CN108774067A - A kind of ceramic water-permeable brick and preparation method thereof produced using shraff and stalk - Google Patents

A kind of ceramic water-permeable brick and preparation method thereof produced using shraff and stalk Download PDF

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Publication number
CN108774067A
CN108774067A CN201810640027.5A CN201810640027A CN108774067A CN 108774067 A CN108774067 A CN 108774067A CN 201810640027 A CN201810640027 A CN 201810640027A CN 108774067 A CN108774067 A CN 108774067A
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Prior art keywords
shraff
stalk
permeable brick
aggregate
mesh
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CN201810640027.5A
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丁左宏
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Jiangsu Tianzige New Material Technology Co Ltd
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Jiangsu Tianzige New Material Technology Co Ltd
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Publication of CN108774067A publication Critical patent/CN108774067A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/0675Vegetable refuse; Cellulosic materials, e.g. wood chips, cork, peat, paper
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C15/00Pavings specially adapted for footpaths, sidewalks or cycle tracks
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/04Pavings made of prefabricated single units made of bricks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602Making the green bodies or pre-forms by moulding
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention discloses a kind of ceramic water-permeable brick produced using shraff and stalk, the idiosome of the ceramic water-permeable brick is that mainly the grade distribution structure made of bottom aggregate knead dough layer aggregate, the bottom aggregate are mainly made of the raw material of following proportion by weight:4~10 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3, the face layer aggregate are mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3.The ceramic water-permeable brick is produced using shraff and stalk, simultaneously using the distributing mode of grading and natural pore forming material, the inside blockage problem of water-permeable brick generally existing can be effectively improved, also shraff and agricultural waste stalk can be made full use of, it reduces occupation of land and agricultural stalk burns the atmosphere polluting problem brought, reduce to the pollutions such as soil and water source, air.

Description

A kind of ceramic water-permeable brick and preparation method thereof produced using shraff and stalk
Technical field
The invention belongs to water-permeable brick technical fields, and in particular to a kind of ceramic water permeable produced using shraff and stalk Brick and preparation method thereof.
Background technology
China urban construction obtains apparent achievement, but exists simultaneously that mining inetesity is high, hard is mated formation the problems such as more.City Large scale construction, which changes the Facilities Constructions such as the structure of original underlying surface, especially roofing, road, leads to underlying surface overvulcanization, Change the original natural, ecological background in city and hydrological characteristics, 70% or more rainfall forms runoff, and " heavy rain must flood, rain in city It is i.e. non-irrigated afterwards ".A large amount of hard grounds are discharged into pipe network with leading to excessive rainfall, to pipe instead of the ground with penetrating power Net causes to impact, and has exceeded the drainability of pipe network, to there are a large amount of waterloggings, has seriously affected life and the city of the common people Orderly function.It, can if being by general purpose hard underlying surface construction for the outstanding problem of waterlogging and city underlying surface hardening Urban waterlogging problem is effectively relieved in the very big discharge pressure for alleviating city planting ductwork with permeable underlying surface.
China's ceramic industry is fast-developing, waste ceramic and the polished bricks mill that ceramics waste material is increasing, and pile up like a mountain Bits etc. not only take up an area but also pollute air and water source, exert heavy pressures on to urban environment, so the processing of ceramic industry waste material It is extremely important with utilizing.Currently, the producing level of China's ceramic industry waste material is relatively low, how to turn waste into wealth, it is money to change waste material Source, oneself is through becoming the scientific and technological task of top priority with environmental protection administration.How shraff and waste product are utilized, and gone out for its feature development New product is urgent problem.
In addition, agricultural stalk burning causes serious atmosphere pollution, it is detrimental to health, straw collecting Utilizing question is badly in need of It solves.
Currently, there is the exploration for producing water-permeable brick using waste old ceramics.Such as:
CN102351508A discloses a kind of production method using the porcelain colorful ceramic brick that gives up, including:Useless porcelain 50- 60%, clay 0-50%, toner etc..Clay is natural resources, and accounting is larger in material prescription, and product can cause nature to provide The corresponding consumption in source.
CN0Z151782 discloses a kind of production technology for the novel environment friendly ecological architectural material being related to refuse reclamation, profit The production technology that environment friendly pervious air brick is quickly fired with roller kilns, with industrial residues such as waste ceramic, refractory material, slags, certainly Right coal grinds clear stone, waste incineration, urban sewer sludge, waste plastics, this bits, bamboo scraps and mountain organic matter and inorganic matter and constitutes and mix The special low temperature adhesive of object is raw material.Raw material is complicated, ingredient is unstable, and the pollution that cannot fundamentally solve ceramic industry is asked Topic.
Therefore, shraff and agricultural stalk how are made full use of, shraff occupation of land is reduced and agricultural stalk burns The atmosphere polluting problem brought reduces the pollution to soil, water source and air etc., is that technology urgently to be resolved hurrily is needed to ask at present Topic.
Invention content
The object of the present invention is to provide a kind of ceramic water-permeable bricks produced using shraff and stalk.The ceramic water-permeable brick It is produced using shraff and stalk, while using the distributing mode of grading and natural pore forming material, can be effectively improved permeable The inside blockage problem of brick generally existing can also make full use of shraff and agricultural waste stalk, reduce occupation of land and agriculture straw Stalk burns the atmosphere polluting problem brought, reduces to the pollutions such as soil and water source, air.
The present invention also aims to provide the preparation side of the above-mentioned ceramic water-permeable brick produced using shraff and stalk Method.
First purpose of the present invention is achieved through the following technical solutions:It is a kind of to be given birth to using shraff and stalk The ceramic water-permeable brick of production, the main grade distribution structure made of bottom aggregate knead dough layer aggregate of the idiosome of the ceramic water-permeable brick, Described in bottom aggregate be mainly made of the raw material of following proportion by weight:4~10 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3, the face layer aggregate is mainly by the raw material system of following proportion by weight At:10~16 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3.
Shraff particle of the present invention preferably uses waste ceramic product, the substandard products of ceramic product and breakage ceramics One or more of it is broken after grind and be made.
Shraff carries out particle size of the crushing grinding at above-mentioned mesh number preferably by crusher.
Bottom aggregate 4~10 mesh shraff particles of selection, the larger porosity of guarantee bottom, face layer aggregate selection 10~ 16 mesh shraff particles can retain larger pollutant and enter inside water-permeable brick.
Binder of the present invention is preferably bentonite and waterglass.
Fluxing agent of the present invention is preferably feldspar.
Organic plasticizers of the present invention are preferably carboxyl methyl cellulose.
Second object of the present invention is achieved through the following technical solutions:It is above-mentioned to be given birth to using shraff and stalk The preparation method of the ceramic water-permeable brick of production, includes the following steps:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1050~1250 DEG C and is fired, and cooling discharge utilizes pottery to obtain the final product The ceramic water-permeable brick of porcelain waste material production.
The thickness of bottom aggregate is preferably 40~50mm described in step (3) of the present invention, and the thickness of the face layer aggregate is excellent It is selected as 10~15mm.
Compared with prior art, the present invention has the following advantages:
(1) ceramic water-permeable brick of the present invention fully recycles shraff, reduces shraff and takes up an area, reduce to soil and The pollutions such as water source;
(2) ceramic water-permeable brick of the present invention can recycle agricultural stalk, reduce atmosphere pollution caused by crop straw burning;
(3) ceramic water-permeable brick of the present invention is using the double-deck grading fabric construction, and 4~10 mesh shraff particles are as bottom bone The raw material of material, raw material of 10~16 mesh shraff particles as face layer aggregate, can be effectively improved using the distributing mode of grading The inside blockage problem of water-permeable brick generally existing;
(4) ceramic water-permeable brick of the present invention can improve the osmotic adjustment ability of hardening underlying surface, be conducive to rainwater and infiltrate on the spot, Avoid the destruction to hydrologic condition;
(5) rainwater quickly pressure of the exclusion to city planting ductwork can be effectively relieved in the ceramic water-permeable brick in the present invention when in use Power improves region microenvironment and alleviates urban heat land effect, is widely portable to square, shopping mall, garden, cell, municipal administration Engineering etc..
Specific implementation mode
Embodiment 1
The ceramic water-permeable brick provided in this embodiment produced using shraff and stalk, the idiosome of the ceramic water-permeable brick are The mainly grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein bottom aggregate is mainly by the raw material of following proportion by weight It is made:4~10 mesh shraff particles 70, binder 6, fluxing agent 1, organic plasticizers and stalk (being used as pore creating material) 3, Face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 70, binder 6, fluxing agent 1, organic plasticizers and stalk 3.
The binder is bentonite and waterglass;Fluxing agent is feldspar;Organic plasticizers are carboxyl methyl cellulose.
After shraff particle is crushed using the substandard products of ceramic product made of grinding.
The preparation method of the above-mentioned ceramic water-permeable brick produced using shraff and stalk is as follows:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1050 DEG C and fired, and cooling discharge utilizes shraff to obtain the final product The ceramic water-permeable brick of production.
The thickness of bottom embryo material is 40mm in step (3), and the thickness of face layer embryo material is 10mm.
Embodiment 2
The ceramic water-permeable brick provided in this embodiment produced using shraff and stalk, the idiosome of the ceramic water-permeable brick are The mainly grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein bottom aggregate is mainly by the raw material of following proportion by weight It is made:4~10 mesh shraff particles 80, binder 4.5, fluxing agent 2, organic plasticizers and stalk (being used as pore creating material) 2, face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 80, help binder 4.5 Flux 2, organic plasticizers and stalk 2.
The binder is bentonite and waterglass;Fluxing agent is feldspar;Organic plasticizers are carboxyl methyl cellulose.
After shraff particle is crushed using waste ceramic product and damaged ceramics made of grinding.
The preparation method of the above-mentioned ceramic water-permeable brick using shraff production is as follows:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1100 DEG C and fired, and cooling discharge utilizes shraff to obtain the final product The ceramic water-permeable brick of production.
The thickness of bottom embryo material is 43mm in step (3), and the thickness of face layer embryo material is 12mm.
Embodiment 3
The ceramic water-permeable brick provided in this embodiment produced using shraff and stalk, the idiosome of the ceramic water-permeable brick are The mainly grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein bottom aggregate is mainly by the raw material of following proportion by weight It is made:4~10 mesh shraff particles 90, binder 3, fluxing agent 3, organic plasticizers and stalk (being used as pore creating material) 1, Face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 90, binder 3, fluxing agent 3, organic plasticizers and stalk 1.
The binder is bentonite and waterglass;Fluxing agent is feldspar;Organic plasticizers are carboxyl methyl cellulose.
After shraff particle is crushed using waste ceramic product made of grinding.
The preparation method of the above-mentioned ceramic water-permeable brick using shraff production is as follows:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and bottom is made Aggregate;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, by above-mentioned use 10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk are added water mixing by magnitude relation, and face layer is made Aggregate;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1250 DEG C and fired, and cooling discharge utilizes shraff to obtain the final product The ceramic water-permeable brick of production.
The thickness of bottom embryo material is 50mm in step (3), and the thickness of face layer embryo material is 10mm.
The foregoing is only a preferred embodiment of the present invention, core of the invention thought is comprehensive utilization ceramics Waste material and agricultural stalk, using stalk as natural pore forming material.But scope of protection of the present invention is not limited thereto, every In technical scope of the present invention, according to the technique and scheme of the present invention and its design of the hierarchical with cloth is replaced or is changed Become, building waste is replaced with into other waste materials, agricultural stalk is replaced with into other fiber combustible materials etc., should all be covered in this hair In bright protection domain.

Claims (7)

1. a kind of ceramic water-permeable brick produced using shraff and stalk, it is characterized in that:The idiosome master of the ceramic water-permeable brick Will the grade distribution structure made of bottom aggregate knead dough layer aggregate, wherein the bottom bone material is mainly by the original of following proportion by weight Material is made:4~10 mesh shraff particles 70~90, binder 3~6, fluxing agent 1~3, organic plasticizers and stalk 1~3, The face layer aggregate is mainly made of the raw material of following proportion by weight:10~16 mesh shraff particles 70~90, binder 3 ~6, fluxing agent 1~3, organic plasticizers and stalk 1~3.
2. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:The pottery Porcelain waste granules grind system after being crushed using one or more of waste ceramic product, the substandard products of ceramic product and breakage ceramics At.
3. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:Described is viscous It is bentonite and waterglass to tie agent.
4. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:Described helps Flux is feldspar.
5. the ceramic water-permeable brick according to claim 1 produced using shraff and stalk, it is characterized in that:Described has Machine plasticizer is carboxyl methyl cellulose.
6. the preparation method for the ceramic water-permeable brick that claim 1-5 any one of them is produced using shraff and stalk, It is characterized in including the following steps:
(1) 4~10 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, are closed by above-mentioned dosage System, adds water mixing by 4~10 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk, and bottom aggregate is made;
(2) 10~16 mesh shraff particles are prepared, binder, fluxing agent, organic plasticizers and stalk are taken, are closed by above-mentioned dosage System, adds water mixing by 10~16 mesh shraff particles, binder, fluxing agent, organic plasticizers and stalk, and face layer bone is made Material;
(3) bottom aggregate knead dough layer aggregate is placed in mold, a grade distribution structure idiosome is made in compression moulding;
(4) it is finished product above-mentioned grade distribution structure idiosome to be warming up to 1050~1250 DEG C and fired, and cooling discharge utilizes waste ceramic to obtain the final product Expect the ceramic water-permeable brick of production.
7. the preparation method of the ceramic water-permeable brick according to claim 6 produced using shraff and stalk, feature It is:The thickness of bottom aggregate described in step (3) is 40~50mm, and the thickness of the face layer aggregate is 10~15mm.
CN201810640027.5A 2018-06-21 2018-06-21 A kind of ceramic water-permeable brick and preparation method thereof produced using shraff and stalk Withdrawn CN108774067A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109650777A (en) * 2018-12-29 2019-04-19 佛山生态海绵城市科技发展有限公司 A kind of composite water permeable brick and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109650777A (en) * 2018-12-29 2019-04-19 佛山生态海绵城市科技发展有限公司 A kind of composite water permeable brick and preparation method thereof

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Application publication date: 20181109