CN103738035A - Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof - Google Patents

Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof Download PDF

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Publication number
CN103738035A
CN103738035A CN201310500581.0A CN201310500581A CN103738035A CN 103738035 A CN103738035 A CN 103738035A CN 201310500581 A CN201310500581 A CN 201310500581A CN 103738035 A CN103738035 A CN 103738035A
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China
Prior art keywords
plasticizing
antifouling
film
preparation
printing
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CN201310500581.0A
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CN103738035B (en
Inventor
赵霞
费春燕
朱建雄
徐伟
徐妤
赵丽芳
李向华
王燕
朱广和
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Jiangsu Econess Energy Co.,Ltd.
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Jiangyin Huadong Decorative Material Co Ltd
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Abstract

The invention relates to an antifouling antibacterial high-molecular furniture decorative film and a preparation method thereof. The antifouling antibacterial high-molecular furniture decorative film is characterized by comprising a base material, an antibacterial film and a printed surface film. The antifouling antibacterial high-molecular furniture decorative film is formed by hot-pressing lamination of the base material, the antibacterial film and the printed surface film. The preparation method of the antifouling antibacterial high-molecular furniture decorative film comprises the following steps: step one, preparing the base material; step two, preparing the antibacterial film; step three, preparing the printed surface film; step four, printing the surface film; and step five, carrying out hot-pressing lamination. The antifouling antibacterial high-molecular furniture decorative film has the advantages of fire resistance and high strength, and the preparation method has the advantages of low production cost and high product production quality.

Description

Antifouling and antibiosis macromolecule furniture decoration film and preparation method thereof
Technical field
The present invention relates to a kind of antifouling and antibiosis macromolecule furniture decoration film and preparation method thereof, belong to ornament materials preparation field.
Background technology
Modern furniture product is paid much attention to decoration, to the ornament materials of top-grade furniture, and the main dependence on import of China, existing domestic ornament materials can not reach due technique effect, such as, intensity is lower, antifouling and antibiosis ability, fire resistance are poor.Therefore seeking one, to have fire resistance and high-intensity antifouling and antibiosis macromolecule furniture decoration film and preparation method thereof particularly important.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency, a kind of fire resistance and high-intensity antifouling and antibiosis macromolecule furniture decoration film and preparation method thereof are provided.
The object of the present invention is achieved like this:
A kind of antifouling and antibiosis macromolecule furniture decoration film and preparation method thereof, this antifouling and antibiosis macromolecule furniture decoration film comprises base material, antibacterial film and printing facial mask, described base material, antibacterial film and printing facial mask hot pressing laminating form antifouling and antibiosis macromolecule furniture decoration film, and the preparation method of this antifouling and antibiosis macromolecule furniture decoration film comprises the following steps:
Step 1, prepare base material
1.1, batching
Employing polyvinyl chloride resin is major ingredient, by proportioning, adds PE reinforcing agent, 1000 object titanium dioxides, dioctyl ester, background color slurry and other plasticizing adjuvants, and the weight proportion of its each component is as follows:
100 parts of polyvinyl chloride resins
12 parts of PE reinforcing agents
1000 object titanium dioxide 25-30 parts
Dioctyl ester 20-25 part
1 ~ 2 part, background color slurry
1 ~ 2 part of other plasticizing adjuvant
1.2, stir
1.3, blend copolymerization plasticizing
1.4, refining is filtered
1.5, calendering
1.6, sided corona treatment
1.7, cooling
Step 2, prepare antibacterial film
2.1, batching
Employing polyvinyl chloride resin is major ingredient, by proportioning, adds dioctyl ester with, 1000 order titanium dioxides, antimicrobial silver ionic agent and other plasticizing auxiliary agents, and the weight proportion of its each component is:
100 parts of polyvinyl chloride resins
Dioctyl ester 20-23 part
1000 order titanium dioxide 25-28 parts
1 ~ 2 part of other plasticizing adjuvant
1 ~ 2 part of antimicrobial silver ionic agent
2.2, stir
2.3, plasticizing
2.4, refining is filtered
2.5, calendering
2.6, antimicrobial silver sheath coating
2.7, sided corona treatment
2.8, cooling
Step 3, preparation printing facial mask
3.1, batching
Adopting PP plastics is major ingredient, by proportioning, adds PE reinforcing agent, dioctyl ester, fire-retardant N H1197, background color slurry and other plasticizing auxiliary agents, and the weight proportion of its each component is:
100 parts, PP plastics
10 parts of PE reinforcing agents
Dioctyl ester 18-20 part
1.5 parts of fire-retardant N H1197
1 ~ 2 part, background color slurry
1 ~ 2 part of other plasticizing auxiliary agent
3.2, stir
3.3, blend copolymerization plasticizing
3.4, refining is filtered
3.5, calendering
3.6, cooling
Step 4, facial mask are printed
4.1, allotment ink
4.2, printing machine heating
4.3, the inking up of getting the raw materials ready
4.4, start printing
4.5, dry
4.6, acupuncture
By completing the printing facial mask printing and dry, by spiked roller, carry out acupuncture;
Step 5, hot pressing laminating
5.1, smooth drying
5.2, opposite side
5.3, degasification
5.4, hot pressing laminating
5.5, cooling and shaping.
Preferred as one, 2.6, antimicrobial silver sheath application step is as follows:
The antibacterial film of calendering formation is delivered to antimicrobial silver sheath apparatus for coating by deflector roll and carries out silver ion antimicrobial agent coating, antimicrobial silver sheath apparatus for coating comprises twice applicator roll, per pass applicator roll rear is provided with scraper and warm-up mill, the antibacterial film of calendering formation is delivered to applicator roll by deflector roll and carries out silver ion antimicrobial agent slurry sizing, after the starching of per pass applicator roll, scraper scrapes unnecessary slurry, by scraper, pressurizeed and made slurry coating evenly, antibacterial film is successively by twice applicator roll and warm-up mill.
Preferred as one, silver ion agent and ethyl acetate proportioning that described silver ion antimicrobial agent slurry is 5:95 by weight ratio form.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention by adding fire-retardant N H1197 in printing surface film preparation, improved fire resistance, at base material, in the preparation of antibacterial film and printing facial mask, add reinforcing agent, improved intensity, in antibacterial film preparation, add silver ion, by acupuncture step, make the antibacterial film surface of product there is micropore, good permeability, silver ion can come out has good antifouling and antibiosis performance, during the coating of antimicrobial silver sheath, pass through twice applicator roll, the combination of scraper and warm-up mill, when making valuable silver ion reach optimum utilization, make again all even effect moulding the bests of silver ion antimicrobial agent coating.Therefore this invention antifouling and antibiosis macromolecule furniture decoration film has fire resistance and high-intensity advantage, and it is low that its preparation method has production cost, the advantage that production product quality is high.
The specific embodiment
A kind of antifouling and antibiosis macromolecule furniture decoration film the present invention relates to, it comprises base material, antibacterial film and printing facial mask, described base material, antibacterial film and printing facial mask hot pressing laminating form antifouling and antibiosis macromolecule furniture decoration film.Described base material is formed by polyvinyl chloride resin and the calendering of PE reinforcing agent blend copolymerization, when prepared by described antibacterial film, inside is added with silver ion, during described printing surface film preparation, add fire retardant calendering to form, then be printed as on request the printing facial mask of various pattern colors, and described printing facial mask, antibacterial film and base material directly develop.
The preparation method of this antifouling and antibiosis macromolecule furniture decoration film comprises the following steps:
Step 1, prepare base material
1.1, batching
Employing polyvinyl chloride resin is major ingredient, by proportioning, adds PE reinforcing agent, 1000 object titanium dioxides, dioctyl ester, background color slurry and other plasticizing adjuvants.The weight proportion of its each component is as follows:
100 parts of polyvinyl chloride resins
12 parts of PE reinforcing agents
1000 object titanium dioxide 25-30 parts
Dioctyl ester 20-25 part
1 part, background color slurry
1 part of other plasticizing adjuvant
Wherein background color slurry can be: natural wood color slurry, red wingceltis, red sandalwood mill base material, Manchurian ash and pear wood mill base material.
Other plasticizing adjuvants can be: plastics reinforcing agent, plastics are high temperature resistant dose, plastic extrusion forming lubricant.
1.2, stir
By proportioning, weigh up formulation material, first polyvinyl chloride resin is added to mixer, then add PE reinforcing agent and 1000 object titanium dioxides, stir 3 minutes, then add dioctyl ester, stir after 7 minutes and add again background color to starch and other plasticizing adjuvants, then stir 5 minutes.
Omnidistance whipping temp is 105 ~ 115 ℃, and mixing speed is 145 ~ 160 turn/min.
1.3, blend copolymerization plasticizing
Add banbury to be heated to 170 ~ 175 ℃ the compound being fully stirred, with rotating speed polymerization plasticizing under sealing state of 120 ~ 130 turn/min, this process is 20 minutes, makes the plasticizing of compound copolymerization.
1.4, refining is filtered
The compound having plastified is transported to extruder, extruder control temperature is at 175 ~ 180 ℃, and extruder screw rotating speed is turn/min of 85-95, and extruder pushes to advance and stirs refining, then push to die orifice footpath 180 order screen packs, " flake " and the contaminant filter of not plasticizing are fallen.
1.5, calendering
The clinker conveyor of plasticizing completely is after filtering entered to five roll calendars, according to thickness, width, specification requirement, be rolled into the opaque base material of all size.The calendering heating roller temperature of five roll calendars is controlled at 180 ~ 185 ℃, turn/min of rotating speed 40 ~ 42.
1.6, sided corona treatment
The base material of calendering formation is delivered to corona treatment plant by deflector roll, and the front of base material impacts processing through high-pressure electrostatic.
1.7, cooling
It is standby that base material after sided corona treatment is delivered to five roller spacer cooling cylinder roller rolling after cooling through deflector roll again, and chill-roll temperature is controlled at 10 ~ 30 ℃.
Step 2, prepare antibacterial film
2.1, batching
Adopt polyvinyl chloride resin, add antimicrobial silver ionic agent, dioctyl ester with, 1000 order titanium dioxides and other plasticizing auxiliary agents, the weight proportion of its each component is:
100 parts of polyvinyl chloride resins
Dioctyl ester 20-23 part
1000 order titanium dioxide 25-28 parts
1 part of other plasticizing adjuvant
1 part of antimicrobial silver ionic agent
2.2, stir
By proportioning, weigh up formulation material, first polyvinyl chloride resin is added, then add 1000 order titanium dioxides to stir 3 minutes, then add dioctyl ester and antimicrobial silver ionic agent to stir 7 minutes, then add other plasticizing adjuvants, then stir 5 minutes.
Omnidistance whipping temp is 115 ℃, and mixing speed is 145 ~ 160 turn/min.
2.3, plasticizing
Add banbury to be heated to 155 ~ 160 ℃ the compound being fully stirred, with rotating speed polymerization plasticizing under sealing state of 120 ~ 130 turn/min.This process is 22 minutes, makes the plasticizing of compound copolymerization.
2.4, refining is filtered
The compound having plastified is transported to extruder, extruder control temperature is at 160 ~ 165 ℃, and extruder screw rotating speed is 70 ~ 80 turn/min, and extruder pushes to advance and stirs refining, then push to die orifice footpath 200 order screen packs, " flake " and the contaminant filter of not plasticizing are fallen.
2.5, calendering
The clinker conveyor of plasticizing completely is after filtering entered to five roll calendars, according to thickness, width, specification requirement, be rolled into antibacterial film.The calendering heating roller temperature of five roll calendars is controlled at 165 ~ 170 ℃, turn/min of rotating speed 38 ~ 40.
2.6, antimicrobial silver sheath coating
The antibacterial film of calendering formation is delivered to antimicrobial silver sheath apparatus for coating by deflector roll and carries out silver ion antimicrobial agent coating.Silver ion agent is become to the silver ion antimicrobial agent slurry of 5:95 with ethyl acetate proportioning.At calendering procedure after-frame Zhuan Er road applicator roll, form antimicrobial silver sheath apparatus for coating, the antibacterial film of calendering formation, by silver ion antimicrobial agent slurry on two roads, is installed during this time additional to warm-up mill and makes the antibacterial film surface slurry solvent volatilization after starching after per pass applicator roll.And by scraper, unnecessary slurry is scraped and fallen into stock tank after each starching.Meanwhile, by scraper, pressurize and make slurry coating evenly, and scraper adjustable pressure, by regulating pressure to control starching amount.In order to make valuable silver ion reach optimum utilization, except scraper regulates, also by two road coating processes, slurry concentration proportioning, to very rare, is both saved to silver ion antimicrobial agent use amount thereby reach, make again all even effect moulding the bests of silver ion antimicrobial agent coating.Silver ion antimicrobial agent slurry applicator roll linear velocity Yu Qian road calender is synchronous.Scraper pressure is at 0.6kg ~ 0.8kg, and heating roller temperature is controlled at 135 ~ 140 ℃.
2.7, sided corona treatment
Antibacterial film after the coating of antimicrobial silver sheath is delivered to corona treatment plant through deflector roll, and positive and negative impacts processing through high-pressure electrostatic.
2.8, cooling
It is standby that antibacterial film after sided corona treatment is delivered to five roller spacer cooling cylinder roller rolling after cooling through deflector roll.Cooling cylinder roll temperature is controlled at 10 ~ 20 ℃.
Step 3, preparation printing facial mask
3.1, batching
Adopting PP plastics is major ingredient, adds PE reinforcing agent, dioctyl ester, fire-retardant N H1197, background color slurry and other plasticizing auxiliary agents, and the weight proportion of its each component is:
100 parts, PP plastics
10 parts of PE reinforcing agents
Dioctyl ester 18-20 part
1.5 parts of fire-retardant N H1197
1 part, background color slurry
1 part of other plasticizing auxiliary agent
3.2, stir
By proportioning, weigh up formulation material, first PP plastics are added to mixer, then add PE reinforcing agent, stir 2 minutes, then add dioctyl ester to stir 5 minutes, then add fire-retardant N H1197 and other plasticizing auxiliary agents to stir 3 minutes, finally add background color slurry to stir 2 minutes.
Omnidistance whipping temp is 105 ~ 115 ℃, and mixing speed is 145 ~ 160 turn/min.
3.3, blend copolymerization plasticizing
Add banbury to be heated to 170 ~ 175 ℃ the compound being fully stirred, with rotating speed polymerization plasticizing under sealing state of 125 ~ 130 turn/min.This process is 22 minutes, makes the plasticizing of compound copolymerization.
3.4, refining is filtered
The compound having plastified is transported to extruder, extruder control temperature is at 175 ~ 180 ℃, and extruder screw rotating speed is 85 ~ 95 turn/min, and extruder pushes to advance and stirs refining, then push to die orifice footpath 220 order screen packs, " flake " and the contaminant filter of not plasticizing are fallen.
3.5, calendering
The clinker conveyor of plasticizing completely is after filtering entered to five roll calendars, according to thickness, width, specification requirement, be rolled into the very thin background color that has, have the antibacterial film of anti-flaming function.The calendering heating roller temperature of five roll calendars is controlled at 180 ~ 185 ℃, turn/min of rotating speed 95 ~ 105.
3.6, cooling
The printing facial mask of moulding is delivered to five roller spacer cooling cylinder roller rolling after cooling through deflector roll standby.Cooling cylinder roll temperature is controlled at 10 ~ 20 ℃, the turn/min of rotating speed 95 ~ 105 of five roller spacer cooling cylinder rollers.
Step 4, facial mask are printed
4.1, allotment ink
By the deployed corresponding color and luster ink of specification requirement, the special good printing ink concentration of GPRS, configures rear container and should cover tightly and prevent volatilization, puts China ink standby.
4.2, printing machine heating
Start heating power supply, make printing machine need heat position and start to be heated to set point of temperature.
4.3, the inking up of getting the raw materials ready
Printing machine unreeling shaft on printing facial mask frame to be printed, regulate tension, to good limit, deployed ink is injected to ink in printing press groove, and regularly stir and test ink concentration.
4.4, start printing
The printing of starting shooting when Deng Ge road warm-up mill liter reaches 130 ~ 135 ℃, and regulate rapidly opposite side, to flower, contraposition, and ink knife angle and pressure, regulate outer net and roller pressure.Regulate speed, normal line speed is 95 ~ 100m/min.
4.5, dry
The printing facial mask having printed is dried through multiple tracks warm-up mill, allows after solvent evaporates in ink through rolling after cooling.
4.6, acupuncture
By completing the printing facial mask printing and dry, by spiked roller, carry out acupuncture, take naked eyes, do not see pin hole as principle, grasp the pin hole degree of depth and size, then rolling is standby.
Step 5, hot pressing laminating
5.1, smooth drying
By make-up machine material axle on the base material preparing, antibacterial film and the printing facial mask frame that prints, base material is at bottom, and antibacterial film is in centre, and printing facial mask is at surface layer, and the printing surface of printing facial mask is at internal layer.Warm-up mill is heated to 100 ~ 105 ℃, adopts tension force roller and twill roller respectively by base material, antibacterial film and printing facial mask longitudinally, laterally draw floating whole, and by heating base material, the aqueous vapor evaporation on antibacterial film and printing facial mask surface, produces bubble and bright spot while preventing from fitting.
5.2, opposite side
Utilize " light eye " opposite side device and tension force deflector roll levelling base material, antibacterial film and printing facial mask vertical, horizontal trend, dislocation laminating prevents from wandering off.
5.3, degasification
Through degasification two-wheel, fold, base material, antibacterial film and printing facial mask binding face to air first squeeze out and remerge, while preventing hot pressing laminating, produce bubble.
5.4, hot pressing laminating
Base material after degasification and that be combined, antibacterial film and printing facial mask are heated to 160 ~ 170 ℃ through two-wheel roller, pressurization 0.4kg, by three layers of hotting mask pressurizing attaching jail in the first plasticizing phase together.
5.5, cooling and shaping
The hot pressing firm hotting mask of fitting becomes antifouling and antibiosis macromolecule furniture decoration film finished product through the then rolling of getting off of the upper chill roll cooling and shaping of deflector roll traction.
5.1 ~ 5.5 operation speed are 60-65m/min.

Claims (3)

1. antifouling and antibiosis macromolecule furniture decoration film and preparation method thereof, it is characterized in that this antifouling and antibiosis macromolecule furniture decoration film comprises base material, antibacterial film and printing facial mask, described base material, antibacterial film and printing facial mask hot pressing laminating form antifouling and antibiosis macromolecule furniture decoration film, and the preparation method of this antifouling and antibiosis macromolecule furniture decoration film comprises the following steps:
Step 1, prepare base material
1.1, batching
Employing polyvinyl chloride resin is major ingredient, by proportioning, adds PE reinforcing agent, 1000 object titanium dioxides, dioctyl ester, background color slurry and other plasticizing adjuvants, and the weight proportion of its each component is as follows:
100 parts of polyvinyl chloride resins
12 parts of PE reinforcing agents
1000 object titanium dioxide 25-30 parts
Dioctyl ester 20-25 part
1 ~ 2 part, background color slurry
1 ~ 2 part of other plasticizing adjuvant
1.2, stir
1.3, blend copolymerization plasticizing
1.4, refining is filtered
1.5, calendering
1.6, sided corona treatment
1.7, cooling
Step 2, prepare antibacterial film
2.1, batching
Employing polyvinyl chloride resin is major ingredient, by proportioning, adds dioctyl ester with, 1000 order titanium dioxides, antimicrobial silver ionic agent and other plasticizing auxiliary agents, and the weight proportion of its each component is:
100 parts of polyvinyl chloride resins
Dioctyl ester 20-23 part
1000 order titanium dioxide 25-28 parts
1 ~ 2 part of other plasticizing adjuvant
1 ~ 2 part of antimicrobial silver ionic agent
2.2, stir
2.3, plasticizing
2.4, refining is filtered
2.5, calendering
2.6, antimicrobial silver sheath coating
2.7, sided corona treatment
2.8, cooling
Step 3, preparation printing facial mask
3.1, batching
Adopting PP plastics is major ingredient, by proportioning, adds PE reinforcing agent, dioctyl ester, fire-retardant N H1197, background color slurry and other plasticizing auxiliary agents, and the weight proportion of its each component is:
100 parts, PP plastics
10 parts of PE reinforcing agents
Dioctyl ester 18-20 part
1.5 parts of fire-retardant N H1197
1 ~ 2 part, background color slurry
1 ~ 2 part of other plasticizing auxiliary agent
3.2, stir
3.3, blend copolymerization plasticizing
3.4, refining is filtered
3.5, calendering
3.6, cooling
Step 4, facial mask are printed
4.1, allotment ink
4.2, printing machine heating
4.3, the inking up of getting the raw materials ready
4.4, start printing
4.5, dry
4.6, acupuncture
By completing the printing facial mask printing and dry, by spiked roller, carry out acupuncture;
Step 5, hot pressing laminating
5.1, smooth drying
5.2, opposite side
5.3, degasification
5.4, hot pressing laminating
5.5, cooling and shaping.
2. a kind of antifouling and antibiosis macromolecule furniture decoration film according to claim 1 and preparation method thereof, is characterized in that 2.6, antimicrobial silver sheath application step is as follows:
The antibacterial film of calendering formation is delivered to antimicrobial silver sheath apparatus for coating by deflector roll and carries out silver ion antimicrobial agent coating, antimicrobial silver sheath apparatus for coating comprises twice applicator roll, per pass applicator roll rear is provided with scraper and warm-up mill, the antibacterial film of calendering formation is delivered to applicator roll by deflector roll and carries out silver ion antimicrobial agent slurry sizing, after the starching of per pass applicator roll, scraper scrapes unnecessary slurry, by scraper, pressurizeed and made slurry coating evenly, antibacterial film is successively by twice applicator roll and warm-up mill.
3. a kind of antifouling and antibiosis macromolecule furniture decoration film according to claim 2 and preparation method thereof, is characterized in that silver ion agent and ethyl acetate proportioning that described silver ion antimicrobial agent slurry is 5:95 by weight ratio form.
CN201310500581.0A 2013-10-21 2013-10-21 Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof Active CN103738035B (en)

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CN105925103A (en) * 2016-06-23 2016-09-07 江苏科德宝建筑节能科技有限公司 Production method of antibacterial coating, antibacterial coating and ventilated antibacterial film containing antibacterial coating
CN106079782A (en) * 2016-06-30 2016-11-09 浙江汇锋新材料股份有限公司 A kind of furniture film and processing method thereof
CN106118155A (en) * 2016-06-23 2016-11-16 江苏科德宝建筑节能科技有限公司 A kind of antibiotic paint and air-permeable anti-bacterial film and waterproof and breathable Antibiotic Membrane thereof
CN108752793A (en) * 2018-06-14 2018-11-06 江苏海美新材料有限公司 A kind of preparation method of antifouling anti-scribble high-molecular decorative film
CN108773147A (en) * 2018-06-14 2018-11-09 江苏海美新材料有限公司 A kind of preparation method of Antistatic type high-molecular decorative film
CN109094124A (en) * 2018-08-28 2018-12-28 江苏海美新材料有限公司 Antifouling and antibiosis skin sense furniture decoration film and preparation method thereof
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CN106079782A (en) * 2016-06-30 2016-11-09 浙江汇锋新材料股份有限公司 A kind of furniture film and processing method thereof
CN106079782B (en) * 2016-06-30 2018-01-30 浙江汇锋新材料股份有限公司 A kind of furniture film and its processing method
CN108752793A (en) * 2018-06-14 2018-11-06 江苏海美新材料有限公司 A kind of preparation method of antifouling anti-scribble high-molecular decorative film
CN108773147A (en) * 2018-06-14 2018-11-09 江苏海美新材料有限公司 A kind of preparation method of Antistatic type high-molecular decorative film
CN109094124A (en) * 2018-08-28 2018-12-28 江苏海美新材料有限公司 Antifouling and antibiosis skin sense furniture decoration film and preparation method thereof
CN111571838A (en) * 2020-05-09 2020-08-25 杭州丹诗丽装饰有限公司 Antibacterial decorative film and preparation method thereof
CN111923545A (en) * 2020-07-23 2020-11-13 安徽嘉阳新材料科技有限公司 PVC furniture film and processing technology thereof
CN111923545B (en) * 2020-07-23 2023-09-15 安徽嘉阳新材料科技有限公司 PVC furniture film and processing technology thereof
CN114103339A (en) * 2021-10-27 2022-03-01 南通百晟新材料科技有限责任公司 Bending-resistant and impact-resistant steel plate water-based decorative film and preparation method thereof
CN115042491A (en) * 2022-06-22 2022-09-13 全椒光太胶粘制品有限公司 Antibacterial furniture film and production process thereof

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