following parts by weight Raw material composition:100 parts of sulphate aluminium cement, 0.8~1.1 part of water-reducing agent, 0.05~0.15 part of defoaming agent, dispersing agent 0.05~ 0.15 part.
2. polyethylene polypropylene fiber waterproof coiled material adhesive according to claim 1, which is characterized in that the polyethylene polypropylene Waterproof roll adhesive is made of the powder mixing of the liquid material and 1.5 parts by weight of 1 parts by weight.
3. polyethylene polypropylene fiber waterproof coiled material adhesive according to claim 1, which is characterized in that the water-reducing agent is three Paracyanogen amine type water-reducing agent.
4. polyethylene polypropylene fiber waterproof coiled material adhesive according to claim 1, which is characterized in that the defoaming agent is to have Machine silicon class defoaming agent.
5. polyethylene polypropylene fiber waterproof coiled material adhesive according to claim 1, which is characterized in that the dispersing agent is more Polyphosphate sodium.
6. a kind of preparation method of polyethylene polypropylene fiber waterproof coiled material adhesive described in claim 1, which is characterized in that including such as Lower step:
Sulphate aluminium cement is fitted into double helix taper dry powder blender according to the formula of the powder, is stirring by step 1 Lower addition water-reducing agent, defoaming agent, dispersing agent, mixing machine revolving speed revolve 2-3 revs/min, and 57~77 revs/min of rotation, stirring is extremely Powder is uniform, and no agglomeration obtains powder, then by powder material weighing obtained, sealed package;
Step 2 chooses the liquid material weighing, sealed package;
Step 3, in the polyethylene polypropylene fiber waterproof coiled material adhesive in use, matching according to the mixing of the liquid material and powder Than powder being added in liquid material while stirring using electric mixer, mixing speed is 200 revs/min, stirring to no block Uniformity obtains this polyethylene polypropylene fiber waterproof coiled material adhesive.
CN201810925755.0A 2018-08-15 2018-08-15 Polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof Active CN108892458B (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113788662A (en) * 2021-10-22 2021-12-14 秦皇岛市松岩建材有限公司 Single-component polyethylene polypropylene fiber waterproof coiled material adhesive
CN113979702A (en) * 2021-10-15 2022-01-28 江苏凯伦建材股份有限公司 Polymer cement waterproof coating and application thereof in wet-laid coiled material bonding

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786100A (en) * 2005-12-22 2006-06-14 王立华 Method of sticking polyethylene polyproylene fiber water proof coiled material
KR101361832B1 (en) * 2013-08-01 2014-02-11 이영남 Early-strength macrofiber polymer modified concrete composition with excellent crack resistance and water tightness, and constructing method of pavement using that
CN104164143A (en) * 2013-05-16 2014-11-26 扬州豪扬新型建筑材料有限公司 Two-component macromolecular high elastic waterproof paint
CN105462496A (en) * 2016-01-06 2016-04-06 北京东方雨虹防水技术股份有限公司 Antibacterial and moldproof polymer modified spray asphalt waterproof paint and application method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786100A (en) * 2005-12-22 2006-06-14 王立华 Method of sticking polyethylene polyproylene fiber water proof coiled material
CN104164143A (en) * 2013-05-16 2014-11-26 扬州豪扬新型建筑材料有限公司 Two-component macromolecular high elastic waterproof paint
KR101361832B1 (en) * 2013-08-01 2014-02-11 이영남 Early-strength macrofiber polymer modified concrete composition with excellent crack resistance and water tightness, and constructing method of pavement using that
CN105462496A (en) * 2016-01-06 2016-04-06 北京东方雨虹防水技术股份有限公司 Antibacterial and moldproof polymer modified spray asphalt waterproof paint and application method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113979702A (en) * 2021-10-15 2022-01-28 江苏凯伦建材股份有限公司 Polymer cement waterproof coating and application thereof in wet-laid coiled material bonding
WO2023061023A1 (en) * 2021-10-15 2023-04-20 江苏凯伦建材股份有限公司 Polymer cement waterproof coating and use thereof in bonding of wet-laid coiled material
CN113788662A (en) * 2021-10-22 2021-12-14 秦皇岛市松岩建材有限公司 Single-component polyethylene polypropylene fiber waterproof coiled material adhesive

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