CN108773147A - A kind of preparation method of Antistatic type high-molecular decorative film - Google Patents

A kind of preparation method of Antistatic type high-molecular decorative film Download PDF

Info

Publication number
CN108773147A
CN108773147A CN201810612073.4A CN201810612073A CN108773147A CN 108773147 A CN108773147 A CN 108773147A CN 201810612073 A CN201810612073 A CN 201810612073A CN 108773147 A CN108773147 A CN 108773147A
Authority
CN
China
Prior art keywords
parts
conductive
titanium dioxide
antistatic
corvic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810612073.4A
Other languages
Chinese (zh)
Inventor
任华
曹婷婷
张翔
张继刚
康拥军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong nanjing university material engineering technology research institute
Sea Of Jiangsu New Materials Co Ltd
Original Assignee
Nantong nanjing university material engineering technology research institute
Sea Of Jiangsu New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong nanjing university material engineering technology research institute, Sea Of Jiangsu New Materials Co Ltd filed Critical Nantong nanjing university material engineering technology research institute
Priority to CN201810612073.4A priority Critical patent/CN108773147A/en
Publication of CN108773147A publication Critical patent/CN108773147A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00—Furniture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2479/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
    • C08J2479/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a kind of preparation methods of the antistatic macromolecule decorating film based on electrically conductive polyaniline and Conductive inorganic filler, including PVC base layer and surface functional layer.Wherein surface functional layer is combined using electrically conductive polyaniline and conduction with polyvinyl chloride, and production stage includes prepared by PVC base layer；The preparation of functional membrane；Hot pressing is bonded.Gained antistatic macromolecule decorating film contains composite conducting auxiliary agent, can significantly reduce the sheet resistance of high-molecular decorative film, it is made to have anti-static function.

Description

A kind of preparation method of Antistatic type high-molecular decorative film
Technical field
The present invention relates to polyvinyl chloride functional technical field of macromolecules, more particularly to a kind of to be based on electrically conductive polyaniline and conduction The preparation method of the PVC macromolecular composite membrane of inorganic filler.
Background technology
PVC macromolecular film exists in recent years because of the features such as its processing and forming is efficient, decoration excellent performance, safety and environmental protection The fields extensive use such as furniture, household electrical appliances, building, traffic.Furnishing fields are applied to various furniture, floor, cabinet, wall indoors Face, furred ceiling etc..
It is especially indoor in family in use, in dirty environment with the continuous expansion of polymeric membrane application field, such as cupboard Cabinet surface decorative film etc., polymeric membrane not only play decoration function, and Functional Requirement is higher and higher, to improve user's body It tests, more strict requirements is proposed for the performances such as dirt, antistatic of refusing of decorating film.Existing conventional polyvinyl chloride macromolecule Film does not have surface conductance ability, and surface resistivity is 109-1012Ω still easily causes the difficulty of charge flowing.Thus, The high-molecular decorative film with anti-static function is developed with highly important application value.
High molecular material anti-static function realizes the introducing for mainly using conductive auxiliary agent, and common includes conductive black, table The introducing of the auxiliary agents such as face activating agent, metal and oxide, when the addition and dispersion of conductive auxiliary agent or filler reach a threshold It is worth, can forms conducting between filler auxiliary agent, form more uniform conductive network inside high molecular material.Obviously, it is filling out Under the premise of expecting that auxiliary agent volume size is similar with deployment conditions, the additive amount of conductive filler is more, to the conduction of high molecular material Performance boost effect becomes apparent, however, conductive filler dosage increase often leads to the decline of high-molecular mechanical performance, or even not It can meet and use minimum performance requirement.On the other hand, it in the manufacturing process of PVC macromolecular film, needs to add titanium dioxide etc. Therefore filler is conductive addition auxiliary agent according to intrinsically conducting polyaniline, while substituting common titanium white with conductive titanium dioxide Powder can improve the conductive characteristic of material under the premise of not influencing high-molecular mechanical performance.
Invention content
It is decorated based on the antistatic macromolecule of electrically conductive polyaniline and Conductive inorganic filler the object of the present invention is to provide a kind of The preparation method of film, including PVC base layer and surface functional layer.Wherein surface functional layer uses electrically conductive polyaniline and conduction It is combined with polyvinyl chloride, production stage includes prepared by PVC base layer；The preparation of functional membrane；Hot pressing is bonded.Gained Antistatic macromolecule decorating film contains composite conducting auxiliary agent, can significantly reduce the sheet resistance of high-molecular decorative film, makes its tool Standby anti-static function.
Technical solution：
A kind of preparation method of Antistatic type high-molecular decorative film, it is characterised in that the Antistatic type polymeric membrane includes polychlorostyrene second Alkenyl layer base material and antistatic surface film layer, the antistatic surface film layer is using electrically conductive polyaniline, conductive titanium dioxide, conductive cloud Female powder is combined with polyvinyl chloride, base material, and antistatic surface film layer hot pressing is bonded to form antifouling anti-scribble high-molecular decorative film, Preparation method includes the following steps：
1）Prepare polyvinyl chloride base material
1.1 dispensing
Use Corvic for major ingredient, according to the ratio be added reinforcing agent, conductive titanium dioxide, plasticizer, background color slurry and secondly The weight proportion of monooctyl ester, each component is as follows:
100 parts of Corvic
10 parts of reinforcing agent
30-35 parts of conductive titanium dioxide
20-25 parts of dioctyl ester
Background color starches 1 ~ 2 part
1 ~ 2 part of other plasticizing adjuvants
1.2, it stirs
1.3, it is plasticized
1.4, Polish filtration
1.5, roll
1.6, sided corona treatment
1.7, cooling
2）Prepare antistatic surface film layer
2.1, dispensing
It uses Corvic for major ingredient, dioctyl ester, conductive titanium dioxide, conductive mica powder, electrically conductive polyaniline is added according to the ratio And other plasticizing aids, the weight proportion of each component are:
100 parts of Corvic
3-10 parts of dioctyl ester
10-28 parts of conductive titanium dioxide
0-20 parts of conductive mica powder
1-15 parts of electrically conductive polyaniline
1 ~ 2 part of other plasticizing adjuvants
2.2, it stirs
2.3, plasticizing is blended
2.4, Polish filtration
2.5, roll
2.6, sided corona treatment
2.7, cooling
3）Hot pressing is bonded
3.1, smooth to dry
3.2, opposite side
3.3, degasification
3.4, hot pressing is bonded
3.5, cooling and shaping
Advantageous effect：
A kind of preparation method of Antistatic type high-molecular decorative film prepared by the present invention, makes full use of intrinsically conducting polyaniline It introduces, acts synergistically without tassement polaire with conduction, the anti-quiet of polymeric membrane can be enhanced under the premise of not influencing material mechanical performance Electrical property.
A kind of preparation method of Antistatic type high-molecular decorative film according to the present invention, it is poly- using polyvinyl chloride, conduction Aniline, dioctyl ester etc. are primary raw material, of low cost, simple for process, and existing process units and technique can be used directly；It prepares anti- It answers process without carrying out by-product separation, is suitable for continuous industrial production.
Antistatic type high-molecular decorative film prepared by the method for the present invention has a wide range of application in furniture decoration material field General, gained decorating film surface resistivity is up to 7.8 × 108Ω。
Specific implementation mode
Following embodiment the present invention is furture elucidated content, but be not used in and limit the scope of the invention.
Embodiment
1）Prepare polyvinyl chloride base material
1.1 dispensing
It uses Corvic for major ingredient, reinforcing agent, titanium dioxide, plasticizer, background color slurry and its dioctyl ester is added according to the ratio, The weight proportion of its each component is as follows:
100 parts of Corvic
10 parts of reinforcing agent
31 parts of titanium dioxide
10 parts of dioctyl ester
Background color starches 1 part
1 part of other plasticizing adjuvants
1.2, it stirs
Now blender is added in Corvic by the formulation material weighed up according to the ratio, and dioctyl ester, titanium dioxide, reinforcing agent is added, adds Heat is stirred evenly to 110 °C -130 °C
1.3, it is plasticized
The hot material being thoroughly mixed is conveyed into mixer and is heated to 170-190 °C, is plasticized in sealed states
1.4, Polish filtration
The good material slitting shape of mill is conveyed into extruder, 140 °C -160 °C is heated to, is squeezed, stir pusher refining, It pushes to die orifice through 120 mesh filter screens, " flake " and contaminant filter that will be plasticized, this process extruder, by what is be plasticized Hot material is conveyed into two roller open mills and turn refining 15 minutes, further rapid to close plasticizing, two roll temperature cylinder temperature at 190-195 °C, Screw speed is 85-95 revs/min
1.5, roll
It will refine and filtered clinker be conveyed into five roll calendars into strips, calendering film forming is required according to thickness, width specifications, Five roller heating roller temperatures are controlled at 180-185 °C, and wire velocity control is at 120-130 ms/min
1.6, sided corona treatment
1.7, cooling
2）Prepare antistatic surface film layer
2.1, dispensing
It uses Corvic for major ingredient, dioctyl ester, conductive titanium dioxide, electrically conductive polyaniline, conductive mica powder is added according to the ratio And other plasticizing aids, the weight proportion of each component are:
100 parts of Corvic
5 parts of dioctyl ester
28 parts of conductive titanium dioxide
1 part of conductive mica powder
15 parts of electrically conductive polyaniline
1 part of other plasticizing adjuvants
2.2, it stirs
Now blender is added in Corvic by the formulation material weighed up according to the ratio, and dioctyl ester, conductive titanium dioxide, conduction is added Mica powder, electrically conductive polyaniline are heated to 110 °C -130 °C, stir evenly；
2.3, plasticizing is blended
The hot material being thoroughly mixed is conveyed into mixer and is heated to 170-190 °C, combined polymerization in sealed states is plasticized；
2.4, Polish filtration
The good material slitting shape of mill is conveyed into extruder, 140 °C -160 °C is heated to, is squeezed, stir pusher refining, It pushes to die orifice through 120 mesh filter screens, " flake " and contaminant filter that will be plasticized, this process extruder, by what is be plasticized Hot material is conveyed into two roller open mills and turn refining 15 minutes, further rapid to close plasticizing, two roll temperature cylinder temperature at 190-195 °C, Screw speed is 85-95 revs/min；
2.5, roll
It will refine and filtered clinker be conveyed into five roll calendars into strips, calendering film forming is required according to thickness, width specifications, Five roller heating roller temperatures are controlled at 180-185 °C, and wire velocity control is at 120-130 ms/min；
2.6, sided corona treatment
2.7, cooling
3）Hot pressing is bonded
3.1, smooth to dry
Base material and functional film layer are made base material and functional film layer longitudinally smooth out whole nothing by hot pressing fitting through twill jockey pulley respectively first Gauffer；
3.2, opposite side
To its base material and functional film layer both sides, two layers of portraitlandscape are adjusted in conjunction with jockey pulley；
3.3, degasification
It is folded through double roller rubber roller, the air put together between base material together and functional film layer first squeezes out to be bonded tightly again, is prevented Bubble is only generated when thermal-adhering；
3.4, hot pressing is bonded
Base material and functional film layer deaerated rear and fit closely together are heated to 160-170 °C through two-wheel hot-pressing roller, pressurization 0.4kg fits together two layers of base material and functional film layer fusion hot pressing in the initial plasticizing phase；
3.5, cooling and shaping
The composite membrane in hot pressing fitting jail is delivered to the cooling of five rollers through deflector roll, five rollers use spacer water cooling, water temperature to control at 15 ° C hereinafter, make material shaping after cooling；
Gained composite film surface resistivity reaches 7.8 × 108Ω has certain antistatic property.

Claims (1)

1. a kind of preparation method of Antistatic type high-molecular decorative film, it is characterised in that the Antistatic type polymeric membrane includes polychlorostyrene Ethylene-based layer base material and antistatic surface film layer, the antistatic surface film layer is using electrically conductive polyaniline, conductive titanium dioxide, conduction Mica powder is combined with polyvinyl chloride, base material, and antistatic surface film layer hot pressing is bonded to form antifouling anti-scribble high-polymer decorative Film, preparation method includes the following steps：
1）Prepare polyvinyl chloride base material
1.1 dispensing
Use Corvic for major ingredient, according to the ratio be added reinforcing agent, conductive titanium dioxide, plasticizer, background color slurry and secondly The weight proportion of monooctyl ester, each component is as follows:
100 parts of Corvic
10 parts of reinforcing agent
30-35 parts of conductive titanium dioxide
20-25 parts of dioctyl ester
Background color starches 1 ~ 2 part
1 ~ 2 part of other plasticizing adjuvants
1.2, it stirs
1.3, it is plasticized
1.4, Polish filtration
1.5, roll
1.6, sided corona treatment
1.7, cooling
2）Prepare antistatic surface film layer
2.1, dispensing
It uses Corvic for major ingredient, dioctyl ester, conductive titanium dioxide, conductive mica powder, electrically conductive polyaniline is added according to the ratio And other plasticizing aids, the weight proportion of each component are:
100 parts of Corvic
3-10 parts of dioctyl ester
10-28 parts of conductive titanium dioxide
0-20 parts of conductive mica powder
1-15 parts of electrically conductive polyaniline
1 ~ 2 part of other plasticizing adjuvants
2.2, it stirs
2.3, plasticizing is blended
2.4, Polish filtration
2.5, roll
2.6, sided corona treatment
2.7, cooling
3）Hot pressing is bonded
3.1, smooth to dry
3.2, opposite side
3.3, degasification
3.4, hot pressing is bonded
3.5, cooling and shaping.
CN201810612073.4A 2018-06-14 2018-06-14 A kind of preparation method of Antistatic type high-molecular decorative film Pending CN108773147A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810612073.4A CN108773147A (en) 2018-06-14 2018-06-14 A kind of preparation method of Antistatic type high-molecular decorative film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810612073.4A CN108773147A (en) 2018-06-14 2018-06-14 A kind of preparation method of Antistatic type high-molecular decorative film

Publications (1)

Publication Number Publication Date
CN108773147A true CN108773147A (en) 2018-11-09

Family

ID=64024989

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810612073.4A Pending CN108773147A (en) 2018-06-14 2018-06-14 A kind of preparation method of Antistatic type high-molecular decorative film

Country Status (1)

Country Link
CN (1) CN108773147A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110652100A (en) * 2019-09-05 2020-01-07 安徽名扬刷业有限公司 Prevent variable brush roller of static
CN113442528A (en) * 2021-04-01 2021-09-28 张豪 Anti-static plastic film and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1073229A (en) * 1991-12-03 1993-06-16 上海宝山钢铁总厂 A kind ofly be used for anlistatig wallpaper
CN101850689A (en) * 2010-03-08 2010-10-06 徐文亚 Method for preparing clinquant high molecular decorative film
CN103738035A (en) * 2013-10-21 2014-04-23 江阴华东装饰材料有限公司 Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1073229A (en) * 1991-12-03 1993-06-16 上海宝山钢铁总厂 A kind ofly be used for anlistatig wallpaper
CN101850689A (en) * 2010-03-08 2010-10-06 徐文亚 Method for preparing clinquant high molecular decorative film
CN103738035A (en) * 2013-10-21 2014-04-23 江阴华东装饰材料有限公司 Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王文广: "《塑料配方设计》", 30 September 2001, 北京化学工业出版社 *
陈玉阁等: "《电工电子技术基础教程》", 31 August 2011, 中央广播电视大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110652100A (en) * 2019-09-05 2020-01-07 安徽名扬刷业有限公司 Prevent variable brush roller of static
CN113442528A (en) * 2021-04-01 2021-09-28 张豪 Anti-static plastic film and preparation process thereof

Similar Documents

Publication Publication Date Title
CN104327530B (en) Preparation method of flame-retardant and antistatic wood-plastic composite material
CN108752793A (en) A kind of preparation method of antifouling anti-scribble high-molecular decorative film
CN108773147A (en) A kind of preparation method of Antistatic type high-molecular decorative film
CN107152146B (en) Negative ion PVC floor and preparation method thereof
CN109594745B (en) Anti-slip colorful PVC waterproof coiled material floor
CN104385735A (en) Colored polyvinyl chloride foamed sheet and preparation method thereof
EP3932666A1 (en) Light-shielding composite film, manufacturing method therefor and use thereof
CN104589746A (en) Composite sheet structure for decoration and preparation method of composite sheet structure
CN111423680A (en) Polyvinyl butyral remainder modified granulated substance, manufacturing process thereof and method for producing product by using casting mode through granulated substance
CN113321838A (en) Antibacterial wear-resistant PVC floor and forming process thereof
KR20180107950A (en) Adhesive wall finish and the production method using the compressed plastic panel
CN108503977A (en) A kind of high-strength composite plastic-wood material
CN106905638A (en) A kind of flame-proof environmental protection PVC floors and preparation method thereof
CN110072938A (en) Floor covering and its manufacturing method
CN102485816A (en) Novel thermoplastic powder coating
CN106046531B (en) A kind of two-sided bronze printing folder flower table mat and its drawing process
EP2398635B1 (en) Decorative welding rod for surface coverings, decorative welding rod use and method for its manufacturing.
CN104760367A (en) Novel cellulose acetate sheet and making method thereof
CN103182820B (en) A kind of CPP direct response membrane
CN108081723A (en) A kind of co-extrusion fireproof flame retarding decorative board and preparation method thereof
TWI257379B (en) Homogeneous amorphous marble flooring and process of making the same
CN107419615A (en) A kind of preparation method of antistatic wallpaper
KR101990287B1 (en) Interior and exterior architectural materials and manufacuring method therefor
CN113462044B (en) Composite embossed flexible foam material and preparation method thereof
CN109438909A (en) A kind of anti-flaming ABS material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181109

WD01 Invention patent application deemed withdrawn after publication