CN103725051A - Base material of inorganic coating and application of base material - Google Patents
Base material of inorganic coating and application of base material Download PDFInfo
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- CN103725051A CN103725051A CN201410003196.XA CN201410003196A CN103725051A CN 103725051 A CN103725051 A CN 103725051A CN 201410003196 A CN201410003196 A CN 201410003196A CN 103725051 A CN103725051 A CN 103725051A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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Abstract
The invention discloses a base material of an inorganic coating and application of the base material. The base material is a mixture of liquid silica sol and calcium carbonate, wherein a mass ratio of the liquid silica sol to the calcium carbonate is 1:(3-10) based on solid content. The inorganic coating can be obtained by adding auxiliary materials which account for less than 20 percent of the total mass of the inorganic coating on the basis of the base material. The inorganic coating has the characteristics of high ageing resistance, high weather resistance, high chemical bonding force with a cement base layer, peeling avoidance, heat resistance, fire resistance, no toxicity, environment friendliness and energy conservation, does not contain strong alkaline ions such as potassium ion and sodium ion, has the pH value of less than 10 and is high in compatibility with pigments, a saltpetering phenomenon is avoided, and inorganic coatings of various colors can be manufactured. The base material can be used for preparing rigid waterproof materials, colored facing mortar, artificial stone materials and art paint.
Description
Technical field
The present invention relates to a kind of inorganic paint, be specifically related to a kind of inorganic paint that adopts silicon sol and its preparation method and application.
Background technology
According to national sector standard JG/26-2002, inorganic architectural coatings can be divided into two classes by main binding agent kind, and the one, take water glass (alkalimetal silicate) as main binding agent, add pigment, filler and auxiliary agent formulated; The 2nd, take silicon sol as main binding agent, add appropriate synthetic resin emulsion, pigment, filler and auxiliary agent formulated.
Conventional as shown in the table for the preparation of potassium silicate and its main physical and chemical indexes of silicon sol of inorganic paint:
From the composition of potassium silicate and silicon sol, both key distinctions are at alkalinity.Although the former also can with calcium carbonate generation calcify reaction, even there is lower shrinking percentage, but because its free alkali content is higher, silicification reaction is had to inhibition, therefore larger on the water tolerance impact of final product, and the accumulation of salt in the surface soil phenomenon of association also can affect painted homogeneity, practical application has been formed to bottleneck.And the latter's alkalinity is extremely low, silication degree is higher, so water tolerance and also better with the consistency of pigment.
But, while using silicon sol separately, often there is the critical defects such as crackle, internal capillary in ambient cure film forming, meanwhile, and silicon sol on the high side, its price several times of water glass often all the time, also far above the synthetic emulsion of same concentration, therefore conventionally silicon sol being used as at present to auxiliary agent and being used, is usually to add organic polymer emulsion to make organic-inorganic compoiste coating, and the coating that adds organic polymer material to obtain is easily aging, weathering resistance is poor.Also have report to adopt water-soluble trimeric cyanamide and polyvalent alcohol to carry out modification to silicon sol, but this class process the complicacy that can increase preparation.
In recent years, along with progressively replacing traditional ion exchange method, silica flour one one-step hydrolysis method production silicon sol technique produces silicon sol technique, the price of silicon sol progressively drops to the level lower than water glass, so silicon sol of today has become a kind of basic chemical raw materials that have a extensive future.Therefore, if can overcome silicon sol film forming, there is the problems such as crackle, internal capillary, can obtain well behaved inorganic paint.
Summary of the invention
Goal of the invention of the present invention is to overcome above shortcomings in prior art, and a kind of body material of inorganic paint is provided, and the application of this body material.
To achieve the above object of the invention, the technical solution used in the present invention is: a kind of body material of inorganic paint, described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, described liquid-state silicon colloidal sol take solid content with the mass ratio of calcium carbonate as 1: 3～10.
Preferred technical scheme, described liquid-state silicon colloidal sol take solid content with the mass ratio of calcium carbonate as 1: 5～8.
In technique scheme, the solid content of described liquid-state silicon colloidal sol is at least 30%, and sodium oxide content is less than 1%, pH value and is less than 11.
Described calcium carbonate is the powder of purity more than 95%, more than fineness 200 orders.
As the one application of above-mentioned body material, the invention provides a kind of inorganic paint, by above-mentioned body material, become with the auxiliary material liquid combo of joining, the described auxiliary material of joining is below 20% of inorganic paint total mass, and the auxiliary material of joining is selected from one or more the combination in high molecular polymer, filler, pigment, paint additive.
The preparation method of above-mentioned inorganic paint, comprises the following steps:
I, by above-mentioned mass ratio, weigh liquid-state silicon colloidal sol, calcium carbonate and the auxiliary material of joining, the described auxiliary material of joining is comprised of high molecular polymer, filler, pigment, paint additive;
II, liquid-state silicon colloidal sol is joined in speed governing Scattered Kettle, stir and slowly add calcium carbonate and the auxiliary material of joining, after interpolation, accelerate to be stirred to evenly, make soup compound and sealing is preserved.
During use, the liquid-state silicon colloidal sol in the inorganic paint of coating reacts with calcium carbonate generation air-setting, generates hydrated calcium silicate.Its process is, unformed active silica in silica aqueous solution and the lip-deep calcium water generation reaction of calcium carbonate granule Calucium Silicate powder, and be wrapped in the surface of calcium carbonate granule, calcium carbonate granule is joined by hydrated calcium silicate glue, when in air, the evaporation of water in system, separates out hydrated calcium silicate crystal, and to form hydrated calcium silicate crystal/calcium carbonate be rostone structure main component, water-fast, that have mechanical strength.Make thus coating and cement basic layer there is stronger Chemical bond power, and make coating that problems of crack can not occur.
In technique scheme, described high molecular polymer is one of EVA redispersable latex powder, acrylic emulsion and redispersable latex powder thereof, fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion, aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin or multiple combination; Described filler is one of titanium dioxide, mica, kaolin or multiple combination; Described pigment is pigment dyestuff, mineral dye or the liquid color paste that is mixed into by multiple pigment; Described paint additive is one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas, calcium containing compound, zinc compound or multiple combination.Metal ion in calcium containing compound and zinc compound can react with silicon sol and generate silicate nonsoluble, can promote the setting rate of inorganic paint, improves the rupture strength of inorganic paint.
Preferably, the minimum film-forming temperature of high molecular polymer (MFT) is in zero degree left and right.
The present invention provides the body material of above-mentioned inorganic paint in the application of preparing in rigidity water-proofing material, colored finish mortar, artificial stone material simultaneously.
In above-mentioned body material, add 20% following pigment, can be used as art painting and use, for drawing the picture of similar oil painting.
Because technique scheme is used, the present invention compared with prior art has following advantages:
1, the present invention has disclosed a kind of of great value gelling chemical reaction, the feature of this chemical reaction is that silica sol liquid can generate water insoluble, to have intensity hydrated calcium silicate artificial stone material with the calcium carbonate generation air-setting reaction of certain fineness, and built accordingly a kind of body material of inorganic paint, by limiting the ratio of silica sol liquid and calcium carbonate, obtained significant technique effect.
2, inorganic paint of the present invention compares to existing inorganic silicate coating and has advantages of outstanding: it has the features such as ageing-resistant, weathering resistance strong, have Chemical bond power with cement basic layer, do not peel, heat-resisting, fire prevention, nontoxic, pollution-free and save energy, and it is not containing strong basicity ions such as potassium, sodium, pH value is less than 10, good with the consistency of pigment, can not produce accumulation of salt in the surface soil phenomenon, can make versicolor inorganic paint.
3, the calcium carbonate of utilization of the present invention belongs to a kind of slightly soluble salt, its carbonic acid ion that dissociates can be replaced by silicate ion, thereby form the insoluble and better Calucium Silicate powder of over-all properties, it also has certain covering effect in whitewash, can replace the effect of the titanium dioxide of most.
Accompanying drawing explanation
Fig. 1 is the XRD diffractogram of silicon sol in embodiment mono-.
Fig. 2 is the XRD diffractogram of silicon sol and calcium carbonate gas mixture hardened product in embodiment mono-.
Embodiment
Below in conjunction with drawings and Examples, the invention will be further described:
Embodiment mono-: a kind of body material of inorganic paint, described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, take respectively 100 grams of liquid-state silicon colloidal sols (solid content is 30%), 100 grams of powder calcium carbonate, silicon sol is injected to speed governing Scattered Kettle, add while stirring calcium carbonate, then high-speed stirring is uniformly dispersed.
Fig. 1 is the XRD diffractogram of raw materials of silica sol, and it is a kind of unformed silicon-dioxide; Fig. 2 is the XRD diffractogram that the product of the present embodiment is placed on the hardened product after 3 days in air, wherein can find that unformed silicon-dioxide all disappears, and has generated and has had the hydrated calcium silicate that crystalline structure is good, the unreacted calcium carbonate of remaining part.From mechanism, unformed active silica in silica aqueous solution and the lip-deep calcium water generation reaction of calcium carbonate granule Calucium Silicate powder, and be wrapped in the surface of calcium carbonate granule, calcium carbonate granule is joined by hydrated calcium silicate glue, when being put in air, the evaporation of water in system, separates out hydrated calcium silicate crystal, and to form hydrated calcium silicate crystal/calcium carbonate be rostone structure main component, water-fast, that have mechanical strength.
In following examples, the silicon sol of use can be: pH value is greater than 8 the active silica colloid dispersion liquid in water, and its range of solid content is 30-40%.
Calcium carbonate can be: the powder being formed through pulverizing, grinding by natural whiting ore, or the calcium carbonate of synthetic, and its calcium carbonate content is no less than 95%, and whiteness is not less than 85%, and fineness is not less than 200 orders.Especially, the density that employing water-ground limestone obtains than light calcium carbonate is larger, performance is better.
High molecular polymer can be has flexible latex powder, emulsion and aqueous resin dispersion, comprising EVA redispersable latex powder, esters of acrylic acid redispersable latex powder, fluorine carbon emulsion (being good through the fluorine carbon emulsion of plasticising), organosilicon crylic acid latex, pure-acrylic emulsion, benzene emulsion, and aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin etc.Adopt the effect of high molecular polymer can improve stability and the application property of " silicon sol-calcium carbonate " system, and can increase splitting resistance and the snappiness of its hardened material.
The auxiliary material of joining such as pigment, filler, paint additive can require to adjust according to the use properties of coating.
Embodiment bis-: first take respectively the liquid-state silicon colloidal sol (solid content=30%, hereinafter to be referred as silicon sol, lower same) of 100 grams, the powder calcium carbonate of 300 grams, then silicon sol is injected to speed governing Scattered Kettle, progressively add calcium carbonate and the auxiliary material of joining, the auxiliary material usage of joining is not more than 20% of total mass, then high-speed stirring is uniformly dispersed again, make soup compound, after barrelling, sealing is preserved, and period of storage reaches 6 months, and the ultimate compression strength of test in its seven days is greater than 12MPa, whiteness is greater than 85%, and Mohs' hardness is greater than 5.
Embodiment tri-: first the silicon sol of 100 grams, the powder calcium carbonate of approximately 200 grams, the pearlstone of 20 grams and the second-order transition temperature MFT of 10 grams are in kind uniformly dispersed after the EVA redispersable latex powder of zero degree left and right mixes in speed governing Scattered Kettle, this product can be used as a kind of inorganic fire thermal insulation coatings and uses, and after use barrelling, period of storage reaches 6 months.Compared with embodiment bis-products, its anti-cracking performance improves.
Embodiment tetra-: be uniformly dispersed in speed governing Scattered Kettle after first the iron oxide pigment of the silicon sol of 100 grams, the powder calcium carbonate of approximately 150 grams, the titanium dioxide of 30 grams, the Acrylic emulsion powder of 10 grams and 2 grams being mixed, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.Compared with embodiment bis-, three products, it can present abundant color.
Products obtained therefrom adopts JG/T 26-2002 < < exterior wall inorganic architectural coatings > > standard test, obtains technical indicator as shown in table 1,
Adopt the inorganic paint of embodiment bis-to four preparations, through be coated with brush after wall, when air drying, unformed silicon sol (silicon-dioxide) will with calcium carbonate reaction, crosslinked webbed " hydrated calcium silicate " structure after dehydration, thus the rostone coating with resistance to compression, tensile strength formed.Its final product is take ionic linkage and covalent linkage as main, and Van der Waals key is auxiliary, and its performance is similar to rock forming mineral.This inorganic paint is painted on (as concrete, cement based putty, cement based insulation surface layer etc.) after cement based metope, can penetrate into cement foundation wall surface, and generate water-fast Calucium Silicate powder with the calcareous material reaction in cement, form anchoring effect, coating and metope are combined as a whole securely.
Embodiment five: be uniformly dispersed in speed governing Scattered Kettle after first the chrome green pigment of the silicon sol of 100 grams, the powder calcium carbonate of approximately 200 grams, the titanium dioxide of 20 grams, the fluorine carbon emulsion of 20 grams and 3 grams being mixed, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.Compared with embodiment bis-, three products, it can present green color.
Embodiment six: be uniformly dispersed in speed governing Scattered Kettle after first the ultramarine blue pigment of the silicon sol of 100 grams, the powder calcium carbonate of approximately 250 grams, the kaolin of 20 grams, the benzene emulsion of 20 grams and 5 grams being mixed, this product can be used as a kind of inorganic exterior coating and uses, and after barrelling, period of storage reaches 6 months.Compared with embodiment bis-, three products, it can present blue color.
Embodiment seven: be uniformly dispersed in speed governing Scattered Kettle after first the ferric oxide red colorant of the silicon sol of 100 grams, the powder calcium carbonate of approximately 150 grams, the ACRYLIC EMULSION of 20 grams and 100 grams being mixed, this product can be used as a kind of art painting and uses, and after barrelling, period of storage reaches 6 months.
Embodiment eight: be uniformly dispersed and be thick pulpous state after first the hydrophobic type redispersable latex powder of the silicon sol of 100 grams, the powder calcium carbonate of approximately 250 grams and 15 grams being mixed in speed governing Scattered Kettle, this product can be used as a kind of rigidity water-proofing material and uses, and its impermeability can reach 0.3MPa.
Embodiment nine: first the iron oxide pigment of the silicon sol of 100 grams, the powder calcium carbonate of 250 grams, the graded sand and stone of 100 grams, the Acrylic emulsion powder of 10 grams and 4 grams and appropriate densification powder (slurry), lignocellulose etc. are mixed and are thixotropy mortar, this material can be used as a kind of not accumulation of salt in the surface soil, uses without the colored finish mortar of cover processing.
Embodiment ten: be uniformly dispersed and be rheological mortar after first the silicon sol of 100 grams, the powder calcium carbonate of approximately 200 grams, the graded sand and stone of 150 grams, the EVA redispersable latex powder of 20 grams, the iron oxide pigment of 4 grams and appropriate flow agent being mixed in speed governing Scattered Kettle, then pour in artificial stone plate's mould, reinforcement vibrating forming, can obtain a kind of artificial stone plate of light through surface finish after the demoulding.
Embodiment 11: first take respectively two samples, the liquid-state silicon colloidal sol of 100 grams, the powder calcium carbonate of 200 grams, then inject silicon sol speed governing Scattered Kettle, more progressively add calcium carbonate.In a sample, add 1 gram of calcium chloride, another sample does not add, then high-speed stirring is uniformly dispersed simultaneously, makes soup compound, and after barrelling, sealing is preserved, and period of storage reaches 6 months.Found that, add the setting rate after wall on the sample of calcium chloride and be greater than the sample that does not add calcium chloride.
Apply technical scheme of the present invention, comparing to existing inorganic silicate coating has advantages of outstanding: it has ageing-resistant, weathering resistance is strong, there is Chemical bond power with cement basic layer, do not peel, heat-resisting, fire prevention, nontoxic, the features such as pollution-free and save energy, and it is not containing potassium, the strong basicity ions such as sodium, pH value is less than 10, good with the consistency of pigment, can not produce accumulation of salt in the surface soil phenomenon, can make versicolor inorganic paint, it has realized a kind of alkali-free and the controlled inorganic coagulation material of open season, and there is good tint permanence, can be used for inorganic paint, colored finish mortar, the industries such as artificial platen and art painting.
Claims (10)
1. a body material for inorganic paint, is characterized in that: described body material is the mixture of liquid-state silicon colloidal sol and calcium carbonate, described liquid-state silicon colloidal sol take solid content with the mass ratio of calcium carbonate as 1: 3～10.
2. the body material of inorganic paint according to claim 1, is characterized in that: described liquid-state silicon colloidal sol take solid content with the mass ratio of calcium carbonate as 1: 5～8.
3. the body material of inorganic paint according to claim 1, is characterized in that: the solid content of described liquid-state silicon colloidal sol is at least 30%, and sodium oxide content is less than 1%, pH value and is less than 11.
4. the body material of inorganic paint according to claim 1, is characterized in that: described calcium carbonate is the powder of purity more than 95%, more than fineness 200 orders.
5. an inorganic paint, it is characterized in that: by body material described in claim 1, become with the auxiliary material liquid combo of joining, the described auxiliary material of joining is below 20% of inorganic paint total mass, and the auxiliary material of joining is selected from one or more the combination in high molecular polymer, filler, pigment, paint additive.
6. inorganic paint according to claim 5, is characterized in that: described high molecular polymer is one of EVA redispersable latex powder, esters of acrylic acid redispersable latex powder, fluorine carbon emulsion, organosilicon crylic acid latex, pure-acrylic emulsion, aqueous epoxy resins, aqueous polyurethane, water-base epoxy ester, aqueous alkide resin or multiple combination; Described filler is one of titanium dioxide, mica, kaolin or multiple combination; Described pigment is pigment dyestuff, mineral dye or the liquid color paste that is mixed into by multiple pigment; Described paint additive is one of polyacrylic acid dispersant, silane water-resisting agent, PVA thickening material, sanitas, calcium containing compound, zinc compound, water glass or multiple combination.
Described in claim 1 body material of inorganic paint in the application of preparing in rigidity water-proofing material.
Described in claim 1 body material of inorganic paint in the application of preparing in colored finish mortar.
Described in claim 1 body material of inorganic paint in the application of preparing in artificial stone material.
Described in claim 1 body material of inorganic paint in the application of preparing in art painting.
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| CN2013104688321 | 2013-10-10 | ||
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| CN104326727A (en) * | 2013-11-26 | 2015-02-04 | 阳泉市澳丽丝科技涂料有限公司 | Inorganic coating |
| CN104927419A (en) * | 2015-07-15 | 2015-09-23 | 武汉佳碧源科技有限责任公司 | Reaction film formation inorganic dry powder coating material and production method thereof |
| CN107163650A (en) * | 2017-03-28 | 2017-09-15 | 苏州弗克技术股份有限公司 | A kind of drawing pigment and preparation method thereof |
| CN107057114A (en) * | 2017-05-19 | 2017-08-18 | 江苏飞亚化学工业有限责任公司 | A kind of emulsion-type high dispersive antioxidant |
| CN107266944A (en) * | 2017-08-11 | 2017-10-20 | 成都职业技术学院 | A kind of novel environment-friendly water-based inorganic coating and preparation method thereof |
| CN110423495A (en) * | 2019-09-17 | 2019-11-08 | 郑州艾比利特节能科技有限公司 | A kind of bi-component inorganic floor coatings |
| CN113025086A (en) * | 2021-03-10 | 2021-06-25 | 宁波瑞凌新能源科技有限公司 | Radiation refrigeration inorganic coating and preparation method thereof |
| CN113025086B (en) * | 2021-03-10 | 2022-04-26 | 宁波瑞凌新能源科技有限公司 | Radiation refrigeration inorganic coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103725051B (en) | 2016-04-13 |
| WO2015051598A1 (en) | 2015-04-16 |
| CN103497545A (en) | 2014-01-08 |
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