CN108774067A - A kind of ceramic water-permeable brick and preparation method thereof produced using shraff and stalk - Google Patents
A kind of ceramic water-permeable brick and preparation method thereof produced using shraff and stalk Download PDFInfo
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- CN108774067A CN108774067A CN201810640027.5A CN201810640027A CN108774067A CN 108774067 A CN108774067 A CN 108774067A CN 201810640027 A CN201810640027 A CN 201810640027A CN 108774067 A CN108774067 A CN 108774067A
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- shraff
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/063—Preparing or treating the raw materials individually or as batches
- C04B38/0635—Compounding ingredients
- C04B38/0645—Burnable, meltable, sublimable materials
- C04B38/0675—Vegetable refuse; Cellulosic materials, e.g. wood chips, cork, peat, paper
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C15/00—Pavings specially adapted for footpaths, sidewalks or cycle tracks
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C5/00—Pavings made of prefabricated single units
- E01C5/04—Pavings made of prefabricated single units made of bricks
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Civil Engineering (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Road Paving Structures (AREA)
Abstract
The invention discloses a kind of ceramic water-permeable brick produced using shraff and stalk, the idiosome of the ceramic water-permeable brick is that mainly the grade distribution structure made of bottom aggregate knead dough layer aggregate, the bottom aggregate are mainly made of the raw material of following proportion by weight:4~10 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3, the face layer aggregate are mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3.The ceramic water-permeable brick is produced using shraff and stalk, simultaneously using the distributing mode of grading and natural pore forming material, the inside blockage problem of water-permeable brick generally existing can be effectively improved, also shraff and agricultural waste stalk can be made full use of, it reduces occupation of land and agricultural stalk burns the atmosphere polluting problem brought, reduce to the pollutions such as soil and water source, air.
Description
Technical field
The invention belongs to water-permeable brick technical fields, and in particular to a kind of ceramic water permeable produced using shraff and stalk
Brick and preparation method thereof.
Background technology
China urban construction obtains apparent achievement, but exists simultaneously that mining inetesity is high, hard is mated formation the problems such as more.City
Large scale construction, which changes the Facilities Constructions such as the structure of original underlying surface, especially roofing, road, leads to underlying surface overvulcanization,
Change the original natural, ecological background in city and hydrological characteristics, 70% or more rainfall forms runoff, and " heavy rain must flood, rain in city
It is i.e. non-irrigated afterwards ".A large amount of hard grounds are discharged into pipe network with leading to excessive rainfall, to pipe instead of the ground with penetrating power
Net causes to impact, and has exceeded the drainability of pipe network, to there are a large amount of waterloggings, has seriously affected life and the city of the common people
Orderly function.It, can if being by general purpose hard underlying surface construction for the outstanding problem of waterlogging and city underlying surface hardening
Urban waterlogging problem is effectively relieved in the very big discharge pressure for alleviating city planting ductwork with permeable underlying surface.
China's ceramic industry is fast-developing, waste ceramic and the polished bricks mill that ceramics waste material is increasing, and pile up like a mountain
Bits etc. not only take up an area but also pollute air and water source, exert heavy pressures on to urban environment, so the processing of ceramic industry waste material
It is extremely important with utilizing.Currently, the producing level of China's ceramic industry waste material is relatively low, how to turn waste into wealth, it is money to change waste material
Source, oneself is through becoming the scientific and technological task of top priority with environmental protection administration.How shraff and waste product are utilized, and gone out for its feature development
New product is urgent problem.
In addition, agricultural stalk burning causes serious atmosphere pollution, it is detrimental to health, straw collecting Utilizing question is badly in need of
It solves.
Currently, there is the exploration for producing water-permeable brick using waste old ceramics.Such as:
CN102351508A discloses a kind of production method using the porcelain colorful ceramic brick that gives up, including:Useless porcelain 50-
60%, clay 0-50%, toner etc..Clay is natural resources, and accounting is larger in material prescription, and product can cause nature to provide
The corresponding consumption in source.
CN0Z151782 discloses a kind of production technology for the novel environment friendly ecological architectural material being related to refuse reclamation, profit
The production technology that environment friendly pervious air brick is quickly fired with roller kilns, with industrial residues such as waste ceramic, refractory material, slags, certainly
Right coal grinds clear stone, waste incineration, urban sewer sludge, waste plastics, this bits, bamboo scraps and mountain organic matter and inorganic matter and constitutes and mix
The special low temperature adhesive of object is raw material.Raw material is complicated, ingredient is unstable, and the pollution that cannot fundamentally solve ceramic industry is asked
Topic.
Therefore, shraff and agricultural stalk how are made full use of, shraff occupation of land is reduced and agricultural stalk burns
The atmosphere polluting problem brought reduces the pollution to soil, water source and air etc., is that technology urgently to be resolved hurrily is needed to ask at present
Topic.
Invention content
The object of the present invention is to provide a kind of ceramic water-permeable bricks produced using shraff and stalk.The ceramic water-permeable brick
It is produced using shraff and stalk, while using the distributing mode of grading and natural pore forming material, can be effectively improved permeable
The inside blockage problem of brick generally existing can also make full use of shraff and agricultural waste stalk, reduce occupation of land and agriculture straw
Stalk burns the atmosphere polluting problem brought, reduces to the pollutions such as soil and water source, air.
The present invention also aims to provide the preparation side of the above-mentioned ceramic water-permeable brick produced using shraff and stalk
Method.
First purpose of the present invention is achieved through the following technical solutions:It is a kind of to be given birth to using shraff and stalk
The ceramic water-permeable brick of production, the main grade distribution structure made of bottom aggregate knead dough layer aggregate of the idiosome of the ceramic water-permeable brick,
Described in bottom aggregate be mainly made of the raw material of following proportion by weight:4~10 mesh shraff particles 70~90, binder
3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3, the face layer aggregate is mainly by the raw material system of following proportion by weight
At:10~16 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3.
Shraff particle of the present invention preferably uses waste ceramic product, the substandard products of ceramic product and breakage ceramics
One or more of it is broken after grind and be made.
Shraff carries out particle size of the crushing grinding at above-mentioned mesh number preferably by crusher.
Bottom aggregate 4~10 mesh shraff particles of selection, the larger porosity of guarantee bottom, face layer aggregate selection 10~
16 mesh shraff particles can retain larger pollutant and enter inside water-permeable brick.
Binder of the present invention is preferably bentonite and waterglass.
Fluxing agent of the present invention is preferably feldspar.
Organic plasticizers of the present invention are preferably carboxyl methyl cellulose.
Second object of the present invention is achieved through the following technical solutions:It is above-mentioned to be given birth to using shraff and stalk
The preparation method of the ceramic water-permeable brick of production, includes the following steps:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made
Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made
Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1050~1250 DEG C and is fired, and cooling discharge utilizes pottery to obtain the final product
The ceramic water-permeable brick of porcelain waste material production.
The thickness of bottom aggregate is preferably 40~50mm described in step (3) of the present invention, and the thickness of the face layer aggregate is excellent
It is selected as 10~15mm.
Compared with prior art, the present invention has the following advantages:
(1) ceramic water-permeable brick of the present invention fully recycles shraff, reduces shraff and takes up an area, reduce to soil and
The pollutions such as water source;
(2) ceramic water-permeable brick of the present invention can recycle agricultural stalk, reduce atmosphere pollution caused by crop straw burning;
(3) ceramic water-permeable brick of the present invention is using the double-deck grading fabric construction, and 4~10 mesh shraff particles are as bottom bone
The raw material of material, raw material of 10~16 mesh shraff particles as face layer aggregate, can be effectively improved using the distributing mode of grading
The inside blockage problem of water-permeable brick generally existing;
(4) ceramic water-permeable brick of the present invention can improve the osmotic adjustment ability of hardening underlying surface, be conducive to rainwater and infiltrate on the spot,
Avoid the destruction to hydrologic condition;
(5) rainwater quickly pressure of the exclusion to city planting ductwork can be effectively relieved in the ceramic water-permeable brick in the present invention when in use
Power improves region microenvironment and alleviates urban heat land effect, is widely portable to square, shopping mall, garden, cell, municipal administration
Engineering etc..
Specific implementation mode
Embodiment 1
The ceramic water-permeable brick provided in this embodiment produced using shraff and stalk, the idiosome of the ceramic water-permeable brick are
The mainly grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein bottom aggregate is mainly by the raw material of following proportion by weight
It is made:4~10 mesh shraff particles 70, binder 6, fluxing agent 1, organic plasticizers and stalk (being used as pore creating material) 3,
Face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 70, binder 6, fluxing agent
1, organic plasticizers and stalk 3.
The binder is bentonite and waterglass;Fluxing agent is feldspar;Organic plasticizers are carboxyl methyl cellulose.
After shraff particle is crushed using the substandard products of ceramic product made of grinding.
The preparation method of the above-mentioned ceramic water-permeable brick produced using shraff and stalk is as follows:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made
Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made
Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1050 DEG C and fired, and cooling discharge utilizes shraff to obtain the final product
The ceramic water-permeable brick of production.
The thickness of bottom embryo material is 40mm in step (3), and the thickness of face layer embryo material is 10mm.
Embodiment 2
The ceramic water-permeable brick provided in this embodiment produced using shraff and stalk, the idiosome of the ceramic water-permeable brick are
The mainly grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein bottom aggregate is mainly by the raw material of following proportion by weight
It is made:4~10 mesh shraff particles 80, binder 4.5, fluxing agent 2, organic plasticizers and stalk (being used as pore creating material)
2, face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 80, help binder 4.5
Flux 2, organic plasticizers and stalk 2.
The binder is bentonite and waterglass;Fluxing agent is feldspar;Organic plasticizers are carboxyl methyl cellulose.
After shraff particle is crushed using waste ceramic product and damaged ceramics made of grinding.
The preparation method of the above-mentioned ceramic water-permeable brick using shraff production is as follows:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made
Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made
Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1100 DEG C and fired, and cooling discharge utilizes shraff to obtain the final product
The ceramic water-permeable brick of production.
The thickness of bottom embryo material is 43mm in step (3), and the thickness of face layer embryo material is 12mm.
Embodiment 3
The ceramic water-permeable brick provided in this embodiment produced using shraff and stalk, the idiosome of the ceramic water-permeable brick are
The mainly grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein bottom aggregate is mainly by the raw material of following proportion by weight
It is made:4~10 mesh shraff particles 90, binder 3, fluxing agent 3, organic plasticizers and stalk (being used as pore creating material) 1,
Face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 90, binder 3, fluxing agent
3, organic plasticizers and stalk 1.
The binder is bentonite and waterglass;Fluxing agent is feldspar;Organic plasticizers are carboxyl methyl cellulose.
After shraff particle is crushed using waste ceramic product made of grinding.
The preparation method of the above-mentioned ceramic water-permeable brick using shraff production is as follows:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made
Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use
10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made
Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1250 DEG C and fired, and cooling discharge utilizes shraff to obtain the final product
The ceramic water-permeable brick of production.
The thickness of bottom embryo material is 50mm in step (3), and the thickness of face layer embryo material is 10mm.
The foregoing is only a preferred embodiment of the present invention, core of the invention thought is comprehensive utilization ceramics
Waste material and agricultural stalk, using stalk as natural pore forming material.But scope of protection of the present invention is not limited thereto, every
In technical scope of the present invention, according to the technique and scheme of the present invention and its design of the hierarchical with cloth is replaced or is changed
Become, building waste is replaced with into other waste materials, agricultural stalk is replaced with into other fiber combustible materials etc., should all be covered in this hair
In bright protection domain.
Claims (7)
1. a kind of ceramic water-permeable brick produced using shraff and stalk, it is characterized in that:The idiosome master of the ceramic water-permeable brick
Will the grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein the bottom bone material is mainly by the original of following proportion by weight
Material is made:4~10 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3,
The face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 70~90, binder 3
~6, fluxing agent 1~3, organic plasticizers and stalk 1~3.
2. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:The pottery
Porcelain waste granules grind system after being crushed using one or more of waste ceramic product, the substandard products of ceramic product and breakage ceramics
At.
3. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:Described is viscous
It is bentonite and waterglass to tie agent.
4. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:Described helps
Flux is feldspar.
5. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:Described has
Machine plasticizer is carboxyl methyl cellulose.
6. the preparation method for the ceramic water-permeable brick that claim 1-5 any one of them is produced using shraff and stalk,
It is characterized in including the following steps:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, are closed by above-mentioned dosage
System, adds water mixing by 4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk, and bottom aggregate is made;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, are closed by above-mentioned dosage
System, adds water mixing by 10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk, and face layer bone is made
Material;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1050~1250 DEG C and fired, and cooling discharge utilizes waste ceramic to obtain the final product
Expect the ceramic water-permeable brick of production.
7. the preparation method of the ceramic water-permeable brick according to claim 6 produced using shraff and stalk, feature
It is:The thickness of bottom aggregate described in step (3) is 40~50mm, and the thickness of the face layer aggregate is 10~15mm.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109650777A (en) * | 2018-12-29 | 2019-04-19 | 佛山生态海绵城市科技发展有限公司 | A kind of composite water permeable brick and preparation method thereof |
-
2018
- 2018-06-21 CN CN201810640027.5A patent/CN108774067A/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109650777A (en) * | 2018-12-29 | 2019-04-19 | 佛山生态海绵城市科技发展有限公司 | A kind of composite water permeable brick and preparation method thereof |
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Application publication date: 20181109 |