CN108797152A - A kind of graphene concentrator and preparation method thereof - Google Patents
A kind of graphene concentrator and preparation method thereof Download PDFInfo
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- CN108797152A CN108797152A CN201810609158.7A CN201810609158A CN108797152A CN 108797152 A CN108797152 A CN 108797152A CN 201810609158 A CN201810609158 A CN 201810609158A CN 108797152 A CN108797152 A CN 108797152A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a kind of graphene concentrator and preparation method thereof, the slurry includes each component of following mass percentage：Graphene microcapsules 0.5%~12%, sodium alginate 0.1%~5%, thickener 1%~5%, dyestuff 0.1%~5%, calcium carbonate 0.5~3%, sodium cellulose glycolate 0.01~0.05%, urea 0.1~2%, remaining is water.Graphene microcapsules are added in the present invention in concentrator, and proportioning is optimized with other components, the printed fabric for preparing pattern fineness can be produced by Conventional decal technique, gained printed fabric has good permeability, firm coloration, Washing can reach 4 grades or more.The concentrator has the performances such as excellent antibiotic property, uvioresistant simultaneously, and bacterium on clothes can be greatly decreased, and also improves fabric uvioresistant performance, protects health.
Description
Technical field
The present invention relates to technical field of textile auxiliary agent, specifically, being related to a kind of graphene concentrator and its preparation side
Method.
Background technology
PRINTED FABRIC is the product rich in artistry, selects dyestuff or pigment on textile fabric according to the floral designs of design
Stamp line is applied, and then floral designs is made to be formed on the fabric.Common printing technology has direct printing, drives dye transfer flower and discharge print
Spend three kinds.Direct printing is that first directly print is obtained using the post-processings such as evaporating with dyestuff or pigment on white or light-colored fabric
Decorative pattern is obtained, technological process is short, most widely used.Drive dye transfer flower be first print on the fabric with drive on dyestuff contaminate or develop the color substance,
Then it is dyed or is developed the color, to obtain decorative pattern on dyed fabric.Discharge printing is printed on dyed fabric to eliminate dye
The substance of color dyestuff obtains the printing technology of decorative pattern on dyed fabric.
Existing concentrator is a kind of organic substance with general colloidal nature, can dissolve or expand in water, at
It, can be to be printed as the delivery agent that dyestuff and other chemicals are attached to fabric for sticky and rich plastic paste
It is eliminated after flower fixation.Slurry itself is simultaneously not involved in the chemical reaction in stamp, only plays instrumentality.Concentrator presses it
Property and attribute can be divided into 6 classes：1. starch and its derivative, such as wheaten starch, corn starch, flour and dextrin.②
Plant type glue class, such as imperial glue, natural gum, algin and Bletilla glucomannan.3. animal-type slurry, such as chitin glue.4. mineral type slurry, such as
Starching clay.5. chemical sizwe, such as hydroxymethyl cellulose, methylcellulose, hydroxymethyl starch and emulsion paste.6. other slurries,
Such as wood molasses, acorn nut powder and field benevolence powder.
However it uses printed fabric made from existing concentrator that there are still permeability is poor, color fastness and washing jail
The problems such as degree difference, and anti-microbial property is also bad.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of graphene concentrators and preparation method thereof.
The purpose of the present invention is what is be achieved through the following technical solutions：
The present invention provides a kind of graphene concentrators, include each component of following mass percentage：
Preferably, the preparation method of the graphene microcapsules includes the following steps：
Graphene powder is scattered in deionized water, then adds dispersant, ultrasonic 30min~60min, dispersion is
It is even；
Finely dispersed graphene slurry is subjected to microencapsulation processing, obtains graphene microcapsules.
The present invention uses the graphene of microencapsulation processing, can reduce graphene reunion, improve graphene in the solution
Dispersion effect.
Preferably, the graphene powder is by mechanically pulling off method, liquid phase stripping method, chemical vapour deposition technique, oxidation also
It is prepared by a kind of method in former method.
Preferably, the addition of the dispersant is the 1%~5% of graphene powder；The dispersant is selected from polyethylene
Alcohol, polyethylene glycol, sodium lignin sulfonate, polyethylene pyrrole network alkanone, cetyl trimethylammonium bromide, dodecyl sodium sulfate,
One or more of lauryl sodium sulfate.Being added with for dispersant is conducive to preferably dyeing.
Preferably, a concentration of 0.1-5mg/ml of the graphene powder in deionized water.
Preferably, the grain size of the graphene microcapsules is less than 5 μm.
Preferably, the thickener is one kind or several in methyl acrylate, butyl acrylate, double acrylic acid fourth diester
Kind.
The present invention also provides a kind of preparation methods of graphene concentrator, include the following steps：
Graphene microcapsules are mixed with sodium alginate, calcium carbonate, sodium cellulose glycolate, urea, stir dye, then
Ultrasonic disperse is uniform；Thickener is added to stir evenly up to the graphene concentrator.
Preferably, the speed of agitator used that is stirred turns/min for 400-600, and mixing time is 20~30min；
The time of the ultrasonic disperse is 20~40min.
Compared with prior art, the present invention has following advantageous effect：
Graphene, which is one kind, has carbon atom by two-dimensional material made of hexagonal array, is that this century is most subversive new
Material, graphene monoatomic layer two-dimensional sheet structure so that graphene has peculiar performance in many aspects, and such as excellent is anti-
Bacterium property, far infrared heating, uvioresistant function etc. significantly enhance the application range of graphene.The present invention is in concentrator
Graphene microcapsules are added, and proportioning is optimized with other components, can be produced by Conventional decal technique and prepare pattern essence
Beautiful printed fabric, gained printed fabric have good permeability, firm coloration, and Washing can reach 4 grades or more.
The concentrator has the performances such as excellent antibiotic property, uvioresistant simultaneously, and bacterium on clothes can be greatly decreased, also improve fabric
Uvioresistant performance protects health.
Graphene concentrator prepared by this method, simple for process easy to operate, of low cost, high financial profit are suitble to big
Technical scale metaplasia is produced.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment 1-6
Present embodiments provide a kind of graphene concentrator and preparation method thereof, each group of the graphene concentrator
Divide and mass percentage is as shown in table 1.
The preparation method of the graphene concentrator is as follows：
Step 1：The graphene powder of preparation is scattered in deionized water, configuration concentration is the water-soluble of 0.1~5mg/ml
Liquid, and dispersant is added in proportion.Then by its ultrasound 30min~60min, it is made to be uniformly dispersed；
The graphene powder is by mechanically pulling off in method, liquid phase stripping method, chemical vapour deposition technique, oxidation-reduction method
A kind of method preparation；
The addition of the dispersant is the 1%~5% of graphene powder；The dispersant is selected from polyvinyl alcohol, poly- second
Glycol, sodium lignin sulfonate, polyethylene pyrrole network alkanone, cetyl trimethylammonium bromide, dodecyl sodium sulfate, dodecyl
One or more of sodium sulphate.
Step 2：Above-mentioned graphene slurry is subjected to microcapsules technology processing, gained graphene microcapsules diameter of particle is small
In 5 μm；
Step 3：Sodium alginate, calcium carbonate, sodium cellulose glycolate, urea, dyestuff are added to the micro- glue of above-mentioned graphene
In capsule, blender stirs 20~30min, and stir speed (S.S.) is 500 turns/min, then 20~40min of ultrasonic disperse；
Step 4：Finally thickener is added in slurry and is carried out, as graphene concentrator；The thickener is selected from
One or more of methyl acrylate, butyl acrylate, double acrylic acid fourth diester.
Table 1
Comparative example 1-5
This comparative example provides a kind of graphene concentrator and preparation method thereof, each group of the graphene concentrator
Divide and mass percentage is as shown in table 2.Wherein：Comparative example 1 compared with Example 1, does not add graphene microcapsules；Comparative example
2 compared with Example 4, and graphene microcapsule content is excessive；Comparative example 3 compared with Example 2, does not add urea；Comparative example 4 with
Embodiment 4 is compared, and dye content is excessive；Comparative example 5 compared with Example 4, does not add calcium carbonate.
The preparation method of the graphene concentrator is identical as embodiment.
Table 2
Comparative example 6
This comparative example provides a kind of graphene concentrator and preparation method thereof, each group of the graphene concentrator
Divide and mass percentage is substantially the same manner as Example 1, the difference is that only：In this comparative example, using step in embodiment
Graphene slurry made from one is directly used in instead of graphene microcapsules in step 3.
Comparative example 7
This comparative example provides a kind of graphene concentrator and preparation method thereof, each group of the graphene concentrator
Divide and mass percentage is substantially the same manner as Example 1, the difference is that only：In this comparative example, the micro- glue of graphene of use
The grain size of capsule is 10 μm.
Compliance test result：
Graphene concentrator prepared by above example and comparative example is tested for the property, test method is with reference to as follows
Standard：
Uvioresistant testing standard：AATCC 183-2010
Antibacterial test standard：AATCC 100-2012
Washing fastness testing standard：GB/T 12490-2007
Color fastness testing standard：GB/T 3920-2008
Test result is as shown in table 3.
Table 3
There are many concrete application approach of the present invention, the above is only a preferred embodiment of the present invention.More than it should be pointed out that
Embodiment is merely to illustrate the present invention, and the protection domain being not intended to restrict the invention.For the common skill of the art
For art personnel, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as this hair
Bright protection domain.
Claims (9)
1. a kind of graphene concentrator, which is characterized in that include each component of following mass percentage：
2. graphene concentrator according to claim 1, which is characterized in that the preparation method of the graphene microcapsules
Include the following steps：
Graphene powder is scattered in deionized water, dispersant is then added, ultrasonic 30min~60min is uniformly dispersed；
Finely dispersed graphene slurry is subjected to microencapsulation processing, obtains graphene microcapsules.
3. graphene concentrator according to claim 2, which is characterized in that the graphene powder is by mechanically pulling off
It is prepared by a kind of method in method, liquid phase stripping method, chemical vapour deposition technique, oxidation-reduction method.
4. graphene concentrator according to claim 2, which is characterized in that the addition of the dispersant is graphene
The 1%~5% of powder；The dispersant is selected from polyvinyl alcohol, polyethylene glycol, sodium lignin sulfonate, polyethylene pyrrole network alkanone, ten
One or more of six alkyl trimethyl ammonium bromides, dodecyl sodium sulfate, lauryl sodium sulfate.
5. graphene concentrator according to claim 2, which is characterized in that the graphene powder is in deionized water
A concentration of 0.1-5mg/ml.
6. graphene concentrator according to claim 1 or 2, which is characterized in that the grain size of the graphene microcapsules
Less than 5 μm.
7. graphene concentrator according to claim 1, which is characterized in that the thickener is methyl acrylate, third
One or more of olefin(e) acid butyl ester, double acrylic acid fourth diester.
8. a kind of preparation method of graphene concentrator according to claim 1, which is characterized in that including following step
Suddenly：
Graphene microcapsules are mixed with sodium alginate, calcium carbonate, sodium cellulose glycolate, urea, stir dye, it is then ultrasonic
It is uniformly dispersed；Thickener is added to stir evenly up to the graphene concentrator.
9. the preparation method of graphene concentrator according to claim 8, which is characterized in that described to be stirred use
Speed of agitator be 400-600 turn/min, mixing time be 20~30min；The time of the ultrasonic disperse is 20~40min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396838A (en) * | 2019-07-19 | 2019-11-01 | 浙江海印数码科技有限公司 | Modified ink-jet printed use coating type ink of a kind of compound particle based on multilevel structure and preparation method thereof, application |
| CN110699983A (en) * | 2019-10-29 | 2020-01-17 | 太仓宝霓实业有限公司 | Reactive dye dyeing promoter composition and preparation method thereof |
| CN110871054A (en) * | 2018-08-31 | 2020-03-10 | 侯梦斌 | Preparation process of activated carbon water slurry agent |
| CN111621998A (en) * | 2020-07-02 | 2020-09-04 | 无锡恒诺纺织科技有限公司 | Preparation method of heating color paste |
| CN112411211A (en) * | 2020-11-25 | 2021-02-26 | 宁波市砥中材料应用有限公司 | Graphene far-infrared health-care antibacterial printing coating and preparation method thereof |
| CN116040671A (en) * | 2022-12-28 | 2023-05-02 | 广西华纳新材料股份有限公司 | Preparation method of flaky calcium carbonate |
| CN117071303A (en) * | 2023-10-16 | 2023-11-17 | 波司登羽绒服装有限公司 | Composite printing paste, antibacterial antistatic thermal fabric and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103938470A (en) * | 2014-04-04 | 2014-07-23 | 朱益锋 | Digital printing color fixing agent for woolen sweater |
| CN103966868A (en) * | 2014-05-15 | 2014-08-06 | 朱益锋 | Printing paste capable of releasing anion |
| CN105970681A (en) * | 2016-06-20 | 2016-09-28 | 湖州新隆龙丝绸印花有限公司 | Environment-friendly brown digital printing ink and preparation method thereof |
| CN106012590A (en) * | 2016-06-20 | 2016-10-12 | 湖州新隆龙丝绸印花有限公司 | Environment-friendly blue ink for digital printing and preparation method thereof |
| CN106400506A (en) * | 2016-09-21 | 2017-02-15 | 东莞市联洲知识产权运营管理有限公司 | Waterborne polyurethane textile size based on graphene modification and preparation method thereof |
| CN107740289A (en) * | 2017-10-19 | 2018-02-27 | 无锡嘉加科技有限公司 | A kind of anhydrous printing with reactive dye ink and preparation method thereof |
| CN107740288A (en) * | 2017-10-19 | 2018-02-27 | 无锡嘉加科技有限公司 | A kind of wool anhydrous printing ink and preparation method thereof |
-
2018
- 2018-06-13 CN CN201810609158.7A patent/CN108797152A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103938470A (en) * | 2014-04-04 | 2014-07-23 | 朱益锋 | Digital printing color fixing agent for woolen sweater |
| CN103966868A (en) * | 2014-05-15 | 2014-08-06 | 朱益锋 | Printing paste capable of releasing anion |
| CN105970681A (en) * | 2016-06-20 | 2016-09-28 | 湖州新隆龙丝绸印花有限公司 | Environment-friendly brown digital printing ink and preparation method thereof |
| CN106012590A (en) * | 2016-06-20 | 2016-10-12 | 湖州新隆龙丝绸印花有限公司 | Environment-friendly blue ink for digital printing and preparation method thereof |
| CN106400506A (en) * | 2016-09-21 | 2017-02-15 | 东莞市联洲知识产权运营管理有限公司 | Waterborne polyurethane textile size based on graphene modification and preparation method thereof |
| CN107740289A (en) * | 2017-10-19 | 2018-02-27 | 无锡嘉加科技有限公司 | A kind of anhydrous printing with reactive dye ink and preparation method thereof |
| CN107740288A (en) * | 2017-10-19 | 2018-02-27 | 无锡嘉加科技有限公司 | A kind of wool anhydrous printing ink and preparation method thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110871054A (en) * | 2018-08-31 | 2020-03-10 | 侯梦斌 | Preparation process of activated carbon water slurry agent |
| CN110396838A (en) * | 2019-07-19 | 2019-11-01 | 浙江海印数码科技有限公司 | Modified ink-jet printed use coating type ink of a kind of compound particle based on multilevel structure and preparation method thereof, application |
| CN110396838B (en) * | 2019-07-19 | 2022-04-01 | 浙江海印数码科技有限公司 | Multi-stage structure based composite particle modified coating type ink for inkjet printing, and preparation method and application thereof |
| CN110699983A (en) * | 2019-10-29 | 2020-01-17 | 太仓宝霓实业有限公司 | Reactive dye dyeing promoter composition and preparation method thereof |
| CN110699983B (en) * | 2019-10-29 | 2022-01-04 | 太仓宝霓实业有限公司 | Reactive dye dyeing promoter composition and preparation method thereof |
| CN111621998A (en) * | 2020-07-02 | 2020-09-04 | 无锡恒诺纺织科技有限公司 | Preparation method of heating color paste |
| CN112411211A (en) * | 2020-11-25 | 2021-02-26 | 宁波市砥中材料应用有限公司 | Graphene far-infrared health-care antibacterial printing coating and preparation method thereof |
| CN116040671A (en) * | 2022-12-28 | 2023-05-02 | 广西华纳新材料股份有限公司 | Preparation method of flaky calcium carbonate |
| CN116040671B (en) * | 2022-12-28 | 2024-05-03 | 广西华纳新材料股份有限公司 | Preparation method of flaky calcium carbonate |
| CN117071303A (en) * | 2023-10-16 | 2023-11-17 | 波司登羽绒服装有限公司 | Composite printing paste, antibacterial antistatic thermal fabric and application thereof |
| CN117071303B (en) * | 2023-10-16 | 2024-01-05 | 波司登羽绒服装有限公司 | Composite printing paste, antibacterial antistatic thermal fabric and application thereof |
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Application publication date: 20181113 |